JP2019074181A - Air spring - Google Patents

Air spring Download PDF

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JP2019074181A
JP2019074181A JP2017202247A JP2017202247A JP2019074181A JP 2019074181 A JP2019074181 A JP 2019074181A JP 2017202247 A JP2017202247 A JP 2017202247A JP 2017202247 A JP2017202247 A JP 2017202247A JP 2019074181 A JP2019074181 A JP 2019074181A
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layer
flexible member
rubber
thickness
air spring
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JP7014562B2 (en
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裕喜 安永
Hiroyoshi Yasunaga
裕喜 安永
薫 堀内
Kaoru Horiuchi
薫 堀内
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Toyo Tire Corp
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Toyo Tire and Rubber Co Ltd
Toyo Tire Corp
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Abstract

To provide an air spring capable of improving fire retardancy in a state of maintaining mechanical characteristics and physical characteristics of a cylindrical flexible member.SOLUTION: An air spring comprises an upper member 2, a lower member 3 arranged below the upper member 2, and a cylindrical flexible member 4 interposed between the upper member 2 and the lower member 3. The flexible member 4 comprises an outer layer 15, an inner layer 16, and an intermediate layer 17 interposed between the outer layer 15 and the inner layer 16. The outer layer 15 and the inner layer 16 are composed of a fire-retardant rubber composition. The intermediate layer is composed a reinforcement rubber layer where a reinforcement cord 18 is embedded in the fire-retardant rubber composition. An average thickness of a thickness Y of the inner layer 16 and a thickness X of the outer layer 15 are equal to or more than 1.1 times of a thickness Z of the intermediate layer 17.SELECTED DRAWING: Figure 3

Description

本発明は、車両用、特に鉄道車両用として好適に用いられる、難燃性を備えた空気ばねに関するものである。   The present invention relates to a flame-retardant air spring suitably used for vehicles, in particular for railway vehicles.

近年、欧州においては、様々な分野において防炎要件が厳しくなっており、鉄道車両についても、欧州の新しい統一規格であるEN45545−2が制定されるに至っている。空気ばねは、筒状の可撓部材(ダイヤフラム等)や、ストッパーなど、ゴム状弾性体として有機材料が使用されていることから、これらの部材について上記基準をクリアすることが要求される。上記基準では、ハロゲン含有ガスの発生量も厳しく制限される。   In recent years, in Europe, flameproof requirements have become strict in various fields, and EN45545-2 which is a new unified standard of Europe has come to be established also for railway vehicles. Since an air spring uses an organic material as a rubber-like elastic body, such as a cylindrical flexible member (diaphragm or the like), a stopper, etc., it is required to clear the above criteria for these members. With the above criteria, the amount of halogen-containing gas generated is also severely limited.

EN45545−2では、鉄道車両に用いられる主要ゴム部材の難燃性の評価は、ISO 5660−1に準じてコーンカロリーメータ法による発熱試験(以下、発熱試験と略する。)によって行うことが規定されており、この方法で測定されたMaximum Average Rate of Heat Emission(以下、MARHE)の値が、所定値以下であることが要求される。   In EN 45545-2, it is stipulated that the evaluation of the flame retardancy of the main rubber members used for rail vehicles is carried out by a heat generation test (hereinafter abbreviated as heat generation test) by the cone calorimeter method according to ISO 5660-1. It is required that the value of Maximum Average Rate of Heat Emission (hereinafter, MARHE) measured by this method is equal to or less than a predetermined value.

具体的に、ハザードレベル(HL)1及び2では、MARHE値が90以下、HL3では、MARHE値が60以下であることが要求される。上記発熱試験に供せられる試験片のサイズは10cm×10cmであり、試験片の厚みは、ダイヤフラムの厚みのままとされる(ただし、試料片の最大厚みは25mm以下)。   Specifically, hazard levels (HL) 1 and 2 require MARHE values of 90 or less, and HL3 require MARHE values of 60 or less. The size of the test piece to be subjected to the heat generation test is 10 cm × 10 cm, and the thickness of the test piece is the same as the thickness of the diaphragm (however, the maximum thickness of the test piece is 25 mm or less).

ハロゲン系難燃剤を含まないノンハロゲンの難燃性ゴムとして、たとえば、特許文献1に示すように、クロロプレンゴムに対して水酸化マグネシウム及び赤燐を配合した難燃性ゴムが開示されている。また、特許文献2には、ポリリン酸塩及び水酸化アルミニウムを配合した難燃性ゴム組成物が開示されている。このように、ノンハロゲンの難燃性ゴム組成物として、リン系難燃剤や金属水酸化物を組み合わせて配合したものが知られている。   As a non-halogen flame retardant rubber which does not contain a halogen-based flame retardant, for example, as shown in Patent Document 1, a flame retardant rubber is disclosed in which magnesium hydroxide and red phosphorus are mixed with chloroprene rubber. Patent Document 2 discloses a flame retardant rubber composition containing a polyphosphate and aluminum hydroxide. As described above, as a non-halogen flame retardant rubber composition, one in which a phosphorus-based flame retardant and a metal hydroxide are combined and blended is known.

ところで、空気ばねを構成するダイヤフラムなどの筒状の可撓部材は、使用状態において、上端部と下端部とが上下左右方向に相対的に変位するため、良好な機械的特性(モジュラス、引張強度等)を備えることが要求される。さらに、耐候性、耐熱性、耐老化性等の物理的特性に優れていることも要求される。   By the way, since the upper end and the lower end are relatively displaced in the vertical and horizontal directions in use, a cylindrical flexible member such as a diaphragm constituting the air spring has good mechanical characteristics (modulus, tensile strength, etc.) Etc.) are required. Furthermore, it is also required to be excellent in physical properties such as weather resistance, heat resistance and aging resistance.

このような要求を満たすため、筒状の可撓部材は、一般的に、補強コードが埋設された補強ゴム層を中間層とし、その中間層の内側と外側とに保護ゴム層(外層及び内層)が積層された積層構造のものが使用される。上記積層構造を備えた筒状の可撓部材を難燃化する場合、各層を構成するゴム組成物中にリン系難燃剤や金属水酸化物を配合することが考えられる。   In order to satisfy such requirements, a cylindrical flexible member generally has a reinforcing rubber layer in which a reinforcing cord is embedded as an intermediate layer, and a protective rubber layer (an outer layer and an inner layer) on the inside and the outside of the intermediate layer. The thing of the laminated structure in which is laminated is used. When making the cylindrical flexible member provided with the said laminated structure flame-retardant, it is possible to mix | blend a phosphorus-type flame retardant and a metal hydroxide in the rubber composition which comprises each layer.

特開2005−146256号公報JP, 2005-146256, A 特開2010−047644号公報JP, 2010-047644, A

しかしながら、難燃剤として用いられる金属水酸化物は粉体であり、これをゴム組成物に配合すると、ゴム組成物の流動性が低下する。特に、補強コードが埋設される中間層を構成するゴム組成物に金属水酸化物を配合すると、ゴム組成物の流動性が低下することにより、補強コードとゴム組成物との間に未充填部分が残存したり、補強コードとゴム組成物との密着性の低下によるゴムの機械的特性の低下が懸念される。その一方で、金属水酸化物の配合量を減量すると、難燃性を発揮させるにはリン系難燃剤を多量に配合する必要が生じ、この場合もゴムの機械的特性の低下が懸念される。   However, the metal hydroxide used as a flame retardant is a powder, and when it is blended into the rubber composition, the flowability of the rubber composition is reduced. In particular, when a metal hydroxide is compounded into the rubber composition constituting the intermediate layer in which the reinforcing cords are embedded, the fluidity of the rubber composition is reduced, so that the unfilled portion between the reinforcing cords and the rubber composition There is a concern that the mechanical properties of the rubber may be reduced due to the remaining of the rubber and the adhesion between the reinforcing cord and the rubber composition. On the other hand, when the compounding amount of metal hydroxide is reduced, it is necessary to incorporate a large amount of a phosphorus-based flame retardant to exhibit flame retardancy, and also in this case, there is a concern that mechanical properties of the rubber may be deteriorated. .

また、中間層を構成するゴム組成物に難燃剤を配合しない場合には、内外層の難燃性を高めることで可撓部材全体としての難燃性を維持する必要が生じるが、配合できる難燃剤の量に限度がある。その結果、可撓部材全体としての難燃性はEN45545−2に規定されるHLに近いレベルとなり、発熱試験を複数回実施したときにはHLを超える場合も生じ得る。   Moreover, when a flame retardant is not mix | blended with the rubber composition which comprises an intermediate | middle layer, it becomes necessary to maintain the flame retardance as the whole flexible member by raising the flame retardance of inner and outer layers, but it can be mixable. There is a limit to the amount of flame retardant. As a result, the flame retardance as the whole flexible member becomes a level close to HL specified in EN 45545-2 and may occur even when the heat generation test is performed a plurality of times.

そこで、本発明では、筒状の可撓部材の機械的特性や物理的特性を維持しつつ、難燃性を向上させることが可能な空気ばねを提供することを目的とする。   So, in this invention, it aims at providing the air spring which can improve a flame retardance, maintaining the mechanical characteristic and physical characteristic of a cylindrical flexible member.

上記課題を解決するため、本発明の一態様として、上側部材と、前記上側部材の下方に配置される下側部材と、前記上側部材と前記下側部材の間に介装される筒状の可撓部材とを備えた空気ばねであって、前記可撓部材は、外層及び内層と、前記外層及び内層の間に介在される中間層とを備え、前記外層及び内層は、難燃性ゴム組成物から構成され、前記中間層は、非難燃性ゴム組成物に樹脂製の補強コードが埋設された補強ゴム層から構成され、前記内層の厚みと前記外層の厚みの平均厚み(以下、「内外層の平均厚み」という)が、前記中間層の厚みの1.1倍以上であることを特徴とする。   In order to solve the above problems, according to one aspect of the present invention, an upper member, a lower member disposed below the upper member, and a tubular member interposed between the upper member and the lower member An air spring comprising a flexible member, the flexible member comprising an outer layer and an inner layer, and an intermediate layer interposed between the outer layer and the inner layer, the outer layer and the inner layer being made of a flame retardant rubber The intermediate layer is composed of a reinforcing rubber layer in which a resin reinforcing cord is embedded in a non-combustible rubber composition, and the average thickness of the thickness of the inner layer and the thickness of the outer layer (hereinafter referred to It is characterized in that “the average thickness of the inner and outer layers” is 1.1 or more times the thickness of the intermediate layer.

本発明における難燃性は、ISO 5660−1に規定される発熱試験のMARHE値によって評価される。本発明において、難燃性ゴム組成物とは、難燃性ゴム組成物からなるゴム単体を発熱試験に供したときに、EN45545−2で要求される所定のHLを満たすMARHE値を有するものをいう。本発明者らは、種々のゴム組成物で上記発熱試験を行った結果、ゴムの組成にかかわらず、発熱試験の試験片の厚みが厚くなるほど、MARHE値が低下するとの知見を得て、本発明を完成させたものである。   The flame retardancy in the present invention is evaluated by the MARHE value of the heat generation test defined in ISO 5660-1. In the present invention, the flame retardant rubber composition refers to one having a MARHE value satisfying a predetermined HL required by EN 45545-2 when a single rubber composed of the flame retardant rubber composition is subjected to the heat generation test. Say. As a result of conducting the above-mentioned heat generation test with various rubber compositions, the inventors obtained the knowledge that the MARHE value decreases as the thickness of the test piece of the heat generation test becomes larger, regardless of the rubber composition. The invention is completed.

すなわち、本発明においては、機械的特性に大きな影響を及ぼす中間層のゴム組成物としては、難燃剤を配合しない非難燃性ゴム組成物を用い、外層及び内層を構成するゴム組成物として、難燃性ゴム組成物を用いている。これにより、筒状の可撓部材としての機械的特性の低下を抑制することが可能となる。   That is, in the present invention, as the rubber composition of the middle layer which greatly affects the mechanical properties, it is difficult to use a non-flame retardant rubber composition not containing a flame retardant as the rubber composition constituting the outer layer and the inner layer. A flame retardant rubber composition is used. Thereby, it becomes possible to suppress the fall of the mechanical characteristic as a cylindrical flexible member.

その一方で、中間層で使用されるゴム組成物は非難燃性ゴム組成物である。一般的な空気ばねの場合、筒状の可撓部材における内層、中間層及び外層の厚みは、各層とも同程度の厚みに設計される(中間層が2プライの場合)。そうすると、可撓部材全体としての難燃性は、中間層が難燃性を備えている場合に比べて低下することになる。その結果、内外層を構成するゴム組成物に難燃剤を多く配合しても、可撓部材全体としての難燃性はEN45545−2に規定されるHLに近いレベルとなる。 On the other hand, the rubber composition used in the intermediate layer is a non-flammable rubber composition. In the case of a general air spring, the thickness of the inner layer, the intermediate layer and the outer layer in the cylindrical flexible member is designed to be about the same thickness in each layer (in the case where the intermediate layer is two plies). In this case, the flame retardancy of the entire flexible member is reduced as compared to the case where the intermediate layer is provided with the flame retardancy. As a result, even if a large amount of a flame retardant is blended in the rubber composition constituting the inner and outer layers, the flame retardancy of the entire flexible member becomes a level close to the HL defined in EN 45545-2.

そこで、本発明では、内外層の平均厚みを、中間層の厚みの1.1倍以上に厚くすることで、可撓部材としてのMARHE値を低下させ、要求されるHLを安定してクリアすることが可能となる。なお、可撓部材は、基本的には、外層、中間層及び内層の3層構造とされるが、これに限らず、可撓部材の少なくとも一部に前記3層以外のゴム層を加えることも可能である。この場合は、追加するゴム層が難燃層であるか非難燃層であるかによって、可撓部材の厚みを調整すればよい。   Therefore, in the present invention, by increasing the average thickness of the inner and outer layers to 1.1 times or more the thickness of the intermediate layer, the MARHE value as the flexible member is lowered to stably clear the required HL. It becomes possible. Although the flexible member basically has a three-layer structure of an outer layer, an intermediate layer, and an inner layer, the present invention is not limited thereto, and rubber layers other than the three layers may be added to at least a part of the flexible member. Is also possible. In this case, the thickness of the flexible member may be adjusted depending on whether the rubber layer to be added is a flame retardant layer or a non-combustible layer.

すなわち、上側部材と、前記上側部材の下方に配置される下側部材と、前記上側部材と前記下側部材の間に介装される筒状の可撓部材とを備えた空気ばねであって、前記可撓部材は、外層及び内層と、前記外層及び内層の間に介在される中間層とを備え、前記外層及び内層は、難燃性ゴム組成物から構成された難燃層とされ、前記中間層は、非難燃性ゴム組成物に補強コードが埋設された補強ゴム層から構成された非難燃層とされ、前記難燃層の合計厚みが、前記非難燃層の厚みの2.2倍以上であるようにしてもよい。   That is, the air spring comprises an upper member, a lower member disposed below the upper member, and a cylindrical flexible member interposed between the upper member and the lower member. The flexible member includes an outer layer and an inner layer, and an intermediate layer interposed between the outer layer and the inner layer, and the outer layer and the inner layer are a flame retardant layer formed of a flame retardant rubber composition, The intermediate layer is a non-combustible layer formed of a reinforced rubber layer having a reinforcing cord embedded in the non-flammable rubber composition, and the total thickness of the flame retardant layer is 2.2 of the thickness of the non-flammable layer. It may be doubled or more.

前記中間層は、前記補強ゴム層が1層からなる単層構造であってもよいし、前記補強ゴム層が複数層積層された積層構造であってもよい。また、前記可撓部材は、下部及び上部の厚みよりも中間部の厚みが厚くなるように形成してもよい。   The intermediate layer may have a single-layer structure in which the reinforcing rubber layer is a single layer, or may have a laminated structure in which a plurality of the reinforcing rubber layers are stacked. The flexible member may be formed such that the thickness of the middle portion is larger than the thickness of the lower and upper portions.

本発明の一態様に係る空気ばねによれば、可撓部材において、中間層を構成するゴム組成物として非難燃性のものを使用し、外層及び内層を構成するゴム組成物として難燃性ゴム組成物を使用し、可撓部材の内外層の平均厚みを、中間層の厚みの1.1倍以上としたため、可撓部材の機械的特性や物理的特性の低下を抑えつつ、安定して難燃性を確保することが可能な空気ばねを得ることができる。   According to the air spring according to one aspect of the present invention, in the flexible member, the noncombustible one is used as the rubber composition constituting the intermediate layer, and the flame retardant rubber as the rubber composition constituting the outer layer and the inner layer. Since the composition is used and the average thickness of the inner and outer layers of the flexible member is made 1.1 times or more of the thickness of the intermediate layer, the decrease in mechanical properties and physical properties of the flexible member is suppressed stably. It is possible to obtain an air spring capable of securing flame retardancy.

本発明に係る空気ばねの第1実施形態を示す縦断面図Longitudinal sectional view showing a first embodiment of an air spring according to the present invention 図1の可撓部材を示す斜視図A perspective view showing the flexible member of FIG. 1 可撓部材の断面概略図Cross-sectional schematic view of the flexible member 本発明の第2実施形態を示す可撓部材の断面概略図The cross-sectional schematic of the flexible member which shows 2nd Embodiment of this invention 発熱試験における可撓部材の厚みとMARHE値の関係を示すグラフGraph showing relationship between thickness of flexible member and MARHE value in heat generation test

[第1実施形態]
以下、本発明の第1実施形態について図面を基に説明する。図1は、本発明に係る空気ばねの実施形態を示す縦断面図である。図2は、図1の空気ばねで使用される可撓部材を示す斜視図であり、図3は可撓部材の断面概略図である。
First Embodiment
Hereinafter, a first embodiment of the present invention will be described based on the drawings. FIG. 1 is a longitudinal sectional view showing an embodiment of the air spring according to the present invention. 2 is a perspective view showing a flexible member used in the air spring of FIG. 1, and FIG. 3 is a schematic cross-sectional view of the flexible member.

図1に示すように、本実施形態の空気ばね1は、鉄道車両用であり、上側部材2と、その下方に配置される下側部材3と、上側部材2及び下側部材3の間にダイヤフラムやベローズなどの筒状の可撓部材4を備える。上側部材2は、可撓部材4と車体とを接続する部材であり、本実施形態では上面板が使用されているが、これに限らず、たとえば、車体の一部を上側部材2として利用してもよい。下側部材3は、可撓部材4と台車枠とを接続する部材であり、本実施形態では一般にストッパーと称される弾性機構7を備えているが、これに限らず、たとえば、弾性機構7を除いた構成としてもよい。   As shown in FIG. 1, the air spring 1 of the present embodiment is for a railway vehicle, and between the upper member 2, the lower member 3 disposed below the upper member 2, and the upper member 2 and the lower member 3. A cylindrical flexible member 4 such as a diaphragm or a bellows is provided. The upper member 2 is a member connecting the flexible member 4 and the vehicle body, and in the present embodiment, the upper surface plate is used, but not limited to this, for example, a part of the vehicle body is used as the upper member 2 May be The lower member 3 is a member for connecting the flexible member 4 and the bogie frame, and in the present embodiment, the elastic mechanism 7 generally referred to as a stopper is provided. However, the present invention is not limited thereto. It is good also as composition except.

下側部材3は、弾性機構7と、弾性機構7の頂板8の上面外周縁部から外周部にかけて装着される環状で帯状の下面板9と、頂板8にボルト止めされるフランジ部を有する円盤状の上側部材受部11とを備える。   The lower member 3 includes an elastic mechanism 7, an annular belt-like lower surface plate 9 mounted from the upper outer periphery to the outer peripheral portion of the top plate 8 of the elastic mechanism 7, and a disk having a flange portion bolted to the top plate 8. And the upper member receiving portion 11 of

弾性機構7は、環状の頂板8と、環状の底板12との間にゴム製で環状の弾性材層13と環状の硬質板14とが交互に積層された積層ゴムを備えた構造とされる。本実施形態では、頂板8、底板12及び硬質板14として金属板が用いられている。弾性機構7としては、積層ゴム構造を備え、ストッパーとしての機能を有するものであればよく、コニカルストッパー等であってもよい。また、下側部材3として、前述のごとく、弾性機構7を除いた構成とすることも可能である。   The elastic mechanism 7 has a structure including a laminated rubber in which an annular elastic material layer 13 made of rubber and an annular hard plate 14 are alternately laminated between an annular top plate 8 and an annular bottom plate 12. . In the present embodiment, metal plates are used as the top plate 8, the bottom plate 12 and the hard plate 14. The elastic mechanism 7 may have a laminated rubber structure and have a function as a stopper, and may be a conical stopper or the like. Further, as described above, the lower member 3 may be configured without the elastic mechanism 7.

可撓部材4の上端及び下端にはビードコアに補強ゴム層を巻き付けた肉厚のビード部が形成されている。可撓部材4の上端側ビード部は、上側部材2に設けられた円盤状のビード受部2aに外嵌される。下端側ビード部は、弾性機構7の頂板8に設けられたビード受部8aに外嵌される。   At the upper end and the lower end of the flexible member 4, a thick bead portion in which a reinforcing rubber layer is wound around a bead core is formed. The upper end bead portion of the flexible member 4 is externally fitted to a disk-shaped bead receiving portion 2 a provided on the upper member 2. The lower end bead portion is externally fitted to a bead receiving portion 8 a provided on the top plate 8 of the elastic mechanism 7.

図2に示すように、可撓部材4は、外層15及び内層16と、外層15及び内層16の間に介在される中間層17とを備えた積層構造とされている。外層15及び内層16は、難燃性ゴム組成物から構成され、中間層17は、非難燃性ゴム組成物に補強コード18が埋設された補強ゴム層17aから構成される。   As shown in FIG. 2, the flexible member 4 has a laminated structure including an outer layer 15 and an inner layer 16, and an intermediate layer 17 interposed between the outer layer 15 and the inner layer 16. The outer layer 15 and the inner layer 16 are composed of a flame retardant rubber composition, and the middle layer 17 is composed of a reinforced rubber layer 17 a in which a reinforcing cord 18 is embedded in a non-flame retardant rubber composition.

補強コードとしては、ポリアミド、ポリエステル、レーヨン、ポリビニルアルコール等の樹脂製コードが挙げられるが、強度の点でポリアミド製コードを用いるのが好ましい。補強ゴム層は1層からなる単層構造であってもよいが、強度的に複数層積層された積層構造であることが好ましい。特に、2層等の偶数層であることが強度のバランス面で好ましい。   Examples of the reinforcing cords include cords made of resin such as polyamide, polyester, rayon, polyvinyl alcohol and the like, but it is preferable to use cords made of polyamide in terms of strength. The reinforcing rubber layer may have a single-layer structure consisting of a single layer, but in terms of strength, it is preferable to have a laminated structure in which a plurality of layers are laminated. In particular, an even number of layers such as two layers is preferable in terms of balance of strength.

本発明の空気ばねに用いられるゴム組成物のゴム成分としては、天然ゴムのほか、合成ゴムとして、クロロプレンゴム、イソプレンゴム、ブタジエンゴム、スチレン−ブタジエンゴム、アクリロニトリル−ブタジエンゴムなどのジエン系ゴムや、エチレン−プロピレン−ジエン・ターポリマー、イソブチレン−イソプレンンゴムなどのオレフィン系ゴムや、ウレタンゴムなどを挙げることができ、これらのゴムを単独で、又は、2種以上を組み合わせて使用することができる。なお、本実施態様では、内外層のゴム成分としては、耐候性、耐熱性、耐老化性等の物理的特性に優れたクロロプレンを主成分として用い、中間層のゴム成分としては、機械的特性に優れた天然ゴムを用いている。   As a rubber component of the rubber composition used for the air spring of the present invention, in addition to natural rubber, as synthetic rubber, diene rubber such as chloroprene rubber, isoprene rubber, butadiene rubber, styrene-butadiene rubber, acrylonitrile-butadiene rubber and the like And olefin rubbers such as ethylene-propylene-diene terpolymer and isobutylene-isoprene rubber, urethane rubbers, etc. These rubbers can be used alone or in combination of two or more. . In this embodiment, as the rubber component of the inner and outer layers, chloroprene excellent in physical properties such as weather resistance, heat resistance and aging resistance is used as a main component, and as the rubber component of the intermediate layer, mechanical characteristics are used. Natural rubber is used.

本発明においては、難燃剤としてノンハロゲン系難燃剤を用いることが望ましい。ノンハロゲン系難燃剤としては、金属水酸化物、金属酸化物、リン系、シリコーン系、窒素化合物系、有機金属化合物系などが挙げられ、1種を単独で用いてもよいし、2種以上を組み合わせて用いることもできる。ただ、可撓部材4の機械的特性及び物理的特性をバランスよく維持するには、リン系難燃剤及び金属水酸化物を適宜組み合わせて使用することが好ましい。   In the present invention, it is desirable to use a non-halogen based flame retardant as the flame retardant. Examples of non-halogen flame retardants include metal hydroxides, metal oxides, phosphorouss, silicones, nitrogen compounds, organic metal compounds, etc. One may be used alone, or two or more may be used. It can also be used in combination. However, in order to maintain the mechanical properties and the physical properties of the flexible member 4 in a well-balanced manner, it is preferable to use a phosphorus-based flame retardant and a metal hydroxide in combination as appropriate.

リン系難燃剤としては、当業者に公知のリン酸塩を使用することができるが、特に、ゴム燃焼時にゴム表面にイントメッセント(発泡膨張層)を形成するイントメッセント系のリン酸塩が、より高い難燃性が得られる点で好ましい。   As phosphorus-based flame retardants, phosphates known to those skilled in the art can be used, and in particular, intomescent phosphates that form an intumescent (foam expansion layer) on the rubber surface during rubber combustion. Is preferred in that higher flame retardancy is obtained.

金属水酸化物としては、水酸化マグネシウム、水酸化アルミニウム、水酸化バリウム、水酸化カルシウム等を挙げることができ、これらを1種単独で、又は、2種以上を組み合わせて使用することができる。特に、水酸化マグネシウム、水酸化アルミニウムは、より高い難燃性が得られる点で好ましい。   As a metal hydroxide, magnesium hydroxide, aluminum hydroxide, barium hydroxide, calcium hydroxide etc. can be mentioned, These can be used individually by 1 type or in combination of 2 or more types. In particular, magnesium hydroxide and aluminum hydroxide are preferable in that higher flame retardancy can be obtained.

外層15及び内層16を構成する難燃性ゴム組成物には上記難燃剤が配合され、中間層を構成する非難燃性ゴム組成物には難燃剤は配合されない。可撓部材4で用いられるゴム組成物には、上記のゴム成分や難燃剤以外に、硫黄、カーボンブラック、加硫促進剤、老化防止剤、加硫促進助剤、加硫遅延剤、シリカ、シランカップリング剤、酸化亜鉛、ステアリン酸、可塑剤、ワックスやオイル等の軟化剤、加工助剤等の公知の配合剤を、本発明の効果を損なわない範囲において適宜配合して用いることができる。   The above-described flame retardant is compounded in the flame retardant rubber composition constituting the outer layer 15 and the inner layer 16, and the flame retardant is not compounded in the non-flame retardant rubber composition constituting the intermediate layer. The rubber composition used in the flexible member 4 includes, in addition to the above rubber component and flame retardant, sulfur, carbon black, a vulcanization accelerator, an antiaging agent, a vulcanization accelerator auxiliary, a vulcanization retarder, silica, Known compounding agents such as silane coupling agents, zinc oxide, stearic acid, plasticizers, softeners such as waxes and oils, processing aids and the like can be appropriately blended and used without impairing the effects of the present invention. .

本実施形態では、中間層17は、2プライの補強ゴム層17a、17aで構成される。内外層の平均厚み(X+Y)/2は、それぞれ中間層の厚みZの1.1倍以上である。なお、各層の厚みは、中間層17と、内外層15及び16とでゴム組成が異なることから、可撓部材4の断面を光学的又はX線や電子線を用いた表面分析等により確認することができる。   In the present embodiment, the intermediate layer 17 is configured of two plies of reinforcing rubber layers 17a and 17a. The average thickness (X + Y) / 2 of the inner and outer layers is at least 1.1 times the thickness Z of the intermediate layer. The thickness of each layer is different in rubber composition between the intermediate layer 17 and the inner and outer layers 15 and 16. Therefore, the cross section of the flexible member 4 is confirmed by optical analysis or surface analysis using X-ray or electron beam. be able to.

図3は、空気ばねに組み込む前の可撓部材の形状を示す斜視図である。図示のごとく、可撓部材4は筒状で、上部4a及び下部4cよりも中間部4bの径が大きくなるように形成されており、この中間部4bが、可撓部材4を組み込んだ空気ばね1が加圧されて使用状態におかれたときに、上側部材2と下側部材3との間で外部に露出する部分となる。   FIG. 3 is a perspective view showing the shape of the flexible member before being incorporated into the air spring. As shown, the flexible member 4 is cylindrical and is formed so that the diameter of the middle portion 4b is larger than that of the upper portion 4a and the lower portion 4c. This middle portion 4b is an air spring incorporating the flexible member 4 When 1 is pressurized and put into use, it becomes a part exposed to the outside between the upper member 2 and the lower member 3.

図3において、可撓部材4の上端開口4dの径をd1、可撓部材4の下端開口4eの径をd2、可撓部材4の最大径部4fの径をd3としたとき、可撓部材の上部4aは、上端開口4dの端縁から可撓部材の外径が(d1+d3)/2になるまでの領域を意味し、可撓部材の下部4cは、下端開口4eの端縁から可撓部材の外径が(d2+d3)/2になるまでの領域を意味する。そして、可撓部材の中間部4bは、可撓部材の外径が(d1+d3)/2から(d2+d3)/2までの領域を意味する。   In FIG. 3, when the diameter of the upper end opening 4d of the flexible member 4 is d1, the diameter of the lower end opening 4e of the flexible member 4 is d2, and the diameter of the largest diameter portion 4f of the flexible member 4 is d3, the flexible member The upper portion 4a of the upper end opening 4d means an area from the end edge of the upper end opening 4d to the outer diameter of the flexible member being (d1 + d3) / 2, and the lower portion 4c of the flexible member is flexible from the end edge of the lower end opening 4e It means the region until the outer diameter of the member becomes (d2 + d3) / 2. And the middle part 4b of a flexible member means the field from the outer diameter of a flexible member to (d1 + d3) / 2 to (d2 + d3) / 2.

可撓部材4の中間部4bは、可撓部材を加硫成形する際に、上部4a及び下部4cよりも拡径されるため肉厚が薄くなりやすく、その結果、中間部4bの難燃性が低下するおそれがある。そこで、可撓部材4を加硫成形する前の未加硫ゴム成形体において、加硫後に中間部4bを構成する部分の内外層の厚みを他の部分よりも予め厚くしておくことも可能である。   The middle portion 4b of the flexible member 4 has a larger diameter than the upper portion 4a and the lower portion 4c when the flexible member is formed by vulcanization, so that the thickness tends to be thinner. As a result, the flame retardancy of the middle portion 4b May decrease. Therefore, in the unvulcanized rubber molded product before vulcanization molding of the flexible member 4, the thickness of the inner and outer layers of the portion constituting the intermediate portion 4b can be made thicker than the other portions after vulcanization. It is.

この場合、中間部4bの全域において可撓部材の厚みを厚くしてもよいし、中間部4bの一部について全周にわたって帯状に可撓部材の厚みを厚くしてもよい。これにより、加硫後の可撓部材の中間部4bの厚みを上部4a及び下部4cの厚みと同等又はそれ以上とすることができ、可撓部材4の中間部4bの難燃性を良好に維持することができる。   In this case, the thickness of the flexible member may be increased in the entire area of the intermediate portion 4b, or the thickness of the flexible member may be increased in a band shape over the entire circumference of a part of the intermediate portion 4b. As a result, the thickness of the middle portion 4b of the flexible member after vulcanization can be made equal to or greater than the thicknesses of the upper portion 4a and the lower portion 4c, and the flame retardancy of the middle portion 4b of the flexible member 4 is excellent. Can be maintained.

[第2実施形態]
本実施形態では、可撓部材4の中間部4bにおいて、ゴム層を追加して可撓部材の厚みを厚くした点が特徴とされ、その他の構成は第1実施形態と同様とされる。
Second Embodiment
The present embodiment is characterized in that a rubber layer is added to the middle portion 4b of the flexible member 4 to increase the thickness of the flexible member, and the other configuration is the same as that of the first embodiment.

図4に示すように、本実施形態では、可撓部材4の中間部4bにおいて、補強ゴム層17aと補強ゴム層17aとの間に緩衝ゴム層19を設けている。すなわち、中間部4bにおいては、可撓部材の厚みが薄くなるため、補強コード層17a及び17aのコード18同士が近接する。その状況で、空気ばねに外力が加わって可撓部材が変位すると、コード18,18同士がこすれ合い、耐久性が低下するおそれが生じる。   As shown in FIG. 4, in the present embodiment, the buffer rubber layer 19 is provided between the reinforcing rubber layer 17 a and the reinforcing rubber layer 17 a in the middle portion 4 b of the flexible member 4. That is, in the intermediate portion 4b, the thickness of the flexible member is reduced, so the cords 18 of the reinforcing cord layers 17a and 17a are close to each other. In such a situation, when an external force is applied to the air spring and the flexible member is displaced, the cords 18 and 18 may rub against each other, resulting in a possibility that the durability may be reduced.

そのため、補強ゴム層17aと補強ゴム層17aとの間に緩衝ゴム層19を設けることにより、コード18,18同士の接触を防止し、可撓部材4の耐久性を維持すると共に、可撓部材の中間部4bの難燃性を良好に維持することが可能となる。   Therefore, by providing the buffer rubber layer 19 between the reinforcing rubber layer 17a and the reinforcing rubber layer 17a, contact between the cords 18 and 18 is prevented, and the durability of the flexible member 4 is maintained, and the flexible member It is possible to maintain good flame retardancy of the middle part 4b of

緩衝ゴム層19として、非難燃性ゴム組成物を用いる場合、緩衝ゴム層19は中間層17と同じ非難燃層とされる。従って、この場合には、補強ゴム層17a及び17aの両層の厚みに緩衝ゴム層19の厚みを足した厚みを非難燃層の厚みとし、難燃層である外層15及び内層16の合計厚みが、非難燃層の2.2倍以上になるように調整すればよい。   When a nonflammable rubber composition is used as the buffer rubber layer 19, the buffer rubber layer 19 is the same nonflammable layer as the intermediate layer 17. Therefore, in this case, the total thickness of the outer layer 15 and the inner layer 16 which is the flame retardant layer is determined by adding the thickness of the buffer rubber layer 19 to the thickness of both layers of the reinforcing rubber layers 17a and 17a as the thickness of the flame retardant layer. However, it should be adjusted to be 2.2 times or more of the non-combustible layer.

また、緩衝ゴム層19として、難燃性ゴム組成物を用いる場合、緩衝ゴム層19は、外層15及び内層16と同じ難燃層とされる。従って、この場合には、補強ゴム層17a及び17aの両層の厚みを足した厚みを非難燃層の厚みとし、難燃層である外層15、内層16及び緩衝ゴム層19の合計厚みが、非難燃層の2.2倍以上になるように調整すればよい。緩衝ゴム層19は、中間部4bの全域に設けてもよいし、中間部4bの一部について全周にわたって帯状に設けてもよい。   When a flame retardant rubber composition is used as the buffer rubber layer 19, the buffer rubber layer 19 is the same flame retardant layer as the outer layer 15 and the inner layer 16. Therefore, in this case, the total thickness of the outer layer 15, the inner layer 16 and the buffer rubber layer 19 which is the flame retardant layer is the thickness of the non-combustible layer where the thickness of the reinforcing rubber layers 17a and 17a is added It should be adjusted to be 2.2 times or more of the non-combustible layer. The buffer rubber layer 19 may be provided on the entire area of the middle portion 4 b or may be provided in a band shape over the entire circumference of a part of the middle portion 4 b.

本実施例では、可撓部材を作製して、EN45545−2に規定される発熱試験を実施し難燃性を評価した。以下にその詳細について説明する。   In this example, a flexible member was produced, and a heat generation test specified in EN 45545-2 was performed to evaluate flame resistance. The details will be described below.

[可撓部材の作製]
先ず、表1に示すように、4種類のゴム組成物を調製した(組成A〜D)。ゴム組成物のゴム成分としては、クロロプレンゴム(CR)、天然ゴム(NR)及びエチレン−プロピレン−ジエン・ターポリマー(EPDM)の3種類を用いた。カーボンブラックとしては、HAFを使用した。 難燃剤としては、イントメッセント系のリン酸塩及び/又は金属水酸化物を用いた。表1に示す量で各原料を配合した後、バンバリーミキサーにて混練しゴム組成物を調製した。
[Production of flexible member]
First, as shown in Table 1, four rubber compositions were prepared (Compositions A to D). Three kinds of chloroprene rubber (CR), natural rubber (NR) and ethylene-propylene-diene terpolymer (EPDM) were used as rubber components of the rubber composition. HAF was used as carbon black. As a flame retardant, an intumescent phosphate and / or metal hydroxide was used. After blending each raw material in the amount shown in Table 1, the rubber composition was prepared by kneading with a Banbury mixer.

次に、調製したゴム組成物(組成A及び組成B)を用いて、表2に示すように、厚みの異なる3種類の可撓部材を作製し(試料1、試料3及び試料4)、そこから発熱試験に供する試料を10cm×10cmのサイズでカットした。なお、試料1と、試料2とは同一の可撓部材からカットした厚み違いの試料である。   Next, using the rubber compositions (composition A and composition B) prepared, as shown in Table 2, three types of flexible members having different thicknesses are produced (Sample 1, Sample 3 and Sample 4), The sample to be subjected to the heat generation test was cut into a size of 10 cm × 10 cm. The sample 1 and the sample 2 are samples of different thickness cut from the same flexible member.

可撓部材の具体的な構成としては、内外層を構成する難燃性ゴム組成物として組成Aを使用し、中間層を構成する非難燃性ゴム組成物として組成Bを使用した。補強コードとしては直径0.6mmのポリアミド製コードを使用し、組成Bのゴム組成物をトッピングして補強ゴムシートを形成し、これを2プライ積層して1.8mm厚みの中間層を形成した。   As a specific configuration of the flexible member, the composition A was used as a flame retardant rubber composition that constitutes the inner and outer layers, and the composition B was used as a non-flammable rubber composition that constitutes an intermediate layer. As a reinforcing cord, a polyamide cord having a diameter of 0.6 mm was used, and a rubber composition of composition B was topped to form a reinforcing rubber sheet, which was laminated in two plies to form an intermediate layer having a thickness of 1.8 mm. .

上記中間層を所定の厚みの内層及び外層で挟んで積層して未加硫ゴム成形体を形成した後、これを加硫金型内にセットした。次いで、未加硫ゴム成形体の内側にブラダーと称されるゴム膜を配置し、このブラダーに蒸気を供給して未加硫ゴム成形体を加温・加圧することにより、可撓部材を加硫成形した。得られた3種類の可撓部材は、いずれも空気ばねに使用するのに必要な機械的特性及び物理的特性を満たすものであった。   The above-mentioned intermediate layer was laminated by being sandwiched between an inner layer and an outer layer of a predetermined thickness to form an unvulcanized rubber molded body, which was then set in a vulcanizing mold. Next, a rubber film called a bladder is disposed inside the unvulcanized rubber molded body, and the flexible member is heated by supplying steam to the bladder to heat and pressurize the unvulcanized rubber molded body. It was vulcanized and molded. The three types of flexible members obtained all met the mechanical properties and physical properties necessary for use in an air spring.

本実施例では、可撓部材以外に、組成A及びBとは別の組成(組成C及び組成D)の難燃性ゴム組成物を使用した単層のゴムシート(試料5〜8)、及び、組成Aの難燃性ゴム組成物を使用した単層のゴムシート(試料9)をそれぞれ加硫成形し、10cm×10cmのサイズでカットして試料1〜4と同様に発熱試験に供した。   In this example, a single-layer rubber sheet (samples 5 to 8) using a flame retardant rubber composition having a composition (composition C and composition D) different from the compositions A and B, in addition to the flexible member A single-layer rubber sheet (sample 9) using the flame retardant rubber composition of composition A was vulcanized and molded, cut to a size of 10 cm × 10 cm, and subjected to the heat generation test as in samples 1 to 4. .

[発熱試験]
表2に示す9種類の試料(試料1〜9)について、ISO 5660−1に準じて発熱試験を実施した。試験時間20分間、測定間隔2秒毎、輻射量25kW/m2の測定条件で発熱速度を測定し、MARHEを算出した。結果を表2に示す。
[Fever test]
The heat generation test was implemented about nine types of samples (samples 1-9) shown in Table 2 according to ISO 5660-1. The heat generation rate was measured under the measurement conditions of a radiation amount of 25 kW / m 2 every 20 seconds for the test time and for every 2 seconds of measurement interval to calculate MARHE. The results are shown in Table 2.

なお、MARHE値は、試料1〜4及び9については、試料1のMARHE値を100とするインデックス表示で示している。試料5〜6については、試料5のMARHE値を100とするインデックス表示で示している。試料7〜8については、試料7のMARHE値を100とするインデックス表示で示している。   In addition, the MARHE value is shown by the index display which sets the MARHE value of the sample 1 to 100 about the samples 1-4 and 9. FIG. The samples 5 to 6 are shown in the index display in which the MARHE value of the sample 5 is 100. The samples 7 to 8 are shown in the index display in which the MARHE value of the sample 7 is 100.

[評価結果]
図4は、試料1〜4の厚みと、MARHE値の関係を示すグラフ(黒丸プロット)である。このグラフより、可撓部材の厚みに比例して、MARHE値が低くなっている、すなわち、難燃性が高くなっていることがわかる。この傾向は、特定のゴム組成及び構造にのみ見られるのではなく、ゴム組成の異なる単層構造の試料5〜6及び試料7〜8の間でも同様の傾向が認められた。これにより、ゴム組成にかかわりなく、可撓部材の厚みが厚くなるほど、難燃性が高くなることが確認された。なお、試料1〜4のハザードレベル(HL)については、試料1及び2はHL2をクリアするレベルであり、試料3及び4については、HL3をクリアするレベルであった。
[Evaluation results]
FIG. 4 is a graph (black circle plot) showing the relationship between the thickness of samples 1 to 4 and the MARHE value. From this graph, it can be seen that the MARHE value is low, that is, the flame retardancy is high, in proportion to the thickness of the flexible member. This tendency was not only found in a specific rubber composition and structure, but a similar tendency was observed among samples 5 to 6 and samples 7 to 8 of monolayer structures having different rubber compositions. From this, it was confirmed that the flame retardancy increases as the thickness of the flexible member increases regardless of the rubber composition. The hazard levels (HL) of the samples 1 to 4 were the levels at which the samples 1 and 2 cleared the HL2, and the levels at which the samples 3 and 4 cleared the HL3.

従来の空気ばねにおいては、可撓部材の内外層は補強ゴム層である中間層を外部環境から保護するためのものであって、これを積極的に厚く形成しようという思想はなかった。これに対し、本発明では、上記評価結果の知見に基づき、可撓部材の内外層にのみ難燃性ゴム組成物を用いるとともに、中間層よりも積極的に層厚を厚くすることによって、可撓部材の機械的特性や物理的特性の性能を維持しつつ、難燃性を確保することを可能としている。   In the conventional air spring, the inner and outer layers of the flexible member are intended to protect the intermediate layer which is a reinforced rubber layer from the external environment, and there has been no idea of actively forming the intermediate layer thick. On the other hand, in the present invention, based on the findings of the above evaluation results, the flame retardant rubber composition is used only for the inner and outer layers of the flexible member, and the layer thickness is made thicker than the intermediate layer. It is possible to ensure the flame retardance while maintaining the performance of the mechanical properties and physical properties of the flexible member.

ISO 5660−1の発熱試験においては、n=3で試験が実施され、3回の試験で得られたMARHE値の平均値が採用される。同じ可撓部材からカットした同じ厚みの複数の試料を測定した結果から、MARHE値としては10程度の範囲でばらつきが生じることがわかっている。一方、図4のグラフの結果より、中間層の厚みが1.8mmのときに、内外層の平均厚みを2.0mmにすると、MARHE値は10低下する。   In the ISO 5660-1 exotherm test, the test is performed at n = 3, and the average value of the MARHE values obtained in the three tests is adopted. From the result of measuring a plurality of samples of the same thickness cut from the same flexible member, it is known that the MARHE value varies within a range of about 10. On the other hand, according to the results of the graph of FIG. 4, the MARHE value decreases by 10 when the average thickness of the inner and outer layers is 2.0 mm when the thickness of the intermediate layer is 1.8 mm.

すなわち、内層、中間層及び外層の厚みが同じである可撓部材において、内外層を構成する難燃性ゴム組成物について所定のHLをクリアする組成を決定した後、内外層の平均厚みを中間層の1.1倍以上に形成することにより、ゴム組成を変更することなくMARHE値のばらつきを加味して予め全体的にMARHE値10程度下げることができる。   That is, in a flexible member in which the thickness of the inner layer, the intermediate layer and the outer layer is the same, the composition for clearing the predetermined HL for the flame retardant rubber composition constituting the inner and outer layers is determined, and then the average thickness of the inner and outer layers is intermediate By forming the film at 1.1 times or more the layer, it is possible to reduce the MARHE value by about 10 as a whole in consideration of the variation in the MARHE value without changing the rubber composition.

図4中に、試料9のMARHE値を記す(四角プロット)。試料9では組成Aで構成される厚み5.2mmのゴムシートのMARHE値は60である。これにより、可撓部材を構成するゴム組成物を全て難燃性ゴム組成物(組成A)としたときには、MARHE値は60程度になると見込まれる。中間層を構成するゴム組成物として非難燃性のものを使用して中間層の厚みを1.8mmとする場合、可撓部材の厚みを7.2mmとすれば、MARHE値を60とすることができる。すなわち、内外層の平均厚みを中間層の1.5倍とすることにより、組成Aの難燃性レベルを維持することができる。   The MARHE value of sample 9 is noted in FIG. 4 (square plot). In sample 9, the MARHE value of a 5.2 mm thick rubber sheet composed of composition A is 60. Thereby, when all the rubber compositions which comprise a flexible member are used as a flame-retardant rubber composition (composition A), it is estimated that a MARHE value will be about 60. When the thickness of the intermediate layer is 1.8 mm using a non-combustible one as the rubber composition constituting the intermediate layer, the MARHE value is 60 if the thickness of the flexible member is 7.2 mm. Can. That is, the flame retardance level of the composition A can be maintained by setting the average thickness of the inner and outer layers 1.5 times that of the intermediate layer.

試料1及び試料2について検討してみると、両者は、同じ可撓部材から切り出されたものである。この可撓部材は、厚み5.4mmになるように形成されたものであり、成形後に空気ばねに組み入れて実際に使用した後、空気ばねを分解し可撓部材を取り出した。試料1は、可撓部材の下部から切り出し、試料2は、可撓部材の中間部から切り出した。試料1の厚みは5.4mmであり、試料2の厚みは4.6mmである。   When examining the sample 1 and the sample 2, both are cut out from the same flexible member. This flexible member was formed to have a thickness of 5.4 mm, and after being molded, it was incorporated into an air spring and actually used, and then the air spring was disassembled and the flexible member was taken out. The sample 1 was cut out from the lower part of the flexible member, and the sample 2 was cut out from the middle part of the flexible member. The thickness of the sample 1 is 5.4 mm, and the thickness of the sample 2 is 4.6 mm.

これは、未加硫ゴム成形体を加硫成形する際に、ブラダ―によって未加硫ゴム成形体にかかる圧力が中間部で大きくなり、その結果、中間部の厚みが薄くなったものと推察された。この結果より、未加硫ゴム成形体の中間部の厚みを予め厚くしておくことで、加硫成形後の可撓部材の中間部の厚みを、可撓部材の上部及び下部と同等以上の厚みに維持することができ、可撓部材全体の難燃性を良好に維持することが可能となる。   The reason is that the pressure applied to the unvulcanized rubber molded body is increased at the intermediate portion by the bladder when the unvulcanized rubber molded body is vulcanized and formed, and as a result, the thickness of the intermediate portion is reduced. It was done. From this result, by thickening the thickness of the middle portion of the unvulcanized rubber molded body in advance, the thickness of the middle portion of the flexible member after vulcanization molding is equal to or greater than that of the upper and lower portions of the flexible member. The thickness can be maintained, and the flame resistance of the entire flexible member can be favorably maintained.

以上、本発明の実施形態につき説明したが、本発明の範囲はこれに限定されるものではなく、発明の趣旨を逸脱しない範囲で種々の変更を加えて実施することができる。たとえば、本実施形態においては、内外層の厚みは異なっていてもよく、たとえば、外層を内層よりも厚く設定してもよい。また、本発明の空気ばねは、鉄道車両のみならず、トラック・バス等の車両にも適用可能である。   The embodiment of the present invention has been described above, but the scope of the present invention is not limited to this, and various modifications can be made without departing from the scope of the invention. For example, in the present embodiment, the thickness of the inner and outer layers may be different, and for example, the outer layer may be set thicker than the inner layer. Moreover, the air spring of the present invention is applicable not only to railway cars but also to vehicles such as trucks and buses.

本実施形態及び上記変形例に開示されている構成要件は互いに組合せ可能であり、組合せることにより、新しい技術的特徴を形成することができる。   The constituent features disclosed in the present embodiment and the above modifications can be combined with each other, and by combining, new technical features can be formed.

1 空気ばね
2 上側部材
3 下側部材
4 可撓部材
7 弾性機構
8 頂板
9 下面板
11 上側部材受部
12 底板
13 弾性材層
14 硬質板
15 外層
16 内層
17 中間層
18 補強コード
REFERENCE SIGNS LIST 1 air spring 2 upper member 3 lower member 4 flexible member 7 elastic mechanism 8 top plate 9 lower plate 11 upper member receiving portion 12 bottom plate 13 elastic material layer 14 hard plate 15 outer layer 16 inner layer 17 intermediate layer 18 reinforcing cord

Claims (3)

上側部材と、前記上側部材の下方に配置される下側部材と、前記上側部材と前記下側部材の間に介装される筒状の可撓部材とを備えた空気ばねであって、前記可撓部材は、外層及び内層と、前記外層及び内層の間に介在される中間層とを備え、前記外層及び内層は、難燃性ゴム組成物から構成され、前記中間層は、非難燃性ゴム組成物に補強コードが埋設された補強ゴム層から構成され、前記内層の厚みと前記外層の厚みの平均厚みが、前記中間層の厚みの1.1倍以上であることを特徴とする空気ばね。 An air spring comprising an upper member, a lower member disposed below the upper member, and a cylindrical flexible member interposed between the upper member and the lower member, the air spring comprising: The flexible member comprises an outer layer and an inner layer, and an intermediate layer interposed between the outer layer and the inner layer, wherein the outer layer and the inner layer are composed of a flame retardant rubber composition, and the intermediate layer is non-combustible Air comprising a reinforcing rubber layer in which a reinforcing cord is embedded in a rubber composition, and the average thickness of the thickness of the inner layer and the thickness of the outer layer is 1.1 times or more the thickness of the intermediate layer Spring. 上側部材と、前記上側部材の下方に配置される下側部材と、前記上側部材と前記下側部材の間に介装される筒状の可撓部材とを備えた空気ばねであって、前記可撓部材は、外層及び内層と、前記外層及び内層の間に介在される中間層とを備え、前記外層及び内層は、難燃性ゴム組成物から構成された難燃層とされ、前記中間層は、非難燃性ゴム組成物に補強コードが埋設された補強ゴム層から構成された非難燃層とされ、前記難燃層の合計厚みが、前記非難燃層の厚みの2.2倍以上であることを特徴とする空気ばね。 An air spring comprising an upper member, a lower member disposed below the upper member, and a cylindrical flexible member interposed between the upper member and the lower member, the air spring comprising: The flexible member comprises an outer layer and an inner layer, and an intermediate layer interposed between the outer layer and the inner layer, the outer layer and the inner layer being a flame retardant layer composed of a flame retardant rubber composition, the intermediate layer The layer is a non-combustible layer composed of a reinforced rubber layer having a reinforcing cord embedded in the non-flammable rubber composition, and the total thickness of the flame retardant layer is 2.2 times or more the thickness of the non-flammable layer An air spring characterized by being. 前記中間層は、前記補強ゴム層が1層からなる単層構造又は前記補強ゴム層が複数層積層された積層構造であることを特徴とする請求項1又は2に記載の空気ばね。 The air spring according to claim 1 or 2, wherein the intermediate layer has a single-layer structure in which the reinforcing rubber layer is a single layer or a laminated structure in which a plurality of the reinforcing rubber layers are laminated.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115302684A (en) * 2022-08-08 2022-11-08 株洲时代瑞唯减振装备有限公司 Hourglass spring and manufacturing process thereof
EP4205964A1 (en) * 2021-12-28 2023-07-05 Nitta Chemical Industrial Products Co., Ltd Laminated vibration-proof rubber and rubber member

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05296275A (en) * 1992-04-21 1993-11-09 Yokohama Rubber Co Ltd:The Film body for air spring
US20080111288A1 (en) * 2006-11-14 2008-05-15 Howard Michael C Air spring sleeve
JP2008132641A (en) * 2006-11-28 2008-06-12 Bridgestone Corp Cylindrical flexible film body

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05296275A (en) * 1992-04-21 1993-11-09 Yokohama Rubber Co Ltd:The Film body for air spring
US20080111288A1 (en) * 2006-11-14 2008-05-15 Howard Michael C Air spring sleeve
JP2008132641A (en) * 2006-11-28 2008-06-12 Bridgestone Corp Cylindrical flexible film body

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4205964A1 (en) * 2021-12-28 2023-07-05 Nitta Chemical Industrial Products Co., Ltd Laminated vibration-proof rubber and rubber member
CN115302684A (en) * 2022-08-08 2022-11-08 株洲时代瑞唯减振装备有限公司 Hourglass spring and manufacturing process thereof

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