JP2019065424A - Ultraviolet protection optically functional fabric - Google Patents

Ultraviolet protection optically functional fabric Download PDF

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JP2019065424A
JP2019065424A JP2017192408A JP2017192408A JP2019065424A JP 2019065424 A JP2019065424 A JP 2019065424A JP 2017192408 A JP2017192408 A JP 2017192408A JP 2017192408 A JP2017192408 A JP 2017192408A JP 2019065424 A JP2019065424 A JP 2019065424A
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layer
color
fabric
fluorescent pigment
pigment paste
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王曼卿
Man Qing Wang
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INPROTEX CO Ltd
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Abstract

To provide an ultraviolet protection optically functional fabric.SOLUTION: An ultraviolet protection optically functional fabric comprises a base fabric layer 201, a colored layer 21, and a discoloration-resistant layer 22. The fabric is formed by: first, weaving polyester fiber Nylon and an elastic yarn into a gray fabric raw material; refining it into a preset gray fabric by bleaching with a nontoxic fluorescent agent to finish a raw material layer 21; then, on the base fabric layer 201, by a tension-free whole surface pattern layer application step of a first layer, performing coloration with fluorescent pigment paste of a first tone color, and impregnating it into a spun layer of a fabric surface to finish the application of the colored layer 21; and then, by an application step of a second layer, applying fluorescent pigment paste of a second tone color to perform coloration, thereby performing the application of the discoloration-resistant layer 22 of the second layer. In the fabric, by the synergistic effect of dyeing molecules in the two pattern layers, the chromaticity of a fabric surface layer can be achieved, and the absorption condition of coloration can be controlled.SELECTED DRAWING: Figure 2

Description

本発明は、紫外線防護光学機能性生地に関するものであり、さらに詳しくは、プレセット生機素材層の基布層が第1層と第2層の無張力の全面図柄層塗布ステップによって、着色層と耐変色層を塗布して、着色吸収具合を制御した生地表層に仕上げ、陽射し防止と、有益な光波を吸収し、耐変色性と、透光性、光吸収性の向上を実現し、水洗に強く、プリント可能と共に、マイナスイオンエネルギーを有し、遠赤外線を放出できるため、血液循環を促進し保温効果を有する紫外線防護光学機能性生地に関するものである。     The present invention relates to an ultraviolet protective optical functional fabric, and more specifically, the base layer of the preset green machine material layer is a non-tension full-surface pattern coating step of the first layer and the second layer. Apply a color-resistant layer, finish on the surface of the fabric with controlled color absorption condition, prevent sunlight and absorb useful light waves, realize improvement in color-resistance, light transmission and light absorption, and wash in water The present invention relates to an ultraviolet protective optical functional fabric having a strong, printable, negative ion energy, and emitting far infrared rays, thereby promoting blood circulation and having a heat retaining effect.

公知の紫外線防護光学機能性生地(図11,本発明者が出願した台灣特許I400376号紫外線防護光学機能性生地)は、ポリエステル繊維ナイロン(Nylon)と、弾性糸(Spandex(登録商標))材料から織り上げた織生地を高温処理されている、生機素材を定型した後、無毒性蛍光漂白剤で処理し、生機素材に精錬した後、無毒蛍光化合物分子による光吸収能力を利用し、静電気防止、通気性を持つプレセット生機を形成するとともに、プレセット生機の表層に直接単一色値の蛍光顔料ペーストを染色の顔料ペーストとして全面に塗布し、最後に、成型処理プロセスにおいて、無張力乾燥と無塵乾燥を経て、顔料の着色をより均一化させる。同時にホルムアルデヒドを除去し、ホルムアルデヒドが完全に除去されたことを確認した上、最後は高温プレセットにより、防護能力を有する光学機能性生地を仕上げる。これを身体に装着すると、身体に害を与え紫外線が特定波長の光エネルギーに置き換えられ、かかる光エネルギーが肌に対して、パルス光によるフォートセラピー作用を有するほか、クール感覚、陽射し防止、除臭、無毒、光吸収特性を有し、肌に有益な機能性生地を提供することができる。
しかし、陽射し防止機能性生地で作用する蛍光顔料ペースト図柄層は、単一色値の顔料ペーストを表層の全面に塗布して付着させた図柄層に過ぎない、色度の有効な付着と耐久性を持たないことから、汚れやすく、水洗に弱いほか、水洗の回数制限を受ける。繰り返してもみ洗いした後、耐変色性の安定性が失われるにつれて、陽射し防止の効果も失われる。さらに、生地表面は素地のみしかできず、表層にプリントすることはできない、色調と陽射し防止効果に影響し、機能性生地従来の機能性が低下する。
Known UV protection optical functional fabrics (FIG. 11, Taiwan patent No. I 400 376 UV protection optical functional fabrics filed by the present inventor) are made of polyester fiber nylon (Nylon) and elastic yarn (Spandex (registered trademark)) materials The woven fabric which has been woven up is treated at high temperature, after the raw material is fixed, treated with non-toxic fluorescent bleaching agent and refined into the raw material, and then light absorption ability by non-toxic fluorescent compound molecules is used to prevent static electricity and aeration. Together with the formation of a pre-set green machine, and applying a single color fluorescent pigment paste directly to the surface of the pre-set green machine as a dye pigment paste, and finally, in the molding process, no tension drying and no dust After drying, the pigment coloration is made more uniform. At the same time, formaldehyde was removed, and it was confirmed that formaldehyde was completely removed. Finally, a high temperature presetting was used to finish an optical functional fabric having protective ability. When it is worn on the body, it harms the body and the ultraviolet light is replaced by light energy of a specific wavelength, and such light energy has a fort therapeutic action with pulse light on the skin, and also has a cool feeling, sunshine prevention, deodorizing It has non-toxic, light-absorbing properties, and can provide functional fabrics that are beneficial to the skin.
However, the fluorescent pigment paste pattern layer acting on the functional fabric for preventing sunshine is only the pattern layer formed by applying and adhering the pigment paste of single color value to the whole surface of the surface layer, the effective adhesion and durability of chromaticity Because it does not have, it is easy to get dirty, and it is weak to washing with water, and the number of times of washing with water is limited. After repeated washing, as the color change stability is lost, the sun protection effect is also lost. Furthermore, the surface of the fabric can only be a substrate, and can not be printed on the surface layer, which affects the color tone and the effect of preventing sunshine, and the functional functionality of the functional fabric is reduced.

従って、本発明の主な課題は、生地表層の色度を制御し、UV UPF/FPU耐性と、光波の変換効果を持たせるプレセット処理を経て、陽射し防止と有益な光波を吸収でき、耐変色性と、透光性、光吸収性の向上を実現し、水洗に強い、プリント可能な使用効果を有する紫外線防護光学機能性生地を提供することにある。       Therefore, the main object of the present invention is to control the color of the surface layer of the fabric, to prevent UV UPF / FPU resistance and to convert light waves, and to prevent sunlight and absorb useful light waves through preset processing, It is an object of the present invention to provide an ultraviolet protective optical functional fabric which achieves color change, light transmission and light absorption and has a printable use effect that is strong in washing with water.

本発明のつぎの課題は、自発的に電子と熱エネルギーを伝導して、最高のジュール熱吸収が得られると共に、可視光の波長変換効果を実現し、透光性及び自主的に有益な可視光を吸収する特長と、マイナスイオンエネルギーを有し、赤外線を放出し、血液循環促進と保温効果を有する紫外線防護光学機能性生地を提供することにある。     The next object of the present invention is to conduct electrons and thermal energy spontaneously to obtain the highest Joule heat absorption and to realize the wavelength conversion effect of visible light, and to make the light transmissive and independently beneficial visible An object of the present invention is to provide an ultraviolet protective optical functional fabric having a light absorbing feature, negative ion energy, emitting infrared rays, and promoting blood circulation and heat retention.

本発明もう一つの課題は、陽射し防止効果を備えた陽射し防止製品の美観性と、市場競争力を向上できる紫外線防護光学機能性生地の基材を撥水性テフロン加工により、第2層の無張力の全面図柄層の耐変色層の表層に塗布して、撥水防止層を形成するか、または第2層の無張力の全面図柄層の耐変色層の表層に様々な柄模様のプリント層をプリントするなど、紫外線防護光学機能性生地を提供することにある。     Another object of the present invention is to make the second layer tension-free by water repellent teflon processing of the base material of the ultraviolet protective optical functional fabric which can improve the market appearance and the beauty of the sun protection product with a sun protection effect. Apply to the surface layer of the color-resistant layer of the full-color pattern layer to form a water repellent prevention layer, or print the various patterned patterns on the surface layer of the color-resistant layer of the full-length pattern layer without tension. An object of the invention is to provide an ultraviolet protective optical functional fabric such as printing.

そこで、本願発明者は、本発明の前記課題を解決するために鋭意検討を重ねた結果、本発明の主な課題に対しては、基布層と、基布層の上層繊維に織り込む着色層と、表層に結合する耐変色層とを備える。成形のときは、まずポリエステル繊維ナイロンと弾性糸より生機素材に織り上げて、さらに蛍光剤を用いて、プレセット生機を漂白してプレセット生機素材層に仕上げた後、あらかじめに設定された染色温度により、プレセット生機素材層の基布層に順を追って、片面の全レイヤーに第1と第2色調カラーの蛍光顔料ペーストを着色し、第1色調カラーの蛍光顔料ペーストを生地面の紡績層に染み込ませて、第1層の無張力の全面図柄層の着色層塗布を完了した後、引き続いて第2色調カラーの蛍光顔料ペーストを第1層の無張力の全面図柄層の着色層に塗布して結合させ、第2層の無張力の全面図柄層塗布ステップによって、第2層の無張力の全面図柄層の耐変色層を形成し、生地表層に形成する2つのパターン層の染色分子の相乗効果により、前記の通り課題とする生地表層の色度を制御し、UV UPF/FPU耐性と、光波の変換効果を持たせる。プレセット処理を経て、陽射し防止と有益な光波を吸収でき、耐変色性と、透光性、光吸収性の向上を実現し、水洗に強い、プリント可能な使用効果を有する点に着目し、かかる知見に基いて、本発明に想到するに至った。     Then, as a result of the inventors of the present invention earnestly studying in order to solve the above-mentioned problems of the present invention, the main problems of the present invention are a colored layer embedded in the base fabric layer and the upper layer fiber of the base fabric layer. And a discoloration resistant layer bonded to the surface layer. At the time of molding, the polyester fiber nylon and elastic yarn are first woven into the raw material from the raw material, and then the fluorescent material is used to bleach the pre-set raw material to finish the pre-set raw material layer, and then the dyeing temperature set in advance. The fluorescent pigment paste of the first and second color tones is colored on the entire surface of one side sequentially with the base fabric layer of the preset green machine material layer, and the fluorescent pigment paste of the first color tone is spun on the fabric surface The second layer color fluorescent pigment paste is subsequently applied to the colored layer of the first non-tensioned overall pattern layer of the first layer. Of the second layer, the color-resistant layer of the second layer of the tension-free entire surface pattern layer, and the dye molecules of the two pattern layers formed on the surface layer of the fabric. To synergy Ri to control the chromaticity of the fabric surface to the street challenge, giving a UV UPF / FPU resistance, the conversion effect of the light wave. Through pre-set processing, attention is paid to the point that it can prevent sunlight and absorb useful light waves, realize improvement in color fastness, translucency, and light absorption, and has a printable use effect that is strong in water washing, The present invention has been conceived based on such findings.

前記の本発明のつぎの課題に対しては、第1色調カラーと第2色調カラーの蛍光顔料ペーストは着色する前に、ゲルマニウム元素を溶け込ませて、ナノゲルマニウム元素を含む第1と第2色調カラーの蛍光顔料ペーストを形成した後、引き続いて、プレセット生機素材層の片面に第1色調カラーと第2色調カラーの蛍光顔料ペーストを全面に塗布して、第1層と第2層の無張力の全面図柄層の着色層と耐変色層塗布と着色を行い、生地表層の着色具合を制御することによって、生地表層が体との接触による熱エネルギーが繊維にあるゲルマニウム元素と相互に作用させることにより前記課題の自発的に電子と熱エネルギーを伝導して、最高のジュール熱吸収が得られると共に、可視光の波長変換効果を実現し、透光性及び自主的に有益な可視光を吸収する特長と、マイナスイオンエネルギーを有し、赤外線を放出し、血液循環促進と保温効果を有する点に着目し、かかる知見に基いて本発明に想到するに至った。     With respect to the next subject of the present invention, the fluorescent pigment pastes of the first color tone and the second color tone are made to dissolve the germanium element prior to coloring, and the first and second color tones containing the nano germanium element After the color fluorescent pigment paste is formed, subsequently, the fluorescent pigment paste of the first color tone and the second color tone is applied over the entire surface of the preset green machine material layer, and the first layer and the second layer do not exist. By applying coloring and color-resistant layer and coloring layer of the entire pattern pattern layer of tension, by controlling the coloring condition of the surface layer of the fabric, thermal energy by contact with the body surface interacts with the germanium element in the fiber Therefore, the above-mentioned problem spontaneously conducts electrons and thermal energy to obtain the highest Joule heat absorption and realize the wavelength conversion effect of visible light, and it is a translucent and independently useful visible light And Features of absorbing, have negative ion energy, emit infrared, focusing on points with thermal effect and blood circulation promotion, it led to conceiving the present invention based on this finding.

前記の本発明もう一つの課題に対して、紫外線防護光学機能性生地の基材を撥水性テフロン加工により、第2層の無張力の全面図柄層の耐変色層の表層に塗布して、撥水防止層を形成するか、または第2層の無張力の全面図柄層の耐変色層の表層に様々な柄模様のプリント層をプリントするなどにより、前記課題の陽射し防止効果を備えた陽射し防止製品の美観性と、市場競争力を向上できる点に着目し、本発明に想到するに至った。
かくして、本発明の要旨は、次の(1)〜(5)に記載の通りのものである。
(1)基布層と、前記基布層の上層の繊維内編地に織り込む着色層と、表層に結合する耐変色層とから構成される紫外線防護光学機能性生地であって、その成形プロセスステップは、
まず、ポリエステル繊維ナイロンと弾性糸の組織材料の重合物を高温処理により汚れを除去してなる生機素材を取得し、無毒性の蛍光漂白前処理を経て、生機の成型を完了し、生地表面の糸に付着した油脂、汚れ、不純物を取り除き、さらに無毒性の蛍光化合物分子によって、強い光吸収能力を持たせて、染色釜に適量の染色補助剤を添加して、生機素材層の成型を仕上げる漂白処理先処理(プレセット生機)プロセスであるステップ1と、無張力によるレイヤーの顔料着色プロセスであるステップ2と、成型処理プロセスであるステップ3とを含み、
前記ステップ2の顔料着色プロセスは、
メインカラーの蛍光顔料ペーストの基準色値を予め設定すると同時に、メインカラーと同じ色系列で、異なる色値の第1と第2色調カラーの蛍光顔料ペーストを1組として設定し、メインカラーと同じ色系列で、メインカラーの色値よりも明るい色調の前記第1色調カラーの蛍光顔料ペーストを選定し、その色値をメインカラーの色値の20%〜30%とし、メインカラーと同じ色系列で、メインカラーの色値よりもやや明るい色調の前記第2色調カラーの蛍光顔料ペーストを選定し、その色値をメインカラーの色値の70%〜80%とする顔料予め設定ステップ(a)と、
予め設定した染色温度において、前記の漂白前処理を経て成型された生機素材層の基布層上に、二軸ローラーによって、片面に前記第1色調カラーの蛍光顔料ペーストを全面塗布して着色し、明るい色度の前記第1色調カラーの蛍光顔料ペーストを成型された生機素材層の前記基布層の上層の生地表面の内編地繊維内に深く染み込ませて、第1層の無張力の全面図柄層の前記着色層の塗布と着色を完成し、前記基布層の下地色層を脱色しないで固色性を安定に維持すると共に、UVの保護指数UPF/FPUを向上させる機能を有し、波長変換効果が50%〜60%に達することで、その後に染色される無張力による全面図柄層の色堅牢度吸尽率を容易に向上させる第1層の無張力の全面図柄層の着色層塗布着色ステップ(b)と、
予め設定した染色温度において、再び二軸ローラーによって、片面に第1層の無張力の全面図柄層の前記着色層上に、前記第2色調カラーの蛍光顔料ペーストを全面塗布して着色を行い、第2層の無張力の全面図柄層の前記耐変色層の塗布を行い、第2層の無張力の全面図柄層の前記耐変色層を生地表層に被覆すると共に、第1と第2層の無張力の全面図柄層の前記着色層との重層作用により、染色分子の相乗効果と相俟って完成した前記生地表層の色度によって着色吸尽率の程度を制御でき、2層の無張力による全面図柄層を有する前記生地表層をUVの保護指数UPF/FPUを向上させる機能を有し、光波長変換効果が70%〜80%に達することで、図柄層の顔料着色工程である前記ステップ2を円滑に完成する第2層の無張力の全面図柄層の前記耐変色層塗布着色ステップ(c)とを含み、
前記ステップ3は、全面図柄層の塗布を経て着色を完了した前記生地表層のみに無張力による乾燥と無塵乾燥を実施し、高温170°〜180°によって生地表面に分散成型し、顔料の発色をより均一化させ、色堅牢度をより良くさせると共に、ホルムアルデヒドを完全に除去と確認した上、ホルムアルデヒド除去した高温成型を完了し、その色堅牢度がパルス光による治療のように、透光性、光吸収性、洗濯堅牢性を兼ね備えた紫外線防護光学機能性生地の基材を形成するステップであることを特徴とする紫外線防護光学機能性生地。
(2)前記紫外線防護光学機能性生地のもう一つの成形プロセススは、
メインカラーの蛍光顔料ペーストの基準色値を予め設定すると同時に、同じ色系列で、異なる色値の2つのゲルマニウム元素を溶融含浸させた第1と第2色調カラーの蛍光顔料ペーストを予め設定し、ゲルマニウム元素を溶融含浸させた第1と第2色調カラーの蛍光顔料ペーストの溶融含浸方法として、アルグ石(ゲルマニウム合金の圧電性結晶,GAC)をミクロン単位の微粉末(約5μm)のゲルマニウム元素に研磨粉砕した後、温度を1500〜1800度に設定した環境に置いて高温焼結を行い、まず、残存したその他の不純物を取り除くアッシング作用を行い、引き続いて、前記ミクロン単位の微粉末のゲルマニウム元素を二次研磨粉砕により、ナノレベルの超微細粉末のゲルマニウム元素に仕上げ、それから、前記第1と第2色調カラーの蛍光顔料ペーストに溶融含浸させて、ゲルマニウム元素を溶融含浸させた前記第1と第2色調カラーの蛍光顔料ペーストを形成し、続いてポリエステル繊維ナイロンと弾性糸の組織材料の重合物により織り上げてなる生機素材を取得し、無毒性の蛍光漂白前処理を経てなる生機の成型を完了し、これにより、前記紫外線防護光学機能性生地の基材の成型された生機素材層の基布層上に、順次に二軸ローラーによって、片面にゲルマニウム元素を溶融含浸させた前記第1と第2色調カラーの蛍光顔料ペーストを塗布して着色した後、全面図柄層の塗布を経て着色を完了した前記生地表層のみに、無張力による乾燥と無塵乾燥を実施し、高温によって生地表面に分散成型し、顔料の発色をより均一化させ、色堅牢度をより良くさせると共に、ホルムアルデヒドを完全に除去と確認した上、ホルムアルデヒド除去した高温成型を完了し、その色堅牢度がパルス光による治療のように、透光性、光吸収性、洗濯堅牢性を兼ね備えた前記紫外線防護光学機能性生地の基材を形成することで、図柄層に機能性を持たせて、2層の無張力の全面図柄層を塗布した前記生地表層が人体自身との接触により生じる熱エネルギーで繊維内にあるゲルマニウム元素と相互に作用し、自発的に電子を伝導して最高ジュール数の熱エネルギーが得られて、可視光部分を吸収して波長変換効果を実現し、透光性及び自発的に有益な可視光を吸収する特長を有し、前記紫外線防護光学機能性生地の基材から成形された製品(衣類など)を装着した者は、マイナスイオンエネルギーを発生させ、遠赤外線を放出させることにより、血液循環の促進並びに保温効果を得ることを特徴とする、前記(1)記載の紫外線防護光学機能性生地。
(3)前記第1色調カラーの蛍光顔料ペーストを、メインカラーと同じ色系列で、かつメインカラーの色値よりも明るい色調であるメインカラーの色値の20%〜30%の色値として設定し、前記第1色調カラーの蛍光顔料ペーストと、メインカラーとの色値比を0.2〜0.3:1に設定し、前記第2色調カラーの蛍光顔料ペーストを、メインカラーと同じ色系列で、かつメインカラーの色値よりもやや明るい色調であるメインカラーの色値の70%〜80%の色値として設定し、前記第2色調カラーの蛍光顔料ペーストと、メインカラーとの色値比を0.7〜0.8:1に設定することを特徴とする、前記(1)または(2)記載の紫外線防護光学機能性生地。
(4)前記第1層の無張力の全面図柄層の前記着色層の前記第1色調カラーの蛍光顔料ペーストの染色温度を90°〜100°に設定すると、前記第2層の無張力の全面図柄層の前記耐変色層の前記第2色調カラーの蛍光顔料ペーストの染色温度を90°〜100°に設定することを特徴とする、前記(1)または(2)記載の紫外線防護光学機能性生地。
(5)前記紫外線防護光学機能性生地の基材は、前記耐変色層に撥水性テフロン加工を施した撥水防止層を塗設し、前記撥水防止層を前記耐変色層の最外表層に織り込むか、あるいは前記耐変色層上に図柄層や文様を印刷してなるプリント層を前記耐変色層の最外表層にプリントすることを特徴とする、前記(1)または前記(2)記載の紫外線防護光学機能性生地。
With respect to the above-mentioned another subject of the present invention, the base material of the ultraviolet protection optically functional fabric is applied to the surface layer of the color-resistant layer of the second layer, tension-free full surface pattern layer by water repellent Teflon processing. The sun protection with the sun protection effect of the above-mentioned subject is carried out by forming a water prevention layer, or printing a print layer of various patterns on the surface layer of the color-resistant layer of the second pattern Focusing on the aesthetics of the product and the ability to improve market competitiveness, the inventors have arrived at the present invention.
Thus, the subject matter of the present invention is as described in the following (1) to (5).
(1) An ultraviolet protective optical functional fabric comprising a base fabric layer, a colored layer to be woven into the in-fiber knitted fabric in the upper layer of the base fabric layer, and a color change resistant layer bonded to the surface layer The steps are
First, the raw material of polyester fiber nylon and polymer of elastic yarn is removed by high temperature treatment to remove dirt, and after the non-toxic fluorescent bleaching pre-treatment, the raw molding is completed and the surface of the fabric is finished. Remove fats and oils, stains and impurities attached to the yarn, and give strong light absorbing ability by non-toxic fluorescent compound molecules, add appropriate amount of dyeing assistant to the dyeing pot, and finish molding of the raw material layer Step 1 which is a pre-bleaching treatment (preset green machine) process, step 2 which is a pigment coloring process without tension, and step 3 which is a molding process
The pigmenting process of step 2 is
The reference color value of the main color fluorescent pigment paste is set in advance, and at the same time, the first and second color tone fluorescent pigment pastes of the same color series as the main color but having different color values are set as one set and the same as the main color In the color series, select the fluorescent pigment paste of the first color tone that is brighter than the color value of the main color, and set the color value to 20% to 30% of the color value of the main color, and the same color series as the main color Then, select the second color tone fluorescent pigment paste whose color tone is a little brighter than the color value of the main color, and set the color value to 70% to 80% of the color value of the main color in advance (a) When,
The first color tone fluorescent pigment paste is coated on one side with a biaxial roller on the base cloth layer of the raw material raw material layer molded through the above-mentioned bleaching pretreatment at a predetermined dyeing temperature and colored The light-colored fluorescent pigment paste of the first color tone is deeply impregnated into the inner knitted fabric fibers of the upper surface of the base fabric layer of the molded raw material layer, and the first layer is tensionless. Completes the application and coloring of the colored layer on the entire surface pattern layer, maintains the solid color stability without decolorizing the base colored layer of the base fabric layer, and has the function of improving the UV protection index UPF / FPU And the wavelength conversion effect reaches 50% to 60%, and the color fastness of the whole pattern layer by the no-tensile dyed after that is easily improved the color fastness exhaustion rate of the first layer of the no-tension whole pattern layer Coloring layer application coloring step (b),
At the previously set dyeing temperature, the second color tone fluorescent pigment paste is coated on the entire surface of the first layer of the first layer of no tension full pattern layer again by the biaxial roller, and coloring is performed, The color-resistant layer of the second layer, the non-tension full surface pattern layer, is coated, and the color-resistant layer of the second layer, the non-tension whole surface pattern layer is coated on the fabric surface, The layering effect of the overall pattern pattern layer without tension with the colored layer allows the degree of the coloration exhaustion rate to be controlled by the color of the finished surface layer of the fabric combined with the synergistic effect of the dye molecules, and the tension of two layers is not tensioned. Has the function of improving the UV protection index UPF / FPU of the fabric surface layer having the entire pattern layer according to the above, and the light wavelength conversion effect reaches 70% to 80%, the step of pigment coloring process of the pattern layer 2nd layer no tension all to smoothly complete 2 And a the discoloration layer coating coloring step of the design layer (c),
In step 3 above, only the surface layer of the fabric which has been completely colored through application of the entire pattern layer is subjected to no-tension drying and dust-free drying, and dispersedly molded on the surface of the fabric at a high temperature of 170 ° to 180 °. It is confirmed that the formaldehyde is removed completely, and the high temperature molding with formaldehyde removed is completed, and the color fastness is light-transmissive like treatment with pulsed light An ultraviolet protective optical functional fabric characterized in that it is a step of forming a base of the ultraviolet protective optical functional fabric having light absorbability and washing fastness.
(2) Another molding process of the UV protection optical functional fabric is
At the same time as presetting reference color values of the main color fluorescent pigment paste, first and second color tone fluorescent pigment pastes in which two germanium elements of different color values are melted and impregnated in the same color series are preset. Algite (piezoelectric crystal of germanium alloy, GAC) is used as a germanium element in micron unit fine powder (about 5 μm) as a method of melting and impregnating fluorescent pigment pastes of the first and second color tones which are melt-impregnated with germanium element. After grinding and grinding, high temperature sintering is performed in an environment where the temperature is set at 1500 to 1800 ° C., first, ashing operation is performed to remove remaining other impurities, and subsequently, germanium element of fine powder of the above-mentioned micron unit The secondary polishing and grinding, to finish the nano-level ultrafine powder of germanium element, and then, said first and second color The fluorescent pigment paste of the color is melt-impregnated to form the fluorescent pigment paste of the first and second color tones which is melt-impregnated with the germanium element, and subsequently woven by the polymer of the structure material of polyester fiber nylon and elastic yarn The raw material of the raw material is obtained, and the molding of the raw material made through non-toxic fluorescent bleaching pretreatment is completed, whereby the base layer of the molded raw material layer of the base material of the ultraviolet protective optical functional fabric is formed. The fluorescent pigment paste of the first and second color tones is applied and colored on one side sequentially by a biaxial roller by melting and impregnating the germanium element on one side, and then coloring is completed through application of the entire pattern layer. Only the surface layer of the fabric is subjected to tension-free drying and dust-free drying, and is dispersed and molded on the surface of the fabric by high temperature to make the color development of the pigment more uniform and improve color fastness. In addition, formaldehyde was completely removed, and then the formaldehyde was removed to complete the high-temperature molding, and the color fastness of the ultraviolet ray combined with light transmittance, light absorbability, and washing fastness like treatment with pulsed light. By forming the base material of the protective optical functional fabric, the functional layer is rendered functional, and the surface layer of the fabric coated with two layers of tension-free full surface pattern layer is the thermal energy generated by contact with the human body itself It interacts with the germanium element in the fiber and spontaneously conducts electrons to obtain the highest Joule's thermal energy, absorbs visible light to realize wavelength conversion effect, translucency and spontaneous Those who wear a product (such as clothing) molded from the base material of the UV protection optical functional fabric have the feature of absorbing visually useful visible light, generate negative ion energy and emit far infrared rays. By, characterized by obtaining a promotion and heating effect of the blood circulation, the (1), wherein the UV protection optical functional fabric.
(3) The fluorescent pigment paste of the first color tone is set as a color value of 20% to 30% of the color value of the main color having the same color series as the main color and brighter than the color value of the main color And setting the color value ratio between the fluorescent pigment paste of the first color tone and the main color to 0.2 to 0.3: 1, and setting the fluorescent pigment paste of the second color tone to the same color as the main color It is set as a color value of 70% to 80% of the color value of the main color that is a series and slightly brighter than the color value of the main color, and the color of the second color tone fluorescent pigment paste and the color of the main color The ultraviolet protection optical functional fabric according to (1) or (2), wherein the value ratio is set to 0.7 to 0.8: 1.
(4) If the dyeing temperature of the fluorescent pigment paste of the first color tone of the colored layer of the colored layer of the non-tensioned entire surface pattern layer of the first layer is set to 90 ° to 100 °, the non-tensioned entire surface of the second layer The ultraviolet protection optical functionality according to the above (1) or (2), wherein the dyeing temperature of the fluorescent pigment paste of the second color tone of the color-resistant layer of the pattern layer is set to 90 ° -100 °. Cloth.
(5) The base material of the ultraviolet protective optically functional fabric is provided with a water repellent preventing layer having a water repellent Teflon finish on the color resistant layer, and the water repellent preventing layer is the outermost surface of the color resistant layer (1) or (2) according to the above (1) or (2), characterized in that a printed layer formed by weaving a pattern layer or a pattern on the color-resistant layer is printed on the outermost surface of the color-resistant layer. UV protection optical functional fabric.

本発明の一実施形態に係る紫外線防護光学機能性生地の製造フロー図(その1)である。It is a manufacture flow figure (the 1) of the ultraviolet protection optical functional textile concerning one embodiment of the present invention. 本発明の一実施形態に係る紫外線防護光学機能性生地の局所拡大図(その1)である。It is a local enlarged view (the 1) of the ultraviolet protection optical functional cloth concerning one embodiment of the present invention. 本発明による一実施形態に係る紫外線防護光学機能性生地の斜視図断面図(その1)である。It is a perspective view sectional view (the 1) of ultraviolet protection optical functional cloth concerning one embodiment by the present invention. 本発明の一実施形態に係る紫外線防護光学機能性生地の使用態様図である。It is a usage aspect figure of the ultraviolet protection optical functional textile concerning one embodiment of the present invention. 本発明の一実施形態に係る紫外線防護光学機能性生地の一つの応用例として、陽射し防止帽子に仕上げた図である。It is the figure which finished to the sun protection hat as one application example of the ultraviolet protection optical functional cloth concerning one embodiment of the present invention. 本発明の一実施形態に係る紫外線防護光学機能性生地の製造フロー図(その2)である。It is a manufacture flow figure (the 2) of the ultraviolet protection optical functional cloth concerning one embodiment of the present invention. 本発明の一実施形態に係る紫外線防護光学機能性生地の斜視図と局所拡大図(その2)である。It is the perspective view and the local enlarged view (the 2) of the ultraviolet protection optical functional cloth which concerns on one Embodiment of this invention. 本発明の一実施形態に係る紫外線防護光学機能性生地の断面図(その2)である。It is sectional drawing (the 2) of the ultraviolet protection optical functional cloth which concerns on one Embodiment of this invention. 本発明のもう一つの断面図である。It is another sectional view of the present invention. 本発明の一つの実施例として、アームカーバーに仕上げた図である。FIG. 7 is a view of an arm carver finished as one embodiment of the present invention. 公知の紫外線防護光学機能性生地の製造フロー図である。It is a manufacture flow figure of a well-known ultraviolet protection optical functional cloth.

図1に示すように、本発明の製造フローは、     As shown in FIG. 1, the manufacturing flow of the present invention is:

(ステップ1) 漂白処理先処理(プレセット生機)プロセス:     (Step 1) Bleaching destination processing (preset production machine) process:

ポリエステル繊維ナイロンと弾性糸の組織材料の重合物を用いて、弾性、密度、透光性を有し、かつ、太陽光照射により最高量の紫外線ジュール熱を吸収でき、高温処理により汚れを除去した生機素材に織り上げた後、無毒蛍光剤漂白の前処理を経て、生地の表面糸に付着した油脂、汚れ、不純物を取り除き、さらに、無毒蛍光化合物分子によって、強い光吸収能力を持たせる。引き続き、染色釜に染色補助剤を適宜に添加して、生機素材層に仕上げて、静電気防止、保温、吸熱汗排出機能を有するプレセット生機に仕上げる。     Using the polymer of polyester fiber nylon and elastic yarn texture material, it has elasticity, density, translucency, and can absorb the maximum amount of UV Joule heat by sunlight irradiation, and remove dirt by high temperature treatment After being woven into a raw material, it is pretreated with a nontoxic fluorescent agent to remove fats and oils, stains and impurities attached to the surface yarn of the fabric, and to have strong light absorbing ability by nontoxic fluorescent compound molecules. Subsequently, a dyeing adjunct is appropriately added to the dyeing pot to finish the biomaterial layer, and a pre-set biomachine having anti-static, heat retention, and endothermic sweat discharging functions is finished.

(ステップ2) 無張力による全面レイヤー顔料着色プロセス:     (Step 2) Overall layer pigmenting process with no tension:

(a) 顔料設定:             (A) Pigment setting:

メインカラーの蛍光顔料ペーストの基準色値を設定した後に、メインカラーと同じ色系列、異なる色値の第1と第2色調カラーの蛍光顔料ペーストをそれぞれ設定し、第1色調カラーの蛍光顔料ペーストがメインカラーと同じ色系列、メインカラーより浅い色調を選定し、色値をメインカラー色値の20%〜30%とし、第2色調カラーの蛍光顔料ペーストがメインカラーと同じ色系列、メインカラーより浅いものを選定し、色値をメインカラー色値の70%〜80%とする。             After setting the reference color value of the main color fluorescent pigment paste, first and second color tone fluorescent pigment pastes of the same color series and different color values as the main color are respectively set, and the first color tone fluorescent pigment paste Select the same color series as the main color, and a color tone shallower than the main color, set the color value to 20% to 30% of the main color color value, and the second color color fluorescent pigment paste has the same color series as the main color, main color A shallower one is selected, and the color value is 70% to 80% of the main color value.

(b) 第1層の無張力の全面図柄層の着色層塗布着色ステップ:
染色温度を90°−100°に設定し、前述無毒蛍光剤を用いて漂白したプレセット生機素材層の基布層201において、2軸ローラーによって、片面全面に第1色調カラーの蛍光顔料ペーストを着色し(第1色調カラーの蛍光顔料ペーストと、メインカラーの色値との比を0.2〜0.3:1に設定。すなわち、メインカラー色値の20%〜30%にする)、第1色調カラーの蛍光顔料ペーストをプレセット生機素材層の基布層201表層の紡績生地層の繊維に染み込ませて、第1層の無張力全面図柄層の着色層21の塗布と着色を完成し、第1層の無張力の全面図柄層の着色層21を効率良く繊維層に染み込ませて、基布層201の下地色層の色調がぬけずに維持すると共に、UV UPF/FPU耐性効果を有し、一部の波長変換効果が50%−60%に達し、その後に染色される無張力の全面図柄層の耐変色性吸収率向上に備える。
(B) Coloring layer application coloring step of the first layer of the tension-free entire surface pattern layer:
In the base fabric layer 201 of the pre-set green material layer set to a dyeing temperature of 90 ° -100 ° and bleached using the above-mentioned non-toxic fluorescent agent, the first color tone fluorescent pigment paste is applied to the entire surface on one side by a biaxial roller. Coloring (the ratio of the first color tone fluorescent pigment paste to the main color color value is set to 0.2 to 0.3: 1, ie, 20% to 30% of the main color color value), The fluorescent pigment paste of the first color tone is impregnated into the fibers of the spun fabric layer of the surface layer of the base fabric layer 201 of the pre-set green machine material layer to complete the application and coloring of the colored layer 21 of the first tensionless overall pattern layer. And the color layer 21 of the first non-tensioned whole surface pattern layer is efficiently impregnated into the fiber layer to maintain the color tone of the base color layer of the base fabric layer 201 completely, and also the UV UPF / FPU resistance effect Have some wavelength conversion effects It reached 0% -60%, comprising the fastness improving color absorption rate of no tension in the entire pattern layer to be dyed subsequently.

(c) 第2層の無張力の全面図柄層の耐変色層塗布着色ステップ:             (C) Color-resistant layer application coloring step of the second layer of the tension-free entire surface pattern layer:

染色温度を90°−100°に設定および維持し、第1層の無張力の全面図柄層の着色層21において、2軸ローラーによって、片面に第2色調カラーの蛍光顔料ペースト(メインカラーと同じ色系列に設定し、メインカラーの色値よりやや薄く、第2色調カラーの蛍光顔料ペーストとメインカラーの色値との比を0.7〜0.8:1に設定する。すなわち、メインカラー色値の70%〜80%に設定する)を着色し、第2色調カラーの蛍光顔料ペーストの着色を行い、第2層の無張力の全面図柄層の耐変色層12を生地表層に塗布すると共に、第2層の無張力の全面図柄層の耐変色層12と、第1層の無張力の全図柄層の着色層11とのオーバーラップ効果により、染色分子の相乗効果によって、生地表層の色度を完成して着色の吸収具合を制御でき、染色完了の生地表層がメインカラーの飽和色度効果を、2つの無張力の全面レイヤーが生地表層において、UV UPF/FPU耐性と光波変換効率が70%〜80%に達して、図柄層の着色プロセスステップを完成する。             The dyeing temperature is set and maintained at 90 ° -100 °, and the second color tone fluorescent pigment paste (same as the main color) is formed on one side by the biaxial roller in the coloring layer 21 of the first layer non tension full pattern layer. The color series is set, the color value of the second color is slightly thinner than the color value of the main color, and the ratio of the fluorescent pigment paste of the second color to the color value of the main color is set to 0.7 to 0.8: 1. Apply 70% to 80% of the color value), color the fluorescent pigment paste of the second color tone, and apply the color-resistant layer 12 of the second layer, tension-free full surface pattern layer to the fabric surface At the same time, due to the overlapping effect of the second layer, the color-resistant layer 12 of the non-tension full surface pattern layer of the second layer and the colored layer 11 of all the non-tension layer of the first layer Complete the color and absorb the color The surface of the fabric that can be controlled and dyed is saturated color effect of the main color, and the two tension-free full surface layers have 70% to 80% UV UPF / FPU resistance and lightwave conversion efficiency reaching 70% to 80%. Complete the layer coloring process step.

(ステップ3) 成型処理プロセス:     (Step 3) Molding process:

前述した全面着色塗布完了の生地表層に無張力乾燥と無塵乾燥を実施し、生地表面に過大な張力による弾性糸弾性と透光率への影響、ホルムアルデヒド(ホルマリン)残存(高温昇華)、粉塵飛散、不純物、生地表面の汚れを防ぐため、高温170°−180°によって生地表面をプレセットし、顔料の着色をより均一化させ、耐変色性をより良くさせ、ホルムアルデヒドを取り除き、ホルムアルデヒドを完全に除去と確認した上、最後に高温プレセットにより、顔料の着色をより均一化させ、耐変色性をより良くさせ、透光性、光吸収性、水洗に強い、図案プリント可能な紫外線防護光学機能性生地の基材20を形成する(図2)。       No tension drying and dust free drying are carried out on the surface of the fabric on which the entire color application has been completed, and excessive tension on the surface of the fabric affects elastic thread elasticity and light transmittance, formaldehyde (formalin) remains (high temperature sublimation), dust Pre-set the dough surface by high temperature 170 ° -180 ° to prevent splashing, impurities, dirt on the dough surface, make the pigment color more uniform, make the color fastness better, remove formaldehyde, completely eliminate formaldehyde Finally, the high temperature preset makes the coloring of the pigment more uniform, makes the color fastness better, and is light transmitting, light absorbing, strong in water washing, and printable UV protection optical design The base material 20 of the functional fabric is formed (FIG. 2).

前述紫外線防護光学機能性生地の基材20(図3)は、体の肌に軽く貼り合わせる基布層201と、基布層201の上部層繊維の紡績層に織り込む着色層21と、表層に結合する耐変色層22と、を含む。       The base material 20 (FIG. 3) of the ultraviolet protection optical functional fabric described above comprises a base fabric layer 201 to be lightly attached to the skin of the body, a colored layer 21 to be woven into the spinning layer of upper layer fibers of the base fabric layer 201, And a color-resistant layer 22 to be bonded.

引き続き図4を参照する。無毒蛍光化合物分子の強い光吸収力を利用し、太陽光から放出される長短波長光エネルギーを吸収して体に有益な赤、オレンジ、黄色、緑、青、インジゴチン、紫外光、波長780(nm)〜390(nm)を幅広く利用する。その例として、帽子20A(図5)、マスク、アームカーバー、衣類、長ズボン、日傘等に適用できる。       Continuing to refer to FIG. Red, orange, yellow, green, blue, indigotin, ultraviolet light, wavelength 780 (nm) which is beneficial to the body by absorbing the long and short wavelength light energy emitted from sunlight utilizing the strong light absorption power of non-toxic fluorescent compound molecule )-390 (nm) widely used. As an example, it can be applied to a hat 20A (FIG. 5), a mask, an arm carver, clothes, long pants, a parasol and the like.

引き続き図6、本発明もう一つの実施例による成形ステップを参照する。       Continuing to refer to FIG. 6, a molding step according to another embodiment of the present invention.

メインカラー蛍光顔料ペーストの基準色値と、2つの同じ色系列異なる色値の融含ゲルマニウム元素を含ませた第1と第2色調カラーの蛍光顔料ペーストを設定、ゲルマニウム元素を融合した第1と第2色調カラーの蛍光顔料ペーストの融合方法として、輝銀鉱(合金ゲルマニウムトランジスタ,GAC)をミクロン単位の微粉末(約5μm)ゲルマニウム元素35に粉砕した後、温度を1500−1800度環境に高温焼結を行い、残存したその他不純物を取り除く灰化作用させ、引き続いて、二次粉砕により、ミクロン単位の微粉末ゲルマニウム元素35をナノクラスの超微細粉末のゲルマニウム元素35に仕上げ、さらに、第1と第2色調カラーの蛍光顔料ペーストを融合し、融合ゲルマニウム元素の第1と第2色調カラーの蛍光顔料ペーストを形成する。続いてポリエステル繊維ナイロンと弾性糸の組織材料の重合物により生機素材に織り上げたプレセット生機は、無毒性の蛍光漂白剤を用いて前処理し、プレセット生機素材層に仕上げる。これにより、プレセット生機素材層の基布層301に、順を追って、2軸ローラーを用いて、片面にゲルマニウム元素を融合した第1と第2色調カラーの蛍光顔料ペーストを塗布及び着色し、第1と第2層の無張力の全面図柄層の着色層31と耐変色層32の塗布着色ステップを行った後に、前述の全面に塗布着色して仕上げられた生地表層に、無張力乾燥と無塵乾燥を経て、生地表面に過大な張力による弾性糸弾性と透光率への影響、ホルムアルデヒド(ホルマリン)残存(高温昇華)、粉塵飛散、不純物、生地表面の汚れを防ぐため、高温170°−180°によって生地表面をプレセットし、顔料の着色をより均一化させ、耐変色性をより良くさせ、ホルムアルデヒドを取り除き、ホルムアルデヒドを完全に除去と確認した上、最後に高温プレセットにより、顔料の着色をより均一化させ、耐変色性をより良くさせ、透光性、光吸収性、水洗に強い、図案プリント可能な紫外線防護光学機能性生地の基材30を形成する(図7)。図柄層に機能性を持たせて、2つの無張力の全面レイヤーの生地表層を合わせてゲルマニウム元素を融合させる。生地表層が体との接触による熱エネルギーが繊維にあるゲルマニウム元素と相互に作用し、自発的に電子と熱エネルギーを伝導して、最高なジュール熱吸収が得られると共に、可視光の波長変換効果を実現し、透光性及び自主的に有益な可視光を吸収する特長を有する。本発明の紫外線防護光学機能性生地から成形された製品(衣類など)を装着した者がマイナスイオンエネルギーを有し、赤外線を放出し、血液循環促進と保温効果を有する。       The first and second color tone fluorescent pigment pastes containing the reference color value of the main color fluorescent pigment paste and the fused germanium elements of two same color series but different color values are set, and the germanium element is fused with the first As a method of fusing the fluorescent pigment paste of the second color tone, after pulverizing pyogenite (alloy germanium transistor, GAC) into micron unit fine powder (about 5 μm) germanium element 35, high temperature baking is performed at 1500-1800 ° C. environment. To form an ashing action to remove the remaining other impurities, and subsequently finish the micronized finely powdered germanium element 35 into a nanoclass ultrafine powdered germanium element 35 by secondary grinding, and further The fluorescent pigment paste of the second color tone is fused, the fluorescent pigment of the first and second color tone of the fused germanium element To form a paste. Subsequently, a pre-set green machine woven into a green machine material with a polymer of polyester fiber nylon and elastic yarn structure material is pretreated with a non-toxic fluorescent bleach to finish it into a pre-set green machine material layer. Thus, first and second color tone fluorescent pigment pastes in which germanium elements are fused on one side are applied and colored to the base fabric layer 301 of the preset green machine material layer sequentially using a biaxial roller, After applying the coloring step of the coloring layer 31 and the color-resistant layer 32 of the first and second non-tension full-surface pattern layers, the non-tension drying is carried out on the surface of the fabric finished by applying coloring on the entire surface. Through dust-free drying, excessive tension on the fabric surface affects elastic thread elasticity and light transmittance, formaldehyde (formalin) remaining (high temperature sublimation), dust scattering, impurities, contamination of the fabric surface, high temperature 170 ° Pre-set the fabric surface by -180 °, make the pigment color more uniform, make the color fastness better, remove the formaldehyde, confirm that the formaldehyde is completely removed, and finally Warm preset makes the coloring of the pigment more uniform, improves the color fastness, and forms the base material 30 of the UV protection optically functional fabric that can transmit light, absorb light, and resists washing with water. Do it (Figure 7). Functionalize the pattern layer and combine the surface layers of the two tension-free full surface layers to fuse the germanium element. The surface layer of the fabric interacts with the thermal energy from contact with the body with the germanium element in the fibers, and spontaneously conducts electrons and thermal energy to obtain the highest Joule heat absorption and the wavelength conversion effect of visible light It has the features of achieving light transmission and absorbing visible light that is beneficial for itself. A person wearing a product (such as clothing) molded from the ultraviolet protective optically functional fabric of the present invention has negative ion energy, emits infrared light, and has blood circulation promoting and heat retaining effects.

図8に示すとおり、前述紫外線防護光学機能性生地の基材30は、基布層301と、着色層31と、耐変色層32とを含む。基布層301の紡績層繊維に着色層31を織り込み、着色層31に耐変色層32を形成する。       As shown in FIG. 8, the base material 30 of the ultraviolet protective optical functional fabric described above includes a base fabric layer 301, a colored layer 31, and a discoloration resistant layer 32. The colored layer 31 is woven into the spun layer fiber of the base fabric layer 301 to form the color-resistant layer 32 in the colored layer 31.

引き続き図9、前述耐変色層32は例えば、撥水性のテフロンを耐変色層32の最外表層に塗布して、撥水防止層33を形成しても良い。       Subsequently, as shown in FIG. 9, for example, water-repellent Teflon may be applied to the outermost surface of the color-resistant layer 32 to form the water-repellent layer 33.

図10に示すように、前述耐変色層32の最外表層に様々な図案のプリント層34(図10)を加工し、プリント層34表層に撥水防止層33を加えても良い。       As shown in FIG. 10, the print layer 34 (FIG. 10) of various designs may be processed on the outermost surface layer of the color change resistant layer 32, and the water repellent prevention layer 33 may be added to the surface layer of the print layer 34.

以上に開示された内容は、本発明の好ましい実施形態であり、本発明の実施範囲を制限するものではない。       The content disclosed above is a preferred embodiment of the present invention, and does not limit the implementation scope of the present invention.

20 紫外線防護光学機能性生地の基材
201 基布層
21 着色層
22 耐変色層
20A 帽子
30 紫外線防護光学機能性生地の基材
301 基布層
31 着色層
32 耐変色層
33 撥水防止層
34 プリント層
35 ゲルマニウム元素
20 Base material of UV protection optical functional fabric
201 Foundation layer
21 colored layer
22 Color resistant layer
20A hat
30 Base material of UV protection optical functional fabric
301 Foundation layer
31 colored layer
32 Color resistant layer
33 Water repellent layer
34 printed layers
35 germanium element

Claims (5)

基布層と、前記基布層の上層の繊維内編地に織り込む着色層と、表層に結合する耐変色層とから構成される紫外線防護光学機能性生地であって、その成形プロセスステップは、
まず、ポリエステル繊維ナイロンと弾性糸の組織材料の重合物を高温処理により汚れを除去してなる生機素材を取得し、無毒性の蛍光漂白前処理を経て、生機の成型を完了し、生地表面の糸に付着した油脂、汚れ、不純物を取り除き、さらに無毒性の蛍光化合物分子によって、強い光吸収能力を持たせて、染色釜に適量の染色補助剤を添加して、生機素材層の成型を仕上げる漂白処理先処理(プレセット生機)プロセスであるステップ1と、無張力によるレイヤーの顔料着色プロセスであるステップ2と、成型処理プロセスであるステップ3とを含み、
前記ステップ2の顔料着色プロセスは、
メインカラーの蛍光顔料ペーストの基準色値を予め設定すると同時に、メインカラーと同じ色系列で、異なる色値の第1と第2色調カラーの蛍光顔料ペーストを1組として設定し、メインカラーと同じ色系列で、メインカラーの色値よりも明るい色調の前記第1色調カラーの蛍光顔料ペーストを選定し、その色値をメインカラーの色値の20%〜30%とし、メインカラーと同じ色系列で、メインカラーの色値よりもやや明るい色調の前記第2色調カラーの蛍光顔料ペーストを選定し、その色値をメインカラーの色値の70%〜80%とする顔料予め設定ステップ(a)と、
予め設定した染色温度において、前記の漂白前処理を経て成型された生機素材層の基布層上に、二軸ローラーによって、片面に前記第1色調カラーの蛍光顔料ペーストを全面塗布して着色し、明るい色度の前記第1色調カラーの蛍光顔料ペーストを成型された生機素材層の前記基布層の上層の生地表面の内編地繊維内に深く染み込ませて、第1層の無張力の全面図柄層の前記着色層の塗布と着色を完成し、前記基布層の下地色層を脱色しないで固色性を安定に維持すると共に、UVの保護指数UPF/FPUを向上させる機能を有し、波長変換効果が50%〜60%に達することで、その後に染色される無張力による全面図柄層の色堅牢度吸尽率を容易に向上させる第1層の無張力の全面図柄層の着色層塗布着色ステップ(b)と、
予め設定した染色温度において、再び二軸ローラーによって、片面に第1層の無張力の全面図柄層の前記着色層上に、前記第2色調カラーの蛍光顔料ペーストを全面塗布して着色を行い、第2層の無張力の全面図柄層の前記耐変色層の塗布を行い、第2層の無張力の全面図柄層の前記耐変色層を生地表層に被覆すると共に、第1と第2層の無張力の全面図柄層の前記着色層との重層作用により、染色分子の相乗効果と相俟って完成した前記生地表層の色度によって着色吸尽率の程度を制御でき、2層の無張力による全面図柄層を有する前記生地表層をUVの保護指数UPF/FPUを向上させる機能を有し、光波長変換効果が70%〜80%に達することで、図柄層の顔料着色工程である前記ステップ2を円滑に完成する第2層の無張力の全面図柄層の前記耐変色層塗布着色ステップ(c)とを含み、
前記ステップ3は、全面図柄層の塗布を経て着色を完了した前記生地表層のみに無張力による乾燥と無塵乾燥を実施し、高温170°〜180°によって生地表面に分散成型し、顔料の発色をより均一化させ、色堅牢度をより良くさせると共に、ホルムアルデヒドを完全に除去と確認した上、ホルムアルデヒド除去した高温成型を完了し、その色堅牢度がパルス光による治療のように、透光性、光吸収性、洗濯堅牢性を兼ね備えた紫外線防護光学機能性生地の基材を形成するステップであることを特徴とする紫外線防護光学機能性生地。
An ultraviolet protective optical functional fabric comprising a base fabric layer, a colored layer to be woven into an in-fiber knitted fabric in the upper layer of the base fabric layer, and a color change resistant layer bonded to the surface layer, the forming process step comprising
First, the raw material of polyester fiber nylon and polymer of elastic yarn is removed by high temperature treatment to remove dirt, and after the non-toxic fluorescent bleaching pre-treatment, the raw molding is completed and the surface of the fabric is finished. Remove fats and oils, stains and impurities attached to the yarn, and give strong light absorbing ability by non-toxic fluorescent compound molecules, add appropriate amount of dyeing assistant to the dyeing pot, and finish molding of the raw material layer Step 1 which is a pre-bleaching treatment (preset green machine) process, step 2 which is a pigment coloring process without tension, and step 3 which is a molding process
The pigmenting process of step 2 is
The reference color value of the main color fluorescent pigment paste is set in advance, and at the same time, the first and second color tone fluorescent pigment pastes of the same color series as the main color but having different color values are set as one set and the same as the main color In the color series, select the fluorescent pigment paste of the first color tone that is brighter than the color value of the main color, and set the color value to 20% to 30% of the color value of the main color, and the same color series as the main color Then, select the second color tone fluorescent pigment paste whose color tone is a little brighter than the color value of the main color, and set the color value to 70% to 80% of the color value of the main color in advance (a) When,
The first color tone fluorescent pigment paste is coated on one side with a biaxial roller on the base cloth layer of the raw material raw material layer molded through the above-mentioned bleaching pretreatment at a predetermined dyeing temperature and colored The light-colored fluorescent pigment paste of the first color tone is deeply impregnated into the inner knitted fabric fibers of the upper surface of the base fabric layer of the molded raw material layer, and the first layer is tensionless. Completes the application and coloring of the colored layer on the entire surface pattern layer, maintains the solid color stability without decolorizing the base colored layer of the base fabric layer, and has the function of improving the UV protection index UPF / FPU And the wavelength conversion effect reaches 50% to 60%, and the color fastness of the whole pattern layer by the no-tensile dyed after that is easily improved the color fastness exhaustion rate of the first layer of the no-tension whole pattern layer Coloring layer application coloring step (b),
At the previously set dyeing temperature, the second color tone fluorescent pigment paste is coated on the entire surface of the first layer of the first layer of no tension full pattern layer again by the biaxial roller, and coloring is performed, The color-resistant layer of the second layer, the non-tension full surface pattern layer, is coated, and the color-resistant layer of the second layer, the non-tension whole surface pattern layer is coated on the fabric surface, The layering effect of the overall pattern pattern layer without tension with the colored layer allows the degree of the coloration exhaustion rate to be controlled by the color of the finished surface layer of the fabric combined with the synergistic effect of the dye molecules, and the tension of two layers is not tensioned. Has the function of improving the UV protection index UPF / FPU of the fabric surface layer having the entire pattern layer according to the above, and the light wavelength conversion effect reaches 70% to 80%, the step of pigment coloring process of the pattern layer 2nd layer no tension all to smoothly complete 2 And a the discoloration layer coating coloring step of the design layer (c),
In step 3 above, only the surface layer of the fabric which has been completely colored through application of the entire pattern layer is subjected to no-tension drying and dust-free drying, and dispersedly molded on the surface of the fabric at a high temperature of 170 ° to 180 °. It is confirmed that the formaldehyde is removed completely, and the high temperature molding with formaldehyde removed is completed, and the color fastness is light-transmissive like treatment with pulsed light An ultraviolet protective optical functional fabric characterized in that it is a step of forming a base of the ultraviolet protective optical functional fabric having light absorbability and washing fastness.
前記紫外線防護光学機能性生地のもう一つの成形プロセスは、
メインカラーの蛍光顔料ペーストの基準色値を予め設定すると同時に、同じ色系列で、異なる色値の2つのゲルマニウム元素を溶融含浸させた第1と第2色調カラーの蛍光顔料ペーストを予め設定し、ゲルマニウム元素を溶融含浸させた第1色調カラーと第2色調カラーの蛍光顔料ペーストの溶融含浸方法として、アルグ石(ゲルマニウム合金の圧電性結晶,GAC)をミクロン単位の微粉末(約5μm)のゲルマニウム元素に研磨粉砕した後、温度を1500〜1800度に設定した環境に置いて高温焼結を行い、まず、残存したその他の不純物を取り除くアッシング作用を行い、引き続いて、前記ミクロン単位の微粉末のゲルマニウム元素を二次研磨粉砕により、ナノレベルの超微細粉末のゲルマニウム元素に仕上げ、それから、前記第1色調カラーと第2色調カラーの蛍光顔料ペーストに溶融含浸させて、ゲルマニウム元素を溶融含浸させた前記第1色調カラーと第2色調カラーの蛍光顔料ペーストを形成し、続いてポリエステル繊維ナイロンと弾性糸の組織材料の重合物により織り上げてなる生機素材を取得し、無毒性の蛍光漂白前処理を経てなる生機の成型を完了し、これにより、前記紫外線防護光学機能性生地の基材の成型された生機素材層の基布層上に、順次に二軸ローラーによって、片面にゲルマニウム元素を溶融含浸させた前記第1色調カラーと第2色調カラーの蛍光顔料ペーストを塗布して着色した後、全面図柄層の塗布を経て着色を完了した前記生地表層のみに、無張力による乾燥と無塵乾燥を実施し、高温によって生地表面に分散成型し、顔料の発色をより均一化させ、色堅牢度をより良くさせると共に、ホルムアルデヒドを完全に除去と確認した上、ホルムアルデヒド除去した高温成型を完了し、その色堅牢度がパルス光による治療のように、透光性、光吸収性、洗濯堅牢性を兼ね備えた前記紫外線防護光学機能性生地の基材を形成することで、図柄層に機能性を持たせて、2層の無張力の全面図柄層を塗布した前記生地表層が人体自身との接触により生じる熱エネルギーで繊維内にあるゲルマニウム元素と相互に作用し、自発的に電子を伝導して最高ジュール数の熱エネルギーが得られて、可視光部分を吸収して波長変換効果を実現し、透光性及び自発的に有益な可視光を吸収する特長を有し、前記紫外線防護光学機能性生地の基材から成形された製品(衣類など)を装着した者は、マイナスイオンエネルギーを発生させ、遠赤外線を放出させることにより、血液循環の促進並びに保温効果を得ることを特徴とする請求項1記載の紫外線防護光学機能性生地。
Another molding process of the UV protection optical functional fabric is
At the same time as presetting reference color values of the main color fluorescent pigment paste, first and second color tone fluorescent pigment pastes in which two germanium elements of different color values are melted and impregnated in the same color series are preset. As a method of melting and impregnating fluorescent pigment pastes of the first color tone and the second color tone in which the germanium element is melt-impregnated, germanium (algite (piezoelectric crystal of germanium alloy, GAC)) in fine powder (approximately 5 μm) of micron unit After grinding and grinding to elements, high temperature sintering is performed in an environment where the temperature is set at 1500 to 1800 ° C, first, ashing is performed to remove remaining other impurities, and subsequently, the fine powder of the micron unit is obtained. Elemental germanium is finished by secondary grinding and grinding to nano level ultrafine powder of elemental germanium, and The fluorescent pigment paste of the color tone and the second color is melt-impregnated to form the fluorescent pigment paste of the first color and the second color which is melt-impregnated with the germanium element, and the polyester fiber nylon and the elastic yarn are subsequently formed. The raw material made of woven fabric is obtained by the polymer of the tissue material, and the molding of the raw material made through non-toxic fluorescent bleaching pretreatment is completed, whereby the base material of the ultraviolet protective optical functional fabric is molded After applying and coloring the first color tone color and the second color tone fluorescent pigment paste of which the germanium element is melt-impregnated on one side sequentially with a biaxial roller on the base fabric layer of the green body material layer, the overall pattern Drying without tension and dust-free drying are carried out only on the surface layer of the fabric that has been completely colored through application of a layer, and dispersion molding is carried out on the surface of the fabric by high temperature, and color development of the pigment is made Make uniform, improve color fastness, confirm complete removal of formaldehyde and complete high temperature molding with formaldehyde removed, and its color fastness is translucency, light like treatment with pulse light By forming the base material of the ultraviolet protective optical functional fabric having both absorbability and washing fastness, the pattern layer is provided with functionality, and the surface layer of the fabric coated with two layers of tension-free entire surface pattern layer The thermal energy generated by contact with the human body interacts with the germanium element in the fiber to spontaneously conduct electrons to obtain the thermal energy of the highest Joule number and absorb the visible light portion to the wavelength A person who wears a product (such as clothing) molded from the base material of the ultraviolet protective optical functional fabric has features of realizing a conversion effect, absorbing light and spontaneously beneficial visible light, minus ON energy is generated, by releasing far infrared of claim 1, wherein the UV protection optical functional material, characterized in that to obtain the promotion and heating effect of the blood circulation.
前記第1色調カラーの蛍光顔料ペーストを、メインカラーと同じ色系列で、かつメインカラーの色値よりも明るい色調であるメインカラーの色値の20%〜30%の色値として設定し、前記第1色調カラーの蛍光顔料ペーストと、メインカラーとの色値比を0.2〜0.3:1に設定し、前記第2色調カラーの蛍光顔料ペーストを、メインカラーと同じ色系列で、かつメインカラーの色値よりもやや明るい色調であるメインカラーの色値の70%〜80%の色値として設定し、前記第2色調カラーの蛍光顔料ペーストと、メインカラーとの色値比を0.7〜0.8:1に設定することを特徴とする、請求項1または請求項2記載の紫外線防護光学機能性生地。     The fluorescent pigment paste of the first color tone is set as a color value of 20% to 30% of the color value of the main color which has the same color series as the main color and is brighter than the color value of the main color, The color value ratio of the fluorescent pigment paste of the first color tone to the main color is set to 0.2 to 0.3: 1, and the fluorescent pigment paste of the second color tone is the same color series as the main color, And set as a color value of 70% to 80% of the color value of the main color that is a little brighter than the color value of the main color, and the color value ratio between the fluorescent pigment paste of the second color and the main color The ultraviolet protection optical functional fabric according to claim 1 or 2, characterized in that it is set to 0.7 to 0.8: 1. 前記第1層の無張力の全面図柄層の前記着色層の前記第1色調カラーの蛍光顔料ペーストの染色温度を90°〜100°に設定すると、前記第2層の無張力の全面図柄層の前記耐変色層の前記第2色調カラーの蛍光顔料ペーストの染色温度を90°〜100°に設定することを特徴とする、請求項1または請求項2記載の紫外線防護光学機能性生地。     When the dyeing temperature of the first color tone fluorescent pigment paste of the colored layer of the non-tension full surface pattern layer of the first layer is set to 90 ° to 100 °, the non-tension full surface pattern layer of the second layer The UV protective optical functional fabric according to claim 1 or 2, wherein the dyeing temperature of the fluorescent pigment paste of the second color tone of the color-resistant layer is set to 90 ° to 100 °. 前記紫外線防護光学機能性生地の基材は、前記耐変色層に撥水性テフロン加工を施した撥水防止層を塗設し、前記撥水防止層を前記耐変色層の最外表層に織り込むか、また前記耐変色層上に図柄層や文様を印刷してなるプリント層を前記耐変色層の最外表層にプリントすることを特徴とする請求項1または請求項2記載の紫外線防護光学機能性生地。     Whether the base material of the UV protection optically functional fabric is coated with a water repellent preventing layer having a water repellent Teflon finish on the color changing layer, and the water repellent preventing layer is woven into the outermost surface of the color changing layer The ultraviolet protection optical functionality according to claim 1 or 2, wherein a print layer formed by printing a pattern layer or a pattern on the color-resistant layer is printed on the outermost surface of the color-resistant layer. Cloth.
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CN114451513A (en) * 2022-01-07 2022-05-10 西北农林科技大学 Method for degrading food endogenous formaldehyde by virtue of Glu-Cys solution soaking and coupled pulsed intense light

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JP2009166407A (en) * 2008-01-18 2009-07-30 Toray Ind Inc Skin material for interior decoration
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114451513A (en) * 2022-01-07 2022-05-10 西北农林科技大学 Method for degrading food endogenous formaldehyde by virtue of Glu-Cys solution soaking and coupled pulsed intense light
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