JP2018515667A - 熱可塑性ポリマー組成物、それから製造された物品、およびそれを作製する方法 - Google Patents
熱可塑性ポリマー組成物、それから製造された物品、およびそれを作製する方法 Download PDFInfo
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- JP2018515667A JP2018515667A JP2017560700A JP2017560700A JP2018515667A JP 2018515667 A JP2018515667 A JP 2018515667A JP 2017560700 A JP2017560700 A JP 2017560700A JP 2017560700 A JP2017560700 A JP 2017560700A JP 2018515667 A JP2018515667 A JP 2018515667A
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- polyamide
- weight
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- molded article
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- 239000000203 mixture Substances 0.000 title claims abstract description 134
- 238000000034 method Methods 0.000 title claims abstract description 51
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 25
- 239000004952 Polyamide Substances 0.000 claims abstract description 71
- 229920002647 polyamide Polymers 0.000 claims abstract description 71
- 239000000654 additive Substances 0.000 claims abstract description 42
- 229910052751 metal Inorganic materials 0.000 claims abstract description 38
- 239000002184 metal Substances 0.000 claims abstract description 38
- 230000008569 process Effects 0.000 claims abstract description 34
- 230000000996 additive effect Effects 0.000 claims abstract description 31
- 229920006012 semi-aromatic polyamide Polymers 0.000 claims abstract description 24
- 229920006114 semi-crystalline semi-aromatic polyamide Polymers 0.000 claims abstract description 23
- 150000003839 salts Chemical class 0.000 claims abstract description 20
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000012745 toughening agent Substances 0.000 claims abstract description 10
- 229920006177 crystalline aliphatic polyamide Polymers 0.000 claims abstract 2
- 238000007747 plating Methods 0.000 claims description 27
- -1 aliphatic diamines Chemical class 0.000 claims description 19
- 239000004953 Aliphatic polyamide Substances 0.000 claims description 18
- 229920003231 aliphatic polyamide Polymers 0.000 claims description 18
- 239000004416 thermosoftening plastic Substances 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000012744 reinforcing agent Substances 0.000 claims description 12
- 229920006345 thermoplastic polyamide Polymers 0.000 claims description 10
- 230000004913 activation Effects 0.000 claims description 7
- 239000011256 inorganic filler Substances 0.000 claims description 7
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 7
- 238000013532 laser treatment Methods 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- 239000004954 Polyphthalamide Substances 0.000 claims description 4
- 229920006375 polyphtalamide Polymers 0.000 claims description 4
- 229920000572 Nylon 6/12 Polymers 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
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- 229920000305 Nylon 6,10 Polymers 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000012784 inorganic fiber Substances 0.000 claims 1
- 239000004760 aramid Substances 0.000 abstract 1
- 229920003235 aromatic polyamide Polymers 0.000 abstract 1
- 238000002844 melting Methods 0.000 description 20
- 230000008018 melting Effects 0.000 description 20
- 239000000463 material Substances 0.000 description 16
- 239000000178 monomer Substances 0.000 description 16
- 239000011029 spinel Substances 0.000 description 16
- 229910052596 spinel Inorganic materials 0.000 description 16
- 239000000835 fiber Substances 0.000 description 14
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 13
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 12
- 125000003118 aryl group Chemical group 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 11
- 239000003365 glass fiber Substances 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 239000003063 flame retardant Substances 0.000 description 8
- 125000001931 aliphatic group Chemical group 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 6
- 229920006123 polyhexamethylene isophthalamide Polymers 0.000 description 6
- 230000002195 synergetic effect Effects 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- 229920002292 Nylon 6 Polymers 0.000 description 5
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- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 238000001465 metallisation Methods 0.000 description 5
- PGGROMGHWHXWJL-UHFFFAOYSA-N 4-(azepane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCC1 PGGROMGHWHXWJL-UHFFFAOYSA-N 0.000 description 4
- 239000004609 Impact Modifier Substances 0.000 description 4
- 229920002302 Nylon 6,6 Polymers 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000001413 amino acids Chemical class 0.000 description 4
- 239000004020 conductor Substances 0.000 description 4
- 150000001879 copper Chemical class 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- 150000003951 lactams Chemical class 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910044991 metal oxide Inorganic materials 0.000 description 4
- 150000004706 metal oxides Chemical class 0.000 description 4
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 229910001053 Nickel-zinc ferrite Inorganic materials 0.000 description 3
- XSAOTYCWGCRGCP-UHFFFAOYSA-K aluminum;diethylphosphinate Chemical compound [Al+3].CCP([O-])(=O)CC.CCP([O-])(=O)CC.CCP([O-])(=O)CC XSAOTYCWGCRGCP-UHFFFAOYSA-K 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- JGDFBJMWFLXCLJ-UHFFFAOYSA-N copper chromite Chemical compound [Cu]=O.[Cu]=O.O=[Cr]O[Cr]=O JGDFBJMWFLXCLJ-UHFFFAOYSA-N 0.000 description 3
- 238000007772 electroless plating Methods 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 229920006119 nylon 10T Polymers 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 229920006128 poly(nonamethylene terephthalamide) Polymers 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- PWGJDPKCLMLPJW-UHFFFAOYSA-N 1,8-diaminooctane Chemical compound NCCCCCCCCN PWGJDPKCLMLPJW-UHFFFAOYSA-N 0.000 description 2
- ZDVRPQIPVMARSE-UHFFFAOYSA-N 11-aminododecanoic acid Chemical compound CC(N)CCCCCCCCCC(O)=O ZDVRPQIPVMARSE-UHFFFAOYSA-N 0.000 description 2
- GAGWMWLBYJPFDD-UHFFFAOYSA-N 2-methyloctane-1,8-diamine Chemical compound NCC(C)CCCCCCN GAGWMWLBYJPFDD-UHFFFAOYSA-N 0.000 description 2
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 description 2
- FQLAJSQGBDYBAL-UHFFFAOYSA-N 3-(azepane-1-carbonyl)benzamide Chemical compound NC(=O)C1=CC=CC(C(=O)N2CCCCCC2)=C1 FQLAJSQGBDYBAL-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 229920006154 PA11T Polymers 0.000 description 2
- 229920006153 PA4T Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 2
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 2
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 2
- RAOSIAYCXKBGFE-UHFFFAOYSA-K [Cu+3].[O-]P([O-])([O-])=O Chemical compound [Cu+3].[O-]P([O-])([O-])=O RAOSIAYCXKBGFE-UHFFFAOYSA-K 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 229910001377 aluminum hypophosphite Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- QVYARBLCAHCSFJ-UHFFFAOYSA-N butane-1,1-diamine Chemical compound CCCC(N)N QVYARBLCAHCSFJ-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 229910000365 copper sulfate Inorganic materials 0.000 description 2
- PDZKZMQQDCHTNF-UHFFFAOYSA-M copper(1+);thiocyanate Chemical compound [Cu+].[S-]C#N PDZKZMQQDCHTNF-UHFFFAOYSA-M 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- YQLZOAVZWJBZSY-UHFFFAOYSA-N decane-1,10-diamine Chemical compound NCCCCCCCCCCN YQLZOAVZWJBZSY-UHFFFAOYSA-N 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- QFTYSVGGYOXFRQ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN QFTYSVGGYOXFRQ-UHFFFAOYSA-N 0.000 description 2
- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
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- 239000000314 lubricant Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- ZETYUTMSJWMKNQ-UHFFFAOYSA-N n,n',n'-trimethylhexane-1,6-diamine Chemical compound CNCCCCCCN(C)C ZETYUTMSJWMKNQ-UHFFFAOYSA-N 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
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- DJZKNOVUNYPPEE-UHFFFAOYSA-N tetradecane-1,4,11,14-tetracarboxamide Chemical compound NC(=O)CCCC(C(N)=O)CCCCCCC(C(N)=O)CCCC(N)=O DJZKNOVUNYPPEE-UHFFFAOYSA-N 0.000 description 2
- 229910000859 α-Fe Inorganic materials 0.000 description 2
- 125000006832 (C1-C10) alkylene group Chemical group 0.000 description 1
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- QFGCFKJIPBRJGM-UHFFFAOYSA-N 12-[(2-methylpropan-2-yl)oxy]-12-oxododecanoic acid Chemical compound CC(C)(C)OC(=O)CCCCCCCCCCC(O)=O QFGCFKJIPBRJGM-UHFFFAOYSA-N 0.000 description 1
- WUIAYLSDSVSPRW-UHFFFAOYSA-N 4-(3-methylpiperidine-1-carbonyl)benzamide Chemical compound C1C(C)CCCN1C(=O)C1=CC=C(C(N)=O)C=C1 WUIAYLSDSVSPRW-UHFFFAOYSA-N 0.000 description 1
- LKWSTQPRPRGLDP-UHFFFAOYSA-N 4-(azacycloundecane-1-carbonyl)benzamide Chemical compound C1=CC(C(=O)N)=CC=C1C(=O)N1CCCCCCCCCC1 LKWSTQPRPRGLDP-UHFFFAOYSA-N 0.000 description 1
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 1
- 239000005750 Copper hydroxide Substances 0.000 description 1
- 229910002477 CuCr2O4 Inorganic materials 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
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- 229920000571 Nylon 11 Polymers 0.000 description 1
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- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910001308 Zinc ferrite Inorganic materials 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
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- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- IYABWNGZIDDRAK-UHFFFAOYSA-N allene Chemical group C=C=C IYABWNGZIDDRAK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229920006020 amorphous polyamide Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- OBTARUYASFQRHM-UHFFFAOYSA-N benzene-1,3-diol;diphenoxyphosphoryl diphenyl phosphate Chemical compound OC1=CC=CC(O)=C1.C=1C=CC=CC=1OP(OP(=O)(OC=1C=CC=CC=1)OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 OBTARUYASFQRHM-UHFFFAOYSA-N 0.000 description 1
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- 150000004696 coordination complex Chemical class 0.000 description 1
- OSDANZNEPXWSQQ-UHFFFAOYSA-N copper chromium(3+) oxygen(2-) Chemical compound [O--].[Cr+3].[Cu++] OSDANZNEPXWSQQ-UHFFFAOYSA-N 0.000 description 1
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- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- WCMHCPWEQCWRSR-UHFFFAOYSA-J dicopper;hydroxide;phosphate Chemical compound [OH-].[Cu+2].[Cu+2].[O-]P([O-])([O-])=O WCMHCPWEQCWRSR-UHFFFAOYSA-J 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
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- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000004957 naphthylene group Chemical group 0.000 description 1
- NQNBVCBUOCNRFZ-UHFFFAOYSA-N nickel ferrite Chemical compound [Ni]=O.O=[Fe]O[Fe]=O NQNBVCBUOCNRFZ-UHFFFAOYSA-N 0.000 description 1
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical compound NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
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- 230000003647 oxidation Effects 0.000 description 1
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- FULFYAFFAGNFJM-UHFFFAOYSA-N oxocopper;oxo(oxochromiooxy)chromium Chemical compound [Cu]=O.O=[Cr]O[Cr]=O FULFYAFFAGNFJM-UHFFFAOYSA-N 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920006115 poly(dodecamethylene terephthalamide) Polymers 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 230000008672 reprogramming Effects 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 229910052566 spinel group Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- GTOWTBKGCUDSNY-UHFFFAOYSA-K tris[[ethyl(methyl)phosphoryl]oxy]alumane Chemical compound [Al+3].CCP(C)([O-])=O.CCP(C)([O-])=O.CCP(C)([O-])=O GTOWTBKGCUDSNY-UHFFFAOYSA-K 0.000 description 1
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical group [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 description 1
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 1
Classifications
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Abstract
Description
(A.1)半結晶性半芳香族ポリアミドと、
(A.2)非晶質半芳香族ポリアミド(a.2.i)もしくは脂肪族ポリアミド(a.2.ii)、または(a.2.i)および(a.2.ii)の混合物と
を含む、少なくとも2つのポリアミドのブレンドを含む。
(A.3)半結晶性脂肪族ポリアミドと、
(A.4)非晶質半芳香族ポリアミドと
を含む、少なくとも2つのポリアミドのブレンドを含む。
またはこれらのポリマーであり、式中、R1およびR2は同一であっても異なっていてもよく、線状または分枝状C1〜C6−アルキルおよび/またはアリールであり;R3は線状または分枝状C1〜C10−アルキレン、C6〜C10−アリーレン、−アルキルアリーレンまたは−アリールアルキレンであり;Mはカルシウムイオン、マグネシウムイオン、アルミニウムイオンおよび亜鉛イオンのうちの1つまたは複数であり、mは2または3であり;nは1または3であり;xは1または2である。R1およびR2は同一であっても異なっていてもよく、好ましくは、メチル、エチル、n−プロピル、イソプロピル、n−ブチル、tert−ブチル、n−ペンチルおよび/またはフェニルである。R3は、好ましくは、メチレン、エチレン、n−プロピレン、イソプロピレン、n−ブチレン、tert−ブチレン、n−ペンチレン、n−オクチレン、n−ドデシレン、またはフェニレンまたはナフチレン、またはメチルフェニレン、エチルフェニレン、tert−ブチルフェニレン、メチルナフチレン、エチルナフチレンまたはtert−ブチルナフチレン、またはフェニルメチレン、フェニルエチレン、フェニルプロピレンまたはフェニルブチレンである。Mは、好ましくは、アルミニウムイオンまたは亜鉛イオンであるように選択される。これらの化合物は、本明細書により参照によって本明細書中に援用される米国特許第6,255,371号明細書に開示される。
(A)合わせて30〜80重量%の量の熱可塑性ポリアミド(A.1)および(A.2)、
(B)5〜60重量%の強化剤、
(C)1〜10重量%のLDS添加剤、
(D)1〜15重量%の(ジ)ホスフィン酸金属塩。
ここで、(A)、(B)、(C)および(D)の合計は最大100重量%である。
(A)合わせて30〜70重量%の量の熱可塑性ポリアミド(A.1)および(A.2);
(B)10〜50重量%の強化剤;
(C)1〜10重量%のLDS添加剤;
(D)1〜15重量%の(ジ)ホスフィン酸金属塩;
(E)0〜30重量%の1つまたは複数のさらなる成分
からなる。ここで、(A)、(B)、(C)、(D)および(E)の合計は100重量%である。
− 熱可塑性組成物がレーザーを用いて活性化された後にめっきされることが可能である、成形されたままの物品;または
− 成形物品であって、レーザー処理によって得られた活性化パターンを成形物品上に含み、レーザー処理により活性化された後にめっきされて導電路を形成することが可能である、成形物品;
− 成形物品であって、レーザー処理により活性化された後に金属めっきされることによって得られる導電路を形成するめっき金属パターンをその上に含む、成形物品
のいずれかであり得る。
PA−1 半結晶性半芳香族ポリアミド:PA−4T/66コポリマー、Tm=320℃、Mn約10,000g/mol、Mw約20,000g/mol
PA−2 半結晶性半芳香族ポリアミド:PA−10T
PA−3 半結晶性脂肪族ポリアミド:PA−410
ガラス繊維 ポリアミドに対する標準グレード、直径10マイクロメートル
LDS添加剤 Cu/CrOx−スピネル
(ジ)ホスフィン酸金属塩Exolit OP1230、ジエチルホスフィン酸アルミニウム
衝撃改質剤 Fusabond A560、エチレン−アクリル系衝撃改質剤
表1および2に示される実施例Iおよび比較例A〜Dの組成物は、Werner&Pfleiderer ZE−25ツインスクリュー押出機において、330℃の平坦な温度プロファイルを用いて構成成分を溶融ブレンドすることによって調製した。ホッパーを介して成分を供給し、サイドフィード(side feed)を介してガラス繊維を添加した。スループットは20kg/時であり、スクリュー速度は200rpmであった。設定の結果、通常、約320〜約350℃の測定溶融温度が得られた。押出機の最後にポリマー溶融物を脱気した。溶融物を押出してストランドにし、冷却し、切断して顆粒にした。
乾燥した顆粒状材料をモールド内で射出成形して、引張試験のISO527タイプ1A、ノッチなしシャルピー試験のISO179/1eU、ノッチ付きシャルピー試験のISO179/1eA、およびHDT試験のISO75に適合する、厚さ4mmの試験棒を形成した。射出成形機内の溶融物の温度は、比較実験A〜Bでは340℃であり、比較実験C〜Dおよび実施例1では310℃であった。モールドの温度は120℃であった。試験棒を使用して、組成物の機械特性を測定した。全ての試験は、製造したままの乾燥状態の試験棒において実行した。組成および主要な試験結果は、表1および表2にまとめられている。
LDS挙動は、最大レーザー出力(最大20W)の50%〜90%の範囲の種々の出力レベル、および種々のパルス周波数(60kHz、80kHzおよび100kHz)を適用し、直径40μmのレーザースポットサイズで20Wレーザーを用いて試験した。Cuのみを含む標準Ethoneめっき浴を用いて10分のめっき時間でめっきを行なった。直径300ミクロンのX線ビームを用いてめっき厚さを測定し、プロセス条件のそれぞれについて3つの異なる測定値を平均化した。結果は表3に示される。
Claims (15)
- A.ポリアミドと、
B.強化剤と、
C.レーザーダイレクトストラクチャリング(LDS)添加剤と
を含む熱可塑性ポリマー組成物であって、前記ポリアミドが、
− (A.1)半結晶性半芳香族ポリアミドと、
− (A.2)非晶質半芳香族ポリアミドもしくは脂肪族ポリアミド、またはこれらの混合物と
のブレンド、または
− (A.3)半結晶性脂肪族ポリアミドと、
− (A.4)非晶質半芳香族ポリアミドと
のブレンドを含み、前記熱可塑性ポリマー組成物が、
D.ホスフィン酸もしくはジホスフィン酸の金属塩、またはその任意のポリマー、またはその任意の混合物
を含む、熱可塑性ポリマー組成物。 - (A.1)が、ポリフタルアミドホモポリマー(PA−XT)、または少なくとも2つの脂肪族ジアミン(X、Y)を含むポリフタルアミドコポリアミド(PA−XT/YT)である、請求項1に記載のポリアミド組成物。
- (A.2)が、好ましくはPA−410、PA−412、PA−610およびPA−612、またはこれらの任意の組み合わせからなる群から選択される脂肪族ポリアミドを含むか、またはそれからなる、請求項1または2に記載のポリアミド組成物。
- (A.3)が、PA−46、PA−66もしくはPA−410、またはこれらの任意の組み合わせを含むか、またはそれからなる、請求項1に記載のポリアミド組成物。
- 成分(D)が(ジ)ホスフィン酸金属塩を含み、金属がアルミニウムもしくは亜鉛、またはこれらの組み合わせである、請求項1〜4のいずれか一項に記載のポリアミド組成物。
- 前記強化剤(B)が無機繊維強化剤もしくは無機充填剤、またはこれらの組み合わせを含む、請求項1〜5のいずれか一項に記載のポリアミド組成物。
- (A)合わせて30〜80重量%の量の熱可塑性ポリアミド(A.1)および(A.2)、または合わせて30〜80重量%の量の熱可塑性ポリアミド(A.3)および(A.4)と、
(B)5〜60重量%の強化剤と、
(C)1〜10重量%のLDS添加剤と、
(D)1〜15重量%の(ジ)ホスフィン酸金属塩と
を含み、(A)、(B)、(C)および(D)の合計が最大で100重量%であり、前記重量百分率(重量%)が前記組成物の全重量に対するものである、請求項1〜6のいずれか一項に記載のポリアミド組成物。 - (A.1)および(A.2)が80/20〜20/80の範囲の重量比(A.1):(A:2)で存在するか、または(A.3)および(A.4)が80/20〜20/80の範囲の重量比(A.3):(A:4)で存在する、請求項1〜7のいずれか一項に記載のポリアミド組成物。
- 前記組成物の前記全重量に対して0.5〜15重量%の量の1つまたは複数のさらなる成分(E)を含む、請求項1〜8のいずれか一項に記載のポリアミド組成物。
- 請求項1〜9のいずれか一項に記載の熱可塑性組成物から製造される成形物品であって、前記熱可塑性組成物が、レーザーを用いて活性化された後にめっきされることが可能である、成形物品。
- 請求項1〜9のいずれか一項に記載の熱可塑性組成物から製造される成形物品であって、レーザー処理によって得られた活性化パターンを前記成形物品上に含み、かつ前記レーザー処理により活性化された後にめっきされて導電路を形成することが可能である、成形物品。
- 請求項1〜9のいずれか一項に記載の熱可塑性組成物から製造される成形物品であって、レーザー処理により活性化された後に金属めっきによって得られる、導電路を形成するめっき金属パターンをその上に含む、成形物品。
- 請求項12に記載の成形物品であって、導電路を形成するめっき金属パターンをその上に含む成形物品を含む、製造物品。
- RFアンテナ、センサー、コネクタ、および電子デバイス用の筺体、例えば、ノートパソコン、携帯電話およびPCタブレット用の筺体および枠からなる群から選択される物品である、請求項13に記載の物品。
- 熱可塑性組成物から製造される成形物品であって、導電路を形成するめっき金属パターンをその上に含む成形物品を製造する方法であって、
− 請求項1〜9のいずれか一項に記載の熱可塑性組成物を成形し、それにより成形物品を得るステップと、
− 前記成形物品をレーザー処理によって処理し、それにより活性化パターンを前記成形物品上に得るステップと、
− 前記成形物品であって、前記活性化パターンをその上に含む前記成形物品を無電解金属めっきプロセスによって処理し、それにより、成形物品であって、めっき金属パターンをその上に含む成形物品を得るステップと
を含む、方法。
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PCT/EP2016/061774 WO2016189023A1 (en) | 2015-05-28 | 2016-05-25 | A thermoplastic polymer composition, an article made thereof and a process for preparing the same |
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US (1) | US11261327B2 (ja) |
EP (1) | EP3303477B1 (ja) |
JP (1) | JP2018515667A (ja) |
KR (1) | KR20180014019A (ja) |
CN (1) | CN107646047B (ja) |
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CN107646047B (zh) | 2020-07-31 |
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