JP2018505562A - 太陽光発電糸および製造方法 - Google Patents
太陽光発電糸および製造方法 Download PDFInfo
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Abstract
Description
1)第1世代:結晶シリコン太陽電池(c-Siおよびmc-Si)
2)第2世代:薄膜太陽電池(a-Si, CdTe, CISまたはCIGS)
3)第3世代:ナノテクノロジーベースの有機太陽電池
1.太陽光発電糸
2.糸
3.中間層
4.カソード層
5.電子伝達層; electron transmission layer (正孔防止層; hole prevention layer) (ETL)
6.活性層
7.正孔伝達層; hole transmission layer(電子防止層;electron prevention layer) (HTL)
8.光透過性および伝導性層(アノード層)
A.光
- 少なくともひとつの加工糸(2)、
- 糸(2)を被覆して、その糸(2)の接着強度を増強する少なくともひとつの中間層(3)、
- 糸(2)の上に、中間層(3)によって付着させることによってコートされ、太陽光発電構造体を有する少なくともひとつのカソード層(4)、
- カソード層(4)の上に位置し、電子アクセプターおよび電子ドナー材料を含み、太陽光発電構造体を有する少なくともひとつの活性層(6);
- いかなる光源からくる光(A)をも光透過性構造体によって他の層にまで転送することができ、カソード層(4)と相互作用することによって電気伝導を行う少なくともひとつのアノード層(8)
を本質的に含む。
- 糸(2)を洗浄するステップ (101)、
- 糸(2)に紡績加工を適用するか、または、糸(2)の表面をコーティングするかによって、中間層(3)を形成するステップ (102)、
- 中間層上にカソード層(4)を形成するステップ (103)、
- 電子アクセプターおよび電子ドナー有機材料を溶媒に溶解し、それらを混合した後、活性層(6)としてコーティングするステップ (104)、
- 光透過性および電気伝導性を可能とする溶液を調製し、アノード層(8)としてコーティングするステップ (105)
を含む。
1.太陽から来る光、換言すれば、フォトンが吸収され、電子-正孔対(エキシトン)が形成された後、刺激状態を実現する
2.電荷分離が実現されるドナー−アクセプター中間面にエキシトンが通過(拡散)する
3.エキシトン電荷分離がドナー−アクセプター中間面上で実現される
4.分離された自由電荷キャリアが、換言すれば、正孔がアノードへ、電子がカソードへ拡散する
5.最後に、適当な電極に電荷が、換言すれば、正孔がアノードへ、電子がカソードへ収集されて、直流を得る
Claims (17)
- 太陽光を使用して発電でき、特に、織物工業に使用すべく開発された太陽光発電糸(1)であって、
- 少なくともひとつの加工糸(2)、
- 糸(2)を被覆して、その糸(2)の接着強度を増強する少なくともひとつの中間層(3)、
- 糸(2)の上に、中間層(3)によって付着させることによってコートされ、太陽光発電構造体を有する少なくともひとつのカソード層(4)、
- カソード層(4)の上に位置し、電子アクセプターおよび電子ドナー材料を含み、太陽光発電構造体を有する少なくともひとつの活性層(6);
- いかなる光源からくる光(A)をも光透過性構造体によって他の層にまで転送することができ、カソード層(4)と相互作用することによって電気伝導を行う少なくともひとつのアノード層(8)
を特徴とする、太陽光発電糸(1)。 - 少なくともひとつの電子伝達層(5)がカソード層(4)と活性層(6)との間に位置することを特徴とする、請求項1に記載の太陽光発電糸(1)。
- 太陽光発電構造体中、少なくともひとつの正孔伝達層 (HTL)(電子防止層) (7)が、活性層(6)とアノード層(8)との間に位置することを特徴とする、前記請求項いずれかに記載の太陽光発電糸(1)。
- 空気媒体中で行われ、前記請求項いずれかに記載の太陽光発電糸(1)を得る、太陽光発電糸製造方法 (100)であって、以下の:
- 糸(2)を洗浄するステップ (101)、
- 糸(2)に紡績加工を適用するか、または、糸(2)の表面をコーティングするかによって、中間層(3)を形成するステップ (102)、
- 中間層上にカソード層(4)を形成するステップ (103)、
- 電子アクセプターおよび電子ドナー有機材料を溶媒に溶解し、それらを混合した後、活性層(6)としてコーティングするステップ (104)、
- 光透過性および電気伝導性を可能とする溶液を調製し、アノード層(8)としてコーティングするステップ (105)
を特徴とする、太陽光発電糸製造方法 (100)。 - 糸(2)を、コートする前に、メタノール、イソプロパノール、および蒸留水プロセスに各々通過させることによって洗浄するステップ (101)を特徴とする、請求項4に記載の太陽光発電糸製造方法 (100)。
- 糸(2)表面を中間層(3)でコーティング (102)し、ここに、表面加工または付着力を促進するポリマーベース溶液を、洗浄された糸(2)にコーティングし、加熱処理を施すステップを特徴とする、請求項4または5に記載の太陽光発電糸製造方法 (100)。
- 中間層(3)上にカソード層(4)を形成し (103)、ここに、太陽光発電構造体中、ガリウム-イリジウム合金 (Ga-Ir)を中間層(3)上に室温条件でコートするステップを特徴とする、請求項4〜6いずれかに記載の太陽光発電糸製造方法 (100)。
- カソード層(7)を中間層(3)の上に形成し (103)、ここに、液体形態のガリウム-イリジウム合金 (Ga-Ir)を室温条件で、いかなる真空システムも必要とせずに、ブラシで中間層(3)上に塗るステップを特徴とする、請求項7に記載の太陽光発電糸製造方法 (100)。
- ZnOおよび/またはTiO2溶液を、ドリッピング、ディッピングまたはスプレイングでカソード層(4)上に塗ることによって電子伝達層(5)を形成し、加熱処理を施すステップを特徴とする、請求項4〜8いずれか1に記載の太陽光発電糸製造方法 (100)。
- 電子アクセプターおよび電子ドナー有機材料を溶媒に溶解し、混合した後に、活性層(6)としてコーティングし (104)、ここに、活性層(6)をカソード層(4)上にコートするステップを特徴とする、請求項4〜8いずれか1に記載の太陽光発電糸製造方法 (100)。
- 電子アクセプターおよび電子ドナー有機材料を溶媒に溶解し、混合した後に、活性層(6)としてコーティングし (104)、ここに、活性層(6)を電子伝達層(5)上にコートするステップを特徴とする、請求項9に記載の太陽光発電糸製造方法 (100)。
- 電子ドナーとして、p-型のポリ(3-ヘキシルチオフェン) (P3HT)、ポリ[N-9’-ヘプタ-デカニル-2,7-カルバゾル-alt-5,5-(4’,7’-ジ-2-チエニル-2’,1’,3’-ベンゾチアジアゾル)] (PCDTBT)、ポリ[2,6-(4,4-ビス-(2-エチルヘキシル)-4H-シクロペンタ[2,1-b;3,4-b’]ジチオフェン)-alt-4,7-(2,1,3-ベンゾチアジアゾル)] (PCPDTBT)、ポリ({4,8-ビス[(2-エチルヘキシル)オキシ]ベンゾ[1,2-b:4,5-b’]ジチオフェン-2,6-ジイル}{3-フルオロ-2-[(2-エチルヘキシル)カルボニル]チエノ[3,4-b]チオフェンジイル}) (PTB7)および当該半導体ポリマーを;電子アクセプターとして、n-型のカーボン-60誘導[6,6]-フェニル-C61-酪酸メチルエステル (PCBM);(6,6)-フェニルC71-酪酸メチルエステル (PC71BM)、1’,1’’,4’,4’’-テトラヒドロ-ジ[1,4]メタノナフタレノ[1,2:2’,3’,56,60:2’’,3’’][5,6]フラーレン-C60、C60誘導体、インデン-C60ビス付加体 (ICBA)および当該半導体ポリマーを、それらを有機溶媒に溶解し、混合して、活性層(6)を形成する材料を得た後、活性層(6)としてコーティングする (104)ステップを特徴とする、請求項10または11に記載の太陽光発電糸製造方法 (100)。
- 二酸化五バナジウム (V2O5)、酸化モリブデン (MoO3)、酸化タングステン (WO3)または酸化ニッケル (NiO)を適切な溶媒に溶解して調製した溶液をドリッピング、ディッピングまたはスプレイングでコートし、次いで、加熱処理を施して、正孔伝達層(7)を形成するステップを特徴とする、請求項4〜12いずれか1に記載の太陽光発電糸製造方法 (100)。
- 光透過性および電気伝達を可能とする溶液を調製し、アノード層(8)としてコーティングし (105)、ここに、アノード層(8)を活性層(6)上にコートするステップを特徴とする、請求項4〜12いずれか1に記載の太陽光発電糸製造方法 (100)。
- 光透過性および電気伝達を可能とする溶液を調製し、アノード層(8)としてコーティングし (105)、ここに、アノード層(8)を正孔伝達層(7)上にコートするステップを特徴とする、請求項13に記載の太陽光発電糸製造方法 (100)。
- 光透過性および電気伝達を可能とする溶液を調製し、アノード層(8)としてコーティングし (105)、ここに、ポリ(3,4-エチレンジオキシチオフェン) (PEDOT)、ポリスチレンスルホネート (PSS)、ジメチルスルホキシド (DMSO)およびトリトンX-100を含む混合物を空気媒体中、ドリッピング、ディッピングまたはスプレイングでコートし、次いで、加熱処理を施すステップを特徴とする、請求項14または15に記載の太陽光発電糸製造方法 (100)。
- 5質量%DMSO、0.1質量%トリトンX-100を含み、光透過性および電気伝達を可能にするポリ(3,4-エチレンジオキシチオフェン):ポリスチレンスルホネート (PEDOT:PSS)材料をアノード層(8)としてコーティングするステップを特徴とする、請求項16に記載の太陽光発電糸製造方法 (100)。
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