JP2018145208A - Brightening cosmetic - Google Patents
Brightening cosmetic Download PDFInfo
- Publication number
- JP2018145208A JP2018145208A JP2018126873A JP2018126873A JP2018145208A JP 2018145208 A JP2018145208 A JP 2018145208A JP 2018126873 A JP2018126873 A JP 2018126873A JP 2018126873 A JP2018126873 A JP 2018126873A JP 2018145208 A JP2018145208 A JP 2018145208A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- present
- cosmetic
- makeup cosmetic
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 229940045920 sodium pyrrolidone carboxylate Drugs 0.000 description 1
- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 1
- HYRLWUFWDYFEES-UHFFFAOYSA-M sodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[O-]C(=O)N1CCCC1=O HYRLWUFWDYFEES-UHFFFAOYSA-M 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229960004274 stearic acid Drugs 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229960003080 taurine Drugs 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229960000984 tocofersolan Drugs 0.000 description 1
- AOBORMOPSGHCAX-DGHZZKTQSA-N tocofersolan Chemical compound OCCOC(=O)CCC(=O)OC1=C(C)C(C)=C2O[C@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C AOBORMOPSGHCAX-DGHZZKTQSA-N 0.000 description 1
- 229940042585 tocopherol acetate Drugs 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 150000003698 vitamin B derivatives Chemical class 0.000 description 1
- 235000011912 vitamin B7 Nutrition 0.000 description 1
- 239000011735 vitamin B7 Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 229940045997 vitamin a Drugs 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- 239000002076 α-tocopherol Substances 0.000 description 1
- 235000004835 α-tocopherol Nutrition 0.000 description 1
- 239000011590 β-tocopherol Substances 0.000 description 1
- 235000007680 β-tocopherol Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、ブライトニング化粧料、さらに詳細には、自然で色白の肌を演出するメークアップ化粧料に関する。 The present invention relates to brightening cosmetics, and more particularly, to makeup cosmetics that produce natural and pale skin.
女性にとって色白の肌を手に入れることは、永遠の憧れであり、このような要求に応えるため、化粧料の分野においては種々の試みがなされている。
たとえば、メラニンの産生を抑制する、いわゆる美白剤と称する化合物を配合した化粧料が商品化されている（例えば、特許文献１、２、及び３参照）。しかしながら、これらの技術においては、美白剤の効果が色白の肌が得られるまでには、数ヶ月の期間を有し、使用直後に色白の肌を得たいという欲求には応えられないという課題が存在する。
また、ファンデーション等のメークアップ化粧料に、特定の無機粉体を着色剤で被覆した改質粉体、微粒子酸化亜鉛被覆粉体、１ミクロン未満の二酸化チタン等の肌を明るく見せる効果を有する素材を配合して、化粧料の使用直後に色白の肌を手に入れようとする試みもある（例えば、特許文献４、５及び６参照）しかしながら、これらの試みにおいては、肌を必要以上に白く見せ、人工的な印象を与えてしまうという課題を有する場合があった。
Obtaining fair skin for women is an eternal admiration, and various attempts have been made in the field of cosmetics to meet such demands.
For example, cosmetics containing a compound called a whitening agent that suppresses the production of melanin have been commercialized (see, for example, Patent Documents 1, 2, and 3). However, in these techniques, there is a problem that the whitening effect has a period of several months until the effect of the whitening agent is obtained, and the desire to obtain the fair skin immediately after use cannot be met. Exists.
In addition, materials that have the effect of brightening skin, such as modified cosmetics coated with specific inorganic powders with colorants, fine-particle zinc oxide-coated powders, titanium dioxide of less than 1 micron, etc., for makeup cosmetics such as foundations However, there are also attempts to obtain fair skin immediately after the use of cosmetics (see, for example, Patent Documents 4, 5 and 6). However, in these attempts, the skin becomes whiter than necessary. There was a case where it had the subject of showing and giving an artificial impression.
すなわち、使用直後に色白の肌が得られ、且つ、人工的でない自然な仕上がりを与える、いわゆる、ライトニング効果を有するメークアップ化粧料が求められていた。一方、鱗片状のアクリルポリマー粉末と金属酸化物を被覆した無機板状粉体とを一定比率で含有するメークアップ化粧料が、人工的でない自然な色白の肌を演出することは知られていなかった。 That is, there has been a demand for makeup cosmetics that have a so-called lightening effect that give light-skinned skin immediately after use and give a non-artificial natural finish. On the other hand, it is not known that makeup cosmetics containing a certain ratio of scaly acrylic polymer powder and inorganic plate-like powder coated with a metal oxide produce non-artificial natural fair skin. It was.
本発明は、人工的でない自然な色白の肌を演出するメークアップ化粧料を提供することを課題とする。 This invention makes it a subject to provide the makeup cosmetics which produce the skin of the natural fairness which is not artificial.
前述した、従来技術の課題を鑑み、本発明者らは人工的でない自然な色白の肌を演出するメークアップ化粧料を求めて鋭意研究した結果、鱗片状のアクリルポリマー粉末と金属酸化物を被覆した無機板状粉体とを一定比率で含有するメークアップ化粧料が課題を解決することを見出し、本発明にいたった。すなわち、本発明は以下に示すとおりである。
（１）以下の成分Ａ）及びＢ）を含有するメークアップ化粧料であって、成分Ａ）と成分Ｂ）との比率Ａ／Ｂが７／３〜３／７の範囲にあることを特徴とするメークアップ化粧料。
Ａ） 鱗片状のアクリルポリマー粉末
Ｂ） 金属酸化物を被覆した無機板状粉体
（２）成分Ｂ）における金属酸化物が二酸化チタン、酸化亜鉛、アルミナ及びシリカから選択される一種または二種以上であることを特徴とする（１）記載のメークアップ化粧料。
（３）成分Ｂ）における無機板状粉体がタルク及び／またはセリサイトであることを特徴とする（１）または（２）記載のメークアップ化粧料。
（４）乳化剤形であることを特徴とする（１）〜（３）いずれかに記載のメークアップ化粧料。
In view of the above-mentioned problems of the prior art, the present inventors have intensively studied for a makeup cosmetic that produces non-artificial natural fair skin, and as a result, coated with scaly acrylic polymer powder and metal oxide. The present inventors have found that a makeup cosmetic containing a certain amount of the inorganic plate-like powder solves the problem and has arrived at the present invention. That is, the present invention is as follows.
(1) A makeup cosmetic containing the following components A) and B), wherein the ratio A / B between component A) and component B) is in the range of 7/3 to 3/7. Makeup cosmetics.
A) Scale-like acrylic polymer powder B) Inorganic plate-like powder coated with metal oxide (2) The metal oxide in component B) is one or more selected from titanium dioxide, zinc oxide, alumina and silica The make-up cosmetic according to (1), wherein
(3) The makeup cosmetic according to (1) or (2), wherein the inorganic plate-like powder in component B) is talc and / or sericite.
(4) The makeup cosmetic according to any one of (1) to (3), which is in an emulsifier form.
本発明によれば、人工的でない自然な色白の肌を演出するメークアップ化粧料を提供することができる。 ADVANTAGE OF THE INVENTION According to this invention, the makeup cosmetics which produce the natural fair skin which is not artificial can be provided.
以下、本発明を詳細に説明する。
＜１＞本発明の必須成分である鱗片状のアクリルポリマー粉末
本発明のメークアップ化粧料は必須成分として、鱗片状のアクリルポリマー粉末を含有することを特徴とする。本発明における鱗片状とは長径が厚さの５倍以上、好ましくは１０倍以上である形状を意味する。また、アクリルポリマーとは、（メタ）アクリル酸、（メタ）アクリル酸エステル、（メタ）アクリル酸アミド等の（メタ）アクリル酸及びその誘導体からなる群から選択される一種または二種以上のモノマー（以後アクリルモノマーと称する）を重合して得られるポリマーを意味する。さらに本発明のアクリルポリマーはスチレン、酢酸ビニル等のアクリルモノマーと共重合可能なモノマーとアクリルモノマーのコポリマーであっても良い。これらの内では、透明性に優れ、自然な仕上がりを与えやすいことから（メタ）アクリル酸エステルのホモポリマーまたはコポリマーが好ましい。
Hereinafter, the present invention will be described in detail.
<1> Scale-like acrylic polymer powder which is an essential component of the present invention The makeup cosmetic of the present invention is characterized by containing a scale-like acrylic polymer powder as an essential component. The scale shape in the present invention means a shape whose major axis is 5 times or more, preferably 10 times or more the thickness. The acrylic polymer is one or more monomers selected from the group consisting of (meth) acrylic acid such as (meth) acrylic acid, (meth) acrylic acid ester, (meth) acrylic acid amide, and derivatives thereof. It means a polymer obtained by polymerizing (hereinafter referred to as acrylic monomer). Further, the acrylic polymer of the present invention may be a copolymer of a monomer copolymerizable with an acrylic monomer such as styrene and vinyl acetate and an acrylic monomer. Among these, a homopolymer or copolymer of (meth) acrylic acid ester is preferable because it is excellent in transparency and easily gives a natural finish.
本発明の鱗片状のアクリルポリマー粉末の粒子径は、電子顕微鏡で観察した長径が１．０〜１００μｍの範囲にあることが好ましい。粒子径が下限値以下では本発明の効果が不十分である場合があり好ましくない。一方、上限値以上では、化粧料の使用時に違和感をおぼえる場合があり好ましくない。 The particle diameter of the scaly acrylic polymer powder of the present invention is preferably in the range of 1.0 to 100 μm in the major axis observed with an electron microscope. If the particle diameter is less than the lower limit, the effect of the present invention may be insufficient, which is not preferable. On the other hand, when the amount is not less than the upper limit, it may be uncomfortable when the cosmetic is used, which is not preferable.
本発明の鱗片状のアクリルポリマー粉末は、例えば、特開２００２−３０８９９６記載の方法で調製することが可能であるが、市販品も存在するので、そのような市販品を入手して使用することも可能である。このような市販としては「スノーリーフS」（昭立プラスチックス工業株式会社製）を例示することができる。 The scaly acrylic polymer powder of the present invention can be prepared, for example, by the method described in JP-A No. 2002-308996. However, since there are commercially available products, such commercially available products should be obtained and used. Is also possible. An example of such a commercially available product is “Snow Leaf S” (manufactured by Shosho Plastics Co., Ltd.).
本発明のメークアップ化粧料における鱗片状のアクリルポリマー粉末の含有量は、化粧料全量に対して０．００１〜１５．０質量％であることが好ましく、０．００５〜１０．０質量％であることがより好ましい。
下限値以下では本発明の効果が得られない場合があり、好ましくない。一方、上限値以上では、自然な仕上がりが損なわれる場合があり好ましくない。
The content of the scaly acrylic polymer powder in the makeup cosmetic of the present invention is preferably 0.001 to 15.0% by mass, and 0.005 to 10.0% by mass with respect to the total amount of the cosmetic. More preferably.
Below the lower limit, the effects of the present invention may not be obtained, which is not preferable. On the other hand, if it is at least the upper limit value, the natural finish may be impaired.
＜２＞本発明の必須成分である金属酸化物を被覆した無機板状粉体
本発明のメークアップ化粧料は必須成分として、金属酸化物を被覆した無機板状粉体（以後、複合板状粉体と称する）を含有することを特徴とする。本発明の複合板状粉体における金属酸化物としては、化粧料としての使用が許容できるものであれば特に限定されないが、複合酸化物として自然な仕上がりを与える効果が高いことから、二酸化チタン、酸化亜鉛、アルミナ及びシリカから選択される一種又は二種以上であることが好ましい。
<2> Inorganic plate-like powder coated with a metal oxide which is an essential component of the present invention The makeup cosmetic composition of the present invention has an inorganic plate-shaped powder coated with a metal oxide as an essential component (hereinafter referred to as a composite plate-like powder). (Referred to as powder). The metal oxide in the composite plate-like powder of the present invention is not particularly limited as long as it can be used as a cosmetic, but since it has a high effect of giving a natural finish as a composite oxide, titanium dioxide, It is preferable that it is 1 type, or 2 or more types selected from a zinc oxide, an alumina, and a silica.
本発明の複合粉体における無機板状粉体としては、具体的には、セリサイト、タルク、
マイカ、カオリン、窒化ホウ素等が例示されるが、使用感が良好なこと、不自然なつやを与えないことから、セリサイト、タルクが好ましい。
As the inorganic plate-like powder in the composite powder of the present invention, specifically, sericite, talc,
Mica, kaolin, boron nitride and the like are exemplified, but sericite and talc are preferable because they have a good feeling of use and do not give an unnatural gloss.
本発明の複合粉体における金属酸化物の被覆量は複合粉体の１０〜５０質量％であることが好ましい。下限値以下では本発明の効果が十分に発揮されない場合があり好ましくない。一方、上限値以上では、化粧料の使用時に違和感をおぼえる場合があり好ましくない。 The coating amount of the metal oxide in the composite powder of the present invention is preferably 10 to 50% by mass of the composite powder. Below the lower limit, the effects of the present invention may not be sufficiently exhibited, which is not preferable. On the other hand, when the amount is not less than the upper limit, it may be uncomfortable when the cosmetic is used, which is not preferable.
本発明の複合粉体の粒子径は、電子顕微鏡で観察した長径が１．０〜４０μｍの範囲にあることが好ましい。粒子径が下限値以下では本発明の効果が不十分である場合があり好ましくない。一方、上限値以上では、化粧料の使用時に違和感をおぼえる場合があり好ましくない。 As for the particle diameter of the composite powder of the present invention, the major axis observed with an electron microscope is preferably in the range of 1.0 to 40 μm. If the particle diameter is less than the lower limit, the effect of the present invention may be insufficient, which is not preferable. On the other hand, when the amount is not less than the upper limit, it may be uncomfortable when the cosmetic is used, which is not preferable.
本発明の複合粉体は無機板状粉体に、通常の湿式の被覆法により金属酸化物を被覆することにより得られるが、市販品も存在するので、これら市販品を入手して使用することもできる。このような市販品としては、「カバーリーフＡＲ８０（二酸化チタン、アルミナ及びシリカ被覆タルク）」、「カバーリーフＰＣ−２０５５（二酸化チタン被覆タルク」、「カバーリーフＰＣ−１０３５（二酸化チタン被覆セリサイト）」（いずれも、日揮触媒化成株式会社製）等が例示される。 The composite powder of the present invention can be obtained by coating an inorganic plate-like powder with a metal oxide by a usual wet coating method. However, since there are commercially available products, these commercial products should be obtained and used. You can also. As such commercially available products, “Coverleaf AR80 (titanium dioxide, alumina and silica-coated talc)”, “Coverleaf PC-2055 (titanium dioxide-coated talc”), “Coverleaf PC-1035 (titanium dioxide-coated sericite)” (All manufactured by JGC Catalysts & Chemicals Co., Ltd.).
本発明のメークアップ化粧料における複合粉体の含有量は、化粧料全量に対して０．００１〜１５．０質量％であることが好ましく、０．００５〜１０．０質量％であることがより好ましい。下限値以下では本発明の効果が得られない場合があり、好ましくない。一方、上限値以上では、自然な仕上がりが損なわれる場合があり好ましくない。 The content of the composite powder in the makeup cosmetic of the present invention is preferably 0.001 to 15.0% by mass, and preferably 0.005 to 10.0% by mass with respect to the total amount of the cosmetic. More preferred. Below the lower limit, the effects of the present invention may not be obtained, which is not preferable. On the other hand, if it is at least the upper limit value, the natural finish may be impaired.
＜３＞本発明のメークアップ化粧料
本発明のメークアップ化粧料は、必須成分としてＡ）鱗片状のアクリルポリマー粉末及びＢ）金属酸化物を被覆した無機板状粉体を、これらの比率Ａ／Ｂ（質量比）が７／３〜３／７、好ましくは６／４〜４／６の範囲で含有することを特徴とする。本発明のメークアップ化粧料においては前記比率Ａ／Ｂが該範囲内である場合のみ目的とする効果が得られる。
<3> Makeup Cosmetic of the Present Invention The makeup cosmetic of the present invention comprises an inorganic plate-like powder coated with A) scaly acrylic polymer powder and B) metal oxide as essential components. / B (mass ratio) is 7/3 to 3/7, preferably 6/4 to 4/6. In the makeup cosmetic of the present invention, the intended effect can be obtained only when the ratio A / B is within this range.
さらに、本発明のメークアップ化粧料は上記必須成分以外に通常化粧料で使用される任意成分を発明の効果を損なわない範囲で含有することができる。かかる任意成分としては、例えば、マカデミアナッツ油、アボカド油、トウモロコシ油、オリーブ油、ナタネ油、ゴマ油、ヒマシ油、サフラワー油、綿実油、ホホバ油、ヤシ油、パーム油、液状ラノリン、硬化ヤシ油、硬化油、モクロウ、硬化ヒマシ油、ミツロウ、キャンデリラロウ、カルナウバロウ、イボタロウ、ラノリン、還元ラノリン、硬質ラノリン、ホホバロウ等のオイル、ワックス類、流動パラフィン、スクワラン、プリスタン、オゾケライト、パラフィン、セレシン、ワセリン、マイクロクリスタリンワックス等の炭化水素類、オレイン酸、イソステアリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、ウンデシレン酸等の高級脂肪酸類、セチルアルコール、ステアリルアルコール、イソステアリルアルコール、ベヘニルアルコール、オクチルドデカノール、ミリスチルアルコール、セトステアリルアルコール等の高級アルコール等、イソオクタン酸セチル、ミリスチン酸イソプロピル、イソステアリン酸ヘキシルデシル、アジピン酸ジイソプロピル、セバチン酸ジ−２−エチルヘキシル、乳酸セチル、リンゴ酸ジイソステアリル、ジ−２−エチルヘキサン酸エチレングリコール、ジカプリン酸ネオペンチルグリコール、ジ−２−ヘプチルウンデカン酸グリセリン、トリ−２−エチルヘキサン酸グリセリン、トリ−２−エチルヘキサン酸トリメチロールプロパン、トリイソステアリン酸トリメチロールプロパン、テトラ−２−エチルヘキサン酸ペンタンエリトリット等の合成エステル油類、ジメチルポリシ
ロキサンメチルフェニルポリシロキサン、ジフェニルポリシロキサン等の鎖状ポリシロキサン、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサンシロキサン等の環状ポリシロキサン、アミノ変性ポリシロキサン、ポリエーテル変性ポリシロキサン、アルキル変性ポリシロキサン、フッ素変性ポリシロキサン等の変性ポリシロキサン、脂肪酸セッケン（ラウリン酸ナトリウム、パルミチン酸ナトリウム等）、ラウリル硫酸カリウム、アルキル硫酸トリエタノールアミンエーテル等のアニオン界面活性剤類、塩化ステアリルトリメチルアンモニウム、塩化ベンザルコニウム、ラウリルアミンオキサイド等のカチオン界面活性剤類、イミダゾリン系両性界面活性剤（２−ココイル−２−イミダゾリニウムヒドロキサイド−１−カルボキシエチロキシ２ナトリウム塩等）、ベタイン系界面活性剤（アルキルベタイン、アミドベタイン、スルホベタイン等）、アシルメチルタウリン等の両性界面活性剤類、ソルビタン脂肪酸エステル類（ソルビタンモノステアレート、セスキオレイン酸ソルビタン等）、グリセリン脂肪酸類（モノステアリン酸グリセリン等）、プロピレングリコール脂肪酸エステル類（モノステアリン酸プロピレングリコール等）、硬化ヒマシ油誘導体、グリセリンアルキルエーテル、ＰＯＥソルビタン脂肪酸エステル類（ＰＯＥソルビタンモノオレエート、モノステアリン酸ポリオキシエチレンソルビタン等）、ＰＯＥソルビット脂肪酸エステル類（ＰＯＥ−ソルビットモノラウレート等）、ＰＯＥグリセリン脂肪酸エステル類（ＰＯＥ−グリセリンモノイソステアレート等）、ＰＯＥ脂肪酸エステル類（ポリエチレングリコールモノオレート、ＰＯＥジステアレート等）、ＰＯＥアルキルエーテル類（ＰＯＥ２−オクチルドデシルエーテル等）、ＰＯＥアルキルフェニルエーテル類（ＰＯＥノニルフェニルエーテル等）、プルロニック型類、ＰＯＥ・ＰＯＰアルキルエーテル類（ＰＯＥ・ＰＯＰ２−デシルテトラデシルエーテル等）、テトロニック類、ＰＯＥヒマシ油・硬化ヒマシ油誘導体（ＰＯＥヒマシ油、ＰＯＥ硬化ヒマシ油等）、ショ糖脂肪酸エステル、アルキルグルコシド等の非イオン界面活性剤類、ポリエチレングリコール、グリセリン、１，３−ブチレングリコール、エリスリトール、ソルビトール、キシリトール、マルチトール、プロピレングリコール、ジプロピレングリコール、ジグリセリン、イソプレングリコール、１，２−ペンタンジオール、２，４−ヘキシレングリコール、１，２−ヘキサンジオール、１，２−オクタンジオール等の多価アルコール類、ピロリドンカルボン酸ナトリウム、乳酸、乳酸ナトリウム等の保湿成分類、グアガム、クインスシード、カラギーナン、ガラクタン、アラビアガム、ペクチン、マンナン、デンプン、キサンタンガム、カードラン、メチルセルロース、ヒドロキシエチルセルロース、カルボキシメチルセルロース、メチルヒドロキシプロピルセルロース、コンドロイチン硫酸、デルマタン硫酸、グリコーゲン、ヘパラン硫酸、ヒアルロン酸、ヒアルロン酸ナトリウム、トラガントガム、ケラタン硫酸、コンドロイチン、ムコイチン硫酸、ヒドロキシエチルグアガム、カルボキシメチルグアガム、デキストラン、ケラト硫酸，ローカストビーンガム，サクシノグルカン，カロニン酸，キチン，キトサン、カルボキシメチルキチン、寒天、ポリビニルアルコール、ポリビニルピロリドン、カルボキシビニルポリマー、ポリアクリル酸ナトリウム、ポリエチレングリコール、ベントナイト等の増粘剤、表面処理されていても良い、マイカ、タルク、カオリン、合成雲母、炭酸カルシウム、炭酸マグネシウム、無水ケイ酸（シリカ）、酸化アルミニウム、硫酸バリウム等の粉体類、表面処理されていても良い、酸化コバルト、群青、紺青、酸化亜鉛の無機顔料類、表面処理されていても良い、酸化鉄二酸化チタン焼結体等の複合顔料、表面処理されていても良い、雲母チタン、魚燐箔、オキシ塩化ビスマス等のパール剤類、レーキ化されていても良い赤色２０２号、赤色２２８号、赤色２２６号、黄色４号、青色４０４号、黄色５号、赤色５０５号、赤色２３０号、赤色２２３号、橙色２０１号、赤色２１３号、黄色２０４号、黄色２０３号、青色１号、緑色２０１号、紫色２０１号、赤色２０４号等の有機色素類、ポリエチレン末、ポリメタクリル酸メチル、ナイロン粉末、オルガノポリシロキサンエラストマー等の有機粉体類、エタノール、イソプロパノール等の低級アルコール類、ビタミンＡ又はその誘導体、ビタミンＢ６塩酸塩，ビタミンＢ６トリパルミテート，ビタミンＢ６ジオクタノエート，ビタミンＢ２又はその誘導体，ビタミンＢ１２，ビタミンＢ１５又はその誘導体等のビタミンＢ類、α−トコフェロール
，β−トコフェロール，γ−トコフェロール，ビタミンＥアセテート等のビタミンＥ類、ビタミンＤ類、ビタミンＨ、パントテン酸、パンテチン、ピロロキノリンキノン等のビタミン類などが好ましく例示できる。
Furthermore, the makeup cosmetics of this invention can contain the arbitrary component normally used with cosmetics other than the said essential component in the range which does not impair the effect of invention. Such optional ingredients include, for example, macadamia nut oil, avocado oil, corn oil, olive oil, rapeseed oil, sesame oil, castor oil, safflower oil, cottonseed oil, jojoba oil, coconut oil, palm oil, liquid lanolin, hydrogenated coconut oil, hardened Oil, molasses, hydrogenated castor oil, beeswax, candelilla wax, carnauba wax, botarou, lanolin, reduced lanolin, hard lanolin, jojoba oil, waxes, liquid paraffin, squalane, pristane, ozokerite, paraffin, ceresin, petrolatum, micro Hydrocarbons such as crystallin wax, oleic acid, isostearic acid, lauric acid, myristic acid, palmitic acid, higher fatty acids such as stearic acid, behenic acid, undecylenic acid, cetyl alcohol, stearyl alcohol, isostearyl High alcohols such as alcohol, behenyl alcohol, octyldodecanol, myristyl alcohol, cetostearyl alcohol, cetyl isooctanoate, isopropyl myristate, hexyldecyl isostearate, diisopropyl adipate, di-2-ethylhexyl sebacate, cetyl lactate, malic acid Diisostearyl, di-2-ethylhexanoic acid ethylene glycol, dicaprate neopentyl glycol, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid glycerin, tri-2-ethylhexanoic acid trimethylolpropane, tri Synthetic ester oils such as trimethylolpropane isostearate and pentane erythritol tetra-2-ethylhexanoate, dimethylpolysiloxane methylphenylpolysiloxane Sun, chain polysiloxane such as diphenylpolysiloxane, cyclic polysiloxane such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexanesiloxane, amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, Modified polysiloxanes such as fluorine-modified polysiloxanes, fatty acid soaps (sodium laurate, sodium palmitate, etc.), anionic surfactants such as potassium lauryl sulfate, alkyl sulfate triethanolamine ether, stearyltrimethylammonium chloride, benzalkonium chloride , Cationic surfactants such as laurylamine oxide, imidazoline-based amphoteric surfactants (2-cocoyl-2-imidazolinium hydroxide-1- Carboxyethyloxy disodium salt, etc.), betaine surfactants (alkyl betaine, amide betaine, sulfobetaine, etc.), amphoteric surfactants such as acylmethyl taurine, sorbitan fatty acid esters (sorbitan monostearate, sesquioleic acid) Sorbitan, glycerin fatty acids (glyceryl monostearate, etc.), propylene glycol fatty acid esters (propylene glycol monostearate, etc.), hardened castor oil derivatives, glycerin alkyl ether, POE sorbitan fatty acid esters (POE sorbitan monooleate, Monostearate polyoxyethylene sorbitan, etc.), POE sorbite fatty acid esters (POE-sorbite monolaurate, etc.), POE glycerin fatty acid esters (POE-glycerin) Noisostearate, etc.), POE fatty acid esters (polyethylene glycol monooleate, POE distearate, etc.), POE alkyl ethers (POE2-octyldodecyl ether, etc.), POE alkyl phenyl ethers (POE nonylphenyl ether, etc.), Pluronic type , POE / POP alkyl ethers (POE / POP2-decyltetradecyl ether, etc.), Tetronics, POE castor oil / hardened castor oil derivatives (POE castor oil, POE hardened castor oil, etc.), sucrose fatty acid ester, alkyl Nonionic surfactants such as glucoside, polyethylene glycol, glycerin, 1,3-butylene glycol, erythritol, sorbitol, xylitol, maltitol, propylene glycol, dipropylene glycol Polyol, diglycerin, isoprene glycol, 1,2-pentanediol, 2,4-hexylene glycol, 1,2-hexanediol, 1,2-octanediol and other polyhydric alcohols, sodium pyrrolidonecarboxylate, lactic acid , Moisturizing ingredients such as sodium lactate, guar gum, quince seed, carrageenan, galactan, gum arabic, pectin, mannan, starch, xanthan gum, curdlan, methylcellulose, hydroxyethylcellulose, carboxymethylcellulose, methylhydroxypropylcellulose, chondroitin sulfate, dermatan sulfate , Glycogen, heparan sulfate, hyaluronic acid, sodium hyaluronate, tragacanth gum, keratan sulfate, chondroitin, mucoitin sulfate, hydroxyethyl guar gum, cal Boxymethyl guar gum, dextran, keratosulfuric acid, locust bean gum, succinoglucan, caronic acid, chitin, chitosan, carboxymethylchitin, agar, polyvinyl alcohol, polyvinylpyrrolidone, carboxyvinyl polymer, sodium polyacrylate, polyethylene glycol, bentonite Thickener such as mica, talc, kaolin, synthetic mica, calcium carbonate, magnesium carbonate, silicic acid (silica), aluminum oxide, barium sulfate, etc., surface treated Cobalt oxide, ultramarine blue, bitumen, zinc oxide inorganic pigments, surface treated, composite pigments such as iron oxide titanium dioxide sintered body, surface treated, mica titanium, Pearl agents such as fish phosphorus foil and bismuth oxychloride Red 202, Red 228, Red 226, Yellow 4, Blue 404, Yellow 5, Red 505, Red 230, Red 223, Orange 201, Red 213, which may be raked No., Yellow No. 204, Yellow No. 203, Blue No. 1, Green No. 201, Purple No. 201, Red No. 204, etc., organic powders such as polyethylene powder, polymethyl methacrylate, nylon powder, organopolysiloxane elastomer, etc. Body, lower alcohols such as ethanol, isopropanol, vitamin A or derivatives thereof, vitamin B 6 hydrochloride, vitamin B 6 tripalmitate, vitamin B 6 dioctanoate, vitamin B 2 or derivatives thereof, vitamin B 12 , vitamin B 15 Or vitamin B such as derivatives thereof, α-tocopherol, β-tocopherol, γ-to Ferrol, vitamin E such as vitamin E acetate, vitamin D, vitamin H, pantothenic acid, pantethine, and vitamins pyrroloquinoline quinone or the like can preferably be mentioned.
本発明のメークアップ化粧料の形態としては、乳化剤形化粧料、粉末化粧料、油性化粧料、ゲル状化粧料、液状化粧料等が例示できる。また、本発明のメークアップ化粧料としては、ファンデーション、アンダーメーク、フェイスカラー、チークカラー、アイカラー、リップカラー等が例示できるが、これらのうちでは、塗布面積が広く、発明の効果が得やすいことから、ファンデーション、アンダーメークが好ましい。
本発明のメークアップ化粧料は、前記必須成分と任意成分を常法にしたがって処理することにより得られる。
Examples of the makeup cosmetic composition of the present invention include emulsifier cosmetics, powder cosmetics, oily cosmetics, gel cosmetics, and liquid cosmetics. Examples of the makeup cosmetic of the present invention include foundations, undermakes, face colors, cheek colors, eye colors, lip colors, etc. Among them, the application area is wide and the effects of the invention can be easily obtained. Therefore, a foundation and an undermake are preferable.
The makeup cosmetic of the present invention can be obtained by treating the essential components and optional components according to a conventional method.
以下、実施例を挙げて本発明を詳細に説明するが、本発明がこれら実施例に限定されるものではない。 EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated in detail, this invention is not limited to these Examples.
＜実施例１〜５、比較例１〜４＞
表１の処方に従って本発明のメークアップ化粧料である、油中水乳化型ファンデーション及び比較例の油中水乳化型ファンデーションを調製した。すなわち、成分（イ）を攪拌混合した後、７０℃に加熱した。この混合物に、ディスパーにより成分（ロ）を均一分散した。加熱下、攪拌を続けながら、７０℃に加熱した成分（ハ）を徐々に添加して乳化を行った。室温まで冷却して、油中水乳化型ファンデーションを得た。なお、表中の数値は質量％を表す。
<Examples 1-5, Comparative Examples 1-4>
A water-in-oil emulsified foundation and a water-in-oil emulsified foundation of Comparative Example, which are makeup cosmetics of the present invention, were prepared according to the formulations in Table 1. That is, the component (I) was stirred and mixed and then heated to 70 ° C. In this mixture, the component (b) was uniformly dispersed by a disper. While continuing stirring under heating, the component (c) heated to 70 ° C. was gradually added to emulsify. After cooling to room temperature, a water-in-oil emulsified foundation was obtained. In addition, the numerical value in a table | surface represents the mass%.
＊２）「カバーリーフＰＣ−１０３５」 日揮触媒化成株式会社製
＊３）「スノーリーフＳ」 昭立プラスチックス工業株式会社製
＜試験例１＞ライトニング効果の評価
実施例１〜５、比較例１〜４の油中水乳化型ファンデーションを肌に塗布し、塗布後の明度の変化ΔＬ及び彩度の変化ΔＣを求めた。結果を表２に示す。ΔＬが大きく、ΔＣの小さいほどごく自然なライトニング効果が高いことを示す。
<Test Example 1> Evaluation of Lightning Effect The water-in-oil emulsified foundations of Examples 1 to 5 and Comparative Examples 1 to 4 were applied to the skin, and lightness change ΔL and chroma change ΔC after application were determined. The results are shown in Table 2. A larger ΔL and a smaller ΔC indicate a higher natural lightening effect.
＜試験例２＞ライトニング効果の官能評価
実施例１〜５、比較例１〜４の油中水乳化型ファンデーションを肌に塗布し、熟練評価者５名により、以下の基準に従って、肌を明るく見せる効果及び素肌感を評価した。５名の平均値をその油中水乳化型ファンデーションのスコアとした。結果を表２に示す。
表２から明らかなように、本発明のファンデーションを肌に塗布するとΔＬが大きくかつΔＣが小さく高いライトニング効果を有することが確認された。また、この効果は、官能評価によっても確認された。
＊評価基準１＊
肌を明るく見せる効果が比較例１のファンデーションと比較して
かなりある・・・・・・・・・・・・・５点
ある・・・・・・・・・・・・・・・・４点
同等・・・・・・・・・・・・・・・・３点
ややない・・・・・・・・・・・・・・２点
ほとんどない・・・・・・・・・・・・１点
＊評価基準２＊
素肌感が比較例１のファンデーションと比較して
かなりある・・・・・・・・・・・・・５点
ある・・・・・・・・・・・・・・・・４点
同等・・・・・・・・・・・・・・・・３点
ややない・・・・・・・・・・・・・・２点
ほとんどない・・・・・・・・・・・・１点
<Test Example 2> Sensory evaluation of lightening effect The water-in-oil emulsified foundations of Examples 1 to 5 and Comparative Examples 1 to 4 were applied to the skin, and the skin was brightened by five skilled evaluators according to the following criteria. The effect and the feeling of bare skin were evaluated. The average value of 5 people was used as the score of the water-in-oil emulsion type foundation. The results are shown in Table 2.
As is apparent from Table 2, it was confirmed that when the foundation of the present invention was applied to the skin, ΔL was large and ΔC was small and had a high lightening effect. This effect was also confirmed by sensory evaluation.
* Evaluation criteria 1 *
Compared with the foundation of Comparative Example 1, the effect of making the skin look brighter is considerably ... 5 points ... 4 Equivalent to the point ... 3 No, not enough ... 2 Almost no ... .. 1 point
* Evaluation criteria 2 *
Compared with the foundation of Comparative Example 1 there is a lot of bare skin feeling ... 5 points ... 4 points equivalent ... ……………… 3 points are not enough ・ ・ ・ ・ ・ ・ ・ ・ ・ ・ ・ 2 points are almost not ... 1 point
＜実施例６〜１０、比較例５〜８＞
表３の処方に従って本発明のメークアップ化粧料である、水中油乳化型ファンデーション及び比較例の水中油乳化型ファンデーションを調製した。すなわち、成分（イ）を攪拌混合した後、７０℃に加熱した。この混合物に、ディスパーにより成分（ロ）を均一分散した。加熱下、攪拌を続けながら、７０℃に加熱した成分（ハ）を徐々に添加して乳化を行った。冷却をおこなって、５０℃になったところで、成分（ニ）添加し、さらに室温まで冷却して水中油乳化型ファンデーションを得た。なお、表中の数値は質量％を表す。
さらに、試験例1及び２に準じて実施例６〜１０、比較例５〜８の水中油乳化型ファンデーションのライトニング効果を評価した。なお、官能評価においては比較例５を対象とした。結果を表4に示す。
表４からあきらかなように水中油乳化剤形においても本発明の効果が確認された。
<Examples 6 to 10, Comparative Examples 5 to 8>
According to the formulation in Table 3, oil-in-water emulsified foundations and comparative oil-in-water emulsified foundations, which are makeup cosmetics of the present invention, were prepared. That is, the component (I) was stirred and mixed and then heated to 70 ° C. In this mixture, the component (b) was uniformly dispersed by a disper. While continuing stirring under heating, the component (c) heated to 70 ° C. was gradually added to emulsify. When cooling was performed and the temperature reached 50 ° C., component (d) was added, and further cooled to room temperature to obtain an oil-in-water emulsion type foundation. In addition, the numerical value in a table | surface represents the mass%.
Furthermore, the lightening effect of the oil-in-water emulsion foundations of Examples 6 to 10 and Comparative Examples 5 to 8 was evaluated according to Test Examples 1 and 2. In sensory evaluation, Comparative Example 5 was used. The results are shown in Table 4.
As clearly shown in Table 4, the effect of the present invention was also confirmed in the oil-in-water emulsifier form.
＊２）「カバーリーフＰＣ−１０３５」 日揮触媒化成株式会社製
＊３）「スノーリーフＳ」 昭立プラスチックス工業株式会社製
＜実施例１１〜１５、比較例９〜１２＞
下記、表５にしたがって本発明のメークアップ化粧料であるパウダーファンデーション及び比較例のメークアップ化粧料であるパウダーファンデーションを調製した。すなわち、成分（イ）をヘンシェルミキサー均一混合した後、丸穴スクリーンを装着したパルベライザーで粉砕した後、再び、ヘンシェルミキサー中で成分（ロ）と混合し、へリングボーンスクリーンを装着したパルベライザーにて粉砕し、アルミ中皿にプレス充填し、パウダーファンデーションを得た。なお、表中の数値は質量％を表す。
さらに、試験例1及び２に準じて実施例１１〜１５、比較例９〜１２のパウダーファンデーションのライトニング効果を評価した。なお、官能評価においては比較例９を対象と
した。結果を表６に示す。
表６からあきらかなように粉末化粧料においても本発明の効果が確認された。
<Examples 11 to 15 and Comparative Examples 9 to 12>
According to the following Table 5, the powder foundation which is the makeup cosmetic of the present invention and the powder foundation which is the makeup cosmetic of the comparative example were prepared. That is, after the component (I) is uniformly mixed in the Henschel mixer, pulverized with a pulverizer equipped with a round hole screen, then mixed again with the component (b) in a Henschel mixer, and then pulverized with a herringbone screen. The powder foundation was obtained by crushing and press-filling into an aluminum pan. In addition, the numerical value in a table | surface represents the mass%.
Furthermore, the lightening effect of the powder foundations of Examples 11 to 15 and Comparative Examples 9 to 12 was evaluated according to Test Examples 1 and 2. In sensory evaluation, Comparative Example 9 was used. The results are shown in Table 6.
As apparent from Table 6, the effect of the present invention was confirmed also in the powder cosmetic.
＊２）「カバーリーフＰＣ−１０３５」 日揮触媒化成株式会社製
＊３）「スノーリーフＳ」 昭立プラスチックス工業株式会社製
本発明は化粧料として利用できる。 The present invention can be used as a cosmetic.
Claims (4)
Ａ） 鱗片状のアクリルポリマー粉末を化粧料全量に対して０．００１〜１５．０質量％Ｂ） 金属酸化物を被覆した無機板状粉体を化粧料全量に対して０．００１〜１５．０質量％ A makeup cosmetic containing the following components A) and B), wherein the ratio A / B (mass ratio) between component A) and component B) is in the range of 7/3 to 3/7. The make-up cosmetics featured.
A) 0.001 to 15.0% by mass of the scaly acrylic polymer powder based on the total amount of the cosmetic B) The inorganic plate-shaped powder coated with the metal oxide is 0.001 to 15% based on the total amount of the cosmetic. 0% by mass
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004002274A (en) * | 2002-03-29 | 2004-01-08 | Shiyouritsu Plast Kogyo Kk | Cosmetic |
| JP2010285609A (en) * | 2009-05-11 | 2010-12-24 | Kose Corp | Shape-anisotropic tabular particle, method for producing the same, and cosmetic obtained by formulating shape-anisotropic tabular particle |
| JP2011513463A (en) * | 2008-03-10 | 2011-04-28 | シャネル パフュームズ ビューテ | Water-in-oil emulsified cosmetic composition |
| JP2011524406A (en) * | 2008-06-17 | 2011-09-01 | シャネル パフュームズ ビューテ | Compact powder for skin care or skin makeup |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004002274A (en) * | 2002-03-29 | 2004-01-08 | Shiyouritsu Plast Kogyo Kk | Cosmetic |
| JP2011513463A (en) * | 2008-03-10 | 2011-04-28 | シャネル パフュームズ ビューテ | Water-in-oil emulsified cosmetic composition |
| JP2011524406A (en) * | 2008-06-17 | 2011-09-01 | シャネル パフュームズ ビューテ | Compact powder for skin care or skin makeup |
| JP2010285609A (en) * | 2009-05-11 | 2010-12-24 | Kose Corp | Shape-anisotropic tabular particle, method for producing the same, and cosmetic obtained by formulating shape-anisotropic tabular particle |
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