JP2017104126A - Method for manufacturing food with reduced adhesiveness by ultrasound - Google Patents

Method for manufacturing food with reduced adhesiveness by ultrasound Download PDF

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JP2017104126A
JP2017104126A JP2017028606A JP2017028606A JP2017104126A JP 2017104126 A JP2017104126 A JP 2017104126A JP 2017028606 A JP2017028606 A JP 2017028606A JP 2017028606 A JP2017028606 A JP 2017028606A JP 2017104126 A JP2017104126 A JP 2017104126A
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food
ultrasonic
enzyme
softened
reduced
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JP6509264B2 (en
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基樹 住田
motoki Sumida
基樹 住田
洋紀 金指
Hiroki Kanezashi
洋紀 金指
啓司 庵原
Keiji Iohara
啓司 庵原
小泉 大輔
Daisuke Koizumi
大輔 小泉
裕介 柿崎
Yusuke Kakizaki
裕介 柿崎
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Maruha Nichiro Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a method for manufacturing softened food by ultrasound.SOLUTION: The present invention provides a method for manufacturing softened food for the elderly and those who have difficulty in chewing and swallowing, wherein the method includes irradiating a food ingredient with ultrasound to increase the effect by which a liquid containing a component for softening the food ingredient is introduced into the food ingredient, and change the hardness of the food ingredient.SELECTED DRAWING: None

Description

本発明は、軟化食品の製造方法に関する。さらに詳しくは、超音波を用いた、摂食者の咀嚼・嚥下機能又は消化機能に応じた適切なかたさを有する軟化食品の製造方法に関する。   The present invention relates to a method for producing a softened food. More specifically, the present invention relates to a method for producing a softened food having an appropriate hardness according to the chewing / swallowing function or digestive function of an eater using ultrasonic waves.

食品原料を軟化するために、食品原料を凍結、解凍後、減圧下で酵素液に浸漬し、原型を留めた状態で、食品原料の組織へ酵素を導入する方法(特許文献1)、テンダライズ処理を実施する方法(特許文献2)等が開発されているが、減圧含浸や酵素反応時間の短縮化、製造工程の簡略化の要請が高い。また、植物食品原料又は食肉に関する軟化食品の製造には、主にタンパク質分解酵素(プロテアーゼ)やペクチナーゼ等の分解酵素が使用されている(特許文献3及び4)。しかし、酵素量が少ないと柔らかくならないため、多量の酵素を必要とする。また、含浸処理を長時間すると食品原料の組織が破損する等、保水性が低下する等の問題がある。   In order to soften the food material, the food material is frozen, thawed, immersed in an enzyme solution under reduced pressure, and the enzyme is introduced into the tissue of the food material in a state where the original shape is retained (Patent Document 1), tenderizing treatment However, there are high demands for reduced pressure impregnation, shortening of enzyme reaction time, and simplification of the manufacturing process. Also, in the production of softened foods related to plant food raw materials or meat, proteolytic enzymes (proteases) and degrading enzymes such as pectinases are mainly used (Patent Documents 3 and 4). However, if the amount of enzyme is small, it does not become soft, so a large amount of enzyme is required. In addition, when the impregnation treatment is performed for a long time, there is a problem that the water retention is lowered, for example, the structure of the food material is damaged.

特開2003-284522号公報JP2003-284522A 特開2013-247928号公報JP 2013-247928 特開2011-092216号公報JP 2011-092216 特表2007-525144号公報Special Table 2007-525144

本発明は、超音波を用いて軟化食品を製造する方法の提供を目的とする。   An object of the present invention is to provide a method for producing a softened food using ultrasonic waves.

本発明者らは、効率的かつ有効性の大きい、軟化食品製造方法について鋭意検討を行った。その結果、食品原料に対して超音波を照射することにより、簡便に食品原料本来の形状を保持しつつ軟化させることができること、及び従来技術に比べて軟化食品の保水性が高くなることを見出した。   The present inventors have intensively studied a method for producing a softened food that is efficient and highly effective. As a result, it was found that by irradiating the food material with ultrasonic waves, it can be easily softened while maintaining the original shape of the food material, and the water retention of the softened food is higher than that of the prior art. It was.

従来技術として、例えば、食品原料の軟化を凍結、解凍後、テンダライズし、減圧下で酵素溶液を含浸させる方法等が知られている。本発明者らは、超音波を用いることにより効率的に食品原料を軟化し得ることを見出した。さらに、食品原料の軟化に酵素を用いる場合、食品原料を軟化処理するときに、超音波を用いることによって酵素溶液をより効率よく含浸させ、さらに酵素反応を高めることによって軟化が起こる反応時間を短縮し、保水性が高い軟化食品を製造し得ることを見出した。例えば、サケの切り身については比較的硬い身質で軟化しにくいとされるが、テンダライズ処理を行わずとも短時間の照射で魚肉を軟化させることが可能である。さらに、本発明者らは、単に軟化させるだけでなく、咀嚼・嚥下困難者用食品はユニバーサルデザインフード区分(日本介護食品協議会)、えん下困難者用食品許可基準(消費者庁)が定める基準に即した軟化度、凝集性、付着性を得られる超音波の最適照射条件を見出し、本発明を完成させた。   As a conventional technique, for example, a method of softening a food material by freezing, thawing and then tendering and impregnating with an enzyme solution under reduced pressure is known. The present inventors have found that food raw materials can be efficiently softened by using ultrasonic waves. Furthermore, when enzymes are used to soften food ingredients, when the food ingredients are softened, the ultrasonic solution is used to impregnate the enzyme solution more efficiently, and the reaction time for softening is shortened by enhancing the enzyme reaction. The present inventors have found that a softened food with high water retention can be produced. For example, salmon fillet is relatively hard and difficult to soften, but fish meat can be softened by short-time irradiation without performing a tenderization process. Furthermore, the present inventors not only soften, but foods for persons with difficulty in chewing / swallowing are determined by the Universal Design Food Category (Japan Care Food Council) and food permit standards for persons with difficulty swallowing (Consumer Agency) The present inventors have completed the present invention by finding optimum irradiation conditions of ultrasonic waves that can obtain softness, cohesiveness, and adhesion in accordance with standards.

すなわち、本発明は以下のとおりである。
[1] 咀嚼・嚥下困難者用及び高齢者向け軟化食品の製造方法であり、食品原料に超音波を照射することにより、食品原料を軟化させる成分を含む液体の食品原料への導入効果を高めて、食品原料のかたさを変化させることを含む、軟化食品の製造方法。
[2] 照射する超音波の周波数が20〜200kHzである、[1]の軟化食品の製造方法。
[3] 超音波の照射を、20〜200kHzの周波数を2種以上組み合わせて行う、[1]又は[2]の軟化食品の製造方法。
[4] 超音波の照射強度が、300〜3000Wである、[1]〜[3]のいずれかの軟化食品の製造方法。
[5] 超音波の出力密度が、0.5〜50 W/cm2である、[1]〜[4]のいずれかの軟化食品の製造方法。
[6] 超音波の照射を、0〜40℃で行う、[1]〜[5]のいずれかの軟化食品の製造方法。
[7] 超音波の照射時間が10〜30分間である、[1]〜[6]のいずれかの軟化食品の製造方法。
[8] 食品原料が、魚介類の肉、畜肉、卵、青果物、芋類、穀物及び海藻からなる群から選択される、[1]〜[7]のいずれかの軟化食品の製造方法。
[9] 食品原料を軟化させる成分が食品原料の主成分を分解する酵素又は増粘剤若しくはゲル化剤である、[1]〜[8]のいずれかの軟化食品の製造方法。
[10] 食品原料を軟化しつつ、食品原料の形が崩れるのを防止し、かつドリップを防止し得る、[1]〜[9]のいずれかの軟化食品の製造方法。
[11] 咀嚼・嚥下困難者用に適した性質を持つ軟化食品であり、直径20mmのプランジャーで圧縮速度10mm/secの速度で試料の厚みの70%まで押し込んだ際の荷重値が500000(N/m2)以下であり、及び/又は圧縮速度10mm/secで試料を2回、70%まで潰したときの荷重(N)を測定し、試料に付着して、引き離そうとする力(N)の面積(エネルギー)を算出した付着性が400(J/m3)以下となる軟化食品を製造する、[1]〜[10]のいずれかの軟化食品の製造方法。
That is, the present invention is as follows.
[1] A method for producing softened foods for those with difficulty in chewing and swallowing and for the elderly, and by irradiating food ingredients with ultrasonic waves, the effect of introducing liquid ingredients that soften food ingredients into food ingredients is enhanced. A method for producing a softened food, comprising changing the hardness of the food material.
[2] The method for producing a softened food according to [1], wherein the frequency of ultrasonic waves to be irradiated is 20 to 200 kHz.
[3] The method for producing a softened food according to [1] or [2], wherein the ultrasonic irradiation is performed by combining two or more frequencies of 20 to 200 kHz.
[4] The method for producing a softened food according to any one of [1] to [3], wherein the ultrasonic irradiation intensity is 300 to 3000 W.
[5] The method for producing a softened food according to any one of [1] to [4], wherein the ultrasonic power density is 0.5 to 50 W / cm 2 .
[6] The method for producing a softened food according to any one of [1] to [5], wherein the ultrasonic irradiation is performed at 0 to 40 ° C.
[7] The method for producing a softened food according to any one of [1] to [6], wherein the ultrasonic irradiation time is 10 to 30 minutes.
[8] The method for producing a softened food according to any one of [1] to [7], wherein the food material is selected from the group consisting of seafood meat, livestock meat, eggs, fruits and vegetables, potatoes, grains, and seaweed.
[9] The method for producing a softened food according to any one of [1] to [8], wherein the component that softens the food material is an enzyme, a thickener, or a gelling agent that decomposes the main component of the food material.
[10] The method for producing a softened food according to any one of [1] to [9], wherein the food raw material is softened, the shape of the food raw material is prevented from collapsing, and drip can be prevented.
[11] Softened food with properties suitable for those who have difficulty chewing and swallowing, with a load value of 500,000 when the plunger is pushed to 70% of the sample thickness at a compression speed of 10 mm / sec with a plunger with a diameter of 20 mm. N / m 2 ) and / or the load (N) when the sample is crushed to 70% twice at a compression rate of 10 mm / sec. The method for producing a softened food according to any one of [1] to [10], wherein the softened food having an adhesiveness of 400 (J / m 3 ) or less calculated from the area (energy) of (1) is produced.

超音波により、食品原料の軟化のために導入したい成分を含む溶液を効率的かつ簡便に含浸させることができる。また、食品原料の軟化のために導入する成分が酵素の場合、酵素反応を促進させることによる製造工程の時間短縮、簡略化が期待できる。さらに、食品原料に対してより損傷の少ない緩和された条件で歩留良く軟化食品を作ることができる。   Ultrasonic can efficiently and simply impregnate a solution containing a component to be introduced for softening food materials. In addition, when the component to be introduced for softening the food material is an enzyme, it can be expected to shorten the manufacturing process time and simplify the process by promoting the enzyme reaction. Furthermore, a softened food can be made with a good yield under relaxed conditions with less damage to the food material.

超音波を利用して製造した軟化食品は、適切なかたさを有するため、咀嚼・嚥下困難者用食品や、消化機能低下者用食品として使用することが可能である。また、超音波は効率良く酵素反応を進行させるだけでなく、物理的な変化をもたらすことから付着性が低下するなどの咀嚼、嚥下食困難者用食品として好ましい品質に改変できる。   Since the softened food produced using ultrasonic waves has an appropriate hardness, it can be used as a food for persons with difficulty in chewing / swallowing or a food for persons with reduced digestive function. In addition, the ultrasonic wave not only allows the enzyme reaction to proceed efficiently, but also can be modified to a quality suitable as a food for those having difficulty in chewing or swallowing such as a decrease in adhesion due to a physical change.

凝集性及び付着性の算出方法を示す図である。It is a figure which shows the calculation method of cohesiveness and adhesiveness. 超音波実験装置の模式図である。It is a schematic diagram of an ultrasonic experiment apparatus. 超音波を用いて製造した軟化食品の軟化度(かたさ)を示す図である。It is a figure which shows the softening degree (hardness) of the softened food manufactured using the ultrasonic wave. 超音波を用いて製造した軟化食品の凝集性(図4A)及び付着性(図4B)を示す図である。It is a figure which shows the cohesion (FIG. 4A) and adhesiveness (FIG. 4B) of the softened food manufactured using the ultrasonic wave. 超音波を用いて製造した軟化食品の浸漬歩留(図5A)及び加熱歩留(図5B)を示す図である。It is a figure which shows the immersion yield (FIG. 5A) and heating yield (FIG. 5B) of the softened food manufactured using the ultrasonic wave. 超音波の照射時間を変えて製造した軟化食品の軟化度(かたさ)を示す図である。It is a figure which shows the softening degree (hardness) of the softened food manufactured by changing the irradiation time of an ultrasonic wave. 超音波の照射時間を変えて製造した軟化食品の付着性(図6−2A)及び凝集性(図6−2B)を示す図である。It is a figure which shows the adhesiveness (FIG. 6-2A) and the cohesiveness (FIG. 6-2B) of the softened food manufactured by changing the irradiation time of an ultrasonic wave. 超音波の照射時間を変えて製造した軟化食品の浸漬歩留(図6−3A)及び加熱歩留(図6−3B)を示す図である。It is a figure which shows the immersion yield (FIG. 6-3A) and heating yield (FIG. 6-3B) of the softened food manufactured by changing the irradiation time of an ultrasonic wave. 超音波の周波数を変えて製造した軟化食品の軟化度(かたさ)を示す図である。It is a figure which shows the softening degree (hardness) of the softened food manufactured by changing the frequency of an ultrasonic wave. 超音波の周波数を変えて製造した軟化食品の付着性(図7−2A)及び凝集性(図7−2B)を示す図である。It is a figure which shows the adhesiveness (FIG. 7-2A) and cohesiveness (FIG. 7-2B) of the softened food manufactured by changing the frequency of an ultrasonic wave. 超音波の周波数を変えて製造した軟化食品の浸漬歩留(図7−3A)及び加熱歩留(図7−3B)を示す図である。It is a figure which shows the immersion yield (FIG. 7-3A) and heating yield (FIG. 7-3B) of the softened food manufactured by changing the frequency of an ultrasonic wave. 175kHzの超音波により製造した軟化食品の軟化度(かたさ)(図7−4A)及び付着性(図7−4B)を示す図である。It is a figure which shows the softening degree (hardness) (FIG. 7-4A) and adhesiveness (FIG. 7-4B) of the softened food manufactured by the ultrasonic wave of 175kHz. ホキを超音波処理した場合の物性値を示す図である。It is a figure which shows the physical-property value at the time of ultrasonically processing a hoki. サトイモを超音波処理した場合の浸漬歩留(図9−1A)及び加熱歩留(図9−1B)を示す図である。It is a figure which shows the immersion yield (FIG. 9-1A) and heating yield (FIG. 9-1B) at the time of ultrasonically treating a taro. サトイモを超音波処理した場合の軟化度(かたさ)(図9−2A)、付着性(図9−2B)及び凝集性(図9−2C)を示す図である。It is a figure which shows the softening degree (hardness) at the time of ultrasonically processing a taro (FIG. 9-2A), adhesiveness (FIGS. 9-2B), and cohesion (FIG. 9-2C).

以下、本発明を詳細に説明する。   Hereinafter, the present invention will be described in detail.

本発明は、食品原料に、超音波を照射することにより軟化食品を製造する方法である。本発明は、さらに、食品原料を軟化させるための成分を食品原料中に導入する際に、超音波を使用し、軟化食品を製造する方法である。また、本発明の方法は、軟化食品の加工方法でもある。   The present invention is a method for producing a softened food by irradiating a food material with ultrasonic waves. The present invention further relates to a method for producing a softened food using ultrasonic waves when a component for softening a food raw material is introduced into the food raw material. The method of the present invention is also a method for processing softened food.

1.食品原料
適応対象となる食品原料は、生鮮原料でも凍結解凍原料でもよい。本発明において食品原料を食品素材ともいう。対象は食品の原料となる食材であり、そのままではかたくて咀嚼・嚥下困難者、高齢者、乳幼児等に適さない食品であり、食用となるすべての食材である。好ましくは、魚肉等の魚介類の肉や畜肉などの食肉、卵、青果物、芋類、穀物、海藻等であり、さらに好ましくは魚介類の肉、特に好ましくは魚肉である。青果物とは、野菜類及び果物類をいう。魚介類の種、畜肉の種、品種、青果物の種には制限はない。具体的には、例えば、魚介類として、サケ、さば、ホキ等の魚類、アワビ、サザエ、ミルガイ、エビ、カニ、タコ、イカ、ナマコ、クラゲ等の貝類やその他の水産動物等が挙げられ、畜肉として、鶏肉、牛肉、豚肉、羊肉等が挙げられ、卵は、卵製品も含む。野菜類として、ブロッコリー、カリフラワー、ニンジン、ダイコン等が挙げられ、果物として、リンゴ、ナシ等が挙げられ、芋類として、サトイモ、ジャガイモ、サツマイモ等が挙げられ、穀類としてダイズ、ソラマメ等が挙げられ、海藻としてワカメ、コンブ等が挙げられる。また食品原料の形態についても特に制限はなく、切身やブロックなど、どの形態も選択することができる。
1. Food raw material The food raw material to be applied may be a fresh raw material or a frozen and thawed raw material. In the present invention, the food material is also referred to as a food material. The target is foodstuffs that are raw materials of food, and are foodstuffs that are difficult to chew / swallow, elderly people, infants and the like, and are all edible foodstuffs. Preferred are meats of seafood such as fish meat and meat such as livestock meat, eggs, fruits and vegetables, potatoes, grains, seaweeds, etc., more preferably meat of seafood, particularly preferably fish meat. Vegetables and fruits refer to vegetables and fruits. There are no restrictions on seafood species, livestock species, varieties, and fruit and vegetable species. Specifically, for example, fish and shellfish such as salmon, mackerel, hoki, abalone, turban shell, shrimp, crab, octopus, squid, sea cucumber, jellyfish and other marine animals, etc. Examples of livestock meat include chicken, beef, pork, and lamb, and eggs include egg products. Examples of vegetables include broccoli, cauliflower, carrot, and radish, examples of fruits include apples and pears, examples of potatoes include taro, potato, and sweet potato, and examples of cereals include soybeans and broad beans. Examples of seaweed include wakame and kombu. Moreover, there is no restriction | limiting in particular also about the form of a foodstuff raw material, Any forms, such as a fillet and a block, can be selected.

また、上記の食品原料を原料として、本発明の方法で軟化した食品原料を、軟化食品原料又は軟化食品という。具体的には、例えば、軟化魚肉、軟化食肉、軟化青果物等という。   Moreover, the food raw material softened by the method of the present invention using the food raw material as a raw material is referred to as a softened food raw material or a softened food. Specifically, for example, it is called softened fish meat, softened meat, softened fruit and vegetables.

2.超音波による軟化
従来は、食品原料を軟化させるために、食品原料に対してテンダライズ処理を行ったり、タンブリング処理又は減圧処理を行うことにより、酵素等の食品原料を軟化するための成分を食品原料中に含浸させていた(特開2011-92216号公報、特開2013-247928号公報等)。ここで、テンダライズ処理とは、針状の器具を刺し通し、原形を保ったまま食品原料の硬い筋や繊維を切断する等の物理的損傷を与える処理をいい、タンブリング処理とは、一般的に、回転させる等により食品原料に物理的処理を行い、調味液を食品原料組織内部に一様に浸透させる処理をいう。
2. Softening by ultrasonic waves Conventionally, ingredients for softening food ingredients such as enzymes are softened by applying a tendering treatment, tumbling treatment or decompression treatment to the food ingredients to soften the food ingredients. It was impregnated inside (JP 2011-92216, JP 2013-247928, etc.). Here, the tenderizing process refers to a process that punctures a needle-like instrument and causes physical damage such as cutting hard streaks and fibers of food ingredients while maintaining the original shape, and the tumbling process is generally This refers to a process in which a food raw material is physically treated by rotating, etc., and the seasoning liquid is uniformly permeated into the food raw material tissue.

本発明においては、超音波を用いることにより、食品原料を軟化させるための成分を食品原料中に導入することなく、食品原料のかたさを変化させて、軟化することができる。また、超音波と食品原料を軟化させるための成分を併用して、食品原料を軟化することもできる。すなわち、超音波を用いて食品原料を軟化させるための成分の食品原料への導入効果を高めて効率的に食品原料に導入する。食品原料を酵素、増粘剤、ゲル化剤等の食品原料を軟化する成分を含んだ調味液等の溶液に浸漬した状態で食品原料に超音波を照射すればよい。ここで、食品原料を溶液に浸漬するとは、食品原料を食品原料が完全に沈む程度の量の溶液中に入れることも、食品原料が浸る程度の量の溶液中に浸すことも含む。   In the present invention, by using ultrasonic waves, the hardness of the food material can be changed and softened without introducing a component for softening the food material into the food material. In addition, the ingredients for softening the ultrasonic material and the food material can be used in combination to soften the food material. That is, the effect of introducing the ingredients for softening the food raw material using ultrasonic waves into the food raw material is enhanced and efficiently introduced into the food raw material. What is necessary is just to irradiate a food raw material with an ultrasonic wave in the state immersed in solutions, such as a seasoning liquid containing the component which softens food raw materials, such as an enzyme, a thickener, and a gelatinizer. Here, immersing the food raw material in the solution includes putting the food raw material in a solution in such an amount that the food raw material is completely submerged, or immersing the food raw material in a solution in such an amount that the food raw material is immersed.

超音波は、超音波発生装置を用いて発生させる。例えば、超音波発生装置は、超音波発振器と超音波振動子を含み、超音波発振器で特定周波数を作り出し、超音波振動子の振動により超音波が発生する。例えば、超音波振動子を備えた容器中に食品原料を入れ、超音波を発生させることにより食品原料に超音波を照射する。超音波振動子は、例えば、容器の底面や側面に備えてあればよく、複数の超音波振動子が備えてあってもよい。容器に食品原料を入れたときに、超音波振動子と食品原料の距離が数cm〜数十cm、好ましくは5〜20cmになるようにして超音波を発生する。好ましくは、容器に液体を入れ、液体中で食品原料に超音波を照射する。液体としては、種々の調味料を含む調味液を用いればよく、また、食品原料を軟化するための成分を含んでいてもよい。   The ultrasonic waves are generated using an ultrasonic generator. For example, an ultrasonic generator includes an ultrasonic oscillator and an ultrasonic vibrator, generates a specific frequency with the ultrasonic oscillator, and generates ultrasonic waves by vibration of the ultrasonic vibrator. For example, a food material is put in a container equipped with an ultrasonic vibrator, and the food material is irradiated with ultrasonic waves by generating ultrasonic waves. For example, the ultrasonic transducer may be provided on the bottom surface or the side surface of the container, and a plurality of ultrasonic transducers may be provided. When the food material is put in the container, the ultrasonic wave is generated so that the distance between the ultrasonic vibrator and the food material is several cm to several tens cm, preferably 5 to 20 cm. Preferably, the container is filled with a liquid, and the food material is irradiated with ultrasonic waves in the liquid. As the liquid, a seasoning liquid containing various seasonings may be used, and a component for softening the food material may be included.

さらに、超音波振動子を備えた容器を用いずに、食品材料を容器に入れ、容器中に超音波振動子を入れて超音波を照射してもよい。   Further, the food material may be put in the container without using the container provided with the ultrasonic vibrator, and the ultrasonic vibrator may be put in the container and irradiated with the ultrasonic wave.

超音波処理は、キャビテーションの発生を伴うように行うことが好ましく、このために超音波の照射方向、発振周波数、照射強度、照射時間、及び照射雰囲気温度を制御し、液体を介して超音波の照射を行うことが好ましい。ここで、キャビテーションとは、超音波により液体中に真空の気泡が発生することをいうが、本発明においては食品材料中の液体中でキャビテーションを発生させる。気泡が破裂することにより衝撃波を発生し、この衝撃波により食品原料の軟化が促進され、さらに、軟化させる成分の食品原料中への導入が促進される。このキャビテーションの物理的効果により付着性が低下し、より咀嚼・嚥下困難者用食品に適した食品に改変することができる。   The ultrasonic treatment is preferably performed so as to cause cavitation. For this purpose, the ultrasonic irradiation direction, oscillation frequency, irradiation intensity, irradiation time, and irradiation atmosphere temperature are controlled, and the ultrasonic wave is transmitted through the liquid. Irradiation is preferably performed. Here, cavitation refers to the generation of vacuum bubbles in the liquid by ultrasonic waves. In the present invention, cavitation is generated in the liquid in the food material. When the bubbles burst, a shock wave is generated. The shock wave promotes softening of the food material, and further promotes introduction of the softening component into the food material. The physical effect of this cavitation reduces the adhesiveness and can be modified to a food that is more suitable for food for persons with difficulty in chewing / swallowing.

食品原料に照射する超音波の周波数は、20kHz〜200kHz、好ましくは25kHz〜170kHzの範囲であることが好ましく、より好ましくは25kHzの低周波数である。この周波数は例示であり、超音波の出力(W)が高い場合にはより高周波でもよい。   The frequency of the ultrasonic wave applied to the food material is preferably in the range of 20 kHz to 200 kHz, preferably 25 kHz to 170 kHz, more preferably a low frequency of 25 kHz. This frequency is an example, and may be higher when the output (W) of the ultrasonic wave is high.

また、食品原料に照射する超音波の周波数は一定である必要はなく、20〜200kHzの周波数を2種以上組み合わせて、照射してもよい。ここで、周波数を2種以上組合せるとは、複数の周波数を一定時間間隔で発振させることにより、複数の周波数の超音波を発生させ照射することをいう。例えば、25kHzと100kHzの周波数の超音波を組合せればよく、10秒間ずつの照射を繰り返せばよい。   Moreover, the frequency of the ultrasonic wave irradiated to the food material does not need to be constant, and may be irradiated by combining two or more frequencies of 20 to 200 kHz. Here, combining two or more types of frequencies refers to generating and irradiating ultrasonic waves of a plurality of frequencies by oscillating a plurality of frequencies at a constant time interval. For example, ultrasonic waves having a frequency of 25 kHz and 100 kHz may be combined, and irradiation for 10 seconds may be repeated.

食品原料に照射する超音波の照射強度は、300〜3000Wの出力の照射強度が好ましい。また、出力を振動子面積で除した値である超音波出力密度は、0.5〜50W/cm2が好ましく、より好ましくは0.5〜10W/cm2である。 The irradiation intensity of the ultrasonic wave applied to the food material is preferably an irradiation intensity of 300 to 3000 W. The ultrasonic power density, which is a value obtained by dividing the output by the transducer area, is preferably 0.5 to 50 W / cm 2 , more preferably 0.5 to 10 W / cm 2 .

実際に食品原料に照射する超音波の強度は、例えば、音圧計を用いて測定することができる。   The intensity of the ultrasonic wave actually applied to the food material can be measured using, for example, a sound pressure meter.

食品原料に超音波を照射するときの温度(照射雰囲気温度)は限定されないが、温度が低すぎると食品原料が凍結してしまい、温度が高すぎると食品原料が加熱されることで品位が低下してしまうことから、0〜40℃程度の範囲内で実施されることが好ましく、より好ましくは5〜20℃の範囲である。   The temperature (irradiation atmosphere temperature) when the food material is irradiated with ultrasonic waves is not limited, but if the temperature is too low, the food material will freeze, and if the temperature is too high, the food material will be heated and the quality will be lowered. Therefore, it is preferably performed within a range of about 0 to 40 ° C, and more preferably within a range of 5 to 20 ° C.

また、食品原料に超音波を照射する時間は限定されず、超音波を処理する食品原料の種類や量により適宜調節することができるが、1〜60分間、好ましくは10〜30分間である。超音波の照射は連続的でもよいし、断続的でもよい。   Moreover, the time for irradiating the food material with ultrasonic waves is not limited and can be appropriately adjusted depending on the type and amount of the food material to be processed with ultrasonic waves, but it is 1 to 60 minutes, preferably 10 to 30 minutes. The ultrasonic irradiation may be continuous or intermittent.

3.食品原料を軟化させる成分
本発明の方法においては、食品原料に超音波を照射するだけで、食品原料の軟化を達成することができるが、食品原料を軟化させるための成分を用いてもよく、食品原料を軟化する成分を食品原料中に含浸させるときに超音波を照射すればよい。
3. Ingredients that soften food ingredients In the method of the present invention, it is possible to achieve softening of food ingredients simply by irradiating food ingredients with ultrasonic waves, but ingredients for softening food ingredients may be used, What is necessary is just to irradiate an ultrasonic wave when impregnating the ingredient which softens a food raw material in a food raw material.

食品原料を軟化させるための成分としては、酵素や増粘剤、ゲル化剤等が挙げられる。 酵素としては、食品原料の構成成分を分解する酵素が挙げられる。例えば、食品原料が畜肉、魚肉等タンパク質を主成分とする場合、タンパク質分解酵素(プロテアーゼ)が挙げられる。タンパク質分解酵素として、例えばバシラス(Bacillus)属(例えばバシラス・サブチリス(Bacillus subtilis)、バシラス・サーモプロテオリティカス(Bacillus thermoproteolyticus)、バシラス・リシェニフォルミス(Bacillus licheniformis)等)の産生するタンパク質分解酵素、アスペルギルス(Aspergillus)属(例えばアスペルギルス・オリーゼ(Aspergillus oryzae)、アスペルギルス・ニガー(Aspergillus niger)、アスペルギルス・メレンス(Aspergillus mellens)等)の産生する酵素、リゾパス(Rhizopus)属(例えばリゾパス・ニベウス(Rhizopus niveus)、リゾパス・デレマー(Rhizopus delemar)等)の産生するタンパク質分解酵素、ペプシン、パンクレアチン、パパイン、ブロメライン等が挙げられる。これらのタンパク質分解酵素は単独、又は2種以上を組み合わせてもよい。タンパク質分解酵素は、酵素溶液として溶媒に希釈して用い、対象食品原料の種類によっても異なるが、酵素溶液中のタンパク質分解酵素濃度として0.001〜10質量%となるように添加し、よく懸濁して用いる。これらのタンパク質分解酵素は市販の酵素製剤を用いることができる。酵素製剤としては、例えば、ブロメラインF(天野エンザイム)、プロテックス6L(ジェネンコア)、オリエンターゼ 22BF(エイチビィアイ)、プロチンSD-AY-10(天野エンザイム)、ビオプラーゼSP-15FG(ナガセケムテックス)、アルカラーゼ 2.4LFG(ノボザイムズ)、スミチーム MP(新日本化学工業)、アロアーゼ XA-10(ヤクルト薬品工業)等を用いることができる。酵素溶液を調製する際の溶媒は、特に限定されず、酵素が変性や失活せず、食品衛生上問題ないものであればよい。   Examples of components for softening food materials include enzymes, thickeners, and gelling agents. Examples of the enzyme include an enzyme that decomposes a constituent of a food raw material. For example, when the food material is mainly composed of protein such as livestock meat and fish meat, a proteolytic enzyme (protease) can be mentioned. Proteolytic enzymes produced by, for example, the genus Bacillus (for example, Bacillus subtilis, Bacillus thermoproteolyticus, Bacillus licheniformis, etc.) Enzymes produced by the genus Aspergillus (for example, Aspergillus oryzae, Aspergillus niger, Aspergillus mellens, etc.), the genus Rhizopus (for example, Rhizopus pus niveus), Rhizopus delemar, etc.), and pepsin, pancreatin, papain, bromelain and the like. These proteolytic enzymes may be used alone or in combination of two or more. Proteolytic enzyme is used as an enzyme solution diluted in a solvent, and depending on the type of target food material, it is added so that the proteolytic enzyme concentration in the enzyme solution is 0.001 to 10% by mass and well suspended. Use. Commercially available enzyme preparations can be used for these proteolytic enzymes. Examples of enzyme preparations include Bromelain F (Amano Enzyme), Protex 6L (Genencore), Orientase 22BF (Hichiai), Protin SD-AY-10 (Amano Enzyme), Biopase SP-15FG (Nagase ChemteX), Alcalase 2.4 LFG (Novozymes), Sumiteam MP (Shin Nihon Chemical Industry), Aroase XA-10 (Yakult Pharmaceutical Co., Ltd.), etc. can be used. The solvent for preparing the enzyme solution is not particularly limited as long as the enzyme is not denatured or deactivated and does not cause any problem in food hygiene.

また、食品原料が野菜、果物等ペクチンやセルロースを主成分とする場合、セルラーゼ、ペクチナーゼ及びヘミセルラーゼが挙げられ、これら3種類のうち少なくとも1種を含む酵素が用いられる。具体的には、例えばトリコデルマ・ビリデ(Trichoderma viride)、アスペルギルス・ニガー(Aspergillus niger)、リゾパス(Rhizopus)属(リゾパス・ニベウス(Rhizopus niveus)、リゾパス・デレマー(Rhizopus delemar)等)、バシラス・サブチリス(Bacillus subtilis)、ビブリオ・アルギノリチカス(Vibrio alginolyticus)等の産生する酵素が挙げられる。本発明において、セルラーゼ活性を有する酵素をセルラーゼ系酵素、ぺクチナーゼ活性を有する酵素をぺクチナーゼ系酵素、ヘミセルラーゼ活性を有する酵素をヘミセルラーゼ系酵素という。すなわち、本発明の方法においては、セルラーゼ系酵素、ペクチナーゼ系酵素及びヘミセルラーゼ系酵素の3種類のうち少なくとも1種を含む酵素を使用する。これらの酵素は、酵素溶液として溶媒に希釈して用い、対象の種類によっても異なるが、酵素溶液中の酵素濃度として0.001〜10重量%となるように添加し、よく懸濁して用いる。これらの分解酵素は市販の酵素製剤を用いることができる。酵素製剤としては、例えば、ヘミセルラーゼ「アマノ」90((主)ヘミセルラーゼ、(副)セルラーゼ・ペクチナーゼ)(天野エンザイム社);ビスコザイムL((主)ヘミセルラーゼ、(副)ペクチナーゼ)(ノボザイム社);PECLYVELI(樋口商会)((主)ペクチナーゼ・ヘミセルラーゼ、(副)セルラーゼ);Rapidase ADEX-G(DSMジャパン)((主)ペクチナーゼ・ヘミセルラーゼ);Rapidase Pineapple(DSMジャパン)((主)ペクチナーゼ・ヘミセルラーゼ);Rapidase FC(DSMジャパン)((主)ペクチナーゼ・セルラーゼ);Rapidase TF(DSMジャパン)((主)ペクチナーゼ・ヘミセルラーゼ);セルラーゼXL-531(長瀬産業)((主)セルラーゼ);スミチームSPC(新日本化学社)((主)ペクチナーゼ、(副)セルラーゼ・ヘミセルラーゼ)等を用いることができる。酵素溶液を調製する際の溶媒は、特に限定されず、酵素が変性や失活せず、食品衛生上問題ないものであればよい。   In addition, when the food material is composed mainly of pectin or cellulose such as vegetables and fruits, cellulase, pectinase and hemicellulase can be mentioned, and an enzyme containing at least one of these three types is used. Specifically, for example, Trichoderma viride, Aspergillus niger, Rhizopus genus (Rhizopus niveus, Rhizopus delemar, etc.), Bacillus subtilis ( Examples include enzymes produced by Bacillus subtilis, Vibrio alginolyticus, and the like. In the present invention, an enzyme having cellulase activity is referred to as a cellulase enzyme, an enzyme having pectinase activity is referred to as a pectinase enzyme, and an enzyme having hemicellulase activity is referred to as a hemicellulase enzyme. That is, in the method of the present invention, an enzyme containing at least one of cellulase enzyme, pectinase enzyme and hemicellulase enzyme is used. These enzymes are used by diluting them in a solvent as an enzyme solution, and depending on the type of the target, they are added so that the enzyme concentration in the enzyme solution is 0.001 to 10% by weight, and they are used after being well suspended. Commercially available enzyme preparations can be used for these degrading enzymes. Examples of enzyme preparations include hemicellulase “Amano” 90 ((main) hemicellulase, (sub) cellulase / pectinase) (Amano Enzyme); Viscozyme L ((main) hemicellulase, (sub) pectinase) (Novozyme) ); PECLYVELI (Higuchi Shokai) ((main) pectinase hemicellulase, (secondary) cellulase); Rapidase ADEX-G (DSM Japan) ((main) pectinase hemicellulase); Rapidase Pineapple (DSM Japan) ((main) Rapidase FC (DSM Japan) ((Main) Pectinase cellulase); Rapidase TF (DSM Japan) ((Main) Pectinase hemicellulase); Cellulase XL-531 (Nagase Sangyo) (Main) Cellulase ); Use Sumiteam SPC (Shin Nippon Chemical Co., Ltd.) ((main) pectinase, (sub) cellulase / hemicellulase), etc. Can be. The solvent for preparing the enzyme solution is not particularly limited as long as the enzyme is not denatured or deactivated and does not cause any problem in food hygiene.

増粘剤やゲル化剤としては、デンプン、カードラン、こんにゃく粉、ゼラチン、寒天、ガム類、卵白等が挙げられ、これらの1種又は複数種を混合したものを用いることができる。好適には、デンプン、カードラン及び卵白を混合したものを用いることができる。   Examples of thickeners and gelling agents include starch, curdlan, konjac flour, gelatin, agar, gums, egg white, and the like, and a mixture of one or more of these can be used. Preferably, a mixture of starch, curdlan and egg white can be used.

デンプンの由来植物は限定されず、トウモロコシデンプン、小麦デンプン、馬鈴薯デンプン等いずれの由来のデンプンも用いることができる。デンプンは市販のものを用いればよい。デンプンには、デンプン誘導体も含まれる。デンプン誘導体として、デンプンに種々の官能基を導入したものがあり、例えば、カルボキシメチルデンプン、ヒドロキシアルキルデンプン、酢酸デンプン、リン酸デンプン等がある。また、架橋デンプンも含まれる。カードランは微生物により生産される発酵多糖類をいい、(C6H10O5)nで表されるD-グルコースがC1位とC3位でβ-グルコシド結合した非イオン性の直鎖状の多糖類(β-1,3グルカン)である。デンプン製剤として、例えば「松谷マーガレット(松谷化学工業化素株式会社)」等が挙げられる。カードランは公知の方法で製造することができる。また、β-1,3グルカンを90重量%程度含む市販のカードラン製剤を用いてもよい。市販のカードラン製剤としては、キリン協和フーズ「カードランスNS」等がある。卵白は鳥類の卵の卵黄膜と卵殻膜の間のゾル上の物質をいい、好ましくはニワトリの卵白である。卵白は市販の乾燥品を用いることもできる。 The starch-derived plant is not limited, and any starch derived from corn starch, wheat starch, potato starch or the like can be used. A commercially available starch may be used. Starch also includes starch derivatives. Examples of starch derivatives include those in which various functional groups are introduced into starch, such as carboxymethyl starch, hydroxyalkyl starch, starch acetate, and phosphate starch. Cross-linked starch is also included. Curdlan is a fermented polysaccharide produced by microorganisms. It is a non-ionic linear chain in which D-glucose represented by (C 6 H 10 O 5 ) n is β-glucoside bonded at the C1 and C3 positions. It is a polysaccharide (β-1,3 glucan). Examples of the starch preparation include “Matsutani Margaret (Matsutani Chemical Industrial Co., Ltd.)” and the like. The curdlan can be manufactured by a known method. A commercially available curdlan preparation containing about 90% by weight of β-1,3 glucan may also be used. Examples of commercially available curdlan preparations include Kirin Kyowa Foods “Cardlance NS”. Egg white refers to a substance on the sol between the yolk membrane and eggshell membrane of avian eggs, preferably chicken egg white. A commercially available dried product can also be used for the egg white.

また、上記の増粘剤やゲル化剤には、ヒドロキシプロピルセルロースやカルボキシメチルセルロース等のセルロース系添加物、トレハロース等の糖、ソルビトール、マルチトール、マンニトール、エリスリトール等の糖アルコールが含まれていてもよい。   Further, the above thickener and gelling agent may contain cellulose additives such as hydroxypropylcellulose and carboxymethylcellulose, sugars such as trehalose, and sugar alcohols such as sorbitol, maltitol, mannitol and erythritol. Good.

増粘剤やゲル化剤は、pH調整のため緩衝剤中に溶解又は懸濁させて用いる。緩衝液はpH7.5〜8.5に調整して用いることが好ましい。緩衝液の種類は限定されないが、例えば、クエン酸とリン酸3ナトリウムを添加すればよい。   A thickener or a gelling agent is used by dissolving or suspending in a buffer for pH adjustment. It is preferable to adjust the buffer to pH 7.5 to 8.5. The type of the buffer solution is not limited. For example, citric acid and trisodium phosphate may be added.

増粘剤やゲル化剤を用いて食品原料を軟化するときは酵素を用いる必要はなく、増粘剤やゲル化剤のみにより十分な軟化を達成することができるが、酵素を併用してもよい。   When using a thickener or gelling agent to soften food ingredients, it is not necessary to use an enzyme and sufficient thickening or gelling agent can be used to achieve sufficient softening. Good.

食品原料を軟化させる成分は、調味液中に混合して用いればよい。
食品原料を軟化するための成分を含む液体中に食品原料を浸漬し、食品原料に超音波を照射することにより、食品原料中に食品原料を軟化するための成分が効率的に含浸し、軟化を促進することができる。また、食品原料を軟化するための成分として酵素を用いた場合、超音波を照射することにより酵素と食品原料の基質との接触機会が増加し、より効率的に酵素を作用させることができ、結果的に酵素反応を促進し、軟化を促進することができる。
The ingredients that soften the food material may be mixed in the seasoning liquid.
By immersing the food raw material in a liquid containing ingredients for softening the food raw material and irradiating the food raw material with ultrasonic waves, the food raw material is efficiently impregnated and softened with the component for softening the food raw material. Can be promoted. In addition, when an enzyme is used as a component for softening food ingredients, the chance of contact between the enzyme and the substrate of the food ingredients is increased by irradiating ultrasonic waves, and the enzyme can act more efficiently. As a result, the enzyme reaction can be promoted and softening can be promoted.

また、超音波を用いて食品原料を軟化する成分を食品原料に含浸させる前に、食品原料に対してテンダライズ処理を行ってもよい。テンダライズ処理は魚肉に物理的損傷を与えるほか、後の食品原料を軟化するための成分をテンダライズ処理による損傷箇所から原料内部へ効率良く導入する目的で行う。テンダライズ処理には、先の尖った細い針状の器具を用いる。例えば、ようじ、ドライバー、錐、千枚通し等を用いることができる。また、一度に複数の穴を開けるために、食器として用いられる家庭用フォークや生け花用の剣山、及びテンダライザー等も用い得る。さらに、カッター、ドリル、ミシン等を含む自動穴あけ機、ナイフなどの刃物類、レーザー、超音波、風圧及び水圧等を利用した傷つけ処理も含む。テンダライズに用いる器具をテンダライザーと呼ぶ。なおテンダライズ処理における穿孔密度は、孔1個/7.5mm×7.5mm以上で行えばよい。「孔1個/7.5mm×7.5mm以上」とは、7.5mm×7.5mmの単位面積あたり1個以上の穿孔が形成されることを意味する。また、上記の細い針状の器具の食品原料に穿孔する部分の太さは、φ1.5〜5mm、好ましくはφ1.7〜3.5mm、さらに好ましくはφ2〜2.5mmである。また、テンダライズ処理する場合の孔の深さは、原料の片側から孔をあけ、原料の厚さの3/4に達する程度の孔が望ましく、また、片側に皮がついているような原料の場合、皮目に傷がつき、焼成後の見た目が悪くなるのを防ぐため、皮がついていない面から孔をあけるのが好ましい。   In addition, before the food raw material is impregnated with a component that softens the food raw material using ultrasonic waves, the food raw material may be subjected to a tenderization process. The tenderization treatment is performed for the purpose of efficiently introducing components for softening the raw material of food later from the damaged portion by the tenderization treatment into the raw material in addition to physical damage to the fish meat. A thin needle-like instrument with a sharp point is used for the tenderization process. For example, it is possible to use a toothpick, a driver, a cone, a threader, etc. Further, in order to open a plurality of holes at a time, a household fork used as tableware, a sword mountain for ikebana, a tenderizer, or the like can also be used. Further, it includes an automatic drilling machine including cutters, drills, sewing machines, etc., blades such as knives, scratching processing using laser, ultrasonic waves, wind pressure, water pressure, and the like. An instrument used for tenderization is called a tenderizer. The perforation density in the tenderization process may be 1 hole / 7.5 mm × 7.5 mm or more. “One hole / 7.5 mm × 7.5 mm or more” means that one or more perforations are formed per unit area of 7.5 mm × 7.5 mm. In addition, the thickness of the portion of the thin needle-like utensil that is perforated in the food material is φ1.5 to 5 mm, preferably φ1.7 to 3.5 mm, and more preferably φ2 to 2.5 mm. In addition, the depth of the hole for the tenderization process is preferably a hole that is drilled from one side of the raw material to reach 3/4 of the thickness of the raw material, and the raw material has a skin on one side In order to prevent the skin from being scratched and the appearance after firing from getting worse, it is preferable to make a hole from the surface without the skin.

本発明において、テンダライズ処理は孔あけ処理、あるいは孔あけ処理を含む物理的加工ということもできる。   In the present invention, the tenderizing process can also be referred to as a boring process or physical processing including a boring process.

超音波を用いることにより、上記の食品原料を軟化させるための成分だけでなく、調味液中の調味成分等の食品原料を導入したい成分も効率的に食品原料中に導入することができる。   By using the ultrasonic wave, not only the component for softening the above-mentioned food material, but also the component for which the food material such as the seasoning component in the seasoning liquid is to be introduced can be efficiently introduced into the food material.

4.超音波により製造した軟化食品の物性
食品原料に超音波を照射した場合、超音波の作用で食品原料が軟化する。さらに、酵素、増粘剤、ゲル化剤等の食品原料を軟化する成分を含む溶液に食品原料を浸し、食品原料に超音波を照射することにより、食品原料を軟化する成分が効率的に食品原料中に入り込み、その作用により食品原料が軟化する。また、酵素を用いた場合、食品原料中の酵素の基質となる物質と酵素の接触が促進され、酵素反応が効率的に進むことにより軟化が促進され、食品原料の軟化度が大きくなる。
4). Physical properties of softened foods produced by ultrasound When food raw materials are irradiated with ultrasonic waves, the food raw materials are softened by the action of ultrasonic waves. Furthermore, the ingredients that soften the food ingredients can be efficiently obtained by immersing the food ingredients in a solution containing ingredients that soften the ingredients such as enzymes, thickeners, and gelling agents, and irradiating the food ingredients with ultrasonic waves. Entering into the raw material, the action of the food material softens. In addition, when an enzyme is used, contact between the enzyme and a substance serving as a substrate for the enzyme in the food material is promoted, and the softening is promoted by the efficient enzymatic reaction, thereby increasing the degree of softening of the food material.

また、超音波を照射することにより製造した軟化食品は、軟化度が高まるだけではなく、付着性や凝集性が低下し、さらに食品原料の保水性も向上する。   Moreover, the softened food manufactured by irradiating with an ultrasonic wave not only increases the degree of softening, but also decreases adhesion and cohesion, and further improves the water retention of the food material.

軟化度
本発明の方法で製造した軟化食品の軟化度は、物性としてのかたさで表すことができる。かたさは、例えば、日本介護食品協議会のユニバーサルデザインフード(UDF)自主規格の方法あるいはそれに準ずる方法で測定することができる。日本介護食品協議会のユニバーサルデザインフード自主規格の方法は以下のとおりである。
Softening degree The softening degree of the softened food produced by the method of the present invention can be expressed by hardness as a physical property. Hardness can be measured, for example, by the method of the Universal Design Food (UDF) voluntary standard of the Japan Nursing Food Council or a method based thereon. The method of the universal design food voluntary standard of the Japan Nursing Food Council is as follows.

試料を直径40mmの容器に高さ15mmに充填し、直径20mmのプランジャーで圧縮速度10mm/sec、クリアランス5mmで測定する。測定は20±2℃で行う。ただし、測定容器に移すことで物性が変化するもの、測定容器に移せないもの、不定形なものなどは測定に支障のないことを確認して、クリアランスを試料の厚さ30%として直接測定してもよい。プランジャーの材質には規定はなく、測定機器としては、直線運動により物質の圧縮応力を測定することが可能な装置を用いる。   A sample is filled into a container with a diameter of 40 mm to a height of 15 mm, and measured with a plunger with a diameter of 20 mm at a compression speed of 10 mm / sec and a clearance of 5 mm. The measurement is performed at 20 ± 2 ° C. However, confirm that there are no obstacles to the measurement of those whose physical properties change when transferred to a measurement container, those that cannot be transferred to a measurement container, or those that are irregularly shaped, and measure the clearance directly at a sample thickness of 30%. May be. The material of the plunger is not specified, and as the measuring instrument, a device capable of measuring the compressive stress of the substance by linear motion is used.

例えば、直線運動により物質の圧縮応力を測定することが可能な装置としてテクスチャーアナライザー(例えば、TA Xt plus(英弘精機社製))を用い、本発明の方法で製造した軟化食品又は該軟化食品を加熱調理した食品に、φ20mm円柱型プランジャーを10mm/secの速度でサンプル厚みの70%まで押し込んだ際の荷重値を測定することにより行えばよい。ここで、加熱調理は例えば、畜肉、魚肉等の食品の中心温度が70℃となる条件でスチーム加熱することにより行う。荷重値は、N/m2で表すことができ、本発明の軟化食品を加熱調理した場合、上記方法で測定したときのかたさが、500,000 N/m2以下、好ましくは100,000 N/m2以下、さらに好ましくは、50,000 N/m2以下、さらに好ましくは30,000 N/m2以下、さらに好ましくは28,000 N/m2以下、さらに好ましくは26,000 N/m2以下、さらに好ましくは24,000 N/m2以下、特に好ましくは22,000 N/m2以下である。 For example, using a texture analyzer (for example, TA Xt plus (manufactured by Eiko Seiki Co., Ltd.)) as a device capable of measuring the compressive stress of a substance by linear motion, the softened food produced by the method of the present invention or the softened food What is necessary is just to measure the load value when a φ20 mm cylindrical plunger is pushed into cooked food at a speed of 10 mm / sec to 70% of the sample thickness. Here, for example, the cooking is performed by steam heating under the condition that the center temperature of food such as livestock meat and fish meat is 70 ° C. The load value can be expressed as N / m 2 , and when the softened food of the present invention is cooked, the hardness when measured by the above method is 500,000 N / m 2 or less, preferably 100,000 N / m 2 or less. More preferably, 50,000 N / m 2 or less, more preferably 30,000 N / m 2 or less, more preferably 28,000 N / m 2 or less, more preferably 26,000 N / m 2 or less, more preferably 24,000 N / m 2 Hereinafter, it is particularly preferably 22,000 N / m 2 or less.

日本介護食品協議会では、介護食を咀嚼の容易さにより、4つの区分に分けている。すなわち、「容易にかめる」ものを区分1とし、「歯ぐきでつぶせる」ものを区分2とし、「舌でつぶせるもの」を区分3とし、「かまなくてもよい」ものを区分4としている。区分1から区分4の上記方法で測定したときのかたさ上限値は、区分1が5×105N/m2、区分2が5×104N/m2、区分3が1×104N/m2(ゾルの場合)、区分4が3×103N/m2(ゾルの場合)である。本発明の方法により製造された軟化食品は、上記のそれぞれの区分に属するよう、超音波処理によりかたさ(荷重値)を調節できる。 The Japan Nursing Food Council has divided nursing food into four categories according to the ease of chewing. That is, “Easy to bite” is classified as Category 1, “Crushable with gums” is classified as Category 2, “Things that can be crushed with the tongue” are classified as Category 3, and “Can be bitten” are classified as Category 4. The upper limit of hardness when measured by the above method for Category 1 to Category 4 is 5 × 10 5 N / m 2 for Category 1, 5 × 10 4 N / m 2 for Category 2 , and 1 × 10 4 N for Category 3. / m 2 (for sol), Category 4 is 3 × 10 3 N / m 2 (for sol). The softened food produced by the method of the present invention can be adjusted in hardness (load value) by ultrasonic treatment so as to belong to each of the above categories.

また、「嚥下食ピラミッド」(坂井他、日摂食嚥下リハ会誌、10(3):239-248(2006);坂井他、日本病態栄養学会誌、10(3): 269-279(2007))の基準により、かたさを定めてもよい。嚥下食ピラミッドの基準では、日本介護食品協議会のユニバーサルデザインフード自主規格の測定方法において、圧縮速度以外はほぼ同等であり、試料を直径40mmに容器に高さ15mmまで充填し、φ20mm、高さ8mmのプランジャーで速度1mm/sec、クリアランス5mmで2回圧縮して測定する。この測定法で測定した場合のかたさは、40,000 N/m2以下、好ましくは15,000 N/m2以下、さらに好ましくは10,000 N/m2以下である。 In addition, "Swallowing food pyramid" (Sakai et al., Journal of the Japan Ingestion Swallowing Rehabilitation Society, 10 (3): 239-248 (2006); Sakai et al. Hardness may be determined according to the criteria of). The standard of the swallowing food pyramid is almost the same as the universal design food voluntary standard measurement method of the Japan Nursing Food Council, except for the compression speed, filling the sample to a diameter of 40 mm and a container height of 15 mm, φ20 mm, height Measure by compressing twice with an 8mm plunger at a speed of 1mm / sec and a clearance of 5mm. The hardness when measured by this measuring method is 40,000 N / m 2 or less, preferably 15,000 N / m 2 or less, more preferably 10,000 N / m 2 or less.

本発明の方法により超音波照射を行って得られた軟化食品のやわらかさは均一であり、例えば上記方法で軟化食品の複数点のかたさを測定した場合、測定値のばらつきは少なく、例えば、複数点の測定値の変動係数(標準偏差/平均×100)は、20%以下、好ましくは15%以下である。   The softness of the softened food obtained by performing ultrasonic irradiation according to the method of the present invention is uniform. The coefficient of variation (standard deviation / average × 100) of the measured values of the points is 20% or less, preferably 15% or less.

凝集性及び付着性
本発明の方法で製造した軟化食品は、適切な凝集性及び付着性を有している。ここで、「凝集性」とは舌で押しつぶされた食物が結着し合って飲み込みやすい食塊を形成する能力のことをいう。食塊を形成しにくいと、気管に入りこみ誤嚥となる可能性が高くなる。また、「付着性」とは食物が口腔内にベタつく度合いのことをいい、この付着性が高過ぎると口腔内や咽頭などに食物が貼り付き、後に唾液に溶け出して誤嚥する可能性が高くなる。そのため、適度な粘度があって食塊形成しやすく、ベタつかずに軟らかく変形しながら咽頭を滑らかに通過するものが咀嚼・嚥下障害を有する者に適した物性条件となる。本発明の軟化食品は、適切な凝集性と付着性を有しているため、咀嚼したときの咀嚼物がまとまりやすく、食塊を形成し易い。従って、本発明の軟化食品は、咀嚼後飲み込みやすく、咀嚼後の繊維カス等が口内残存物として残りにくいので、誤嚥性肺炎を引き起こしにくい。凝集性や付着性は、上記のユニバーサルデザインフード自主規格によるかたさ測定法を2回繰り返すことにより測定することができる。凝集性及び付着性の算出法は、厚生労働省通知食安発第0212001号「特別用途食品の表示許可等について」(平成21年2月12日)に示されており、具体的には、凝集性及び付着性は以下の方法で算出する。
Cohesiveness and adhesiveness The softened food produced by the method of the present invention has appropriate cohesiveness and adhesiveness. Here, “cohesiveness” refers to the ability of foods crushed by the tongue to bind and form a bolus that is easy to swallow. If it is difficult to form a bolus, the possibility of entering the trachea and aspiration increases. “Adhesiveness” refers to the degree to which food is sticky in the oral cavity. If this adhesiveness is too high, the food may stick to the oral cavity or pharynx, and then dissolve into saliva and aspiration may occur. Get higher. Therefore, a material having an appropriate viscosity and easily forming a bolus, and smoothly passing through the pharynx while being softly deformed without stickiness is a physical property condition suitable for a person having a mastication / swallowing disorder. Since the softened food of the present invention has appropriate cohesiveness and adhesiveness, the chewed product when chewed is easy to gather and easily forms a bolus. Therefore, the softened food of the present invention is easy to swallow after mastication, and the fiber residue after mastication hardly remains as a residue in the mouth, so that it is difficult to cause aspiration pneumonia. The cohesion and adhesion can be measured by repeating the hardness measurement method according to the above universal design hood voluntary standard twice. The calculation method of cohesiveness and adhesion is shown in the Ministry of Health, Labor and Welfare Notification No. 0212001 “Permission to Label Special Use Foods” (February 12, 2009). Properties and adhesion are calculated by the following methods.

凝集性、付着性はテクスチャアナライザークリープメータ(RE2-3305B:山電(株))を用いて測定する。図1に凝集性及び付着性の算出方法を示す。凝集性は所定の負荷を連続2回加え、1回目と2回目の負荷面積(エネルギー)の比を求めることで算出することができる。付着性は試料に付着して、引き離そうとする力(N)の面積(エネルギー)を算出すればよく、図1中A3の面積を求めることで算出することができる。   Aggregation and adhesion are measured using a texture analyzer creep meter (RE2-3305B: Yamaden Co., Ltd.). FIG. 1 shows a calculation method for cohesion and adhesion. The cohesiveness can be calculated by applying a predetermined load twice in succession and determining the ratio of the first and second load areas (energy). Adhesiveness should just calculate the area (energy) of the force (N) which adheres to a sample and tries to separate, and can calculate it by calculating | requiring the area of A3 in FIG.

本発明の軟化食品の凝集性は、0〜1.0、好ましくは0〜0.9である。また、付着性は1,000J/m3以下、好ましくは500J/m3以下、さらに好ましくは450J/m3以下、特に好ましくは400J/m3以下である。 The cohesiveness of the softened food of the present invention is 0 to 1.0, preferably 0 to 0.9. Further, adhesion is 1,000 J / m 3 or less, preferably 500 J / m 3 or less, more preferably 450 J / m 3 or less, particularly preferably 400 J / m 3 or less.

保水性
本発明においては、超音波処理を行った軟化食品への酵素等を含むか、あるいは含まない調味液の浸透度合いを浸漬歩留という。浸漬歩留は以下の式で表すことができる。浸漬歩留が高い程、超音波処理が良好に行われたと判断することができる。食品原料を本発明の方法で超音波処理した場合の浸漬歩留は、例えば、100%以上、好ましくは105%以上、さらに好ましくは110%以上である。
Water retention In the present invention, the permeation degree of the seasoning liquid that contains or does not contain the enzyme or the like to the softened food subjected to ultrasonic treatment is referred to as immersion yield. The immersion yield can be expressed by the following formula. It can be determined that the higher the immersion yield, the better the ultrasonic treatment. The immersion yield when the food material is sonicated by the method of the present invention is, for example, 100% or more, preferably 105% or more, and more preferably 110% or more.

浸漬歩留(%)=浸漬後重量/処理前重量×100 Immersion yield (%) = Weight after immersion / Weight before treatment x 100

また、超音波処理を行って得られた軟化食品は、加熱調理時の水分放出が抑制される。このため、上記のように浸漬させた調味液が食品原料全体に均一に留まっている。本発明においては、上記の処理を行った軟化食品を加熱調理したときに、食品から水分が放出される程度を加熱歩留といい、以下の式で表すことができる。加熱歩留が高い程、超音波処理を行った食品から水分が放出されないことを示し、食品原料を本発明の方法で処理し加熱調理した場合の加熱歩留は、処理を行わなかった場合の歩留より高く、例えば、80%以上、好ましくは91%以上、さらに好ましくは92%以上である。   In addition, the softened food obtained by performing the ultrasonic treatment has reduced moisture release during cooking. For this reason, the seasoning liquid soaked as described above remains uniformly throughout the food material. In the present invention, when the softened food subjected to the above treatment is cooked and cooked, the degree to which moisture is released from the food is called the heating yield, and can be expressed by the following equation. The higher the heating yield is, the less moisture is released from the ultrasonically treated food, and the heating yield when the food material is processed and cooked by the method of the present invention is the value when the treatment is not performed. It is higher than the yield, for example, 80% or more, preferably 91% or more, more preferably 92% or more.

加熱歩留(%)(95℃、10分加熱)=処理後重量/処理前重量×100 Heating yield (%) (95 ° C, heating for 10 minutes) = weight after treatment / weight before treatment x 100

さらに、超音波処理を行って得られた軟化食品はパネルを用いた官能試験を行うことにより評価試験を行うことができ、他の方法で軟化処理を行った食品原料と区別することができる。   Furthermore, the softened food obtained by performing ultrasonic treatment can be subjected to an evaluation test by performing a sensory test using a panel, and can be distinguished from food raw materials that have been softened by other methods.

官能評価は、例えば、本発明の方法で製造した軟化食品を加熱調理し、室温まで冷やした後に、加熱調理後のにおい(嫌なにおいかどうか)、脂の劣化具合(においや味の両面について総合的に判断)、食味(魚本来の味かどうか、苦味)、食感(やわらかさ、しっとり感)について、パネルによって評価することにより行えばよい。例えば、10名のパネルを用い、それぞれの評価項目について、1〜5のスコアを付けさせ、10名のスコアを平均すればよい。この際、本発明の方法によって製造していない食品を加熱調理したものを比較対象とし、該比較対象のスコアを3としてスコアを付けてもよい。このような官能評価により、本発明の方法で製造した魚肉は食感のスコアが4以上、好ましくは4.5以上であり、他のスコアも3以上である。   For sensory evaluation, for example, after the softened food produced by the method of the present invention is cooked and cooled to room temperature, the smell after cooking (whether it is unpleasant) or the deterioration of fat (both smell and taste) Comprehensive judgment), taste (whether it is the original taste of fish, bitterness), and texture (softness, moist feeling) may be evaluated by a panel. For example, a panel of 10 people is used, a score of 1 to 5 is assigned to each evaluation item, and the scores of 10 people may be averaged. Under the present circumstances, what cooked the foodstuff which is not manufactured with the method of this invention may be made into a comparison object, and the score of this comparison object may be set as 3, and a score may be attached. By such sensory evaluation, the fish meat produced by the method of the present invention has a texture score of 4 or more, preferably 4.5 or more, and other scores of 3 or more.

本発明の方法で、超音波処理を行って得られた軟化食品は、処理後、そのまま真空包装し、あるいは冷凍して保存又は流通させることができる。また、処理後スライスしてIQFとして保存又は流通させることもできる。さらに、処理後、加工しやすいようにチューブやリテーナーにて整形し冷凍し、保存又は流通させることもできる。   The softened food obtained by sonication by the method of the present invention can be vacuum-packed as it is after treatment, or frozen and stored or distributed. Further, it can be sliced after processing and stored or distributed as IQF. Furthermore, after processing, it can be shaped and frozen by a tube or a retainer so as to be easily processed, and stored or distributed.

本発明の方法で超音波処理を行った食品は、さらに、焼成処理、スチーム加熱等の加熱処理、缶詰処理等を行い、加工品とすることができる。例えば、魚肉に焼成処理、スチーム加熱等の加熱処理、缶詰処理等を行い、魚肉加工品とすることができる。すなわち、本発明は軟化魚肉等の軟化食品の加工品の製造方法を包含する。   The foods that have been subjected to ultrasonic treatment by the method of the present invention can be further processed by baking, heating such as steam heating, canning, and the like. For example, a processed fish meat product can be obtained by subjecting the fish meat to a baking process, a heating process such as steam heating, and a canning process. That is, the present invention includes a method for producing a processed product of softened food such as softened fish meat.

本発明の超音波を利用して製造した軟化食品は上記の物性を有しているため、咀嚼・嚥下困難者、高齢者や消化機能低下者に適した食品として用いることができる。   Since the softened food manufactured using the ultrasonic wave of the present invention has the above-described physical properties, it can be used as a food suitable for persons with difficulty in chewing / swallowing, the elderly and those with reduced digestive function.

本発明を以下の実施例によって具体的に説明するが、本発明はこれらの実施例によって限定されるものではない。   The present invention will be specifically described by the following examples, but the present invention is not limited to these examples.

実施例で用いた実験装置の説明
図2に実験装置の模式図を示す。実験装置は容器(超音波振動槽2)(日本テクノサービス株式会社製 ステンレス550mm×356mm×343mm)に超音波振動子3(385mm×430mm×145mm、投げ込み型多周波超音波発生装置、1000W可変式、25/45/72/100kHz、株式会社ソニックテクノロジー FL-1000)を底面に設置し、酵素入り調味液を約30L満たした。酵素は、Multifect PR6L(DUPONT GENENCOR)を使用した。酵素濃度は0.5(w/w)%であった。超音波発振器1により底面側から試料に対し超音波を一定時間照射した。超音波実験装置には音圧計5及び温度計4も備わっている。図2中の矢印は超音波が伝播する方向を示す。以下の実施例は、それぞれ前示の実験装置を用いて行ったものであり、その実験操作とともに説明する。
Explanation of Experimental Apparatus Used in Examples FIG. 2 shows a schematic diagram of the experimental apparatus. The experimental equipment is a container (ultrasonic vibration tank 2) (manufactured by Nippon Techno Service Co., Ltd., stainless steel 550mm x 356mm x 343mm) and ultrasonic vibrator 3 (385mm x 430mm x 145mm, throw-in type multi-frequency ultrasonic wave generator, 1000W variable type , 25/45/72 / 100kHz, Sonic Technology FL-1000 Co., Ltd.) was installed on the bottom, and about 30 L of enzyme-containing seasoning liquid was filled. As the enzyme, Multifect PR6L (DUPONT GENENCOR) was used. The enzyme concentration was 0.5 (w / w)%. The ultrasonic wave was irradiated to the sample from the bottom side by the ultrasonic oscillator 1 for a certain period of time. The ultrasonic experimental apparatus also includes a sound pressure meter 5 and a thermometer 4. The arrows in FIG. 2 indicate the direction in which the ultrasonic waves propagate. Each of the following examples was carried out using the experimental apparatus shown above, and will be described together with the experimental operation.

実施例1 超音波を用いて製造した軟化食品の特性
超音波実験装置1の容器に調味液6を入れ、4℃〜20℃以下の条件下にて、サケ切り身7(約70gにカットした切り身)に対して超音波振動子3を用いて30分間の照射を行った。網(425mm×280mm 18-8角バットアミ)の上に切り身を配置し、これを超音波発生装置から約10cmの位置(最適水深、最適位置については音圧計(OTARI 音圧計 SONOSABER-W水用標準型)を用いて最適条件を確認しながらサンプルの固定を行い所定時間超音波照射を行った。軟化食品の物性は、例えば、日本介護食品協議会のユニバーサルデザインフード(UDF)自主規格の方法あるいはそれに準ずる方法で測定することができる。日本介護食品協議会の日本介護食品協議会のユニバーサルデザインフード自主規格の方法は以下のとおりである。試料を直径40mmの容器に高さ15mmに充填し、直径20mmのプランジャーで圧縮速度10mm/sec、クリアランス5mmで測定する。ただし、測定容器に移すことで物性が変化するもの、測定容器に移せないもの、不定形なものなどは測定に支障のないことを確認して、クリアランスを試料の厚さ30%として直接測定してもよい。プランジャーの材質には規定はなく、測定機器としては、直線運動により物質の圧縮応力を測定することが可能な装置を用いる。例えば、直線運動により物質の圧縮応力を測定することが可能な装置としてテクスチャーアナライザー(例えば、TA XTplus(英弘精機社製))を用い、スチームチャンバーを用いて加熱調理した食品に、φ20mm円柱型プランジャーを10mm/secの速度で試料の厚みの70%まで押し込んだ際の荷重値を測定することにより行えばよい。
Example 1 Characteristics of softened food produced using ultrasonic waves Seasoning liquid 6 is placed in a container of ultrasonic experimental apparatus 1 and salmon fillet 7 (filled cut to about 70 g under conditions of 4 ° C. to 20 ° C. or less) ) Was irradiated for 30 minutes using the ultrasonic vibrator 3. A fillet is placed on a net (425mm x 280mm 18-8 square buttami), and this is placed at a position approximately 10cm from the ultrasonic generator (optimum water depth, sound pressure gauge (OTARI sound pressure gauge SONOSABER-W water standard) The sample was fixed using a mold, and the sample was fixed and subjected to ultrasonic irradiation for a predetermined time.The physical properties of the softened food are, for example, the Universal Design Food (UDF) voluntary standard method of the Japan Nursing Food Association or It can be measured by a method similar to that.The method of the Japan Nursing Food Council's Universal Design Food Voluntary Standard is as follows: The sample is filled in a 40 mm diameter container to a height of 15 mm, Measure with a plunger with a diameter of 20 mm at a compression rate of 10 mm / sec and clearance of 5 mm.However, those that change the physical properties when transferred to a measurement container, those that cannot be transferred to a measurement container, and those that are indefinite. The clearance may be measured directly with a sample thickness of 30% .There is no provision for the plunger material, and the measuring instrument is designed to measure the compressive stress of the substance by linear motion. For example, a texture analyzer (for example, TA XTplus (manufactured by Eihiro Seiki Co., Ltd.)) is used as a device capable of measuring the compressive stress of a substance by linear motion, and a steam chamber is used. What is necessary is just to measure the load value when a φ20 mm cylindrical plunger is pushed into cooked food at a speed of 10 mm / sec to 70% of the thickness of the sample.

凝集性及び付着性については、圧縮速度10mm/secで試料を2回、70%まで潰したときの荷重(N)を測定した。凝集性は食品に負荷を加えると、試料が変形、破損する際に負荷を連続2回加えて、1回目と2回目の負荷面積(エネルギー)の比を算出したものである。また、付着性は試料に付着して、引き離そうとする力(N)の面積(エネルギー)を算出したものである。   For cohesion and adhesion, the load (N) when the sample was crushed to 70% twice at a compression rate of 10 mm / sec was measured. Cohesiveness is calculated by calculating the ratio of the load area (energy) between the first time and the second time by applying a load twice continuously when a sample is deformed or broken when a load is applied to food. Adhesiveness is calculated by calculating the area (energy) of the force (N) that adheres to the sample and tries to separate it.

歩留測定については、30秒間網に魚を静置させ水切りを行った後、調味液への浸漬前、浸漬後、及び加熱後の重量をそれぞれ測定し算出した。歩留は、浸漬歩留及び加熱歩留で示した。浸漬歩留及び加熱歩留は以下の式で算出した。   For the yield measurement, the fish was allowed to stand in a net for 30 seconds and drained, and then the weight before immersion in the seasoning liquid, after immersion, and after heating was measured and calculated. Yield is shown by immersion yield and heating yield. Immersion yield and heating yield were calculated by the following equations.

浸漬歩留(%)=浸漬後/処理前×100
加熱歩留(%)(95℃、10分加熱)=処理後/処理前×100
Immersion yield (%) = after immersion / before treatment x 100
Heating yield (%) (95 ° C, heating for 10 minutes) = after treatment / before treatment x 100

軟化処理は以下の条件で行った。
1.酵素溶液への浸漬のみ(コントロール)(図3では、「浸漬のみ」と表示)
切り身(n=3)を食品原料として用い、凍結原料を4℃の低温室で解凍し、テンダライズ処理を2回行い、酵素を含む調味液(25L)に15分間浸漬し、5℃で24時間、酵素反応を行った。次いで、-30℃で急速冷凍し、95℃に設定したスチームチャンバーで10分間処理し酵素を失活させた。その後、放冷し室温で軟化度、凝集性及び付着性を測定し、浸漬歩留及び加熱歩留を算出した。
The softening treatment was performed under the following conditions.
1. Only immersion in the enzyme solution (control) (in FIG. 3, “immersion only” is displayed)
Using fillets (n = 3) as food ingredients, thawing frozen ingredients in a low-temperature room at 4 ° C, tenderizing treatment twice, immersing in seasoning liquid (25L) containing enzyme for 15 minutes, and at 5 ° C for 24 hours The enzyme reaction was performed. Next, the enzyme was inactivated by rapid freezing at −30 ° C. and treatment in a steam chamber set at 95 ° C. for 10 minutes. Then, it was allowed to cool, and the degree of softening, cohesiveness and adhesion were measured at room temperature, and the immersion yield and heating yield were calculated.

テンダライズ処理とは、針状の器具を刺し通し、原形を保ったまま食品原料の硬い筋や繊維を切断する等の物理的損傷を与える処理をいう。テンダライズ処理には、テンダライザー(4.5×4.5mm, 線径2.3φ)を用いた。酵素Multifect PR6L(DUPONT GENENCOR)を0.5%以下で一定量添加した。   The tenderizing process refers to a process of puncturing a needle-like instrument and causing physical damage such as cutting hard streaks or fibers of the food material while maintaining the original shape. A tenderizer (4.5 × 4.5 mm, wire diameter 2.3φ) was used for the tenderization process. Enzyme Multifect PR6L (DUPONT GENENCOR) was added in a fixed amount at 0.5% or less.

2.減圧法(コントロール)(図3では、「減圧法」と表示)
切り身(n=3)を食品原料として用い、凍結原料を4℃の低温室で解凍し、テンダライズ処理を2回行い、酵素溶液(375mL)に入れ0.09MPa条件下で5分間減圧し、その後常圧に戻すという操作を4回繰り返すことにより酵素溶液を含浸させ、5℃で24時間、酵素反応を行った。次いで、-30℃で急速冷凍し、95℃に設定したスチームチャンバーで10分間処理し酵素を失活させた。その後、放冷し室温で軟化度(かたさ、Firmness)、凝集性及び付着性を測定し、浸漬歩留及び加熱歩留を算出した。
2. Decompression method (control) (shown as “decompression method” in FIG. 3)
Using fillet (n = 3) as a raw material for food, thawing the frozen raw material in a low-temperature room at 4 ° C, performing tenderization twice, placing it in an enzyme solution (375 mL), reducing the pressure under 0.09 MPa for 5 minutes, and then The operation of returning to pressure was repeated 4 times to impregnate the enzyme solution, and the enzyme reaction was carried out at 5 ° C. for 24 hours. Next, the enzyme was inactivated by rapid freezing at −30 ° C. and treatment in a steam chamber set at 95 ° C. for 10 minutes. Then, it was allowed to cool, and the degree of softening (hardness, firmness), cohesiveness and adhesion were measured at room temperature, and the immersion yield and heating yield were calculated.

3.酵素の存在下での25kHzの超音波処理(図3では、「25kHz」と表示)
切り身(n=3)を食品原料として用い、凍結原料を4℃の低温室で解凍し、テンダライズ処理を2回行い、酵素を含む調味液(25L)に入れ、切り身に超音波を1000W、25kHzで15分間照射した。次いで、5℃で24時間、酵素反応を行った。次いで、-30℃で急速冷凍し、95℃に設定したスチームチャンバーで10分間処理し酵素を失活させた。その後、放冷し室温で軟化度、凝集性及び付着性を測定し、浸漬歩留及び加熱歩留を算出した。
3. Sonication at 25kHz in the presence of enzyme (shown as "25kHz" in Fig. 3)
Use fillet (n = 3) as a raw material for food, thaw frozen raw material in a low-temperature room at 4 ° C, perform tenderization twice, put in seasoning liquid (25 L) containing enzyme, and apply ultrasonic waves to fillet at 1000 W, 25 kHz For 15 minutes. Subsequently, the enzyme reaction was performed at 5 ° C. for 24 hours. Next, the enzyme was inactivated by rapid freezing at −30 ° C. and treatment in a steam chamber set at 95 ° C. for 10 minutes. Then, it was allowed to cool, and the degree of softening, cohesiveness and adhesion were measured at room temperature, and the immersion yield and heating yield were calculated.

4.酵素の非存在下での25kHzの超音波処理(図3では、「25kHz(酵素なし)」と表示) 切り身(n=3)を食品原料として用い、凍結原料を4℃の低温室で解凍し、テンダライズ処理を2回行い、酵素を含まない調味液(25L)に入れ、切り身に超音波を1000W、25kHzで15分間照射した。次いで、5℃で24時間、酵素反応を行った。次いで、-30℃で急速冷凍し、酵素を失活させた。その後、放冷し室温で軟化度、凝集性及び付着性を測定し、浸漬歩留及び加熱歩留を算出した。 4). Sonication at 25 kHz in the absence of enzyme (indicated as “25 kHz (no enzyme)” in FIG. 3) Using cuts (n = 3) as food ingredients and thawing frozen ingredients in a low-temperature room at 4 ° C The tenderization treatment was performed twice, the mixture was put in a seasoning solution (25 L) containing no enzyme, and the slices were irradiated with ultrasonic waves at 1000 W and 25 kHz for 15 minutes. Subsequently, the enzyme reaction was performed at 5 ° C. for 24 hours. Next, the enzyme was inactivated by rapid freezing at −30 ° C. Then, it was allowed to cool, and the degree of softening, cohesiveness and adhesion were measured at room temperature, and the immersion yield and heating yield were calculated.

5.テンダライズ無しで酵素の存在下での25kHzの超音波処理(図3では、「テンダライズ無」と表示)
切り身(n=3)を食品原料として用い、凍結原料を4℃の低温室で解凍し、酵素を含む調味液(25L)に入れ、切り身に超音波を1000W、25kHzで15分間照射した。次いで、5℃で24時間、酵素反応を行った。次いで、-30℃で急速冷凍し、酵素を失活させた、その後、放冷し室温で軟化度、凝集性及び付着性を測定し、浸漬歩留及び加熱歩留を算出した。
5). Sonication at 25kHz in the presence of enzyme without tenderization (shown as "no tenderization" in Figure 3)
Slices (n = 3) were used as food ingredients, frozen ingredients were thawed in a low-temperature room at 4 ° C., put into a seasoning liquid (25 L) containing enzymes, and the slices were irradiated with ultrasonic waves at 1000 W and 25 kHz for 15 minutes. Subsequently, the enzyme reaction was performed at 5 ° C. for 24 hours. Subsequently, the enzyme was inactivated by rapid freezing at −30 ° C., and then allowed to cool, and the softening degree, cohesiveness and adhesion were measured at room temperature, and the immersion yield and the heating yield were calculated.

結果を図3に示す。図3に示すように、超音波による酵素反応の促進効果について確認できた。酵素の存在下での25kHzの超音波処理を行う方法において、減圧法よりも約30%切り身が軟化されていることが確認できた。また、従来では野菜や肉等を凍結解凍しテンダライズした物を減圧含浸する手法が用いられているが、テンダライズ処理無しの切り身に対して酵素の存在下での25kHzの超音波処理を行う方法により、ユニバーサルデザインフード(UDF)区分2の軟化度50000(N/m2)以下になるため、より効率的に軟化食品を製造できることが示された。 The results are shown in FIG. As shown in FIG. 3, the effect of promoting the enzyme reaction by ultrasonic waves could be confirmed. In the method of performing ultrasonic treatment at 25 kHz in the presence of the enzyme, it was confirmed that the fillet was softened by about 30% compared to the decompression method. In addition, conventionally, a technique in which vegetables, meat, etc. are frozen and thawed and subjected to reduced pressure impregnation is used, but by a method of performing ultrasonic treatment at 25 kHz in the presence of an enzyme on fillets without tenderization treatment Since the softening degree of Universal Design Food (UDF) Category 2 is 50000 (N / m 2 ) or less, it was shown that softened food can be produced more efficiently.

図4Aに凝集性を、図4Bに付着性の結果を示す。図4Bに示すように酵素の存在下での25kHzの超音波処理を行う方法において、減圧法に比べ付着性が約50%低下し、より嚥下困難者用食品として適した物性となることが確認できた。   FIG. 4A shows the cohesive property, and FIG. 4B shows the adhesive property result. As shown in FIG. 4B, in the method of performing ultrasonic treatment at 25 kHz in the presence of an enzyme, the adhesion is reduced by about 50% compared to the decompression method, and it is confirmed that the physical properties are more suitable as foods for people with difficulty swallowing. did it.

図5Aに浸漬歩留の結果を示し、図5Bに加熱歩留の結果を示す。図5A及び図5Bに示すように、浸漬歩留は酵素の存在下での25kHzの超音波処理を行う方法と減圧法ではほぼ同じ歩留であるが、加熱歩留では酵素の存在下での25kHzの超音波処理を行う方法において、減圧法に比べて約6%程度高くなることを確認できた。このように減圧法に比べてより緩和な条件で軟化させ、歩留効果も高まることが示唆された。   FIG. 5A shows the result of the immersion yield, and FIG. 5B shows the result of the heating yield. As shown in FIG. 5A and FIG. 5B, the immersion yield is almost the same in the method of performing ultrasonic treatment at 25 kHz in the presence of the enzyme and the reduced pressure method, but in the heating yield, the immersion yield is in the presence of the enzyme. It was confirmed that the method of performing ultrasonic treatment at 25 kHz was about 6% higher than the pressure reduction method. In this way, it was suggested that softening was performed under milder conditions as compared with the decompression method, and the yield effect was increased.

実施例2 超音波の照射時間の検討
実施例1で用いたサケの切り身を用い、酵素の存在下での25kHzの超音波処理の方法により食品原料を製造する際に、超音波処理の時間を5分、15分、30分又は60分で行い、超音波の照射時間による軟化食品への影響を検討した。
Example 2 Examination of Ultrasonic Irradiation Time Using the salmon fillet used in Example 1 to produce a food raw material by the 25 kHz ultrasonic treatment method in the presence of an enzyme, the ultrasonic treatment time is set. The test was performed at 5, 15, 30, or 60 minutes, and the effect of the ultrasonic irradiation time on the softened food was examined.

図6−1に軟化度(かたさ、Firmness)の結果を示す。図6−1に示すように、照射時間が長いほど軟化する傾向が確認できた。15分程度の照射が最適時間と考えられた。   Fig. 6-1 shows the results of softness (hardness, Firmness). As shown in FIG. 6A, it was confirmed that the longer the irradiation time, the softening tendency. Irradiation of about 15 minutes was considered the optimal time.

図6−2Aに付着性の結果を示し、図6−2Bに凝集性の結果を示す。長時間照射するにしたがって、身の表面が柔らかくなり付着性、凝集性が増加したと考えられる。また、超音波照射することで減圧法に比べ付着性が約50%低下し、より嚥下困難者用食品に適した軟化食品であることが確認できた。   Fig. 6-2A shows the adhesion results, and Fig. 6-2B shows the cohesion results. It is thought that as the irradiation was continued for a long time, the surface of the body became soft and the adhesion and cohesion increased. In addition, the adhesiveness was reduced by about 50% compared to the reduced pressure method by irradiating with ultrasonic waves, and it was confirmed that the softened food was more suitable for food for persons with difficulty in swallowing.

図6−3Aに浸漬歩留の結果を示し、図6−3Bに加熱歩留の結果を示す。超音波照射5分では浸漬液が身に入りにくいため歩留が低く、照射15分で歩留が最大となり、それ以降は柔らかくなり過ぎて、身崩れが起きるため、歩留が低下していく傾向が確認された。   FIG. 6-3A shows the result of the immersion yield, and FIG. 6-3B shows the result of the heating yield. The yield is low because the immersion liquid is difficult to get into with ultrasonic irradiation for 5 minutes, the yield is maximum after 15 minutes of irradiation, and after that it becomes too soft and the body collapses, causing the yield to decrease. A trend was confirmed.

実施例3 超音波の周波数の検討
実施例1で用いたサケの切り身を用い、酵素の存在下での超音波処理の方法により食品原料を製造する際に、照射する超音波の周波数を25kHz、45kHz、100kHz及び25kHzと100kHzの交互照射(25kHzで10秒間照射し、100kHzで10秒間照射を所定時間繰り返し照射)とし、超音波の周波数による軟化食品への影響を検討した。照射時間は30分であった。
Example 3 Examination of ultrasonic frequency When producing food ingredients by the method of ultrasonic treatment in the presence of enzyme, using the salmon fillet used in Example 1, the frequency of ultrasonic wave to be irradiated is 25 kHz, 45kHz, 100kHz and 25kHz and 100kHz alternating irradiation (irradiated for 10 seconds at 25kHz, repeated irradiation for 10 seconds at 100kHz for a predetermined time), and examined the influence of the ultrasonic frequency on the softened food. The irradiation time was 30 minutes.

図7−1に軟化度の結果を示す。図7−1に示すように、25kHzが一番かたさが低下し、低周波ほど軟化効果が高いことが確認できた。調味液や身の質によっても軟化度に与える影響がある可能性がある。   FIG. 7-1 shows the result of the softening degree. As shown in FIG. 7A, it was confirmed that 25 kHz was the hardest and the softening effect was higher at lower frequencies. The seasoning liquid and the quality of the body may also affect the softening level.

図7−2Aに付着性の結果を示し、図7−2Bに凝集性の結果を示す。図7−2Aに示すように、周波数が増加するにしたがって、付着性が増加する傾向が確認された。また、図7−2Bに示すように、周波数が増加するに従って、凝集性も増加する傾向が確認されたが、25kHzと100kHzの交互照射ではそれほど増加しなかった。   FIG. 7-2A shows the adhesion results, and FIG. 7-2B shows the aggregation results. As shown to FIG. 7-2A, the tendency for adhesiveness to increase was confirmed as the frequency increased. Further, as shown in FIG. 7-2B, it was confirmed that the cohesiveness also increased as the frequency increased, but it did not increase so much by alternating irradiation of 25 kHz and 100 kHz.

図7−3Aに浸漬歩留の結果を示し、図7−3Bに加熱歩留の結果を示す。図7−3A及び図7−3Bに示すように、低周波である25kHzでの歩留(浸漬歩留、加熱歩留)が他の周波数に比べて高くなることが確認できた。   FIG. 7-3A shows the result of the immersion yield, and FIG. 7-3B shows the result of the heating yield. As shown in FIGS. 7-3A and 7-3B, it was confirmed that the yield (immersion yield, heating yield) at 25 kHz, which is a low frequency, was higher than other frequencies.

また、図7−4に175kHz,1000Wの超音波を処理した場合の結果を示す。図7−4Aに軟化度(かたさ、Firmness)を示し、図7−4Bに付着性を示す。図7−4は、175kHzの高周波帯でも同様に軟化食品を製造することが可能であることを示している。   Moreover, the result at the time of processing an ultrasonic wave of 175 kHz and 1000 W in FIG. 7-4 is shown. FIG. 7-4A shows the softness (hardness, Firmness), and FIG. 7-4B shows the adhesion. FIG. 7-4 shows that the softened food can be produced in the same manner in the high frequency band of 175 kHz.

実施例4 超音波の照射強度の検討
実施例1の「酵素の存在下での25kHzの超音波処理」の検討において、超音波の照射強度を28kHz、1800Wで行った。
軟化度(かたさ、Firmness)、付着性及び凝集性、並びに浸漬歩留及び加熱歩留を表1に示す。
Example 4 Examination of Ultrasonic Irradiation Intensity In the examination of “25 kHz ultrasonic treatment in the presence of enzyme” in Example 1, the ultrasonic irradiation intensity was 28 kHz and 1800 W.
Table 1 shows the softness (hardness, firmness), adhesion and cohesiveness, and immersion yield and heating yield.

Figure 2017104126
Figure 2017104126

表1に示すように、1800Wでの照射によっても、良好な物性を有する軟化食品を製造することができた。   As shown in Table 1, a softened food having good physical properties could be produced even by irradiation at 1800 W.

実施例5 サケ以外の魚種に対する超音波処理の検討
実施例1で用いたサケの切り身をホキの切り身に代えて酵素の存在下での超音波処理の影響を検討した。図8に、軟化度(かたさ、Firmness)(図8A)、付着性(図8B)及び凝集性(図8C)、並びに浸漬歩留及び加熱歩留を表2に示す。
Example 5 Examination of ultrasonic treatment for fish species other than salmon The influence of ultrasonic treatment in the presence of an enzyme was examined by replacing the salmon fillet used in Example 1 with a hoki fillet. FIG. 8 shows the softness (hardness) (FIG. 8A), adhesion (FIG. 8B) and cohesiveness (FIG. 8C), and immersion yield and heating yield.

Figure 2017104126
Figure 2017104126

図8に示すように、ホキの切り身においても、軟化食品を製造することができた。このように比較的軟らかい切り身であるホキに対しても照射時間や周波数等の緩和な条件で軟化させることが示唆された。   As shown in FIG. 8, the softened food could be manufactured even in the fillet of the hoki. It was suggested that even the relatively soft fillet can be softened under mild conditions such as irradiation time and frequency.

実施例6 野菜に対する超音波処理の検討
酵素溶液への浸漬のみ(図9−1及び9−2では「浸漬のみ」と表示)サトイモ(約100g)を食品原料として用い、輪切り(約5mm)にした凍結原料を4℃の低温室で解凍した。実施例1と同様の超音波処理の方法により、酵素を含む調味液(25L)に30分間浸漬し、5℃で24時間酵素反応を行った。減圧法についても実施例1と同様に行った。超音波照射は実施例1の「酵素の存在下での25kHzの超音波処理」の検討と同様の方法で30分間照射した(図9−1及び9−2では「超音波」と表示)。図9−1に歩留結果を示す。図9−1Aは、浸漬歩留を示し、図9−1Bは加熱歩留を示す。図9−1に示すように、従来法である減圧処理に比べて超音波処理は歩留(浸漬歩留、加熱歩留)が向上していることが確認できた。
Example 6 Examination of ultrasonic treatment for vegetables Only immersion in enzyme solution (shown as “immersion only” in FIGS. 9-1 and 9-2) Using taro (about 100 g) as a food ingredient, round slices (about 5 mm) The frozen material was thawed in a cold room at 4 ° C. By the same ultrasonic treatment method as in Example 1, it was immersed in a seasoning liquid (25 L) containing an enzyme for 30 minutes, and an enzyme reaction was carried out at 5 ° C. for 24 hours. The decompression method was performed in the same manner as in Example 1. Ultrasonic irradiation was performed for 30 minutes in the same manner as in the examination of “25 kHz ultrasonic treatment in the presence of enzyme” in Example 1 (indicated as “ultrasound” in FIGS. 9-1 and 9-2). Fig. 9-1 shows the yield results. FIG. 9-1A shows the immersion yield, and FIG. 9-1B shows the heating yield. As shown in FIG. 9A, it was confirmed that the yield (immersion yield, heating yield) was improved in the ultrasonic treatment compared with the conventional decompression treatment.

また、図9−2に物性値として、軟化度(かたさ、Firmness)(図9−2A)及び付着性(図9−2B)及び凝集性(図9−2C)の結果を示す。超音波試験区では付着性が低下し、凝集性が高くなる傾向があることから、嚥下困難者用食品として適した物性となることが確認できた。   9-2 shows the results of the softness (hardness, Firmness) (FIG. 9-2A), adhesion (FIG. 9-2B), and cohesiveness (FIG. 9-2C) as physical property values. In the ultrasonic test section, the adhesiveness decreased and the cohesiveness tended to increase, so that it was confirmed that the physical properties were suitable as a food for people with difficulty in swallowing.

実施例7 超音波の高出力密度下の検討
DKSHジャパン社製UIP1000hd(約600W,20kHz)出力密度41W/cm2を用いて、酵素存在下で検討を実施した。実施例1で用いたサケで酵素入り調味液500mLに対して切り身1枚を片面1分間照射した後、裏返し、更に片面1分間(合計2分間)超音波を照射した。投げ込み型超音波装置(約0.6W/cm2)では魚肉を軟化させるために約15分間の照射を要したため、更に時間短縮・酵素反応促進を期待し、強力な超音波装置(ホーン型)で検討を行った。その硬さの結果を表3に示す。表3に示すように、2分間の照射でも高出力密度下の超音波照射を行えば、軟化できる可能性が示唆された。
Example 7 Examination under Ultrasonic High Power Density
Using UIP1000hd (about 600W, 20kHz) output density of 41W / cm 2 manufactured by DKSH Japan, examination was carried out in the presence of the enzyme. The salmon used in Example 1 was irradiated with a slice of 500 ml of enzyme-containing seasoning liquid for 1 minute on one side, then turned over, and further irradiated with ultrasonic waves for 1 minute on each side (2 minutes in total). The throw-in type ultrasonic device (approx. 0.6 W / cm 2 ) required irradiation for about 15 minutes to soften the fish meat, so it was expected to further shorten the time and promote enzyme reaction, and with a powerful ultrasonic device (horn type) Study was carried out. The hardness results are shown in Table 3. As shown in Table 3, the possibility of softening can be suggested by performing ultrasonic irradiation under high power density even with irradiation for 2 minutes.

Figure 2017104126
Figure 2017104126

1 超音波発振器
2 超音波振動槽
3 超音波振動子
4 温度計
5 音圧計
6 調味液
7 切り身サンプル
DESCRIPTION OF SYMBOLS 1 Ultrasonic oscillator 2 Ultrasonic vibration tank 3 Ultrasonic vibrator 4 Thermometer 5 Sound pressure meter 6 Seasoning liquid 7 Fillet sample

Claims (10)

咀嚼・嚥下困難者用の付着性が低下した食品の製造方法であり、食品原料に超音波を照射することにより、食品原料の付着性を低下させることを含む、付着性が低下した食品の製造方法。   This is a method for producing foods with reduced adhesion for those with difficulty in chewing and swallowing, and producing foods with reduced adhesion, including reducing the adhesion of food ingredients by irradiating the food ingredients with ultrasound. Method. 超音波により、食品材料中の液体中でキャビテーションにより気泡を発生させ、発生した気泡の破裂により発生した衝撃波により、食品原料の付着性を低下させる、請求項1記載の付着性が低下した食品の製造方法。   The method of claim 1, wherein bubbles are generated by cavitation in a liquid in a food material by ultrasonic waves, and the adhesion of the food material is reduced by shock waves generated by bursting of the generated bubbles. Production method. 照射する超音波の周波数が20〜200kHzである、請求項1又は2に記載の付着性が低下した食品の製造方法。   The method for producing a food product with reduced adhesion according to claim 1 or 2, wherein the frequency of ultrasonic waves to be irradiated is 20 to 200 kHz. 超音波の照射を、20〜200kHzの周波数を2種以上組み合わせて行う、請求項1〜3のいずれか1項に記載の付着性が低下した食品の製造方法。   The method for producing a food with reduced adhesion according to any one of claims 1 to 3, wherein the ultrasonic irradiation is performed by combining two or more frequencies of 20 to 200 kHz. 超音波の照射強度が、300〜3000Wである、請求項1〜4のいずれか1項に記載の付着性が低下した食品の製造方法。   The manufacturing method of the foodstuff with which the adhesiveness fell of any one of Claims 1-4 whose ultrasonic irradiation intensity | strength is 300-3000W. 超音波の出力密度が、0.5〜50 W/cm2である、請求項1〜5のいずれか1項に記載の付着性が低下した食品の製造方法。 Power density of the ultrasound is, 0.5 to 50 W is / cm 2, the manufacturing method of food adhesion was reduced according to any one of claims 1 to 5. 超音波の照射を、0〜40℃で行う、請求項1〜6のいずれか1項に記載の付着性が低下した食品の製造方法。   The method for producing a food with reduced adhesion according to any one of claims 1 to 6, wherein the ultrasonic irradiation is performed at 0 to 40 ° C. 超音波の照射時間が10〜30分間である、請求項1〜7のいずれか1項に記載の付着性が低下した食品の製造方法。   The method for producing a food with reduced adhesion according to any one of claims 1 to 7, wherein the irradiation time of ultrasonic waves is 10 to 30 minutes. 食品原料が、魚介類の肉、畜肉、卵、青果物、芋類、穀物及び海藻からなる群から選択される、請求項1〜8のいずれか1項に記載の付着性が低下した食品の製造方法。   The production of food with reduced adhesion according to any one of claims 1 to 8, wherein the food material is selected from the group consisting of seafood meat, livestock meat, eggs, fruits and vegetables, cereals, cereals and seaweed. Method. 咀嚼・嚥下困難者用に適した性質を持つ付着性が低下した食品であり、直径20mmのプランジャーで圧縮速度10mm/secの速度で試料の厚みの70%まで押し込んだ際の荷重値が500000(N/m2)以下であり、及び/又は圧縮速度10mm/secで試料を2回、70%まで潰したときの荷重(N)を測定し、試料に付着して、引き離そうとする力(N)の面積(エネルギー)を算出した付着性が400(J/m3)以下となる付着性が低下した食品を製造する、請求項1〜9のいずれか1項に記載の付着性が低下した食品の製造方法。 A food with reduced adhesiveness that has properties suitable for those with difficulty in chewing and swallowing, with a load value of 500000 when it is pushed to 70% of the sample thickness at a compression speed of 10 mm / sec with a plunger with a diameter of 20 mm (N / m 2 ) or less, and / or the load (N) when the sample is crushed to 70% twice at a compression speed of 10 mm / sec. The adhesiveness according to any one of claims 1 to 9, wherein a food product with reduced adhesiveness in which the adhesiveness calculated from the area (energy) of N) is 400 (J / m 3 ) or less is produced. Food manufacturing method.
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KR102612391B1 (en) 2019-10-02 2023-12-12 강병원 Manufacturing method of canned radishleaves for immediate cooking and canned radishleaves for immediate cooking manufactured by the same
KR102459654B1 (en) * 2020-05-28 2022-10-31 고려자연식품(주) Manufacturing method of silver food using citrus fruits and silver food prepared therefrom
KR20210147177A (en) * 2020-05-28 2021-12-07 군산대학교산학협력단 Manufacturing method of silver food using citrus fruits and silver food prepared therefrom

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