JP2014064542A - Manufacturing method of meat-containing retort food - Google Patents

Manufacturing method of meat-containing retort food Download PDF

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JP2014064542A
JP2014064542A JP2012213899A JP2012213899A JP2014064542A JP 2014064542 A JP2014064542 A JP 2014064542A JP 2012213899 A JP2012213899 A JP 2012213899A JP 2012213899 A JP2012213899 A JP 2012213899A JP 2014064542 A JP2014064542 A JP 2014064542A
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meat
retort
baking soda
pressure
treatment
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Tadayuki Nishiumi
理之 西海
Yun-Jung Kim
娟廷 金
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NIIGATA IND CREATION ORGANIZATION
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Abstract

PROBLEM TO BE SOLVED: To provide a manufacturing method of a retort food, which allows meat contained in the retort food to be processed to have a soft and moist texture with fine tissues and high water holding capacity.SOLUTION: The manufacturing method includes a sodium bicarbonate-immersion step (S1) of immersing raw meat in a sodium bicarbonate solution, a high-pressure treatment step (S2) of applying a pressure of 100 MPa to 500 MPa to meat, and a retort treatment step (S4) of performing retort treatment of meat. Instead of the sodium bicarbonate-immersion step (S1), a sodium bicarbonate-injection step (S11) of injecting sodium bicarbonate solution to raw meat may be included. A heating and cooling step (S3) of heating meat and then cooling the meat may be further included between the high-pressure treatment step (S2) and the retort treatment step (S4).

Description

本発明は、レトルト食品中の食肉を、軟らかく、かつ組織が緻密で保水性が高くてしっとりとした食感を有するように加工可能なレトルト食品の製造方法に関し、特に食肉が極めて硬い輸入牛肉に対して上述のように加工可能なレトルト食品の製造方法に関する。   The present invention relates to a method for producing a retort food that can be processed so that the meat in the retort food is soft and has a dense texture, high water retention, and a moist texture, and particularly to imported beef with extremely hard meat. On the other hand, it is related with the manufacturing method of the retort food which can be processed as mentioned above.

食品を加熱することは、調理、加工、又は保存のために古くから広く用いられてきた加工法である。近年、加熱処理に代わる新しい食品加工法として、数千気圧(数百MPa)の静水圧を利用した高圧処理技術が注目されている。高圧処理は、まだ一般にはなじみの少ない加工法であるが、微生物の生育抑制・殺菌に役立つことに注目されて以来、高圧処理についての研究が進められている。さらには、加熱処理とは異なり化学反応を伴わないので、栄養成分の損失や異臭・異常物質の発生がないこと、生体膜構造の損傷による酵素反応の制御が可能なこと、ならびに省エネ効果等のメリットが期待できることから、近年、食品分野への利用も進んでいる。   Heating food is a processing method that has long been widely used for cooking, processing, or storage. In recent years, high pressure processing technology using a hydrostatic pressure of several thousand atmospheres (several hundred MPa) has attracted attention as a new food processing method that replaces heat treatment. Although high-pressure treatment is still a processing method that is generally unfamiliar, research on high-pressure treatment has been underway since it was noted that it was useful for the suppression and sterilization of microorganisms. Furthermore, unlike heat treatment, it does not involve chemical reactions, so there is no loss of nutrients, no off-flavors or abnormal substances, the ability to control enzyme reactions due to damage to biological membrane structures, and energy-saving effects. In recent years, it has been used in the food field because of its merit.

本発明者らは、近年、「高圧処理が食肉タンパク質構造の脆弱化を誘導する」という知見を基に、高圧処理と重曹処理の併用処理(以下、「重曹・高圧併用処理」とも呼ぶ。)を用いた食肉の加工方法を既に提案している(非特許文献1及び特許文献1を参照)。具体的には、非特許文献1では、豚肉に対して重曹浸漬処理と高圧処理を併用することで重曹浸漬処理単独に比べさらに処理後の肉質が軟らかく飲み込み易くなるという研究報告がされている。また、特許文献1では、重曹浸漬処理と高圧処理とに加えて、醤油及びみりん等の調味液に食肉を浸漬する調味液処理をさらに施すことで、更なる食肉の軟化が実現するとともに、調味液の浸透により美味しさも向上することが可能であることが開示されている。   Based on the knowledge that “high-pressure treatment induces weakening of meat protein structure” in recent years, the present inventors have used high-pressure treatment and sodium bicarbonate treatment (hereinafter also referred to as “bicarbonate / high-pressure combination treatment”). Have already proposed a method of processing meat using sushi (see Non-Patent Document 1 and Patent Document 1). Specifically, in Non-Patent Document 1, there is a research report that the meat quality after treatment is softer and easier to swallow by combining the baking soda immersion treatment and the high pressure treatment for pork compared to the baking soda immersion treatment alone. Moreover, in patent document 1, in addition to a baking soda immersion process and a high-pressure process, by further performing the seasoning liquid process which immerses meat in seasoning liquids, such as soy sauce and mirin, while further softening of meat is implement | achieved, seasoning It is disclosed that the taste can be improved by the penetration of the liquid.

一方、加熱殺菌法を採用した食品加工法としてレトルト処理による調理法が現在までに確立されており、加工されたレトルト食品は長期保存や調理の簡便性などの利点を有するため、食品市場に広く普及している。   On the other hand, cooking methods using retort treatment have been established as food processing methods that employ heat sterilization, and processed retort foods have advantages such as long-term storage and ease of cooking. It is popular.

食肉のレトルト加工の前処理に高圧処理のみを適用した先行技術として、特許文献2に記載の内臓肉の加工方法が開示されている。しかしながら、高圧処理のみを前処理として行った場合には、レトルト処理に伴う内臓肉の脂肪の溶出が抑制され、内臓肉の形状や食感が保持される等の効果が得られるが、普通の食肉では筋線維がばらばらに離れてパサパサした硬い食感となるため、食肉の軟化の観点からは、なお、改善の余地がある。特に、輸入牛肉は安価な食材であるが、極めて硬いため上記方法を含めた先行技術では軟化されず、レトルト食品の食肉原料として不向きであると指摘されている。   As a prior art in which only high-pressure processing is applied to pretreatment of meat retort processing, a method for processing visceral meat described in Patent Document 2 is disclosed. However, when only high-pressure treatment is performed as a pretreatment, elution of visceral meat fat due to retort treatment is suppressed, and effects such as maintaining the shape and texture of visceral meat are obtained. In meat, since the muscle fibers are separated apart and become a hard texture, there is still room for improvement from the viewpoint of meat softening. In particular, imported beef is an inexpensive food, but since it is extremely hard, it is pointed out that it is not softened by the prior art including the above method and is not suitable as a raw material for retort food.

特開2011−83228号公報JP 2011-83228 A 特開2011−36141号公報JP 2011-36141 A

金娟廷ほか、豚肉の物性及び嗜好性に及ぼす高圧処理の影響、日本調理科学会誌、Vol.39 No.1 (2006年2月)Kim Jong-soo et al., Effect of high-pressure treatment on physical properties and palatability of pork, Journal of the Japan Society of Cookery Science, Vol.39 No.1 (February 2006)

しかしながら、本発明者らは、上記非特許文献1の報告や特許文献1の開示の後も、上記技術をベースに更なる食肉の軟化や美味しさの向上を達成可能な食肉加工技術について追求し続けている。   However, the present inventors have pursued a meat processing technology that can achieve further softening of meat and an improvement in taste after the report of Non-Patent Document 1 and the disclosure of Patent Document 1. continuing.

なお、非特許文献1や特許文献1に記載の実施例では、原料として比較的軟らかい生の豚肉を使用して重曹・高圧併用処理した効果の確認試験を行い、この効果を実証しているが、豚肉に比べ極めて硬い食肉である牛肉(特に輸入牛肉)に対して、上記併用処理の効果を奏するか否かは不明であった。また、非特許文献1や特許文献1に開示の加工方法は、その後のレトルト処理への応用については言及も示唆もされていない。従って、レトルト加工の前処理として上記併用処理を行った場合に、この併用処理とレトルト加工とが上手く適合し、結果として、食肉の軟らかさや美味しさの観点において高品質なレトルト食品を製造できるか否かについても不明であった。   In the examples described in Non-Patent Document 1 and Patent Document 1, a confirmation test of the effect of using a relatively soft raw pork as a raw material and a combined treatment with sodium bicarbonate and high pressure was conducted to demonstrate this effect. It has been unclear whether or not the above-mentioned combined treatment effect is exerted on beef (especially imported beef) which is extremely hard meat compared to pork. Further, the processing methods disclosed in Non-Patent Document 1 and Patent Document 1 are neither mentioned nor suggested for subsequent application to retort processing. Therefore, when the above combined treatment is performed as a pretreatment for retort processing, the combined treatment and the retort processing are well adapted, and as a result, can a high-quality retort food be produced in terms of meat tenderness and deliciousness? It was also unclear whether or not.

本発明は、このような事情を考慮してなされたものであり、レトルト食品中の食肉を、軟らかく、かつ組織が緻密で保水性が高くてしっとりとした食感を有するように加工可能なレトルト食品の製造方法を提供することを目的とする。   The present invention has been made in view of such circumstances, and the retort can be processed so that the meat in the retort food is soft and has a dense texture, high water retention and a moist texture. It aims at providing the manufacturing method of foodstuffs.

本発明者らは、鋭意検討の末、重曹・高圧併用処理とその後のレトルト加工とが適合すること、及び、レトルト加工の前処理としての重曹・高圧併用処理における好適な条件を見出し、本発明を完成するに至った。   As a result of intensive studies, the present inventors have found that the combined treatment of sodium bicarbonate and high pressure and the subsequent retort processing are suitable, and found suitable conditions in the combined treatment of sodium bicarbonate and high pressure as pretreatment of the retort processing. It came to complete.

すなわち、本発明は、少なくとも次の特徴を備えたものである。
(態様1)
生の食肉を重曹溶液中に浸漬する重曹浸漬工程と、
前記食肉に100MPa〜500MPaの圧力を加える高圧処理工程と、
前記食肉にレトルト処理を施すレトルト処理工程と、
を含むことを特徴とする食肉入りレトルト食品の製造方法。
(態様2)
前記重曹溶液の濃度が0.1M〜0.5Mであり、該重曹溶液中への前記食肉の浸漬時間が30分間〜60分間であることを特徴とする態様1に記載の食肉入りレトルト食品の製造方法。
(態様3)
生の食肉に重曹溶液を注入する重曹インジェクション工程と、
前記食肉に100MPa〜500MPaの圧力を加える高圧処理工程と、
前記食肉にレトルト処理を施すレトルト処理工程と、
を含むことを特徴とする食肉入りレトルト食品の製造方法。
(態様4)
前記重曹溶液の濃度及び注入量と前記圧力と、前記レトルト処理工程後の前記食肉の物性と、の関係を予め算出する予備分析工程と、
前記予備分析工程で得られた前記関係から、前記重曹インジェクション工程及び前記高圧処理工程における前記重曹溶液の前記濃度及び前記注入量と前記圧力とを決定する食感パラメータ決定工程と、
をさらに含むことを特徴とする態様3に記載の食肉入りレトルト食品の製造方法。
(態様5)
前記圧力が300MPa〜400MPaであることを特徴とする態様1〜4のいずれかに記載の食肉入りレトルト食品の製造方法。
(態様6)
前記高圧処理工程と前記レトルト処理工程との間に、前記食肉を加熱した後に冷却する加熱冷却工程をさらに含むことを特徴とする態様1〜5のいずれかに記載の食肉入りレトルト食品の製造方法。
(態様7)
前記重曹溶液の濃度が0.3M〜0.4Mであり、前記圧力が300MPa〜400MPaであり、前記食肉への該重曹溶液の注入量を前記食肉の重量の10%〜25%に相当する重量を有した分量であることを特徴とする態様3〜6のいずれかに記載の食肉入りレトルト食品の製造方法。
That is, the present invention has at least the following features.
(Aspect 1)
A baking soda immersing step of immersing raw meat in a baking soda solution;
A high-pressure treatment step of applying a pressure of 100 MPa to 500 MPa to the meat;
A retort treatment step of subjecting the meat to a retort treatment;
The manufacturing method of the retort food containing meat characterized by including.
(Aspect 2)
The concentration of the baking soda solution is 0.1 M to 0.5 M, and the immersion time of the meat in the baking soda solution is 30 minutes to 60 minutes. Production method.
(Aspect 3)
A baking soda injection process in which a baking soda solution is poured into raw meat,
A high-pressure treatment step of applying a pressure of 100 MPa to 500 MPa to the meat;
A retort treatment step of subjecting the meat to a retort treatment;
The manufacturing method of the retort food containing meat characterized by including.
(Aspect 4)
A preliminary analysis step of calculating in advance the relationship between the concentration and injection amount of the sodium bicarbonate solution and the pressure, and the physical properties of the meat after the retort treatment step;
From the relationship obtained in the preliminary analysis step, the texture parameter determination step for determining the concentration and the injection amount and the pressure of the sodium bicarbonate solution in the sodium bicarbonate injection step and the high pressure treatment step,
The method for producing a retort food containing meat according to aspect 3, further comprising:
(Aspect 5)
The method for producing a retort food containing meat according to any one of aspects 1 to 4, wherein the pressure is 300 MPa to 400 MPa.
(Aspect 6)
The method for producing a meat-containing retort food according to any one of aspects 1 to 5, further comprising a heating and cooling step of cooling the meat after heating the high-pressure treatment step and the retort treatment step. .
(Aspect 7)
The concentration of the baking soda solution is 0.3 M to 0.4 M, the pressure is 300 MPa to 400 MPa, and the amount of injection of the baking soda solution into the meat is equivalent to 10% to 25% of the weight of the meat The method for producing a meat-containing retort food according to any one of aspects 3 to 6, wherein the retort food contains meat.

本発明の製造方法によれば、重曹・高圧併用処理をレトルト処理の前処理として行うために、重曹処理と高圧処理との相乗効果をレトルト処理後の食肉に与えることができる。具体的には、非常に大きな軟化、保水性の向上、組織の緻密化、パサパサ感の発生防止、及び重曹風味の消失といった様々な効果を食肉に与えることができる。この製造方法を用いれば、例えば、通常、極めて硬い輸入牛肉等でも、レトルト食品の食材として利用できる程に軟らかくなり、レトルト食品の食材の選択の幅が広がるとともにレトルト食品の原材料コストを下げることが可能となる。   According to the production method of the present invention, since the combined baking soda / high pressure treatment is performed as a pretreatment for the retort treatment, a synergistic effect of the baking soda treatment and the high pressure treatment can be imparted to the meat after the retort treatment. Specifically, various effects such as extremely large softening, improvement of water retention, densification of the structure, prevention of the feeling of papasa, and disappearance of the baking soda flavor can be given to the meat. If this manufacturing method is used, for example, even extremely hard imported beef can be softened to the extent that it can be used as an ingredient for retort food, the range of choice of ingredients for retort food can be expanded, and the raw material cost of retort food can be reduced. It becomes possible.

(a)は本発明の一実施形態に係る製造方法の各工程を説明したフローチャートであり、(b)はもう一つの実施形態に係る製造方法の各工程を説明したフローチャートである。(A) is the flowchart explaining each process of the manufacturing method which concerns on one Embodiment of this invention, (b) is the flowchart explaining each process of the manufacturing method which concerns on another embodiment. (a)は圧力とその圧力で処理した加工肉の破断応力を示した図であり、(b)は破断応力と水分含有量との関係を示した図である。(A) is the figure which showed the rupture stress of the processed meat processed with the pressure and the pressure, (b) is the figure which showed the relationship between rupture stress and moisture content. レトルト処理を更に施した各加工肉の破断応力を示した図である。It is the figure which showed the breaking stress of each processed meat which performed the retort process further. (a)はレトルト処理を更に施した各加工肉の水分含有量を示した図であり、(b)は各加工肉の重量減少率を示した図である。(A) is the figure which showed the water content of each processed meat which performed the retort process further, (b) is the figure which showed the weight decreasing rate of each processed meat. (a)は実施例1及び比較例1〜3の加工肉を咀嚼した際の嚥下までの咀嚼回数を示し、(b)はその咀嚼時間を示し、(c)はその総筋活動量を示し、及び(d)は一回平均咀嚼時の筋活動量を示す。(A) shows the number of chewing times until swallowing when the processed meat of Example 1 and Comparative Examples 1 to 3 is chewed, (b) shows the chewing time, and (c) shows the total muscle activity. , And (d) show the amount of muscle activity during one average mastication. (a)は実施例2及び比較例4の加工肉の破断応力を示し、(b)は、更にレトルト処理した後の実施例2の加工肉の破断応力を示した図である。(A) shows the breaking stress of the processed meat of Example 2 and Comparative Example 4, and (b) shows the breaking stress of the processed meat of Example 2 after further retorting. (a)は実施例2及び比較例1の加工肉を咀嚼した際の嚥下までの咀嚼回数を示し、(b)はその咀嚼時間を示し、(c)はその総筋活動量を示し、及び(d)は一回平均咀嚼時の筋活動量を示す。(A) shows the number of chewing times until swallowing when the processed meat of Example 2 and Comparative Example 1 is chewed, (b) shows the chewing time, (c) shows the total muscle activity, and (D) shows the amount of muscle activity at the time of average chewing. 実施例3のレトルトビーフカレーの外観を示した画像である。6 is an image showing an appearance of a retort beef curry of Example 3. 実施例3及び比較例5のレトルトビーフカレーにおける官能評価結果を示した図である。It is the figure which showed the sensory evaluation result in the retort beef curry of Example 3 and Comparative Example 5.

以下、本発明を図面に示す実施の形態に基づき説明するが、本発明は、下記の具体的な実施態様に何等限定されるものではない。   Hereinafter, the present invention will be described based on embodiments shown in the drawings, but the present invention is not limited to the following specific embodiments.

本発明に適用可能な食肉原料として、牛、豚、鶏、羊、鴨等が挙げられる。但し、これらの例示に限定されず、レトルト食品として使用可能な食用肉であれば良い。   Examples of meat materials applicable to the present invention include cows, pigs, chickens, sheep, and duck. However, it is not limited to these examples, and any edible meat that can be used as a retort food may be used.

(本発明の製造方法のフロー)
図1(a)に本発明の一実施形態に係る製造方法の各工程を説明したフローチャートを示す。この製造方法は、図1(a)に示すように、生の食肉を重曹(つまり、炭酸水素ナトリウム(NaHCO))溶液中に浸漬する重曹浸漬工程(図中、符号S1参照)と、食肉に100MPa〜500MPaの圧力を加える高圧処理工程(図中、符号S2参照)と、食肉にレトルト処理を施すレトルト処理工程(図中、符号S4参照)と、を有する。なお、図示のように、食肉を加熱した後に冷却する加熱冷却工程(図中、符号S3参照)を施しても良い。
(Flow of the manufacturing method of the present invention)
FIG. 1 (a) shows a flowchart illustrating each process of a manufacturing method according to an embodiment of the present invention. As shown in FIG. 1 (a), this production method includes a baking soda dipping step (see S1 in the figure) in which raw meat is immersed in a sodium bicarbonate (that is, sodium bicarbonate (NaHCO 3 )) solution, A high-pressure treatment step (see symbol S2 in the figure) for applying a pressure of 100 MPa to 500 MPa, and a retort treatment step (see symbol S4 in the figure) for retorting the meat. As shown in the figure, a heating / cooling step (see S3 in the figure) for cooling the meat after heating may be performed.

(重曹浸漬工程)
この重曹浸漬工程S1によって、重曹処理前の食肉のpHが上昇し、食肉のタンパク質の水和が促進されて食肉中の水分含有量が上昇し、加熱後の食肉の軟化に第1次的な効果がもたらされる。ただし、この工程が終了した段階の食肉には、重曹風味が残存するといったデメリットも生じる。
(Baking soda immersion process)
By this baking soda dipping step S1, the pH of the meat before baking soda treatment is increased, the hydration of the protein of the meat is promoted, the moisture content in the meat is increased, and this is the primary for softening of the meat after heating. The effect is brought about. However, there is a demerit that the baking soda flavor remains in the meat at the end of this process.

なお、重曹浸漬工程S1では、重曹溶液の濃度が0.1M〜0.5M(単位のMは、mol/l、好ましくは0.3M〜0.4M)である。この重曹溶液中への食肉の浸漬時間は30分間〜60分間であることが好ましい。   In the baking soda dipping step S1, the concentration of the baking soda solution is 0.1M to 0.5M (unit M is mol / l, preferably 0.3M to 0.4M). It is preferable that the immersion time of the meat in this baking soda solution is 30 minutes to 60 minutes.

(高圧処理工程)
ここで、高圧処理とは、水を圧力媒体として高い静水圧(100MPa〜500MPa程度の圧力)を食肉に与える加工法である。この高圧処理は、加熱処理とは異なり、共有結合は開裂せず、栄養成分の損失や異臭・異常物質の発生がないという特徴がある。この高圧処理には、ピストンで圧力容器を直接加圧する直接加圧式の装置と圧力容器内にポンプで水を送る間接加圧式の装置を用いることができる。高圧処理工程S2によって食肉の保水性が向上するとともに、食肉組織の緻密化が促進されるといった効果が得られる。
(High pressure treatment process)
Here, the high-pressure treatment is a processing method that applies high hydrostatic pressure (pressure of about 100 MPa to 500 MPa) to meat using water as a pressure medium. Unlike the heat treatment, this high-pressure treatment is characterized in that the covalent bond is not cleaved, and no loss of nutritional components or generation of off-flavors or abnormal substances occurs. For this high-pressure treatment, a direct pressurization type device that directly pressurizes the pressure vessel with a piston and an indirect pressurization type device that feeds water into the pressure vessel with a pump can be used. The high-pressure treatment step S2 improves the water retention of the meat, and the effect of promoting the densification of the meat tissue is obtained.

(重曹・高圧併用処理)
本発明では、上述したように、レトルト処理工程S4の前処理として、重曹浸漬工程S1と高圧処理工程S2とを併せて施すことになる。この併用処理によって、重曹浸漬工程S1と高圧処理工程S2との相乗効果が発揮される。言い換えれば、それぞれの工程S1,S2にて得られる利点を残しつつ、単独の処理のみ施した場合に生じる欠点を改善することができる。具体的には、食肉に対して、非常に大きな軟化、保水性の向上、及び組織の緻密化を達成するだけでなく、重曹浸漬工程S1に起因して発生した重曹風味も消失させることが可能となる。
(Baking soda / high pressure treatment)
In the present invention, as described above, the baking soda immersion step S1 and the high pressure treatment step S2 are performed together as the pretreatment of the retort treatment step S4. By this combined treatment, a synergistic effect of the baking soda immersion step S1 and the high pressure treatment step S2 is exhibited. In other words, it is possible to improve the disadvantages that occur when only a single process is performed while retaining the advantages obtained in the respective steps S1 and S2. Specifically, it can not only achieve a very large softening, improved water retention and densification of the meat, but also eliminate the baking soda flavor caused by the baking soaking step S1. It becomes.

(レトルト処理工程)
ここで、レトルト処理とは加圧加熱処理のことであり、具体的には、耐熱性容器中に食肉を充填・密封し、0.1MPa〜0.3MPa程度に加圧された環境下で105℃〜140℃の蒸気または熱水で数分〜60分間程度の湿熱加熱を施すことである。これにより、食中毒の原因となる細菌(例えば、ボツリヌス菌)の多くを殺菌できると同時に、食品の調理を兼ねて利用されている。このレトルト処理の実施には、バッチ式レトルト装置と連続式レトルト装置を用いることができる。
(Retort treatment process)
Here, the retort treatment is a pressure heat treatment. Specifically, the meat is filled and sealed in a heat-resistant container and pressed under an environment of about 0.1 MPa to 0.3 MPa. It is to perform wet heat heating for about several minutes to 60 minutes with steam or hot water of ℃ to 140 ℃. Thereby, many bacteria (for example, Clostridium botulinum) which cause food poisoning can be sterilized, and at the same time, they are used for cooking food. A batch retort device and a continuous retort device can be used for carrying out this retort treatment.

(重曹インジェクション工程)
図1(b)に本発明のもう一つの実施形態に係る製造方法の各工程を説明したフローチャートを示す。この実施形態では、最初の重曹インジェクション工程のみが、図1(a)を用いて説明した上述の実施形態と異なっている。その他の点は同様であるので、ここでは説明を省略する。
(Baking soda injection process)
FIG. 1B is a flowchart illustrating each process of the manufacturing method according to another embodiment of the present invention. In this embodiment, only the first baking soda injection process is different from the above-described embodiment described with reference to FIG. Since the other points are the same, the description is omitted here.

ここで、重曹インジェクション工程S11とは、注射器又は注射器と同等の働きをする装置によって、食肉に直接、重曹溶液を注入することである。これにより、所望量の重曹溶液を即座に食肉中に注入することができるため、上述した重曹浸漬工程S1で浸漬に必要とされる処理時間(待ち時間)を排除することができ、本発明の製造方法に要する作業時間を短縮することが可能になる。また、後述するように、その注入量若しくは濃度、又は高圧処理の圧力値を事前に設定することで、レトルト処理後の食肉の軟らかさを自由に調整することも可能となる。   Here, the baking soda injection process S11 is to inject the baking soda solution directly into the meat by a syringe or a device having the same function as the syringe. Thereby, since a desired amount of baking soda solution can be immediately poured into meat, the processing time (waiting time) required for soaking in the baking soda soaking step S1 described above can be eliminated. It is possible to reduce the work time required for the manufacturing method. As will be described later, the softness of the meat after the retort treatment can be freely adjusted by setting the injection amount or concentration or the pressure value of the high-pressure treatment in advance.

また、重曹インジェクション工程S11を使用する場合は、上述したように、食肉への重曹溶液の注入量を正確かつ容易に調整できるため、以下に示す予備分析工程と、食感パラメータ決定工程と、を事前に行うようにしても良い。   In addition, when using the baking soda injection step S11, as described above, since the amount of sodium bicarbonate solution injected into the meat can be adjusted accurately and easily, the preliminary analysis step and the texture parameter determination step shown below are performed. It may be performed in advance.

(予備分析工程)
先ず、重曹溶液の濃度及び注入量と圧力(これらのパラメータを以下、食感決定パラメータとも呼ぶ。)と、レトルト処理工程後の食肉の軟化特性(例えば、破断応力、水分含有量、重量減少率)と、の関係を予め算出する予備分析工程(S101)を行う(図1(b)を参照)。この工程S101では、例えば、重曹溶液の濃度と高圧処理の圧力を0.3M〜0.4Mと300MPa〜400MPaに設定しておき、食肉への重曹溶液の注入量のみを変化(例えば、食肉との相対的な重量の割合を変化)させて、レトルト処理工程S4後の食肉の軟化特性(例えば、破断応力)を逐次取得する。これらのデータを分析することにより、その相関関係(例えば、注入量と破断応力との検量線(校正曲線))を求めておく。なお、上述の例に限らず、濃度と注入量、圧力の全てを網羅的に変化させて、種々の関係を分析・取得するようにしてもよい。
(Preliminary analysis process)
First, the concentration and the injection amount and pressure of the baking soda solution (these parameters are also referred to as texture determination parameters hereinafter) and the softening characteristics of the meat after the retort treatment process (for example, breaking stress, moisture content, weight loss rate) ) And a preliminary analysis step (S101) for calculating in advance (see FIG. 1B). In this step S101, for example, the concentration of the baking soda solution and the pressure of the high pressure treatment are set to 0.3 M to 0.4 M and 300 MPa to 400 MPa, and only the injection amount of the baking soda solution into the meat is changed (for example, meat and The ratio of the relative weight of the meat is changed), and the meat softening characteristics (for example, breaking stress) after the retort processing step S4 are sequentially acquired. By analyzing these data, a correlation (for example, a calibration curve (calibration curve) between the injection amount and the breaking stress) is obtained. Note that the present invention is not limited to the above example, and all of the concentration, the injection amount, and the pressure may be changed comprehensively to analyze and acquire various relationships.

(食感パラメータ決定工程)
次に、この予備算出工程S101で得られた上述の相関関係から、実際の製造段階での重曹インジェクション工程S11での重曹溶液の濃度及び注入量と高圧処理工程S2での圧力(食感決定パラメータ)を決定する(食感決定工程S102)。これにより、実際の製造段階でのレトルト処理工程S4後の食肉に対して所望の軟化具合や保水性を決定することが可能となる。例えば、予備分析工程S101で得られた、重曹溶液の注入量とレトルト処理肉の破断応力との校正曲線から、所望の破断応力(軟化具合)となるよう、これに対応する注入量を決定することが挙げられる。
(Food texture parameter determination process)
Next, from the above correlation obtained in the preliminary calculation step S101, the concentration and injection amount of the sodium bicarbonate solution in the sodium bicarbonate injection step S11 in the actual production stage and the pressure (texture determination parameter) in the high pressure treatment step S2 ) Is determined (texture determination step S102). Thereby, it becomes possible to determine a desired softening condition and water retention for the meat after the retort processing step S4 in the actual manufacturing stage. For example, the injection amount corresponding to this is determined from the calibration curve of the injection amount of the baking soda solution and the break stress of the retorted meat obtained in the preliminary analysis step S101 so that the desired break stress (softening degree) is obtained. Can be mentioned.

これらの予備的かつ分析的な工程S101,S102を予め踏まえておくことにより、レトルト処理後の肉の食感を適切に調整することができる。例えば、レトルト処理肉を高齢者向けに軟らくしたり、若者向けにやや歯応えのある軟化具合にしたりと、処理肉の軟化具合に微調整をすることができ、軟化具合や保水性の面からレトルト食品の品揃えを増加することに貢献できるものと期待される。   By considering these preliminary and analytical steps S101 and S102 in advance, the texture of the meat after the retort treatment can be adjusted appropriately. For example, retort-treated meat can be softened for elderly people, or softened for young people, and the softness of the processed meat can be fine-tuned from the standpoint of softening and water retention. It is expected to contribute to increasing the retort food lineup.

次に本発明の具体的な実施例について説明する。   Next, specific examples of the present invention will be described.

(試料肉の調整)
後述の実施例1、実施例2、及び、比較例1〜3においては、以下の方法で調整された試料肉を出発原料として使用した。すなわち、生の輸入牛肉の塊(オーストラリア産牛肉の外腿部位)を用い、表面の脂肪分を取り除いてボックス状に成形し、筋原線維と平行に切断し、縦5cm×横15cm×厚さ1cmの大きさに切断したものを試料とした。
(Adjustment of sample meat)
In Example 1, Example 2, and Comparative Examples 1 to 3 described later, sample meat prepared by the following method was used as a starting material. That is, using a lump of raw imported beef (Australian beef outer thigh part), removing the fat on the surface, forming it into a box shape, cutting it parallel to the myofibrils, length 5cm x width 15cm x thickness A sample cut to a size of 1 cm was used as a sample.

(実施例1 重曹浸漬処理と高圧処理とを組合せた試料肉の調製)
浸漬用包材袋に試料肉とともに濃度0.1M〜0.5M(より好ましくは濃度0.4M)に調整した重曹溶液200mlを加えて真空包装(脱気包装)し、20℃の恒温水槽中で30分間〜60分間(より好ましくは40分間)浸漬した(重曹浸漬工程S1)。次いで、浸漬用包材袋から試料肉を取り出し、真空調理用包材袋に入れて真空包装し、100MPa〜500MPa(より好ましくは400MPa)の静水圧(20℃)で10分間処理した(高圧処理工程S2)。工程S2後直ちに、試料肉を真空包装した包材袋を80℃に調整した恒温水槽に入れて30分間加熱を行い、さらに氷水中に入れて試料肉の内部温度が20℃になるまで冷却して加工肉Pを得た(加熱冷却工程S3)。なお、各図及び以下の明細書において、実施例1に対応する符号はPと表示する。さらに、工程2で付与した圧力値を識別する場合には、Pt_100、Pt_200、Pt_300、Pt_400、Pt_500等と表示する(以下の比較例等においても同様の表記とする)。
(Example 1 Preparation of sample meat combining baking soda immersion treatment and high pressure treatment)
200 ml of baking soda solution adjusted to a concentration of 0.1M to 0.5M (more preferably a concentration of 0.4M) together with the sample meat is added to the packaging bag for immersion, and vacuum packaging (deaeration packaging) is performed in a constant temperature water bath at 20 ° C. For 30 minutes to 60 minutes (more preferably 40 minutes) (sodium bicarbonate immersion step S1). Next, the sample meat is taken out from the packaging bag for immersion, placed in a packaging bag for vacuum cooking, vacuum packaged, and treated at a hydrostatic pressure (20 ° C.) of 100 MPa to 500 MPa (more preferably 400 MPa) for 10 minutes (high pressure treatment). Step S2). Immediately after step S2, the packaging bag in which the sample meat is vacuum packaged is placed in a constant temperature water bath adjusted to 80 ° C., heated for 30 minutes, and further cooled in ice water until the internal temperature of the sample meat reaches 20 ° C. Thus, processed meat Pt was obtained (heating and cooling step S3). In each figure and the following specification, the symbol corresponding to Example 1 is denoted as Pt . Furthermore, when identifying the pressure value applied in step 2, it is displayed as P t — 100 , P t — 200 , P t — 300 , P t — 400 , P t — 500, etc. (the same notation is used in the following comparative examples).

(比較例1 重曹浸漬処理と高圧処理とのいずれの処理も施さない輸入牛肉(未処理肉))
比較例1として、実施例1で説明した重曹浸漬工程S1の重曹に替えて、純水(脱塩水)に工程S1と同様の手順で浸漬し、その後、加熱冷却工程S3を施しただけの(つまり、重曹浸漬処理と高圧処理とのいずれの処理も施さない)未処理肉Cを用意した。なお、各図及び以下の明細書において、比較例1に対応する符号はCと表示する。つまり、比較例1の未処理肉Cは大気圧(0.1MPa)の下で調整されている。
(Comparative Example 1 Imported beef (untreated meat) without any treatment of baking soda soaking and high pressure treatment)
As Comparative Example 1, instead of the baking soda in the baking soda immersing step S1 described in Example 1, it was immersed in pure water (demineralized water) in the same procedure as in the step S1, and then the heating and cooling step S3 was performed ( In other words, untreated meat Co was prepared, in which neither sodium bicarbonate dipping treatment nor high pressure treatment was applied. In the drawings and following specification, reference numerals corresponding to Comparative Example 1 is indicated as C o. That is, the untreated meat Co of Comparative Example 1 is adjusted under atmospheric pressure (0.1 MPa).

(比較例2 高圧処理のみを施した試料肉の調整)
また、比較例2として、比較例1と同様に試料肉を純水(脱塩水)に浸漬した後、100MPa〜500MPa(より好ましくは400MPa)の高圧処理工程S2及び加熱冷却工程S3を施したものを用意した。なお、各図及び以下の明細書において、比較例2に対応する符号はPと表示する。
(Comparative Example 2 Preparation of sample meat subjected to high pressure treatment only)
As Comparative Example 2, the sample meat was immersed in pure water (demineralized water) in the same manner as in Comparative Example 1, and then subjected to a high pressure treatment step S2 and a heating and cooling step S3 of 100 MPa to 500 MPa (more preferably 400 MPa). Prepared. In each figure and the following specification, a symbol corresponding to Comparative Example 2 is denoted as Po .

(比較例3 重曹浸漬処理のみを施した試料肉の調整)
また、比較例3として、実施例1と同様な重曹浸漬処理(工程S1)を試料肉に施し、その後は、実施例1で説明した高圧処理工程S2を施さずに加熱冷却工程S3を施しただけのものを用意した。なお、各図及び以下の明細書において、比較例3に対応する符号はCと表示する。
(Comparative Example 3 Preparation of sample meat subjected to baking soda immersion treatment only)
Moreover, as comparative example 3, the baking soda immersion process (process S1) similar to Example 1 was applied to the sample meat, and then the heating and cooling process S3 was performed without performing the high-pressure treatment process S2 described in Example 1. I just prepared something. In the drawings and following specification, reference numerals corresponding to Comparative Example 3 displays a C t.

上述の実施例1及び比較例1〜3の処理の違い(各工程S1〜S4の有無)が視覚的にも分かり易くなるよう、以下の表1を示す。   The following Table 1 is shown so that the difference in processing between the above-described Example 1 and Comparative Examples 1 to 3 (presence or absence of each step S1 to S4) can be easily understood visually.

(各試料肉の物性(軟化特性)の評価)
上述のように調整した各試料肉P,C,P,Cの軟化特性を評価するため、くさび型のプランジャーによって、10mm/secの速度で破断させた際の試料肉の破断応力(N/m)を測定した(図2(a)を参照)。いずれの試料肉も処理圧力が高くなるに伴って破断圧力は低下し、また重曹・高圧併用処理した実施例1である試料肉Pt_100〜Pt_500では更なる軟化効果が得られた。特に300MPaと400MPaで高圧処理した場合に軟化特性に与える影響が大きく、未処理肉Cに比べ、50%以上の軟化がみられた。
(Evaluation of physical properties (softening properties) of each sample meat)
In order to evaluate the softening characteristics of the sample meats P t , C o , P o , and C t adjusted as described above, the sample meat was broken when it was broken at a speed of 10 mm / sec by a wedge-shaped plunger. Stress (N / m 2 ) was measured (see FIG. 2 (a)). In any of the sample meats, the breaking pressure decreased as the processing pressure increased, and in the sample meats P t — 100 to P t — 500 of Example 1, which were treated with sodium bicarbonate and high pressure, a further softening effect was obtained. Particularly large influence on the softening properties when high-pressure treatment at 300MPa and 400 MPa, as compared to untreated meat C o, was observed softening of 50% or more.

(各試料肉の軟化特性と保水性との相関関係)
また、重曹高圧処理による肉の保水性を比較評価するために各試料肉の水分含有量(%)を測定した。この結果、図2(b)に示すように、重曹処理(S1)後に高圧処理(S2)を施すことにより、水分含有量が増加し、特に300MPaと400MPaの高圧処理で保水性が大きく向上させることができた(p<0.05)。このことから、硬い輸入牛肉に対し重曹処理(S1)と高圧処理(S2)を併用することにより、非常に大きな軟化や保水性の向上がみられた。
(Correlation between softening characteristics and water retention of each sample meat)
In addition, the moisture content (%) of each sample meat was measured in order to compare and evaluate the water retention of the meat by the baking soda high pressure treatment. As a result, as shown in FIG. 2 (b), the water content is increased by performing the high pressure treatment (S2) after the baking soda treatment (S1), and the water retention is greatly improved particularly by the high pressure treatment of 300 MPa and 400 MPa. (P <0.05). From this fact, very large softening and improvement in water retention were observed by using sodium bicarbonate treatment (S1) and high pressure treatment (S2) in combination with hard imported beef.

(レトルト処理)
次に、未処理C、重曹処理(S1 濃度は0.4M)のみ、高圧処理のみ(圧力は300MPa)、上述の重曹処理S1および高圧処理S2を併用した4種類の試料肉C,Po_300,C,Pt_300について、レトルト処理(工程S4)への影響を検討した。レトルト処理(S4)の処理条件は、120℃、30分間とした。
(Retort processing)
Next, untreated C o, baking soda process (S1 concentration 0.4 M) only, high-pressure treatment alone (pressure 300 MPa), above 4 kinds of combination of sodium bicarbonate processing S1 and the high-pressure process S2 of the sample meat C o, P o_300, C t, the P t_300, and evaluating the effect of the retorting (step S4). The processing conditions of the retort process (S4) were 120 ° C. and 30 minutes.

(レトルト処理後の試料肉の軟化特性)
図3に、上述の軟化特性の評価と同様の方法で測定した各レトルト処理肉C,Po_300,C,Pt_300の破断応力(N/m)を示す。この図3より、重曹・高圧処理(S1,S2)を行わずレトルト処理(S4)した未処理肉Cに比べ、重曹処理(S1)後に直ぐにレトルト処理(S4)した肉C、または重曹処理(S1)を施さずに高圧処理(S2)のみを施した後にレトルト処理(S4)した試料肉Po_300は、破断応力の数値が比較的に低く、特に重曹処理と高圧処理を併用後にレトルト処理した加工肉Pt_300では、他の試料肉C,Po_300,Cに比べ、最も破断応力の数値が有意に低かった。
(Softening characteristics of sample meat after retort treatment)
FIG. 3 shows the rupture stress (N / m 2 ) of each retort-treated meat C o , P o — 300 , C t , P t — 300 measured by the same method as the evaluation of the softening characteristics described above. From this Figure 3, as compared to untreated meat C o which retorting (S4) and without sodium bicarbonate-pressure processing (S1, S2), baking soda process (S1) immediately retorted after (S4) meat C t or sodium bicarbonate, The sample meat Po_300 , which was retorted (S4) after being subjected only to the high pressure treatment (S2) without being subjected to the treatment (S1), has a relatively low value of the breaking stress, and in particular, the retort after the combined use of sodium bicarbonate treatment and high pressure treatment. the treated processed meat P t_300, other samples meat C o, P o_300, compared with C t, value of the most fracture stress was significantly lower.

(レトルト処理後の試料肉の保水性と重量減少)
また、図4(a)と図4(b)にレトルト処理(S4)後の各試料肉C,Po_300,C,Pt_300の水分含有量(%)と重量減少率(%)を示す。図4(a)から、重曹処理(S1)単独或いは重曹処理(S1)と高圧処理(S2)を併用した試料肉C,Pt_300が、その他の試料肉C,Po_300に比べて、水分含有量の数値が有意に高かった。また、図4(b)から、重量減少率は、未処理肉C、高圧処理(S2)のみ施した肉Po_300、重曹処理(S1)のみ施した肉C、高圧・重曹併用処理(S1,S2)を施した肉Pt_300の順に、低かった。
(Water retention and weight reduction of sample meat after retort treatment)
4 (a) and 4 (b) show the moisture content (%) and the weight reduction rate (%) of each sample meat C o , P o — 300 , C t , P t — 300 after the retort processing (S4). Show. From FIG. 4 (a), the sample meat C t , P t — 300 using the baking soda treatment (S1) alone or the sodium bicarbonate treatment (S1) and the high pressure treatment (S2) in comparison with the other sample meats C o , P o — 300 The value of moisture content was significantly higher. Further, from FIG. 4 (b), the weight reduction rate, untreated meat C o, high-pressure treatment (S2) only subjected meat P O_300, baking soda process (S1) only subjected meat C t, the high-pressure-sodium bicarbonate combined treatment ( It was low in order of meat Pt_300 which gave S1, S2).

(人の咀嚼運動に及ぼす影響)
さらに、各試料肉を実際に人に食べてもらい、その時の咀嚼運動を評価した。具体的には、試食を行う人の左右の咬筋の部位に電極を貼り付け、嚥下終了までの咀嚼中の筋電位を測定した。測定装置にはパワーラブシステム4/25T(AD Instruments社製)を利用した。
(Influence on human chewing movement)
Furthermore, each sample meat was actually eaten by a person, and the chewing movement at that time was evaluated. Specifically, electrodes were attached to the left and right masseter muscles of the person performing the tasting, and the myoelectric potential during mastication until the end of swallowing was measured. The power lab system 4 / 25T (made by AD Instruments) was utilized for the measuring apparatus.

上記測定によって得られた筋電図から、嚥下までの咀嚼回数(図5(a)を参照)、咀嚼時間(図5(b)を参照)、総筋活動量(図5(c)を参照)、及び一回平均咀嚼時の筋活動量(図5(d)を参照)を導出・分析した。これらのどの分析結果をみても、高圧・重曹併用処理(S1,S2)を施した肉Pt_300が他の比較例1〜3の試料肉C,Po_300,Cに比べて、顕著に低下しており、本発明の製造方法で処理したレトルト牛肉Pt_300が咀嚼し易く、飲みこみ易いものとなっていることが判明した。 From the electromyogram obtained by the above measurement, the number of chewing times until swallowing (see FIG. 5A), the chewing time (see FIG. 5B), and the total muscle activity (see FIG. 5C) ), And the amount of muscle activity during one average mastication (see FIG. 5D) was derived and analyzed. In any of these analysis results, the meat P t — 300 subjected to the combined treatment with high pressure and baking soda (S 1, S 2) is significantly more than the sample meats C o , P o — 300 , C t of the other comparative examples 1 to 3. It has been found that the retort beef Pt_300 processed by the production method of the present invention is easy to chew and swallow.

以上の評価結果から、レトルト処理の前処理として重曹・高圧併用処理(S1,S2)を行うことにより、レトルト処理後の牛肉の軟化効果、保水性及び飲みこみ易さの向上が認められ、その結果として牛肉の食感や食べ易さの向上につながることが期待される。   From the above evaluation results, by performing baking soda / high pressure combined treatment (S1, S2) as pretreatment for retort treatment, beef softening effect, water retention and ease of swallowing after retort treatment are recognized, and the results As a result, it is expected to improve the texture and ease of eating of beef.

(実施例2 重曹インジェクション処理と高圧処理とを組合せた試料肉の調製)
注射針を使って、濃度0.1〜0.5M(より好ましくは濃度0.4M)に調整した重曹溶液を試料肉(上記実施例1と同様に調整)に注入した(重曹インジェクション工程S11)。なお、重曹溶液の注入量は、試料肉の重量に対して重曹溶液の重量が13%〜25%に相当する分量とした。次いで、試料肉を真空調理用包材袋に入れて真空包装し、300MPaの静水圧(20℃)で10分間処理した(高圧処理工程S2)。工程S2後直ちに、試料肉を真空包装した包材袋を80℃に調整した恒温水槽に入れて30分間加熱を行い、さらに氷水中に入れて試料肉の内部温度が20℃になるまで冷却した(加熱冷却工程S3)。その後、121℃及び30分間の条件でレトルト処理を施し(レトルト処理工程S4)、加工肉Pt_300を得た。
(Example 2 Preparation of sample meat combining sodium bicarbonate injection treatment and high pressure treatment)
Using an injection needle, a baking soda solution adjusted to a concentration of 0.1 to 0.5M (more preferably a concentration of 0.4M) was injected into the sample meat (adjusted in the same manner as in Example 1 above) (Baking soda injection step S11). . In addition, the injection amount of the sodium bicarbonate solution was an amount corresponding to the weight of the sodium bicarbonate solution corresponding to 13% to 25% with respect to the weight of the sample meat. Next, the sample meat was put into a packaging bag for vacuum cooking and vacuum-packed, and treated with a hydrostatic pressure of 300 MPa (20 ° C.) for 10 minutes (high pressure treatment step S2). Immediately after step S2, the packaging bag in which the sample meat is vacuum-packed is placed in a thermostatic water bath adjusted to 80 ° C., heated for 30 minutes, and further cooled in ice water until the internal temperature of the sample meat reaches 20 ° C. (Heating and cooling step S3). Then, the retort process was performed on the conditions of 121 degreeC and 30 minutes (retort process process S4), and processed meat Pt_300 was obtained.

(比較例4 重曹インジェクション処理のみを施した試料肉の調製)
比較例4として、上述した重曹インジェクション工程S11のみを試料肉に施し、上述の高圧処理工程S2を施さずに、上述の加熱冷却工程S3を施して、加工肉Cを得た。
(Comparative Example 4 Preparation of sample meat subjected to baking soda injection treatment only)
As Comparative Example 4, only the baking soda injection step S11 described above was applied to the sample meat, and the above-described heating and cooling step S3 was performed without performing the above-described high-pressure treatment step S2, thereby obtaining processed meat Ct .

(試料肉の物性(軟化特性)の評価)
上述の実施例2及び比較例4での加工肉Pt_300,Cの破断応力を上述の実施例1で説明した測定方法と同様な方法で評価した。これらの測定結果を図6(a)に示す。なお、図中の実施例2の加工肉Pt_300は重曹溶液の注入量が試料肉重量の25%のときの測定値である。また、図6(a)には、実施例1、比較例1、比較例3での加工肉Pt_300,C,Cも併せて表示した。これにより、本実施例2の加工肉は、浸漬処理S1を適用した実施例1の加工肉よりさらに軟化特性が向上していることが判明した。つまり、重曹インジェクション工程S11の方が、重曹溶液をより確実に試料肉に注入でき、重曹処理の効果を発揮させることができることが分かった。
(Evaluation of physical properties (softening properties) of sample meat)
The breaking stresses of the processed meats P t — 300 and C t in Example 2 and Comparative Example 4 described above were evaluated by the same method as the measurement method described in Example 1 above. These measurement results are shown in FIG. In addition, the processed meat Pt_300 of Example 2 in the figure is a measured value when the injection amount of the baking soda solution is 25% of the sample meat weight. In FIG. 6A , the processed meats P t — 300 , C o , and C t in Example 1, Comparative Example 1, and Comparative Example 3 are also displayed. Thereby, it turned out that the processed meat of the present Example 2 has further improved softening characteristics as compared with the processed meat of Example 1 to which the immersion treatment S1 is applied. That is, it was found that the baking soda injection step S11 can more reliably inject the baking soda solution into the sample meat and can exert the effect of the baking soda treatment.

(インジェクション量が軟化特性に及ぼす影響の評価)
実施例2及び比較例1の加工肉にレトルト処理(工程S4)を施して、各加工肉の破断応力を測定した。図6(b)に、重曹溶液のインジェクション量が試料肉の破断応力(軟化特性)に及ぼす影響を示す。この図6(b)より、インジェクション量が増加すると破断応力は徐々に低下し、特にインジェクション量が20%を超えると、未処理肉(比較例1の試料肉C)に比べて、破断応力は半分以下になっていることが判明した。なお、破断応力は上記インジェクション量の他に、重曹溶液の濃度や高圧処理の圧力値によっても変化し得ることが考えられる。
(Evaluation of the effect of injection volume on softening properties)
The processed meat of Example 2 and Comparative Example 1 was subjected to retort processing (step S4), and the breaking stress of each processed meat was measured. FIG. 6B shows the influence of the injection amount of the baking soda solution on the breaking stress (softening property) of the sample meat. From FIG. 6 (b), when the injection amount increases, the rupture stress gradually decreases. In particular, when the injection amount exceeds 20%, the rupture stress is greater than that of untreated meat (sample meat Co in Comparative Example 1). Turned out to be less than half. In addition, it is considered that the breaking stress can be changed depending on the concentration of the baking soda solution and the pressure value of the high pressure treatment in addition to the above injection amount.

従って、重曹溶液の濃度及びインジェクション量と圧力値が軟化特性に及ぼす相関関係を予備的に導出しておけば(工程S101)、この相関関係から所望の濃度、インジェクション量や圧力値を決定し(工程S102)、レトルト処理後の食肉を所望の軟化具合に制御することも可能となると考えられる。   Therefore, if the correlation between the concentration and the injection amount of the sodium bicarbonate solution and the pressure value on the softening characteristics is derived in advance (step S101), the desired concentration, injection amount and pressure value are determined from this correlation ( It is thought that it becomes possible to control the meat after process S102) and a retort process to desired softening condition.

(人の咀嚼運動に及ぼす影響)
実施例2の加工肉Pにおいても、実施例1で説明した方法と同様の方法で、人の咀嚼運動に及ぼす影響を評価した。この測定によって得られた筋電図から、嚥下までの咀嚼回数(図7(a)を参照)、咀嚼時間(図7(b)を参照)、総筋活動量(図7(c)を参照)、及び一回平均咀嚼時の筋活動量(図7(d)を参照)を導出・分析した。これらのどの分析結果をみても、実施例2の加工肉Pt_300の値が比較例1の未処理肉Cの値に比べて、顕著に低下しており、実施例2で処理したレトルト牛肉Pt_300が咀嚼し易く、飲みこみ易いものとなっていることが判明した。
(Influence on human chewing movement)
Also in processed meat P t of Example 2, in a manner similar to that described in Example 1 to evaluate the effect on chewing movements of people. From the electromyogram obtained by this measurement, the number of mastications until swallowing (see FIG. 7 (a)), mastication time (see FIG. 7 (b)), total muscle activity (see FIG. 7 (c)) ), And the amount of muscle activity during one average mastication (see FIG. 7D) was derived and analyzed. Looking at how the analysis results of these, the value of the processed meat P T_300 of compared to the value of raw meat C o Comparative Example 1 Example 2 has significantly decreased, retort beef treated with Example 2 It was found that Pt_300 is easy to chew and swallow.

(実施例3 重曹・高圧併用処理及びレトルト処理を施した肉で調理したレトルト食品)
実施例3として、実施例1で加工された加工肉Pを使用してレトルトビーフカレーを実際に調理した。また、比較例5として、比較例1の肉Cを使用してレトルトビーフカレーを実際に調理した。なお、実施例3及び比較例5の製造方法の以下に詳しく説明する。
(Example 3 Retort food cooked with meat subjected to baking soda / high pressure combined treatment and retort treatment)
Example 3 was actually cooked retort beef curry using processed meats P t which is processed in Example 1. Further, as Comparative Example 5, a retort beef curry was actually cooked using the meat Co of Comparative Example 1. The production methods of Example 3 and Comparative Example 5 will be described in detail below.

(実施例3 レトルトカレーの製造)
オーストラリア産牛外もも肉のブロックを原料として、インジェクション装置を用い、食塩0.5%、重曹0.4Mの混合溶液を肉重量に対して21%(−2%〜+2%の範囲内)となるようにインジェクションを行った(工程S11)。次いで、ポリエチレンバックに入れて真空包装を行い、300MPa、10分間の条件で高圧処理を行った後(工程S2)、重量8〜10gのコロ肉に切断し、ポリエチレンバックに入れ真空包装を行って80℃、30分間加熱後、直ちに冷水中で冷却した(工程S3)。
(Example 3 Production of retort curry)
Using Australian beef thigh block as a raw material, an injection device is used, and a mixed solution of 0.5% sodium chloride and 0.4M sodium bicarbonate is 21% (within a range of -2% to + 2%) of the meat weight. The injection was performed as described above (step S11). Next, it is put into a polyethylene bag and vacuum-packed. After high pressure treatment at 300 MPa for 10 minutes (step S2), it is cut into 8 to 10 g of coro meat and put into a polyethylene bag and vacuum-packed. After heating at 80 ° C. for 30 minutes, it was immediately cooled in cold water (step S3).

カレーは、タマネギ、ニンジン、ジャガイモをそれぞれ適度な大きさに切断し、市販の固形カレールウ、水を鍋に入れて加熱して予備調理を行い、前述の処理を行った牛外もも肉とともにレトルトパウチ用の包材に入れて脱気包装を行い、レトルト装置により120℃、30分間の条件で加熱調理を行った(工程S4)。   Curry cut onions, carrots and potatoes to a suitable size, pre-cooked by putting commercially available solid curry roux and water in a pan and heating them for the retort pouch together with the beef outside the above-mentioned treatment The packaging material was deaerated and subjected to heat cooking under the conditions of 120 ° C. and 30 minutes using a retort apparatus (step S4).

(比較例5 レトルトカレーの製造)
また、比較例5としてオーストラリア産牛外もも肉のブロックをインジェクション、及び高圧処理を行わず、重量8〜10gのコロ肉に切断し、加熱、冷却し、直接カレーの予備調理、レトルト処理を行ったものを製造した。
(Comparative Example 5 Production of Retort Curry)
Moreover, as a comparative example 5, an Australian beef cattle block was not injected and subjected to high-pressure treatment, but was cut into 8 to 10 g of coro meat, heated and cooled, and subjected directly to curry pre-cooking and retort treatment. Things were manufactured.

重曹処理(工程S11)、高圧処理(工程S2)、レトルト処理(工程S4)を行った実施例3のカレーの肉は、未処理の比較例5に比べ肉の収縮が抑えられ、図8に示すようにふっくらとした外観で、筋線維がばらばらにならずにまとまっており、軟かく美味しい食感のカレー肉が得られた。   The curry meat of Example 3 subjected to the baking soda treatment (step S11), the high pressure treatment (step S2), and the retort treatment (step S4) is suppressed in the shrinkage of the meat compared to the untreated comparative example 5, FIG. As shown in the figure, curry meat with a soft and delicious texture was obtained with a plump appearance and a collection of muscle fibers without being separated.

(官能評価の結果)
これらのレトルトビーフカレーに対して官能評価を行った。官能評価の評価方法として二点識別法を用いた。この評価を実施するパネルは、年齢が20代〜80代の健康な成人合計355名(内訳:男性274名、女性81名)から構成された。
(Result of sensory evaluation)
Sensory evaluation was performed on these retort beef curry. A two-point discrimination method was used as an evaluation method for sensory evaluation. The panel that performed this evaluation consisted of a total of 355 healthy adults aged 20 to 80 (breakdown: 274 men, 81 women).

図9(a)及び(b)に上述の官能評価の結果を示す。図9(a)に示すように、92%のパネルが実施例3のレトルトビーフカレーを美味しいと答えた。また、図9(b)に示すように、(1)美味しさ、(2)やわらかさ、(3)ジューシーさ、(4)飲み込み易さ、(5)残渣のなさ、のいずれの観点においても、実施例3のカレーの方が、比較例5のカレーに比べて、相対的に、評価が高い結果となった。   The result of the above-mentioned sensory evaluation is shown in Drawing 9 (a) and (b). As shown in FIG. 9 (a), 92% of the panels answered that the retort beef curry of Example 3 was delicious. In addition, as shown in FIG. 9B, in any of the viewpoints of (1) deliciousness, (2) softness, (3) juiciness, (4) ease of swallowing, and (5) no residue. The curry of Example 3 was relatively highly evaluated as compared with the curry of Comparative Example 5.

本発明の製造方法によれば、重曹・高圧併用処理をレトルト処理の前処理として行うために、重曹処理と高圧処理との相乗効果をレトルト処理後の食肉に与えることができる。具体的には、非常に大きな軟化、保水性の向上、組織の緻密化、及び重曹風味の消失といった様々な効果を食肉に与えることができる。この製造方法を用いれば、例えば、通常、極めて硬い輸入牛肉等でも、レトルト食品の食材として利用できる程に軟らかくなり、レトルト食品の食材の選択の幅が広がるとともにレトルト食品の原材料コストを下げることが可能となる。   According to the production method of the present invention, since the combined baking soda / high pressure treatment is performed as a pretreatment for the retort treatment, a synergistic effect of the baking soda treatment and the high pressure treatment can be imparted to the meat after the retort treatment. Specifically, various effects such as very large softening, improvement of water retention, densification of tissue, and disappearance of baking soda flavor can be given to meat. If this manufacturing method is used, for example, even extremely hard imported beef can be softened to the extent that it can be used as an ingredient for retort food, the range of choice of ingredients for retort food can be expanded, and the raw material cost of retort food can be reduced. It becomes possible.

以上のように、本発明の産業上の利用価値及び利用可能性は非常に高い。   As described above, the industrial utility value and applicability of the present invention are very high.

S1 重曹浸漬工程
S2 高圧処理工程
S3 加熱冷却工程
S4 レトルト処理工程
S11 重曹インジェクション工程
S101 予備分析工程
S102 食感パラメータ決定工程
S1 Sodium bicarbonate dipping process S2 High pressure treatment process S3 Heating and cooling process S4 Retort treatment process S11 Sodium bicarbonate injection process S101 Preliminary analysis process S102 Texture parameter determination process

Claims (7)

生の食肉を重曹溶液中に浸漬する重曹浸漬工程と、
前記食肉に100MPa〜500MPaの圧力を加える高圧処理工程と、
前記食肉にレトルト処理を施すレトルト処理工程と、
を含むことを特徴とする食肉入りレトルト食品の製造方法。
A baking soda immersing step of immersing raw meat in a baking soda solution;
A high-pressure treatment step of applying a pressure of 100 MPa to 500 MPa to the meat;
A retort treatment step of subjecting the meat to a retort treatment;
The manufacturing method of the retort food containing meat characterized by including.
前記重曹溶液の濃度が0.1M〜0.5Mであり、該重曹溶液中への前記食肉の浸漬時間が30分間〜60分間であることを特徴とする請求項1に記載の食肉入りレトルト食品の製造方法。   The retort food containing meat according to claim 1, wherein the concentration of the baking soda solution is 0.1M to 0.5M, and the immersion time of the meat in the baking soda solution is 30 minutes to 60 minutes. Manufacturing method. 生の食肉に重曹溶液を注入する重曹インジェクション工程と、
前記食肉に100MPa〜500MPaの圧力を加える高圧処理工程と、
前記食肉にレトルト処理を施すレトルト処理工程と、
を含むことを特徴とする食肉入りレトルト食品の製造方法。
A baking soda injection process in which a baking soda solution is poured into raw meat,
A high-pressure treatment step of applying a pressure of 100 MPa to 500 MPa to the meat;
A retort treatment step of subjecting the meat to a retort treatment;
The manufacturing method of the retort food containing meat characterized by including.
前記重曹溶液の濃度及び注入量と前記圧力と、前記レトルト処理工程後の前記食肉の物性と、の関係を予め算出する予備分析工程と、
前記予備分析工程で得られた前記関係から、前記重曹インジェクション工程及び前記高圧処理工程における前記重曹溶液の前記濃度及び前記注入量と前記圧力とを決定する食感パラメータ決定工程と、
をさらに含むことを特徴とする請求項3に記載の食肉入りレトルト食品の製造方法。
A preliminary analysis step of calculating in advance the relationship between the concentration and injection amount of the sodium bicarbonate solution and the pressure, and the physical properties of the meat after the retort treatment step;
From the relationship obtained in the preliminary analysis step, the texture parameter determination step for determining the concentration and the injection amount and the pressure of the sodium bicarbonate solution in the sodium bicarbonate injection step and the high pressure treatment step,
The method for producing a retort food containing meat according to claim 3, further comprising:
前記圧力が300MPa〜400MPaであることを特徴とする請求項1〜4のいずれかに記載の食肉入りレトルト食品の製造方法。   The said pressure is 300MPa-400MPa, The manufacturing method of the retort food containing meat in any one of Claims 1-4 characterized by the above-mentioned. 前記高圧処理工程と前記レトルト処理工程との間に、前記食肉を加熱した後に冷却する加熱冷却工程をさらに含むことを特徴とする請求項1〜5のいずれかに記載の食肉入りレトルト食品の製造方法。   The manufacturing of the meat-containing retort food according to any one of claims 1 to 5, further comprising a heating and cooling step of cooling the meat after heating the high-pressure treatment step and the retort treatment step. Method. 前記重曹溶液の濃度が0.3M〜0.4Mであり、前記圧力が300MPa〜400MPaであり、前記食肉への該重曹溶液の注入量を前記食肉の重量の10%〜25%に相当する重量を有した分量であることを特徴とする請求項3〜6のいずれかに記載の食肉入りレトルト食品の製造方法。   The concentration of the baking soda solution is 0.3 M to 0.4 M, the pressure is 300 MPa to 400 MPa, and the amount of injection of the baking soda solution into the meat is equivalent to 10% to 25% of the weight of the meat The method for producing a retort food containing meat according to any one of claims 3 to 6, wherein the amount of the retort food contains meat.
JP2012213899A 2012-09-27 2012-09-27 Manufacturing method of meat-containing retort food Pending JP2014064542A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
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JP2018057358A (en) * 2016-09-29 2018-04-12 テーブルマーク株式会社 Agent for improving water holding ability of food product under pressure and use thereof
WO2020031401A1 (en) * 2018-08-07 2020-02-13 ポッカサッポロフード&ビバレッジ株式会社 Method for producing dried meat
JP2020061959A (en) * 2018-10-16 2020-04-23 ポッカサッポロフード&ビバレッジ株式会社 Production method of dry meat
JP2020096594A (en) * 2016-11-21 2020-06-25 ノルティンダル シー プロダクツ, エス.エル.Nortindal Sea Products, S.L. Sterilization method by heat treatment for preserving ink of coleoid cephalopod mollusk
WO2021090830A1 (en) * 2019-11-05 2021-05-14 東洋製罐株式会社 Method for producing food contained in container

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018057358A (en) * 2016-09-29 2018-04-12 テーブルマーク株式会社 Agent for improving water holding ability of food product under pressure and use thereof
JP2020096594A (en) * 2016-11-21 2020-06-25 ノルティンダル シー プロダクツ, エス.エル.Nortindal Sea Products, S.L. Sterilization method by heat treatment for preserving ink of coleoid cephalopod mollusk
WO2020031401A1 (en) * 2018-08-07 2020-02-13 ポッカサッポロフード&ビバレッジ株式会社 Method for producing dried meat
JP2020061959A (en) * 2018-10-16 2020-04-23 ポッカサッポロフード&ビバレッジ株式会社 Production method of dry meat
JP7241500B2 (en) 2018-10-16 2023-03-17 ポッカサッポロフード&ビバレッジ株式会社 Method for producing dried meat
WO2021090830A1 (en) * 2019-11-05 2021-05-14 東洋製罐株式会社 Method for producing food contained in container

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