WO2020031401A1 - Method for producing dried meat - Google Patents

Method for producing dried meat Download PDF

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Publication number
WO2020031401A1
WO2020031401A1 PCT/JP2018/045149 JP2018045149W WO2020031401A1 WO 2020031401 A1 WO2020031401 A1 WO 2020031401A1 JP 2018045149 W JP2018045149 W JP 2018045149W WO 2020031401 A1 WO2020031401 A1 WO 2020031401A1
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WO
WIPO (PCT)
Prior art keywords
meat
dried
baking soda
drying
treatment
Prior art date
Application number
PCT/JP2018/045149
Other languages
French (fr)
Japanese (ja)
Inventor
奈穂 中村
花子 佐藤
Original Assignee
ポッカサッポロフード&ビバレッジ株式会社
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Priority claimed from JP2018148734A external-priority patent/JP7241485B2/en
Priority claimed from JP2018194964A external-priority patent/JP7241500B2/en
Application filed by ポッカサッポロフード&ビバレッジ株式会社 filed Critical ポッカサッポロフード&ビバレッジ株式会社
Publication of WO2020031401A1 publication Critical patent/WO2020031401A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00General methods for preserving meat, sausages, fish or fish products
    • A23B4/02Preserving by means of inorganic salts
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B4/00General methods for preserving meat, sausages, fish or fish products
    • A23B4/03Drying; Subsequent reconstitution
    • A23B4/037Freeze-drying, i.e. cryodessication, lyophilisation; Apparatus therefor
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof

Definitions

  • the present invention relates to a method for producing dried meat.
  • Dried meat is used as an ingredient in instant dry foods such as instant soups, instant ramen, and tea pickles.
  • a method for producing dried meat include, for example, a method for producing a freeze-dried char shoe that is formed by molding a raw meat using a binder and then freeze-drying (Patent Literature 1), and improving the reflow of instant drying ingredients including meat raw materials.
  • Patent Document 2 a method of sandwiching a sheet-like material
  • Patent Document 3 a method of producing a dry food in which soybean protein is contained in a raw meat material
  • Dried animal meat may produce a deteriorating odor due to aging. It cannot be said that the means for suppressing this deterioration with time has been sufficiently studied in the past.
  • an object of the present invention is to provide a method for producing dried livestock meat in which deterioration over time is suppressed.
  • the present invention provides a method for producing dried meat, comprising a step of drying the meat that has been subjected to the immersion treatment, wherein the immersion treatment is a treatment of immersing the meat in a baking soda solution.
  • the production method according to the present invention includes immersing meat in a baking soda solution before drying, it is possible to produce dried meat with reduced deterioration over time (particularly generation of deterioration odor over time).
  • the dried meat obtained by the production method according to the present invention is excellent in both hot-water reversibility, softness (physical) after hot-water replenishment, and texture (softness, chewing response, juicy). ing.
  • the immersion treatment is preferably a treatment in which the meat is immersed in a baking soda solution under reduced pressure.
  • the (physical) softness after hot water can be improved more than in the case of performing under normal pressure, and the treatment time of the immersion treatment can be reduced. Even so, the effect of improving the hot water removability of the dried animal meat, the (physical) softness after hot water replenishment, and the texture can be sufficiently obtained.
  • the drying step is preferably a step of freeze-drying the meat that has been subjected to the immersion treatment. Thereby, the above-described effects are more remarkably exhibited.
  • the baking soda solution may have a baking soda concentration of 0.1 to 10% by weight. When the baking soda concentration is within this range, the above-mentioned effects can be sufficiently obtained.
  • the present invention can also be considered as a method for suppressing the deterioration of dried meat over time, which comprises a step of drying the meat immersed in the baking soda solution.
  • the present invention can further be regarded as a use (method) of using baking soda for suppressing the deterioration of dried meat with time, which comprises a step of immersing the meat with a baking soda solution before drying.
  • the present invention can be further regarded as an agent for suppressing deterioration of dried meat over time, which contains sodium bicarbonate as an active ingredient.
  • the present invention by immersing the meat in a baking soda solution before drying, it is possible to easily produce a dried meat in which deterioration with time (particularly generation of a deterioration odor with time) is suppressed.
  • the present invention by immersing the meat in a baking soda solution before drying, the deterioration with time is suppressed, and the hot water removability and the (physical) softness after hot water replenishment and the texture are improved. In each case, good dried animal meat can be easily produced.
  • the immersion treatment by performing the immersion treatment under reduced pressure, it is possible to easily obtain dried livestock meat with further improved hot water removability, softness (physical) after hot water replenishment, and texture. Further, the obtained dried meat can be returned by immersing in not only hot water (for example, hot water at 90 to 100 ° C.) but also water (for example, water at 28 ° C.) for about one minute. Therefore, the returned meat can be eaten even in an environment where the use of hot water is restricted, such as during a disaster.
  • hot water for example, hot water at 90 to 100 ° C.
  • water for example, water at 28 ° C.
  • the method for producing dried meat according to the present embodiment includes a step of drying the meat that has been subjected to the immersion treatment (hereinafter, also referred to as a “drying step”).
  • the manufacturing method according to the present embodiment may further include a step of performing immersion processing on the meat (hereinafter, also referred to as “immersion processing step”).
  • livestock means meat of livestock and poultry used for meat.
  • livestock meat include beef, pork, chicken, horse, sheep, goat, and duck.
  • Dried meat is obtained by drying meat, and usually has a water content of 10% by weight or less.
  • the water content of the dried meat is preferably 7.5% by weight or less, more preferably 5% by weight or less.
  • the moisture content of the dried meat can be measured using, for example, an infrared light moisture analyzer.
  • any of processed meat and unprocessed meat can be used.
  • the forming process means, for example, a process of mixing a plurality of types of meat and / or raw materials other than the meat to solidify, and a process of molding or laminating the meat into a specific shape.
  • the baking soda solution is a solution in which baking soda (sodium hydrogen carbonate) is dissolved in a solvent.
  • the solvent is not particularly limited as long as it can dissolve sodium bicarbonate, and examples thereof include water, lower alcohols (eg, alcohols having 1 to 3 carbon atoms), and mixed solutions thereof.
  • the baking soda solution is preferably an aqueous solution of baking soda.
  • the concentration of baking soda contained in the baking soda solution may be from 0.1 to 10% by weight based on the total amount of the baking soda solution.
  • the baking soda concentration is preferably from 0.5 to 5% by weight, more preferably from 1 to 4% by weight, and even more preferably from 1 to 3% by weight, based on the total amount of the baking soda solution.
  • the pH of the sodium bicarbonate solution may be, for example, 7.0 to 9.0.
  • the pH of the baking soda solution is in this range, the effect of the present invention can be more remarkably exhibited.
  • the immersion treatment may be a treatment of immersing the meat in a baking soda solution.
  • the immersion treatment is preferably a treatment in which the meat is immersed in a sodium bicarbonate solution under reduced pressure.
  • the meat to be immersed may be cut to an appropriate size according to the purpose.
  • livestock meat cut to a thickness of 1.5 cm or more, or a thickness of 2.0 to 4.0 cm may be used, a thickness of less than 1.5 cm, or a thickness of 0.3 to 1.
  • Livestock meat cut to 0 cm may be used.
  • thickness means the length or width of the shortest surface or curved surface of meat such as plate, block, or cube.
  • the amount of the baking soda solution to be used relative to the amount of the meat may be, for example, 50 to 300 parts by weight, preferably 75 to 200 parts by weight, and more preferably 100 to 150 parts by weight based on 100 parts by weight of the meat. More preferably, there is. Thereby, the effect of the present invention can be more remarkably exhibited.
  • the method of performing the immersion treatment under reduced pressure is not particularly limited as long as the immersion treatment can be performed in a state where a pressure lower than the atmospheric pressure is applied.
  • immersion treatment can be performed under reduced pressure by putting meat and baking soda solution into a pressure-resistant container equipped with a valve that can be sealed and opened, and reducing the pressure in the container with a vacuum pump.
  • the immersion treatment under reduced pressure can be performed using, for example, a vacuum kneader, a vacuum packaging machine, or the like.
  • the pressure at the time of performing the immersion treatment under reduced pressure may be a pressure lower than the atmospheric pressure.
  • the gauge pressure may be ⁇ 0.01 MPa or less, preferably ⁇ 0.03 MPa or less, and ⁇ 0 MPa or less. 0.05MPa or less, more preferably -0.06MPa or less, still more preferably -0.07MPa or less, and even more preferably -0.08MPa or less.
  • the lower limit of the pressure is not particularly limited, but may be, for example, -0.10 MPa.
  • the gauge pressure is a pressure when the atmospheric pressure is 0 MPa and the absolute vacuum is -0.101 MPa.
  • the immersion treatment is preferably performed for 1 hour or more, preferably for 3 hours or more, more preferably for 5 hours or more, more preferably for 10 hours or more, further preferably for 15 hours or more, and more preferably for 20 hours or more. Is even more preferred.
  • the longer the immersion time the better the reclaimed water and the (physical) softness and texture of the obtained dried animal meat after reconstitution.
  • the treatment time (at immersion time) required to achieve the same hot water removability, softness (physical) after hot water replenishment, and texture as compared with normal pressure. ) Can be shortened.
  • the temperature of the baking soda solution at the time of the immersion treatment is not particularly limited, and may be a room temperature range (eg, 18 to 28 ° C) or a refrigerated range (eg, about 4 to 10 ° C).
  • the temperature of the sodium bicarbonate solution at the time of the immersion treatment is preferably in a refrigerated region (for example, about 4 to 10 ° C.).
  • baking soda solution used for the immersion treatment components other than baking soda (eg, nutrients such as sugars, proteins, vitamins and minerals, seasoning compositions such as soy sauce and salt, spices) are used for the purpose of seasoning and / or softening of meat.
  • components other than baking soda eg, nutrients such as sugars, proteins, vitamins and minerals, seasoning compositions such as soy sauce and salt, spices
  • Amino acids, nucleic acids, thickeners, coloring agents, antioxidants and alcohols, and proteases are used for the purpose of seasoning and / or softening of meat.
  • the baking soda solution contains only baking soda, and components other than baking soda may be used in other steps as necessary.
  • seasoning after the immersion treatment, after the subsequent heat treatment, or after the drying treatment, to the extent that the effects of the present invention are not impaired, application of a seasoning liquid containing the above components, or spraying of a powder seasoning, etc. It can be performed.
  • the drying step is a step of drying the meat that has been immersed as described above.
  • the drying treatment can be performed according to a conventional method such as, for example, hot air drying, heat drying, freeze drying, and supercritical drying.
  • the drying treatment is preferably performed by freeze drying (freeze drying).
  • Freeze-drying can be performed, for example, by a method including a step of freezing the immersed meat (freezing step) and a step of removing water (ice) from the frozen meat under reduced pressure (removal step).
  • the freezing step may be, for example, air cooling of the immersed meat, followed by freezing at about ⁇ 20 ° C. to ⁇ 60 ° C. for 1 to 3 hours.
  • the removing step may be, for example, using a freeze dryer to freeze frozen meat to a water content of 10% by weight or less, preferably 7.5% by weight or less, more preferably 5% by weight or less.
  • a freeze dryer to freeze frozen meat to a water content of 10% by weight or less, preferably 7.5% by weight or less, more preferably 5% by weight or less.
  • Known freeze dryers can be used.
  • the freeze-drying condition by the freeze dryer is not particularly limited as long as the water content of the meat can be kept in the above range, and for example, the degree of vacuum is 0.8 torr (mmHg) or less, preferably 0.08 torr (mmHg) or less, more preferably. Is a condition in which the treatment is performed under a vacuum condition of 0.04 torr (mmHg) or less at a temperature setting according to the degree of vacuum for about 10 to 36 hours.
  • the meat that has been immersed may be subjected to a drying treatment as it is, or may be subjected to a heating treatment before the drying treatment.
  • a drying treatment as it is, or may be subjected to a heating treatment before the drying treatment.
  • the heat treatment include a steaming treatment (steam treatment), a boil treatment, and an oil conditioning treatment (frying treatment).
  • the heat treatment may be a combination of these treatments.
  • the steaming treatment is not limited to this.
  • steam having a temperature of 100 to 130 ° C. and a pressure of about 0.01 to 0.5 MPa is brought into contact with the dipped meat for about 30 seconds to 10 minutes.
  • the steaming treatment may be performed under closed conditions.
  • the oil-conditioning treatment is not limited to this, but can be performed, for example, by treating the immersed meat at 160 to 190 ° C. (normal pressure) for about 60 to 300 seconds.
  • the oil conditioning treatment may be performed under reduced pressure using a closed-type fryer or the like capable of reducing pressure.
  • the conditions under which the pressure is reduced may be set by appropriately adjusting the degree of vacuum, the temperature, the frying time, and the like so that the state is substantially the same as that in the case of performing the oil adjustment process at normal pressure.
  • the oil used in the oil preparation is not particularly limited.
  • various edible oils derived from animals and plants (soybean oil, rapeseed oil, rice oil, corn oil, palm oil, safflower oil, sunflower oil, lard and het, and the like) Or more mixed oils selected from the group consisting of:
  • raw meat ingredients such as bread crumbs may be added to the meat before the oil conditioning treatment.
  • the present invention described above can also be considered as a method for suppressing the deterioration of dried meat over time, which comprises a step of drying the meat immersed in the baking soda solution.
  • the use of baking soda to suppress the deterioration of dried meat over time can be considered as a use (method) including a step of immersing the meat with a baking soda solution before drying.
  • it can also be regarded as an agent for suppressing the deterioration of dried livestock meat over time, which contains baking soda as an active ingredient.
  • Each of the manufactured dried chicken breasts was put in an aluminum bag and stored in a thermostat at 37 ° C. After storage for 6 weeks and 15 weeks, the deterioration odor due to orthonasal was evaluated by sensory evaluation. Similarly, after storing for 15 weeks, the deterioration odor due to the retronasal was evaluated by sensory evaluation.
  • the sensory evaluation of the deterioration odor by the retro nasal was carried out by three selected panels.
  • the sensory evaluation was performed by keeping the samples refrigerated immediately after freeze-drying and maintaining the quality (dried chicken breasts) as a control (five points).
  • Table 3 shows the evaluation results.
  • Example 2 Hot water reversion test
  • the chicken breast was cut into cubes each having a side of 2.5 to 3 cm, and immersed in each of the solutions shown in Table 4 below for 20 hours (refrigerated).
  • the baking soda solution (pH 8.1) of Example 2 was prepared by a method of dissolving baking soda in cold water.
  • the baking soda solution (pH 8.7) of Example 3 was prepared by dissolving baking soda with hot water to generate sodium carbonate. After immersion, each chicken breast was taken out, heated with steam (steam) for 8 minutes, and freeze-dried under the same conditions as in Test Example 1 to obtain each dried chicken breast.
  • Each dried chicken breast produced was put in a cup, and hot water of 98 ° C. was poured from above, and after 1 minute, “hot water return” and “softness” were determined by the selected four panelists as follows. Sensory evaluation was performed based on criteria.
  • Hot water reversion comprehensively evaluated the degree of hot water permeation based on the following criteria. :: Hot water has sufficiently penetrated into the interior and good.
  • Table 5 shows the evaluation results.
  • Test sections 6 to 9 shown in Table 7 were immersed under reduced pressure. After 1 kg of the prepared chicken breast and 1 kg of each immersion liquid (water or sodium bicarbonate solution) shown in Table 7 were put in a vacuum polycarbonate desiccator, the inside of the desiccator was depressurized using a vacuum pump. When the vacuum pressure (gauge pressure) became -0.09 MPa, the vacuum pump was stopped and sealed, and the desiccator was put into a refrigerator (4 ° C.), and each immersion time shown in Table 7 (1 hour, 4 hours, 8 hours or 15 hours). The gauge pressure is a pressure when the atmospheric pressure is 0 MPa and the absolute vacuum is -0.101 MPa.
  • each chicken breast was taken out, heated with steam (steam) for 8 minutes, frozen, and freeze-dried (product of Kyowa Vacuum Engineering Co., Ltd .: Model RLE II-103) to obtain a vacuum degree.
  • the dried chicken breast was obtained by drying at 0.04 torr (mmHg) or less, at a temperature of 70 ° C. and a drying time of 26 hours.
  • the tenderness of the meat 1 very hard to bite 2: hard and hard to bite 3: neither neither 4: soft 5: very soft Meat bite response (elasticity, muscle feeling) 1: Strong bite response (hard enough to bite) 2: Responsive (hard) 3: Moderate chewing response (original meat's original chewing response (strain feeling)) 4: weak chewing response (slightly soft) 5: No chewing response (soft) Juicy (moisture) 1: Slightly sullen 2: Slightly sullen 3: Neither 4: Juicy 5: Very juicy
  • Dried meat (Dried chicken breast) in test categories 3 to 9 which had been subjected to a dipping treatment using a baking soda solution, had the hot water penetrated into the dried meat at the time of hot water reconstitution, and had returned to the hot water (the hot water in Table 7). Return property (sensory evaluation)). Also, in proportion to the immersion time, the meat (chicken breast) after the hot water softened (breaking load and breaking energy in Table 7), and the texture (sensory) was also improved (meat after hot water return). Was soft and juicy) (see the sensory evaluations “softness”, “chewing response” and “juicyness” in Table 7).
  • test category 5 when the immersion treatment using the sodium bicarbonate solution was performed under normal pressure, water was rehydrated in an immersion time of 15 hours (test category 5) when performed under reduced pressure, and in an immersion time of 8 hours (test category 8). If the return time is 1 minute and not only the hot water but also the hot water can be returned, the returned meat can be eaten even in an environment where the use of hot water is restricted such as in a disaster.

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Abstract

The present invention pertains to a method for producing dried meat, the method comprising a step for drying meat that has been subjected to a soaking process, wherein the soaking process is a process for soaking meat in a sodium bicarbonate solution.

Description

乾燥畜肉の製造方法Dry meat production method
 本発明は、乾燥畜肉の製造方法に関する。 The present invention relates to a method for producing dried meat.
 乾燥畜肉は、例えば、即席スープ、即席ラーメン及び茶漬け等の即席乾燥食品の具材として用いられている。乾燥畜肉の製造法として、例えば、原料肉を結着剤を用いて成型した後フリーズドライにするフリーズドライチャーシューの製造法(特許文献1)、肉原料を含む即席乾燥具材の湯戻り改善のためにシート状のものを挟み込む方法(特許文献2)、大豆タンパク質を畜肉原料に含有させた乾燥食品の製造法(特許文献3)が開示されている。 Dried meat is used as an ingredient in instant dry foods such as instant soups, instant ramen, and tea pickles. Examples of a method for producing dried meat include, for example, a method for producing a freeze-dried char shoe that is formed by molding a raw meat using a binder and then freeze-drying (Patent Literature 1), and improving the reflow of instant drying ingredients including meat raw materials. For this purpose, a method of sandwiching a sheet-like material (Patent Document 2) and a method of producing a dry food in which soybean protein is contained in a raw meat material (Patent Document 3) are disclosed.
特開2003-235515号公報JP-A-2003-235515 特開2005-052141号公報JP 2005-052141 A 特開2004-041041号公報JP 2004-041041 A
 乾燥畜肉は、経時劣化により劣化臭を生じることがある。この経時劣化を抑制する手段について、従来、充分な検討がなされていたとは言えない。 Dried animal meat may produce a deteriorating odor due to aging. It cannot be said that the means for suppressing this deterioration with time has been sufficiently studied in the past.
 そこで本発明は、経時劣化が抑制された乾燥畜肉の製造方法を提供することを目的とする。 Therefore, an object of the present invention is to provide a method for producing dried livestock meat in which deterioration over time is suppressed.
 本発明は、浸漬処理を施した畜肉を乾燥させる工程を備え、上記浸漬処理が、畜肉を重曹溶液に浸漬する処理である、乾燥畜肉の製造方法を提供する。 The present invention provides a method for producing dried meat, comprising a step of drying the meat that has been subjected to the immersion treatment, wherein the immersion treatment is a treatment of immersing the meat in a baking soda solution.
 本発明に係る製造方法は、乾燥前に畜肉を重曹溶液で浸漬処理することを含むため、経時劣化(特に、経時的な劣化臭の発生)が抑制された乾燥畜肉を製造することができる。加えて、本発明に係る製造方法により得られる乾燥畜肉は、湯戻り性及び湯戻り後の(物理的な)柔らかさ、及び食感(柔らかさ、噛み応え、ジューシーさ)のいずれにも優れている。 た め Since the production method according to the present invention includes immersing meat in a baking soda solution before drying, it is possible to produce dried meat with reduced deterioration over time (particularly generation of deterioration odor over time). In addition, the dried meat obtained by the production method according to the present invention is excellent in both hot-water reversibility, softness (physical) after hot-water replenishment, and texture (softness, chewing response, juicy). ing.
 上記浸漬処理は、減圧下で畜肉を重曹溶液に浸漬する処理であることが好ましい。重曹溶液に浸漬する処理を減圧下で行うことにより、常圧下で行った場合よりも湯戻り後の(物理的な)柔らかさをより向上させることができると共に、浸漬処理の処理時間を短縮しても乾燥畜肉の湯戻り性、並びに湯戻り後の(物理的な)柔らかさ、及び食感を向上させる効果が充分に得られる。 The immersion treatment is preferably a treatment in which the meat is immersed in a baking soda solution under reduced pressure. By performing the treatment of immersion in a baking soda solution under reduced pressure, the (physical) softness after hot water can be improved more than in the case of performing under normal pressure, and the treatment time of the immersion treatment can be reduced. Even so, the effect of improving the hot water removability of the dried animal meat, the (physical) softness after hot water replenishment, and the texture can be sufficiently obtained.
 上記乾燥させる工程は、上記浸漬処理を施した畜肉を凍結乾燥させる工程であることが好ましい。これにより、上述の効果がより顕著に奏される。 The drying step is preferably a step of freeze-drying the meat that has been subjected to the immersion treatment. Thereby, the above-described effects are more remarkably exhibited.
 上記重曹溶液は、重曹濃度が0.1~10重量%であってよい。重曹濃度がこの範囲にあると、上述の効果が充分に得られる。 The baking soda solution may have a baking soda concentration of 0.1 to 10% by weight. When the baking soda concentration is within this range, the above-mentioned effects can be sufficiently obtained.
 本発明はまた、重曹溶液で浸漬処理した畜肉を乾燥させる工程を備える、乾燥畜肉の経時劣化を抑制する方法と捉えることもできる。 The present invention can also be considered as a method for suppressing the deterioration of dried meat over time, which comprises a step of drying the meat immersed in the baking soda solution.
 本発明はさらに、乾燥畜肉の経時劣化を抑制するための重曹の使用であって、乾燥前に畜肉を重曹溶液で浸漬処理する工程を備える、使用(方法)と捉えることもできる。 The present invention can further be regarded as a use (method) of using baking soda for suppressing the deterioration of dried meat with time, which comprises a step of immersing the meat with a baking soda solution before drying.
 本発明はさらにまた、重曹を有効成分とする、乾燥畜肉の経時劣化抑制剤と捉えることもできる。 The present invention can be further regarded as an agent for suppressing deterioration of dried meat over time, which contains sodium bicarbonate as an active ingredient.
 本発明によれば、乾燥前に畜肉を重曹溶液で浸漬処理することにより、経時劣化(特に、経時的な劣化臭の発生)が抑制された乾燥畜肉を簡便に製造することができる。 According to the present invention, by immersing the meat in a baking soda solution before drying, it is possible to easily produce a dried meat in which deterioration with time (particularly generation of a deterioration odor with time) is suppressed.
 本発明によればまた、乾燥前に畜肉を重曹溶液で浸漬処理することにより、経時劣化が抑制されていると共に、湯戻り性及び湯戻り後の(物理的な)柔らかさ、及び食感のいずれも良好な乾燥畜肉を簡便に製造することができる。 According to the present invention, by immersing the meat in a baking soda solution before drying, the deterioration with time is suppressed, and the hot water removability and the (physical) softness after hot water replenishment and the texture are improved. In each case, good dried animal meat can be easily produced.
 さらに、浸漬処理を減圧下で行うことにより、湯戻り性、並びに湯戻り後の(物理的な)柔らかさ、及び食感がより一層向上した乾燥畜肉を簡便に得ることができる。また、得られる乾燥畜肉は、湯(例えば、90~100℃の湯)のみならず、水(例えば、28℃の水)への1分間程度の浸漬で戻すこともできる。したがって、災害時など湯の使用が制限される環境下でも、戻した畜肉を食することができる。 Furthermore, by performing the immersion treatment under reduced pressure, it is possible to easily obtain dried livestock meat with further improved hot water removability, softness (physical) after hot water replenishment, and texture. Further, the obtained dried meat can be returned by immersing in not only hot water (for example, hot water at 90 to 100 ° C.) but also water (for example, water at 28 ° C.) for about one minute. Therefore, the returned meat can be eaten even in an environment where the use of hot water is restricted, such as during a disaster.
 以下、本発明を実施するための形態について詳細に説明する。ただし、本発明は以下の実施形態に限定されるものではない。 Hereinafter, embodiments for carrying out the present invention will be described in detail. However, the present invention is not limited to the following embodiments.
 本実施形態に係る乾燥畜肉の製造方法は、浸漬処理を施した畜肉を乾燥させる工程(以下、「乾燥工程」ともいう。)を備える。本実施形態に係る製造方法は、浸漬処理を畜肉に施す工程(以下、「浸漬処理工程」ともいう。)を更に備えるものであってもよい。 方法 The method for producing dried meat according to the present embodiment includes a step of drying the meat that has been subjected to the immersion treatment (hereinafter, also referred to as a “drying step”). The manufacturing method according to the present embodiment may further include a step of performing immersion processing on the meat (hereinafter, also referred to as “immersion processing step”).
 本明細書において、「畜肉」とは、食肉用となる家畜及び家禽の肉を意味する。畜肉の具体例としては、牛肉、豚肉、鶏肉、馬肉、羊肉、山羊肉及び合鴨肉が挙げられる。 書 In this specification, “meat” means meat of livestock and poultry used for meat. Specific examples of livestock meat include beef, pork, chicken, horse, sheep, goat, and duck.
 乾燥畜肉は、畜肉を乾燥させたものであり、水分含有率は通常10重量%以下である。乾燥畜肉の水分含有率は、7.5重量%以下であることが好ましく、5重量%以下であることがより好ましい。乾燥畜肉の水分含有率は、例えば、赤外光水分分析計を用いて測定することができる。 Dried meat is obtained by drying meat, and usually has a water content of 10% by weight or less. The water content of the dried meat is preferably 7.5% by weight or less, more preferably 5% by weight or less. The moisture content of the dried meat can be measured using, for example, an infrared light moisture analyzer.
 本実施形態に係る製造方法には、成形加工した畜肉、及び成形加工していない畜肉のいずれも用いることができる。ここで、成形加工とは、例えば、複数種の畜肉、及び/又は畜肉以外の原料を混合して固形化する加工、畜肉を特定の形状に成型又は積層する加工を意味する。 製造 In the manufacturing method according to the present embodiment, any of processed meat and unprocessed meat can be used. Here, the forming process means, for example, a process of mixing a plurality of types of meat and / or raw materials other than the meat to solidify, and a process of molding or laminating the meat into a specific shape.
 重曹溶液は、重曹(炭酸水素ナトリウム)を溶媒に溶解した溶液である。溶媒としては、重曹を溶解できるものであれば特に制限はなく、例えば、水、低級アルコール(例えば、炭素原子数1~3のアルコール)、及びこれらの混合溶液を挙げることができる。重曹溶液は、好ましくは重曹水溶液である。 The baking soda solution is a solution in which baking soda (sodium hydrogen carbonate) is dissolved in a solvent. The solvent is not particularly limited as long as it can dissolve sodium bicarbonate, and examples thereof include water, lower alcohols (eg, alcohols having 1 to 3 carbon atoms), and mixed solutions thereof. The baking soda solution is preferably an aqueous solution of baking soda.
 重曹溶液に含まれる重曹の濃度は、重曹溶液全量を基準として、0.1~10重量%であってよい。重曹濃度は、重曹溶液全量を基準として、0.5~5重量%であることが好ましく、1~4重量%であることがより好ましく、1~3重量%であることが更に好ましい。 濃度 The concentration of baking soda contained in the baking soda solution may be from 0.1 to 10% by weight based on the total amount of the baking soda solution. The baking soda concentration is preferably from 0.5 to 5% by weight, more preferably from 1 to 4% by weight, and even more preferably from 1 to 3% by weight, based on the total amount of the baking soda solution.
 重曹溶液のpHは、例えば、7.0~9.0であってよい。重曹溶液のpHがこの範囲にあると、本発明による効果をより顕著に奏することができる。 PH The pH of the sodium bicarbonate solution may be, for example, 7.0 to 9.0. When the pH of the baking soda solution is in this range, the effect of the present invention can be more remarkably exhibited.
 浸漬処理は、畜肉を重曹溶液に浸漬する処理であってよい。浸漬処理は、減圧下で畜肉を重曹溶液に浸漬する処理であるのが好ましい。浸漬処理を減圧下で行うことにより、常圧下で行った場合よりも湯戻り後の(物理的な)柔らかさをより向上させることができると共に、浸漬処理の処理時間を短縮しても湯戻り性、並びに湯戻り後の(物理的な)柔らかさ、及び食感を向上させる効果を充分に得ることができる。 The immersion treatment may be a treatment of immersing the meat in a baking soda solution. The immersion treatment is preferably a treatment in which the meat is immersed in a sodium bicarbonate solution under reduced pressure. By performing the immersion treatment under reduced pressure, the (physical) softness after the hot water can be improved more than when the immersion treatment is performed under normal pressure, and the hot water can be returned even if the processing time of the immersion processing is shortened. The effect of improving the properties, the (physical) softness after hot water return, and the texture can be sufficiently obtained.
 浸漬する畜肉は、目的に応じて、適切な大きさにカットされていてもよい。例えば、厚さ1.5cm以上、又は厚さ2.0~4.0cmに肉厚にカットされた畜肉を用いてもよいし、厚さ1.5cm未満、又は厚さ0.3~1.0cmにカットされた畜肉を用いてもよい。ここで、「厚さ」とは、板状、ブロック状、又は方体状等の畜肉において最短となる面又は曲面の長さ又は幅を意味する。 畜 The meat to be immersed may be cut to an appropriate size according to the purpose. For example, livestock meat cut to a thickness of 1.5 cm or more, or a thickness of 2.0 to 4.0 cm may be used, a thickness of less than 1.5 cm, or a thickness of 0.3 to 1. Livestock meat cut to 0 cm may be used. Here, "thickness" means the length or width of the shortest surface or curved surface of meat such as plate, block, or cube.
 畜肉の量に対する重曹溶液の使用量は、例えば、畜肉100重量部に対して、重曹溶液50~300重量部であってよく、75~200重量部であることが好ましく、100~150重量部であることがより好ましい。これにより、本発明による効果をより顕著に奏することができる。 The amount of the baking soda solution to be used relative to the amount of the meat may be, for example, 50 to 300 parts by weight, preferably 75 to 200 parts by weight, and more preferably 100 to 150 parts by weight based on 100 parts by weight of the meat. More preferably, there is. Thereby, the effect of the present invention can be more remarkably exhibited.
 浸漬処理を減圧下で行う方法は、大気圧より低い圧力がかかった状態で浸漬処理を行うことができる方法であれば、特に制限されない。具体的には、例えば、密封及び開封自在の弁を備えた耐圧容器に畜肉及び重曹溶液を入れ、真空ポンプで容器内の圧力を低下させることで、減圧下で浸漬処理を行うことができる。減圧下での浸漬処理は、例えば、真空ニーダー、真空包装機等を使用して実施することができる。 方法 The method of performing the immersion treatment under reduced pressure is not particularly limited as long as the immersion treatment can be performed in a state where a pressure lower than the atmospheric pressure is applied. Specifically, for example, immersion treatment can be performed under reduced pressure by putting meat and baking soda solution into a pressure-resistant container equipped with a valve that can be sealed and opened, and reducing the pressure in the container with a vacuum pump. The immersion treatment under reduced pressure can be performed using, for example, a vacuum kneader, a vacuum packaging machine, or the like.
 減圧下で浸漬処理を行う際の圧力は、大気圧より低い圧力であればよく、例えば、ゲージ圧で-0.01MPa以下であってよく、-0.03MPa以下であるのが好ましく、-0.05MPa以下であるのがより好ましく、-0.06MPa以下であるのが更に好ましく、-0.07MPa以下であるのが更により好ましく、-0.08MPa以下であるのが更によりまた好ましい。圧力の下限は、特に制限されないが、例えば、-0.10MPaであってよい。なお、ゲージ圧は、大気圧を0MPa、絶対真空を-0.101MPaとしたときの圧力である。 The pressure at the time of performing the immersion treatment under reduced pressure may be a pressure lower than the atmospheric pressure. For example, the gauge pressure may be −0.01 MPa or less, preferably −0.03 MPa or less, and −0 MPa or less. 0.05MPa or less, more preferably -0.06MPa or less, still more preferably -0.07MPa or less, and even more preferably -0.08MPa or less. The lower limit of the pressure is not particularly limited, but may be, for example, -0.10 MPa. The gauge pressure is a pressure when the atmospheric pressure is 0 MPa and the absolute vacuum is -0.101 MPa.
 浸漬処理は、1時間以上行うことが好ましく、3時間以上行うことが好ましく、5時間以上行うことが好ましく、10時間以上行うことがより好ましく、15時間以上行うことが更に好ましく、20時間以上行うことが更により好ましい。浸漬時間が長くなる程、得られる乾燥畜肉の湯戻り性、並びに湯戻り後の(物理的な)柔らかさ、及び食感がより優れたものとなる。また、減圧下で浸漬処理を行う場合は、常圧下と比べて、同等の湯戻り性、並びに湯戻り後の(物理的な)柔らかさ、及び食感を達成するまでの処理時間(浸漬時間)を短縮することができる。 The immersion treatment is preferably performed for 1 hour or more, preferably for 3 hours or more, more preferably for 5 hours or more, more preferably for 10 hours or more, further preferably for 15 hours or more, and more preferably for 20 hours or more. Is even more preferred. The longer the immersion time, the better the reclaimed water and the (physical) softness and texture of the obtained dried animal meat after reconstitution. When the immersion treatment is performed under reduced pressure, the treatment time (at immersion time) required to achieve the same hot water removability, softness (physical) after hot water replenishment, and texture as compared with normal pressure. ) Can be shortened.
 浸漬処理の際の重曹溶液の温度は、特に制限はなく、室温域(例えば、18~28℃)であってもよく、冷蔵域(例えば、4~10℃程度)であってもよい。浸漬処理の際の重曹溶液の温度は、好ましくは、冷蔵域(例えば、4~10℃程度)である。 温度 The temperature of the baking soda solution at the time of the immersion treatment is not particularly limited, and may be a room temperature range (eg, 18 to 28 ° C) or a refrigerated range (eg, about 4 to 10 ° C). The temperature of the sodium bicarbonate solution at the time of the immersion treatment is preferably in a refrigerated region (for example, about 4 to 10 ° C.).
 浸漬処理に用いる重曹溶液には、調味等及び/又は畜肉の軟化処理を目的として、重曹以外の成分(例えば、糖類、タンパク質、ビタミン及びミネラル等の栄養素、醤油及び食塩等の調味組成物、スパイス、アミノ酸、核酸、増粘剤、着色料、酸化防止剤及びアルコール等、並びにプロテアーゼ等)を更に添加してもよい。これにより、浸漬処理と調味及び/又は畜肉の軟化処理を同時に行うことができる。また、重曹溶液は、重曹のみを含有するものとし、重曹以外の成分は必要に応じて他の工程で用いてもよい。例えば、調味については、浸漬処理後、後の加熱処理後、又は乾燥処理後等において、本発明の効果を阻害しない範囲で、上記成分等を含む調味液の塗布、又は粉末調味料の散布等を行うことができる。 In the baking soda solution used for the immersion treatment, components other than baking soda (eg, nutrients such as sugars, proteins, vitamins and minerals, seasoning compositions such as soy sauce and salt, spices) are used for the purpose of seasoning and / or softening of meat. , Amino acids, nucleic acids, thickeners, coloring agents, antioxidants and alcohols, and proteases). Thereby, the immersion treatment and the seasoning and / or the meat softening treatment can be performed simultaneously. The baking soda solution contains only baking soda, and components other than baking soda may be used in other steps as necessary. For example, for the seasoning, after the immersion treatment, after the subsequent heat treatment, or after the drying treatment, to the extent that the effects of the present invention are not impaired, application of a seasoning liquid containing the above components, or spraying of a powder seasoning, etc. It can be performed.
 乾燥工程は、上述のように浸漬処理した畜肉を乾燥処理する工程である。乾燥処理は、例えば、熱風乾燥、加熱乾燥、凍結乾燥、超臨界乾燥等の常法に従って実施することができる。 The drying step is a step of drying the meat that has been immersed as described above. The drying treatment can be performed according to a conventional method such as, for example, hot air drying, heat drying, freeze drying, and supercritical drying.
 本発明による効果をより顕著に奏するという観点から、乾燥処理は、凍結乾燥(フリーズドライ)により実施することが好ましい。凍結乾燥は、例えば、浸漬処理した畜肉を凍結するステップ(凍結ステップ)、凍結した畜肉から減圧下で水分(氷)を除去するステップ(除去ステップ)を含む方法により実施することができる。 乾燥 From the viewpoint that the effects of the present invention are more remarkably exhibited, the drying treatment is preferably performed by freeze drying (freeze drying). Freeze-drying can be performed, for example, by a method including a step of freezing the immersed meat (freezing step) and a step of removing water (ice) from the frozen meat under reduced pressure (removal step).
 凍結ステップは、例えば、浸漬処理した畜肉を空冷した後、-20℃~-60℃程度で1~3時間凍結処理を行うものであってよい。 The freezing step may be, for example, air cooling of the immersed meat, followed by freezing at about −20 ° C. to −60 ° C. for 1 to 3 hours.
 除去ステップは、例えば、凍結した畜肉を凍結乾燥機を使用して、水分含有率10重量%以下、好ましくは7.5重量%以下、より好ましくは5重量%以下とするものであってよい。凍結乾燥機は公知のものを使用することができる。凍結乾燥機による凍結乾燥条件は、畜肉の水分含量を上記範囲にすることができれば特に限定されず、例えば、真空度0.8torr(mmHg)以下、好ましくは0.08torr(mmHg)以下、より好ましくは0.04torr(mmHg)以下の真空条件で、真空度に応じた温度設定で10~36時間程度処理する条件などが例示される。 The removing step may be, for example, using a freeze dryer to freeze frozen meat to a water content of 10% by weight or less, preferably 7.5% by weight or less, more preferably 5% by weight or less. Known freeze dryers can be used. The freeze-drying condition by the freeze dryer is not particularly limited as long as the water content of the meat can be kept in the above range, and for example, the degree of vacuum is 0.8 torr (mmHg) or less, preferably 0.08 torr (mmHg) or less, more preferably. Is a condition in which the treatment is performed under a vacuum condition of 0.04 torr (mmHg) or less at a temperature setting according to the degree of vacuum for about 10 to 36 hours.
 浸漬処理した畜肉は、そのまま乾燥処理を行ってもよいが、乾燥処理前に加熱処理を行ってもよい。加熱処理としては、例えば、蒸煮処理(スチーム処理)、ボイル処理、及び油調処理(フライ処理)を挙げることができる。加熱処理は、これらの処理を組み合わせて行うものであってもよい。 畜 The meat that has been immersed may be subjected to a drying treatment as it is, or may be subjected to a heating treatment before the drying treatment. Examples of the heat treatment include a steaming treatment (steam treatment), a boil treatment, and an oil conditioning treatment (frying treatment). The heat treatment may be a combination of these treatments.
 蒸煮処理は、これに限定されるものではないが、例えば、温度100~130℃、圧力0.01~0.5MPa程度の水蒸気を、30秒~10分間程度、浸漬処理した畜肉に接触させることで行うことができる。蒸煮処理は、密閉された条件で行ってもよい。 The steaming treatment is not limited to this. For example, steam having a temperature of 100 to 130 ° C. and a pressure of about 0.01 to 0.5 MPa is brought into contact with the dipped meat for about 30 seconds to 10 minutes. Can be done with The steaming treatment may be performed under closed conditions.
 油調処理は、これに限定されるものではないが、例えば、160~190℃(常圧)で60~300秒程度、浸漬処理した畜肉を処理することで行うことができる。油調処理は、減圧可能な密閉式の油揚げ装置等を用いて減圧条件で実施してもよい。減圧条件下で実施する場合の条件は、常圧で油調処理した場合と同程度の状態になるように適宜、真空度、温度、フライ時間等を調整して設定すればよい。油調処理に使用する油は、特に限定されず、例えば、動植物由来の各種食用油(大豆油、菜種油、米油、コーン油、パーム油、ベニバナ油、ヒマワリ油、ラード及びヘット等、並びにこれらから選ばれる種以上の混合油)が広く使用できる。さらには、油調処理前にパン粉などのフライ衣原料を畜肉に付けてもよい。 The oil-conditioning treatment is not limited to this, but can be performed, for example, by treating the immersed meat at 160 to 190 ° C. (normal pressure) for about 60 to 300 seconds. The oil conditioning treatment may be performed under reduced pressure using a closed-type fryer or the like capable of reducing pressure. The conditions under which the pressure is reduced may be set by appropriately adjusting the degree of vacuum, the temperature, the frying time, and the like so that the state is substantially the same as that in the case of performing the oil adjustment process at normal pressure. The oil used in the oil preparation is not particularly limited. For example, various edible oils derived from animals and plants (soybean oil, rapeseed oil, rice oil, corn oil, palm oil, safflower oil, sunflower oil, lard and het, and the like) Or more mixed oils selected from the group consisting of: Furthermore, raw meat ingredients such as bread crumbs may be added to the meat before the oil conditioning treatment.
 以上説明した本発明は、重曹溶液で浸漬処理した畜肉を乾燥させる工程を備える、乾燥畜肉の経時劣化を抑制する方法と捉えることもできる。また、乾燥畜肉の経時劣化を抑制するための重曹の使用であって、乾燥前に畜肉を重曹溶液で浸漬処理する工程を備える、使用(方法)と捉えることもできる。さらに、重曹を有効成分とする、乾燥畜肉の経時劣化抑制剤と捉えることもできる。 The present invention described above can also be considered as a method for suppressing the deterioration of dried meat over time, which comprises a step of drying the meat immersed in the baking soda solution. In addition, the use of baking soda to suppress the deterioration of dried meat over time can be considered as a use (method) including a step of immersing the meat with a baking soda solution before drying. Furthermore, it can also be regarded as an agent for suppressing the deterioration of dried livestock meat over time, which contains baking soda as an active ingredient.
 以下、実施例等に基づいて本発明を具体的に説明する。ただし、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be specifically described based on examples and the like. However, the present invention is not limited to these.
〔試験例1:経時劣化抑制試験〕
 鶏胸肉を2.5cm角のダイスカットにし、下記表1に示す各溶液にそれぞれ15時間浸漬した(冷蔵)。浸漬後、各鶏胸肉を取り出し、スチーム(蒸気)で8分間加熱した後、凍結し、凍結乾燥機(共和真空技術株式会社製品:型式RLE II-103)を用い、真空度0.04torr(mmHg)以下、温度70℃、乾燥時間26時間の条件で乾燥させて、各乾燥鶏胸肉を得た。なお、ビタミンE及びビタミンCは、鶏胸肉の油脂含量を基準に酸化防止効果が認められる量を使用した。
[Test Example 1: Temporal deterioration suppression test]
The chicken breast was cut into 2.5 cm square dice and immersed in each of the solutions shown in Table 1 below for 15 hours (refrigerated). After immersion, each chicken breast was taken out, heated with steam (steam) for 8 minutes, frozen, and freeze-dried (Kyowa Vacuum Engineering Co., Ltd. product: Model RLE II-103), using a degree of vacuum of 0.04 torr ( mmHg) and dried at a temperature of 70 ° C. and a drying time of 26 hours to obtain each dried chicken breast. Vitamin E and Vitamin C were used in amounts that would have an antioxidant effect based on the fat content of chicken breast.
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 製造した各乾燥鶏胸肉をアルミ袋に入れ、37℃の恒温庫で保管した。6週間及び15週間保管した後、オルトネーザルによる劣化臭を官能評価で評価した。同様に、15週間保管した後、レトロネーザルによる劣化臭を官能評価で評価した。 Each of the manufactured dried chicken breasts was put in an aluminum bag and stored in a thermostat at 37 ° C. After storage for 6 weeks and 15 weeks, the deterioration odor due to orthonasal was evaluated by sensory evaluation. Similarly, after storing for 15 weeks, the deterioration odor due to the retronasal was evaluated by sensory evaluation.
 オルトネーザルによる劣化臭の官能評価は、選抜されたパネル3名により実施した。37℃の恒温庫で6週間及び15週間保管した各乾燥鶏胸肉をプラスチックカップに移し、カップから立ち上がる香気を評価対象とした。下記評価尺度に従って6段階で評点を付け、3名のパネルの平均値をとった。
(評価尺度)
 5点:「劣化臭」を全く感じない
 4点:「劣化臭」を非常に弱く感じる
 3点:「劣化臭」を弱く感じる
 2点:「劣化臭」をはっきり感じる
 1点:「劣化臭」を強く感じる
 0点:「劣化臭」を非常に強く感じる
The sensory evaluation of the deterioration odor by orthonasal was carried out by three selected panels. Each dried chicken breast stored in a thermostat at 37 ° C. for 6 weeks and 15 weeks was transferred to a plastic cup, and the aroma rising from the cup was evaluated. Scores were given on a six-point scale according to the following rating scale, and the average of three panels was taken.
(Evaluation scale)
5 points: Do not feel "deterioration odor" at all 4 points: Feel "deterioration odor" very weak 3 points: Feel "deterioration odor" weakly 2 points: clearly feel "deterioration odor" 1 point: "deterioration odor" 0: Feel very strong “deterioration odor”
 評価結果を下記表2に示す。
Figure JPOXMLDOC01-appb-T000002
The evaluation results are shown in Table 2 below.
Figure JPOXMLDOC01-appb-T000002
 レトロネーザルによる劣化臭の官能評価は、選抜されたパネル3名により実施した。官能評価は、凍結乾燥直後から冷蔵保管し、品質を維持したサンプル(乾燥鶏胸肉)をコントロール(評点5点)とし、37℃の恒温庫で15週間保管した各乾燥鶏胸肉の劣化臭の強さを相対評価で評価した。具体的には、37℃の恒温庫で15週間保管した各乾燥鶏胸肉をビーカーに移し、各乾燥鶏胸肉が充分に浸る程度の熱湯をポットから注ぎ、1分以上経過した後、各乾燥鶏胸肉を口に含み、口腔内で感じられる風味を評価対象とした。下記評価尺度に従って6段階で評点を付け、3名のパネルの平均値をとった。
(評価尺度)
 5点:「劣化臭」を全く感じない(コントロールと同等)
 4点:「劣化臭」を非常に弱く感じる
 3点:「劣化臭」を弱く感じる
 2点:「劣化臭」をはっきり感じる
 1点:「劣化臭」を強く感じる
 0点:「劣化臭」を非常に強く感じる
The sensory evaluation of the deterioration odor by the retro nasal was carried out by three selected panels. The sensory evaluation was performed by keeping the samples refrigerated immediately after freeze-drying and maintaining the quality (dried chicken breasts) as a control (five points). Was evaluated by relative evaluation. Specifically, each dried chicken breast stored in a thermostat at 37 ° C. for 15 weeks was transferred to a beaker, and boiling water was poured from the pot so that each dried chicken breast was sufficiently immersed. Dried chicken breast was included in the mouth, and the flavor felt in the mouth was evaluated. Scores were given on a six-point scale according to the following rating scale, and the average of three panels was taken.
(Evaluation scale)
5 points: No "deteriorating odor" is felt (equivalent to control)
4 points: Feel the "deteriorating odor" very weakly 3 points: Feel the "deteriorating odor" weakly 2 points: Feel the "deteriorating odor" clearly 1 point: Feel the "deteriorating odor" strongly 0 point: "deteriorating odor" Feel very strong
 評価結果を表3に示す。
Figure JPOXMLDOC01-appb-T000003
Table 3 shows the evaluation results.
Figure JPOXMLDOC01-appb-T000003
 凍結乾燥前に重曹溶液に浸漬した実施例1の乾燥鶏胸肉は、37℃保管後も乾燥直後と変わらず「劣化臭」が全く感じられなかった。一方、凍結乾燥前に浸漬処理を行わなかった比較例1の乾燥鶏胸肉、凍結乾燥前に水に浸漬した比較例2の乾燥鶏胸肉、凍結乾燥前にリン酸緩衝液(重曹溶液と同等のpH)に浸漬した比較例3の乾燥鶏胸肉、凍結乾燥前にビタミンE又はビタミンC溶液(酸化防止剤)に浸漬した比較例4又は比較例5の乾燥鶏胸肉では、37℃保管後に「劣化臭」が認められた。これらの結果は、「劣化臭」の抑制が、pH又は酸化防止作用に依存しない、重曹に特有の効果であることを示している。 乾燥 The dried chicken breast of Example 1, which was immersed in a sodium bicarbonate solution before freeze-drying, showed no “deteriorating odor” after storage at 37 ° C., just as it did immediately after drying. On the other hand, the dried chicken breast of Comparative Example 1 in which the immersion treatment was not performed before lyophilization, the dried chicken breast of Comparative Example 2 immersed in water before lyophilization, and a phosphate buffer solution (with sodium bicarbonate solution) before lyophilization The dried chicken breast of Comparative Example 3 immersed in the same pH) and the dried chicken breast of Comparative Example 4 or Comparative Example 5 immersed in a vitamin E or vitamin C solution (antioxidant) before lyophilization was 37 ° C. After storage, "deterioration odor" was observed. These results show that the suppression of the “deterioration odor” is an effect peculiar to baking soda that does not depend on the pH or antioxidant action.
〔試験例2:湯戻り性試験〕
 鶏胸肉を一辺が2.5~3cmの立方体にカットし、下記表4に示す各溶液にそれぞれ20時間浸漬した(冷蔵)。なお、実施例2の重曹溶液(pH8.1)は、冷水で重曹を溶解させる方法で調製した。実施例3の重曹溶液(pH8.7)は、熱水で重曹を溶解し、炭酸ナトリウムを発生させる方法で調製した。浸漬後、各鶏胸肉を取り出し、スチーム(蒸気)で8分間加熱した後、試験例1と同様の条件で凍結乾燥させて、各乾燥鶏胸肉を得た。
[Test Example 2: Hot water reversion test]
The chicken breast was cut into cubes each having a side of 2.5 to 3 cm, and immersed in each of the solutions shown in Table 4 below for 20 hours (refrigerated). The baking soda solution (pH 8.1) of Example 2 was prepared by a method of dissolving baking soda in cold water. The baking soda solution (pH 8.7) of Example 3 was prepared by dissolving baking soda with hot water to generate sodium carbonate. After immersion, each chicken breast was taken out, heated with steam (steam) for 8 minutes, and freeze-dried under the same conditions as in Test Example 1 to obtain each dried chicken breast.
Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004
 製造した各乾燥鶏胸肉をそれぞれカップに入れ、上から98℃の湯を投入して、1分後の「湯戻り性」及び「柔らかさ」を、選抜されたパネル4名により、以下の基準で官能評価した。 Each dried chicken breast produced was put in a cup, and hot water of 98 ° C. was poured from above, and after 1 minute, “hot water return” and “softness” were determined by the selected four panelists as follows. Sensory evaluation was performed based on criteria.
 「湯戻り性」は、湯の浸透の程度を以下の基準で総合的に評価した。
 ○:内部に湯が十分浸透しており、良い
 △:湯の浸透状態にばらつきがある
 ×:内部に湯が浸透しておらず、悪い
“Hot water reversion” comprehensively evaluated the degree of hot water permeation based on the following criteria.
:: Hot water has sufficiently penetrated into the interior and good.
 「柔らかさ」については、食べた時の食感を以下の基準で評価した。
 ◎:柔らかくてジューシー
 ○:柔らかい
 △:どちらでもない
 ×:硬い
Regarding “softness”, the texture when eaten was evaluated according to the following criteria.
◎: Soft and juicy ○: Soft △: Neither ×: Hard
 評価結果を表5に示す。
Figure JPOXMLDOC01-appb-T000005
Table 5 shows the evaluation results.
Figure JPOXMLDOC01-appb-T000005
 凍結乾燥前に重曹溶液に浸漬した実施例2及び実施例3の乾燥鶏胸肉は、「湯戻り性」及び「柔らかさ」のいずれも良好な結果であった。 乾燥 The dried chicken breasts of Examples 2 and 3 immersed in a baking soda solution before freeze-drying had good results in both “hot water reversibility” and “softness”.
〔試験例3:減圧下での浸漬処理による効果の検証〕
[乾燥畜肉の製造]
〔1.鶏胸肉及び浸漬液の準備〕
 鶏胸肉は、2.5cm角のダイスカットにした。浸漬液(水又は重曹溶液)は、表6に記載の配合割合で調整した。
Figure JPOXMLDOC01-appb-T000006
[Test Example 3: Verification of the effect of immersion treatment under reduced pressure]
[Manufacture of dried meat]
[1. Preparation of chicken breast and dipping solution)
The chicken breast was cut into 2.5 cm square dice. The immersion liquid (water or sodium bicarbonate solution) was adjusted at the mixing ratio shown in Table 6.
Figure JPOXMLDOC01-appb-T000006
〔2.浸漬処理〕
(2-1.常圧下での浸漬処理)
 表7に示す試験区分1~5は、常圧(大気圧)下で浸漬処理を行った。準備した鶏胸肉1kgと、表7に示す各浸漬液(水又は重曹溶液)1kgをそれぞれビニール製の袋に入れ、浸漬液がこぼれないように口を閉じた。浸漬液に鶏胸肉が充分接触するように鶏胸肉と浸漬液を混合した後、冷蔵庫(4℃)にて表7に示す各浸漬時間(4時間、8時間又は15時間)の間保管した。なお、試験区分1(無浸漬)では、浸漬液を添加しなかったこと以外は、上記の手順で処理を行った。
[2. Immersion treatment)
(2-1. Immersion treatment under normal pressure)
Test categories 1 to 5 shown in Table 7 were immersed at normal pressure (atmospheric pressure). 1 kg of the prepared chicken breast and 1 kg of each immersion liquid (water or baking soda solution) shown in Table 7 were each placed in a plastic bag, and the mouth was closed so that the immersion liquid did not spill. After mixing the chicken breast and the immersion liquid so that the chicken breast is sufficiently in contact with the immersion liquid, store in a refrigerator (4 ° C.) for each immersion time (4 hours, 8 hours or 15 hours) shown in Table 7. did. In the test category 1 (no immersion), the treatment was performed in the above procedure except that the immersion liquid was not added.
(2-2.減圧下での浸漬処理)
 表7に示す試験区分6~9は、減圧下で浸漬処理を行った。準備した鶏胸肉1kgと、表7に示す各浸漬液(水又は重曹溶液)1kgをそれぞれ真空ポリカデシケータ内に入れた後、真空ポンプを使用して、デシケータ内を減圧した。真空圧力(ゲージ圧)が-0.09MPaになったところで真空ポンプを止めて密栓し、デシケータごと冷蔵庫(4℃)に入れ、表7に示す各浸漬時間(1時間、4時間、8時間又は15時間)の間保管した。なお、ゲージ圧は、大気圧を0MPa、絶対真空を-0.101MPaとしたときの圧力である。
(2-2. Immersion treatment under reduced pressure)
Test sections 6 to 9 shown in Table 7 were immersed under reduced pressure. After 1 kg of the prepared chicken breast and 1 kg of each immersion liquid (water or sodium bicarbonate solution) shown in Table 7 were put in a vacuum polycarbonate desiccator, the inside of the desiccator was depressurized using a vacuum pump. When the vacuum pressure (gauge pressure) became -0.09 MPa, the vacuum pump was stopped and sealed, and the desiccator was put into a refrigerator (4 ° C.), and each immersion time shown in Table 7 (1 hour, 4 hours, 8 hours or 15 hours). The gauge pressure is a pressure when the atmospheric pressure is 0 MPa and the absolute vacuum is -0.101 MPa.
〔3.乾燥処理〕
 浸漬処理を行った後、各鶏胸肉を取り出し、スチーム(蒸気)で8分間加熱した後、凍結し、凍結乾燥機(共和真空技術株式会社製品:型式RLE II-103)を用い、真空度0.04torr(mmHg)以下、温度70℃、乾燥時間26時間の条件で乾燥させて、各乾燥鶏胸肉を得た。
[3. (Drying treatment)
After the immersion treatment, each chicken breast was taken out, heated with steam (steam) for 8 minutes, frozen, and freeze-dried (product of Kyowa Vacuum Engineering Co., Ltd .: Model RLE II-103) to obtain a vacuum degree. The dried chicken breast was obtained by drying at 0.04 torr (mmHg) or less, at a temperature of 70 ° C. and a drying time of 26 hours.
[湯戻り性、又は水戻り性の評価]
 上記で得られた各試験区分の乾燥鶏胸肉に対して、湯戻り性を評価した。また、試験区分1,2,5及び8の乾燥鶏胸肉に対しては、水戻り性も併せて評価した。
[Evaluation of hot water return or water return]
The hot-water reversibility was evaluated for the dried chicken breast of each test category obtained above. For the dried chicken breasts of test categories 1, 2, 5, and 8, water reversion was also evaluated.
〔戻し率の測定〕
 100mLのビーカーに乾燥鶏胸肉1個を入れ、重量を測定した(湯戻し前の重さ:g)。次いで、90℃の湯を約80mL注ぎ、1分間静置した。その後、茶こしで湯を切って鶏胸肉を取り出し、直ちに重量を測定した(湯戻し後の重さ:g)。戻し率は、下記式に従って算出した。これを6回繰り返して、戻し率の平均値を算出した(平均戻し率)。結果は、表7に示した。
 戻し率=(湯戻し後の重さ:g)/(湯戻し前の重さ:g)
[Measurement of return rate]
One dried chicken breast was placed in a 100 mL beaker and weighed (weight before reconstitution: g). Next, about 80 mL of hot water at 90 ° C. was poured, and the mixture was allowed to stand for 1 minute. Thereafter, the hot water was cut off with a tea strainer, and the chicken breast was taken out and immediately weighed (weight after reconstitution: g). The return rate was calculated according to the following equation. This was repeated six times, and the average value of the return rate was calculated (average return rate). The results are shown in Table 7.
Reversion rate = (weight after reconstitution: g) / (weight before reconstitution: g)
 水戻り性の評価では、90℃の湯に代えて28℃の蒸留水を用いたこと以外は同じ手順で平均戻し率を算出した。結果は、表7に示した。 評 価 In the evaluation of the water return property, the average return rate was calculated by the same procedure except that distilled water at 28 ° C. was used instead of hot water at 90 ° C. The results are shown in Table 7.
〔官能評価〕
 200mLのビーカーに乾燥鶏胸肉7gを量り入れ、100℃の湯を150mL注ぎ、1分間静置した。直ちに肉片を取り出し、官能評価に供した。官能評価は、訓練されたパネル5名により、湯の浸透の程度を以下の評価基準で総合的に評価した。結果は、表7に示した。
 ×:肉の表層に湯が浸透していない(湯戻しができていない)
 △:肉の表層にのみ湯が浸透している(湯戻しができていない)
 ○:肉の中心部まで湯が浸透している(湯戻しできている)
〔sensory evaluation〕
7 g of dried chicken breast was weighed into a 200 mL beaker, 150 mL of 100 ° C. water was poured, and the mixture was allowed to stand for 1 minute. Immediately, the meat pieces were taken out and subjected to sensory evaluation. In the sensory evaluation, five trained panels comprehensively evaluated the degree of penetration of hot water according to the following evaluation criteria. The results are shown in Table 7.
×: Hot water has not penetrated into the surface layer of meat (hot water has not been reconstituted)
△: Hot water has penetrated only into the surface layer of meat (hot water cannot be reconstituted)
○: Hot water has penetrated to the center of the meat (hot water can be returned)
 水戻り性の評価では、100℃の湯に代えて28℃の軟水化処理水を用いたこと以外は同じ手順で水の浸透の程度を評価した。結果は、表7に示した。 評 価 In the evaluation of the water return property, the degree of permeation of water was evaluated by the same procedure except that softened water at 28 ° C was used instead of hot water at 100 ° C. The results are shown in Table 7.
〔テクスチャー測定〕
 100mLのビーカーに乾燥鶏胸肉1個を入れ、90℃の湯を約80mL注ぎ、1分間静置した。その後、茶こしで湯を切って鶏胸肉を取り出し、測定サンプルとした。食品物性試験機(クリープメータ,株式会社山電製)を使用し、鶏胸肉の筋繊維に垂直になるように治具を当て、各試験区分の鶏胸肉の破断荷重(単位:N)及び破断エネルギー(単位:J/m)を測定した。測定条件は以下のとおりである。
 ロードセル:200N
 治具:L50+くさび型49
 測定歪率:99%
 測定速度:1mm/秒
[Texture measurement]
One dried chicken breast was placed in a 100 mL beaker, about 80 mL of 90 ° C. water was poured, and the mixture was allowed to stand for 1 minute. Thereafter, the hot water was cut off with a tea strainer, and the chicken breast was taken out and used as a measurement sample. Using a food property tester (Creep Meter, manufactured by Sanden Co., Ltd.), apply a jig vertically to the muscle fiber of chicken breast, and the breaking load of chicken breast in each test category (unit: N) And the breaking energy (unit: J / m 3 ) were measured. The measurement conditions are as follows.
Load cell: 200N
Jig: L50 + wedge type 49
Measurement distortion rate: 99%
Measuring speed: 1mm / sec
 各試験区分について、それぞれ独立に5~8回測定を行い、各試験区分の鶏胸肉の破断荷重(単位:N)及び破断エネルギー(単位:J/m)の平均値を算出した。結果は、表7に示した。 The measurement was independently performed 5 to 8 times for each test section, and the average value of the breaking load (unit: N) and the breaking energy (unit: J / m 3 ) of the chicken breast of each test section was calculated. The results are shown in Table 7.
 水戻り性の評価では、90℃の湯に代えて28℃の蒸留水を用いたこと以外は同じ手順で各試験区分の鶏胸肉の破断荷重(単位:N)及び破断エネルギー(単位:J/m)の平均値を算出した。結果は、表7に示した。 In the evaluation of the water return property, the breaking load (unit: N) and breaking energy (unit: J) of the chicken breast in each test section were determined in the same procedure except that distilled water at 28 ° C. was used instead of hot water at 90 ° C. / M 3 ) was calculated. The results are shown in Table 7.
[湯戻り後、又は水戻り後の食感評価]
 200mLのビーカーに乾燥鶏胸肉7gを量り入れ、100℃の湯を150mL注ぎ、1分間静置した。直ちに肉片を取り出し、官能評価に供した。官能評価では、訓練されたパネル5名により、「肉の柔らかさ」、「肉の噛み応え(弾力、筋感)」及び「ジューシーさ(水分感)」の項目について、以下の評価尺度で評価を行い、平均値を算出した。結果は、表7に示した。
[Evaluation of texture after returning to hot water or after returning to water]
7 g of dried chicken breast was weighed into a 200 mL beaker, 150 mL of 100 ° C. water was poured, and the mixture was allowed to stand for 1 minute. Immediately, the meat pieces were taken out and subjected to sensory evaluation. In the sensory evaluation, five trained panels evaluated the items of "softness of meat", "meat chewing response (elasticity, muscular feeling)" and "juicyness (moisture feeling)" using the following evaluation scale. And the average was calculated. The results are shown in Table 7.
 肉の柔らかさ
  1:非常に硬く噛み切れない
  2:硬く噛み切れない
  3:どちらでもない
  4:柔らかい
  5:非常に柔らかい
 肉の噛み応え(弾力、筋感)
  1:噛み応えが強い(噛み切れないくらい硬い)
  2:噛み応えがある(硬い)
  3:適度な噛み応え(畜肉本来の噛み応え(筋感))
  4:噛み応えが弱い(少し柔らかい)
  5:噛み応えがない(柔らかい)
 ジューシーさ(水分感)
  1:パサパサしている
  2:少しパサついている
  3:どちらでもない
  4:ジューシーである
  5:非常にジューシーである
The tenderness of the meat 1: very hard to bite 2: hard and hard to bite 3: neither neither 4: soft 5: very soft Meat bite response (elasticity, muscle feeling)
1: Strong bite response (hard enough to bite)
2: Responsive (hard)
3: Moderate chewing response (original meat's original chewing response (strain feeling))
4: weak chewing response (slightly soft)
5: No chewing response (soft)
Juicy (moisture)
1: Slightly sullen 2: Slightly sullen 3: Neither 4: Juicy 5: Very juicy
 水戻り性の評価では、100℃の湯に代えて28℃の軟水化処理水を用いたこと以外は同じ手順で官能評価を実施した。結果は、表7に示した。 評 価 Evaluation of water reversion was carried out by the same procedure except that 28 ° C. softened water was used instead of 100 ° C. hot water. The results are shown in Table 7.
Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007
 重曹溶液を使用した浸漬処理を施した試験区分3~9の乾燥畜肉(乾燥鶏胸肉)は、湯戻し時に乾燥畜肉の内部にまで湯が浸透し、湯戻りしていた(表7の湯戻り性(官能評価)参照)。また、浸漬時間に比例して、湯戻り後の畜肉(鶏胸肉)が柔らかくなり(表7の破断荷重、破断エネルギー)、また食感(官能)も向上していた(湯戻り後の畜肉が柔らかく、ジューシーになった)(表7の官能評価「柔らかさ」「噛み応え」「ジューシーさ」参照)。さらに、減圧下で重曹溶液を使用した浸漬処理を施した試験区分6~9の乾燥畜肉(乾燥鶏胸肉)では、常圧下と比べて、湯戻り後の畜肉(鶏胸肉)がより柔らかくなった(表7の破断荷重、破断エネルギー)。また、減圧下で重曹溶液を使用した浸漬処理を施した乾燥畜肉(乾燥鶏胸肉)は、常圧下で同じ時間浸漬処理を施した乾燥畜肉(乾燥鶏胸肉)と比べて、畜肉本来の噛み応え(筋感)を感じられるものであった(表7の官能評価「噛み応え」の評点がより3に近い)。さらに、減圧下で重曹溶液を使用した浸漬処理を施した乾燥畜肉(乾燥鶏胸肉)は、浸漬時間が1時間の場合でも、湯戻し時に乾燥畜肉の内部にまで湯が浸透し、湯戻りしていた。(表7の試験区分6参照)。 Dried meat (Dried chicken breast) in test categories 3 to 9 which had been subjected to a dipping treatment using a baking soda solution, had the hot water penetrated into the dried meat at the time of hot water reconstitution, and had returned to the hot water (the hot water in Table 7). Return property (sensory evaluation)). Also, in proportion to the immersion time, the meat (chicken breast) after the hot water softened (breaking load and breaking energy in Table 7), and the texture (sensory) was also improved (meat after hot water return). Was soft and juicy) (see the sensory evaluations “softness”, “chewing response” and “juicyness” in Table 7). In addition, in the case of dried livestock meat (dried chicken breast) in test categories 6 to 9 subjected to immersion treatment using a baking soda solution under reduced pressure, the livestock meat (chicken breast) after returning to hot water is softer than under normal pressure. (Breaking load and breaking energy in Table 7). In addition, dried meat (dried chicken breast) immersed under a reduced pressure using a baking soda solution is compared with dried meat (dried chicken breast) immersed under normal pressure for the same period of time. Chewing response (streak feeling) was felt (the score of the sensory evaluation “biting response” in Table 7 was closer to 3). Furthermore, even if the dipping time is 1 hour, the hot meat permeates into the dried meat at the time of hot water reconstitution, and the hot water returns to the hot meat. Was. (See Test Category 6 in Table 7).
 水戻り性については、重曹溶液を使用した浸漬処理を施した試験区分5及び8の乾燥畜肉(乾燥鶏胸肉)では、水戻し時に乾燥畜肉の内部にまで水が浸透し水戻りしていた。また、重曹溶液を使用した浸漬処理を常圧下で行った場合は浸漬時間15時間(試験区分5)、減圧下で行った場合は浸漬時間8時間(試験区分8)で水戻しができた。戻し時間1分で、湯戻りのみならず水戻りが可能であれば、災害時など湯の使用が制限される環境下でも、戻した畜肉を食することができる。 Regarding the water recycle property, in the dry meat (dry chicken breast) of test categories 5 and 8 which had been subjected to the immersion treatment using the sodium bicarbonate solution, water permeated into the inside of the dried meat at the time of rehydration and returned. . In addition, when the immersion treatment using the sodium bicarbonate solution was performed under normal pressure, water was rehydrated in an immersion time of 15 hours (test category 5) when performed under reduced pressure, and in an immersion time of 8 hours (test category 8). If the return time is 1 minute and not only the hot water but also the hot water can be returned, the returned meat can be eaten even in an environment where the use of hot water is restricted such as in a disaster.

Claims (7)

  1.  浸漬処理を施した畜肉を乾燥させる工程を備え、
     前記浸漬処理が、畜肉を重曹溶液に浸漬する処理である、乾燥畜肉の製造方法。
    With a step of drying the meat that has been subjected to the immersion treatment,
    A method for producing dried meat, wherein the immersion treatment is a treatment of immersing the meat in a baking soda solution.
  2.  前記浸漬処理が、減圧下で畜肉を重曹溶液に浸漬する処理である、請求項1に記載の製造方法。 The method according to claim 1, wherein the immersion treatment is a treatment of immersing the meat in a sodium bicarbonate solution under reduced pressure.
  3.  前記乾燥させる工程は、前記浸漬処理を施した畜肉を凍結乾燥させる工程である、請求項1又は2に記載の製造方法。 The method according to claim 1 or 2, wherein the drying step is a step of freeze-drying the meat that has been subjected to the immersion treatment.
  4.  前記重曹溶液は、重曹濃度が0.1~10重量%である、請求項1~3のいずれか一項に記載の製造方法。 The method according to any one of claims 1 to 3, wherein the baking soda solution has a baking soda concentration of 0.1 to 10% by weight.
  5.  重曹溶液で浸漬処理した畜肉を乾燥させる工程を備える、乾燥畜肉の経時劣化を抑制する方法。 方法 A method for suppressing the deterioration of dried meat over time, comprising a step of drying the meat immersed in a sodium bicarbonate solution.
  6.  乾燥畜肉の経時劣化を抑制するための重曹の使用であって、
     乾燥前に畜肉を重曹溶液で浸漬処理する工程を備える、使用。
    The use of baking soda to suppress the deterioration of dried meat over time,
    Use comprising a step of dipping meat in a baking soda solution before drying.
  7.  重曹を有効成分とする、乾燥畜肉の経時劣化抑制剤。 (4) An agent for suppressing the deterioration of dried meat over time, comprising baking soda as an active ingredient.
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JPH0213345A (en) * 1988-05-03 1990-01-17 Soc Prod Nestle Sa Production of dehydrated meat product
US20020048623A1 (en) * 2000-09-06 2002-04-25 Konrad Baarda Composite meat product and method for the manufacture thereof
JP2014064542A (en) * 2012-09-27 2014-04-17 Niigata Industrial Creation Organization Manufacturing method of meat-containing retort food
WO2014112623A1 (en) * 2013-01-18 2014-07-24 マルハニチロ株式会社 Method for manufacturing frozen fish paste having excellent freeze-storage properties
JP2016524518A (en) * 2013-04-03 2016-08-18 ルドルフ ヴィルト ゲーエムベーハー ウント ツェーオー.カーゲー Methods for incorporating substances into organic solids

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JPH0213345A (en) * 1988-05-03 1990-01-17 Soc Prod Nestle Sa Production of dehydrated meat product
US20020048623A1 (en) * 2000-09-06 2002-04-25 Konrad Baarda Composite meat product and method for the manufacture thereof
JP2014064542A (en) * 2012-09-27 2014-04-17 Niigata Industrial Creation Organization Manufacturing method of meat-containing retort food
WO2014112623A1 (en) * 2013-01-18 2014-07-24 マルハニチロ株式会社 Method for manufacturing frozen fish paste having excellent freeze-storage properties
JP2016524518A (en) * 2013-04-03 2016-08-18 ルドルフ ヴィルト ゲーエムベーハー ウント ツェーオー.カーゲー Methods for incorporating substances into organic solids

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