JP2016165746A - Manufacturing method of joint structure, joint structure, and laser device - Google Patents

Manufacturing method of joint structure, joint structure, and laser device Download PDF

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Publication number
JP2016165746A
JP2016165746A JP2015047515A JP2015047515A JP2016165746A JP 2016165746 A JP2016165746 A JP 2016165746A JP 2015047515 A JP2015047515 A JP 2015047515A JP 2015047515 A JP2015047515 A JP 2015047515A JP 2016165746 A JP2016165746 A JP 2016165746A
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JP
Japan
Prior art keywords
laser
manufacturing
concave portion
joining
metal member
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2015047515A
Other languages
Japanese (ja)
Inventor
和義 西川
Kazuyoshi Nishikawa
和義 西川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Omron Corp
Original Assignee
Omron Corp
Omron Tateisi Electronics Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Omron Corp, Omron Tateisi Electronics Co filed Critical Omron Corp
Priority to JP2015047515A priority Critical patent/JP2016165746A/en
Priority to PCT/JP2016/056090 priority patent/WO2016143586A1/en
Publication of JP2016165746A publication Critical patent/JP2016165746A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/04Automatically aligning, aiming or focusing the laser beam, e.g. using the back-scattered light
    • B23K26/046Automatically focusing the laser beam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • B29C65/1603Laser beams characterised by the type of electromagnetic radiation
    • B29C65/1612Infrared [IR] radiation, e.g. by infrared lasers
    • B29C65/1616Near infrared radiation [NIR], e.g. by YAG lasers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/02Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
    • B23K26/06Shaping the laser beam, e.g. by masks or multi-focusing
    • B23K26/062Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam
    • B23K26/0622Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/08Devices involving relative movement between laser beam and workpiece
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/352Working by laser beam, e.g. welding, cutting or boring for surface treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K26/00Working by laser beam, e.g. welding, cutting or boring
    • B23K26/50Working by transmitting the laser beam through or within the workpiece
    • B23K26/57Working by transmitting the laser beam through or within the workpiece the laser beam entering a face of the workpiece from which it is transmitted through the workpiece material to work on a different workpiece face, e.g. for effecting removal, fusion splicing, modifying or reforming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • B29C65/1629Laser beams characterised by the way of heating the interface
    • B29C65/1635Laser beams characterised by the way of heating the interface at least passing through one of the parts to be joined, i.e. laser transmission welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • B29C65/1629Laser beams characterised by the way of heating the interface
    • B29C65/1654Laser beams characterised by the way of heating the interface scanning at least one of the parts to be joined
    • B29C65/1661Laser beams characterised by the way of heating the interface scanning at least one of the parts to be joined scanning repeatedly, e.g. quasi-simultaneous laser welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/78Means for handling the parts to be joined, e.g. for making containers or hollow articles, e.g. means for handling sheets, plates, web-like materials, tubular articles, hollow articles or elements to be joined therewith; Means for discharging the joined articles from the joining apparatus
    • B29C65/7802Positioning the parts to be joined, e.g. aligning, indexing or centring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/02Preparation of the material, in the area to be joined, prior to joining or welding
    • B29C66/024Thermal pre-treatments
    • B29C66/0246Cutting or perforating, e.g. burning away by using a laser or using hot air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/118Single monotone curved joints
    • B29C66/1182Single monotone curved joints the joint being C-shaped
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/124Tongue and groove joints
    • B29C66/1244Tongue and groove joints characterised by the male part, i.e. the part comprising the tongue
    • B29C66/12443Tongue and groove joints characterised by the male part, i.e. the part comprising the tongue having the tongue substantially in the middle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/124Tongue and groove joints
    • B29C66/1246Tongue and groove joints characterised by the female part, i.e. the part comprising the groove
    • B29C66/12463Tongue and groove joints characterised by the female part, i.e. the part comprising the groove being tapered
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/126Tenon and mortise joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/20Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines
    • B29C66/21Particular design of joint configurations particular design of the joint lines, e.g. of the weld lines said joint lines being formed by a single dot or dash or by several dots or dashes, i.e. spot joining or spot welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/301Three-dimensional joints, i.e. the joined area being substantially non-flat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/303Particular design of joint configurations the joint involving an anchoring effect
    • B29C66/3032Particular design of joint configurations the joint involving an anchoring effect making use of protrusions or cavities belonging to at least one of the parts to be joined
    • B29C66/30325Particular design of joint configurations the joint involving an anchoring effect making use of protrusions or cavities belonging to at least one of the parts to be joined making use of cavities belonging to at least one of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/74Joining plastics material to non-plastics material
    • B29C66/742Joining plastics material to non-plastics material to metals or their alloys
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/83General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
    • B29C66/832Reciprocating joining or pressing tools
    • B29C66/8322Joining or pressing tools reciprocating along one axis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/721Fibre-reinforced materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/72General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the structure of the material of the parts to be joined
    • B29C66/721Fibre-reinforced materials
    • B29C66/7212Fibre-reinforced materials characterised by the composition of the fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7392General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7394General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoset
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/74Joining plastics material to non-plastics material
    • B29C66/742Joining plastics material to non-plastics material to metals or their alloys
    • B29C66/7422Aluminium or alloys of aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/74Joining plastics material to non-plastics material
    • B29C66/742Joining plastics material to non-plastics material to metals or their alloys
    • B29C66/7428Transition metals or their alloys
    • B29C66/74281Copper or alloys of copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/74Joining plastics material to non-plastics material
    • B29C66/742Joining plastics material to non-plastics material to metals or their alloys
    • B29C66/7428Transition metals or their alloys
    • B29C66/74283Iron or alloys of iron, e.g. steel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/90Measuring or controlling the joining process
    • B29C66/91Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux
    • B29C66/919Measuring or controlling the joining process by measuring or controlling the temperature, the heat or the thermal flux characterised by specific temperature, heat or thermal flux values or ranges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/90Measuring or controlling the joining process
    • B29C66/92Measuring or controlling the joining process by measuring or controlling the pressure, the force, the mechanical power or the displacement of the joining tools
    • B29C66/929Measuring or controlling the joining process by measuring or controlling the pressure, the force, the mechanical power or the displacement of the joining tools characterized by specific pressure, force, mechanical power or displacement values or ranges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/90Measuring or controlling the joining process
    • B29C66/93Measuring or controlling the joining process by measuring or controlling the speed
    • B29C66/939Measuring or controlling the joining process by measuring or controlling the speed characterised by specific speed values or ranges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0079Liquid crystals

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  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
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  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

PROBLEM TO BE SOLVED: To provide a laser device which inhibits energy loss in laser processing, and to provide a joint structure manufactured by using the laser device and a manufacturing method of the joint structure.SOLUTION: A manufacturing method of a joint structure includes a joint step in which a second member (a resin member 3) is placed to face a first member (a metal member 2) and joined thereto. The manufacturing method of the joint structure includes a recessed part formation step in which a recessed part o, which is to be filled with the second member, is formed on a joint surface BP in the first member before the joint step. The recessed part formation step is performed in a state that the first member (the metal member 2) is rotating so that the joint surface BP of the first member (the metal member 2) is arranged perpendicular to a radiation direction of a processing laser 11a which forms the recessed part o in the first member (the metal member 2).SELECTED DRAWING: Figure 2

Description

本発明は、接合構造体の製造方法、接合構造体、及びレーザ装置に関する。   The present invention relates to a method for manufacturing a bonded structure, a bonded structure, and a laser device.

従来から、三次元レーザ加工機が記載された文献として、特許文献1が知られている。   Conventionally, Patent Document 1 is known as a document describing a three-dimensional laser processing machine.

特許文献1には、被加工物に照射されるレーザ光の焦点位置を所定位置に設定することにより、被加工物に高精度なレーザ加工を施す三次元レーザ加工機であって、被加工物の三次元形状を測定する三次元形状測定器が備えられており、三次元形状測定器によって測定した被加工物の三次元形状データに基づいて、レーザ光の焦点位置を設定する三次元レーザ加工機が開示されている。   Patent Document 1 discloses a three-dimensional laser processing machine that performs high-precision laser processing on a workpiece by setting the focal position of laser light applied to the workpiece to a predetermined position. 3D shape measuring device that measures the 3D shape of the 3D laser processing that sets the focal position of the laser beam based on the 3D shape data of the workpiece measured by the 3D shape measuring device A machine is disclosed.

この三次元レーザ加工機によれば、三次元形状測定器によって測定した被加工物の三次元形状データに基づいて、レーザ光と被加工物との間の距離を設定してレーザ加工を施すことができる。   According to this three-dimensional laser processing machine, laser processing is performed by setting the distance between the laser beam and the workpiece based on the three-dimensional shape data of the workpiece measured by the three-dimensional shape measuring instrument. Can do.

特開2014−133248号公報JP 2014-133248 A

しかしながら、特許文献1の三次元レーザ加工機で被加工物をレーザ加工すると、次のような不都合があった。以下、この点について図15A及び図15Bを参照しながら説明する。図15Aは、従来のレーザ加工方法を示す模式図、図15Bは、従来のレーザ加工方法で加工された被加工物を説明する説明図である。   However, when the workpiece is laser processed with the three-dimensional laser processing machine of Patent Document 1, there are the following disadvantages. This point will be described below with reference to FIGS. 15A and 15B. FIG. 15A is a schematic diagram illustrating a conventional laser processing method, and FIG. 15B is an explanatory diagram illustrating a workpiece processed by the conventional laser processing method.

特許文献1のレーザ加工方法では、被加工物200におけるレーザ照射面が例えば凸面210である場合、加工用レーザLからのレーザ光を被加工物200に向けて照射すると、凸面210によって反射光Rが生じる。このように反射光Rが発生すると、反射光Rに相当するエネルギー損失が生じるため、被加工物200の凹状部220の加工深さが設定よりも浅く加工される問題があった。   In the laser processing method of Patent Document 1, when the laser irradiation surface of the workpiece 200 is, for example, the convex surface 210, when the laser light from the processing laser L is irradiated toward the workpiece 200, the reflected light R is reflected by the convex surface 210. Occurs. When the reflected light R is generated in this way, an energy loss corresponding to the reflected light R occurs, so that there is a problem that the processing depth of the concave portion 220 of the workpiece 200 is processed to be shallower than the setting.

本発明は、かかる点に鑑みてなされたものであり、その目的とするところは、レーザ加工においてエネルギー損失を抑制することができるレーザ装置及び、このレーザ装置を用いて製造された接合構造体、並びにこの接合構造体の製造方法を提供することにある。   The present invention has been made in view of the above points, and its object is to provide a laser device capable of suppressing energy loss in laser processing, and a bonded structure manufactured using the laser device, Another object of the present invention is to provide a method for manufacturing the joined structure.

上記目的を達するために、本発明は次のとおりの構成としている。   In order to achieve the above object, the present invention is configured as follows.

本発明に係る接合構造体の製造方法は、第1部材に第2部材を対峙させて接合する接合工程を備えた接合構造体の製造方法であって、前記接合工程を行う前に、前記第1部材における接合面に前記第2部材が充填される凹状部を形成する凹状部形成工程が備えられており、前記凹状部形成工程は、前記第1部材に凹状部を形成する加工用レーザの照射方向に対して、前記第1部材の接合面が垂直となるように、前記第1部材を回転させて行われることを特徴とする。   The method for manufacturing a bonded structure according to the present invention is a method for manufacturing a bonded structure including a bonding process in which a second member is opposed to a first member and bonded to the first member. A concave portion forming step of forming a concave portion filled with the second member on a joint surface of one member is provided, and the concave portion forming step is a processing laser for forming a concave portion on the first member. The first member is rotated so that the bonding surface of the first member is perpendicular to the irradiation direction.

また、上記接合構造体の製造方法であって、前記レーザ照射は、前記第1部材の接合面に対して焦点位置を調整しながら行われてもよい。   Moreover, it is a manufacturing method of the said joining structure, Comprising: The said laser irradiation may be performed, adjusting a focus position with respect to the joint surface of a said 1st member.

また、上記接合構造体の製造方法であって、前記接合工程は、前記第1部材と前記第2部材とを接合させる接合用レーザの照射方向に対して、前記接合面が垂直となるように、前記第1部材及び前記第2部材を回転させて行われてもよい。   Further, in the manufacturing method of the bonded structure, the bonding step is such that the bonding surface is perpendicular to the irradiation direction of a bonding laser for bonding the first member and the second member. The first member and the second member may be rotated.

また、上記接合構造体の製造方法であって、前記第1部材における前記第2部材と対峙される面は、凸形状であってもよい。   Moreover, it is a manufacturing method of the said joining structure, Comprising: A convex shape may be sufficient as the surface facing the said 2nd member in a said 1st member.

また、上記接合構造体の製造方法であって、前記凹状部形成工程では、1パルスが複数のサブパルスで構成されるレーザを照射することによって前記凹状部を形成してもよい。   Moreover, it is a manufacturing method of the said junction structure, Comprising: In the said recessed part formation process, you may form the said recessed part by irradiating the laser with which 1 pulse consists of several subpulses.

また、上記接合構造体の製造方法であって、前記第1部材には、金属、熱可塑性樹脂、又は、熱硬化樹脂が用いられていてもよい。   Moreover, it is a manufacturing method of the said joining structure, Comprising: A metal, a thermoplastic resin, or a thermosetting resin may be used for the said 1st member.

また、上記接合構造体の製造方法であって、前記第2部材には、レーザを透過する樹脂が用いられていてもよい。   In the method for manufacturing the bonded structure, a resin that transmits a laser may be used for the second member.

本発明に係る接合構造体は、上記接合構造体の製造方法によって製造されたことを特徴とする。   The bonded structure according to the present invention is manufactured by the method for manufacturing a bonded structure.

本発明に係るレーザ装置は、被照射部材に向けてレーザ光を照射するレーザと、前記レーザの照射方向に対して前記被照射部材が垂直となるように、前記被照射部材を回転させる回転手段と、が備えられており、前記レーザは、1パルスが複数のサブパルスを照射することを特徴とする。   The laser apparatus according to the present invention includes a laser that irradiates a laser beam toward the irradiated member, and a rotating unit that rotates the irradiated member so that the irradiated member is perpendicular to the irradiation direction of the laser. The laser is characterized in that one pulse irradiates a plurality of sub-pulses.

本発明によれば、レーザ加工においてエネルギー損失を抑制することができるレーザ装置及び、このレーザ装置を用いて製造された接合構造体、並びにこの接合構造体の製造方法を提供することができる。   ADVANTAGE OF THE INVENTION According to this invention, the laser apparatus which can suppress energy loss in laser processing, the junction structure manufactured using this laser apparatus, and the manufacturing method of this junction structure can be provided.

本発明に係るレーザ装置の構成を説明する説明図である。It is explanatory drawing explaining the structure of the laser apparatus based on this invention. 本発明に係る接合構造体の製造方法における凹状部形成工程を説明する説明図である。It is explanatory drawing explaining the recessed part formation process in the manufacturing method of the joining structure which concerns on this invention. 本発明に係る接合構造体の製造方法における凹状部形成工程を説明する説明図である。It is explanatory drawing explaining the recessed part formation process in the manufacturing method of the joining structure which concerns on this invention. 本発明に係る接合構造体の製造方法における接合工程を説明する説明図である。It is explanatory drawing explaining the joining process in the manufacturing method of the joining structure which concerns on this invention. 本発明に係る接合構造体の製造方法における接合工程を説明する説明図である。It is explanatory drawing explaining the joining process in the manufacturing method of the joining structure which concerns on this invention. 本発明に係る接合構造体の製造方法における接合工程を説明する説明図である。It is explanatory drawing explaining the joining process in the manufacturing method of the joining structure which concerns on this invention. 本発明に係る接合構造体の製造方法における接合工程を説明する説明図である。It is explanatory drawing explaining the joining process in the manufacturing method of the joining structure which concerns on this invention. 本発明に係る接合構造体の斜視図である。It is a perspective view of the junction structure concerning the present invention. 本発明に係る他の接合構造体の製造方法における凹状部形成工程を説明する説明図である。It is explanatory drawing explaining the recessed part formation process in the manufacturing method of the other joining structure which concerns on this invention. 本発明に係る他の接合構造体の製造方法における凹状部形成工程を説明する説明図である。It is explanatory drawing explaining the recessed part formation process in the manufacturing method of the other joining structure which concerns on this invention. 本発明に係る他の接合構造体の製造方法における接合工程を説明する説明図である。It is explanatory drawing explaining the joining process in the manufacturing method of the other joined structure which concerns on this invention. 本発明に係る他の接合構造体の製造方法における接合工程を説明する説明図である。It is explanatory drawing explaining the joining process in the manufacturing method of the other joined structure which concerns on this invention. 本発明に係る他の接合構造体の製造方法における接合工程を説明する説明図である。It is explanatory drawing explaining the joining process in the manufacturing method of the other joined structure which concerns on this invention. 本発明に係る他の接合構造体の斜視図である。It is a perspective view of the other junction structure concerning the present invention. 従来のレーザ加工方法を示す模式図である。It is a schematic diagram which shows the conventional laser processing method. 従来のレーザ加工方法で加工された被加工物を説明する説明図である。It is explanatory drawing explaining the to-be-processed object processed with the conventional laser processing method.

以下、本発明に係るレーザ装置の実施形態を説明した後に、当該レーザ装置を用いた接合構造体の製造方法の実施形態について説明する。なお、本発明に係る接合構造体の説明は、接合構造体の製造方法の説明を以ってこれに代える。   Hereinafter, after describing an embodiment of a laser device according to the present invention, an embodiment of a method for manufacturing a bonded structure using the laser device will be described. In addition, description of the joining structure which concerns on this invention replaces with this by description of the manufacturing method of a joining structure.

図1は、レーザ装置の構成を説明する説明図、図2及び図3は、凹状部形成工程を説明する説明図、図4〜図7は、接合工程を説明する説明図、図8は、接合構造体の斜視図である。   FIG. 1 is an explanatory diagram for explaining a configuration of a laser device, FIGS. 2 and 3 are explanatory diagrams for explaining a concave portion forming process, FIGS. 4 to 7 are explanatory diagrams for explaining a joining process, and FIG. It is a perspective view of a junction structure.

[レーザ装置]
本発明に係るレーザ装置10は、被照射部材に向けてレーザ照射するレーザと、走査手段12と、位置調整手段13と、回転手段14と、が備えられている(図1参照)。
[Laser device]
The laser apparatus 10 according to the present invention includes a laser that irradiates a target member with laser, a scanning unit 12, a position adjusting unit 13, and a rotating unit 14 (see FIG. 1).

被照射部材は、例えば、後述する本発明に係る接合構造体の場合では、第1部材(金属部材2)又は第2部材(樹脂部材3)である。   The irradiated member is, for example, a first member (metal member 2) or a second member (resin member 3) in the case of a bonded structure according to the present invention described later.

レーザは、一例として、金属部材2を加工する加工用レーザ11aが挙げられる。加工用レーザ11aの種類としては、ファイバレーザ、YAGレーザ、YVOレーザ、半導体レーザ、炭酸ガスレーザ、エキシマレーザが選択できる。レーザの波長を考慮すると、ファイバレーザ、YAGレーザ、YAGレーザの第2高調波、YVOレーザ、半導体レーザが好ましい。さらに、金属部材2の加工形状に応じて、パルス発振可能なレーザであってもよく、さらには、1パルスが複数のサブパルスで構成されていてもよい。 As an example of the laser, a processing laser 11a for processing the metal member 2 can be given. As the type of the processing laser 11a, a fiber laser, a YAG laser, a YVO 4 laser, a semiconductor laser, a carbon dioxide gas laser, or an excimer laser can be selected. Considering the wavelength of the laser, a fiber laser, a YAG laser, a second harmonic of a YAG laser, a YVO 4 laser, and a semiconductor laser are preferable. Further, a laser capable of pulse oscillation may be used according to the processing shape of the metal member 2, and one pulse may be composed of a plurality of subpulses.

走査手段12は、加工用レーザ11aから照射されたレーザ光を被照射部材(金属部材2又は樹脂部材3)の照射面に対して水平方向(図1のX方向及びY方向)に走査させるものである。一例として、ガルバノミラーとテレセントリックfθレンズを用いて被照射部材の水平方向に走査させる手段が挙げられる。すなわち、ガルバノミラーを動作させることによって、レーザ光をガルバノミラーで走査可能な走査範囲A(図1参照)内で反射させるとともに、コリメーションレンズにより、被照射部材における照射面に対して垂直にレーザ光を照射させることができる。なお、レーザの走査は、後述するとおり位置調整手段13によって行われてもよい。   The scanning unit 12 scans the laser beam irradiated from the processing laser 11a in the horizontal direction (X direction and Y direction in FIG. 1) with respect to the irradiation surface of the irradiated member (metal member 2 or resin member 3). It is. As an example, there is a means for scanning the irradiated member in the horizontal direction using a galvano mirror and a telecentric fθ lens. That is, by operating the galvanometer mirror, the laser beam is reflected within a scanning range A (see FIG. 1) that can be scanned by the galvanometer mirror, and the laser beam is perpendicular to the irradiation surface of the irradiated member by the collimation lens. Can be irradiated. The laser scanning may be performed by the position adjusting unit 13 as described later.

位置調整手段13は、加工用レーザ11aからのレーザ光の焦点位置を調整するものである。本実施形態では、後述するステージ14aを鉛直方向に動作させることによってレーザ光の焦点位置を調整させている。また、位置調整手段13は、鉛直動作に限定されず、ステージ14aを水平方向に動作させてもよい。これにより、ガルバノミラーの走査範囲Aを超える範囲であっても、被照射部材における照射面に対して垂直にレーザ光を照射させることができる。なお、位置調整手段13の前述の形態に限られず、加工用レーザ11a自体を鉛直又は水平方向に動作させてもよい。   The position adjusting means 13 adjusts the focal position of the laser beam from the processing laser 11a. In the present embodiment, the focal position of the laser beam is adjusted by operating a stage 14a described later in the vertical direction. Further, the position adjusting means 13 is not limited to the vertical operation, and the stage 14a may be operated in the horizontal direction. Thereby, even if it is the range exceeding the scanning range A of a galvanometer mirror, a laser beam can be irradiated perpendicularly | vertically with respect to the irradiation surface in a to-be-irradiated member. The position adjusting means 13 is not limited to the above-described form, and the processing laser 11a itself may be operated in the vertical or horizontal direction.

回転手段14は、加工用レーザ11aから照射されたレーザ光の照射方向に対して被照射部材(金属部材2又は樹脂部材3)が垂直となるように、被照射部材を回転させるものであり、被照射部材を載置するステージ14aと、ステージ14aを回転させる回転軸14bと、が備えられている(図1参照)。回転軸14bは、図示例において、X軸周りに回転させることができるとともに、Y軸周りに回転させることも可能である。なお、回転手段14及び位置調整手段13は、上述した走査手段12の走査速度と同期させて所望の位置にレーザを照射してレーザ加工するように制御されていてもよい。   The rotating means 14 rotates the irradiated member so that the irradiated member (metal member 2 or resin member 3) is perpendicular to the irradiation direction of the laser beam emitted from the processing laser 11a. A stage 14a on which the irradiated member is placed and a rotating shaft 14b for rotating the stage 14a are provided (see FIG. 1). In the illustrated example, the rotation shaft 14b can be rotated around the X axis and can also be rotated around the Y axis. The rotating unit 14 and the position adjusting unit 13 may be controlled so as to perform laser processing by irradiating a laser at a desired position in synchronization with the scanning speed of the scanning unit 12 described above.

以上、本発明に係るレーザ装置10として、レーザが加工用レーザ11aとする実施形態(図1)について説明したが、レーザの変形例として加工用レーザ11aに代えて、接合用レーザ11bであってもよい(図5参照)。この場合、接合用レーザ11bは、例えば、ファイバレーザ、YAGレーザ、YVO4レーザ、半導体レーザ、炭酸ガスレーザ、エキシマレーザとする。 As described above, the laser device 10 according to the present invention has been described with respect to the embodiment in which the laser is the processing laser 11a (FIG. 1). However, as a modified example of the laser, the laser 11 for bonding is used instead of the processing laser 11a. (See FIG. 5). In this case, the bonding laser 11b is, for example, a fiber laser, a YAG laser, a YVO 4 laser, a semiconductor laser, a carbon dioxide laser, or an excimer laser.

[接合構造体の製造方法]
本発明に係る接合構造体の製造方法について2つの実施形態を説明する。
[Method of manufacturing joined structure]
Two embodiments of the method for manufacturing a bonded structure according to the present invention will be described.

−第1実施形態−
本実施形態に係る接合構造体の製造方法は、第1部材に第2部材を対峙させて接合する接合構造体の製造方法であって、凹状部形成工程と、接合工程と、を備えている。
-First embodiment-
The manufacturing method of the bonded structure according to the present embodiment is a method of manufacturing a bonded structure in which the second member is opposed to the first member and bonded, and includes a concave portion forming step and a bonding step. .

第1部材は、金属部材2であり、金属の一例としては、鉄系金属、ステンレス系金属、銅系金属、アルミ系金属、マグネシウム系金属、および、それらの合金が挙げられる。また、金属成型体であってもよく、亜鉛ダイカスト、アルミダイカスト、粉末冶金などであってもよい。   The first member is the metal member 2, and examples of the metal include iron metal, stainless steel metal, copper metal, aluminum metal, magnesium metal, and alloys thereof. Moreover, a metal molding may be sufficient and zinc die-casting, aluminum die-casting, powder metallurgy, etc. may be sufficient.

第1部材(金属部材2)における後述する第2部材(樹脂部材3)と対峙される面は、凸形状である。本実施形態の凸形状は、湾曲面とされている。   The surface of the first member (metal member 2) that faces a second member (resin member 3) described later has a convex shape. The convex shape of this embodiment is a curved surface.

第2部材は、レーザを透過する可撓性の樹脂部材3であり、熱可塑性樹脂、又は、熱硬化性樹脂である。熱可塑性樹脂の一例としては、PVC(ポリ塩化ビニル)、PS(ポリスチレン)、AS(アクリロニトリル・スチレン)、ABS(アクリロニトリル・ブタジエン・スチレン)、PMMA(ポリメチルメタクリレート)、PE(ポリエチレン)、PP(ポリプロピレン)、PC(ポリカーボネート)、m−PPE(変性ポリフェニレンエーテル)、PA6(ポリアミド6)、PA66(ポリアミド66)、POM(ポリアセタール)、PET(ポリエチレンテレフタレート)、PBT(ポリブチレンテレフタレート)、PSF(ポリサルホン)、PAR(ポリアリレート)、PEI(ポリエーテルイミド)、PPS(ポリフェニレンサルファイド)、PES(ポリエーテルサルホン)、PEEK(ポリエーテルエーテルケトン)、PAI(ポリアミドイミド)、LCP(液晶ポリマー)、PVDC(ポリ塩化ビニリデン)、PTFE(ポリテトラフルオロエチレン)、PCTFE(ポリクロロトリフルオロエチレン)、および、PVDF(ポリフッ化ビニリデン)が挙げられる。また、TPE(熱可塑性エラストマ)であってもよく、TPEの一例としては、TPO(オレフィン系)、TPS(スチレン系)、TPEE(エステル系)、TPU(ウレタン系)、TPA(ナイロン系)、および、TPVC(塩化ビニル系)が挙げられる。   The 2nd member is the flexible resin member 3 which permeate | transmits a laser, and is a thermoplastic resin or a thermosetting resin. Examples of thermoplastic resins include PVC (polyvinyl chloride), PS (polystyrene), AS (acrylonitrile styrene), ABS (acrylonitrile butadiene styrene), PMMA (polymethyl methacrylate), PE (polyethylene), PP ( Polypropylene), PC (polycarbonate), m-PPE (modified polyphenylene ether), PA6 (polyamide 6), PA66 (polyamide 66), POM (polyacetal), PET (polyethylene terephthalate), PBT (polybutylene terephthalate), PSF (polysulfone) ), PAR (polyarylate), PEI (polyetherimide), PPS (polyphenylene sulfide), PES (polyethersulfone), PEEK (polyetheretherketone), PAI ( Riamidoimido), LCP (liquid crystal polymer), PVDC (polyvinylidene chloride), PTFE (polytetrafluoroethylene), PCTFE (polychlorotrifluoroethylene), and include PVDF (poly (vinylidene fluoride)) it is. TPE (thermoplastic elastomer) may also be used, and examples of TPE include TPO (olefin-based), TPS (styrene-based), TPEE (ester-based), TPU (urethane-based), TPA (nylon-based), And TPVC (vinyl chloride type) is mentioned.

熱硬化性樹脂の一例としては、EP(エポキシ)、PUR(ポリウレタン)、UF(ユリアホルムアルデヒド)、MF(メラミンホルムアルデヒド)、PF(フェノールホルムアルデヒド)、UP(不飽和ポリエステル)、および、SI(シリコーン)が挙げられる。また、FRP(繊維強化プラスチック)であってもよい。   Examples of thermosetting resins include EP (epoxy), PUR (polyurethane), UF (urea formaldehyde), MF (melamine formaldehyde), PF (phenol formaldehyde), UP (unsaturated polyester), and SI (silicone) Is mentioned. Further, it may be FRP (fiber reinforced plastic).

なお、熱可塑性樹脂および熱硬化性樹脂には、充填剤が添加されていてもよい。充填剤の一例としては、無機系充填剤(ガラス繊維、無機塩類など)、金属系充填剤、有機系充填剤、および、炭素繊維などが挙げられる。   Note that a filler may be added to the thermoplastic resin and the thermosetting resin. Examples of the filler include inorganic fillers (glass fibers, inorganic salts, etc.), metal fillers, organic fillers, and carbon fibers.

また、第2部材(樹脂部材3)は、後述する接合工程において、樹脂部材3の上方からレーザ光を照射する場合は、レーザ光を透過する材料が好ましく、その透過率は、厚みが3mmのときに15%以上であることが好ましい。一方、後述する接合工程において、樹脂部材3の下方からレーザ光を照射する場合は、樹脂部材3はレーザ透過性を有していなくてもよい。   The second member (resin member 3) is preferably made of a material that transmits laser light when the laser beam is irradiated from above the resin member 3 in the joining step described later. The transmittance is 3 mm. Sometimes it is preferably 15% or more. On the other hand, in the joining process described later, when the laser beam is irradiated from below the resin member 3, the resin member 3 may not have laser transparency.

樹脂部材3における金属部材2と対峙される面(接合面BP)は、前述した金属部材2の湾曲面に対応した凹面形状である。   A surface (bonding surface BP) facing the metal member 2 in the resin member 3 has a concave shape corresponding to the curved surface of the metal member 2 described above.

以下、本実施形態に係る接合構造体の製造方法の各工程について説明する。   Hereinafter, each process of the manufacturing method of the junction structure concerning this embodiment is explained.

・凹状部形成工程
凹状部形成工程は、金属部材2における接合面BPに、樹脂部材3が充填される凹状部oを形成する工程であり、加工用レーザ11aを備えたレーザ装置10を用いて行われる。加工用レーザ11aの一例としては、オムロン製のファイバレーザマーカMXZ2000又はMX−Z2050を挙げることができる。
-Concave part formation process A concave part formation process is a process of forming the concave part o by which the resin member 3 is filled in the joint surface BP in the metal member 2, and uses the laser apparatus 10 provided with the processing laser 11a. Done. As an example of the processing laser 11a, an Omron fiber laser marker MXZ2000 or MX-Z2050 can be cited.

まず、金属部材2をステージ14aに載置する(図1参照)。そして、本実施形態では、まず最初に、走査手段12の走査範囲Aを超える位置における金属部材2の接合面BPに凹状部oを形成するため、位置調整手段13によって、凹状部oを形成する位置が走査範囲A内に入るように、ステージ14aを移動させる。   First, the metal member 2 is placed on the stage 14a (see FIG. 1). In this embodiment, first, the concave portion o is formed by the position adjusting means 13 in order to form the concave portion o on the joint surface BP of the metal member 2 at a position exceeding the scanning range A of the scanning means 12. The stage 14a is moved so that the position falls within the scanning range A.

次に、回転軸14bによって、金属部材2の接合面BPに対して垂直に加工用レーザ11aからのレーザ光が照射されるように、回転軸14bによってステージ14aを回転させる(図2参照)。   Next, the stage 14a is rotated by the rotating shaft 14b so that the laser beam from the processing laser 11a is irradiated perpendicularly to the joint surface BP of the metal member 2 by the rotating shaft 14b (see FIG. 2).

次に、位置調整手段13によって、加工用レーザ11aから照射されるレーザ光の焦点位置を、金属部材2の接合面BPに位置調節する。すなわち、ステージ14aを上下動させる。   Next, the position adjusting means 13 adjusts the position of the focal point of the laser light emitted from the processing laser 11 a to the joint surface BP of the metal member 2. That is, the stage 14a is moved up and down.

そして、金属部材2における凹状部oを形成する位置に加工用レーザ11aからのレーザ光としてパルス光(好ましくはサブパルス光)を照射する。   And the pulsed light (preferably subpulsed light) is irradiated to the position which forms the recessed part o in the metal member 2 as a laser beam from the processing laser 11a.

ここで、オムロン製のファイバレーザマーカでは、1パルスが複数のサブパルスで構成されるレーザ光を照射することが可能である。このため、レーザ光のエネルギーを深さ方向に集中させやすいので、凹状部oを形成するのに好適である。   Here, in the fiber laser marker made from OMRON, it is possible to irradiate the laser beam which 1 pulse consists of several subpulses. For this reason, the energy of the laser beam is easily concentrated in the depth direction, which is suitable for forming the concave portion o.

具体的には、金属部材2にレーザ光が照射されると、金属部材2が局部的に溶融されることにより凹状部oの形成が進行する。このとき、レーザ光が複数のサブパルスで構成されているため、溶融された金属部材2が飛散されにくく、凹状部oの近傍に堆積されやすい。そして、凹状部oの形成が進行すると、溶融された金属部材2が凹状部oの内部に堆積されることにより、凹状部oの内周面に、内側に突出する突出部tが形成される。   Specifically, when the metal member 2 is irradiated with laser light, the metal member 2 is locally melted to advance the formation of the concave portion o. At this time, since the laser beam is composed of a plurality of sub-pulses, the molten metal member 2 is not easily scattered and easily deposited in the vicinity of the concave portion o. Then, as the formation of the concave portion o proceeds, the molten metal member 2 is deposited inside the concave portion o, so that a protruding portion t protruding inward is formed on the inner peripheral surface of the concave portion o. .

本実施形態では、突出部tの形成位置は、凹状部oの開口近傍位置であるが、上記ファイバレーザマーカによる加工条件により、開口端に形成されていてもよいし、凹状部oの底部近傍位置に形成されていてもよい。   In the present embodiment, the projecting portion t is formed at a position near the opening of the concave portion o, but may be formed at the opening end depending on the processing conditions by the fiber laser marker, or may be near the bottom of the concave portion o. It may be formed.

なお、上記ファイバレーザマーカによる加工条件としては、サブパルスの1周期が15ns以下であることが好ましい。これは、サブパルスの1周期が15nsを超えると、熱伝導によりエネルギーが拡散しやすくなり、突出部tを有する凹状部oを形成しにくくなるためである。なお、サブパルスの1周期は、サブパルスの1回分の照射時間と、そのサブパルスの照射が終了されてから次回のサブパルスの照射が開始されるまでの間隔との合計時間である。   As a processing condition by the fiber laser marker, it is preferable that one period of the sub-pulse is 15 ns or less. This is because when one period of the sub-pulse exceeds 15 ns, energy is easily diffused by heat conduction, and it becomes difficult to form the concave portion o having the protruding portion t. Note that one cycle of the subpulse is a total time of the irradiation time for one subpulse and the interval from the end of the irradiation of the subpulse to the start of the irradiation of the next subpulse.

また、上記ファイバレーザマーカによる加工条件としては、1パルスのサブパルス数は、2以上50以下であることが好ましい。これは、サブパルス数が50を超えると、サブパルスの単位あたりの出力が小さくなり、突出部tを有する凹状部oを形成しにくくなるためである。   Further, as a processing condition by the fiber laser marker, the number of subpulses of one pulse is preferably 2 or more and 50 or less. This is because if the number of subpulses exceeds 50, the output per unit of subpulses becomes small, and it becomes difficult to form the concave portion o having the protruding portion t.

凹状部oの開口径は、30μm以上、100μm以下が好ましい。これは、開口径が30μmを下回ると、後述する接合工程において、照射された接合用レーザ11b(図4参照)からのレーザ光が凹状部o内に十分に閉じ込められず、レーザ光のエネルギーを熱に変換する変換効率が低下する場合があるためである。一方、開口径が100μmを上回ると、単位面積あたりの凹状部oの数が減少して、レーザ光のエネルギーを熱に変換する変換効率が低下する場合があるためである。   The opening diameter of the concave portion o is preferably 30 μm or more and 100 μm or less. This is because if the opening diameter is less than 30 μm, the laser beam from the irradiated bonding laser 11b (see FIG. 4) is not sufficiently confined in the concave portion o in the bonding step described later, and the energy of the laser beam is reduced. This is because the conversion efficiency for conversion into heat may be reduced. On the other hand, if the opening diameter exceeds 100 μm, the number of concave portions o per unit area decreases, and conversion efficiency for converting the energy of the laser light into heat may decrease.

また、凹状部oの深さは、10μm以上であることが好ましい。これは、深さが10μmを下回ると、後述する接合用レーザ11bからのレーザ光のエネルギーを熱に変換する変換効率が低下する場合があるためである。本実施形態では、凹状部oの加工深さは43μm〜45μmとする。   Moreover, it is preferable that the depth of the recessed part o is 10 micrometers or more. This is because if the depth is less than 10 μm, the conversion efficiency for converting the energy of laser light from the bonding laser 11b described later into heat may be reduced. In the present embodiment, the processing depth of the concave portion o is 43 μm to 45 μm.

1つ目の凹状部oを形成後、金属部材2に2つ目の凹状部oを形成する。ここで、2つ目の凹状部oの形成する位置が、走査範囲A内に入っている場合は、上述したとおり、回転軸14bによってステージ14aを回転させるとともに位置調整手段13によって昇降させて、凹状部oの形成を行う。一方、走査範囲A内に入っていない場合は、位置調整手段13によって、ステージ14aを走査範囲A内に移動させた後に、上述したとおり、回転軸14bによってステージ14aを回転させるとともに位置調整手段13によって昇降させて、凹状部oの形成を行う。   After forming the first concave portion o, the second concave portion o is formed in the metal member 2. Here, when the position formed by the second concave portion o is within the scanning range A, as described above, the stage 14a is rotated by the rotating shaft 14b and moved up and down by the position adjusting means 13, The concave portion o is formed. On the other hand, if not within the scanning range A, after the stage 14a is moved into the scanning range A by the position adjusting means 13, the stage 14a is rotated by the rotating shaft 14b and the position adjusting means 13 as described above. The concave portion o is formed by raising and lowering.

上述した工程を、凹状部oを形成する個数分、繰り返し行う(図3は、3つ目の凹状部oを形成している状態を模式的に説明している。)
ここで、凹状部oの間隔(所定の凹状部oの中心と、所定の凹状部oと隣接する凹状部oの中心との距離)は、200μm以下であることが好ましい。これは、凹状部oの間隔が200μmを上回ると、単位面積あたりの凹状部oの数が減少して、後述する接合用レーザ11bからのレーザ光のエネルギーを熱に変換する変換効率が低下する場合があるためである。なお、凹状部oの間隔の下限の一例としては、凹状部oが重畳して潰れない距離である。また、凹状部oの間隔は等間隔であることが好ましい。これは、凹状部oが等間隔であると、接合用のレーザが照射される際の熱の分布が等方的になるためである。
The above-described steps are repeated for the number of the concave portions o to be formed (FIG. 3 schematically illustrates a state in which the third concave portion o is formed).
Here, the interval between the concave portions o (the distance between the center of the predetermined concave portion o and the center of the concave portion o adjacent to the predetermined concave portion o) is preferably 200 μm or less. This is because when the interval between the concave portions o exceeds 200 μm, the number of the concave portions o per unit area decreases, and the conversion efficiency for converting the energy of laser light from the bonding laser 11b described later into heat decreases. This is because there are cases. An example of the lower limit of the interval between the concave portions o is a distance at which the concave portions o are not overlapped and crushed. Moreover, it is preferable that the interval of the recessed part o is an equal interval. This is because when the concave portions o are equally spaced, the heat distribution when the bonding laser is irradiated becomes isotropic.

以上説明したとおり、凹状部形成工程では、凹状部形成工程では、金属部材2におけるレーザ光の照射面(接合面BP)に対して垂直方向にレーザを照射することができるので、図15Bに示した従来技術と異なり、反射光に相当するエネルギー損失を抑制して金属部材2を加工することができる。   As described above, in the concave portion forming step, since the concave portion forming step can irradiate the laser beam in the direction perpendicular to the laser light irradiation surface (bonding surface BP) in the metal member 2, as shown in FIG. 15B. Unlike the prior art, the metal member 2 can be processed while suppressing energy loss corresponding to reflected light.

なお、本実施形態において、金属部材2の接合面BPに対して垂直とは、接合面BPとレーザ光とのなす角度が厳密に90°である必要はなく、80°から100°の範囲にあればよい。上記範囲であれば、反射光に相当するエネルギー損失を低減することができる。   In the present embodiment, the term “perpendicular to the bonding surface BP of the metal member 2” does not require the angle between the bonding surface BP and the laser light to be strictly 90 °, and is in the range of 80 ° to 100 °. I just need it. If it is the said range, the energy loss equivalent to reflected light can be reduced.

また、本実施形態の凹状部形成工程によれば、位置調整手段13によって焦点位置が調節されるため、焦点距離のずれによる加工ばらつきを低減することができる。   Further, according to the concave portion forming step of the present embodiment, since the focal position is adjusted by the position adjusting means 13, processing variations due to the shift of the focal length can be reduced.

なお、凹状部形成工程における加工用レーザの加工条件の一例を以下に記載する。   An example of the processing conditions of the processing laser in the concave portion forming step will be described below.

<加工用レーザにおける加工条件>
レーザ:ファイバレーザ(波長1062nm)
周波数:10kHz
出力:3.8W
走査速度:650mm/sec
走査回数:40回
照射間隔:65μm
サブパルス数:20
<Processing conditions for processing laser>
Laser: Fiber laser (wavelength 1062nm)
Frequency: 10kHz
Output: 3.8W
Scanning speed: 650mm / sec
Number of scans: 40 times Irradiation interval: 65 μm
Number of subpulses: 20

・接合工程
接合工程は、金属部材2と樹脂部材3とを互いに接合する工程であり、上述した接合用レーザ11bを備えたレーザ装置を用いて行われる。
Bonding process The bonding process is a process of bonding the metal member 2 and the resin member 3 to each other, and is performed using a laser apparatus including the bonding laser 11b described above.

なお、本実施形態では、金属部材2と樹脂部材3とをレーザ接合させる形態を説明するが、この形態に限られず、樹脂部材3をヒータ等で加熱溶融させて接合させる方法や、金属部材2を収容する金型を用いてインサート成形させる方法等を用いてもよい。   In the present embodiment, a mode in which the metal member 2 and the resin member 3 are laser bonded will be described. However, the present invention is not limited to this mode, and the resin member 3 is heated and melted with a heater or the like, or the metal member 2 is bonded. For example, a method of insert molding using a mold that accommodates the material may be used.

また、金属部材2と樹脂部材3とのレーザ接合の方法としては、金属部材2を接合用レーザ11bにより加熱させることによって、金属部材2と接触している樹脂部材3に熱が伝わり、樹脂部材3を溶融させて接合させる方法と、樹脂部材3自体を接合用レーザ11bにより加熱溶融させて金属部材2と接合させる方法が挙げられる。   Further, as a method of laser joining of the metal member 2 and the resin member 3, heat is transmitted to the resin member 3 in contact with the metal member 2 by heating the metal member 2 with the joining laser 11b, and the resin member. And a method in which the resin member 3 itself is heated and melted by the bonding laser 11b and bonded to the metal member 2.

本実施形態では、接合用レーザ11bからのレーザ光を、透光性の樹脂部材3と金属部材2との接合面BPに照射させ、金属部材2を加熱させることにより金属部材2と接触している樹脂部材3に熱を伝え、樹脂部材3を溶融させて接合させる方法について説明する。   In the present embodiment, the laser beam from the bonding laser 11b is irradiated to the bonding surface BP between the translucent resin member 3 and the metal member 2, and the metal member 2 is heated to come into contact with the metal member 2. A method of transferring heat to the existing resin member 3 and melting and bonding the resin member 3 will be described.

まず、ステージ14aに載置された金属部材2の接合面BPに、樹脂部材3を載置する(図4参照)。まず最初に、走査手段12の走査範囲A(図5参照)を超える位置における金属部材2の凹状部oに樹脂部材3を充填するため、位置調整手段13によって、凹状部oが形成された位置が走査範囲A内に入るように、ステージ14aを移動させる。   First, the resin member 3 is placed on the joint surface BP of the metal member 2 placed on the stage 14a (see FIG. 4). First, in order to fill the resin member 3 into the concave portion o of the metal member 2 at a position exceeding the scanning range A (see FIG. 5) of the scanning means 12, the position where the concave portion o is formed by the position adjusting means 13 The stage 14a is moved so that is within the scanning range A.

次に、回転軸14bによって、金属部材2の接合面BPに対して垂直に接合用レーザ11bからのレーザ光が照射されるように、回転軸14bによってステージ14aを回転させる(図6参照)。   Next, the stage 14a is rotated by the rotating shaft 14b so that the laser beam from the bonding laser 11b is irradiated perpendicularly to the bonding surface BP of the metal member 2 by the rotating shaft 14b (see FIG. 6).

次に、位置調整手段13によって、接合用レーザ11bから照射されるレーザ光の焦点位置を、金属部材2の接合面BPに位置調節する。すなわち、ステージ14aを上下動させる。   Next, the position adjustment means 13 adjusts the focal position of the laser light emitted from the bonding laser 11 b to the bonding surface BP of the metal member 2. That is, the stage 14a is moved up and down.

そして、金属部材2における凹状部oを形成する位置に接合用レーザ11bからのレーザ光を連続発振によって照射する。   Then, the laser beam from the bonding laser 11b is irradiated to the position where the concave portion o in the metal member 2 is formed by continuous oscillation.

樹脂部材3と金属部材2との接合面BPにレーザ光を照射することにより、レーザ光のエネルギーが金属部材2の内部で熱に変換され、金属部材2の表面の温度が高くなる。これにより、金属部材2の表面近傍の樹脂部材3が溶融され、その樹脂部材3が凹状部oに充填される。本実施形態では、接合用レーザ11bからのレーザ光を走査手段12によって走査させるとともにレーザ光を連続発振させているので、金属部材2内の熱が拡散されて温度低下することを防ぎ、効率よく金属部材2を蓄熱させて温度を高めることができる。   By irradiating the joint surface BP between the resin member 3 and the metal member 2 with laser light, the energy of the laser light is converted into heat inside the metal member 2 and the surface temperature of the metal member 2 is increased. Thereby, the resin member 3 in the vicinity of the surface of the metal member 2 is melted, and the resin member 3 is filled in the concave portion o. In the present embodiment, since the laser beam from the bonding laser 11b is scanned by the scanning unit 12 and the laser beam is continuously oscillated, the heat in the metal member 2 is prevented from diffusing and the temperature is lowered, and the efficiency is improved. The temperature of the metal member 2 can be increased by storing heat.

1つ目の凹状部oに樹脂部材3を充填した後、2つ目の凹状部oに樹脂部材3を充填する。ここで、2つ目の凹状部oの位置が、走査範囲A内に入っている場合は、上述したとおり、回転軸14bによってステージ14aを回転させさせるとともに位置調整手段13によって昇降させて、凹状部oに樹脂部材3を充填する。一方、走査範囲A内に入っていない場合は、位置調整手段13によってステージ14aを走査範囲A内に移動させた後に、上述したとおり、回転軸14bによってステージ14aを回転させるとともに位置調整手段13によって昇降させて、凹状部oに樹脂部材3を充填する。   After the first concave portion o is filled with the resin member 3, the second concave portion o is filled with the resin member 3. Here, when the position of the second concave portion o is within the scanning range A, as described above, the stage 14a is rotated by the rotating shaft 14b and moved up and down by the position adjusting means 13 to form a concave shape. The portion o is filled with the resin member 3. On the other hand, if not within the scanning range A, after the stage 14a is moved into the scanning range A by the position adjusting means 13, the stage 14a is rotated by the rotating shaft 14b and the position adjusting means 13 as described above. The concave member o is filled with the resin member 3 by moving up and down.

上述した工程を、凹状部oの個数分、繰り返し行う(図7は、3つ目の凹状部oに樹脂部材3を充填している状態を模式的に説明している。)
このようにして、接合工程では、凹状部形成工程において接合面BPに対して垂直方向に形成された凹状部o内に、樹脂部材3を充填することによって金属部材2と樹脂部材3とを反射光によるエネルギー損失を抑制して接合させた接合構造体1(図8参照)を製造することができる。
The above-described steps are repeated for the number of the concave portions o (FIG. 7 schematically illustrates a state where the third concave portion o is filled with the resin member 3).
In this way, in the joining step, the metal member 2 and the resin member 3 are reflected by filling the resin member 3 into the concave portion o formed in the direction perpendicular to the joining surface BP in the concave portion forming step. A bonded structure 1 (see FIG. 8) bonded with suppressing energy loss due to light can be manufactured.

また、凹状部oに樹脂部材3を充填している間も位置調整手段13によってレーザ光の焦点位置が調節されるため、焦点距離のずれによる接合ばらつきが低減された接合構造体1を製造することができる。   In addition, since the focal position of the laser beam is adjusted by the position adjusting means 13 while the concave portion o is filled with the resin member 3, the bonded structure 1 in which the bonding variation due to the shift of the focal length is reduced is manufactured. be able to.

また、接合面BPに対して垂直方向に形成された凹状部o内に、樹脂部材3が充填されるので、図15Bの従来技術のような凹状部oが形成されている方向が一方向に揃っているものと比較してアンカー効果を高めることできる。従って、金属部材2と樹脂部材3との接合強度を向上させた接合構造体1を製造することができる。これについては、第1実施形態の実験例にて詳述する。   Further, since the resin member 3 is filled in the concave portion o formed in the direction perpendicular to the bonding surface BP, the direction in which the concave portion o as in the prior art of FIG. 15B is formed is one direction. An anchor effect can be heightened compared with what is prepared. Therefore, it is possible to manufacture the bonded structure 1 in which the bonding strength between the metal member 2 and the resin member 3 is improved. This will be described in detail in the experimental example of the first embodiment.

なお、接合工程における接合用レーザの照射条件の一例を以下に記載する。   An example of irradiation conditions of the bonding laser in the bonding process is described below.

<接合用レーザ照射条件>
レーザ:半導体レーザ(波長808nm)
発振モード:連続発振
出力:30W
焦点径:4mm
走査速度:1mm/sec
密着圧力:0.6MPa
<Laser irradiation conditions for bonding>
Laser: Semiconductor laser (wavelength 808 nm)
Oscillation mode: Continuous oscillation output: 30W
Focal diameter: 4mm
Scanning speed: 1mm / sec
Contact pressure: 0.6 MPa

−第1実施形態の実験例−
次に、上記した第1実施形態の効果を確認するために行った接合強度の評価について、本発明に係る実施例と、比較例とを比較しながら説明する。なお、実施例の接合構造体及び比較例の接合構造体ともに、樹脂部材の材料はPMMAとし、金属部材の材料はSUS304とした。
-Experimental example of the first embodiment-
Next, the evaluation of the bonding strength performed to confirm the effect of the first embodiment described above will be described while comparing the examples according to the present invention and the comparative examples. In addition, as for the joining structure of an Example and the joining structure of a comparative example, the material of the resin member was PMMA, and the material of the metal member was SUS304.

本発明に係る実施例では、上述した凹状部形成工程及び接合工程を行って接合構造体を製造した(例えば図6参照)。   In the Example which concerns on this invention, the recessed part formation process mentioned above and the joining process were performed, and the joining structure was manufactured (for example, refer FIG. 6).

また、比較例では、上述した凹状部形成工程において、金属部材における接合面に対して垂直に加工用レーザを照射していない(例えば、図15A及び図15B参照)。すなわち、比較例の接合構造体は、図15A及び図15Bで説明したとおり、金属部材に対してレーザ光を照射すると反射光Rが発生しており、この反射光Rに相当するレーザ光のエネルギー分の損失が生じるため、金属部材の凹状部が設定よりも浅く加工されている。   In the comparative example, in the above-described concave portion forming step, the processing laser is not irradiated perpendicularly to the joint surface of the metal member (see, for example, FIGS. 15A and 15B). That is, as described in FIGS. 15A and 15B, the bonded structure of the comparative example generates reflected light R when the metal member is irradiated with laser light. The energy of the laser light corresponding to the reflected light R is generated. Therefore, the concave portion of the metal member is processed shallower than the setting.

また、比較例の接合構造体では、各凹状部が形成される方向が一方向に揃っている。すなわち、金属部材において接合面に対して凹状部の形成角度が一定となっていない。   Moreover, in the joint structure of the comparative example, the direction in which each concave portion is formed is aligned in one direction. That is, the formation angle of the concave portion with respect to the joint surface in the metal member is not constant.

上述した実施例に係る接合構造体及び比較例に係る接合構造体の接合強度の評価は、エスペック製の冷熱衝撃装置TSD−100による熱衝撃試験によって評価した。具体的には、−40℃の環境下で30分、85℃の環境下で30分という1サイクル1時間の熱衝撃を、接合界面が剥離に至るまで実施例および比較例に加え続けた。   Evaluation of the joint strength of the joint structure according to the above-described example and the joint structure according to the comparative example was performed by a thermal shock test using a thermal shock apparatus TSD-100 manufactured by ESPEC. Specifically, a thermal shock of one cycle of 1 hour, 30 minutes in an environment of −40 ° C. and 30 minutes in an environment of 85 ° C., was continuously applied to the examples and comparative examples until the bonding interface reached peeling.

接合界面が剥離に至った否かの確認は、100、250、500、750、1000、1500サイクル(回)の熱衝撃を加えた後にそれぞれ行った。そして、或るサイクルで接合界面が剥離に至った場合には、その前の接合界面の剥離が確認されなかったサイクルを熱衝撃試験耐性として採用した。例えば、接合界面の剥離が1000回の熱衝撃を加えた後に確認された場合には、その前の750回を熱衝撃試験耐性とした。実施例および比較例について得られた熱衝撃試験耐性を表1に示す。   The confirmation of whether or not the bonding interface had been peeled was performed after applying thermal shocks of 100, 250, 500, 750, 1000, and 1500 cycles (times), respectively. And when the joining interface reached peeling in a certain cycle, the cycle in which peeling of the previous joining interface was not confirmed was adopted as the thermal shock test resistance. For example, when peeling of the bonding interface was confirmed after 1000 thermal shocks were applied, the previous 750 times were regarded as thermal shock test resistance. Table 1 shows the thermal shock test resistance obtained for the examples and comparative examples.

Figure 2016165746
Figure 2016165746

上記評価結果より、本発明に係る実施例の接合構造体は、冷熱衝撃試験を1500サイクル行った後に剥離が確認されたので、冷熱衝撃試験耐性は1000サイクルであった。   From the above evaluation results, it was confirmed that the bonded structures of the examples according to the present invention were peeled after 1500 cycles of the thermal shock test, and thus the thermal shock test resistance was 1000 cycles.

一方で、比較例の接合構造体は、冷熱衝撃試験を500サイクル行った後に剥離が確認されたので、冷熱衝撃試験耐性は250サイクルであった。   On the other hand, the bonded structure of the comparative example was confirmed to be peeled after 500 cycles of the thermal shock test, and thus the thermal shock test resistance was 250 cycles.

以上により、本発明に係る接合構造体は、従来技術と比較して、冷熱衝撃試験耐性が向上していることを確認することができた。   From the above, it was confirmed that the bonded structure according to the present invention has improved thermal shock test resistance as compared with the prior art.

−第2実施形態−
接合構造体の製造方法の第2実施形態を図9〜14を参照しながら説明する。図9及び図10は、接合構造体の製造方法における凹状部形成工程を説明する説明図、図11〜図13は、接合構造体の製造方法における接合工程を説明する説明図、図14は、接合構造体の斜視図である。
-Second Embodiment-
A second embodiment of the method for manufacturing a joined structure will be described with reference to FIGS. 9 and 10 are explanatory views for explaining a concave portion forming step in the method for manufacturing a joined structure, FIGS. 11 to 13 are explanatory views for explaining a joining step in the method for producing a joined structure, and FIG. It is a perspective view of a junction structure.

本実施形態は、前述した第1実施形態と、金属部材及び樹脂部材の形状が異なるだけであるので、以下、その相違点に関連する事項について説明し、同一の構成要素については、同一符号を付してその説明を省略する。   Since the present embodiment is different from the first embodiment described above only in the shapes of the metal member and the resin member, the following describes matters related to the differences, and the same components are denoted by the same reference numerals. A description thereof will be omitted.

本実施形態に係る接合構造体の製造方法は、第1部材に第2部材を対峙させて接合する接合構造体の製造方法であって、凹状部形成工程と、接合工程と、を備えている。   The manufacturing method of the bonded structure according to the present embodiment is a method of manufacturing a bonded structure in which the second member is opposed to the first member and bonded, and includes a concave portion forming step and a bonding step. .

第1部材(金属部材2´)における後述する第2部材(樹脂部材3´)と対峙される面(接合面BP´)は、凸形状であり、本実施形態の凸形状は、中央部が膨出された方形状の膨出部B´を備えている。また、膨出部B´の側周面は、傾斜面TP´とされている。   A surface (bonding surface BP ′) that faces a second member (resin member 3 ′), which will be described later, in the first member (metal member 2 ′) has a convex shape. A bulged rectangular bulging portion B ′ is provided. Further, the side peripheral surface of the bulging portion B ′ is an inclined surface TP ′.

樹脂部材3´における金属部材2´と対峙される面は、前述した金属部材2´の膨出部B´に対応した凹形状である。   The surface of the resin member 3 ′ facing the metal member 2 ′ has a concave shape corresponding to the bulging portion B ′ of the metal member 2 ′ described above.

以下、本実施形態に係る接合構造体の製造方法の各工程について説明する。   Hereinafter, each process of the manufacturing method of the junction structure concerning this embodiment is explained.

・凹状部形成工程
まず、金属部材2´を回転手段14のステージ14aに載置する。そして、本実施形態では、まず最初に、走査手段12の走査範囲Aを超える位置における金属部材2´の接合面BP´に凹状部oを形成するため、位置調整手段13によって、凹状部oを形成する位置が走査範囲A内に入るように、ステージ14aを移動させる。
-Concave part formation process First, metal member 2 'is mounted in the stage 14a of the rotation means 14. As shown in FIG. In this embodiment, first, the concave portion o is formed by the position adjusting means 13 in order to form the concave portion o on the joint surface BP ′ of the metal member 2 ′ at a position exceeding the scanning range A of the scanning means 12. The stage 14a is moved so that the position to be formed falls within the scanning range A.

次に、回転軸14bによって、金属部材2´の接合面BPに対して垂直に加工用レーザ11aからのレーザ光が照射されるように、回転軸14bによってステージ14aを回転させる(図9参照)。本実施形態では、まず最初に、金属部材2´の略水平面に凹状部oを形成するため、金属部材2´に対して垂直にレーザ光が照射されるように、ステージ14aを回転軸14bによって微調整する。   Next, the stage 14a is rotated by the rotating shaft 14b so that the laser beam from the processing laser 11a is irradiated perpendicularly to the joint surface BP of the metal member 2 'by the rotating shaft 14b (see FIG. 9). . In the present embodiment, first, in order to form the concave portion o in the substantially horizontal plane of the metal member 2 ′, the stage 14a is moved by the rotating shaft 14b so that the laser beam is irradiated perpendicularly to the metal member 2 ′. Make fine adjustments.

次に、位置調整手段13によって、加工用レーザ11aから照射されるレーザ光の焦点位置を、金属部材2´の接合面BP´に位置調節する。すなわち、ステージ14aを上下動させる。   Next, the position adjusting means 13 adjusts the focal position of the laser light emitted from the processing laser 11a to the bonding surface BP ′ of the metal member 2 ′. That is, the stage 14a is moved up and down.

そして、金属部材2´における凹状部oを形成する位置に加工用レーザ11aからのレーザ光としてパルス光(好ましくはサブパルス光)を照射する。   Then, pulse light (preferably sub-pulse light) is irradiated as laser light from the processing laser 11a to a position where the concave portion o in the metal member 2 ′ is formed.

1つ目の凹状部oを形成後、金属部材2´に2つ目の凹状部oを形成する。ここで、2つ目の凹状部oの形成する位置が、走査手段の走査範囲内に入っている場合は、上述したとおり、回転軸14bによってステージ14aを回転させるとともに位置調整手段13によって昇降させて、凹状部oの形成を行う。一方、走査範囲内に入っていない場合は、位置調整手段13によって、ステージ14aを走査範囲内に移動させた後に、上述したとおり、回転軸14bによってステージ14aを回転させるとともに位置調整手段13によって昇降させて、凹状部oの形成を行う。   After forming the first concave portion o, the second concave portion o is formed in the metal member 2 ′. Here, when the position formed by the second concave portion o is within the scanning range of the scanning means, as described above, the stage 14a is rotated by the rotating shaft 14b and moved up and down by the position adjusting means 13. Then, the concave portion o is formed. On the other hand, if not within the scanning range, after the stage 14a is moved into the scanning range by the position adjusting means 13, the stage 14a is rotated by the rotating shaft 14b and moved up and down by the position adjusting means 13 as described above. Thus, the concave portion o is formed.

上述した工程を、凹状部oを形成する個数分、繰り返し行う(図10は、2つ目の凹状部oを形成している状態を模式的に説明している。)   The above-described steps are repeated for the number of the concave portions o to be formed (FIG. 10 schematically illustrates a state in which the second concave portion o is formed).

・接合工程
接合工程は、金属部材2´と樹脂部材3´とを互いに接合する工程であり、上述した接合用レーザ11bを備えたレーザ装置を用いて行われる。
-Joining process A joining process is a process of joining metal member 2 'and resin member 3' mutually, and is performed using a laser device provided with laser 11b for joining mentioned above.

本実施形態では、接合用レーザ11bからのレーザ光を、透光性の樹脂部材3´と金属部材2´との接合面BP´に照射させ、金属部材2´を加熱させることにより金属部材2´と接触している樹脂部材3´に熱を伝え、樹脂部材3´を溶融させて接合させる方法について説明する。   In the present embodiment, the laser beam from the bonding laser 11b is applied to the bonding surface BP ′ between the translucent resin member 3 ′ and the metal member 2 ′, and the metal member 2 ′ is heated to thereby heat the metal member 2 ′. A method for transferring heat to the resin member 3 ′ in contact with ′ and melting and bonding the resin member 3 ′ will be described.

まず、ステージ14aに載置された金属部材2´の接合面BP´に、樹脂部材3´を載置する(図11参照)。まず最初に、走査手段12の走査範囲を超える位置における金属部材2´の凹状部oに樹脂部材3´を充填するため、位置調整手段13によって、凹状部oが形成された位置が走査範囲内に入るように、ステージ14aを移動させる。   First, the resin member 3 ′ is placed on the joint surface BP ′ of the metal member 2 ′ placed on the stage 14a (see FIG. 11). First, the resin member 3 'is filled in the concave portion o of the metal member 2' at a position beyond the scanning range of the scanning means 12, so that the position where the concave portion o is formed by the position adjusting means 13 is within the scanning range. The stage 14a is moved to enter.

次に、回転軸14bによって、金属部材2´の接合面BP´に対して垂直に接合用レーザ11bからのレーザ光が照射されるように、回転軸14bによってステージ14aを回転させる。本実施形態では、まず最初に、金属部材2´の略水平面の凹状部oに樹脂部材3´を充填するため、樹脂部材3´に対して垂直にレーザ光が照射されるように、ステージ14aを回転軸14bによって微調整する(図12参照)。   Next, the stage 14a is rotated by the rotating shaft 14b so that the rotating shaft 14b irradiates the laser beam from the bonding laser 11b perpendicularly to the bonding surface BP ′ of the metal member 2 ′. In the present embodiment, first, in order to fill the resin member 3 ′ into the substantially horizontal concave portion o of the metal member 2 ′, the stage 14 a is irradiated with the laser beam perpendicularly to the resin member 3 ′. Is finely adjusted by the rotating shaft 14b (see FIG. 12).

次に、位置調整手段13によって、接合用レーザ11bから照射されるレーザ光の焦点位置を、金属部材2´の接合面BP´に位置調節する。すなわち、ステージ14aを上下動させる。   Next, the position adjusting means 13 adjusts the focal position of the laser beam emitted from the bonding laser 11b on the bonding surface BP ′ of the metal member 2 ′. That is, the stage 14a is moved up and down.

そして、金属部材2´における凹状部oを形成する位置に接合用レーザ11bからのレーザ光を連続発振によって照射する。   Then, the laser beam from the bonding laser 11b is irradiated by continuous oscillation to a position where the concave portion o in the metal member 2 ′ is formed.

樹脂部材3´と金属部材2´との接合面BP´に接合用レーザ11bからのレーザ光を照射することにより、レーザ光のエネルギーが金属部材2´の内部で熱に変換され、金属部材2´の表面の温度が高くなる。これにより、金属部材2´の表面近傍の樹脂部材3´が溶融され、その樹脂部材3´が凹状部oに充填される。   By irradiating the bonding surface BP ′ between the resin member 3 ′ and the metal member 2 ′ with the laser beam from the bonding laser 11 b, the energy of the laser beam is converted into heat inside the metal member 2 ′. The surface temperature of ′ becomes high. Thereby, the resin member 3 ′ in the vicinity of the surface of the metal member 2 ′ is melted, and the resin member 3 ′ is filled in the concave portion o.

1つ目の凹状部oに樹脂部材3´を充填した後、2つ目の凹状部oに樹脂部材3´を充填する。ここで、2つ目の凹状部oの位置が、走査手段の走査範囲内に入っている場合は、上述したとおり、回転軸14bによってステージ14aを回転させさせるとともに位置調整手段13によって昇降させて、凹状部oに樹脂部材3を充填する。一方、走査範囲内に入っていない場合は、位置調整手段13によってステージ14aを走査範囲内に移動させた後に、上述したとおり、回転軸14bによってステージ14aを回転させるとともに位置調整手段13によって昇降させて、凹状部oに樹脂部材3´を充填する。   After the first concave portion o is filled with the resin member 3 ′, the second concave portion o is filled with the resin member 3 ′. Here, when the position of the second concave portion o is within the scanning range of the scanning means, as described above, the stage 14a is rotated by the rotating shaft 14b and the position adjusting means 13 is moved up and down. The resin member 3 is filled in the concave portion o. On the other hand, if not within the scanning range, after the stage 14a is moved into the scanning range by the position adjusting means 13, the stage 14a is rotated by the rotating shaft 14b and moved up and down by the position adjusting means 13 as described above. Then, the concave member o is filled with the resin member 3 '.

上述した工程を、凹状部oの個数分、繰り返し行う(図13は、2つ目の凹状部oに樹脂部材3´を充填している状態を模式的に説明している。)   The above-described steps are repeated for the number of the concave portions o (FIG. 13 schematically illustrates a state where the second concave portion o is filled with the resin member 3 ′).

以上により、接合工程では、凹状部形成工程において接合面BP´に対して垂直方向に形成された凹状部o内に、樹脂部材3´を充填することによって金属部材2´と樹脂部材3´とを接合した接合構造体1´を製造することができる(図14参照)。   As described above, in the bonding step, the metal member 2 ′ and the resin member 3 ′ are filled by filling the resin member 3 ′ in the concave portion o formed in the direction perpendicular to the bonding surface BP ′ in the concave portion formation step. Can be manufactured (see FIG. 14).

なお、上記に示した本発明の実施形態及び実施例はいずれも本発明を具体化した例であって、本発明の技術的範囲を限定する性格のものではない。例えば、第1部材を熱可塑性樹脂、又は、熱硬化性樹脂とし、第2部材を金属としてもよい。   The above-described embodiments and examples of the present invention are all examples of the present invention, and are not of a nature that limits the technical scope of the present invention. For example, the first member may be a thermoplastic resin or a thermosetting resin, and the second member may be a metal.

10 レーザ装置
11a 加工用レーザ
11b 接合用レーザ
12 走査手段
13 位置調整手段
14 回転手段
14a ステージ
14b 回転軸
2 金属部材
3 樹脂部材
O 凹状部
t 突出部
BP 接合面
B 膨出部
TP 傾斜面
DESCRIPTION OF SYMBOLS 10 Laser apparatus 11a Processing laser 11b Joining laser 12 Scanning means 13 Position adjusting means 14 Rotating means 14a Stage 14b Rotating shaft 2 Metal member 3 Resin member O Concave part t Protruding part BP Joint surface B Swelling part TP Inclined surface

Claims (9)

第1部材に第2部材を対峙させて接合する接合工程を備えた接合構造体の製造方法であって、
前記接合工程を行う前に、前記第1部材における接合面に前記第2部材が充填される凹状部を形成する凹状部形成工程が備えられており、
前記凹状部形成工程は、前記第1部材に凹状部を形成する加工用レーザの照射方向に対して、前記第1部材の接合面が垂直となるように、前記第1部材を回転させて行われることを特徴とする接合構造体の製造方法。
A method for manufacturing a joined structure including a joining step of joining a first member with a second member facing each other,
Before performing the joining step, a concave portion forming step of forming a concave portion filled with the second member on the joining surface of the first member is provided,
The concave portion forming step is performed by rotating the first member so that the joining surface of the first member is perpendicular to the irradiation direction of the processing laser for forming the concave portion on the first member. The manufacturing method of the joining structure characterized by the above-mentioned.
請求項1に記載された接合構造体の製造方法であって、
前記レーザ照射は、前記第1部材の接合面に対して焦点位置を調整しながら行われることを特徴とする接合構造体の製造方法。
A method for manufacturing a joined structure according to claim 1,
The method of manufacturing a joined structure, wherein the laser irradiation is performed while adjusting a focal position with respect to a joining surface of the first member.
請求項1又は2に記載された接合構造体の製造方法であって、
前記接合工程は、前記第1部材と前記第2部材とを接合させる接合用レーザの照射方向に対して、前記接合面が垂直となるように、前記第1部材及び前記第2部材を回転させて行われることを特徴とする接合構造体の製造方法。
It is a manufacturing method of the joined structure according to claim 1 or 2,
In the joining step, the first member and the second member are rotated so that the joining surface becomes perpendicular to the irradiation direction of the joining laser for joining the first member and the second member. The manufacturing method of the junction structure characterized by the above-mentioned.
請求項1〜3のいずれか1項に記載された接合構造体の製造方法であって、
前記第1部材における前記第2部材と対峙される面は、凸形状であることを特徴とする接合構造体の製造方法。
It is a manufacturing method of the joined structure given in any 1 paragraph of Claims 1-3,
The method of manufacturing a joined structure, wherein a surface of the first member facing the second member is a convex shape.
請求項1〜4のいずれか1項に記載された接合構造体の製造方法であって、
前記凹状部形成工程では、1パルスが複数のサブパルスで構成されるレーザを照射することによって前記凹状部を形成することを特徴とする接合構造体の製造方法。
It is a manufacturing method of the joined structure given in any 1 paragraph of Claims 1-4,
In the concave portion forming step, the concave portion is formed by irradiating a laser in which one pulse is composed of a plurality of subpulses.
請求項1〜5のいずれか1項に記載された接合構造体の製造方法であって、
前記第1部材には、金属、熱可塑性樹脂、又は、熱硬化樹脂が用いられていることを特徴とする接合構造体の製造方法。
It is a manufacturing method of the joined structure given in any 1 paragraph of Claims 1-5,
A metal, a thermoplastic resin, or a thermosetting resin is used for said 1st member, The manufacturing method of the joining structure characterized by the above-mentioned.
請求項1〜6のいずれか1項に記載された接合構造体の製造方法であって、
前記第2部材には、レーザを透過する樹脂が用いられていることを特徴とする接合構造体の製造方法。
It is a manufacturing method of the joined structure given in any 1 paragraph of Claims 1-6,
A method of manufacturing a bonded structure, wherein the second member is made of a resin that transmits laser.
請求項1〜7のいずれか1項に記載された接合構造体の製造方法によって製造された接合構造体。   The joining structure manufactured by the manufacturing method of the joining structure described in any one of Claims 1-7. 被照射部材に向けてレーザ光を照射するレーザと、
前記レーザの照射方向に対して前記被照射部材が垂直となるように、前記被照射部材を回転させる回転手段と、
が備えられており、
前記レーザは、1パルスが複数のサブパルスを照射することを特徴とするレーザ装置。
A laser that emits laser light toward the irradiated member;
Rotating means for rotating the irradiated member so that the irradiated member is perpendicular to the laser irradiation direction;
Is provided,
In the laser apparatus, one pulse irradiates a plurality of sub-pulses.
JP2015047515A 2015-03-10 2015-03-10 Manufacturing method of joint structure, joint structure, and laser device Pending JP2016165746A (en)

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JP2019107881A (en) * 2017-12-18 2019-07-04 株式会社デンソー Joint structure
JP2019536629A (en) * 2016-09-30 2019-12-19 エルジー・ケム・リミテッド Dissimilar material joined body and manufacturing method thereof

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