JP2016079326A - Method for producing coke - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a method capable of stably producing a coke having a high strength even when non- or slightly-caking coal with a low coalification degree of the total expansion ratio of 0% is used.SOLUTION: In a method for producing a coke including charging a mixed coal mixed with non- or slightly-caking coal with a low coalification degree into a coke oven, and dry-distilling the mixed coal, the non- or slightly-caking coal with the low coalification degree is coal of the total expansion ratio of 0% out of coals having a volatile content of 30 mass% or more and a vitrinite reflectance of 0.9 or less. The method includes: determining a high-speed temperature-raising expansion specific volume for each brand of the non- or slightly-caking coal with the low coalification degree; changing a void-filling ratio of the mixed coal for each of the brands; determining an optimal ground particle size; previously determining a relationship between the high-speed temperature-raising expansion specific volume and the void-filling ratio of the mixed coal for each of the ground particle sizes; determining the ground particle size from the relationship according to the high-speed temperature-raising expansion specific volume of the non- or slightly-caking coal with the low coalification degree to be used and the void-filling ratio of the mixed coal determined by the operation condition; and grinding the non- or slightly-caking coal with the low coalification degree to be used so that its ground particle size becomes the determined ground particle size.SELECTED DRAWING: Figure 1

Description

  The present invention relates to a method for producing coke for blast furnace using low-coalizing non-slightly caking coal.

  Coke used for blast furnace operation is produced by pulverizing and blending various types of coal, charging it into a coke oven, and subjecting it to dry distillation in the furnace. Such coke is required to have a required strength in order to ensure air permeability in the blast furnace. On the other hand, in the raw materials for coke, high-quality strong caking coal is in a resource-depleted state, while non-minor caking coal with poor caking properties is rich in reserves and can be obtained at low cost. Therefore, many methods for producing coke having a required strength using non-slightly caking coal have been proposed.

  Patent Document 1 discloses a method of coarsely pulverizing coal rich in active ingredients, finely pulverizing coal not rich in active ingredients such as non-slightly caking coal, and using it as a blended raw material to produce coke by dry distillation Is disclosed.

  Patent Document 2 is not limited to caking coal or non-slightly caking coal, and if there is a coarse inert component in the coal, it causes a reduction in coke strength, so a coarse inert component of 1.5 mm or more. A method of producing coke for blast furnace including a pulverizing step for strongly pulverizing the steel is disclosed.

  Thus, when manufacturing high intensity | strength coke using a non-slightly caking coal, the method of carrying out the strong grinding | pulverization of coal is employ | adopted in many cases. Therefore, a pulverization method for further improving the coke strength is desired in order to improve the coke strength by strongly pulverizing the non-slightly caking coal.

  In response to such demands, Patent Document 3 discloses a method for setting the pulverized particle size within an appropriate range in accordance with the total expansion rate of non-finely caking coal with low coalification and blended coal during strong pulverization. Has been. That is, in Patent Document 3, a low inert low-coalized coal having a total expansion rate of less than 20% is pulverized to a mass size of 82% by mass or more under a sieve with a pulverized particle size of 3 mm when the total expansion rate of the combined coal is 40% or more. When the total expansion rate of charcoal is less than 40%, a method of pulverizing to 72 to 78% under a pulverized particle size of 3 mm is disclosed.

  On the other hand, in recent years, the use of non-slightly caking coal having a total expansion rate of 0%, which has not been used as a coke production raw material, has been demanded against the background of rising coal prices. Although it is described that the technique is directed to a low-coalized coal having a total expansion rate of less than 20%, there is no description of a case where a low-coalized coal having a total expansion rate of 0% is investigated. Therefore, the technique disclosed in Patent Document 3 does not substantially take into account non-slightly caking coal having a low coalification degree with a total expansion rate of 0%.

  And, non-coking coal with a low coalification degree is generally desirable to reduce the pulverization particle size because the size of cracks generated in the inside is reduced and coke strength is increased by strong pulverization. . On the other hand, it is known that if the pulverized particle size is reduced beyond a certain boundary value, the increase in coke strength is hindered. However, as described above, the upper limit of the pulverization particle size for improving the coke strength is not studied in the low coalification non-coking coal having a total expansion rate of 0%, and the low coal having the total expansion rate of 0%. In the pulverization of non-slightly caking coal with a degree of conversion, there was no knowledge about the optimum pulverization particle size for improving the coke strength, and the coke strength could not be improved.

Japanese Unexamined Patent Publication No. 56-032587 JP 2008-297385 A JP 2013-006958 A

  In view of such circumstances, the present invention is a method for producing coke using low-coalizing non-fine coking coal, and using a low-coalizing non-microcoking coal having a total expansion rate of 0%, It is an object of the present invention to provide a method capable of stably producing high strength coke by optimum pulverization.

  First, in order to distinguish low coalification non-slightly caking coals having different brands with a total expansion rate of 0%, the present inventors used a method disclosed in Japanese Patent No. 4691212 to achieve a total expansion rate of 0%. The low-coalification degree non-slightly caking coals were measured and distinguished from each other by measuring the high-temperature expansion specific volume.

  Among these low-coalizing non-caking coals, in a coal with a certain high-temperature temperature expansion ratio, the product of the total expansion ratio volume of the blended coal and the coal-filled bulk density (the degree of void filling of the blended coal) is changed, As a result of investigating the pulverization particle size (optimal pulverization particle size) when the coke strength was highest, it was found that there was an optimal pulverization particle size depending on the void filling degree of the blended coal. As a result, it was found that the degree of void filling can be used as an index for the optimum pulverized particle size of low coalification non-finely caking coal with a total expansion rate of 0%.

  Next, we investigated the optimal pulverization particle size of the low-coalizing coal with different coal grades with the same degree of void filling of the blended coal. Has been found to have an optimal grinding particle size. From this, the knowledge that the expansion specific volume of the low coalification non-slightly caking coal with an overall expansion rate of 0% can be used as an index for the optimum pulverized particle size Got.

  Therefore, the present inventors, based on these findings, arranged the relationship between the high-temperature temperature-expansion specific volume of low-coalizing non-slightly caking coal, the void filling degree of blended coal, and the optimum pulverization particle size, By utilizing this relationship, it was found that the optimal pulverization particle size of the low coalification non-slightly caking coal having a total expansion rate of 0% can be determined, and the present invention was completed.

The gist of the present invention made through such examination is as follows.
(1) In a method for producing coke, in which a blended coal blended with a low-coalizing non-caking coal is charged into a coke oven and dry-distilled,
The low coalification non-caking coal has a total expansion coefficient measured by a method defined in JIS M8801, among coals having a volatile content of 30% by mass or more and a vitrinite reflectance of 0.9 or less. 0% coal,
For each brand of the low-coalizing non-slightly caking coal, obtain a high-temperature temperature-expansion expansion specific volume measured at a temperature-raising rate of 6 ° C./min or more,
For each brand of the low coalification non-slightly caking coal, by changing the value of the product of the total expansion specific volume of coal blended and the coal-filled bulk density, obtain the pulverized particle size that gives the highest coke strength,
For each of the pulverized particle sizes, a relationship between the product of the high temperature rising expansion specific volume of the low coalification non-slightly caking coal, the total expansion specific volume of the blended coal and the coal filling bulk density is determined in advance.
The pulverization particle size is determined from the above relationship depending on the product of the high temperature heating expansion specific volume of the low coalification non-caking coal used and the total expansion specific volume of the coal blend determined by the operating conditions and the coal filling bulk density. And
A method for producing coke, characterized in that the low-coalizing non-coking coal used is pulverized so as to have the determined pulverized particle size.

  According to the present invention, the relationship between the optimum pulverization particle size is obtained in advance by using the high temperature rising expansion specific volume of the low coalification non-slightly caking coal and the void filling degree of the blended coal as indexes. When using non-coking coal with a low coalification rate of 0%, the optimum pulverized particle size can be determined without conducting a pulverized particle size examination test, and high strength coke can be produced stably. .

It is a figure which shows the relationship between the space filling degree of blended coal, the optimal grinding | pulverization particle size, and the high-temperature-heating expansion specific volume of low coalification non-slightly caking coal.

  Hereinafter, the manufacturing method of the coke of this invention is demonstrated.

  The present inventors have developed a low coalification degree non-coking coal having a total expansion rate of 0% (hereinafter referred to as “low coalization with a total expansion rate of 0%”, as measured by a method defined by JIS M 8801 (dilatometer method). In order to stably produce high strength coke using a non-slightly caking coal ”, low-coalizing non-slightly caking coal of different brands is expanded with a predetermined correlation with coke strength. We thought that it was necessary to distinguish according to gender. Japanese Patent No. 4691212 discloses a method for distinguishing the expansibility of low-coalification non-slightly caking coal having a total expansion rate of 0% by the expansion specific volume.

  Since the method for measuring the expansion specific volume is described in detail in Japanese Patent No. 4691212, the method for measuring the expansion specific volume will be briefly described. In addition, since the method for measuring the expansion specific volume is a method for increasing the temperature at the time of softening the coal at high speed, the expansion specific volume measured by this measurement method is hereinafter referred to as “high-speed temperature increase / expansion specific volume”. That's it.

  According to the measuring method of the high-temperature temperature increase and expansion specific volume, the high-speed temperature increase and expansion specific volume of three kinds of low coalification non-slightly caking coals having a total expansion rate of 0% was measured. First, low-coalizing non-slightly caking coal is put into a thin tube, a piston is inserted into this thin tube, the coal is heated so that the heating rate during coal softening becomes 12 ° C / min, and the displacement of the piston Was measured. And it calculated | required from the expansion rate from this displacement amount, and calculated | required the high-speed temperature rising expansion specific volume at the time of softening from this expansion coefficient. Table 1 shows the measured high-temperature temperature-expansion expansion specific volume for low-coalification non-slightly caking coal with a total expansion rate of 0%.

  Thus, the difference in expansibility of low coalification non-slightly caking coal that cannot be distinguished by the total expansion rate measured by the dilatometer method became clear.

  Next, the product of the low expansion ratio non-caking coal and the total expansion specific volume and coal filling bulk density of the coal blend having a predetermined correlation with the coke strength (hereinafter referred to as “the void filling degree of the coal blend”). As for the relationship, the low-coalification non-caking coal is blended with another coal to make a blended coal, dry-distilled to produce test coke, the strength of the test coke is measured, and the coke strength becomes the highest This was investigated by examining the pulverization particle size (hereinafter referred to as “optimal pulverization particle size”).

  The void filling degree is a parameter indicating the filling degree of voids due to the expansion of coal particles, and indicates the adhesion between the coal particles. The expansion specific volume at the time of obtaining the degree of void filling is defined by the ratio of the coal volume at the time of expansion to the mass of the charged coal, and the measurement of the coal volume at the time of expansion is an apparatus defined in JIS M8801. Can be done using. The total expansion specific volume of the blended coal was a weighted average value of the expansion specific volumes of each coal in the blended coal, and the expansion specific volume of each coal was measured at 3 ° C./min.

The coke strength was determined by actually measuring the coke percentage DI ¹⁵⁰ ₁₅ on a 15 mm sieve after the coke was rotated 150 times with a drum tester described in JIS K2151. Hereinafter, the coke strength DI ¹⁵⁰ ₁₅ will be described simply as the coke strength DI.

(Relationship between void filling degree and optimum pulverized particle size of non-coking coal with low coalification degree)
Among the low coalification non-slightly caking coals shown in Table 1, A coal having a high temperature rising expansion ratio volume of 1.9 cm ³ / g is 75% and 85% at a ratio of 3 mm or less with an impact crusher. The coke was pulverized to 95% and mixed with another coal to make a blended coal, and the void filling degree of the blended coal was set to 1.1, and dry-distilled in a test coke oven to produce a test coke.

  When the coke strength DI of the test coke was measured, the coke strength was the highest when A coal was pulverized to a ratio of 95% of 3 mm or less. From this, it was found that even coke with a low coalification degree with a total expansion rate of 0% can produce coke with higher strength by setting the ratio to a pulverized particle size of 3 mm or less at 95%. . Therefore, it was found that 95% of the pulverized particle size of 3 mm or less was a pulverized particle size capable of producing higher strength coke (hereinafter, sometimes referred to as “optimum pulverized particle size”).

  Next, the brand and the mixing ratio of the simple coal constituting the blended coal were changed, and the void filling degree of the blended coal was changed and examined. Coal A is pulverized with an impact crusher so that the ratio of 3 mm or less is 75%, 85%, and 95%, and mixed with another coal to make a blended coal. 0.0 or less, test coke was produced by dry distillation in a test coke oven.

  When the coke strength DI of the test coke was measured, the coke strength was the highest when pulverized to a ratio of 85% of 3 mm or less when the void filling degree of the blended coal was 1.0 or less.

  As described above, even in the case of non-coking coal with a low expansion rate of 0% and a low degree of coalification, there is a difference in the optimum pulverization particle size depending on the degree of void filling, The pulverized particle size increased. When the void filling degree was reduced, the optimum pulverized particle size was increased by reducing the pulverized particle size, that is, by reducing the non-coking coal with a low coalification degree, thereby reducing the expandability of the blended coal. It is considered that the voids of the blended coal cannot be sufficiently filled with the expansion of the blended coal because of the decrease, and the coke strength is lowered. Thus, it was confirmed that the degree of void filling can be used as an index with respect to the optimum pulverized particle size of the low coalification non-slightly caking coal.

(Relationship between high-temperature heating expansion specific volume and optimum pulverization particle size of low-coalizing non-coking coal)
Among the low coalification non-slightly caking coals shown in Table 1, B charcoal with a high temperature rising expansion specific volume of 1.4 cm ³ / g, the ratio of 3 mm or less by impact crusher is 75%, 85%, The mixture was pulverized to 91% and mixed with another coal to obtain a blended coal. The void filling degree of the blended coal was about 1.1, and carbonized in a test coke oven to produce a test coke.

  When the coke strength DI of the test coke was measured, the coke strength was highest when pulverized to a ratio of 91% of 3 mm or less. In Coal A and Coal B, when the degree of void filling of the blended coal is 1.1, the optimum pulverized particle size of the test coke is 95% in a ratio of 3 mm or less for Coal A, and 91% in a ratio of 3 mm or less for Coal B. Met. Thereby, it has confirmed that the high-speed temperature expansion expansion specific volume of the low coalification non-slightly caking coal can be used as a parameter | index with respect to the optimal grinding | pulverization particle size of the low coalification non-slightly caking coal.

Furthermore, among the low-coalizing non-slightly caking coals shown in Table 1, C charcoal having a high temperature rising and expansion specific volume of 1.3 cm ³ / g is 75% in an impact crusher with a ratio of 3 mm or less. Grind to 85% and 95%, mix with other coal to make blended coal, set the void filling degree of the blended coal to 0.9, 1.4, and 2.2, and dry distillation in test coke oven The test coke was manufactured. Then, the coke strength DI of the test coke was measured and determined as the optimum pulverized particle size in the degree of void filling of each blended coal.

  As a result, when the void filling degree of the blended coal was 0.9, it was crushed to a ratio of 75% of 3 mm or less, and when the void filling degree of the blended coal was 1.4, it was crushed to a ratio of 85% of 3 mm or less. In this case, when the void filling degree of the blended coal was 2.2, the coke strength was highest when pulverized to a ratio of 95% of 3 mm or less.

  Based on the results of studies on the above-mentioned coals A, B, and C, the void filling degree of the blended coal is determined as follows: Organized by relationship. FIG. 1 shows the relationship among the void filling degree of the blended coal, the optimum pulverization particle size, and the high-temperature temperature-expansion expansion specific volume of the low coalification non-slightly caking coal.

The examination results are summarized as follows.
Low coalification non-fine caking coal with a total expansion rate of 0%. Optimal with increasing void filling of blended coal and lowering high-temperature temperature expansion specific volume of low coal non-caking coal The pulverized particle size becomes smaller. When producing coke using low coalification non-fine caking coal with a total expansion rate of 0%, the void filling degree of the blended coal, the high-temperature temperature increase expansion specific volume of the low coalization non-fine caking coal, and By utilizing the relationship between the optimum pulverized particle size, the optimum pulverized particle size of the low coalification non-slightly caking coal can be determined, and high strength coke can be produced stably.

  The present invention has reached the invention described in the above (1) through the above examination process, and the present invention is divided into the following configurations (a) to (e) and necessary. Requirements and preferable requirements will be described in order.

(A) Physical properties of low-coalification non-slightly caking coal (b) Determination of high-temperature expansion and expansion specific volume of low-coalification non-slightly caking coal (c) Brands of low-coalification non-slightly caking coal How to obtain the optimum pulverization particle size when changing the degree of void filling of the blended coal for each time (d) The relationship between the high-temperature expansion ratio specific volume for each optimum pulverization particle size and the void filling degree of the blended coal How to obtain (e) The pulverized particle size from the relationship of (d) according to the high temperature rising expansion specific volume of the low coalification non-coking coal used and the void filling degree of the blended coal determined from the operating conditions. How to decide

[Physical properties of non-coking coal with low coal content]
(Volatile content: 30% by mass or more, Vitrinite reflectance: 0.9 or less)
Low coalification non-slightly caking coal does not show caking properties when heated alone, or even if it shows a very low degree of coal, the degree of coalification of the present invention The low-coalizing non-slightly caking coal has a volatile content, which is an index indicating the degree of coalification, of 30% by mass or more and a vitrinite reflectance Ro of 0.9 or less. The volatile matter can be measured by a method specified by JIS M 8812, and the vitrinite reflectance can be measured by a method specified by JIS M 8816.

(Total expansion rate: 0%)
Low coalification non-coking coal is coal having a total expansion rate of 0% as measured by the method defined in JIS M8801, among those satisfying the above volatile content and vitrinite reflectance. In this measurement method, charcoal is charged into a reaction tube, a piston is placed on the top, the container is heated, the amount of rise at the upper end of the molding is read from the displacement of the piston, The fraction of the displacement of the piston with respect to the length of is obtained, and this fraction is taken as the total expansion rate. Such a low-coalizing non-slightly caking coal is adopted because it has a large reserve and is available at a low price among non-slightly caking coals.

[How to find the specific temperature expansion ratio of low coal non-slightly caking coal]
The high-temperature temperature-expansion expansion specific volume of low-coalizing non-slightly caking coal is measured according to the measuring method disclosed in Japanese Patent No. 4691212. Specifically, as described above, non-coking coal with a low degree of coalification is put into a thin tube, and a piston is inserted into this thin tube so that the heating rate during coal softening becomes 6 ° C./min or more. The coal is heated, the amount of displacement of the piston is measured, and the expansion rate is obtained from the amount of displacement, and the high-temperature temperature-expansion expansion specific volume at the time of softening is obtained from the expansion rate.

  In addition, when the high temperature temperature increase / expansion specific volume is measured at the same temperature increase rate when the relationship shown in FIG. 1 is obtained in advance, the temperature increase rate at the time of measurement is not particularly limited. However, the heating rate is preferably 6 to 12 ° C./min from the viewpoint of heating the coal in the narrow tube as uniformly as possible.

[How to find the optimal pulverized particle size when changing the degree of void filling of blended coal for each brand of low-coalizing non-coking coal]
Low coalification degree non-coking coal is pulverized by a pulverizer so as to have various pulverization particle sizes, and each is a blended coal blended with another coal, and the void filling degree of the blended coal is changed, Coke is produced by carbonization in a coke oven. Next, the coke strength DI of the produced coke is measured, and the optimum pulverized particle size is obtained for each degree of void filling of the blended coal. And the same pulverization particle size is calculated | required for every void filling degree of blended coal with the same procedure also about the low grade coalification degree non-coking coal of another brand.

(Pulverization of low coal non-slightly caking coal)
The pulverization is performed using a pulverizer such as an impact crusher. The pulverization method is not particularly limited. The pulverized particle size is preferably 75 to 95% in a ratio of 3 mm or less. If the ratio is less than 75% at 3 mm or less, the coke strength is liable to be reduced. On the other hand, if the ratio is more than 95% at 3 mm or less, it tends to lead to generation of dust due to an increase in required electric energy or increase in fine powder.

(Mixed coal)
The blended coal is obtained by blending non-coking coal having a low coalification degree with a plurality of other coals pulverized to a predetermined pulverization particle size. As for the blending ratio of the low coalification non-slightly caking coal and the total of another coal, the low coalization non-slightly caking coal is 5 to 30% by mass, and the total of another coal is 70 to 95% by mass. The In addition, in preparation of FIG. 1, it was set as 75 mass% of the sum total of 25 mass% of low coalification non-caking coal, and another coal.

  Other coals are not particularly limited, but from the viewpoint of ensuring the required coke strength, ordinary coals including strongly caking coal (weighted average total expansion coefficient ΣTD = 50 to 100% of coal, weighted average volatilization of coal An example is obtained by pulverizing a quantitative determination [Sigma] VM = 26 to 29 dry%) to a particle size of 60% to 95% at a ratio of 3 mm or less.

(Void filling degree)
When the degree of void filling is lower than 1.0, the voids between the coal particles existing at the time of charging cannot be filled due to the expansion of the coal, and the voids between the coal particles remain as defects, resulting in low strength coke. It is easy to become. In addition, when the degree of void filling is one or more, voids between coal particles existing at the time of charging are completely filled by expansion of coal, and there is no defect and the strength tends to be constant. However, in an actual coke oven, it is preferable to set it to about 1.1 or more in consideration of variations in charging bulk density and coal properties. On the other hand, the upper limit is not particularly limited, but about 1.6 is realistic because of the limitation of available coal stock.

[How to find the relationship between the high-temperature expansion and expansion specific volume for each optimum pulverized particle size and the degree of void filling of the blended coal]
The optimum pulverization particle size in the degree of void filling of a predetermined blended coal with respect to the high-temperature temperature-expansion specific volume of low-coalizing non-slightly caking coal obtained as described above is organized as shown in FIG. That is, for each optimum pulverization particle size, an approximate expression is obtained with a quadratic function or the like, an approximate curve is created, and a diagram of the relationship between the high-temperature temperature rise and expansion specific volume and the degree of void filling of the blended coal is created.

[How to determine the pulverized particle size from the relationship (d) according to the high-temperature expansion ratio specific volume of the low-coalizing non-slightly caking coal used and the degree of void filling of the blended coal determined from the operating conditions]
The high-temperature temperature-expansion expansion specific volume of the low coalification non-caking coal used is measured by the method described above. The pulverized particle size is determined using the above-described relational diagram from the measured high-speed temperature-expansion expansion specific volume and the degree of void filling of the blended coal determined from the operating conditions. However, since the degree of void filling of the blended coal is almost determined by the planned operating conditions in the actual coke oven, the high-temperature temperature expansion and expansion specific volume of the low-coalification non-slightly caking coal to be used is found. For example, the optimum pulverized particle size can be obtained.

  In addition, in this relationship diagram, a curve connecting the optimum pulverization particle size at the intersection of the high temperature heating expansion specific volume of the low coal non-slightly caking coal used and the void filling degree of the blended coal determined from the operating conditions. In the range where there is no mark, that is, the range between the curves connected with the optimum pulverized particle size, the pulverized particle size is determined as follows. The optimal pulverization particle size at the intersection is obtained by equally dividing the curve connecting the optimal pulverization particle size by the difference in the numerical value of the optimal pulverization particle size between the upper and lower curves.

  However, in order to determine the optimal pulverization particle size between the curves that connect the optimal pulverization particle size, and the portions that are not shown, where the void filling degree is high or low, the blended coal void filling degree, optimal pulverization It is preferable to obtain the relationship between the particle size and the high-temperature temperature-expansion specific volume of the low-coalizing non-slightly caking coal by experiment and use the relationship in order to accurately determine the pulverized particle size.

  Next, examples of the present invention will be described. The conditions in the examples are one example of conditions used for confirming the feasibility and effects of the present invention, and the present invention is based on these one example conditions. It is not limited. The present invention can adopt various conditions as long as the object of the present invention is achieved without departing from the gist of the present invention.

  Table 2 shows the particle size, moisture, weighted average total expansion coefficient ΣTD of coal, and weighted average volatile content quantification ΣVM of coal blended with low-coalification non-coking coal (D-coal) and another coal. . Table 3 shows the total expansion rate of the low coalification non-slightly caking coal, the high-temperature expansion ratio specific volume, and the void filling degree of the blended coal. The high-temperature temperature-expansion expansion specific volume of the low-coalizing non-caking coal was measured at a temperature-raising rate of 12 ° C./min.

  And it grind | pulverizes so that the grinding | pulverization particle size of a low coalification non-caking coal may become the ratio 75%, 85%, and 95% of 3 mm or less, and 75 mass% of another coal is each about each D particle | grains of each particle size. , D charcoal was blended at 25% by mass to form blended charcoal and charged into a test coke oven to obtain coke.

  Table 3 shows the coke strength DI of the obtained coke. From this, when the pulverized particle size of the low-coalizing non-caking coal was pulverized to a ratio of 95% of 3 mm or less, the coke strength was maximum. In FIG. 1, when the high temperature rising expansion specific volume of the low coalification degree non-slightly caking coal is 1.6 and the void filling degree of the blended coal is 1.2, the optimum pulverization particle size is 95% at a ratio of 3 mm or less. Yes, consistent with experimental results.

  Based on the above, the relationship between the void filling degree of the blended coal, the optimum pulverization particle size, and the high-temperature temperature increase / expansion specific volume of the low coalification non-slightly caking coal is obtained in advance, and the coke strength is increased by using this relationship. The upper limit of the pulverized particle size can be determined.

  According to the present invention, by creating the relationship between the optimum pulverization particle size using the high temperature rising expansion specific volume of the low coalification non-slightly caking coal and the void filling degree of the blended coal as indexes, When the non-coking coal with a low degree of coalification of 1% is used, the optimum pulverized particle size can be determined without conducting a pulverized particle size examination test. Therefore, the present invention has high industrial applicability.

Claims (1)

In the method for producing coke, the coal blended with the low-coalizing non-slightly caking coal is charged into a coke oven and dry-distilled.
The low coalification non-caking coal has a total expansion coefficient measured by a method defined in JIS M8801, among coals having a volatile content of 30% by mass or more and a vitrinite reflectance of 0.9 or less. 0% coal,
For each brand of the low-coalizing non-slightly caking coal, obtain a high-temperature temperature-expansion expansion specific volume measured at a temperature-raising rate of 6 ° C./min or more,
For each brand of the low coalification non-slightly caking coal, by changing the value of the product of the total expansion specific volume of coal blended and the coal-filled bulk density, obtain the pulverized particle size that gives the highest coke strength,
For each of the pulverized particle sizes, a relationship between the product of the high temperature rising expansion specific volume of the low coalification non-slightly caking coal, the total expansion specific volume of the blended coal and the coal filling bulk density is determined in advance.
The pulverization particle size is determined from the above relationship depending on the product of the high temperature heating expansion specific volume of the low coalification non-caking coal used and the total expansion specific volume of the coal blend determined by the operating conditions and the coal filling bulk density. And
A method for producing coke, characterized in that the low-coalizing non-coking coal used is pulverized so as to have the determined pulverized particle size.

Images