JP2015504941A5 - - Google Patents
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- Publication number
- JP2015504941A5 JP2015504941A5 JP2014547502A JP2014547502A JP2015504941A5 JP 2015504941 A5 JP2015504941 A5 JP 2015504941A5 JP 2014547502 A JP2014547502 A JP 2014547502A JP 2014547502 A JP2014547502 A JP 2014547502A JP 2015504941 A5 JP2015504941 A5 JP 2015504941A5
- Authority
- JP
- Japan
- Prior art keywords
- hydrocarbyl
- isobutene
- group
- lewis acid
- hydrocarbyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 24
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 24
- -1 aliphatic alcohols Chemical class 0.000 claims 10
- 239000002879 Lewis base Substances 0.000 claims 9
- 150000007527 lewis bases Chemical class 0.000 claims 8
- 238000000034 method Methods 0.000 claims 8
- 239000000203 mixture Substances 0.000 claims 8
- 239000002841 Lewis acid Substances 0.000 claims 6
- 239000003999 initiator Substances 0.000 claims 6
- 150000007517 lewis acids Chemical class 0.000 claims 6
- 239000000178 monomer Substances 0.000 claims 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 4
- 125000004122 cyclic group Chemical group 0.000 claims 4
- 229910052733 gallium Inorganic materials 0.000 claims 4
- 229910052736 halogen Inorganic materials 0.000 claims 4
- 229910052742 iron Inorganic materials 0.000 claims 4
- 239000011968 lewis acid catalyst Substances 0.000 claims 4
- 239000002184 metal Substances 0.000 claims 4
- 229910052751 metal Inorganic materials 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 125000002015 acyclic group Chemical group 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 125000001743 benzylic group Chemical group 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 150000001723 carbon free-radicals Chemical class 0.000 claims 2
- 150000004292 cyclic ethers Chemical class 0.000 claims 2
- 229910052735 hafnium Inorganic materials 0.000 claims 2
- 150000004820 halides Chemical class 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 150000002367 halogens Chemical class 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims 2
- 150000002576 ketones Chemical class 0.000 claims 2
- 239000012454 non-polar solvent Substances 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229920001083 polybutene Polymers 0.000 claims 2
- 239000002904 solvent Substances 0.000 claims 2
- 229910052717 sulfur Inorganic materials 0.000 claims 2
- 239000011593 sulfur Substances 0.000 claims 2
- 150000003564 thiocarbonyl compounds Chemical class 0.000 claims 2
- 150000003568 thioethers Chemical class 0.000 claims 2
- 229910052721 tungsten Inorganic materials 0.000 claims 2
- 229910052726 zirconium Inorganic materials 0.000 claims 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 1
- 239000001282 iso-butane Substances 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/328,569 | 2011-12-16 | ||
| US13/328,569 US9034998B2 (en) | 2011-12-16 | 2011-12-16 | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| PCT/US2012/069822 WO2013090764A1 (en) | 2011-12-16 | 2012-12-14 | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2015504941A JP2015504941A (ja) | 2015-02-16 |
| JP2015504941A5 true JP2015504941A5 (https=) | 2016-01-28 |
| JP5945605B2 JP5945605B2 (ja) | 2016-07-05 |
Family
ID=47630508
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2014547502A Active JP5945605B2 (ja) | 2011-12-16 | 2012-12-14 | 高反応性オレフィン機能性ポリマーを作製する重合開始系および方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9034998B2 (https=) |
| EP (1) | EP2604635B1 (https=) |
| JP (1) | JP5945605B2 (https=) |
| CN (1) | CN104245758B (https=) |
| CA (1) | CA2859545C (https=) |
| SG (1) | SG11201403295PA (https=) |
| WO (1) | WO2013090764A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9034998B2 (en) | 2011-12-16 | 2015-05-19 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US9156924B2 (en) * | 2013-03-12 | 2015-10-13 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US9631038B2 (en) * | 2013-10-11 | 2017-04-25 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US9771442B2 (en) * | 2015-05-13 | 2017-09-26 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| WO2017151339A1 (en) | 2016-03-03 | 2017-09-08 | Tpc Group Llc | Low-fluoride, reactive polyisobutylene |
| US10167352B1 (en) | 2017-06-28 | 2019-01-01 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US10047174B1 (en) * | 2017-06-28 | 2018-08-14 | Infineum International Limited | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US10174138B1 (en) * | 2018-01-25 | 2019-01-08 | University Of Massachusetts | Method for forming highly reactive olefin functional polymers |
| US10829573B1 (en) * | 2019-05-21 | 2020-11-10 | Infineum International Limited | Method for forming highly reactive olefin functional polymers |
| EP3943518A1 (en) | 2020-07-22 | 2022-01-26 | Indian Oil Corporation Limited | Polymerization catalyst system and process to produce highly reactive polyisobutylene |
Family Cites Families (42)
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|---|---|---|---|---|
| US2682531A (en) | 1951-03-31 | 1954-06-29 | Standard Oil Dev Co | Zirconium tetrachloride-ether complexes as low temperature polymerization catalyst |
| US3850897A (en) | 1971-11-26 | 1974-11-26 | Snam Progetti | Procedure for the production of polymers and copolymers of isobutylene |
| DE2702604C2 (de) | 1977-01-22 | 1984-08-30 | Basf Ag, 6700 Ludwigshafen | Polyisobutene |
| CA2019908A1 (en) * | 1989-12-28 | 1991-06-28 | Rudolf Lukas | Graft copolymers and the method and initiation system for preparation thereof |
| US5254649A (en) | 1990-11-28 | 1993-10-19 | Bp Chemicals Limited | Cationic polymerization of 1-olefins |
| US5286823A (en) | 1991-06-22 | 1994-02-15 | Basf Aktiengesellschaft | Preparation of highly reactive polyisobutenes |
| US5350819A (en) | 1993-02-19 | 1994-09-27 | Exxon Chemical Patents Inc. | Carbocationic catalysts and process for using said catalysts |
| WO1994028036A1 (en) | 1993-05-20 | 1994-12-08 | Exxon Chemical Patents Inc. | Heterogeneous lewis acid-type catalysts |
| US5710225A (en) | 1996-08-23 | 1998-01-20 | The Lubrizol Corporation | Heteropolyacid catalyzed polymerization of olefins |
| DE19704482A1 (de) | 1997-02-06 | 1998-08-13 | Basf Ag | Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten |
| DE19734176A1 (de) | 1997-08-07 | 1999-02-11 | Basf Ag | Verfahren zur Herstellung von halogenfreiem, reaktivem Polyisobuten |
| US6407186B1 (en) | 1997-12-12 | 2002-06-18 | Basf Aktiengesellschaft | Method for producing low-molecular, highly reactive polyisobutylene |
| JP2002517571A (ja) | 1998-06-12 | 2002-06-18 | ユニベーション・テクノロジーズ・エルエルシー | 活性化されたルイス酸−塩基錯体を使用するオレフィン重合方法 |
| US6346585B1 (en) | 1999-06-24 | 2002-02-12 | The Lubrizol Corporation | Ammonium heteropolyacid catalized polymerization of olefins |
| US6407170B1 (en) | 1999-06-24 | 2002-06-18 | The Lubrizol Corporation | Dispersants prepared from high polydispersity olefin polymers |
| US6562913B1 (en) | 1999-09-16 | 2003-05-13 | Texas Petrochemicals Lp | Process for producing high vinylidene polyisobutylene |
| DE19952030A1 (de) | 1999-10-28 | 2001-05-03 | Basf Ag | Verfahren zur Herstellung von hochreaktiven Polyisobutenen |
| US6858690B2 (en) | 1999-11-15 | 2005-02-22 | Exxonmobil Chemical Patents Inc. | Process for polymerizing cationically polymerizable monomers |
| DE10035298A1 (de) | 2000-07-18 | 2002-01-31 | Basf Ag | Verfahren zur Herstellung von Polysiobutenen |
| JP4106265B2 (ja) | 2000-11-17 | 2008-06-25 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリイソブテンの製造における三フッ化ホウ素の不活性化及び回復のための方法 |
| DE10061715A1 (de) * | 2000-12-12 | 2002-06-13 | Basf Ag | Verfahren zur Herstellung von Homo- und Copolymeren des Isobutens |
| DE10118182A1 (de) | 2001-04-11 | 2002-10-17 | Basf Ag | Verfahren zur Aufarbeitung eines flüssigen Reaktionsaustrages der kationischen Polymerisation von Isobuten |
| DE10211418A1 (de) | 2002-03-15 | 2003-09-25 | Bayer Ag | Verfahren zur Herstellung hochreaktiver Polyisobutene |
| CA2493729A1 (en) * | 2002-08-13 | 2004-02-19 | Exxonmobil Chemical Patents Inc. | Process for polymerizing cationically polymerizable monomers |
| AU2003297458A1 (en) | 2002-12-20 | 2004-07-22 | Exxonmobil Chemical Patents Inc. | Polymerization processes |
| CN100402558C (zh) * | 2002-12-20 | 2008-07-16 | 埃克森美孚化学专利公司 | 聚合方法 |
| DE10303212A1 (de) | 2003-01-24 | 2004-08-05 | Basf Ag | Verfahren zur Herstellung von Polyisobuten |
| DE10356768A1 (de) | 2003-12-04 | 2005-07-07 | Universität Karlsruhe (TH) - Körperschaft des öffentlichen Rechts | Verfahren zur Herstellung von Salzen schwach koordinierender Anionen, derartige Salze sowie deren Verwendung |
| WO2006074211A1 (en) | 2005-01-05 | 2006-07-13 | University Of Massachusetts | Polymerization of olefins |
| DE102005055818A1 (de) | 2005-11-21 | 2007-05-24 | Basf Ag | Verfahren zur Herstellung von hochreaktiven Isobutenhomo- oder -copolymeren mittels metallhaltiger Katalysatorkomplexe |
| WO2008095933A1 (de) | 2007-02-09 | 2008-08-14 | Basf Se | Verfahren zur polymerisation von ethylenisch ungesättigten monomeren |
| TW200846017A (en) * | 2007-04-03 | 2008-12-01 | Fancl Corp | Apoptosis inhibitory agent |
| US8394897B2 (en) * | 2008-03-25 | 2013-03-12 | Chevron Oronite Company Llc | Production of vinylidene-terminated polyolefins via quenching with monosulfides |
| US20090258803A1 (en) * | 2008-04-14 | 2009-10-15 | Harrison James J | Copolymers made with quasi-living polyolefins and unsaturated acidic reagents, dispersants using same, and methods of making same |
| US8063154B2 (en) * | 2008-06-24 | 2011-11-22 | The University Of Southern Mississippi | Preparation of exo-olefin terminated polyolefins via quenching with alkoxysilanes or ethers |
| WO2010139684A1 (de) | 2009-06-05 | 2010-12-09 | Basf Se | Verbindung aus einem protonierten aromaten und einem schwach koordinierenden anion als polymerisationskatalysator für isobuten oder ein isobuten-haltiges monomerengemisch |
| CN101955558B (zh) | 2009-07-15 | 2013-03-13 | 北京化工大学 | 制备高反应活性聚异丁烯及其共聚物的引发体系 |
| WO2011054785A1 (de) | 2009-11-04 | 2011-05-12 | Basf Se | Verfahren zur herstellung von homo- oder copolymeren |
| US8349977B2 (en) | 2010-02-17 | 2013-01-08 | Basf Se | Process for preparing high-reactivity isobutene homo- or copolymers |
| US9562117B2 (en) | 2010-11-30 | 2017-02-07 | Basf Se | Preparation of derivatives of isobutene copolymers |
| US9034998B2 (en) | 2011-12-16 | 2015-05-19 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
| US9156924B2 (en) | 2013-03-12 | 2015-10-13 | University Of Massachusetts | Polymerization initiating system and method to produce highly reactive olefin functional polymers |
-
2011
- 2011-12-16 US US13/328,569 patent/US9034998B2/en active Active
- 2011-12-20 EP EP11194680.2A patent/EP2604635B1/en active Active
-
2012
- 2012-12-14 JP JP2014547502A patent/JP5945605B2/ja active Active
- 2012-12-14 CN CN201280069469.XA patent/CN104245758B/zh active Active
- 2012-12-14 SG SG11201403295PA patent/SG11201403295PA/en unknown
- 2012-12-14 WO PCT/US2012/069822 patent/WO2013090764A1/en not_active Ceased
- 2012-12-14 CA CA2859545A patent/CA2859545C/en active Active
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