JP2015168627A - oil-in-water type cosmetic - Google Patents
oil-in-water type cosmetic Download PDFInfo
- Publication number
- JP2015168627A JP2015168627A JP2014042727A JP2014042727A JP2015168627A JP 2015168627 A JP2015168627 A JP 2015168627A JP 2014042727 A JP2014042727 A JP 2014042727A JP 2014042727 A JP2014042727 A JP 2014042727A JP 2015168627 A JP2015168627 A JP 2015168627A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- water
- mass
- water cosmetic
- cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 claims description 3
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- 238000003860 storage Methods 0.000 abstract description 20
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Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明は、水中油型化粧料であって、特に、保存安定性に優れ、噴霧器を用いた場合、即座に霧状となりやすく、また噴霧の広がりが大きく、更に塗布した際の化粧料の滞留性に優れた水中油型化粧料に関するものである。 The present invention is an oil-in-water cosmetic, particularly excellent in storage stability, and when a sprayer is used, it tends to be instantly misty, has a large spray spread, and further retains the cosmetic when applied. The present invention relates to an oil-in-water cosmetic having excellent properties.
近年、幼児から大人まで使用できる皮膚によりやさしい化粧料が求められている。特に噴霧器を用いて霧状にできる化粧料（以下、「噴霧用化粧料」と記載することがある。）は、塗布部分が広範囲であっても均一に塗布できることから、幅広く使用されている。 In recent years, cosmetics that are gentler to skin that can be used from infants to adults have been demanded. In particular, cosmetics that can be made into a mist using a sprayer (hereinafter sometimes referred to as “spraying cosmetics”) are widely used because they can be applied uniformly even in a wide area.
噴霧用化粧料としては、水膨潤性粘土鉱物を水相に分散した化粧料が知られている。水膨潤性粘土鉱物を配合すると、噴霧器内では化粧料成分がゲル状態になることから、化粧料成分の分散状態を維持することができる。そして、噴霧器を押して圧力を加えることで、噴霧用化粧料はゲル状態から瞬時に液化し、簡単に霧状にすることができる（特許文献１参照）。しかしながら、水膨潤性粘土鉱物によりゲル化した噴霧用化粧料は、経時的及び温度変化による離水を生じやすく、長期間に渡り使用する場合には、安定性が悪いという問題がある。 As a spray cosmetic, a cosmetic in which a water-swellable clay mineral is dispersed in an aqueous phase is known. When the water-swellable clay mineral is blended, the cosmetic component is in a gel state in the sprayer, and thus the dispersed state of the cosmetic component can be maintained. And by applying a pressure by pushing the sprayer, the cosmetic for spraying can be instantly liquefied from the gel state and easily made into a mist (see Patent Document 1). However, spray cosmetics gelled with water-swellable clay minerals are prone to water separation over time and temperature changes, and have a problem of poor stability when used over a long period of time.
水膨潤性粘土鉱物を配合した噴霧用化粧料において、上記問題点を解決し、形成されたゲル状の化粧料の経時的及び温度変化による離水を抑制するために、水溶性高分子、特に、エーテル化度が、０．６〜０．７５であり、１重量％水溶液にしたときの粘度領域が、１００〜１０００Ｐａ・ｓであるカルボキシメチルセルロースを配合することも知られている（特許文献２参照）。しかしながら、カルボキシメチルセルロース等の合成高分子は、安定性は優れているものの、皮膚に噴霧した場合、べたつき感が生じる等、使用感触が悪いという問題がある。 In spray cosmetics formulated with water-swellable clay minerals, in order to solve the above-mentioned problems and suppress water separation due to changes in the gel-like cosmetics formed over time and temperature, water-soluble polymers, in particular, It is also known to blend carboxymethyl cellulose having a degree of etherification of 0.6 to 0.75 and a viscosity range of 100 to 1000 Pa · s when a 1 wt% aqueous solution is formed (see Patent Document 2). ). However, although synthetic polymers such as carboxymethyl cellulose are excellent in stability, there is a problem that the feeling of use is poor, for example, a sticky feeling occurs when sprayed on the skin.
ところで、噴霧用化粧料として、皮膚に適当な潤いを与える為に、油性成分を加えた水中油型化粧料が知られている（特許文献３及び４参照）。水中油型化粧料は、水相と油性成分を含むことから、皮膚へのなじみがよく、非常にさっぱりとした使用感触を与えることができる。しかしながら、水中油型化粧料は、長期間保存すると水相と油性成分が分離し易くなるため、化粧料中で濃度勾配が生じ、均一な組成で噴霧することはできないという問題がある。 By the way, oil-in-water cosmetics to which an oily component is added in order to impart appropriate moisture to the skin are known as spray cosmetics (see Patent Documents 3 and 4). Since the oil-in-water cosmetic contains an aqueous phase and an oily component, it is well-familiar with the skin and can give a very refreshing feel. However, oil-in-water cosmetics have a problem that when they are stored for a long period of time, the water phase and the oily component are easily separated, so that there is a concentration gradient in the cosmetics and it cannot be sprayed with a uniform composition.
水相と油性成分の分離は、水性高分子等の配合量を増加し、水中油型化粧料の粘度を上げることで抑えることができる。しかしながら、粘度を上げると水中油型化粧料を噴霧した際に、塗布範囲が狭くなったり、個々の霧の径が大きくなる等、噴霧特性が著しく低下するという問題がある。また、皮膚に塗布した後に皮膜感が残る等、使用性が悪くなるという問題がある。そのため、エモリエント効果を付与する、香料を配合して賦香効果や昆虫忌避効果を付与する、紫外線吸収剤などの紫外線防御効果を付与する等の目的のために、油性成分を配合した水中油型化粧料を噴霧用に用いることが困難であった。 Separation of the water phase and the oily component can be suppressed by increasing the amount of the aqueous polymer or the like and increasing the viscosity of the oil-in-water cosmetic. However, when the viscosity is increased, there is a problem that when the oil-in-water type cosmetic is sprayed, the spraying characteristics are remarkably deteriorated, for example, the application range is narrowed or the diameter of each mist is increased. Moreover, there exists a problem that usability worsens, such as a film feeling remaining after apply | coating to skin. Therefore, it is an oil-in-water type that contains an oil component for the purpose of imparting an emollient effect, blending a fragrance to impart a fragrance effect or insect repellent effect, or imparting an ultraviolet protection effect such as an ultraviolet absorber. It has been difficult to use cosmetics for spraying.
本発明は、上記従来の問題を解決するためになされた発明であり、鋭意研究を行ったところ、（１）前記特許文献２に記載されているカルボキシメチルセルロース、前記特許文献４に記載されているカチオン性高分子等の合成高分子は保存安定性に優れているものの、チキソトロピー性が劣っていること、（２）天然高分子はチキソトロピー性に優れているため、粘度を上げて化粧料成分の分散安定性を経時的に維持しつつ、噴霧器の圧力を高めることで、ゲル状態の水中油型化粧料の粘度を下げることができること、更に、（３）天然高分子に１価又は２価の金属イオンを含有する金属塩を配合することで、チキソトロピー性を維持しつつ水中油型化粧料の粘度を調整できること、を新たに見出し、本願発明を完成した。 The present invention has been made in order to solve the above-described conventional problems, and as a result of intensive research, (1) carboxymethyl cellulose described in Patent Document 2 and described in Patent Document 4 Synthetic polymers such as cationic polymers are excellent in storage stability but inferior in thixotropy. (2) Natural polymers are excellent in thixotropy. The viscosity of the gel oil-in-water cosmetic can be lowered by increasing the pressure of the sprayer while maintaining the dispersion stability over time. Furthermore, (3) the natural polymer is monovalent or divalent. The present invention was completed by newly discovering that the viscosity of an oil-in-water cosmetic can be adjusted while maintaining thixotropy by blending a metal salt containing a metal ion.
すなわち、本発明の目的は、噴霧時の広がり、保存安定性、使用性に優れる等、噴霧用に適した水中油型化粧料を提供することである。 That is, an object of the present invention is to provide an oil-in-water cosmetic suitable for spraying, such as excellent spread during spraying, storage stability, and usability.
本発明は、以下に示す、水中油型化粧料に関する。 The present invention relates to the following oil-in-water cosmetics.
（１）化粧料全量に対し、
（Ａ）水膨潤性粘土鉱物 ０．１〜５質量％
（Ｂ）天然高分子 ０．０１〜３質量％
（Ｃ）油性成分 ０．１〜２０質量％
（Ｄ）界面活性剤 ０．０１〜５質量％
を含むことを特徴とする水中油型化粧料。
（２）前記（Ａ）水膨潤性粘土鉱物が、スメクタイト、ヘクトライト、ベントナイト、モンモリロナイトより選ばれる少なくとも１種以上であることを特徴とする上記（１）に記載の水中油型化粧料。
（３）前記（Ｂ）天然高分子が、グアーガム、ローカストビンガム、クインスシード、カラギーナン、ガラクタン、アラビアガム、トラガカントガム、ペクチン、マンナン、デンプン、アルギン酸、キサンタンガム、デキストラン、サクシノグルカン、カードラン、ヒアルロン酸、ゼラチン、プルラン、カゼイン、アルブミン、コラーゲンより選ばれる少なくとも１種以上であることを特徴とする上記（１）又は（２）に記載の水中油型化粧料。
（４）前記（Ｃ）油性成分が、油脂類、ロウ類、炭化水素類、高級脂肪酸類、高級アルコール類、鉱物油、エステル類、精油、香料から選ばれる少なくとも１種以上であることを特徴とする上記（１）〜（３）の何れか一に記載の水中油型化粧料。
（５）前記（Ｄ）界面活性剤が、レシチン、レシチン誘導体、ポリグリセリン脂肪酸エステル、ショ糖脂肪酸エステルから選ばれる少なくとも１種以上であることを特徴とする上記（１）〜（４）の何れか一に記載の水中油型化粧料。
（６）（Ｅ）１価又は２価の金属イオンを含有する金属塩、から選ばれる少なくとも１種以上を更に含むことを特徴とする上記（１）〜（５）の何れか一に記載の水中油型化粧料。
（７）２５℃における粘度が、１〜３０００ｍＰａ・Ｓであることを特徴とする上記（１）〜（６）の何れか一に記載の水中油型化粧料。
（８）前記水中油型化粧料が、噴霧用であることを特徴とする上記（１）〜（７）の何れか一に記載の水中油型化粧料。
（９）上記（１）〜（８）の何れか一に記載の水中油型化粧料が、噴霧器に入れられていることを特徴とする噴霧用水中油型化粧料。
(1) For the total amount of cosmetics
(A) Water-swellable clay mineral 0.1 to 5% by mass
(B) Natural polymer 0.01-3 mass%
(C) Oil component 0.1-20 mass%
(D) Surfactant 0.01-5% by mass
Oil-in-water cosmetics characterized by containing.
(2) The oil-in-water cosmetic according to (1), wherein (A) the water-swellable clay mineral is at least one selected from smectite, hectorite, bentonite, and montmorillonite.
(3) The natural polymer (B) is guar gum, locust bin gum, quince seed, carrageenan, galactan, arabic gum, tragacanth gum, pectin, mannan, starch, alginic acid, xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid The oil-in-water cosmetic according to (1) or (2) above, wherein the cosmetic is at least one selected from gelatin, pullulan, casein, albumin, and collagen.
(4) The oil component (C) is at least one selected from fats and oils, waxes, hydrocarbons, higher fatty acids, higher alcohols, mineral oils, esters, essential oils, and perfumes. The oil-in-water cosmetic according to any one of (1) to (3) above.
(5) Any of the above (1) to (4), wherein the surfactant (D) is at least one selected from lecithin, a lecithin derivative, a polyglycerin fatty acid ester, and a sucrose fatty acid ester. The oil-in-water cosmetic according to any one of the above.
(6) (E) The metal salt containing a monovalent or divalent metal ion, further comprising at least one selected from the group consisting of (1) to (5) Oil-in-water cosmetics.
(7) The oil-in-water cosmetic according to any one of (1) to (6) above, wherein the viscosity at 25 ° C is 1 to 3000 mPa · S.
(8) The oil-in-water cosmetic according to any one of (1) to (7), wherein the oil-in-water cosmetic is for spraying.
(9) An oil-in-water cosmetic for spraying, wherein the oil-in-water cosmetic according to any one of (1) to (8) is placed in a sprayer.
本発明の水中油型化粧料は、天然高分子を用いて粘度を上げているので、油性成分を加えても保存安定性に優れており、エモリエント効果、賦香効果、紫外線防御効果などの優れた効果を付与させることができる。
また、天然高分子はチキソトロピー性に優れていることから、保存状態の水中油型化粧料の粘度を上げても、良好な噴霧特性が得られる。そして、合成高分子と異なり天然高分子は天然物であるので、皮膚のべたつき感がなく、皮膚にも優しく、年齢を問わず用いることができる。
更に、天然高分子は、金属塩を配合することで粘度を上げることができるため、天然高分子の配合量を少なくしても保存安定性を向上することができる。その結果、皮膚に塗布した後の皮膜感が少ない、使用性に優れた化粧料を得ることができる。
Since the oil-in-water cosmetic of the present invention has a viscosity increased by using a natural polymer, it is excellent in storage stability even when an oil component is added, and has excellent emollient effect, flavoring effect, UV protection effect, etc. Effects can be imparted.
In addition, since natural polymers are excellent in thixotropic properties, good spray characteristics can be obtained even if the viscosity of the preserved oil-in-water cosmetic is increased. And unlike a synthetic polymer, since a natural polymer is a natural product, there is no stickiness of the skin, it is gentle to the skin, and can be used regardless of age.
Furthermore, since a natural polymer can raise a viscosity by mix | blending a metal salt, even if it reduces the compounding quantity of a natural polymer, storage stability can be improved. As a result, it is possible to obtain a cosmetic material that has less film feeling after being applied to the skin and has excellent usability.
以下に、本発明の水中油型化粧料について詳しく説明する。 Hereinafter, the oil-in-water cosmetic of the present invention will be described in detail.
本発明の水中油型化粧料は、化粧料全量に対し、（Ａ）水膨潤性粘土鉱物を０．１〜５質量％、（Ｂ）天然高分子を０．０１〜３質量％、（Ｃ）油性成分を０．１〜２０質量％、（Ｄ）界面活性剤を０．０１〜５質量％を少なくとも含んでいる。 The oil-in-water cosmetic of the present invention is 0.1 to 5% by mass of (A) water-swellable clay mineral, (B) 0.01 to 3% by mass of natural polymer, (C It contains at least 0.1 to 20% by weight of an oily component and 0.01 to 5% by weight of (D) a surfactant.
前記（Ａ）水膨潤性粘土鉱物としては、スメクタイト、ベントナイト、ヘクトライト、モンモリロナイト等があげられる。これら水膨潤性粘土鉱物としては天然産のものを化粧品で使用できる程度に精製したものを使用しても、合成されたものを使用してもよい。その中でもスメクタイト族鉱物が好ましく、例えば、モンモリロナイト、ベントナイト、ヘクトライトなどが挙げられる。前記水膨潤性粘土鉱物は、１種でも良いし、２種以上を組合せて用いてもよい。これらの水膨潤性粘土鉱物は、非常に高いチキソトロピー性を持ち、水を含有させることにより、ゲルを形成させることができる。得られたゲル状の化粧料は、圧力を加えることで液化するので、噴霧器に入れて加圧噴射動作によって霧状化させることが可能であり、皮膚等の使用対象箇所に直接噴霧することができる。 Examples of the (A) water-swellable clay mineral include smectite, bentonite, hectorite, and montmorillonite. As these water-swellable clay minerals, natural ones purified to such an extent that they can be used in cosmetics may be used, or synthesized ones may be used. Among them, smectite group minerals are preferable, and examples thereof include montmorillonite, bentonite, hectorite and the like. One kind of the water-swellable clay mineral may be used, or two or more kinds may be used in combination. These water-swellable clay minerals have very high thixotropic properties, and can form a gel by containing water. The gel-like cosmetic obtained is liquefied by applying pressure, so it can be put into a sprayer and atomized by a pressure injection operation, and can be directly sprayed on the use target site such as the skin. it can.
前記（Ａ）水膨潤性粘土鉱物の配合量は、水中油型化粧料全量に対して０．１〜５．０質量％が好ましく、０．５〜２．０質量％がより好ましい。０．１質量％未満では充分な粘度を得られない。また、５質量％を超えて配合すると、水膨潤性粘土特有のきしみが感じられるようになり、更に、得られた水中油型化粧料のゲル化度も高くなってしまい連続してスプレーすることができなくなることがあるので好ましくない。 The blending amount of the (A) water-swellable clay mineral is preferably 0.1 to 5.0% by mass, and more preferably 0.5 to 2.0% by mass with respect to the total amount of the oil-in-water cosmetic. If it is less than 0.1% by mass, sufficient viscosity cannot be obtained. Moreover, when it mixes exceeding 5 mass%, a squeak peculiar to water-swellable clay will be felt, and further, the gelation degree of the obtained oil-in-water cosmetic will increase, and spray continuously. Is not preferred because it may not be possible.
本発明における「天然高分子」とは、化粧料に増粘効果を付与できる高分子であって、半合成高分子や合成高分子ではなく、天然の高分子を意味する。前記（Ｂ）天然高分子としては、植物及び微生物に由来する多糖類、動物に由来するタンパク質などが挙げられる。植物に由来の多糖類としては、グアーガム、ローカストビンガム、クインスシード、カラギーナン、ガラクタン、アラビアガム、トラガカントガム、ペクチン、マンナン、デンプン、アルギン酸等が挙げられる。微生物に由来する多糖類としては、キサンタンガム、デキストラン、サクシノグルカン、カードラン、ヒアルロン酸、プルラン等が挙げられる。動物に由来するタンパク質としては、ゼラチン、カゼイン、アルブミン、コラーゲン等が挙げられる。前記天然高分子は、１種でも良いし、２種以上を組合せて用いてもよい。 The “natural polymer” in the present invention is a polymer that can impart a thickening effect to cosmetics, and means a natural polymer, not a semi-synthetic polymer or a synthetic polymer. Examples of the (B) natural polymer include polysaccharides derived from plants and microorganisms, proteins derived from animals, and the like. Examples of polysaccharides derived from plants include guar gum, locust bin gum, quince seed, carrageenan, galactan, gum arabic, gum tragacanth, pectin, mannan, starch, alginic acid and the like. Examples of polysaccharides derived from microorganisms include xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid, and pullulan. Examples of proteins derived from animals include gelatin, casein, albumin, and collagen. The natural polymer may be used alone or in combination of two or more.
前記（Ｂ）天然高分子の配合量は、水中油型化粧料全量に対して０．０１〜３．０質量％が好ましく、０．０３〜１．０質量％がより好ましい。０．０１質量％未満では充分な粘度が得られず、また３質量％を超えて配合すると、噴霧した後に天然高分子の皮膜感が感じられるようになるので好ましくない。 The blending amount of the natural polymer (B) is preferably 0.01 to 3.0% by mass, more preferably 0.03 to 1.0% by mass with respect to the total amount of the oil-in-water cosmetic. If it is less than 0.01% by mass, a sufficient viscosity cannot be obtained, and if it exceeds 3% by mass, a film feeling of the natural polymer can be felt after spraying.
前記（Ｃ）油性成分としては、ワセリン、スクワランや流動パラフィン等のような炭化水素系油、ホホバ油やゲイロウ等のようなエステル類、牛脂などの天然油脂、トリ（カプリル酸／カプリン酸）グリセリルやオリーブ油等のトリグリセライド系油、イソステアリルアルコール、オクチルドデカノール、オレイルアルコール等の高級アルコール系油、イソステアリン酸、ステアリン酸、オレイン酸、パルミチン酸等の脂肪酸系油、ミツロウ、カルナバロウ、キャンデリラなどのロウ系油、高重合ジメチルポリシロキサン、ポリエーテル変性ジメチルポリシロキサン、アミノ変性ジメチルポリシロキサンなどのシリコーン系油又はその誘導体、セラミド、コレステロール、フィトステロール、コレステロール又はフィトステロール誘導体、タンパク誘導体、ラノリン、ラノリン誘導体、レシチンなどの油性基剤、ラベンダー油、ユーカリ葉油、ティーツリー葉油、レモングラス油、ハッカ油、メントール、カンフル等の精油、香料又は清涼化剤、メトキシケイヒ酸エチルヘキシル等の紫外線吸収剤などが挙げられる。前記油性成分は、１種でも良いし、２種以上を組合せて用いてもよい。 Examples of the oil component (C) include hydrocarbon oils such as petrolatum, squalane and liquid paraffin, esters such as jojoba oil and gallow, natural fats and oils such as beef tallow, tri (caprylic acid / capric acid) glyceryl. Waxes such as beeswax, carnauba wax, candelilla, triglyceride oils such as olive oil, higher alcohol oils such as isostearyl alcohol, octyldodecanol, oleyl alcohol, fatty acid oils such as isostearic acid, stearic acid, oleic acid, palmitic acid Base oil, highly polymerized dimethylpolysiloxane, polyether-modified dimethylpolysiloxane, amino-modified dimethylpolysiloxane and other silicone oils or derivatives thereof, ceramide, cholesterol, phytosterol, cholesterol or phytosterol derivatives, Oil bases such as park derivatives, lanolin, lanolin derivatives, lecithin, lavender oil, eucalyptus leaf oil, tea tree leaf oil, lemongrass oil, peppermint oil, menthol, camphor, and other essential oils, perfumes or cooling agents, methoxycinnamic acid Examples thereof include ultraviolet absorbers such as ethylhexyl. The oil component may be used alone or in combination of two or more.
前記（Ｃ）油性成分の配合量は、水中油型化粧料全量に対して０．１〜２０．０質量％が好ましく、０．３〜１５．０質量％がより好ましく、０．５〜１０．０質量％が特に好ましい。０．１質量％未満では充分なエモリエント効果、賦香効果、紫外線防御効果を得られず、また２０％を超えて配合すると、油性感が強い使用感となるとともに、油浮きが見られるようになり、安定性が低下することがあるので好ましくない。 0.1-20.0 mass% is preferable with respect to the oil-in-water cosmetics whole quantity, and, as for the compounding quantity of the said (C) oil-based component, 0.3-15.0 mass% is more preferable, 0.5-10 0.0 mass% is particularly preferable. If it is less than 0.1% by mass, sufficient emollient effect, perfume effect, and UV protection effect cannot be obtained, and if it exceeds 20%, oily feeling becomes strong and a feeling of oil floating is seen. This is not preferable because the stability may be lowered.
前記（Ｄ）界面活性剤としては、ポリグリセリン脂肪酸エステル、レシチン及び／又はその誘導体、ショ糖脂肪酸エステルが挙げられる。前記界面活性剤は、１種でも良いし、２種以上を組合せて用いてもよい。 Examples of the surfactant (D) include polyglycerin fatty acid esters, lecithin and / or derivatives thereof, and sucrose fatty acid esters. The surfactant may be used alone or in combination of two or more.
ポリグリセリン脂肪酸エステルとして、例えば、モノイソステアリン酸ジグリセリル、モノオレイン酸ジグリセリル、トリイソステアリン酸ジグリセリルなどのジグリセリン脂肪酸エステル；モノオレイン酸トリグリセリル、ジイソステアリン酸トリグリセリル、（カプリル・カプリン酸）トリグリセリルなどのトリグリセリン脂肪酸エステル；モノオレイン酸ペンタグリセリル、ジイソステアリン酸ペンタグリセリル、トリステアリン酸ペンタグリセリル、ヘキサステアリン酸ペンタグリセリルなどのペンタグリセリン脂肪酸エステル；モノステアリン酸ヘキサグリセリル、ジカプリン酸ヘキサグリセリル、トリミリスチン酸ヘキサグリセリルなどのヘキサグリセリン脂肪酸エステル；モノミリスチン酸デカグリセリル、モノオレイン酸デカグリセリル、ジステアリン酸デカグリセリル、ペンタオレイン酸デカグリセリル、デカステアリン酸デカグリセリルなどのデカグリセリン脂肪酸エステル等が挙げられる。 Examples of polyglycerin fatty acid esters include diglycerin fatty acid esters such as diglyceryl monoisostearate, diglyceryl monooleate, and diglyceryl triisostearate; triglyceryl monooleate, triglyceryl diisostearate, (capryl capric acid) tri Triglycerin fatty acid esters such as glyceryl; pentaglyceryl monooleate, pentaglyceryl diisostearate, pentaglyceryl tristearate, pentaglyceryl hexastearate; hexaglyceryl monostearate, hexaglyceryl dicaprate, trimyristin Hexaglycerin fatty acid esters such as hexaglyceryl acid; decaglyceryl monomyristate, monooleate Glyceryl, decaglyceryl distearate, pentaerythritol oleate decaglyceryl such decaglycerol fatty acid esters such as Dekasutearin decaglyceryl the like.
本発明における「レシチン誘導体」は、ダイズ、コメ、ナタネ、サフラワー、卵黄といった天然由来または化学的に合成されたレシチン類を化学的または酵素処理することで得られたものである。レシチンとはグリセリン骨格に脂肪酸残基とリン酸残基、およびこれにコリン、エタノールアミン、イノシトール、セリン等が結合した構造を有する化合物単品またはこれらの混合物である。レシチン誘導体としては、例えば、酵素分解レシチン、水素添加酵素分解レシチン、ヒドロキシレシチン、ホスファチジルグリセロール、ホスファチジン酸、アセチル化レシチン等が挙げられる。 The “lecithin derivative” in the present invention is obtained by chemically or enzymatically treating naturally derived or chemically synthesized lecithins such as soybean, rice, rapeseed, safflower and egg yolk. Lecithin is a single compound or a mixture thereof having a structure in which a fatty acid residue and a phosphate residue, and choline, ethanolamine, inositol, serine and the like are bonded to a glycerin skeleton. Examples of lecithin derivatives include enzymatically decomposed lecithin, hydrogenated enzymatically decomposed lecithin, hydroxy lecithin, phosphatidylglycerol, phosphatidic acid, acetylated lecithin and the like.
ショ糖脂肪酸エステルとして、例えば、ショ糖ベヘン酸エステル；ステアリン酸スクロース、ジステアリン酸スクロース、トリステアリン酸スクロース、ポリステアリン酸スクロースなどのショ糖ステアリン酸エステル；パルミチン酸スクロース、ヘキサパルミチン酸スクロースなどのショ糖パルミチン酸エステル；ミリスチン酸スクロースなどのショ糖ミリスチン酸エステル；ラウリン酸スクロース、ジラウリン酸スクロース、ポリラウリン酸スクロースなどのショ糖ラウリン酸エステル；ペンタエルカ酸スクロース、ヘキサエルカ酸スクロースなどのショ糖エルカ酸エステル；オレイン酸スクロース、ポリオレイン酸スクロースなどのショ糖オレイン酸エステルなどが挙げられる。 Examples of sucrose fatty acid esters include sucrose behenate; sucrose stearate such as sucrose stearate, sucrose distearate, sucrose tristearate, and sucrose polystearate; Sugar palmitate ester; sucrose myristate ester such as sucrose myristate; sucrose laurate ester such as sucrose laurate, dilaurate sucrose, polylaurate sucrose; sucrose erucate ester such as sucrose pentaerucate sucrose hexahexa Examples thereof include sucrose oleate such as sucrose oleate and sucrose polyoleate.
上記に例示した界面活性材の中でも、ポリグリセリン脂肪酸エステル、レシチン、レシチン誘導体が保湿性の観点から好ましく、更に、水への分散性に優れた水分散成分が得られやすいとの観点から、ペンタグリセリン脂肪酸エステル、ヘキサグリセリン脂肪酸エステル、デカグリセリン脂肪酸エステル、レシチン、酵素分解レシチン、水素添加酵素分解レシチン、ヒドロキシレシチン、ホスファチジルグリセロール、ホスファチジン酸、アセチル化レシチンがより好ましい。 Among the surfactants exemplified above, polyglycerin fatty acid ester, lecithin, and lecithin derivative are preferable from the viewpoint of moisture retention, and moreover, from the viewpoint that a water dispersion component excellent in water dispersibility can be easily obtained. More preferred are glycerin fatty acid ester, hexaglycerin fatty acid ester, decaglycerin fatty acid ester, lecithin, enzymatically decomposed lecithin, hydrogenated enzymatically decomposed lecithin, hydroxylecithin, phosphatidylglycerol, phosphatidic acid, and acetylated lecithin.
前記（Ｄ）界面活性剤の配合量は、水中油型化粧料全量に対して０．０１〜５．０質量％が好ましく、０．０５〜３．０質量％がより好ましい。０．０１質量％未満では、（Ｃ）油性成分を乳化・安定化する効果が得られず、また５質量％を超えて配合すると、噴霧した後に界面活性剤特有のべたつきを感じられるようになり、好ましくない。 The blending amount of the (D) surfactant is preferably 0.01 to 5.0% by mass, more preferably 0.05 to 3.0% by mass with respect to the total amount of the oil-in-water cosmetic. If it is less than 0.01% by mass, the effect of emulsifying and stabilizing the (C) oil component cannot be obtained, and if it exceeds 5% by mass, the stickiness peculiar to the surfactant can be felt after spraying. It is not preferable.
本発明の水中油型化粧料には、前記（Ａ）〜（Ｄ）に加え、（Ｅ）１価又は２価の金属イオンを含有する金属塩、から選ばれる少なくとも１種以上を更に含んでもよい。前記金属塩を配合することで、天然高分子が架橋して更に増粘することができるので、天然高分子の配合を少なくしても水中油型化粧料の保存安定性を向上できる。なお、金属塩を配合して天然高分子を架橋しても、天然高分子自体のチキソトロピー性を損なうことはないので、噴霧器内における水中油型化粧料の粘度が増加しても、噴霧する際にも噴霧器の吐出部で詰まることなく、即座に霧状となり、噴霧の広がりが大きく、噴霧しやすくなる。そして、天然高分子の配合量を少なくすることができるので、皮膚への塗布後の皮膜感を抑えることができる。 The oil-in-water cosmetic of the present invention may further contain at least one or more selected from (E) metal salts containing monovalent or divalent metal ions in addition to (A) to (D). Good. By blending the metal salt, the natural polymer can be cross-linked and further thickened, so that the storage stability of the oil-in-water cosmetic can be improved even if the blend of the natural polymer is reduced. Even if the natural polymer is cross-linked by blending a metal salt, the thixotropy of the natural polymer itself is not impaired, so even if the viscosity of the oil-in-water cosmetic in the sprayer increases, In addition, the spraying portion of the sprayer is not clogged, and the mist is instantly formed. And since the compounding quantity of a natural polymer can be decreased, the film feeling after application | coating to skin can be suppressed.
前記（Ｅ）金属塩について、１価の金属塩としては、例えば、乳酸ナトリウム、塩化ナトリウム、リン酸ナトリウム、クエン酸ナトリウムなどのナトリウムを含有する塩；塩化カリウム、硫酸カリウム、リン酸カリウム、メタリン酸カリウムなどのカリウムを含有する塩が挙げられる。また、２価の金属塩としては、例えば、硫酸マグネシウム、塩化マグネシウム、炭酸マグネシウムなどのマグネシウムを含有する塩；乳酸カルシウム、炭酸カルシウム、塩化カルシウム、リン酸カルシウムなどのカルシウムを含有する塩；乳酸バリウム、水酸化バリウム、リン酸バリウム、塩化バリウム二水和物などのバリウムを含有する塩；などが挙げられる。なお、前記の金属塩は単なる例示であって、天然高分子を架橋して増粘できるものであれば特に制限は無い。また、１価の金属塩を２種以上、２価の金属塩を２種以上、又は、１価の金属塩を１種以上及び２価の金属塩を１種以上等、適宜組み合わせて用いてもよい。 As for the (E) metal salt, examples of the monovalent metal salt include sodium lactate, sodium chloride, sodium phosphate, sodium citrate and other sodium salts; potassium chloride, potassium sulfate, potassium phosphate, metalin Examples include salts containing potassium such as potassium acid. Examples of the divalent metal salt include salts containing magnesium such as magnesium sulfate, magnesium chloride and magnesium carbonate; salts containing calcium such as calcium lactate, calcium carbonate, calcium chloride and calcium phosphate; barium lactate and water. And salts containing barium such as barium oxide, barium phosphate, and barium chloride dihydrate. In addition, the said metal salt is only an illustration, Comprising: If a natural polymer is bridge | crosslinked and can thicken, there will be no restriction | limiting in particular. Also, two or more monovalent metal salts, two or more divalent metal salts, or one or more monovalent metal salts and one or more divalent metal salts are used in appropriate combination. Also good.
前記（Ｅ）金属塩の配合量は、水中油型化粧料全量に対して０．００１〜１質量％が好ましい。０．００１質量％未満では充分な粘度が得られず、また１質量％を超えて配合すると、ゲルが強固となり過ぎ連続して噴霧することができなくなるので好ましくない。 The blending amount of the metal salt (E) is preferably 0.001 to 1% by mass with respect to the total amount of the oil-in-water cosmetic. If it is less than 0.001% by mass, a sufficient viscosity cannot be obtained, and if it exceeds 1% by mass, the gel becomes too strong and cannot be continuously sprayed.
本発明の水中油型化粧料における粘度は、２５℃において、１〜３０００ｍＰａ・Ｓが好ましく、５〜２０００ｍＰａ・Ｓがより好ましく、１０〜１０００ｍＰａ・Ｓが特に好ましい。粘度が、１ｍＰａ・Ｓ未満では相分離を生じ、一方、３０００ｍＰａ・Ｓを超えると使用性が低下する。粘度は、（Ａ）水膨潤性粘土鉱物及び（Ｂ）天然高分子の配合量を変えることで調整することができる。また、（Ｅ）金属塩を配合することでも調整することができる。 The viscosity of the oil-in-water cosmetic of the present invention is preferably 1 to 3000 mPa · S, more preferably 5 to 2000 mPa · S, and particularly preferably 10 to 1000 mPa · S at 25 ° C. When the viscosity is less than 1 mPa · S, phase separation occurs. On the other hand, when the viscosity exceeds 3000 mPa · S, the usability decreases. The viscosity can be adjusted by changing the amount of (A) water-swellable clay mineral and (B) natural polymer. Moreover, it can adjust also by mix | blending (E) metal salt.
本発明の水中油型化粧料には、上記（Ａ）〜（Ｅ）の他に、本発明の効果を損なわない範囲で、１種以上の成分を含んでもよい。例えば、グリセリン、プロピレングリコール、ポリエチレングリコールや１、３ーブチレングリコール等の多価アルコール類；エタノールなどの低級アルコール類；クエン酸、クエン酸ナトリウム、乳酸、水酸化ナトリウムなどのｐＨ調整剤や緩衝剤；ショ糖、トレハロース、オリゴ糖などの糖類；塩化ナトリウム、塩化カリウム、塩化カルシウム、炭酸水素ナトリウム、炭酸ナトリウム、乾燥炭酸ナトリウム、硫酸マグネシウム等の無機塩類；メタリン酸ナトリウム、エチレンジアミン四酢酸、エチレンジアミン四酢酸二ナトリウム（エデト酸ナトリウム）などの安定化剤；ジブチルヒドロキシトルエン（ＢＨＴ）、アスコルビン酸等の抗酸化剤；その他、防腐剤、色素、紛体類、血行促進剤、動植物由来の天然エキス類、アントシアニンなどのフラボノイド類およびその誘導体、ビタミン類及びその誘導体、アミノ酸類、感光素、防腐剤、ハッカ水、ローズ水などの清涼化剤又は芳香水、水膨潤性粘土鉱物以外の各種粉末や紫外線散乱剤、顔料などが挙げられる。これらの成分を定法に従って処理することで、本発明の水中油型化粧料を製造することができる。 In addition to the above (A) to (E), the oil-in-water cosmetic of the present invention may contain one or more components as long as the effects of the present invention are not impaired. For example, polyhydric alcohols such as glycerin, propylene glycol, polyethylene glycol and 1,3-butylene glycol; lower alcohols such as ethanol; pH adjusters and buffers such as citric acid, sodium citrate, lactic acid, sodium hydroxide Sugars such as sucrose, trehalose and oligosaccharide; inorganic salts such as sodium chloride, potassium chloride, calcium chloride, sodium hydrogen carbonate, sodium carbonate, dry sodium carbonate, magnesium sulfate; sodium metaphosphate, ethylenediaminetetraacetic acid, ethylenediaminetetraacetic acid Stabilizers such as disodium (sodium edetate); antioxidants such as dibutylhydroxytoluene (BHT) and ascorbic acid; other preservatives, pigments, powders, blood circulation promoters, natural extracts derived from animals and plants, anthocyanins Any flavonoids and derivatives thereof, vitamins and derivatives thereof, amino acids, photosensitizers, preservatives, mint water, rose water and other refreshing agents or aromatic waters, various powders other than water-swelling clay minerals and UV scattering agents, And pigments. The oil-in-water cosmetic of the present invention can be produced by treating these components according to a conventional method.
本発明の水中油型化粧料は、上記のとおり、チキソトロピー性を有する天然高分子を用いて粘度を高めることで水相と油性成分の分離を抑え、保存安定性を高めていることから、噴霧用に好適に用いることができる。噴霧器としては、水中油型化粧料を噴霧できれば特に制限は無く、市販されている噴霧器に本発明の水中油型化粧料を入れて噴霧すればよい。 The oil-in-water cosmetic of the present invention, as described above, suppresses the separation of the aqueous phase and the oily component by increasing the viscosity using a natural polymer having thixotropy, and improves storage stability. Can be suitably used. The sprayer is not particularly limited as long as the oil-in-water cosmetic can be sprayed, and the oil-in-water cosmetic of the present invention may be sprayed into a commercially available sprayer.
以下に実施例を掲げ、本発明を具体的に説明するが、この実施例は単に本発明の説明のため、その具体的な態様の参考のために提供されているものである。これらの例示は本発明の特定の具体的な態様を説明するためのものであるが、本願で開示する発明の範囲を限定したり、あるいは制限することを表すものではない。なお、配合量は全て、水中油型化粧料全量に対する質量％で表す。 The present invention will be described in detail with reference to the following examples, which are provided merely for the purpose of illustrating the present invention and for reference to specific embodiments thereof. These exemplifications are for explaining specific specific embodiments of the present invention, but are not intended to limit or limit the scope of the invention disclosed in the present application. In addition, all compounding quantities are represented by the mass% with respect to the oil-in-water type cosmetics whole quantity.
＜実施例１〜１５＞
（水中油型化粧料の作製）
表１及び表２に示す原料を用いて、以下の手順で水中油型化粧料を作製した。先ず、（１）精製水及び（Ａ）成分である水膨潤性粘土鉱物を室温にて分散した。また、（２）精製水及び（Ｂ）成分である天然高分子を７０℃に加温しディスパーにて分散・混合した。次に、前記（１）及び（２）と、保湿剤、緩衝剤、防腐剤と精製水の攪拌溶液を混合し、３０℃まで冷却し、最後に（Ｃ）成分である油性成分及び（Ｄ）成分である界面活性剤を適宜加熱溶解分散したものを添加し、ホモミキサーで３０００ｒｐｍ、５分間攪拌し室温まで冷却することで水中油型化粧料を作製した。
<Examples 1-15>
(Production of oil-in-water cosmetics)
Using the raw materials shown in Table 1 and Table 2, oil-in-water cosmetics were prepared by the following procedure. First, (1) purified water and the water-swellable clay mineral (A) component were dispersed at room temperature. Further, (2) purified water and the natural polymer (B) were heated to 70 ° C. and dispersed and mixed with a disper. Next, the (1) and (2), a moisturizer, a buffer, a preservative and a stirred solution of purified water are mixed, cooled to 30 ° C., and finally the oil component (C) and (D ) A component obtained by appropriately dissolving and dispersing a surfactant was added, stirred at 3000 rpm for 5 minutes with a homomixer, and cooled to room temperature to prepare an oil-in-water cosmetic.
（作製した水中油型化粧料の評価）
作製した水中油型化粧料を、手動ポンプ式の噴霧器（(株)三谷バルブ製：ファインミスト品番Ｚ−１５５−４５）に入れ、噴霧時の広がり、保存安定性、使用性（べたつき、ぬるつき）の各項目について、以下に示す評価方法及び判断基準により評価した。
(Evaluation of the produced oil-in-water cosmetics)
Put the prepared oil-in-water cosmetic into a manual pump type sprayer (Mitani Valve Co., Ltd .: Fine Mist product number Z-155-45), spread during spraying, storage stability, usability (stickiness, sliminess) ) Was evaluated according to the following evaluation methods and criteria.
［噴霧時の広がり］
≪評価方法≫
噴霧時の広がりは、実使用実験を実施し、作製した各試料を噴霧した時の状態を目視にて観察し、以下の基準に従い評価した。
≪基準≫
◎：噴霧状態が正常であり、噴霧の広がりが良好であること
○：噴霧状態が正常であり、噴霧の広がりがやや弱いこと
△：噴霧状態が正常であり、噴霧の広がりが弱いこと
×：噴霧状態が不良であり、噴霧の広がりがないこと
[Spread when spraying]
≪Evaluation method≫
The spread at the time of spraying was evaluated according to the following criteria by conducting an actual use experiment, visually observing the state when each of the prepared samples was sprayed.
<< Standard >>
A: The spray state is normal and the spray spread is good. ○: The spray state is normal and the spray spread is slightly weak. Δ: The spray state is normal and the spray spread is weak. The spray condition is poor and there is no spread of spray.
［保存安定性の評価］
≪評価方法≫
保存安定性は、作製した各試料をねじ口瓶に入れ、４０℃で１ヵ月保存後に状態を目視により観察し、以下の基準に従い評価した。
≪基準≫
◎：外観、粘度ともに調整直後と変化がなく安定であること
○：外観、粘度のいずれかに変化があるものの、水または油の分離を生じず安定であること
△：外観、粘度のいずれかに変化があり、水または油の分離をわずかに生じていること
×：外観、粘度において、明らかな沈澱、または分離しており、不安定であること
[Evaluation of storage stability]
≪Evaluation method≫
The storage stability was evaluated according to the following criteria by placing each of the prepared samples in a screw-cap bottle and visually observing the state after storage at 40 ° C. for 1 month.
<< Standard >>
◎: Appearance and viscosity are stable with no change immediately after adjustment ○: Appearance or viscosity is stable but water or oil is not separated, but stable △: Appearance or viscosity There is a change in water and oil or oil is slightly separated. X: Appearance of precipitation, separation in appearance and viscosity, or instability
［使用性（べたつき・ぬるつき）の評価］
≪評価方法≫
使用性（べたつき・ぬるつき）の評価は、実使用実験を実施し、作製した各試料を肌に塗布した時のべたつき・ぬるつきについて、以下の基準に従い評価した。
≪基準≫
◎：べたつきやぬるつきがなく、良好であること
○：わずかにべたつきやぬるつきがあるが、やや良好であること
△：ややべたつきまたはぬるつきがあり、やや不良であること
×：べたつきまたはぬるつきがあり、不良であること
[Evaluation of usability (stickiness / sliminess)]
≪Evaluation method≫
Evaluation of usability (stickiness / stickiness) was conducted according to the following criteria for stickiness / stickiness when each sample prepared was applied to the skin after an actual use experiment.
<< Standard >>
◎: Good without sticky or sticky ○: Slightly sticky or slimy, but slightly good △: Slightly sticky or slimy, slightly poor There is a date, it is bad
表１は実施例１〜８、表２は実施例９〜１５の水中油型化粧料の配合原料の組成及び作製した水中油型化粧料の評価結果を示す。 Table 1 shows compositions of raw materials for oil-in-water cosmetics of Examples 9 to 15 and evaluation results of the produced oil-in-water cosmetics.
表１及び表２から明らかなように、（Ａ）水膨潤性粘土鉱物、（Ｂ）天然高分子、（Ｃ）油性成分、（Ｄ）界面活性剤、を適当な比率で混合することで、離水のない保存安定性に優れ、また、使用感に優れたゲル状の水中油型化粧料を調整できることが分かった。更に、実施例１〜１５の水中油型化粧料は、ゲル状にすることで保存安定性を図っているが、噴霧器で実際に噴霧した際の広がりに優れ、長期間使用した際にも吐出口の目詰まりがなく、良好な噴霧特性を維持し続けけることができた。また、（Ｅ）金属塩を配合することで、（Ｂ）天然高分子の配合を少なくしても、保存安定性及び噴霧特性を維持できることが分かった。 As is clear from Tables 1 and 2, by mixing (A) water-swellable clay mineral, (B) natural polymer, (C) oil component, and (D) surfactant in an appropriate ratio, It was found that a gel-like oil-in-water cosmetic having excellent storage stability without water separation and excellent usability can be prepared. Furthermore, the oil-in-water cosmetics of Examples 1 to 15 are intended for storage stability by being gelled, but they are excellent in spreading when actually sprayed with a sprayer, and even when used for a long time. There was no clogging of the outlet, and good spray characteristics could be maintained. In addition, it was found that storage stability and spray characteristics can be maintained by blending (E) a metal salt even if the blend of (B) natural polymer is reduced.
＜比較例１〜６＞
（Ａ）水膨潤性粘土鉱物を配合しなかった以外は、表３に示す原料を用いて、上記実施例１〜１５と同様の手順で水中油型化粧料を作製し、作製した水中油型化粧料の評価を行った。
<Comparative Examples 1-6>
(A) Except that the water-swellable clay mineral was not blended, an oil-in-water cosmetic was prepared using the raw materials shown in Table 3 in the same procedure as in Examples 1 to 15 above, and the oil-in-water type produced. The cosmetics were evaluated.
表３は比較例１〜６の水中油型化粧料の配合原料の組成及び作製した水中油型化粧料の評価を示す。 Table 3 shows the composition of the blended raw materials of the oil-in-water cosmetics of Comparative Examples 1 to 6 and the evaluation of the produced oil-in-water cosmetics.
表３から明らかなように、（Ａ）水膨潤性粘土鉱物を未配合の比較例１〜６では、乳化直後から（Ｃ）油性成分の解離が確認され、保存安定性に劣ることが分かった。そのため、作製した水中油型化粧料中で濃度勾配が生じてしまい、均一な組成で噴霧することができず、噴霧用水中油型化粧料の特性を十分に発揮できないことが分かった。 As is clear from Table 3, in Comparative Examples 1 to 6 where (A) the water-swellable clay mineral was not blended, the dissociation of the (C) oil component was confirmed immediately after emulsification, and it was found that the storage stability was poor. . Therefore, it has been found that a concentration gradient occurs in the produced oil-in-water cosmetic, and it cannot be sprayed with a uniform composition, and the characteristics of the oil-in-water cosmetic for spraying cannot be fully exhibited.
＜比較例７〜１０＞
（Ｂ）天然高分子を配合しなかった以外は、表４に示す原料を用いて、上記実施例１〜１５と同様の手順で水中油型化粧料を作製し、作製した水中油型化粧料の評価を行った。
<Comparative Examples 7 to 10>
(B) An oil-in-water cosmetic was prepared using the raw materials shown in Table 4 in the same manner as in Examples 1 to 15 except that no natural polymer was blended. Was evaluated.
表４は比較例７〜１０の水中油型化粧料の配合原料の組成及び作製した水中油型化粧料の評価を示す。 Table 4 shows the composition of the raw materials for oil-in-water cosmetics of Comparative Examples 7 to 10 and the evaluation of the produced oil-in-water cosmetics.
表４から明らかなように、（Ｂ）天然高分子を未配合の比較例７〜１０では、一時的な乳化はできるものの、（Ａ）水膨潤性粘土鉱物を配合した際にみられる離水が生じ、保存安定性に劣ることが分かった。そのため、作製した水中油型化粧料中で濃度勾配が生じてしまい、均一な組成で噴霧することができず、噴霧用水中油型化粧料の特性を十分に発揮できないことが分かった。 As is clear from Table 4, in Comparative Examples 7 to 10 in which (B) the natural polymer was not blended, although temporary emulsification was possible, (A) the water separation observed when blending the water-swellable clay mineral was observed. It was found that the storage stability was poor. Therefore, it has been found that a concentration gradient occurs in the produced oil-in-water cosmetic, and it cannot be sprayed with a uniform composition, and the characteristics of the oil-in-water cosmetic for spraying cannot be fully exhibited.
＜比較例１１及び１２＞
（Ｃ）油性成分を配合しなかった以外は、表５に示す原料を用いて、上記実施例１〜１５と同様の手順で水中油型化粧料を作製し、作製した水中油型化粧料の評価を行った。
<Comparative Examples 11 and 12>
(C) An oil-in-water cosmetic was prepared in the same procedure as in Examples 1 to 15 above using the raw materials shown in Table 5 except that no oil component was blended. Evaluation was performed.
＜比較例１３〜１５＞
（Ｄ）界面活性剤を配合しなかった以外は、表５に示す原料を用いて、上記実施例１〜１５と同様の手順で水中油型化粧料を作製し、作製した水中油型化粧料の評価を行った。
<Comparative Examples 13-15>
(D) An oil-in-water cosmetic was prepared using the raw materials shown in Table 5 except that the surfactant was not blended in the same procedure as in Examples 1 to 15 above. Was evaluated.
表５は比較例１１〜１５の水中油型化粧料の配合原料の組成及び作製した水中油型化粧料の評価を示す。 Table 5 shows the composition of the raw materials for oil-in-water cosmetics of Comparative Examples 11 to 15 and the evaluation of the produced oil-in-water cosmetics.
表５から明らかなように、（Ｃ）油性成分を未配合の比較例１１及び１２では、保存安定性のある水中油型化粧料は作製できるものの、べたつき・ぬるつきを生じてしまい、使用性に問題があることが分かった。 As is apparent from Table 5, in Comparative Examples 11 and 12 in which the oil component was not blended (C), a storage-stable oil-in-water cosmetic could be produced, but stickiness and sliminess were produced, and the usability It turns out that there is a problem.
また、（Ｄ）界面活性剤を未配合の比較例１３〜１５では、一時的な乳化はできるものの、経時の保存安定性の評価では油性成分の解離が確認され、保存安定性に劣ることが分かった。そのため、作製した水中油型化粧料中で濃度勾配が生じてしまい、均一な組成で噴霧することができず、噴霧用水中油型化粧料の特性を十分に発揮できないことが分かった。 Further, in Comparative Examples 13 to 15 in which (D) the surfactant is not blended, although temporary emulsification is possible, dissociation of the oil component is confirmed in the evaluation of storage stability over time, and storage stability may be inferior. I understood. Therefore, it has been found that a concentration gradient occurs in the produced oil-in-water cosmetic, and it cannot be sprayed with a uniform composition, and the characteristics of the oil-in-water cosmetic for spraying cannot be fully exhibited.
本発明の水中油型化粧料は、噴霧時の広がりに優れ、長期使用でも吐出口の目詰まりがなく、噴霧を維持し続けることができる。さらに、油性成分を配合しても保存安定性に優れていることから、エモリエント効果、賦香効果、昆虫忌避効、紫外線吸収剤を用いた紫外線防御効果を付与させることができる。したがって、本発明の水中油型化粧料は、フェイス用、ボディ用などの、噴霧用水中油型化粧料として有用である。 The oil-in-water cosmetic of the present invention is excellent in spreading at the time of spraying, there is no clogging of the discharge port even after long-term use, and it is possible to continue to spray. Furthermore, even if an oil component is blended, it is excellent in storage stability, so that an emollient effect, a fragrance effect, an insect repellent effect, and an ultraviolet protection effect using an ultraviolet absorber can be imparted. Therefore, the oil-in-water cosmetic of the present invention is useful as an oil-in-water cosmetic for spraying, such as for face and body.
Claims (9)
（Ａ）水膨潤性粘土鉱物 ０．１〜５質量％
（Ｂ）天然高分子 ０．０１〜３質量％
（Ｃ）油性成分 ０．１〜２０質量％
（Ｄ）界面活性剤 ０．０１〜５質量％
を含むことを特徴とする水中油型化粧料。 For the total amount of oil-in-water cosmetics,
(A) Water-swellable clay mineral 0.1 to 5% by mass
(B) Natural polymer 0.01-3 mass%
(C) Oil component 0.1-20 mass%
(D) Surfactant 0.01-5% by mass
Oil-in-water cosmetics characterized by containing.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017048143A (en) * | 2015-09-02 | 2017-03-09 | 株式会社 わかさ生活 | Oil-in-water type emulsion composition blended with essential oil, and method of producing the same |
| CN110522680A (en) * | 2019-07-18 | 2019-12-03 | 广州雅心化妆品有限公司 | A kind of skin care item carrier and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57171907A (en) * | 1981-04-15 | 1982-10-22 | Kanebo Ltd | Alcohol-containing emulsified cosmetic for make-up |
| JPH11130652A (en) * | 1997-10-24 | 1999-05-18 | Lion Corp | Skin cosmetic |
| JP2003137729A (en) * | 2001-10-29 | 2003-05-14 | Pola Chem Ind Inc | Gel-like mist composition |
| JP2006206448A (en) * | 2005-01-25 | 2006-08-10 | Nof Corp | Pack cosmetic |
| JP2008266252A (en) * | 2007-04-24 | 2008-11-06 | Mandom Corp | Milky lotion of skin cosmetic |
| JP2010043072A (en) * | 2008-07-18 | 2010-02-25 | Ken Products Kk | Cosmetic composition for spray, and makeup method for amending facial expression to youthful physical figure |
| WO2011039790A1 (en) * | 2009-09-29 | 2011-04-07 | 株式会社資生堂 | Oil-in-water-type emulsion composition |
-
2014
- 2014-03-05 JP JP2014042727A patent/JP6345950B2/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57171907A (en) * | 1981-04-15 | 1982-10-22 | Kanebo Ltd | Alcohol-containing emulsified cosmetic for make-up |
| JPH11130652A (en) * | 1997-10-24 | 1999-05-18 | Lion Corp | Skin cosmetic |
| JP2003137729A (en) * | 2001-10-29 | 2003-05-14 | Pola Chem Ind Inc | Gel-like mist composition |
| JP2006206448A (en) * | 2005-01-25 | 2006-08-10 | Nof Corp | Pack cosmetic |
| JP2008266252A (en) * | 2007-04-24 | 2008-11-06 | Mandom Corp | Milky lotion of skin cosmetic |
| JP2010043072A (en) * | 2008-07-18 | 2010-02-25 | Ken Products Kk | Cosmetic composition for spray, and makeup method for amending facial expression to youthful physical figure |
| WO2011039790A1 (en) * | 2009-09-29 | 2011-04-07 | 株式会社資生堂 | Oil-in-water-type emulsion composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017048143A (en) * | 2015-09-02 | 2017-03-09 | 株式会社 わかさ生活 | Oil-in-water type emulsion composition blended with essential oil, and method of producing the same |
| CN110522680A (en) * | 2019-07-18 | 2019-12-03 | 广州雅心化妆品有限公司 | A kind of skin care item carrier and preparation method thereof |
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