JP2015011131A5 - - Google Patents
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- Publication number
- JP2015011131A5 JP2015011131A5 JP2013135594A JP2013135594A JP2015011131A5 JP 2015011131 A5 JP2015011131 A5 JP 2015011131A5 JP 2013135594 A JP2013135594 A JP 2013135594A JP 2013135594 A JP2013135594 A JP 2013135594A JP 2015011131 A5 JP2015011131 A5 JP 2015011131A5
- Authority
- JP
- Japan
- Prior art keywords
- particles
- process cartridge
- toner
- less
- fine particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 14
- 239000002245 particle Substances 0.000 claims 12
- 239000010419 fine particle Substances 0.000 claims 10
- 238000000034 method Methods 0.000 claims 10
- 239000011347 resin Substances 0.000 claims 8
- 229920005989 resin Polymers 0.000 claims 8
- 239000000377 silicon dioxide Substances 0.000 claims 7
- 239000002344 surface layer Substances 0.000 claims 4
- VEALVRVVWBQVSL-UHFFFAOYSA-N Strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 claims 3
- 239000000654 additive Substances 0.000 claims 3
- 230000000996 additive Effects 0.000 claims 3
- 239000011230 binding agent Substances 0.000 claims 3
- 239000000969 carrier Substances 0.000 claims 3
- 238000009792 diffusion process Methods 0.000 claims 3
- 229920002545 silicone oil Polymers 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 239000000758 substrate Substances 0.000 claims 2
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 239000011148 porous material Substances 0.000 claims 1
- 239000011164 primary particle Substances 0.000 claims 1
- 238000007788 roughening Methods 0.000 claims 1
Claims (8)
該プロセスカートリッジは、
静電潜像担持体と、
該静電潜像担持体を帯電するための帯電部材と、
トナーを用いて該静電潜像担持体の表面に形成された静電潜像を現像する現像手段と、
を有し、
該帯電部材は、導電性基体と導電性の表面層を有する帯電部材であって、
該帯電部材の該表面層は、
結着樹脂Cと、
該結着樹脂Cに分散されている導電性粒子と、
該表面層を粗面化させている樹脂粒子と、
を含み、
該帯電部材の該表面層は、その表面に、該樹脂粒子に由来する複数の凸部を有し、
該凸部を形成している該樹脂粒子は、その内部に空孔を有し、
該樹脂粒子全体の空孔率Vtが、2.5体積%以下であり、
該樹脂粒子が空孔を有さない中実粒子であると仮定したときの該中実粒子内の11体積%を占める領域であって該導電性基体からの距離が最も離れた領域における空孔率V11が、5体積%以上20体積%以下であり、
該トナーは、結着樹脂Tおよび着色剤を含有するトナー粒子、ならびに、外添剤としてシリカ微粒子を含有するトナーであり、
X線光電子分光装置(ESCA)により求めた、該トナー表面の該シリカ微粒子による被覆率X1が40.0面積%以上75.0面積%以下であり、
該シリカ微粒子による理論被覆率をX2としたとき、下記式1で示される拡散指数が下記式2を満足する
(式1)拡散指数=X1/X2
(式2)拡散指数≧−0.0042×X1+0.62
ことを特徴とするプロセスカートリッジ。 In a process cartridge detachable from the main body of the image forming apparatus,
The process cartridge is
An electrostatic latent image carrier;
A charging member for charging the electrostatic latent image carrier;
Developing means for developing the electrostatic latent image formed on the surface of the electrostatic latent image carrier using toner;
Have
The charging member is a charging member having a conductive substrate and a conductive surface layer,
The surface layer of the charging member is
Binder resin C;
Conductive particles dispersed in the binder resin C;
Resin particles roughening the surface layer;
Including
The surface layer of the charging member has a plurality of convex portions derived from the resin particles on the surface,
The resin particles forming the convex portion have pores inside thereof,
The porosity Vt of the entire resin particle is 2.5% by volume or less,
Assuming that the resin particles are solid particles having no voids, the voids in a region that occupies 11% by volume in the solid particles and that is farthest from the conductive substrate the rate V 11 is, is 20 vol% 5 vol% or more,
The toner is a toner particle containing a binder resin T and a colorant, and a toner containing silica fine particles as an external additive,
The coverage X1 with the silica fine particles on the toner surface determined by an X-ray photoelectron spectrometer (ESCA) is 40.0 area% or more and 75.0 area% or less,
When the theoretical coverage by the silica fine particles is X2, the diffusion index represented by the following formula 1 satisfies the following formula 2. (Formula 1) Diffusion index = X1 / X2
(Expression 2) Diffusion index ≧ −0.0042 × X1 + 0.62
A process cartridge characterized by that.
該チタン酸ストロンチウム微粒子の一次粒子の個数平均粒径(D1)が、60nm以上200nm以下である請求項1または2に記載のプロセスカートリッジ。 The toner further contains strontium titanate fine particles as an external additive,
The process cartridge according to claim 1 or 2, wherein the number average particle diameter (D1) of primary particles of the strontium titanate fine particles is 60 nm or more and 200 nm or less.
該シリコーンオイルの炭素量基準の固定化率(%)が、70%以上である請求項1〜5のいずれか1項に記載のプロセスカートリッジ。 The silica fine particles are treated with 15.0 parts by mass or more and 40.0 parts by mass or less of silicone oil based on 100 parts by mass of the silica fine particle base.
The process cartridge according to any one of claims 1 to 5, wherein an immobilization rate (%) based on carbon amount of the silicone oil is 70% or more.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013135594A JP6120698B2 (en) | 2013-06-27 | 2013-06-27 | Process cartridge |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013135594A JP6120698B2 (en) | 2013-06-27 | 2013-06-27 | Process cartridge |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2015011131A JP2015011131A (en) | 2015-01-19 |
JP2015011131A5 true JP2015011131A5 (en) | 2016-08-12 |
JP6120698B2 JP6120698B2 (en) | 2017-04-26 |
Family
ID=52304357
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013135594A Active JP6120698B2 (en) | 2013-06-27 | 2013-06-27 | Process cartridge |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP6120698B2 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9529284B2 (en) * | 2014-11-28 | 2016-12-27 | Canon Kabushiki Kaisha | Process cartridge, image forming method, and electrophotographic apparatus |
JP5989201B2 (en) * | 2015-01-23 | 2016-09-07 | 株式会社トクヤマ | Silicone oil-treated silica particles and electrophotographic toner |
WO2016117344A1 (en) * | 2015-01-23 | 2016-07-28 | 株式会社トクヤマ | Silicone oil-treated silica particles and toner for electrophotography |
JP6407086B2 (en) * | 2015-03-31 | 2018-10-17 | キヤノン株式会社 | Image forming method |
JP6714348B2 (en) * | 2015-11-24 | 2020-06-24 | キヤノン株式会社 | Image forming method |
JP6732486B2 (en) * | 2016-03-11 | 2020-07-29 | キヤノン株式会社 | Process cartridge |
US10303075B2 (en) | 2017-02-28 | 2019-05-28 | Canon Kabushiki Kaisha | Toner |
WO2019027039A1 (en) * | 2017-08-04 | 2019-02-07 | キヤノン株式会社 | Toner |
JP6987655B2 (en) * | 2018-01-29 | 2022-01-05 | キヤノン株式会社 | toner |
JP7140604B2 (en) * | 2018-08-28 | 2022-09-21 | キヤノン株式会社 | image forming device |
JP7374654B2 (en) * | 2018-08-28 | 2023-11-07 | キヤノン株式会社 | Image forming device |
JP7374653B2 (en) * | 2018-08-28 | 2023-11-07 | キヤノン株式会社 | Image forming device |
JP7338396B2 (en) * | 2019-10-18 | 2023-09-05 | 株式会社リコー | Toner, Toner Manufacturing Method, Developer, Toner Storage Unit, Image Forming Apparatus and Image Forming Method |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3332727B2 (en) * | 1996-05-28 | 2002-10-07 | キヤノン株式会社 | Image forming method and toner |
JP2003167375A (en) * | 2001-11-30 | 2003-06-13 | Kyocera Mita Corp | Toner for two-component developer |
JP2005300667A (en) * | 2004-04-07 | 2005-10-27 | Canon Inc | Charging member and its manufacture method |
JP2007334119A (en) * | 2006-06-16 | 2007-12-27 | Canon Inc | Image forming apparatus |
JP2009288536A (en) * | 2008-05-29 | 2009-12-10 | Ricoh Co Ltd | Image forming apparatus |
JP2010181819A (en) * | 2009-02-09 | 2010-08-19 | Fuji Xerox Co Ltd | Charging member, charging apparatus, process cartridge and image forming apparatus |
JP2011017981A (en) * | 2009-07-10 | 2011-01-27 | Canon Inc | Image forming method |
JP5748528B2 (en) * | 2011-04-01 | 2015-07-15 | キヤノン株式会社 | Magnetic toner |
JP5911235B2 (en) * | 2011-08-29 | 2016-04-27 | キヤノン株式会社 | toner |
-
2013
- 2013-06-27 JP JP2013135594A patent/JP6120698B2/en active Active
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