JP2015011131A5 - - Google Patents

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Publication number
JP2015011131A5
JP2015011131A5 JP2013135594A JP2013135594A JP2015011131A5 JP 2015011131 A5 JP2015011131 A5 JP 2015011131A5 JP 2013135594 A JP2013135594 A JP 2013135594A JP 2013135594 A JP2013135594 A JP 2013135594A JP 2015011131 A5 JP2015011131 A5 JP 2015011131A5
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JP
Japan
Prior art keywords
particles
process cartridge
toner
less
fine particles
Prior art date
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Application number
JP2013135594A
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Japanese (ja)
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JP2015011131A (en
JP6120698B2 (en
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Publication date
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Priority to JP2013135594A priority Critical patent/JP6120698B2/en
Priority claimed from JP2013135594A external-priority patent/JP6120698B2/en
Publication of JP2015011131A publication Critical patent/JP2015011131A/en
Publication of JP2015011131A5 publication Critical patent/JP2015011131A5/ja
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Publication of JP6120698B2 publication Critical patent/JP6120698B2/en
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Claims (8)

画像形成装置の本体に着脱可能なプロセスカートリッジにおいて、
該プロセスカートリッジは、
静電潜像担持体と、
該静電潜像担持体を帯電するための帯電部材と、
トナーを用いて該静電潜像担持体の表面に形成された静電潜像を現像する現像手段と、
を有し、
該帯電部材は、導電性基体と導電性の表面層を有する帯電部材であって、
該帯電部材の該表面層は、
結着樹脂Cと、
該結着樹脂Cに分散されている導電性粒子と、
該表面層を粗面化させている樹脂粒子と、
を含み、
該帯電部材の該表面層は、その表面に、該樹脂粒子に由来する複数の凸部を有し、
該凸部を形成している該樹脂粒子は、その内部に空孔を有し、
該樹脂粒子全体の空孔率Vtが、2.5体積%以下であり、
該樹脂粒子が空孔を有さない中実粒子であると仮定したときの該中実粒子内の11体積%を占める領域であって該導電性基体からの距離が最も離れた領域における空孔率V11が、5体積%以上20体積%以下であり、
該トナーは、結着樹脂Tおよび着色剤を含有するトナー粒子、ならびに、外添剤としてシリカ微粒子を含有するトナーであり、
X線光電子分光装置(ESCA)により求めた、該トナー表面の該シリカ微粒子による被覆率X1が40.0面積%以上75.0面積%以下であり、
該シリカ微粒子による理論被覆率をX2としたとき、下記式1で示される拡散指数が下記式2を満足する
(式1)拡散指数=X1/X2
(式2)拡散指数≧−0.0042×X1+0.62
ことを特徴とするプロセスカートリッジ。
In a process cartridge detachable from the main body of the image forming apparatus,
The process cartridge is
An electrostatic latent image carrier;
A charging member for charging the electrostatic latent image carrier;
Developing means for developing the electrostatic latent image formed on the surface of the electrostatic latent image carrier using toner;
Have
The charging member is a charging member having a conductive substrate and a conductive surface layer,
The surface layer of the charging member is
Binder resin C;
Conductive particles dispersed in the binder resin C;
Resin particles roughening the surface layer;
Including
The surface layer of the charging member has a plurality of convex portions derived from the resin particles on the surface,
The resin particles forming the convex portion have pores inside thereof,
The porosity Vt of the entire resin particle is 2.5% by volume or less,
Assuming that the resin particles are solid particles having no voids, the voids in a region that occupies 11% by volume in the solid particles and that is farthest from the conductive substrate the rate V 11 is, is 20 vol% 5 vol% or more,
The toner is a toner particle containing a binder resin T and a colorant, and a toner containing silica fine particles as an external additive,
The coverage X1 with the silica fine particles on the toner surface determined by an X-ray photoelectron spectrometer (ESCA) is 40.0 area% or more and 75.0 area% or less,
When the theoretical coverage by the silica fine particles is X2, the diffusion index represented by the following formula 1 satisfies the following formula 2. (Formula 1) Diffusion index = X1 / X2
(Expression 2) Diffusion index ≧ −0.0042 × X1 + 0.62
A process cartridge characterized by that.
前記トナー粒子の平均円形度が0.960以上である請求項1に記載のプロセスカートリッジ。   The process cartridge according to claim 1, wherein the toner particles have an average circularity of 0.960 or more. 前記トナーが、外添剤としてさらにチタン酸ストロンチウム微粒子を含有し、
該チタン酸ストロンチウム微粒子の一次粒子の個数平均粒径(D1)が、60nm以上200nm以下である請求項1または2に記載のプロセスカートリッジ。
The toner further contains strontium titanate fine particles as an external additive,
The process cartridge according to claim 1 or 2, wherein the number average particle diameter (D1) of primary particles of the strontium titanate fine particles is 60 nm or more and 200 nm or less.
前記トナー粒子への前記外添剤の埋め込み率が、25%以上60%以下である請求項1〜3のいずれか1項に記載のプロセスカートリッジ。   4. The process cartridge according to claim 1, wherein an embedding rate of the external additive in the toner particles is 25% or more and 60% or less. 前記チタン酸ストロンチウム微粒子の遊離率が、20%以上70%以下である請求項1〜4のいずれか1項に記載のプロセスカートリッジ。   The process cartridge according to any one of claims 1 to 4, wherein a release rate of the strontium titanate fine particles is 20% or more and 70% or less. 前記シリカ微粒子は、シリカ微粒子原体100質量部に対して15.0質量部以上40.0質量部以下のシリコーンオイルによって処理されており、
該シリコーンオイルの炭素量基準の固定化率(%)が、70%以上である請求項1〜5のいずれか1項に記載のプロセスカートリッジ。
The silica fine particles are treated with 15.0 parts by mass or more and 40.0 parts by mass or less of silicone oil based on 100 parts by mass of the silica fine particle base.
The process cartridge according to any one of claims 1 to 5, wherein an immobilization rate (%) based on carbon amount of the silicone oil is 70% or more.
前記シリカ微粒子の見掛け密度が、15g/L以上50g/L以下である請求項1〜6のいずれか1項に記載のプロセスカートリッジ。   The process cartridge according to claim 1, wherein an apparent density of the silica fine particles is 15 g / L or more and 50 g / L or less. 前記シリカ微粒子原体の、BET比表面積が、130m/g以上330m/g以下である請求項1〜7のいずれか1項に記載のプロセスカートリッジ。 The process cartridge according to claim 1, wherein the silica fine particle base has a BET specific surface area of 130 m 2 / g or more and 330 m 2 / g or less.
JP2013135594A 2013-06-27 2013-06-27 Process cartridge Active JP6120698B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2013135594A JP6120698B2 (en) 2013-06-27 2013-06-27 Process cartridge

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2013135594A JP6120698B2 (en) 2013-06-27 2013-06-27 Process cartridge

Publications (3)

Publication Number Publication Date
JP2015011131A JP2015011131A (en) 2015-01-19
JP2015011131A5 true JP2015011131A5 (en) 2016-08-12
JP6120698B2 JP6120698B2 (en) 2017-04-26

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Family Applications (1)

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Families Citing this family (13)

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Publication number Priority date Publication date Assignee Title
US9529284B2 (en) * 2014-11-28 2016-12-27 Canon Kabushiki Kaisha Process cartridge, image forming method, and electrophotographic apparatus
JP5989201B2 (en) * 2015-01-23 2016-09-07 株式会社トクヤマ Silicone oil-treated silica particles and electrophotographic toner
WO2016117344A1 (en) * 2015-01-23 2016-07-28 株式会社トクヤマ Silicone oil-treated silica particles and toner for electrophotography
JP6407086B2 (en) * 2015-03-31 2018-10-17 キヤノン株式会社 Image forming method
JP6714348B2 (en) * 2015-11-24 2020-06-24 キヤノン株式会社 Image forming method
JP6732486B2 (en) * 2016-03-11 2020-07-29 キヤノン株式会社 Process cartridge
US10303075B2 (en) 2017-02-28 2019-05-28 Canon Kabushiki Kaisha Toner
WO2019027039A1 (en) * 2017-08-04 2019-02-07 キヤノン株式会社 Toner
JP6987655B2 (en) * 2018-01-29 2022-01-05 キヤノン株式会社 toner
JP7140604B2 (en) * 2018-08-28 2022-09-21 キヤノン株式会社 image forming device
JP7374654B2 (en) * 2018-08-28 2023-11-07 キヤノン株式会社 Image forming device
JP7374653B2 (en) * 2018-08-28 2023-11-07 キヤノン株式会社 Image forming device
JP7338396B2 (en) * 2019-10-18 2023-09-05 株式会社リコー Toner, Toner Manufacturing Method, Developer, Toner Storage Unit, Image Forming Apparatus and Image Forming Method

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3332727B2 (en) * 1996-05-28 2002-10-07 キヤノン株式会社 Image forming method and toner
JP2003167375A (en) * 2001-11-30 2003-06-13 Kyocera Mita Corp Toner for two-component developer
JP2005300667A (en) * 2004-04-07 2005-10-27 Canon Inc Charging member and its manufacture method
JP2007334119A (en) * 2006-06-16 2007-12-27 Canon Inc Image forming apparatus
JP2009288536A (en) * 2008-05-29 2009-12-10 Ricoh Co Ltd Image forming apparatus
JP2010181819A (en) * 2009-02-09 2010-08-19 Fuji Xerox Co Ltd Charging member, charging apparatus, process cartridge and image forming apparatus
JP2011017981A (en) * 2009-07-10 2011-01-27 Canon Inc Image forming method
JP5748528B2 (en) * 2011-04-01 2015-07-15 キヤノン株式会社 Magnetic toner
JP5911235B2 (en) * 2011-08-29 2016-04-27 キヤノン株式会社 toner

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