JP2015125302A5 - - Google Patents

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Publication number
JP2015125302A5
JP2015125302A5 JP2013270112A JP2013270112A JP2015125302A5 JP 2015125302 A5 JP2015125302 A5 JP 2015125302A5 JP 2013270112 A JP2013270112 A JP 2013270112A JP 2013270112 A JP2013270112 A JP 2013270112A JP 2015125302 A5 JP2015125302 A5 JP 2015125302A5
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JP
Japan
Prior art keywords
fine particles
less
toner
titanium oxide
particles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2013270112A
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Japanese (ja)
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JP6272024B2 (en
JP2015125302A (en
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Publication date
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Priority to JP2013270112A priority Critical patent/JP6272024B2/en
Priority claimed from JP2013270112A external-priority patent/JP6272024B2/en
Publication of JP2015125302A publication Critical patent/JP2015125302A/en
Publication of JP2015125302A5 publication Critical patent/JP2015125302A5/ja
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Publication of JP6272024B2 publication Critical patent/JP6272024B2/en
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Claims (4)

結着樹脂及び着色剤を含有するトナー粒子と、
外添剤としての、酸化チタン微粒子及びシリカ微粒子と、
を有するトナーであって、
前記酸化チタン微粒子は、
長軸径が30nm以上500nm以下であり、
短軸径が10nm以上80nm以下であり、
長軸径/短軸径の比が2.0以上8.0以下である
ルチル型の酸化チタン微粒子であり、
前記酸化チタン微粒子の含有量が、前記トナー粒子100質量部当たり0.1質量部以上1.0質量部以下であり、
前記トナー中の、前記酸化チタン微粒子の含有量に対する前記シリカ微粒子の含有量の比が、0.4以上30.0以下であり、
X線光電子分光装置(ESCA)により求めた、前記トナー粒子の表面の前記シリカ微粒子による被覆率X1が、40.0面積%以上75.0面積%以下であり、
前記シリカ微粒子による理論被覆率をX2としたとき、下記式1で示される拡散指数が、下記式2を満たし、
前記トナー粒子への前記外添剤の埋め込み率が、25%以上60%以下である
ことを特徴とするトナー。
(式1)拡散指数=X1/X2
(式2)拡散指数≧−0.0042×X1+0.62
Toner particles containing a binder resin and a colorant;
Titanium oxide fine particles and silica fine particles as external additives,
A toner having
The titanium oxide fine particles are:
The major axis diameter is 30 nm or more and 500 nm or less,
The minor axis diameter is 10 nm or more and 80 nm or less,
Rutile-type titanium oxide fine particles having a major axis diameter / minor axis diameter ratio of 2.0 or more and 8.0 or less,
The titanium oxide fine particle content is 0.1 parts by mass or more and 1.0 part by mass or less per 100 parts by mass of the toner particles,
The ratio of the content of the silica fine particles to the content of the titanium oxide fine particles in the toner is 0.4 or more and 30.0 or less,
The coverage X1 with the silica fine particles on the surface of the toner particles determined by an X-ray photoelectron spectrometer (ESCA) is 40.0 area% or more and 75.0 area% or less,
When the theoretical coverage by the silica fine particles is X2, the diffusion index represented by the following formula 1 satisfies the following formula 2,
The toner according to claim 1, wherein an embedding rate of the external additive in the toner particles is 25% or more and 60% or less.
(Formula 1) Diffusion index = X1 / X2
(Expression 2) Diffusion index ≧ −0.0042 × X1 + 0.62
前記トナー粒子の平均円形度が、0.960以上である請求項1に記載のトナー。   The toner according to claim 1, wherein the toner particles have an average circularity of 0.960 or more. 前記酸化チタン微粒子の遊離率が、50%以下である請求項1又は2に記載のトナー。   The toner according to claim 1, wherein a liberation rate of the titanium oxide fine particles is 50% or less. 前記シリカ微粒子の見掛け密度が、15g/L以上50g/L以下である請求項1〜3のいずれか1項に記載のトナー。
The toner according to claim 1, wherein an apparent density of the silica fine particles is 15 g / L or more and 50 g / L or less.
JP2013270112A 2013-12-26 2013-12-26 toner Active JP6272024B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2013270112A JP6272024B2 (en) 2013-12-26 2013-12-26 toner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2013270112A JP6272024B2 (en) 2013-12-26 2013-12-26 toner

Publications (3)

Publication Number Publication Date
JP2015125302A JP2015125302A (en) 2015-07-06
JP2015125302A5 true JP2015125302A5 (en) 2017-02-09
JP6272024B2 JP6272024B2 (en) 2018-01-31

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ID=53536029

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2013270112A Active JP6272024B2 (en) 2013-12-26 2013-12-26 toner

Country Status (1)

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JP (1) JP6272024B2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9606462B2 (en) * 2014-08-07 2017-03-28 Canon Kabushiki Kaisha Toner and method for manufacturing toner
JP2017068006A (en) 2015-09-30 2017-04-06 コニカミノルタ株式会社 Toner for electrostatic charge image development and two-component developer for electrostatic charge image development
JP2017223945A (en) 2016-06-09 2017-12-21 キヤノン株式会社 toner
JP6862769B2 (en) * 2016-11-02 2021-04-21 コニカミノルタ株式会社 Toner for static charge image development
JP6834399B2 (en) * 2016-11-22 2021-02-24 コニカミノルタ株式会社 Manufacturing method of electrostatic latent image developer and electrostatic latent image developer
US10303075B2 (en) * 2017-02-28 2019-05-28 Canon Kabushiki Kaisha Toner
JP2018180146A (en) * 2017-04-07 2018-11-15 コニカミノルタ株式会社 Toner for electrostatic charge image development and method for manufacturing toner for electrostatic charge image development
JP6887868B2 (en) * 2017-05-15 2021-06-16 キヤノン株式会社 toner
DE112018003985T5 (en) * 2017-08-04 2020-04-16 Canon Kabushiki Kaisha TONER

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2633130B2 (en) * 1991-03-08 1997-07-23 キヤノン株式会社 Magnetic toner, image forming method, surface-modified silica fine powder and method for producing the same
JP4310146B2 (en) * 2003-08-06 2009-08-05 キヤノン株式会社 toner
JP5882728B2 (en) * 2011-12-27 2016-03-09 キヤノン株式会社 Magnetic toner

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