JP2015125302A5 - - Google Patents
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- Publication number
- JP2015125302A5 JP2015125302A5 JP2013270112A JP2013270112A JP2015125302A5 JP 2015125302 A5 JP2015125302 A5 JP 2015125302A5 JP 2013270112 A JP2013270112 A JP 2013270112A JP 2013270112 A JP2013270112 A JP 2013270112A JP 2015125302 A5 JP2015125302 A5 JP 2015125302A5
- Authority
- JP
- Japan
- Prior art keywords
- fine particles
- less
- toner
- titanium oxide
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000010419 fine particle Substances 0.000 claims 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 10
- OGIDPMRJRNCKJF-UHFFFAOYSA-N TiO Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims 6
- 229910001929 titanium oxide Inorganic materials 0.000 claims 6
- 239000002245 particle Substances 0.000 claims 5
- 239000000377 silicon dioxide Substances 0.000 claims 5
- 238000009792 diffusion process Methods 0.000 claims 3
- 239000000654 additive Substances 0.000 claims 2
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 claims 1
- 230000000996 additive Effects 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
Claims (4)
外添剤としての、酸化チタン微粒子及びシリカ微粒子と、
を有するトナーであって、
前記酸化チタン微粒子は、
長軸径が30nm以上500nm以下であり、
短軸径が10nm以上80nm以下であり、
長軸径/短軸径の比が2.0以上8.0以下である
ルチル型の酸化チタン微粒子であり、
前記酸化チタン微粒子の含有量が、前記トナー粒子100質量部当たり0.1質量部以上1.0質量部以下であり、
前記トナー中の、前記酸化チタン微粒子の含有量に対する前記シリカ微粒子の含有量の比が、0.4以上30.0以下であり、
X線光電子分光装置(ESCA)により求めた、前記トナー粒子の表面の前記シリカ微粒子による被覆率X1が、40.0面積%以上75.0面積%以下であり、
前記シリカ微粒子による理論被覆率をX2としたとき、下記式1で示される拡散指数が、下記式2を満たし、
前記トナー粒子への前記外添剤の埋め込み率が、25%以上60%以下である
ことを特徴とするトナー。
(式1)拡散指数=X1/X2
(式2)拡散指数≧−0.0042×X1+0.62 Toner particles containing a binder resin and a colorant;
Titanium oxide fine particles and silica fine particles as external additives,
A toner having
The titanium oxide fine particles are:
The major axis diameter is 30 nm or more and 500 nm or less,
The minor axis diameter is 10 nm or more and 80 nm or less,
Rutile-type titanium oxide fine particles having a major axis diameter / minor axis diameter ratio of 2.0 or more and 8.0 or less,
The titanium oxide fine particle content is 0.1 parts by mass or more and 1.0 part by mass or less per 100 parts by mass of the toner particles,
The ratio of the content of the silica fine particles to the content of the titanium oxide fine particles in the toner is 0.4 or more and 30.0 or less,
The coverage X1 with the silica fine particles on the surface of the toner particles determined by an X-ray photoelectron spectrometer (ESCA) is 40.0 area% or more and 75.0 area% or less,
When the theoretical coverage by the silica fine particles is X2, the diffusion index represented by the following formula 1 satisfies the following formula 2,
The toner according to claim 1, wherein an embedding rate of the external additive in the toner particles is 25% or more and 60% or less.
(Formula 1) Diffusion index = X1 / X2
(Expression 2) Diffusion index ≧ −0.0042 × X1 + 0.62
The toner according to claim 1, wherein an apparent density of the silica fine particles is 15 g / L or more and 50 g / L or less.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013270112A JP6272024B2 (en) | 2013-12-26 | 2013-12-26 | toner |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013270112A JP6272024B2 (en) | 2013-12-26 | 2013-12-26 | toner |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2015125302A JP2015125302A (en) | 2015-07-06 |
JP2015125302A5 true JP2015125302A5 (en) | 2017-02-09 |
JP6272024B2 JP6272024B2 (en) | 2018-01-31 |
Family
ID=53536029
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013270112A Active JP6272024B2 (en) | 2013-12-26 | 2013-12-26 | toner |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP6272024B2 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9606462B2 (en) * | 2014-08-07 | 2017-03-28 | Canon Kabushiki Kaisha | Toner and method for manufacturing toner |
JP2017068006A (en) | 2015-09-30 | 2017-04-06 | コニカミノルタ株式会社 | Toner for electrostatic charge image development and two-component developer for electrostatic charge image development |
JP2017223945A (en) | 2016-06-09 | 2017-12-21 | キヤノン株式会社 | toner |
JP6862769B2 (en) * | 2016-11-02 | 2021-04-21 | コニカミノルタ株式会社 | Toner for static charge image development |
JP6834399B2 (en) * | 2016-11-22 | 2021-02-24 | コニカミノルタ株式会社 | Manufacturing method of electrostatic latent image developer and electrostatic latent image developer |
US10303075B2 (en) * | 2017-02-28 | 2019-05-28 | Canon Kabushiki Kaisha | Toner |
JP2018180146A (en) * | 2017-04-07 | 2018-11-15 | コニカミノルタ株式会社 | Toner for electrostatic charge image development and method for manufacturing toner for electrostatic charge image development |
JP6887868B2 (en) * | 2017-05-15 | 2021-06-16 | キヤノン株式会社 | toner |
DE112018003985T5 (en) * | 2017-08-04 | 2020-04-16 | Canon Kabushiki Kaisha | TONER |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2633130B2 (en) * | 1991-03-08 | 1997-07-23 | キヤノン株式会社 | Magnetic toner, image forming method, surface-modified silica fine powder and method for producing the same |
JP4310146B2 (en) * | 2003-08-06 | 2009-08-05 | キヤノン株式会社 | toner |
JP5882728B2 (en) * | 2011-12-27 | 2016-03-09 | キヤノン株式会社 | Magnetic toner |
-
2013
- 2013-12-26 JP JP2013270112A patent/JP6272024B2/en active Active
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