JP2007279588A5 - - Google Patents

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JP2007279588A5
JP2007279588A5 JP2006108792A JP2006108792A JP2007279588A5 JP 2007279588 A5 JP2007279588 A5 JP 2007279588A5 JP 2006108792 A JP2006108792 A JP 2006108792A JP 2006108792 A JP2006108792 A JP 2006108792A JP 2007279588 A5 JP2007279588 A5 JP 2007279588A5
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Japan
Prior art keywords
carrier
developer
magnetic
replenishment
toner
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JP2006108792A
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Japanese (ja)
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JP2007279588A (en
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Priority to JP2006108792A priority Critical patent/JP2007279588A/en
Priority claimed from JP2006108792A external-priority patent/JP2007279588A/en
Publication of JP2007279588A publication Critical patent/JP2007279588A/en
Publication of JP2007279588A5 publication Critical patent/JP2007279588A5/ja
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Claims (8)

磁性キャリア100質量部に対して、トナーを200質量部以上5000質量部以下有している補給用現像剤であって、
該磁性キャリアは、磁性体を有するキャリアコアと該キャリアコアの表面に樹脂被覆層とを有する磁性キャリア粒子を有する磁性キャリアであって、
該トナーは、平均円形度が0.930以上1.000以下であり、
該磁性キャリアは、平均円形度が0.850以上0.950以下であり、かつ、水に対する接触角が95°以上であり、
該樹脂被覆層を形成している樹脂は、式(A1)
Figure 2007279588
(式中、Rは炭素数4以上の炭化水素基を示す)
で示される構造を有するモノマーとメタクリル酸メチルモノマーとを重合した共重合体であり、
該共重合体は、これらのモノマーから形成されるユニットが共重合割合として80質量%以上含有されており、かつ、65℃以上のガラス転移温度を有することを特徴とする補給用現像剤。
A replenishment developer having 200 to 5000 parts by mass of toner with respect to 100 parts by mass of a magnetic carrier,
The magnetic carrier is a magnetic carrier having a carrier core having a magnetic material and magnetic carrier particles having a resin coating layer on the surface of the carrier core,
The toner has an average circularity of 0.930 to 1.000,
The magnetic carrier has an average circularity of 0.850 or more and 0.950 or less, and a contact angle with water of 95 ° or more,
The resin forming the resin coating layer has the formula (A1)
Figure 2007279588
(Wherein R 1 represents a hydrocarbon group having 4 or more carbon atoms)
Is a copolymer obtained by polymerizing a monomer having a structure represented by
The replenishing developer, wherein the copolymer contains a unit formed from these monomers in a proportion of 80% by mass or more and has a glass transition temperature of 65 ° C. or more.
式(A1)中のRが、炭素数10以上であることを特徴とする請求項1に記載の補給用現像剤。 The replenishing developer according to claim 1, wherein R 1 in the formula (A1) has 10 or more carbon atoms. 該磁性キャリアは、水に対する接触角が100°以上であることを特徴とする請求項1又は2に記載の補給用現像剤。   The developer for replenishment according to claim 1, wherein the magnetic carrier has a contact angle with water of 100 ° or more. 該樹脂被覆層が、個数基準での粒度分布において、80nm以上600nm以下に最大ピーク粒径を有する微粒子を有し、
該被覆樹脂層を形成している樹脂が、キャリアコア100質量部に対して0.3質量部以上4.0質量部以下含有されており、
該磁性キャリアは、体積分布基準の50%粒径(D50)が15μm以上70μm以下であることを特徴とする請求項1乃至のいずれかに記載の補給用現像剤。
The resin coating layer has fine particles having a maximum peak particle diameter of 80 nm or more and 600 nm or less in a particle size distribution on the basis of number;
The resin forming the coating resin layer is contained in an amount of 0.3 to 4.0 parts by mass with respect to 100 parts by mass of the carrier core,
The replenishment developer according to any one of claims 1 to 3 , wherein the magnetic carrier has a 50% particle size (D50) based on a volume distribution of 15 µm or more and 70 µm or less.
該樹脂被覆層が、疎水性シリカ微粒子を有することを特徴とする請求項1乃至のいずれかに記載の補給用現像剤。 The resin coating layer, replenishing developer according to any one of claims 1 to 4, characterized in that it has a hydrophobic silica fine particles. 該キャリアコアが、キャリアコアの結着樹脂を形成するためのモノマーを磁性体存在下で重合して得られた磁性体分散型樹脂キャリアコアであることを特徴とする請求項1乃至のいずれかに記載の補給用現像剤。 The carrier core is one of the claims 1 to 5, characterized in that the monomers for forming the binder resin of the carrier core is a magnetic material-dispersed resin carrier cores obtained by polymerization in the presence of magnetic material A developer for replenishment according to any one of the above. 該補給用現像剤が、トナーと磁性キャリアを現像器に補給し、トナーと磁性キャリアとから現像剤担持体上に形成される磁気ブラシで静電荷像を現像してトナー画像形成し、且つ、現像器内部で過剰になった磁性キャリアを現像器から排出する画像形成方法に使用するための補給用現像剤であることを特徴とする請求項1乃至のいずれかに記載の補給用現像剤。 The replenishment developer replenishes toner and magnetic carrier to the developing device, develops an electrostatic image with a magnetic brush formed on the developer carrier from the toner and magnetic carrier, forms a toner image, and The replenishment developer according to any one of claims 1 to 6 , wherein the replenishment developer is used for an image forming method for discharging the excess magnetic carrier inside the development unit from the development unit. . 静電荷像担持体に静電荷像を形成し、磁界発生手段を内包する現像剤担持体上にトナーと磁性キャリアとから磁気ブラシを形成し、現像剤担持体上に形成された磁気ブラシで静電荷像を現像してトナー像を該静電荷像担持体上に形成する画像形成方法であって、
該磁気ブラシが、磁性キャリア100質量部に対して、トナーを5質量部以上20質量部以下有し、
補給用現像剤を現像器に補給し、現像器内部で過剰になった磁性キャリアを現像器から排出し、
該補給用現像剤が、請求項1乃至のいずれかに記載の補給用現像剤であることを特徴とする画像形成方法。
An electrostatic charge image is formed on the electrostatic charge image carrier, a magnetic brush is formed from toner and a magnetic carrier on the developer carrier that contains the magnetic field generating means, and the magnetic brush formed on the developer carrier is used for static electricity. An image forming method for developing a charge image to form a toner image on the electrostatic charge image carrier,
The magnetic brush has 5 to 20 parts by mass of toner with respect to 100 parts by mass of the magnetic carrier,
Replenish the developer for replenishment to the developer unit, discharge the excess magnetic carrier inside the developer unit from the developer unit,
Image forming method, wherein the replenishment developer is a replenishing developer according to any one of claims 1 to 6.
JP2006108792A 2006-04-11 2006-04-11 Developer for replenishment and image forming method Pending JP2007279588A (en)

Priority Applications (1)

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JP2006108792A JP2007279588A (en) 2006-04-11 2006-04-11 Developer for replenishment and image forming method

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Application Number Priority Date Filing Date Title
JP2006108792A JP2007279588A (en) 2006-04-11 2006-04-11 Developer for replenishment and image forming method

Publications (2)

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JP2007279588A JP2007279588A (en) 2007-10-25
JP2007279588A5 true JP2007279588A5 (en) 2008-04-17

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Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5106308B2 (en) * 2008-03-06 2012-12-26 キヤノン株式会社 Magnetic carrier and two-component developer
JP5517471B2 (en) 2008-03-11 2014-06-11 キヤノン株式会社 Two-component developer
JP5174568B2 (en) * 2008-07-17 2013-04-03 京セラドキュメントソリューションズ株式会社 Developing device and image forming apparatus including the same
JP2010276944A (en) * 2009-05-29 2010-12-09 Kyocera Mita Corp Image forming method
JP5517520B2 (en) * 2009-07-30 2014-06-11 キヤノン株式会社 Magnetic carrier, two-component developer and replenishment developer
JP5479193B2 (en) * 2010-04-09 2014-04-23 キヤノン株式会社 Magnetic carrier and two-component developer
JP5581918B2 (en) 2010-09-09 2014-09-03 富士ゼロックス株式会社 Electrostatic charge image developing carrier, electrostatic charge image developing developer, electrostatic charge image developing developer cartridge, process cartridge, image forming apparatus, and image forming method
JP5935424B2 (en) * 2012-03-19 2016-06-15 富士ゼロックス株式会社 Electrostatic charge image developing carrier, electrostatic charge image developing developer, toner cartridge, process cartridge, image forming apparatus, and image forming method
JP5689988B2 (en) * 2014-01-24 2015-03-25 Dowaエレクトロニクス株式会社 Carrier core material for electrophotographic developer and method for producing the same
JP6470588B2 (en) * 2014-02-27 2019-02-13 キヤノン株式会社 Magnetic carrier and two-component developer
JP6233230B2 (en) * 2014-07-30 2017-11-22 京セラドキュメントソリューションズ株式会社 Image forming apparatus
JP6222120B2 (en) * 2015-01-19 2017-11-01 コニカミノルタ株式会社 Two-component developer for developing electrostatic latent images
JP7106956B2 (en) * 2018-04-10 2022-07-27 富士フイルムビジネスイノベーション株式会社 Developer, developer manufacturing method, and image forming apparatus

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08248684A (en) * 1995-03-14 1996-09-27 Konica Corp Electrostatic image developing carrier and manufacture thereof
JP3697167B2 (en) * 2001-02-28 2005-09-21 キヤノン株式会社 Replenishment developer, developing method and image forming method
JP4136999B2 (en) * 2004-04-26 2008-08-20 キヤノン株式会社 Magnetic carrier and two-component developer

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