JP2015006979A - Mixture of natural humic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a block, a powder body or a grain body obtained by hydration-hardening a mixture of natural humic with iron (powder or grain) or an iron-containing mineral component with a curing agent and useful for the project of fisheries in such a manner that pest is suppressed in plant culture, and seawater-damage is suppressed by releasing ionized fulvic acid iron and mineral ions.SOLUTION: By using powder body or grain body obtained by hydration-hardening a mixture of natural humic and iron (powder or grain) or an iron-containing mineral component with a curing agent for a crop land, or submerged-installing a molded block or powder body to a water area, a land or a sea area releasing the fulvic acid iron and mineral ions for a long period and enough in various mineral ions can be made. Further, a powder body, a grain body or a block obtained by being added with seed, a fertilizer and organisms upon the hydration hardening can be used for agriculture and cultivation.

Description

Detailed Description of the Invention

  The present invention relates to a mixture, a solidified product, a culture soil, and a granulated coated seed that are useful for allowing a plant to easily take in iron in water and land.

  Iron and mineral ions are essential elements for plant growth regardless of whether they are water plants or land plants. In particular, deficiency of iron, zinc, calcium and magnesium causes problems such as poor growth and abnormal roots and leaves. Iron is taken into plants as divalent iron ions and iron fulvic acid. In recent years, the growth of seaweed, seagrass and phytoplankton has been seen as a problem in coastal waters, but this problem is also due to the lack of soluble iron and mineral ions available for seaweed, seaweed and phytoplankton. It is considered. In coastal waters, the iron concentration itself is high, but in seawater, iron is easily oxidized to become trivalent iron and insolubilized, so seaweed, seaweed and phytoplankton cannot be ingested.

  As a method for solving such problems and supplying iron and mineral components to water in such a form that seaweed, seaweed and phytoplankton can be easily ingested, for example, Patent Document 1 discloses organic acid iron and iron fulvic acid. A method is shown in which a porous artificial reef made of concrete containing agricultural, forestry and fishery waste containing humus and humus soil is installed in water, and organic acid iron is supplied from the artificial reef into the water. In Patent Documents 2 and 3, a mixture of steel slag, woody humus, and marine waste is filled into a water-permeable bag, and this is placed in water. Iron fulvic acid combined with fulvic acid contained in woody humic plants is supplied into water. Patent Document 4 discloses a method in which an organic acid such as gluconic acid or glutamic acid is added to steel slag and the like, and is dispersed and installed in land and sea.

  On the other hand, terrestrial plants such as agricultural crops need to be ingested with trace amounts of iron and various minerals for stable growth. In particular, alkaline soil is an environment in which iron ions are difficult to elute and iron deficiency is likely to occur.

On the other hand, paddy rice farming involves sowing, seedling, and rice planting processes, but the burden of raising seedlings or the burden of rice planting is excessive, leading to excessive labor and cost increase for workers. The granulated coating seed fir is coated with iron powder and calcined gypsum that promotes oxidation of iron. While rotating the damp seed fir, the coating material (iron + calcined gypsum) is divided into 2 to 3 times. And dry the granulated coating seed fir.
Alternatively, a seed fir has been devised that is coated with a calcium peroxide agent (trade name Calper) that supplies oxygen and a coating agent (iron + calcined gypsum) or trivalent iron and molybdenum trioxide.

However, coated seeds for paddy rice require material costs and labor for coating, and therefore low-cost and labor-saving techniques such as iron coating (iron powder coating) are required.
Gypsum used for fixing materials with a coating of calcium oxide or iron contains sulfide ions. Sulfide ions (autumn fall) generated in the oxygen-deficient state also hinders seedling establishment. In direct seeding of paddy rice, only the vicinity of the seed is strongly reduced and sulfide ions are locally generated. Therefore, the use of gypsum may promote the generation of sulfide ions.

  In the sea area, oyster shelves are used to make sea villages with seeds of seaweed (Amamo, Umihimo, etc.) in the sea to purify seawater. However, it is difficult for the seaweed seeds to settle and germinate in the target location due to the flow of the tide.

JP 2001-61368 A JP 2005-34140 PR JP 2006-345738 A Japanese Patent Application Laid-Open No. 2011-160764

  In modern agricultural cultivation, the use of humus on hardwoods and deciduous trees is reduced, and the use of chemical fertilizers causes a shortage of trace elements of various minerals. Yes.

  Cultivated land is cultivation that does not rely on soil disinfection, as excessive soil disinfection is performed against pests, and the growth of breeding in the line progresses due to the disruption of microbial balance, lack of various mineral components and the acidification of the soil There is a strong need for a method.

  In the fishery industry, minerals and organic matter flowing from the forest play a role in keeping the water area rich. For this reason, tree planting projects are carried out by individuals, groups, and the public, but many years of time and enormous funds are required. However, considering environmental issues and the fishery industry, afforestation is now the best means. In Europe, forests are the mother of the sea. There is a trap with.

  The techniques of Patent Documents 1 to 3 require materials such as humus and marine waste, but it is difficult to stably obtain a large amount of these materials, and therefore, general-purpose use is difficult. It is also difficult to apply to wide water areas such as lakes and marine areas. In addition, these methods bring terrestrial microorganisms into the water area at a high concentration, which is not preferable from the viewpoint of the influence on the ecosystem.

In the technique described in Patent Document 4, a hardened material obtained by processing and adding a substance containing iron, an organic acid such as gluconic acid and glutamic acid is dispersed and installed in land and water. The above-mentioned cured product is a processed product of a cement curing agent and is not suitable for spraying on land because it does not dissolve in water. In addition, it is necessary to produce gluconic acid and glutamic acid.

  Therefore, the object of the present invention is to provide a stable supply of soluble iron ions and various mineral ions that can be easily ingested by plants regardless of whether they are in water or land. An object of the present invention is to provide iron ions and various mineral ion supply materials capable of obtaining effects.

  Another object of the present invention is to provide a mixture or solidified product of iron ions and various mineral ion feed materials that can stably produce iron ions and various mineral feed materials and a granulated coated seed. Is to provide. Furthermore, another object of the present invention is to provide a healthy growth in paddy rice cultivation by suppressing the phenomenon of oxygen deficiency due to sulfide ions and the phenomenon that hinders the growth of paddy rice, such as autumn rice. In addition, various chelated minerals are also eluted in other seed-based farming methods, and natural humic and iron powders that absorb minerals during seed growth are provided.

  The present invention is a mixture comprising natural humin, iron (powder or granules), a mineral component containing iron and a curing agent.

  It is a solidified product obtained by hydrating and curing a mixture of natural humin and iron (powder or grains), a mineral component containing iron and a curing agent into blocks, grains or powders.

  Natural humin, iron (powder or granules), a mineral component containing iron, a hardening agent and a fermenting bacterium are mixed and solidified by hydration.

  Culture soil or compost in which fermented bacterial bed residue is added to natural humin and iron (powder or granules), mineral components containing iron, and solidified product hydrated and cured with a curing agent.

  Granulated coated seeds hydrated and hardened with natural humin and iron (powder or grains), mineral components containing iron and hardeners.

  Sprinkle cultivated land with powder and powder hydrated and hardened with natural humin, iron (powder or grains), mineral components containing iron, and hardeners on land. In the sea area, blocks or granules hydrated and hardened with minerals and hardeners containing a large amount of natural humin and iron and iron are buried in water, releasing iron fulvic acid and trace mineral ions, resulting in seaweed, Seagrass and phytoplankton grow.

  Natural humin, iron (powder or grains), mineral components containing iron, fertilizer, and a mixture of microorganisms hydrated and hardened with a hardener, block, powder and granular solidified products release various mineral components for a long time it can. In addition, by installing the above solidified material at the inlet of the paddy field, each chelated mineral water is stored in the paddy field, and then flows into the river and reaches the sea. In the field, the above solidified product can be put in a tank and filled with water, and a chelated mineral aqueous solution can be used for foliar application, irrigation and irrigation of soil, mineral reinforcement for hydroponics, and the like.

By processing the above-mentioned solidified material into a porous material and installing the solidified material in which microorganisms are propagated in a porous manner in aquaculture farms and aquariums, the mineral ions-rich seawater and fresh water Water purification is performed.
Furthermore, by planting seedlings in a block mixed with either one of the above solidified products, fermented fungus bed residue and culture soil, and planting them in cultivated land, it becomes a soil rich in various mineral ions, humus soil and microorganisms .

Coating materials that do not contain sulfide ions include iron particles, steel slag (trade name Minical), natural humin, and lignin hardener (humus). Fulvic acid, an organic acid contained in natural humin, chelate oxide minerals to make it easier for plants to absorb, steel slag (trivalent iron in products (Fe ₂ O ₃ → Fe (OH) ₂ )) calcium metasilicate _{(C a S I O 3)} + H 2 O 3 + H 2 O → S i (OH) 4 + CaCO3 will, produce changes in the water-soluble orthosilicate of easily absorbing low molecular weight.
(Patent No. 4449030)
There are minerals that are soluble in calcium and silicic acid, soluble in clay, manganese, phosphoric acid, boron, etc., and also release oxygen with chelation. Furthermore, a variety of granulated coated seeds can be produced by adding inorganic fertilizers (chicken manure ash) effective for growth, microbial materials such as endophyte (trade name cell seedling spirit), and the like.

  Natural humic and iron (powder or grains), mineral components containing iron, lignin hardener or cement hardener hydrated hardened blocks, powders and granules, long-term fulvic acid iron and mineral ions in the soil and water The ability to supply stably is particularly high, and even if the soil is in an alkaline or acidic environment, such a function can be exerted. In addition, by using natural humin, especially when steel slag is used as the iron source In addition, even when using iron ion supply materials in an alkaline or acidic soil environment, iron fulvic acid is generated continuously for a long period from the initial stage of material installation, and iron fulvic acid is supplied to the soil and water. can do. Moreover, by blending granular natural humin, the elution property is moderately suppressed, and it is possible to obtain the elution sustainability equivalent to the above.

  Paddy rice seed and seed-use farming method coated with natural humin and iron (powder or grains) or steel slag and lignin hardener is natural humin (fulvic acid) and various minerals contained in iron (powder or grains) and steel slag Elutes minerals such as iron fulvic acid and chelated silicon, magnesia, manganese, phosphoric acid and boron, and is absorbed from the roots to become a strong seedling.

(Natural humic)
Natural humin is a mineral vein created in the process of carbonization over millions of years to thousands of years. It is. It is distributed as ore from Canada and the United States. The most advanced carbonization of this ore is from lignite to coal, and immature materials in the carbonization process are grass and peat. In the middle of the carbonization, there is a humic formation that contains a lot of characteristic substances. Humin is not contained in coal and contains very little lignite and peat.

Natural humin includes organic acids of polymer electrolytes such as humic acid, fulvic acid, and humic acid, and has high complex performance with polyvalent valence trace metal elements. Iron bound in strong bonds with fulvic acid and humic acid flows directly into the sea through the river or when the forest approaches the coast. (Reference: If the forest disappears, the sea will die. Second edition, page 76. See Kodansha, Katsuhiko Matsunaga)
From forests, iron fulvic acid and various mineral ions act as a carrier in the water area and play an important role in marine organism production.

  The organic acid in natural humic is a natural humic substance containing about 70% humic acid, of which about 10% contains fulvic acid (around PH4) and a small amount of humic. In the present invention, natural humin is used in the form of fine powder, powder, and granules. The soluble mineral is soluble in organic acids such as root acid, citric acid / glutamic acid / gluconic acid and fulvic acid.

(Mineral components including iron)
As the mineral component containing iron, steel slag, shell fossils, quartz porphyry, nepheline, silicate clay, and the like can be suitably used. Steel slag is a by-product of steelworks, contains a lot of iron, and is also processed for agriculture (product name Minical etc.) and iron powder (product name Bengala). Mineral components are trivalent iron, It is mainly composed of calcium metasilicate, and contains trace amounts of soluble clay, soluble manganese, soluble phosphoric acid, soluble boron and the like.

  The fossil shells used (such as Shellcan Neo) are crushed in the millions of years, and the seabed has been transformed into land. Other seafood and seaweeds, mainly oysters that lived in the seabed era. Plankton is an ore that remains in the soil, corrodes and fossilizes, and is mined in Iwate Prefecture. Ingredients are mainly silicon and calcium, and contain trace amounts of iron, manganese, clay, phosphoric acid, potash, boron, potash, iodine, and aluminum oxide.

  Quartz porphyry is a general rock-forming mineral that constitutes the crust. It is included in igneous rocks, metamorphic rocks, and sedimentary rocks, and is often produced in Nagano and Gifu prefectures. The component is mainly silicon and contains trace amounts of alumina, iron, calcium, magnesium, sodium, potassium, and titanium. Especially toughen rice and vegetable stalks where silicon is dissolved and absorbed from the roots.

  Meteorite is a mineral that contains biotite that is weathered by biotite and stretches like leeches when heated suddenly. Used for agriculture (trade name vermiculite, etc.). Ingredients contain many minerals such as iron, magnesium, sodium, manganese, potassium, zinc, copper, aluminium, silicon, titanium, fluorine, iodine, sulfur, phosphoric acid, panadium, etc., and many are produced in Fukushima Prefecture.

  Silicate clay is a natural geological material mined only in the Yasawagi area of Akita Prefecture, and is used for afforestation and agriculture (trade name: Soft Silica). The component contains 16 kinds of minerals such as silicic acid, aluminum, iron, sodium, calcium and magnesium. In addition, chicken manure ash is an inorganic fertilizer and contains a lot of phosphoric acid, calcium, potassium, etc. necessary for plants and is inexpensive. Substances and inorganic fertilizers containing the above iron and mineral components are easy to distribute at low cost.

(Curing agent)
As the curing agent used in the present invention, a lignin curing agent or a cement curing agent is typically used. Lignin hardener (trade name such as lignosuper D) is mainly composed of lignin as a by-product of paper manufacturing, 1-5 of the total weight of mixture of iron (powder or granules), steel slag, mineral substances containing iron and humic minerals 1 to 3% of a fulvic acid aqueous solution in the same amount as% is mixed, and hydrated and hardened granules are sprayed on the cultivated land. The amount of lignin used is very low because it hydrates and cures well in small amounts. And lignin slowly biodegrades and eventually integrates with the soil.

  Cement hardeners are generally available. The easiest to purchase as a curing agent. In addition, there are hardeners (trade name such as Agoclean) produced by mixing paper sludge incinerated ash as the main raw material and mixing the secondary material processed from coal ash. Ingredients include calcium, silicon, aluminum, sulfur, iron, magnesium, titanium, potassium and other ingredients. In water bodies (bays, corals, rivers, ponds, lake waters), blocks and granules obtained by hydrating and hardening a mixture of natural humin and steel slag with cement may be submerged in the water areas. In addition, by installing a solidified product obtained by hydrating and hardening a mixture of natural humic and iron-containing mineral components with cement at the inlet of the paddy field, each chelated mineral water is stored in the paddy field and then flows into the river and flows into the sea. To reach. In the field, this solidified product can be filled into water in a tank and the ionized mineral aqueous solution can be irrigated onto the foliage and cultivated land.

(Solidified product)
The blocks, powders, and granular solids of the present invention are made of natural humin powder, granules and iron (powder or grains), steel slag, etc., and powders and granules of substances containing various mineral components. Blocks in which a mixture of a lignin curing agent or a cement-based curing agent is poured into a mold, hydrated and cured particles, or hardened lumps can be crushed or produced with a granulator.

  The hydrated cured product of the present invention can be mixed with fertilizers and microorganisms in addition to natural humin, iron (powder or granules), steel slag, etc. and various mineral components, and fertilizers and various mineral ion components. And microorganisms are supplied over a long period of time, reducing waste of fertilizer.

(Bacteria bed residue)
The fungus bed residue is an artificially grown mushroom medium, which is made by blending wood chips, corn, bacus with mushroom nutrients (rice bran, bran, etc.), filling the container, and planting the mushroom species. The medium packed in the container is discarded once. Nutrients, undegraded cellulose and lignin remain in the discarded fungus bed, and the residue is adjusted in water, mixed with fermenting bacteria, dried and reused. The fermented and dried residue can be used for compost, culture soil, fuel, and for livestock litter, then fermented again and used for compost.

(Fermenting bacteria)
Bacteria used in the present invention (trade name, compolise, etc.) are Bacillus subtilis, lactic acid cocci, and lactobacilli, and various enzymes produced from these bacteria are used to decompose pathogen cell walls, plant fiber, and insect eggs. Degradation and other factors, including proteolytic enzymes and carbohydrases, reduce pests and improve soil. In addition, thermophilic bacteria collected from crustaceans that inhabit the hydrothermal vents on the seabed ferment at temperatures around 95 ° C.

(Operation of the invention)
Unlike animals, plants, seaweed, seaweed, and phytoplankton grow only with minerals as nutrients. Components other than carbon dioxide and water necessary for photosynthesis are various mineral components mainly absorbed from the roots. There are 15 or more kinds of mineral elements that are considered essential for plants, and they are classified into 6 kinds of large elements and 9 kinds or more of trace elements according to the required amount. Ideally, the ingredients required for plant growth are balanced. 6 elements in large quantities are nitrogen, phosphoric acid, potash, calcium, magnesium, sulfur, and trace elements are iron, manganese, silicon, zinc, copper, chlorine, boron, molybdenum, nickel, etc. Is contained in a small amount in natural humin, but in order to release it over a long period of time, it will reinforce mineral components containing the above-mentioned 6 kinds of large elements and 9 elements or more of trace amounts.

  In modern farming methods, the use of humus and organic fertilizer fertilizers is reduced, and the use of chemical fertilizers increases the amount of 15 or more mineral components required by plants, and some fertilizers are excessive. When mineral components containing natural humin and iron are sprayed, fulvic acid chelates (complexes) and solubilizes mineral components, so that plants can easily ingest mineral components over a long period of time.

  Cultivated land that relies on chemical fertilizers has few natural humins and 15 or more mineral components, and the balance of microorganisms is lost. In such cultivated land, soil is acidified due to heavy use of chemical fertilizers, the balance of microorganisms is lost, plant growth effects and soil are unhealthy, and many pests and nematodes are bred. The solidified mixture of natural humic and iron-containing mineral components and microorganisms and fertilizers is sprayed on the cultivated land, and then a small current is generated by the mineral components containing carbon and iron, reducing the damage of soil pests. It enables harvesting of agricultural products containing various mineral components.

  In the sea area, when the solid components of the natural humic and iron-containing mineral components and hardeners of the present invention are installed in water, the action of iron fulvic acid and many mineral ions, the propagation of seaweed, seaweed, phytoplankton and the purification action of shellfish Reduce the occurrence of red tide.

  Seed granulated with natural humin and iron (powder or grains), iron-containing components, inorganic fertilizers and microorganisms with lignin hardener seeds, the seeds contain the minerals and inorganic fertilizers necessary for seed growth Surrounding and healthy seedlings give good results for growth and harvest after growing.

(Effect by embodiment)
Natural humin contains many minerals required by plants and ionizes and absorbs minerals to grow healthy. Moreover, the mineral component containing the iron component which a plant needs to ingest for a long term is sprayed to the land area with the solidified product of natural humin and lignin hardened body. Lignin remains in the soil as humus. Moreover, a solidified product obtained by hydrating and hardening a mixture of natural humin, iron particles, and steel slag with cement in the sea area can be installed in the water area to release iron fulvic acid and various mineral ion components over a long period of time.

In land area, the mixing ratio of natural humic and iron-containing mineral components is 20-50% of natural humin and 50-80% of mineral components containing iron, and mixed and solidified by hydration hardening with lignin hardener. Cultivate by spraying 40 to 80 kg on 10 ares. Good results are obtained by cultivation of rice, Tomato, green pepper, lotus, etc. The fulvic acid (organic acid) contained in natural humic chelates each mineral and is easily absorbed by plants, and the solidified product of the present invention that has been hydrated and cured continuously releases the mineral outflow. it can.
In water, natural humin and iron (powder or granules), mineral components containing iron, and cement hardeners are mixed in blocks or solidified products that mix natural humin around 20 percent and steel slag as an aggregate around 70 percent. Is used. Large solidified matter stays at the bottom of the water area, and iron fulvic acid and chelated minerals are continuously released.

  Natural humin powder, granules and iron (powder or granules), steel slag and powder containing substances containing various mineral components, add a suitable amount of water to the lignin hardener, burn the solidified product that has been hot-pressed, Fermentative bacteria (trade name comporinase, etc.) are mixed with a porous solidified product obtained by carbonizing the lignin component. The fermenting bacteria live as colonies in the gaps and porous areas of the solidified product. The solidified product is installed in a farm and a water tank to release iron fulvic acid and various mineral ion components over a long period of time. Fermentative bacteria decompose organic substances into water and carbon dioxide to help purify water.

  Mushroom bed residue mixed with microorganisms (trade name compolise) and high-temperature fermenting bacteria, and the bacterial bed residue is subjected to high-temperature fermentation, then fermented and dried bacterial bed residue, natural humin, iron (powder or grains), and mineral components containing iron The solidified product hydrated and cured with a lignin curing agent is mixed with culture soil to form a cultivation block, which can grow plants. A block planted with a plant can be directly planted in a cultivated land or pot, and this cultivated block is reduced to soil as humus soil.

  Mushroom bed residue that is easy to ferment and adjusts moisture is mixed with high-temperature fermenting bacteria, humic acid, iron (powder or grains), and mineral components containing iron, and then fermented and dried. It can be used as a covering material for manure. After use, the mixture of the fungal bed residue and manure can be re-fermented after adjusting the moisture again, and then reduced to the soil as compost. This compost contains various mineral ions and organic fertilizers required by plants and returns to the soil. In this way, the fungal bed residue can be recycled as a bedding material or compost.

  The mixture of natural humin + iron powder, steel slag + inorganic fertilizer + microorganisms has mineral components, inorganic fertilizers and effective microorganisms necessary for the initial growth of plants. Seeds granulated and coated with the above mixture and lignin hardener (humus and low molecular weight structure) are seeds of plant seeds such as grains, flowers, vegetables, trees and seaweed seeds (Amamo, Umihimo, etc.) Can be granulated coating.

Claims (5)

  A mixture comprising natural humin, iron (powder or granules), a mineral component containing iron and a curing agent.   A block, powder, or granular solidified product obtained by solidifying the mixture according to claim 1.   The solidified product according to claim 2, which is obtained by mixing fermentative bacteria.   Cultivated soil or compost comprising the solidified product according to claim 2 mixed with blocks, powders, granules, fermented fungal bed residues, etc.   A granulated coating seed comprising the mixture according to claim 1 hardened.