JP2014503507A - ヒドロシリル化触媒 - Google Patents
ヒドロシリル化触媒 Download PDFInfo
- Publication number
- JP2014503507A JP2014503507A JP2013541002A JP2013541002A JP2014503507A JP 2014503507 A JP2014503507 A JP 2014503507A JP 2013541002 A JP2013541002 A JP 2013541002A JP 2013541002 A JP2013541002 A JP 2013541002A JP 2014503507 A JP2014503507 A JP 2014503507A
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- substituted
- unsaturated
- formula
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- GAZWKJNMLLGPKV-UHFFFAOYSA-N CCC(C1)C1N Chemical compound CCC(C1)C1N GAZWKJNMLLGPKV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0803—Compounds with Si-C or Si-Si linkages
- C07F7/0825—Preparations of compounds not comprising Si-Si or Si-cyano linkages
- C07F7/0827—Syntheses with formation of a Si-C bond
- C07F7/0829—Hydrosilylation reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0834—Compounds having one or more O-Si linkage
- C07F7/0838—Compounds with one or more Si-O-Si sequences
- C07F7/0872—Preparation and treatment thereof
- C07F7/0876—Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
- C07F7/0878—Si-C bond
- C07F7/0879—Hydrosilylation reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41708410P | 2010-11-24 | 2010-11-24 | |
| US41709310P | 2010-11-24 | 2010-11-24 | |
| US61/417,084 | 2010-11-24 | ||
| US61/417,093 | 2010-11-24 | ||
| PCT/US2011/061751 WO2012071359A1 (en) | 2010-11-24 | 2011-11-22 | Hydrosilylation catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2014503507A true JP2014503507A (ja) | 2014-02-13 |
| JP2014503507A5 JP2014503507A5 (OSRAM) | 2015-01-29 |
Family
ID=45319391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013541002A Pending JP2014503507A (ja) | 2010-11-24 | 2011-11-22 | ヒドロシリル化触媒 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8637626B2 (OSRAM) |
| EP (1) | EP2643335B1 (OSRAM) |
| JP (1) | JP2014503507A (OSRAM) |
| KR (1) | KR20140042766A (OSRAM) |
| CN (1) | CN103347889A (OSRAM) |
| BR (1) | BR112013012742A2 (OSRAM) |
| TW (1) | TWI450903B (OSRAM) |
| WO (1) | WO2012071359A1 (OSRAM) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20170042319A (ko) | 2014-08-12 | 2017-04-18 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 하이드로실릴화 반응 촉매 |
| KR20170042681A (ko) | 2014-08-19 | 2017-04-19 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 하이드로실릴화 철 촉매 |
| JP2018016626A (ja) * | 2016-07-22 | 2018-02-01 | エボニック デグサ ゲーエムベーハーEvonik Degussa GmbH | トリス[3−(アルコキシシリル)プロピル]イソシアヌレートの製造方法 |
| KR20180030080A (ko) | 2015-07-14 | 2018-03-21 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 하이드로실릴화 반응 촉매 |
| US10000515B2 (en) | 2014-08-12 | 2018-06-19 | Kyushu University, National University Corporation | Hydrosilylation reaction catalyst |
| JP2018118925A (ja) * | 2017-01-25 | 2018-08-02 | 公立大学法人大阪市立大学 | 鉄錯体触媒を用いたカルボニル化合物のヒドロシリル化反応によるアルコキシシランの製造方法 |
| WO2018159595A1 (ja) | 2017-02-28 | 2018-09-07 | 国立大学法人九州大学 | ヒドロシリル化反応、水素化反応およびヒドロシラン還元反応用触媒 |
| KR20180108656A (ko) | 2016-01-22 | 2018-10-04 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 신규 아이소사이아나이드 화합물 및 하이드로실릴화 반응 촉매 |
| WO2019065448A1 (ja) | 2017-09-29 | 2019-04-04 | 国立大学法人九州大学 | コバルト錯体、その製造方法およびヒドロシリル化反応用触媒 |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9139699B2 (en) * | 2012-10-04 | 2015-09-22 | Dow Corning Corporation | Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts |
| US9782763B2 (en) | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
| US8927674B2 (en) | 2012-08-16 | 2015-01-06 | Princeton University | Dehydrogenative silylation and crosslinking using cobalt catalysts |
| US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
| US9447125B2 (en) | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
| WO2014182670A2 (en) | 2013-05-06 | 2014-11-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
| US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
| JP2016520083A (ja) * | 2013-05-15 | 2016-07-11 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | シリルヒドリドによる金属塩の活性化およびヒドロシリル化反応におけるその使用 |
| US9708355B2 (en) | 2013-06-12 | 2017-07-18 | Arizona Board Of Regents On Behalf Of Arizona State University | First-row transition metal hydrogenation and hydrosilylation catalysts |
| WO2015023328A1 (en) * | 2013-08-14 | 2015-02-19 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine dimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
| WO2015077306A1 (en) | 2013-11-19 | 2015-05-28 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| US9387468B2 (en) | 2013-11-19 | 2016-07-12 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| TW201524603A (zh) | 2013-11-19 | 2015-07-01 | Momentive Performance Mat Inc | 鈷觸媒及其於矽氫化與脫氫甲矽烷化之用途 |
| WO2015171881A1 (en) * | 2014-05-08 | 2015-11-12 | Momentive Performance Materials Inc. | Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| US11273432B2 (en) | 2018-05-31 | 2022-03-15 | Arizona Board Of Regents On Behalf Of Arizona State University | Beta-diketiminate manganese catalysts for hydrosilylation, hydroboration, and dehydrogenative pnictogen-silicon and pnictogen-boron bond formation |
| CN112387313B (zh) * | 2020-11-17 | 2022-08-16 | 中山大学 | 三齿邻菲罗啉锰催化剂及其在合成有机硅/硼化合物中的应用 |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5508458A (en) * | 1995-05-26 | 1996-04-16 | Hoechst Celanese Corporation | Chiral catalysts and processes for preparing the same |
| JP2001510198A (ja) * | 1997-07-18 | 2001-07-31 | ビーエーエスエフ アクチェンゲゼルシャフト | 二座配位子でキレートされたモノアルキル金属錯体の製造 |
| CN1546536A (zh) * | 2003-12-16 | 2004-11-17 | 中国科学院长春应用化学研究所 | 树状多核吡啶双亚胺铁烯烃聚合催化剂前体及其制备方法 |
| WO2007104680A1 (en) * | 2006-03-10 | 2007-09-20 | Total Petrochemicals Research Feluy | Polymerisation of ethylene and alpha-olefins with imino-quinolinol complexes |
| JP2007533831A (ja) * | 2004-04-20 | 2007-11-22 | ダウ・コーニング・コーポレイション | シリコーンポリエーテルブロック共重合体の水性分散液 |
| WO2009080237A1 (en) * | 2007-12-21 | 2009-07-02 | Basell Polyolefine Gmbh | Catalyst sytem for olefin polymerization comprising phenantroline-comprising iron complexes |
| CN102060852A (zh) * | 2009-11-17 | 2011-05-18 | 中国科学院化学研究所 | 喹啉类配合物及制备方法以及含有所述喹啉类配合物的催化剂及在催化乙烯聚合中的用途 |
| JP2012532884A (ja) * | 2009-07-10 | 2012-12-20 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | ヒドロシリル化触媒 |
| JP2013544824A (ja) * | 2010-11-24 | 2013-12-19 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | ヒドロシリル化触媒として使用される三座窒素配位子を有する金属錯体のin−situ活性化 |
| JP2014502271A (ja) * | 2010-11-24 | 2014-01-30 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | 多価不飽和化合物の金属触媒モノヒドロシリル化 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3220972A (en) | 1962-07-02 | 1965-11-30 | Gen Electric | Organosilicon process using a chloroplatinic acid reaction product as the catalyst |
| US3159601A (en) | 1962-07-02 | 1964-12-01 | Gen Electric | Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes |
| US3775452A (en) | 1971-04-28 | 1973-11-27 | Gen Electric | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes |
| US8415443B2 (en) | 2009-07-10 | 2013-04-09 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
-
2011
- 2011-11-22 EP EP11794590.7A patent/EP2643335B1/en not_active Not-in-force
- 2011-11-22 KR KR1020137016387A patent/KR20140042766A/ko not_active Withdrawn
- 2011-11-22 JP JP2013541002A patent/JP2014503507A/ja active Pending
- 2011-11-22 BR BR112013012742A patent/BR112013012742A2/pt not_active Application Discontinuation
- 2011-11-22 CN CN2011800658735A patent/CN103347889A/zh active Pending
- 2011-11-22 WO PCT/US2011/061751 patent/WO2012071359A1/en not_active Ceased
- 2011-11-22 US US13/302,448 patent/US8637626B2/en active Active
- 2011-11-23 TW TW100142962A patent/TWI450903B/zh not_active IP Right Cessation
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5508458A (en) * | 1995-05-26 | 1996-04-16 | Hoechst Celanese Corporation | Chiral catalysts and processes for preparing the same |
| JP2001510198A (ja) * | 1997-07-18 | 2001-07-31 | ビーエーエスエフ アクチェンゲゼルシャフト | 二座配位子でキレートされたモノアルキル金属錯体の製造 |
| CN1546536A (zh) * | 2003-12-16 | 2004-11-17 | 中国科学院长春应用化学研究所 | 树状多核吡啶双亚胺铁烯烃聚合催化剂前体及其制备方法 |
| JP2007533831A (ja) * | 2004-04-20 | 2007-11-22 | ダウ・コーニング・コーポレイション | シリコーンポリエーテルブロック共重合体の水性分散液 |
| WO2007104680A1 (en) * | 2006-03-10 | 2007-09-20 | Total Petrochemicals Research Feluy | Polymerisation of ethylene and alpha-olefins with imino-quinolinol complexes |
| WO2009080237A1 (en) * | 2007-12-21 | 2009-07-02 | Basell Polyolefine Gmbh | Catalyst sytem for olefin polymerization comprising phenantroline-comprising iron complexes |
| JP2012532884A (ja) * | 2009-07-10 | 2012-12-20 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | ヒドロシリル化触媒 |
| CN102060852A (zh) * | 2009-11-17 | 2011-05-18 | 中国科学院化学研究所 | 喹啉类配合物及制备方法以及含有所述喹啉类配合物的催化剂及在催化乙烯聚合中的用途 |
| JP2013544824A (ja) * | 2010-11-24 | 2013-12-19 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | ヒドロシリル化触媒として使用される三座窒素配位子を有する金属錯体のin−situ活性化 |
| JP2014502271A (ja) * | 2010-11-24 | 2014-01-30 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | 多価不飽和化合物の金属触媒モノヒドロシリル化 |
Non-Patent Citations (7)
| Title |
|---|
| ARCHER, A. M. ET AL: "Arene Coordination in Bis(imino)pyridine Iron Complexes: Identification of Catalyst Deactivation Pat", ORGANOMETALLICS, vol. 25(18), JPN6015032221, 2006, pages 4269 - 4278, ISSN: 0003133635 * |
| BART S. C. ET AL: "Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and T", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 126(42), JPN6015032220, 2004, pages 13794 - 13807, ISSN: 0003133634 * |
| BOUWKAMP M. W. ET AL: "Bis(imino)pyridine Iron(II) Alkyl Cations for Olefin Polymerization", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 127(27), JPN6015032225, 2005, pages 9660 - 9661, ISSN: 0003133639 * |
| BOUWKAMP, M. W. ET AL: "Iron-Catalyzed [2π + 2π] Cycloaddition of α,ω-Dienes: The Importance of Redox-Active Supporting", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 128(41), JPN6015032226, 2006, pages 13340 - 13341, ISSN: 0003133640 * |
| KOPPL, A.; ALT, H. G.: "Substituted 1-(2-pyridyl)-2-azaethene-(N,N)-nickel dibromide complexes as catalyst precursors for ho", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 154(1-2), JPN6015032224, 2000, pages 45 - 53, ISSN: 0003133638 * |
| TONDREAU, A. M. ET AL: "Bis(imino)pyridine Iron Complexes for Aldehyde and Ketone Hydrosilylation", ORGANIC LETTERS, vol. 10(13), JPN6015032222, 2008, pages 2789 - 2792, ISSN: 0003133636 * |
| ZHANG, SHU ET AL: "Ferrous and Cobaltous Chlorides Bearing 2,8-Bis(imino)quinolines: Highly Active Catalysts for Ethyle", ORGANOMETALLICS, vol. 29(5), JPN6015032223, 2010, pages 1168 - 1173, ISSN: 0003133637 * |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10005797B2 (en) | 2014-08-12 | 2018-06-26 | Kyushu University, National University Corporation | Hydrosilylation reaction catalyst |
| KR20170042319A (ko) | 2014-08-12 | 2017-04-18 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 하이드로실릴화 반응 촉매 |
| US10000515B2 (en) | 2014-08-12 | 2018-06-19 | Kyushu University, National University Corporation | Hydrosilylation reaction catalyst |
| KR20170042681A (ko) | 2014-08-19 | 2017-04-19 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 하이드로실릴화 철 촉매 |
| US10239896B2 (en) | 2014-08-19 | 2019-03-26 | Kyushu University, National University Corporation | Hydrosilylation iron catalyst |
| KR20180030080A (ko) | 2015-07-14 | 2018-03-21 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 하이드로실릴화 반응 촉매 |
| KR20180108656A (ko) | 2016-01-22 | 2018-10-04 | 신에쓰 가가꾸 고교 가부시끼가이샤 | 신규 아이소사이아나이드 화합물 및 하이드로실릴화 반응 촉매 |
| US10829504B2 (en) | 2016-01-22 | 2020-11-10 | Shin-Etsu Chemical Co., Ltd. | Isocyanide compound and hydrosilylation reaction catalyst |
| JP2018016626A (ja) * | 2016-07-22 | 2018-02-01 | エボニック デグサ ゲーエムベーハーEvonik Degussa GmbH | トリス[3−(アルコキシシリル)プロピル]イソシアヌレートの製造方法 |
| JP2018118925A (ja) * | 2017-01-25 | 2018-08-02 | 公立大学法人大阪市立大学 | 鉄錯体触媒を用いたカルボニル化合物のヒドロシリル化反応によるアルコキシシランの製造方法 |
| WO2018159595A1 (ja) | 2017-02-28 | 2018-09-07 | 国立大学法人九州大学 | ヒドロシリル化反応、水素化反応およびヒドロシラン還元反応用触媒 |
| KR20190125374A (ko) | 2017-02-28 | 2019-11-06 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 히드로실릴화 반응, 수소화 반응 및 히드로실란 환원 반응용 촉매 |
| US12296325B2 (en) | 2017-02-28 | 2025-05-13 | Kyushu University, National University Corporation | Catalyst for hydrosilylation reaction, hydrogenation reaction, and hydrosilane reduction reaction |
| WO2019065448A1 (ja) | 2017-09-29 | 2019-04-04 | 国立大学法人九州大学 | コバルト錯体、その製造方法およびヒドロシリル化反応用触媒 |
| KR20200058463A (ko) | 2017-09-29 | 2020-05-27 | 고쿠리쓰다이가쿠호진 규슈다이가쿠 | 코발트 착체, 그 제조 방법 및 히드로실릴화 반응용 촉매 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012071359A1 (en) | 2012-05-31 |
| US8637626B2 (en) | 2014-01-28 |
| EP2643335B1 (en) | 2015-03-11 |
| EP2643335A1 (en) | 2013-10-02 |
| US20120130021A1 (en) | 2012-05-24 |
| TW201235355A (en) | 2012-09-01 |
| BR112013012742A2 (pt) | 2016-09-13 |
| CN103347889A (zh) | 2013-10-09 |
| KR20140042766A (ko) | 2014-04-07 |
| TWI450903B (zh) | 2014-09-01 |
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