JP2014200778A - Antioxidative drinking water - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide antioxidative water capable of suppressing active oxygen with electrolytic water and exhibiting the performance of antioxidation, and a method for producing the same.SOLUTION: The antioxidative water is characterized in that silver ion water produced using a silver electrode is incorporated into electrolytic dissociation water, or, water in the proton doner of dissociated hydroxyl ions (OH) of pH 8 to 10 of cathode water obtained by filtering raw water and generated by an electrolyzer is mixed with silver ion water generated using a silver electrode by 50 to 100 ppb, and a hydroxy radical(. OH) is deleted.

Description

  The present invention relates to antioxidant water obtained by adding silver ions to electrolytically dissociated water and a method for producing the same.

  As shown in Fig. 4, the current water is generated from domestic wastewater sewage, chemical fertilizers and agricultural chemicals, livestock manure, etc., and tap water is sterilized by adding hypochlorous acid for microbial treatment. Carcinogenicity has been pointed out because organic humic substances contained in water become trihalomethane and nitrosamine.

  In addition, it has been confirmed that nitrates in drinking water increase the risk of diabetes. Nitrate concentrations in drinking water increase the rate of patients with insulin-dependent diabetes and are published at the Colorado Health Science Center in the United States.

  Nitrate is reduced to nitrite under the influence of pH in the digestive tract and then combined with secondary amines to form nitrosamines. Nitrosamines that have reached intoxication values have been shown to release free radicals that damage pancreatic B cells, inhibiting insulin production and causing insulin-dependent diabetes. The relationship between nitrate ion and illness suggests insulin-dependent diabetes, adrenal hyperplasia, heart disease, lung malformation, stomach cancer, esophageal cancer, liver cancer, sudden infant death, red blood cell inability to carry oxygen, etc. Has been.

  In addition, water piped from water storage tanks such as buildings has a certain amount of cleaning and water mold, bacteria, and even mice and insects are present. It was.

From the above, when vitamin C corresponding to nutrient active oxygen is determined before determining the functionality of water, vitamin C has two hydroxyl groups (OH) as shown in FIG. When oxygen superoxide (O ^· ₂ ⁻ ) is encountered, it becomes two oxygen atoms (O) and is reduced to hydrogen peroxide.

However, when this hydrogen peroxide (H ₂ O ₂ ) is given an atomic electron like the 4-electron / 4-proton shown in FIG. 6, it becomes a hydroxyl radical (.OH) while hydroxyl ions (OH ⁻ ) Is broken down into

Since this hydroxyl radical (.OH) lacks one electron (e ⁻ ) and is considered to cause damage to cells and cause progression of radical diseases, it is necessary to use active oxygen elimination for hydroxy radicals. It shows that when one electron is given to the radical (.OH), it becomes a hydroxide ion (OH ⁻ ), and when proton (H ⁺ ) is given, it is reduced to water (H ₂ O).

Therefore, in order to protect vitamin C from oxidation, nutritionally, when polyphenols having many hydroxyl groups (OH ⁻ ) shown in FIG. 7 are given, hydroxyl groups are given to vitamin C and protons are supplied to correspond to active oxygen. Conceivable.

  Cathode water approved by the Ministry of Health, Labor and Welfare for water electrolysis is commercially available as reduced water.

The following patent document also relates to electrolyzed water and a method for producing the same, and the inventor of the present invention previously invented, for example, electrolyzed water containing OH radicals or Cl radicals and a method for producing the same.
Japanese Patent Laid-Open No. 7-964

This Patent Document 1 discloses that a dilute electrolyte solution in which 0.5 to 1 mol / Kg of NaCl or KCl is dissolved is electrolyzed to have an electric conductivity of 150 to 2000 μS / cm ³ and contains OH radicals or Cl radicals. Electrolyzed water having a free energy of 22.1 Kcal / mol or more is obtained.

The characteristics of electrolytically dissociated water are as follows.
[Characteristics of cathode water]
1. Electrolysis of water or an aqueous solution generates hydroxyl group or excess (OH ⁻ ) dissociated from hydrogen gas on the cathode side.
2. The dissociated hydroxyl group (OH ⁻ ) exhibits a strong reducing action due to a strong nucleophilic action.
3. The pH that is an indicator of the hydrogen ion concentration depends only on the alkali metal hydroxide, and the dissociated hydroxyl group or excess (OH ⁻ ) does not contribute to the pH.
4. When the dissociated positive ions enter the cathode water, the dissociated hydroxyl group or excess (OH ⁻ ) is consumed to attenuate the reducing property.
5. The presence of an acid in the cathode water causes the alkali metal hydroxide to undergo a neutralization reaction, but the dissociated hydroxyl group (OH ⁻ ) is present stably without causing a neutralization reaction.
6. The behavior of the dissociated hydroxyl group (OH ⁻ ) in the living body exists stably without causing a neutralization reaction with an acid and causes a nucleophilic reaction.
7. Reaction with free radicals prevents radical chain reactions.

[Features of anode water]
1. Electrolysis of water or an aqueous solution generates oxygen or chlorine gas or excess protons (H ⁺ ) on the anode side.
2. pH, an indicator of hydrogen ion concentration, is measured only as a conjugated acid.
3. The dissociated protons exhibit a strong oxidizing action and cause electrons to be extracted.
4. Dissociated protons or excess protons have a proton jump mechanism that causes energy transfer through hydrogen of water molecules, and therefore show a state of extremely high relative permeability and infiltration.
5. Dissociated protons or excess protons exhibit an electrophilic action in association with the electron reduction of oxygen to the living body and contribute to the transition to the four-electron reduction state.

  In general, in water treatment, cathodic water obtained by applying direct current to water through a diaphragm and being electrolyzed is used as health drinking water. However, the water quality standard for nitrates contained in tap water is 10 mg / L or less, but in practice, Since there is 12 to 15 mg / L, the action of electrolytic cathodic water is shown to have an action of reducing the nitrate ion concentration to 10 mg / L or less as shown by graph 1 in FIG. Water is used as water to lower nitrate ions.

As shown in the graph 2 of FIG. 9, the electrolytic cathodic water is obtained by adding the nutrients vitamin C, catechin, and dehydrated quercetin to the chemical alkaline water and the cathodic water to verify the antioxidant effect. Unlike the substance alkaline water, it has been shown to be antioxidant against the nutrient substance.
Symbol: The symbol for AsA / Q / C is added to alkaline water.
Rw + ASA / Rw + Q / Rw + C is added to the cathode water.
Symbol of each nutrient substance AsA: L monoascorbic acid (vitamin C)
C: Catechin Q: Dehydrated quercetin Evaluation: Antioxidation of alkaline water and cathodic water was not observed, but the beneficial effect of the antioxidant action was recognized with the nutritional additive in cathodic water.

  The important thing is that about 2L of water is drunk every day, and our body has 60% of water, so the role of water is utilized in the body by biophysical chemistry. While the mitochondria present in these cells generate energy and provide it to the nucleus of the cell, the substance in which active oxygen is generated in the cell is released into the sea of blood and circulated throughout the body. Therefore, there is a need for drinking water to seek antioxidant water.

Furthermore, it is considered that biological enzymes are produced in cells of all organs and correspond to active oxygen. In other words, the biological enzyme induces protons (H ⁺ ) by the action of electrons (e−) from biological water, responds to active oxygen, and promotes the immune mechanism. For example, electron transfer in the mitochondrial respiratory chain is a continuous reaction, when an electron is transferred from one component to the next and many of these components change from oxidized to reduced, only one Only the above electrons can be obtained, but one other component can generate one or more ionizations on the molecule by obtaining the electrons, increasing the dissociation of the group. Stick.
For example, cytochrome c (cytc) undergoes 1e ^- reduction:
^{Fe3 + -cytc + 1e = Fe 2} + -cytc (-350mV)
The reductase NAD ⁺ undergoes 2e ⁻ reduction to yield one H ⁺ .
NAD ⁺ + 2e ⁻ + H ⁺ = NADH
However, ubiquinone undergoes 2e ⁻ reduction, and then 2H ⁺ is added and 2H is transmitted.
UQ + 2e ⁻ + 2H ⁺ = UQH ₂
For this reason, in oxygen metabolism, protons are supplied by converting the oxidized form to the reduced form through the electron transport system, so it is necessary to make extensive use of proton donors and cathodic water proton donors from water and nutrients. It suggests. Therefore, since our bodies are utilized according to moisture, we need water's original functionality, that is, seeking antioxidant water and antibacterial effects in the digestive tract. The selection technology is important.

For the maintenance of health maintenance, the function corresponding to the active oxygen of water and vitamin C and polyphenols from plants were considered. However, problems of foods is Bifuzusu bacteria good bacteria exist good bacteria and bad bacteria in the small intestine is superoxide in the intestine ^- is reduced (O ₂ ^·) in hydrogen peroxide (H 2 _{O 2)} .

  For the maintenance of health maintenance, the function corresponding to the active oxygen of water and vitamin C and polyphenols from plants were considered. However, in order to protect cells, the small intestine generates hydrogen peroxide to respond to superoxide, and generates hydroxy radicals (.OH) that are acidic substances in the intestine, causing carcinogenicity. Therefore, drinking water for health needs a method for suppressing active oxygen with electrolyzed water and an antioxidant for protecting the small intestine.

  An object of the present invention is to provide an antioxidant water capable of suppressing active oxygen with electrolyzed water and exhibiting antioxidant performance, and a method for producing the same.

In order to achieve the above object, the present invention provides, as an antioxidant drinking water, firstly, the electrolytically dissociated water contains silver ion water obtained by electrolytic silver ion water, and secondly, the raw water is filtered. Then, 50 to 100 ppb of silver ion water is mixed with water in the proton donor of dissociated hydroxide ions (OH ⁻ ) having a pH of 8 to 10 generated by the electrolysis apparatus using a silver electrode, and a hydroxy radical (. OH) was eliminated, and thirdly, the raw water was filtered, the water in which electrolytic silver ion water was produced in an amount of 50 to 100 ppb was electrolyzed in the electrolyzer, and the anode water and the cathode water produced in the electrolyzer were mixed. This is the gist.

  As a method for producing antioxidant drinking water, first, silver electrolysis is performed, and after filtration, water is supplied to the electrolytic anode chamber and the electrolytic cathode chamber of the electrolysis generator to generate anode silver water and cathode silver water, 2) After filtration, silver electrolysis is performed on the electrolyzed cathode water generated by the electrolysis generator to generate cathodic silver water. Third, silver electrolysis is performed, and silver mixed with anodized water and cathode water after filtering The gist is to produce water.

According to the present invention, the antioxidant action by electrolyzed anode water dissociated protons (H ⁺ ) and the hydroxyl group (OH) dissociated by cathode water supplement the hydroxyl groups of vitamin C and polyphenols to induce protons to induce active oxygen. It can be made to correspond.

Moreover, when low concentration electrolytic silver ions are mixed with anode water or cathode water, in addition to sterilization and antibacterial action, by mixing electrolytic silver ion water (Ag ⁺ ) with electrolytic water, hydroxy radicals (.OH) can be mixed. Can be erased and protect the small intestine.

Electrolyzed water includes anode water and cathode water. Superoxide active oxygen in these electrolytic water ^- when mixing (O ₂ ^·), hydroxyl radicals, (· OH), although the cathode water is not in the superoxide scavenging is observed, the anode water is superoxide (O ^- ₂ ^- ) Can be erased as shown in the graph of FIG.

Thus the anode water dissociation (isolated) was ^{(H +)} ions, in the water of pH 3-6, superoxide (O ^- ₂ ^·), hydroxyl radicals, (· OH) is erased active oxygen silver ions with exposure it can. However, in the range of pH 3 to 6, there is no problem with pH 3, but in the case of pH 6, the pH becomes neutral and unstable after a long time, and the addition of silver ions is required.

  Embodiments of the present invention will be described below. First, the method for producing antioxidant drinking water according to the present invention will be described. FIG. 1 shows a first embodiment, in which electrolysis is performed with an electrolysis apparatus 1 in which tap water is silver as an anode, and this is filtered with a filter 2. After filtration, water flows into the electrolytic anode chamber and the electrolytic cathode chamber of the electrolysis generator 3 to generate anodic silver water and cathodic silver water.

  FIG. 2 shows a second embodiment. After filtering with a filter 2, electrolysis is performed with an electrolysis generator 3, and electrolysis cathode water is subjected to silver electrolysis among the generated electrolysis anode water and electrolysis cathode water, thereby producing cathode silver. Water was produced.

  FIG. 3 shows a third embodiment, in which silver electrolysis is performed as in the first embodiment, and after filtration, silver water is produced by mixing anode water and cathode water.

  The drinking water produced in this manner is one containing silver ion water obtained by electrolytic silver ion water in electrolytic dissociated water, that is, antioxidant water obtained by adding silver ions to electrolytic dissociated water.

The present invention provides, as a first embodiment, the raw water is filtered, superoxide dissociated protons (H ⁺⁾ in the active oxygen pH3~6 anode water produced by the electrolytic generator 3 (O ^- ₂ ^·) Ya It is an antioxidant drinking water that eliminates hydroxy radicals (.OH).

As a second embodiment, the drinking water generated in FIG. 2 is filtered into the water in the proton donor of dissociated hydroxide ions (OH ⁻ ) of pH 8 to 10 cathodic water generated by electrolysis by filtering raw water. Antioxidant drinking water in which 50 to 100 ppb of silver ion water is mixed using a silver electrode to remove hydroxy radicals (.OH).

  As a third embodiment, the drinking water generated in FIG. 3 is an antioxidant beverage obtained by filtering raw water and mixing 50 to 100 ppb of electrolytic silver ion water with anodic water and cathodic water generated by an electrolyzer. It is water.

  There is a choice between silver nitrate water and hydrochloric acid mixed with silver nitrate to produce silver chloride, or silver ion or electrolysis using silver as an anode. In order to generate active oxygen due to the above, the drinking water was determined as electrolytic silver ion water.

原水の電気伝導度：７．１２ｍＳ／ｍ 温度１３．３°Ｃ The silver ion concentration by electrolysis is shown in Table 1 below.

Raw water electrical conductivity: 7.12 mS / m Temperature 13.3 ° C

  The Ministry of Health, Labor and Welfare has approved the electrolyzer for drinking water that requires 2 liters every day, but the generated alkaline ionized water is recognized as water for gastric hyperacidity, chronic diarrhea, dyspepsia, and abnormal gastrointestinal fermentation. .

  In addition, water with high alkalinity is considered to have other important functions of preventing cellular aging and blood vessel coins, and therefore, cathodic water using an electrolyzer has been pointed out as drinking water.

  Furthermore, in recent years, diseases caused by heavy metals contained in foods, side effects of drugs, and mental stress have been pointed out medically, and sportsmen and the like are injured due to the amount of oxygen they breathe. These reactions have been known as biotoxins in the past, but in recent years, oxygen-added enzymes have been discovered through research on oxidation-reduction reactions and expressed as “active oxygen”.

This oxidation-reduction reaction is generally known to oxidize when there is a lot of oxygen (O ₂ ), and to reduce when there are a lot of electrons (e ⁻ ) and protons (H ⁺ ). Since these electrons and hydrogen (protons) work and our biological enzymes work smoothly, they show an important role.

In order to eliminate the active oxygen from the oxidation-reduction reaction, the 4-electron / 4-proton reduction generated in the living body is examined from the contents shown in FIG. 6. For example, oxygen (O ₂ ) by respiration is an electron (e ^- ) Is received and superoxide (O ^- ₂ ^· ) having one electron is generated. The superoxide (O ^- ₂ ^·) to the 2H ⁺ is given hydrogen peroxide _(H 2 _{O 2)} it is next to immunization.

  Since the water electrolysis device causes an oxidation-reduction reaction, it is generated by filtering chlorine such as tap water and applying a direct current through a diaphragm. When water is electrolyzed, an oxidation-reduction reaction occurs in the same manner as a phenomenon occurring in the living body, so that it can become drinking water depending on the purpose.

When the positive electrode anode water electrolyzed in this way is neutralized with caustic soda rather than mere acidic water, the hydrochloric acid (HCL) of the electrolytic anode water is different from the chemical hydrochloric acid as shown in the graph 3 of FIG. According to Formula 1, there are protons (H ⁺ ) dissociated as salt water (NaCL).
H ₂ O + HCL + NaOH → H ₂ O + NaCL + (H ⁺ ) 1
Using this anode water, superoxide active oxygen in an electron spin resonance apparatus ^- is characterized to be deleted to give the (O ₂ ^·), hydroxyl radicals, (· OH).

The dissociated proton (H ⁺ ) can also be expressed as an “isolated proton”, and the isolated proton is generated by an oxidation-reduction reaction by electrolysis of water. When the alkali metal salt is present in the electrolyte solution, the alkali metal salt It is shown only as a conjugated acid. Only conjugated acids are involved in the neutralization reaction. Since isolated protons do not react with basic substances, they exist relatively stably and show a strong electrophilic action. Therefore, it reacts in an ion-bonding manner with an oxygen compound having an unpaired electron that is a free radical, thereby changing the high energy level to a stable low energy level and deactivating active oxygen.

Isolated protons form proton jumps for water-soluble radicals through hydrogen atoms of the hydrated water molecules of isolated protons, dramatically increasing the reaction rate and inactivating active oxygen. Compared to cathodic water, isolated hydroxyl groups (OH ⁻ ) bind to fat-soluble and water-soluble radicals, and isolated protons (H ⁺ ) mainly form ionic bonds with water-soluble radicals. Isolated protons play an important role in the wound healing process.

On the other hand, the negative electrode cathode water is not mere alkaline as shown in the following two formulas, and when neutralized with hydrochloric acid, as shown in graph 4, the electrolytic cathodic water is salt water according to the following formula. Then, dissociated hydroxide ions (OH ⁻ ), that is, proton donors exist.
H ₂ O + NaOH + HCL → H ₂ O + NaCL + (OH ⁻ ) 2
Since the two types of hydroxide ions (OH ⁻ ) have an excess electronic role, they supplement vitamin C having two OHs and polyphenols having a plurality of OHs, and indirectly induce active protons by inducing protons. The electronic feature corresponding to is shown.

The dissociated hydroxyl group (OH ⁻ ) can also be expressed as “isolated hydroxyl group (OH ⁻ )”. Two isolated hydroxyl groups are generated from two molecules of water and do not contribute to pH. The reason for this is that the molar concentration of (OH ⁻ ) is too high, it is not a conjugated base, and other alkali metal salts dissolved in the aqueous solution are reduced to form hydroxyl groups. Is considered to contribute to pH.

  Therefore, the pH to be measured is based only on the hydroxyl group derived from the alkali metal salt. The neutralization reaction with an acid having a conjugated base is only a reaction with a hydroxyl group derived from an alkali metal, and an isolated hydroxyl group does not participate in this neutralization reaction. Since the isolated hydroxyl group does not participate in the neutralization reaction with the acid, it is relatively stable in the acidic region or the basic region, and reacts only with protons, that is, those having a positive charge.

  Therefore, when taken into a living body, it is considered that gastric acid does not decompose or neutralize and blood can move relatively stably.

  Further, since the isolated hydroxyl group does not neutralize the gastric acid, only the isolated hydroxyl group has a characteristic that the pH of the gastric acid is not changed. The antioxidative action of cathodic water is thought to be derived from isolated hydroxyl groups, and the reaction with free radicals is thought to cause electron extraction from isolated hydroxyl groups due to radical unpaired electrons. The chain reaction is thought to be able to prevent, so it seems that the chain reaction to organic matter can be prevented.

  From the above, anodic water obtained by electrolyzing water is different from a simple water purifier, and anodic water can electrochemically correspond to active oxygen.

Cathode water can be indirectly supported by nutrition from food. Therefore, it is considered impossible to obtain the role of H ⁺ and OH ⁻ by simply filtering raw water such as tap water and well water. Water is expected as antioxidant water.

  However, in the electrolyzed solution, it is possible to cope with the active oxygen by adding silver ion water because cathodic water cannot directly correspond to the active oxygen.

Despite the noble metals, silver is rich in reactivity and has an excellent catalytic action. Silver is easy to colloid and is in an extremely stable colloidal form in an aqueous solution. From the physical point of view, it is an ultrafine particle and therefore has a very high catalytic activity and promotes oxidation of water. In the case of electrolysis using tap water, since sulfate is present, it becomes beloxodisulfate ion (S ₂ O ² ₈ ⁻ ), and silver ions have been confirmed to react as shown in the following formulas 3-9. Yes.
^{_{S 2 O 2 8 - + Ag}} + → Ag 2 + + SO 2 4 - ... 3
^{_{H 2 O + SO - 4 ·}} → · OH + HSO - 4 ... 4
_{^{Ag + + · OH → Ag 2}} + + OH - ... 5
^{_{Ag + + SO - 4 · →}} Ag 2 + + SO 2 4 - ... 6
2Ag ² + → Ag ⁺ + Ag ³ ₊ ... 7
Ag ³ ₊ + H ₂ O → AgO ⁺ + 2H ⁺ ... 8
AgO ⁺ → Ag ⁺ +1/20 ₂ ... 9

The silver ion concentration is kept constant and acts as a homogeneous catalyst. The entire reaction is H ₂ O + S ₂ O ² ₈ ⁻ → 2SO ² ₄ ⁻ + 2H ⁺ + 1 / 2O ₂
It is.

The rate of decrease of peroxodisulfate ion (S ₂ O ² ₈ ⁻ ) and the rate of O ₂ production follow the following equations.
−d [S ₂ O ² ₈ ⁻ ] / dt = 2d [O ₂ ] = kobsd [S ₂ O ² ₈ ⁻ ]
In the course of more reaction _{proceeds, S} 2 O ^- may contain ₄ ^{·, ·} OH, _{Ag 2+} and Ag ³ ₊ cooperation oxidizing radicals such as.

  Accordingly, since the high concentration of silver ions has a strong catalytic activity, the reaction proceeds using sulfate ions as initiators. When colloidal silver ions reach bacteria, if an initiator is present in the vicinity of the bacteria, strong oxidative radicals are generated and controlled by causing damage. Unlike chlorination with amino groups like chlorination, colloidal silver ions have the characteristic that the reaction continues continuously even with a high protein concentration if an initiator is present.

On the other hand, silver ion water has a bactericidal effect depending on the concentration, but antioxidation is expected even at a low concentration by electrolyzing silver. However, if a high concentration of silver ions is drunk, for example, silver rot has been reported in the case of taking 1,200 to 1,300 silver grains for 3 years a day. Here, since the American FDA is approved as drinking water even if the silver ion concentration of 50 ppb to 100 ppb is added to drinking water, the effect on active oxygen was determined within the range of the concentration. Corresponding to the superoxide (O ^- ₂ ^· ) of active oxygen required for 4 electrons and 4 protons in FIG. 6 with silver ion water of electrolyzed cathodic water, in the superoxide, the silver ion water from the graph 5 shown in FIG. When measured with an electron spin resonance apparatus, it can be seen that the antioxidant effect is not confirmed.

In order to solve the active oxygen of the above-mentioned problem, when a hydroxy radical (.OH) that causes disease progression is obtained, antioxidation is expected according to the following formula 5, and the hydroxy radical is reduced to a hydroxide ion (OH ⁻ ).
^{Ag + + · OH → Ag 2} + + OH - ... 5
That is, when silver ion water was mixed with cathodic water, the antioxidation action of the hydroxy radical was determined by an electron spin resonance apparatus (ESR), and an erasing action was observed. Further, the storage property of silver ion water is stable as shown in the graph of FIG.

  From the above, apart from sterilization, silver ion water is characterized by the fact that the reaction of hydroxy radicals to active oxygen is studied by using electrolyzed silver ion water as the electrolyzed water of bipolar water. Therefore, it is improved as antioxidant water.

Electrolyzed water includes anode water and cathode water. Superoxide active oxygen in these electrolytic water ^- when mixing (O ₂ ^·), hydroxyl radicals, (· OH), although the cathode water is not in the superoxide scavenging is observed, the anode water is superoxide (O ^- ₂ ^The characteristic that.) Is deleted from the graph of FIG. 14 is shown. The measuring method was verified with an electron spin resonance apparatus (SOD).

  When silver ion water was added to the anode water or the cathode water, the removal of the hydroxy radical (.OH) showed the feature of removing the hydroxy radical from the graph of FIG.

  From the above, it was shown that the anode water and cathode water of electrolyzed water to which silver ions of the present invention were added erased hydroxy radicals (.OH) of active oxygen.

When using the electrolytic anodized water of the present invention to cause burns and bed slips caused by skin damage, and also to the damaged part after surgery, radical bilane can be produced without using antibiotics from 200 cases against therapeutic drugs. It did not occur and the treatment was reported to be 100%. This is characterized by the radical elimination of protons (H ⁺ ) because the bilan component generates radicals.

In addition, cases in which urination or defecation is performed tens of minutes later when anodized water is consumed as drinking water when liver cancer causes a phenomenon in which water cannot accumulate and urinate cannot be excreted after surgery for liver cancer patients Was reported. This is thought to be due to the fact that anodic water was effective because of the lack of acidic substances in the kidney and the amide group not being detoxified by amino acids. On the other hand, defecation usually has a pH of about 6 or 5, and it was considered that the pH contributed by the consumption of protons (H ⁺ ) of acidic water in the anode water.

評価：点滴前後の犬から採血した血液（血漿）を、電子スピン共鳴装置にてＳＯＤ活性を測定すると陰極水の点滴後は血液の抗酸化能（ＳＯＤ）が高まっていた。さらに、陰極水を中和した銀イオン水を１００ｐｐｂ添加して犬の血液を調査すると、「１６，８units/ml」になった。これは陰極水が犬の血液に含まれる栄養の影響でスーパーオキサイド（Ｏ⁻ _２ ^・）に寄与した特徴が示された。 Antioxidant activity of blood when electrolytic cathodic water is instilled into dogs.
Conditions: Saline neutralized cathodic water was instilled into dogs as shown in Table 2 below, and SOD activity was examined.

Evaluation: When blood (plasma) collected from dogs before and after infusion was measured for SOD activity using an electron spin resonance apparatus, the antioxidant capacity (SOD) of blood increased after infusion of cathodic water. Further, when 100 ppb of silver ion water neutralized with cathodic water was added and the blood of the dog was examined, it was “16,8 units / ml”. This cathode water superoxide influence nutrient contained in dog blood ^- features that contributed to (O ₂ ^·) is shown.

Name of pilot study in which cathodic water of silver ion water was drunk in dog Name of disease: Canine lymphosarcoma (weight 19 kg)
Test item: white blood cell count, platelet drinking condition: 950 ml / day drinking result: 3 months later, appetite, energy recovery Figure 16 shows the graph.

Steroid hepatitis (weight: 22 kg) in a pilot study dog that allowed the dog to drink silver ion water cathode water
Test item: ALP value (alkaline phosphatase)
Drinking conditions: 1.100 ml / day drinking result: ALP value decreases after 3 months FIG. 17 shows the graph.

A test of mutans, an oral bacterium, was performed with a solution obtained by adding 100 ppb of silver ion water to anodized water.
Number of control bacteria: 5.8 × 10 ⁵
Bactericidal effect: 2,5 × 10 ^{3 in} 1 minute: 0 in 5 minutes.

  Diabetes is indicated by a blood glucose value (75-116 mg / dl), but to investigate other diseases, smokers with the new prostaglandin F2α also tested non-smokers and diabetes tests. FIG. 18 shows the graph.

  The average improvement for prostaglandins is around 200 pg / mg. The peak value on day 42 is the result of having diabetics stop drinking cathodic water and eat sweet candy. In addition, both smokers and non-smokers stopped drinking cathodic water and smoked. This is an example of a report that the cathode water was reduced after that when the cathodic water was drunk.

  From the above results, when the cathodic water added with silver ion water was drunk, the value of diabetes was stable at 80 mg / dl or less even after 3 to 5 months.

  A gastric ulcer caused by Helicobacter pylori was reported to have been completely cured after drinking silver ion water of cathodic water for 7 days in a hospital. In addition, gastric ulcer was completely cured in 5 days after the silver ion water of anodic water was taken by three other patients.

A clinical doctor's report when the patient is given drinking water in which 50 ppb of silver ion water is added to the cathode water is shown below.
1. Salivary nitrate / nitrite test. 2L / day drinking. Test result after 2 days.
2. Acetaldehyde test (alcohol) ··· Drinking whiskey 30cc · After drinking cathodic water 1L / 1H ··· 0.01 mg / L or less.
3. Blood sugar level ··· 2-3L / day drinking ··· Examination after 1-2 months ·· Tend to improve to normal.
4. Uterine cancer clinical ・ First stage symptoms ・ After 6 months of drinking ・ Completely cured.
5. Bacterial examination in the mouth ··· Long-time drinkers · · No spirocheter (alveolar pyorrhea) is detected.
6. The amniotic fluid of pregnant women-The amniotic fluid of pregnant women drinking cathodic water is transparent-The baby has no jaundice symptoms.
7. Liver disease test ・ After half a year of drinking ・ GOT and GPT are improving.

It is explanatory drawing which shows 1st Embodiment of the manufacturing method of the antioxidant drinking water of this invention. It is explanatory drawing which shows 2nd Embodiment of the manufacturing method of the antioxidant drinking water of this invention. It is explanatory drawing which shows 3rd Embodiment of the manufacturing method of the antioxidant drinking water of this invention. It is a matrix that produces the current water. It is explanatory drawing of the vitamin C corresponding to the active oxygen of nutrition. It is explanatory drawing of hydrogen peroxide. It is a chemical formula showing polyphenols having many hydroxyl groups. It is a graph of a nitrate ion removal test. It is a graph which shows each antioxidant action of cathode water and alkaline water. It is a graph which shows the neutralization characteristic of anode water. It is a graph which shows the neutralization characteristic of anode water. It is a graph of silver ion water measured with the electron spin resonance apparatus. It is a graph which shows the characteristic of the preservability of silver ion water. It is a graph which shows a mode that the superoxide (O ^- ₂ ^* ) of anodic water at the time of mixing superoxide (O ^- ₂ ^* ) and hydroxy radical (* OH) of active oxygen in electrolyzed water erase | eliminates. It is a graph which shows erasure | elimination of the hydroxy radical (* OH) at the time of adding silver ion water to anode water or cathode water. It is a graph which shows the result of the pilot test which made the dog drink the cathode water of silver ion water. It is a graph which shows the result of the pilot test which made the dog drink the cathode water of silver ion water. It is a graph of the result of having verified the test of the smoker by the new prostaglandin F2 (alpha), a non-smoker, and diabetes.

DESCRIPTION OF SYMBOLS 1 ... Electrolyzer which made silver the anode 2 ... Filter 3 ... Electrolytic generator

The present invention relates to antioxidant water with the addition of silver ion electrolytic dissociation water.

  As shown in Fig. 4, the current water is generated from domestic wastewater sewage, chemical fertilizers and agricultural chemicals, livestock manure, etc., and tap water is sterilized by adding hypochlorous acid for microbial treatment. Carcinogenicity has been pointed out because organic humic substances contained in water become trihalomethane and nitrosamine.

  In addition, it has been confirmed that nitrates in drinking water increase the risk of diabetes. Nitrate concentrations in drinking water increase the rate of patients with insulin-dependent diabetes and are published at the Colorado Health Science Center in the United States.

  Nitrate is reduced to nitrite under the influence of pH in the digestive tract and then combined with secondary amines to form nitrosamines. Nitrosamines that have reached intoxication values have been shown to release free radicals that damage pancreatic B cells, inhibiting insulin production and causing insulin-dependent diabetes. The relationship between nitrate ion and illness suggests insulin-dependent diabetes, adrenal hyperplasia, heart disease, lung malformation, stomach cancer, esophageal cancer, liver cancer, sudden infant death, red blood cell inability to carry oxygen, etc. Has been.

  In addition, water piped from water storage tanks such as buildings has a certain amount of cleaning and water mold, bacteria, and even mice and insects are present. It was.

From the above, when vitamin C corresponding to nutrient active oxygen is determined before determining the functionality of water, vitamin C has two hydroxyl groups (OH) as shown in FIG. When oxygen superoxide (O ^· ₂ ⁻ ) is encountered, it becomes two oxygen atoms (O) and is reduced to hydrogen peroxide.

However, when this hydrogen peroxide (H ₂ O ₂ ) is given an atomic electron like the 4-electron / 4-proton shown in FIG. 6, it becomes a hydroxyl radical (.OH) while hydroxyl ions (OH ⁻ ) Is broken down into

Since this hydroxyl radical (.OH) lacks one electron (e ⁻ ) and is considered to cause damage to cells and cause progression of radical diseases, it is necessary to use active oxygen elimination for hydroxy radicals. It shows that when one electron is given to the radical (.OH), it becomes a hydroxide ion (OH ⁻ ), and when proton (H ⁺ ) is given, it is reduced to water (H ₂ O).

Therefore, in order to protect vitamin C from oxidation, nutritionally, when polyphenols having many hydroxyl groups (OH ⁻ ) shown in FIG. 7 are given, hydroxyl groups are given to vitamin C and protons are supplied to correspond to active oxygen. Conceivable.

  Cathode water approved by the Ministry of Health, Labor and Welfare for water electrolysis is commercially available as reduced water.

The following patent document also relates to electrolyzed water and a method for producing the same, and the inventor of the present invention previously invented, for example, electrolyzed water containing OH radicals or Cl radicals and a method for producing the same.
Japanese Patent Laid-Open No. 7-964

This Patent Document 1 discloses that a dilute electrolyte solution in which 0.5 to 1 mol / Kg of NaCl or KCl is dissolved is electrolyzed to have an electric conductivity of 150 to 2000 μS / cm ³ and contains OH radicals or Cl radicals. Electrolyzed water having a free energy of 22.1 Kcal / mol or more is obtained.

The characteristics of electrolytically dissociated water are as follows.
[Characteristics of cathode water]
1. Electrolysis of water or an aqueous solution generates hydroxyl group or excess (OH ⁻ ) dissociated from hydrogen gas on the cathode side.
2. The dissociated hydroxyl group (OH ⁻ ) exhibits a strong reducing action due to a strong nucleophilic action.
3. The pH that is an indicator of the hydrogen ion concentration depends only on the alkali metal hydroxide, and the dissociated hydroxyl group or excess (OH ⁻ ) does not contribute to the pH.
4. When the dissociated positive ions enter the cathode water, the dissociated hydroxyl group or excess (OH ⁻ ) is consumed to attenuate the reducing property.
5. The presence of an acid in the cathode water causes the alkali metal hydroxide to undergo a neutralization reaction, but the dissociated hydroxyl group (OH ⁻ ) is present stably without causing a neutralization reaction.
6. The behavior of the dissociated hydroxyl group (OH ⁻ ) in the living body exists stably without causing a neutralization reaction with an acid and causes a nucleophilic reaction.
7. Reaction with free radicals prevents radical chain reactions.

[Features of anode water]
1. Electrolysis of water or an aqueous solution generates oxygen or chlorine gas or excess protons (H ⁺ ) on the anode side.
2. pH, an indicator of hydrogen ion concentration, is measured only as a conjugated acid.
3. The dissociated protons exhibit a strong oxidizing action and cause electrons to be extracted.
4. Dissociated protons or excess protons have a proton jump mechanism that causes energy transfer through hydrogen of water molecules, and therefore show a state of extremely high relative permeability and infiltration.
5. Dissociated protons or excess protons exhibit an electrophilic action in association with the electron reduction of oxygen to the living body and contribute to the transition to the four-electron reduction state.

  In general, in water treatment, cathodic water obtained by applying direct current to water through a diaphragm and being electrolyzed is used as health drinking water. However, the water quality standard for nitrates contained in tap water is 10 mg / L or less, but in practice, Since there is 12 to 15 mg / L, the action of electrolytic cathodic water is shown to have an action of reducing the nitrate ion concentration to 10 mg / L or less as shown by graph 1 in FIG. Water is used as water to lower nitrate ions.

As shown in the graph 2 of FIG. 9, the electrolytic cathodic water is obtained by adding the nutrients vitamin C, catechin, and dehydrated quercetin to the chemical alkaline water and the cathodic water to verify the antioxidant effect. Unlike the substance alkaline water, it has been shown to be antioxidant against the nutrient substance.
Symbol: The symbol for AsA / Q / C is added to alkaline water.
Rw + ASA / Rw + Q / Rw + C is added to the cathode water.
Symbol of each nutrient substance AsA: L monoascorbic acid (vitamin C)
C: Catechin Q: Dehydrated quercetin Evaluation: Antioxidation of alkaline water and cathodic water was not observed, but the beneficial effect of the antioxidant action was recognized with the nutritional additive in cathodic water.

  The important thing is that about 2L of water is drunk every day, and our body has 60% of water, so the role of water is utilized in the body by biophysical chemistry. While the mitochondria present in these cells generate energy and provide it to the nucleus of the cell, the substance in which active oxygen is generated in the cell is released into the sea of blood and circulated throughout the body. Therefore, there is a need for drinking water to seek antioxidant water.

Furthermore, it is considered that biological enzymes are produced in cells of all organs and correspond to active oxygen. In other words, the biological enzyme induces protons (H ⁺ ) by the action of electrons (e−) from biological water, responds to active oxygen, and promotes the immune mechanism. For example, electron transfer in the mitochondrial respiratory chain is a continuous reaction, when an electron is transferred from one component to the next and many of these components change from oxidized to reduced, only one Only the above electrons can be obtained, but one other component can generate one or more ionizations on the molecule by obtaining the electrons, increasing the dissociation of the group. Stick.
For example, cytochrome c (cytc) undergoes 1e ^- reduction:
^{Fe3 + -cytc + 1e = Fe 2} + -cytc (-350mV)
The reductase NAD ⁺ undergoes 2e ⁻ reduction to yield one H ⁺ .
NAD ⁺ + 2e ⁻ + H ⁺ = NADH
However, ubiquinone undergoes 2e ⁻ reduction, and then 2H ⁺ is added and 2H is transmitted.
UQ + 2e ⁻ + 2H ⁺ = UQH ₂
For this reason, in oxygen metabolism, protons are supplied by converting the oxidized form to the reduced form through the electron transport system, so it is necessary to make extensive use of proton donors and cathodic water proton donors from water and nutrients. It suggests. Therefore, since our bodies are utilized according to moisture, we need water's original functionality, that is, seeking antioxidant water and antibacterial effects in the digestive tract. The selection technology is important.

For the maintenance of health maintenance, the function corresponding to the active oxygen of water and vitamin C and polyphenols from plants were considered. However, problems of foods is Bifuzusu bacteria good bacteria exist good bacteria and bad bacteria in the small intestine is superoxide in the intestine ^- is reduced (O ₂ ^·) in hydrogen peroxide (H 2 _{O 2)} .

  For the maintenance of health maintenance, the function corresponding to the active oxygen of water and vitamin C and polyphenols from plants were considered. However, in order to protect cells, the small intestine generates hydrogen peroxide to respond to superoxide, and generates hydroxy radicals (.OH) that are acidic substances in the intestine, causing carcinogenicity. Therefore, drinking water for health needs a method for suppressing active oxygen with electrolyzed water and an antioxidant for protecting the small intestine.

  An object of the present invention is to provide an antioxidant water capable of suppressing active oxygen with electrolyzed water and exhibiting antioxidant performance, and a method for producing the same.

Since the present invention is to achieve the above object, the first, in which silver ion water produced using a silver electrode in the electrolytic dissociation water is contained, the raw water is filtered, the cathode water produced in the electrolyzer It was confirmed that 50 to 100 ppb of silver ion water generated using a silver electrode was mixed with water in a proton donor of dissociated hydroxide ions (OH ⁻ ) having a pH of 8 to 10 to eliminate hydroxy radicals (.OH). It is a summary.

Second, the raw water is filtered, the water produced 50~100ppb electrolytic silver ionized water, in which electrolyzed in electrolyzer, and summarized in that a mixture of anode water and cathode water produced by the electrolytic device is there.

According to the present invention, the antioxidant action by electrolyzed anode water dissociated protons (H ⁺ ) and the hydroxyl group (OH) dissociated by cathode water supplement the hydroxyl groups of vitamin C and polyphenols to induce protons to induce active oxygen. It can be made to correspond.

Moreover, when low concentration electrolytic silver ions are mixed with anode water or cathode water, in addition to sterilization and antibacterial action, by mixing electrolytic silver ion water (Ag ⁺ ) with electrolytic water, hydroxy radicals (.OH) can be mixed. Can be erased and protect the small intestine.

Electrolyzed water includes anode water and cathode water. Superoxide active oxygen in these electrolytic water ^- when mixing (O ₂ ^·), hydroxyl radicals, (· OH), although the cathode water is not in the superoxide scavenging is observed, the anode water is superoxide (O ^- ₂ ^- ) Can be erased as shown in the graph of FIG.

Thus the anode water dissociation (isolated) was ^{(H +)} ions, in the water of pH 3-6, superoxide (O ^- ₂ ^·), hydroxyl radicals, (· OH) is erased active oxygen silver ions with exposure it can. However, in the range of pH 3 to 6, there is no problem with pH 3, but in the case of pH 6, the pH becomes neutral and unstable after a long time, and the addition of silver ions is required.

  Embodiments of the present invention will be described below. First, the method for producing antioxidant drinking water according to the present invention will be described. FIG. 1 shows a first embodiment, in which electrolysis is performed with an electrolysis apparatus 1 in which tap water is silver as an anode, and this is filtered with a filter 2. After filtration, water flows into the electrolytic anode chamber and the electrolytic cathode chamber of the electrolysis generator 3 to generate anodic silver water and cathodic silver water.

  FIG. 2 shows a second embodiment. After filtering with a filter 2, electrolysis is performed with an electrolysis generator 3, and electrolysis cathode water is subjected to silver electrolysis among the generated electrolysis anode water and electrolysis cathode water, thereby producing cathode silver. Water was produced.

  FIG. 3 shows a third embodiment, in which silver electrolysis is performed as in the first embodiment, and after filtration, silver water is produced by mixing anode water and cathode water.

  The drinking water produced in this manner is one containing silver ion water obtained by electrolytic silver ion water in electrolytic dissociated water, that is, antioxidant water obtained by adding silver ions to electrolytic dissociated water.

The present invention provides, as a first embodiment, the raw water is filtered, superoxide dissociated protons (H ⁺⁾ in the active oxygen pH3~6 anode water produced by the electrolytic generator 3 (O ^- ₂ ^·) Ya It is an antioxidant drinking water that eliminates hydroxy radicals (.OH).

As a second embodiment, the drinking water generated in FIG. 2 is filtered into the water in the proton donor of dissociated hydroxide ions (OH ⁻ ) of pH 8 to 10 cathodic water generated by electrolysis by filtering raw water. Antioxidant drinking water in which 50 to 100 ppb of silver ion water is mixed using a silver electrode to remove hydroxy radicals (.OH).

  As a third embodiment, the drinking water generated in FIG. 3 is an antioxidant beverage obtained by filtering raw water and mixing 50 to 100 ppb of electrolytic silver ion water with anodic water and cathodic water generated by an electrolyzer. It is water.

  There is a choice between silver nitrate water and hydrochloric acid mixed with silver nitrate to produce silver chloride, or silver ion or electrolysis using silver as an anode. In order to generate active oxygen due to the above, the drinking water was determined as electrolytic silver ion water.

原水の電気伝導度：７．１２ｍＳ／ｍ 温度１３．３°Ｃ The silver ion concentration by electrolysis is shown in Table 1 below.

Raw water electrical conductivity: 7.12 mS / m Temperature 13.3 ° C

  The Ministry of Health, Labor and Welfare has approved the electrolyzer for drinking water that requires 2 liters every day, but the generated alkaline ionized water is recognized as water for gastric hyperacidity, chronic diarrhea, dyspepsia, and abnormal gastrointestinal fermentation. .

  In addition, water with high alkalinity is considered to have other important functions of preventing cellular aging and blood vessel coins, and therefore, cathodic water using an electrolyzer has been pointed out as drinking water.

  Furthermore, in recent years, diseases caused by heavy metals contained in foods, side effects of drugs, and mental stress have been pointed out medically, and sportsmen and the like are injured due to the amount of oxygen they breathe. These reactions have been known as biotoxins in the past, but in recent years, oxygen-added enzymes have been discovered through research on oxidation-reduction reactions and expressed as “active oxygen”.

This oxidation-reduction reaction is generally known to oxidize when there is a lot of oxygen (O ₂ ), and to reduce when there are a lot of electrons (e ⁻ ) and protons (H ⁺ ). Since these electrons and hydrogen (protons) work and our biological enzymes work smoothly, they show an important role.

In order to eliminate the active oxygen from the oxidation-reduction reaction, the 4-electron / 4-proton reduction generated in the living body is examined from the contents shown in FIG. 6. For example, oxygen (O ₂ ) by respiration is an electron (e ^- ) Is received and superoxide (O ^- ₂ ^· ) having one electron is generated. The superoxide (O ^- ₂ ^·) to the 2H ⁺ is given hydrogen peroxide _(H 2 _{O 2)} it is next to immunization.

  Since the water electrolysis device causes an oxidation-reduction reaction, it is generated by filtering chlorine such as tap water and applying a direct current through a diaphragm. When water is electrolyzed, an oxidation-reduction reaction occurs in the same manner as a phenomenon occurring in the living body, so that it can become drinking water depending on the purpose.

When the positive electrode anode water electrolyzed in this way is neutralized with caustic soda rather than mere acidic water, the hydrochloric acid (HCL) of the electrolytic anode water is different from the chemical hydrochloric acid as shown in the graph 3 of FIG. According to Formula 1, there are protons (H ⁺ ) dissociated as salt water (NaCL).
H ₂ O + HCL + NaOH → H ₂ O + NaCL + (H ⁺ ) 1
Using this anode water, superoxide active oxygen in an electron spin resonance apparatus ^- is characterized to be deleted to give the (O ₂ ^·), hydroxyl radicals, (· OH).

The dissociated proton (H ⁺ ) can also be expressed as an “isolated proton”, and the isolated proton is generated by an oxidation-reduction reaction by electrolysis of water. When the alkali metal salt is present in the electrolyte solution, the alkali metal salt It is shown only as a conjugated acid. Only conjugated acids are involved in the neutralization reaction. Since isolated protons do not react with basic substances, they exist relatively stably and show a strong electrophilic action. Therefore, it reacts in an ion-bonding manner with an oxygen compound having an unpaired electron that is a free radical, thereby changing the high energy level to a stable low energy level and deactivating active oxygen.

Isolated protons form proton jumps for water-soluble radicals through hydrogen atoms of the hydrated water molecules of isolated protons, dramatically increasing the reaction rate and inactivating active oxygen. Compared to cathodic water, isolated hydroxyl groups (OH ⁻ ) bind to fat-soluble and water-soluble radicals, and isolated protons (H ⁺ ) mainly form ionic bonds with water-soluble radicals. Isolated protons play an important role in the wound healing process.

On the other hand, the negative electrode cathode water is not mere alkaline as shown in the following two formulas, and when neutralized with hydrochloric acid, as shown in graph 4, the electrolytic cathodic water is salt water according to the following formula. Then, dissociated hydroxide ions (OH ⁻ ), that is, proton donors exist.
H ₂ O + NaOH + HCL → H ₂ O + NaCL + (OH ⁻ ) 2
Since the two types of hydroxide ions (OH ⁻ ) have an excess electronic role, they supplement vitamin C having two OHs and polyphenols having a plurality of OHs, and indirectly induce active protons by inducing protons. The electronic feature corresponding to is shown.

The dissociated hydroxyl group (OH ⁻ ) can also be expressed as “isolated hydroxyl group (OH ⁻ )”. Two isolated hydroxyl groups are generated from two molecules of water and do not contribute to pH. The reason for this is that the molar concentration of (OH ⁻ ) is too high, it is not a conjugated base, and other alkali metal salts dissolved in the aqueous solution are reduced to form hydroxyl groups. Is considered to contribute to pH.

  Therefore, the pH to be measured is based only on the hydroxyl group derived from the alkali metal salt. The neutralization reaction with an acid having a conjugated base is only a reaction with a hydroxyl group derived from an alkali metal, and an isolated hydroxyl group does not participate in this neutralization reaction. Since the isolated hydroxyl group does not participate in the neutralization reaction with the acid, it is relatively stable in the acidic region or the basic region, and reacts only with protons, that is, those having a positive charge.

  Therefore, when taken into a living body, it is considered that gastric acid does not decompose or neutralize and blood can move relatively stably.

  Further, since the isolated hydroxyl group does not neutralize the gastric acid, only the isolated hydroxyl group has a characteristic that the pH of the gastric acid is not changed. The antioxidative action of cathodic water is thought to be derived from isolated hydroxyl groups, and the reaction with free radicals is thought to cause electron extraction from isolated hydroxyl groups due to radical unpaired electrons. The chain reaction is thought to be able to prevent, so it seems that the chain reaction to organic matter can be prevented.

  From the above, anodic water obtained by electrolyzing water is different from a simple water purifier, and anodic water can electrochemically correspond to active oxygen.

Cathode water can be indirectly supported by nutrition from food. Therefore, it is considered impossible to obtain the role of H ⁺ and OH ⁻ by simply filtering raw water such as tap water and well water. Water is expected as antioxidant water.

  However, in the electrolyzed solution, it is possible to cope with the active oxygen by adding silver ion water because cathodic water cannot directly correspond to the active oxygen.

Despite the noble metals, silver is rich in reactivity and has an excellent catalytic action. Silver is easy to colloid and is in an extremely stable colloidal form in an aqueous solution. From the physical point of view, it is an ultrafine particle and therefore has a very high catalytic activity and promotes oxidation of water. In the case of electrolysis using tap water, since sulfate is present, it becomes beloxodisulfate ion (S ₂ O ² ₈ ⁻ ), and silver ions have been confirmed to react as shown in the following formulas 3-9. Yes.
^{_{S 2 O 2 8 - + Ag}} + → Ag 2 + + SO 2 4 - ... 3
^{_{H 2 O + SO - 4 ·}} → · OH + HSO - 4 ... 4
_{^{Ag + + · OH → Ag 2}} + + OH - ... 5
^{_{Ag + + SO - 4 · →}} Ag 2 + + SO 2 4 - ... 6
2Ag ² + → Ag ⁺ + Ag ³ ₊ ... 7
Ag ³ ₊ + H ₂ O → AgO ⁺ + 2H ⁺ ... 8
AgO ⁺ → Ag ⁺ +1/20 ₂ ... 9

The silver ion concentration is kept constant and acts as a homogeneous catalyst. The entire reaction is H ₂ O + S ₂ O ² ₈ ⁻ → 2SO ² ₄ ⁻ + 2H ⁺ + 1 / 2O ₂
It is.

The rate of decrease of peroxodisulfate ion (S ₂ O ² ₈ ⁻ ) and the rate of O ₂ production follow the following equations.
−d [S ₂ O ² ₈ ⁻ ] / dt = 2d [O ₂ ] = kobsd [S ₂ O ² ₈ ⁻ ]
In the course of more reaction _{proceeds, S} 2 O ^- may contain ₄ ^{·, ·} OH, _{Ag 2+} and Ag ³ ₊ cooperation oxidizing radicals such as.

  Accordingly, since the high concentration of silver ions has a strong catalytic activity, the reaction proceeds using sulfate ions as initiators. When colloidal silver ions reach bacteria, if an initiator is present in the vicinity of the bacteria, strong oxidative radicals are generated and controlled by causing damage. Unlike chlorination with amino groups like chlorination, colloidal silver ions have the characteristic that the reaction continues continuously even with a high protein concentration if an initiator is present.

On the other hand, silver ion water has a bactericidal effect depending on the concentration, but antioxidation is expected even at a low concentration by electrolyzing silver. However, if a high concentration of silver ions is drunk, for example, silver rot has been reported in the case of taking 1,200 to 1,300 silver grains for 3 years a day. Here, since the American FDA is approved as drinking water even if the silver ion concentration of 50 ppb to 100 ppb is added to drinking water, the effect on active oxygen was determined within the range of the concentration. Corresponding to the superoxide (O ^- ₂ ^· ) of active oxygen required for 4 electrons and 4 protons in FIG. 6 with silver ion water of electrolyzed cathodic water, in the superoxide, the silver ion water from the graph 5 shown in FIG. When measured with an electron spin resonance apparatus, it can be seen that the antioxidant effect is not confirmed.

In order to solve the active oxygen of the above-mentioned problem, when a hydroxy radical (.OH) that causes disease progression is obtained, antioxidation is expected according to the following formula 5, and the hydroxy radical is reduced to a hydroxide ion (OH ⁻ ).
^{Ag + + · OH → Ag 2} + + OH - ... 5
That is, when silver ion water was mixed with cathodic water, the antioxidation action of the hydroxy radical was determined by an electron spin resonance apparatus (ESR), and an erasing action was observed. Further, the storage property of silver ion water is stable as shown in the graph of FIG.

  From the above, apart from sterilization, silver ion water is characterized by the fact that the reaction of hydroxy radicals to active oxygen is studied by using electrolyzed silver ion water as the electrolyzed water of bipolar water. Therefore, it is improved as antioxidant water.

Electrolyzed water includes anode water and cathode water. Superoxide active oxygen in these electrolytic water ^- when mixing (O ₂ ^·), hydroxyl radicals, (· OH), although the cathode water is not in the superoxide scavenging is observed, the anode water is superoxide (O ^- ₂ ^The characteristic that.) Is deleted from the graph of FIG. 14 is shown. The measuring method was verified with an electron spin resonance apparatus (SOD).

  When silver ion water was added to the anode water or the cathode water, the removal of the hydroxy radical (.OH) showed the feature of removing the hydroxy radical from the graph of FIG.

  From the above, it was shown that the anode water and cathode water of electrolyzed water to which silver ions of the present invention were added erased hydroxy radicals (.OH) of active oxygen.

When using the electrolytic anodized water of the present invention to cause burns and bed slips caused by skin damage, and also to the damaged part after surgery, radical bilane can be produced without using antibiotics from 200 cases against therapeutic drugs. It did not occur and the treatment was reported to be 100%. This is characterized by the radical elimination of protons (H ⁺ ) because the bilan component generates radicals.

In addition, cases in which urination or defecation is performed tens of minutes later when anodized water is consumed as drinking water when liver cancer causes a phenomenon in which water cannot accumulate and urinate cannot be excreted after surgery for liver cancer patients Was reported. This is thought to be due to the fact that anodic water was effective because of the lack of acidic substances in the kidney and the amide group not being detoxified by amino acids. On the other hand, defecation usually has a pH of about 6 or 5, and it was considered that the pH contributed by the consumption of protons (H ⁺ ) of acidic water in the anode water.

評価：点滴前後の犬から採血した血液（血漿）を、電子スピン共鳴装置にてＳＯＤ活性を測定すると陰極水の点滴後は血液の抗酸化能（ＳＯＤ）が高まっていた。さらに、陰極水を中和した銀イオン水を１００ｐｐｂ添加して犬の血液を調査すると、「１６，８units/ml」になった。これは陰極水が犬の血液に含まれる栄養の影響でスーパーオキサイド（Ｏ⁻ _２ ^・）に寄与した特徴が示された。 Antioxidant activity of blood when electrolytic cathodic water is instilled into dogs.
Conditions: Saline neutralized cathodic water was instilled into dogs as shown in Table 2 below, and SOD activity was examined.

Evaluation: When blood (plasma) collected from dogs before and after infusion was measured for SOD activity using an electron spin resonance apparatus, the antioxidant capacity (SOD) of blood increased after infusion of cathodic water. Further, when 100 ppb of silver ion water neutralized with cathodic water was added and the blood of the dog was examined, it was “16,8 units / ml”. This cathode water superoxide influence nutrient contained in dog blood ^- features that contributed to (O ₂ ^·) is shown.

Name of pilot study in which cathodic water of silver ion water was drunk in dog Name of disease: Canine lymphosarcoma (weight 19 kg)
Test item: white blood cell count, platelet drinking condition: 950 ml / day drinking result: 3 months later, appetite, energy recovery Figure 16 shows the graph.

Steroid hepatitis (weight: 22 kg) in a pilot study dog that allowed the dog to drink silver ion water cathode water
Test item: ALP value (alkaline phosphatase)
Drinking conditions: 1.100 ml / day drinking result: ALP value decreases after 3 months FIG. 17 shows the graph.

A test of mutans, an oral bacterium, was performed with a solution obtained by adding 100 ppb of silver ion water to anodized water.
Number of control bacteria: 5.8 × 10 ⁵
Bactericidal effect: 2,5 × 10 ^{3 in} 1 minute: 0 in 5 minutes.

  Diabetes is indicated by a blood glucose value (75-116 mg / dl), but to investigate other diseases, smokers with the new prostaglandin F2α also tested non-smokers and diabetes tests. FIG. 18 shows the graph.

The average improvement for prostaglandins is around 200 pg / mg.
The peak value on day 42 is the result of having diabetics stop drinking cathodic water and eat sweet candy. In addition, both smokers and non-smokers stopped drinking cathodic water and smoked. This is an example of a report that the cathode water was reduced after that when the cathodic water was drunk.

  From the above results, when the cathodic water added with silver ion water was drunk, the value of diabetes was stable at 80 mg / dl or less even after 3 to 5 months.

  A gastric ulcer caused by Helicobacter pylori was reported to have been completely cured after drinking silver ion water of cathodic water for 7 days in a hospital. In addition, gastric ulcer was completely cured in 5 days after the silver ion water of anodic water was taken by three other patients.

A clinical doctor's report when the patient is given drinking water in which 50 ppb of silver ion water is added to the cathode water is shown below.
1. Salivary nitrate / nitrite test. 2L / day drinking. Test result after 2 days.
2. Acetaldehyde test (alcohol) ··· Drinking whiskey 30cc · After drinking cathodic water 1L / 1H ··· 0.01 mg / L or less.
3. Blood sugar level ··· 2-3L / day drinking ··· Examination after 1-2 months ·· Tend to improve to normal.
4. Uterine cancer clinical ・ First stage symptoms ・ After 6 months of drinking ・ Completely cured.
5. Bacterial examination in the mouth ··· Long-time drinkers · · No spirocheter (alveolar pyorrhea) is detected.
6. The amniotic fluid of pregnant women-The amniotic fluid of pregnant women drinking cathodic water is transparent-The baby has no jaundice symptoms.
7. Liver disease test ・ After half a year of drinking ・ GOT and GPT are improving.

It is explanatory drawing which shows 1st Embodiment of the manufacturing method of the antioxidant drinking water of this invention. It is explanatory drawing which shows 2nd Embodiment of the manufacturing method of the antioxidant drinking water of this invention. It is explanatory drawing which shows 3rd Embodiment of the manufacturing method of the antioxidant drinking water of this invention. It is a matrix that produces the current water. It is explanatory drawing of the vitamin C corresponding to the active oxygen of nutrition. It is explanatory drawing of hydrogen peroxide. It is a chemical formula showing polyphenols having many hydroxyl groups. It is a graph of a nitrate ion removal test. It is a graph which shows each antioxidant action of cathode water and alkaline water. It is a graph which shows the neutralization characteristic of anode water. It is a graph which shows the neutralization characteristic of anode water. It is a graph of silver ion water measured with the electron spin resonance apparatus. It is a graph which shows the characteristic of the preservability of silver ion water. It is a graph which shows a mode that the superoxide (O ^- ₂ ^* ) of anodic water at the time of mixing superoxide (O ^- ₂ ^* ) and hydroxy radical (* OH) of active oxygen in electrolyzed water erase | eliminates. It is a graph which shows erasure | elimination of the hydroxy radical (* OH) at the time of adding silver ion water to anode water or cathode water. It is a graph which shows the result of the pilot test which made the dog drink the cathode water of silver ion water. It is a graph which shows the result of the pilot test which made the dog drink the cathode water of silver ion water. It is a graph of the result of having verified the test of the smoker by the new prostaglandin F2 (alpha), a non-smoker, and diabetes.

DESCRIPTION OF SYMBOLS 1 ... Electrolyzer which made silver the anode 2 ... Filter 3 ... Electrolytic generator

Claims (6)

  Antioxidant drinking water characterized by containing silver ion water produced by using a silver electrode in electrolytically dissociated water. The raw water is filtered, and 50 to 100 ppb of silver ion water generated using a silver electrode is mixed with water in the proton donor of dissociated hydroxide ions (OH ⁻ ) having a pH of 8 to 10 generated by the electrolysis apparatus. The antioxidant drinking water according to claim 1, wherein the hydroxy radical (.OH) is eliminated.   The antioxidant drinking water according to claim 1, wherein raw water is filtered and water in which 50 to 100 ppb of electrolytic silver ion water is generated is electrolyzed in an electrolytic device, and the anode water and the cathode water generated in the electrolytic device are mixed.   A method for producing antioxidant drinking water, wherein silver electrolysis is performed, and after filtration, water is poured into an electrolytic anode chamber and an electrolytic cathode chamber of an electrolysis generator to produce anodic silver water and cathodic silver water.   A method for producing antioxidant drinking water, characterized in that, after filtration, silver electrolysis is performed on electrolytic cathodic water produced by an electrolysis production device to produce cathodic silver water.   A method for producing antioxidant drinking water, wherein silver electrolysis is performed and silver water is produced by mixing anode water and cathode water after filtration.

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