JP2014117186A - Milk beverage having reduced deviation of component during refrigeration storage - Google Patents
Milk beverage having reduced deviation of component during refrigeration storage Download PDFInfo
- Publication number
- JP2014117186A JP2014117186A JP2012272397A JP2012272397A JP2014117186A JP 2014117186 A JP2014117186 A JP 2014117186A JP 2012272397 A JP2012272397 A JP 2012272397A JP 2012272397 A JP2012272397 A JP 2012272397A JP 2014117186 A JP2014117186 A JP 2014117186A
- Authority
- JP
- Japan
- Prior art keywords
- milk
- cellulose
- mass
- beverage
- shaking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000020124 milk-based beverage Nutrition 0.000 title claims abstract description 57
- 238000003860 storage Methods 0.000 title claims abstract description 36
- 238000005057 refrigeration Methods 0.000 title abstract description 3
- 239000001913 cellulose Substances 0.000 claims abstract description 67
- 229920002678 cellulose Polymers 0.000 claims abstract description 66
- 235000013336 milk Nutrition 0.000 claims abstract description 43
- 239000008267 milk Substances 0.000 claims abstract description 43
- 210000004080 milk Anatomy 0.000 claims abstract description 43
- 239000007787 solid Substances 0.000 claims abstract description 19
- 239000002131 composite material Substances 0.000 claims description 33
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 10
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 9
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 9
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 9
- 102000014171 Milk Proteins Human genes 0.000 claims description 8
- 108010011756 Milk Proteins Proteins 0.000 claims description 8
- 235000013353 coffee beverage Nutrition 0.000 claims description 8
- 108010046377 Whey Proteins Proteins 0.000 claims description 7
- 102000007544 Whey Proteins Human genes 0.000 claims description 7
- 235000016213 coffee Nutrition 0.000 claims description 7
- 239000000284 extract Substances 0.000 claims description 7
- 235000021239 milk protein Nutrition 0.000 claims description 7
- 235000019543 dairy drink Nutrition 0.000 claims description 6
- 239000005862 Whey Substances 0.000 claims description 5
- 239000005018 casein Substances 0.000 claims description 4
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 4
- 235000021240 caseins Nutrition 0.000 claims description 4
- 241001122767 Theaceae Species 0.000 claims 1
- 239000000796 flavoring agent Substances 0.000 abstract description 14
- 235000019634 flavors Nutrition 0.000 abstract description 13
- 235000013361 beverage Nutrition 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 230000002776 aggregation Effects 0.000 description 11
- 239000011575 calcium Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 10
- 229960005069 calcium Drugs 0.000 description 10
- 229910052791 calcium Inorganic materials 0.000 description 10
- 239000007788 liquid Substances 0.000 description 10
- 235000002639 sodium chloride Nutrition 0.000 description 10
- 238000004220 aggregation Methods 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 229920006184 cellulose methylcellulose Polymers 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 239000000499 gel Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 7
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 7
- 230000035622 drinking Effects 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 238000004062 sedimentation Methods 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 230000001954 sterilising effect Effects 0.000 description 7
- 238000004659 sterilization and disinfection Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 5
- 244000269722 Thea sinensis Species 0.000 description 5
- -1 alginate ester Chemical class 0.000 description 5
- 239000001110 calcium chloride Substances 0.000 description 5
- 229910001628 calcium chloride Inorganic materials 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 239000006071 cream Substances 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 229920001477 hydrophilic polymer Polymers 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000013049 sediment Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 235000010418 carrageenan Nutrition 0.000 description 4
- 239000000679 carrageenan Substances 0.000 description 4
- 229920001525 carrageenan Polymers 0.000 description 4
- 229940113118 carrageenan Drugs 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 238000000265 homogenisation Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 229920001542 oligosaccharide Polymers 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000000346 sugar Nutrition 0.000 description 4
- 229920001285 xanthan gum Polymers 0.000 description 4
- 235000010493 xanthan gum Nutrition 0.000 description 4
- 239000000230 xanthan gum Substances 0.000 description 4
- 229940082509 xanthan gum Drugs 0.000 description 4
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 4
- 229920001353 Dextrin Polymers 0.000 description 3
- 239000004375 Dextrin Substances 0.000 description 3
- 235000010443 alginic acid Nutrition 0.000 description 3
- 229920000615 alginic acid Polymers 0.000 description 3
- 238000005520 cutting process Methods 0.000 description 3
- 235000019425 dextrin Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000006266 etherification reaction Methods 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 229920000591 gum Polymers 0.000 description 3
- 235000010449 maltitol Nutrition 0.000 description 3
- 239000000845 maltitol Substances 0.000 description 3
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 3
- 229940035436 maltitol Drugs 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 235000018102 proteins Nutrition 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- HDTRYLNUVZCQOY-UHFFFAOYSA-N α-D-glucopyranosyl-α-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(O)C(O)C(CO)O1 HDTRYLNUVZCQOY-UHFFFAOYSA-N 0.000 description 2
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- 229920002148 Gellan gum Polymers 0.000 description 2
- 229920002581 Glucomannan Polymers 0.000 description 2
- 229920002907 Guar gum Polymers 0.000 description 2
- 229920000161 Locust bean gum Polymers 0.000 description 2
- 229930195725 Mannitol Natural products 0.000 description 2
- 229920000881 Modified starch Polymers 0.000 description 2
- 239000004368 Modified starch Substances 0.000 description 2
- 244000090599 Plantago psyllium Species 0.000 description 2
- 235000010451 Plantago psyllium Nutrition 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229930006000 Sucrose Natural products 0.000 description 2
- HDTRYLNUVZCQOY-WSWWMNSNSA-N Trehalose Natural products O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-WSWWMNSNSA-N 0.000 description 2
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 2
- 229940072056 alginate Drugs 0.000 description 2
- HDTRYLNUVZCQOY-LIZSDCNHSA-N alpha,alpha-trehalose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HDTRYLNUVZCQOY-LIZSDCNHSA-N 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 2
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 description 2
- 239000008157 edible vegetable oil Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 235000010492 gellan gum Nutrition 0.000 description 2
- 239000000216 gellan gum Substances 0.000 description 2
- 229940046240 glucomannan Drugs 0.000 description 2
- 235000010417 guar gum Nutrition 0.000 description 2
- 239000000665 guar gum Substances 0.000 description 2
- 229960002154 guar gum Drugs 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 235000010445 lecithin Nutrition 0.000 description 2
- 239000000787 lecithin Substances 0.000 description 2
- 229940067606 lecithin Drugs 0.000 description 2
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 2
- 235000010420 locust bean gum Nutrition 0.000 description 2
- 239000000711 locust bean gum Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 239000000594 mannitol Substances 0.000 description 2
- 235000010355 mannitol Nutrition 0.000 description 2
- 229960001855 mannitol Drugs 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 2
- 235000021243 milk fat Nutrition 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 150000002482 oligosaccharides Chemical class 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 150000004804 polysaccharides Chemical class 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 235000020183 skimmed milk Nutrition 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 229960002920 sorbitol Drugs 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000005720 sucrose Substances 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- 235000021119 whey protein Nutrition 0.000 description 2
- 235000008939 whole milk Nutrition 0.000 description 2
- 239000000811 xylitol Substances 0.000 description 2
- 235000010447 xylitol Nutrition 0.000 description 2
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 2
- 229960002675 xylitol Drugs 0.000 description 2
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 description 1
- 229920001817 Agar Polymers 0.000 description 1
- 108010011485 Aspartame Proteins 0.000 description 1
- 241000283690 Bos taurus Species 0.000 description 1
- 241000282832 Camelidae Species 0.000 description 1
- 241000283707 Capra Species 0.000 description 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- 241000283086 Equidae Species 0.000 description 1
- 241000283074 Equus asinus Species 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 229920000926 Galactomannan Polymers 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 229920000569 Gum karaya Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 239000004384 Neotame Substances 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- HDSBZMRLPLPFLQ-UHFFFAOYSA-N Propylene glycol alginate Chemical compound OC1C(O)C(OC)OC(C(O)=O)C1OC1C(O)C(O)C(C)C(C(=O)OCC(C)O)O1 HDSBZMRLPLPFLQ-UHFFFAOYSA-N 0.000 description 1
- 241000282941 Rangifer tarandus Species 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- 244000228451 Stevia rebaudiana Species 0.000 description 1
- 239000004376 Sucralose Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 240000004584 Tamarindus indica Species 0.000 description 1
- 235000004298 Tamarindus indica Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000000619 acesulfame-K Substances 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000000605 aspartame Substances 0.000 description 1
- 235000010357 aspartame Nutrition 0.000 description 1
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 description 1
- 229960003438 aspartame Drugs 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 235000001465 calcium Nutrition 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical class [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 description 1
- FYGDTMLNYKFZSV-ZWSAEMDYSA-N cellotriose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](OC(O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-ZWSAEMDYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- HEBKCHPVOIAQTA-NGQZWQHPSA-N d-xylitol Chemical compound OC[C@H](O)C(O)[C@H](O)CO HEBKCHPVOIAQTA-NGQZWQHPSA-N 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 235000020669 docosahexaenoic acid Nutrition 0.000 description 1
- 235000020673 eicosapentaenoic acid Nutrition 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013861 fat-free Nutrition 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- CADNYOZXMIKYPR-UHFFFAOYSA-B ferric pyrophosphate Chemical compound [Fe+3].[Fe+3].[Fe+3].[Fe+3].[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])([O-])=O CADNYOZXMIKYPR-UHFFFAOYSA-B 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- FTSSQIKWUOOEGC-RULYVFMPSA-N fructooligosaccharide Chemical compound OC[C@H]1O[C@@](CO)(OC[C@@]2(OC[C@@]3(OC[C@@]4(OC[C@@]5(OC[C@@]6(OC[C@@]7(OC[C@@]8(OC[C@@]9(OC[C@@]%10(OC[C@@]%11(O[C@H]%12O[C@H](CO)[C@@H](O)[C@H](O)[C@H]%12O)O[C@H](CO)[C@@H](O)[C@@H]%11O)O[C@H](CO)[C@@H](O)[C@@H]%10O)O[C@H](CO)[C@@H](O)[C@@H]9O)O[C@H](CO)[C@@H](O)[C@@H]8O)O[C@H](CO)[C@@H](O)[C@@H]7O)O[C@H](CO)[C@@H](O)[C@@H]6O)O[C@H](CO)[C@@H](O)[C@@H]5O)O[C@H](CO)[C@@H](O)[C@@H]4O)O[C@H](CO)[C@@H](O)[C@@H]3O)O[C@H](CO)[C@@H](O)[C@@H]2O)[C@@H](O)[C@@H]1O FTSSQIKWUOOEGC-RULYVFMPSA-N 0.000 description 1
- 229940107187 fructooligosaccharide Drugs 0.000 description 1
- 229960002737 fructose Drugs 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 229940071676 hydroxypropylcellulose Drugs 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 239000000832 lactitol Substances 0.000 description 1
- 235000010448 lactitol Nutrition 0.000 description 1
- VQHSOMBJVWLPSR-JVCRWLNRSA-N lactitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@@H]1O[C@H](CO)[C@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-JVCRWLNRSA-N 0.000 description 1
- 229960003451 lactitol Drugs 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 229960002160 maltose Drugs 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229960002900 methylcellulose Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 235000019412 neotame Nutrition 0.000 description 1
- HLIAVLHNDJUHFG-HOTGVXAUSA-N neotame Chemical compound CC(C)(C)CCN[C@@H](CC(O)=O)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 HLIAVLHNDJUHFG-HOTGVXAUSA-N 0.000 description 1
- 108010070257 neotame Proteins 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 238000006864 oxidative decomposition reaction Methods 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000008476 powdered milk Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 description 1
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 1
- 235000020185 raw untreated milk Nutrition 0.000 description 1
- HELXLJCILKEWJH-NCGAPWICSA-N rebaudioside A Chemical compound O([C@H]1[C@H](O)[C@@H](CO)O[C@H]([C@@H]1O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@]12C(=C)C[C@@]3(C1)CC[C@@H]1[C@@](C)(CCC[C@]1([C@@H]3CC2)C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O HELXLJCILKEWJH-NCGAPWICSA-N 0.000 description 1
- 238000005464 sample preparation method Methods 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000019408 sucralose Nutrition 0.000 description 1
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 239000000892 thaumatin Substances 0.000 description 1
- 235000010436 thaumatin Nutrition 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229940074410 trehalose Drugs 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Dairy Products (AREA)
- Non-Alcoholic Beverages (AREA)
Abstract
Description
本発明は、冷蔵保存中の成分の偏りが少なく、風味が良い乳飲料に関する。 The present invention relates to a dairy drink having a small flavor and having a good flavor during refrigerated storage.
一般にCa強化乳や、ミルクコーヒー、ミルクティーのような乳飲料は、カルシウムを強化するために添加するミルクカルシウムや、乳成分に含まれるたんぱく質・脂肪などが保存中に沈殿や凝集を生じることがある。そのため、乳飲料を安定化させるために、安定剤を添加するなどの方法が取られている。例えば、特許文献1では、ガラクトマンナンやカラギナンと、乳化剤を添加する乳飲料の安定化方法が開示されている。さらに、特許文献2には、乳化剤とセルロース複合体を含有する乳成分入りのコーヒー飲料が開示されている。特許文献3では、アルギン酸プロピレングリコールエステルを含むセルロース複合体が乳飲料の安定化に適していることが開示されている。 In general, in milk beverages such as Ca-enriched milk, milk coffee, and milk tea, milk calcium added to strengthen calcium and proteins and fats contained in milk components may precipitate or aggregate during storage. is there. Therefore, in order to stabilize a milk drink, methods, such as adding a stabilizer, are taken. For example, Patent Document 1 discloses a method for stabilizing a milk beverage in which galactomannan or carrageenan and an emulsifier are added. Furthermore, Patent Document 2 discloses a coffee beverage containing a milk component containing an emulsifier and a cellulose composite. Patent Document 3 discloses that a cellulose composite containing propylene glycol alginate is suitable for stabilizing a milk beverage.
乳飲料の保存中の安定性を向上させるために、前述のような技術は一般的に知られている。しかし、特許文献1は、カラギナンなどに乳成分との反応性があり、その反応で弱いゲルが形成されることにより安定性が向上するものであるため、急冷や、5℃以下に長期保存することにより、ゲルの強度が上がってしまい(凝集が強くなって)味に濃淡が生じてしまって風味が悪くなる傾向があった。特許文献2では乳飲料を安定化させるために、安定剤を多く添加する必要があり、飲み口が重くなる傾向があった。特許文献3では、確かにミルクコーヒーのオイルリングの発生は抑制できるものの、例えば、カルシウム強化乳のような不溶性成分を多く含む乳飲料では、安定剤の添加量が低い場合は沈降を起こし、高い添加量では、凝集を生じる場合があった。さらに、これまでの技術では、いずれも、乳飲料を製造直後に急冷却したり、5℃以下で長時間冷蔵保存することにより、安定剤と乳成分の凝集(ゲル化)が促進されてしまい、乳成分の沈殿を生じたり、上部と下部で味の濃さが違いを生じることがあった。 In order to improve the stability during storage of milk beverages, such techniques are generally known. However, in Patent Document 1, since carrageenan and the like are reactive with milk components, and a weak gel is formed by the reaction, stability is improved. As a result, the gel strength increased (aggregation became stronger), and there was a tendency for the taste to become darker and the flavor to deteriorate. In patent document 2, in order to stabilize a milk drink, it was necessary to add many stabilizers, and there was a tendency for a drinking mouth to become heavy. In Patent Document 3, although the occurrence of an oil ring of milk coffee can surely be suppressed, for example, in a milk beverage containing a large amount of insoluble components such as calcium-enriched milk, sedimentation occurs when the amount of stabilizer added is low, and is high. Aggregation may occur at the added amount. Furthermore, in all of the conventional techniques, aggregation of the stabilizer and milk components (gelation) is promoted by rapidly cooling the milk drink immediately after production or by refrigerated storage at 5 ° C. or lower for a long time. In some cases, precipitation of milk components occurs, and the intensity of the taste differs between the upper and lower parts.
本発明では、風味が良好で、急冷却したり、5℃以下で長時間冷蔵保存してもゲルを生じにくく、均一で安定性の高い乳飲料を提供することを目的とする。 An object of the present invention is to provide a uniform and highly stable milk beverage that has a good flavor, does not easily form a gel even if it is rapidly cooled or refrigerated at 5 ° C. or lower for a long time.
本発明者らは、前記課題を解決するために鋭意検討した結果、セルロースを用いて飲料の粘弾性を特定の範囲にコントロールすることにより、風味が良好で、急冷却したり5℃以下で長時間冷蔵保存してもゲルを生じにくい、より均一で安定性の高い乳飲料が出来ることを見出し、本発明を成すに至った。
すなわち、本発明は以下の通りである。
(1)乳固形分を0.5〜20質量%、セルロースを0.05〜0.4質量%含み、振盪直後の5℃におけるtanδが1.55〜2.40である乳飲料。
(2)前記セルロースが、1質量%で分散して1時間放置後の分散液の25℃における貯蔵弾性率(G’)が0.3Pa以上であるセルロース複合体である、(1)に記載の乳飲料。
(3)前記セルロース複合体中に、少なくとも一種類のカルボキシメチルセルロースナトリウムを含み、セルロースとカルボキシメチルセルロースナトリウムの質量比が80/20〜95/5である、(2)に記載の乳飲料。
(4)前記乳飲料が、二価の塩を0.15mmol/L以上添加されたものである、(1)〜(3)のいずれかに記載の乳飲料。
(5)乳タンパクのホエイ/カゼインの質量比が3/7〜2/1である、(1)〜(4)のいずれかに記載の乳飲料。
(6)さらにコーヒー抽出物又は紅茶抽出物を含む、(1)〜(5)のいずれかに記載の乳飲料。
(7)振盪直後の5℃におけるtanδが2.4以下で、かつ、振盪直後の貯蔵弾性率(G’)と振盪後に5℃で5時間静置後の貯蔵弾性率(G’)の比率を測定した時に、(5時間後のG’)/(振盪直後のG’)の値が0.95〜1.20である乳飲料。
As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention controlled the viscoelasticity of a beverage within a specific range using cellulose, and thus the flavor was good, and it was rapidly cooled or long at 5 ° C. or less. It has been found that a more uniform and highly stable milk beverage can be obtained that is less likely to form a gel even when stored for refrigeration for a long time, and the present invention has been accomplished.
That is, the present invention is as follows.
(1) A milk beverage containing 0.5 to 20% by mass of milk solids and 0.05 to 0.4% by mass of cellulose and having a tan δ at 5 ° C. of 1.55 to 2.40 immediately after shaking.
(2) The cellulose composite according to (1), wherein the cellulose is a cellulose composite having a storage elastic modulus (G ′) at 25 ° C. of 0.3 Pa or more after being dispersed at 1% by mass and allowed to stand for 1 hour. Milk drink.
(3) The milk beverage according to (2), wherein the cellulose composite contains at least one kind of sodium carboxymethylcellulose, and a mass ratio of cellulose to sodium carboxymethylcellulose is 80/20 to 95/5.
(4) The milk beverage according to any one of (1) to (3), wherein the milk beverage is a divalent salt added in an amount of 0.15 mmol / L or more.
(5) The milk beverage according to any one of (1) to (4), wherein the whey / casein mass ratio of milk protein is 3/7 to 2/1.
(6) The milk beverage according to any one of (1) to (5), further comprising a coffee extract or a tea extract.
(7) Ratio of tan δ at 5 ° C. immediately after shaking of 2.4 or less and storage elastic modulus (G ′) immediately after shaking and storage elastic modulus (G ′) after standing at 5 ° C. for 5 hours after shaking A milk beverage having a value of (G ′ after 5 hours) / (G ′ immediately after shaking) of 0.95 to 1.20.
本発明により、風味が良好で、急冷却したり5℃以下で長時間冷蔵保存してもゲルを生じにくく、均一で安定性の高い乳飲料を提供できる。 According to the present invention, it is possible to provide a uniform and highly stable milk beverage that has a good flavor and is less likely to form a gel even when rapidly cooled or refrigerated at 5 ° C. or lower for a long time.
本発明でいう乳飲料とは、カルシウム強化乳、ミルクコーヒー、ミルクティー、抹茶ミルクなどの乳成分を少なくとも一種類含む飲料であって、乳固形分を0.5〜35質量%含むものをいう。好ましくは、5〜30質量%、より好ましくは10〜25質量%である。ここでいう乳成分とは、牛、ラクダ、ロバ、ヤギ、ウマ、トナカイ、羊、水牛、ヤクなどから得られる乳(ミルク)そのものや、それらを加工して得られる濃縮乳、還元乳、乳タンパク、ミルクカルシウム、生クリーム、バター、乳糖、脱脂粉乳、全脂粉乳のことを言う。また、乳固形分とは、無脂乳固形分(乳タンパクを主成分とする乳脂肪以外の固形分)と乳脂肪分との合計をいう。乳固形分中の乳タンパクの割合は10質量%以上が好ましい。より好ましくは20質量%以上である。上限は特になく、乳固形分がすべて乳タンパク質であっても構わない。 The milk beverage as used in the present invention refers to a beverage containing at least one kind of milk component such as calcium-enriched milk, milk coffee, milk tea, and matcha milk, and containing 0.5 to 35% by mass of milk solids. . Preferably, it is 5-30 mass%, More preferably, it is 10-25 mass%. The milk component here means milk (milk) obtained from cows, camels, donkeys, goats, horses, reindeers, sheep, buffalos, yaks, etc., and concentrated milk, reduced milk, milk obtained by processing them. It means protein, milk calcium, fresh cream, butter, lactose, skim milk powder, and whole milk powder. Moreover, milk solid content means the sum total of non-fat milk solid content (solid content other than milk fat which has milk protein as a main component) and milk fat content. The ratio of the milk protein in the milk solid content is preferably 10% by mass or more. More preferably, it is 20 mass% or more. There is no particular upper limit, and all milk solids may be milk protein.
本発明では、セルロースを0.05〜0.4質量%含ませ、且つ乳飲料の振盪直後の5℃におけるtanδを1.55〜2.30とすることにより、軽い飲み口を維持したままで、急冷却したり5℃以下で長時間冷蔵保存してもゲルを生じにくい、より均一で安定性の高い乳飲料となる。 In the present invention, by containing 0.05 to 0.4% by mass of cellulose and tan δ at 5 ° C. immediately after shaking of the milk drink is set to 1.55 to 2.30, the light drinking mouth is maintained. Even when rapidly cooled or refrigerated at 5 ° C. or lower for a long period of time, it becomes a more uniform and highly stable milk beverage that is less prone to gel formation.
本発明のセルロース複合体とは、セルロースと親水性高分子を湿式混合することにより得られるものをいう。親水性高分子としては、例えば、カルボキシメチルセルロースナトリウム、カルボキシメチルセルロースカルシウム、メチルセルロース、ヒドロキシプロピルセルロース、ヒドロキシメチルセルロース、キサンタンガム、グルコマンナン、カラヤガム、カラギナン、ローカストビーンガム、グアガム、サイリウムシードガム、アルギン酸エステル、ジェランガムなどが挙げられる。セルロースの複合体として用いる親水性高分子は一種類でも複数種類を併用しても構わない。特に、高い貯蔵弾性率(G’)を示す傾向があるカルボキシメチルセルロースナトリウムを複合体成分として用いたセルロース複合体が好ましい。セルロース複合体に用いるカルボキシメチルセルロースナトリウムは一種類でも複数を混合しても構わない。ここでいう、カルボキシメチルセルロースナトリウムとは、セルロースを主原料としたアニオン性の水溶性高分子であり、一般的にCMC・Naと呼ばれているものである。セルロースとカルボキシメチルセルロースナトリウムの比率(質量比)は、80/20〜95/5であることが特に好ましい。より好ましくは、85/15〜93/7である。セルロース複合体に用いるカルボキシメチルセルロースナトリウムのエーテル化度は特に制限はないが、0.3〜1.5が好ましい。より好ましくは0.6〜1.3である。カルボキシメチルセルロースナトリウムのエーテル化度とは、セルロースの無水グルコース単位あたりのカルボキシメチル基の置換度のことを言う。無水グルコース単位1個あたりには、水酸基は3個あるので、エーテル化度は理論的には3が最大値となる。また、セルロース複合体には、その機能が発揮できる範囲で、セルロースと親水性高分子以外の成分を含んでいても構わない。例えば、デキストリン、砂糖、水飴、還元水飴、トレハロース、澱粉、加工澱粉、糖アルコール(例えば、ソルビトール、マルチトール、キシリトール、マンニトール、マルチトールなど)、オリゴ糖(例えば、フラクトオリゴ糖、セロオリゴ糖、キシロオリゴ糖、マンノオリゴ糖など)、水溶性金属塩(例えば、塩化ナトリウム、塩化カリウム、塩化カルシウム、塩化マグネシウム、クエン酸塩など)、不溶性金属塩(例えば、炭酸カルシウム、酸化チタン、硫酸カルシウムなど)の少なくとも一種類以上をセルロース複合体中に含んでいても構わない。 The cellulose composite of the present invention is obtained by wet-mixing cellulose and a hydrophilic polymer. Examples of the hydrophilic polymer include sodium carboxymethylcellulose, carboxymethylcellulose calcium, methylcellulose, hydroxypropylcellulose, hydroxymethylcellulose, xanthan gum, glucomannan, karaya gum, carrageenan, locust bean gum, guar gum, psyllium seed gum, alginate ester, gellan gum and the like. Is mentioned. The hydrophilic polymer used as the cellulose composite may be one kind or a combination of plural kinds. In particular, a cellulose composite using sodium carboxymethyl cellulose having a tendency to exhibit a high storage elastic modulus (G ′) as a composite component is preferable. The sodium carboxymethylcellulose used for the cellulose composite may be one kind or a plurality thereof. Here, sodium carboxymethylcellulose is an anionic water-soluble polymer mainly composed of cellulose, and is generally called CMC · Na. The ratio (mass ratio) between cellulose and sodium carboxymethyl cellulose is particularly preferably 80/20 to 95/5. More preferably, it is 85/15 to 93/7. Although there is no restriction | limiting in particular in the etherification degree of the carboxymethylcellulose sodium used for a cellulose composite, 0.3-1.5 are preferable. More preferably, it is 0.6-1.3. The degree of etherification of carboxymethylcellulose sodium refers to the degree of substitution of carboxymethyl groups per anhydroglucose unit of cellulose. Since there are three hydroxyl groups per anhydroglucose unit, theoretically, the maximum degree of etherification is 3. In addition, the cellulose composite may contain components other than cellulose and hydrophilic polymer as long as the function can be exhibited. For example, dextrin, sugar, starch syrup, reduced starch syrup, trehalose, starch, modified starch, sugar alcohol (eg, sorbitol, maltitol, xylitol, mannitol, maltitol), oligosaccharide (eg, fructooligosaccharide, cellooligosaccharide, xylooligosaccharide) , Manno-oligosaccharides, etc.), water-soluble metal salts (eg sodium chloride, potassium chloride, calcium chloride, magnesium chloride, citrate etc.), insoluble metal salts (eg calcium carbonate, titanium oxide, calcium sulfate etc.) More than one kind may be contained in the cellulose composite.
本発明のセルロース複合体としては、水に対して1質量%の濃度で分散させ、1時間放置後の分散液の25℃における貯蔵弾性率(G’)が0.3Pa以上であるものを用いることが有利である。ここでいう、貯蔵弾性率(G’)の測定方法は次の通りである。まず、セルロース複合体を1質量%になるように、純水に分散する。純水への分散方法は、セルロース複合体が均一に分散できる方法であれば特に制限はないが、例えば、エクセルオートホモジナイザーED−7(製品名、(株)日本精機製作所製)で15,000rpm×5分間、分散する方法などが挙げられる。得られた分散液を25℃の恒温槽に1hr静置した後、粘弾性測定装置で貯蔵弾性率(G’)を測定する。例えば、ARES 100FTRN1型(Reometoric Scientific.Ink製)を用いて測定できる。セルロース複合体の貯蔵弾性率(G’)が0.3Pa未満の場合、懸濁安定性が不足する場合がある。上限は特に制限はないが、通常は5Pa未満である。好ましくは0.4〜3Paである。セルロース複合体の貯蔵弾性率(G’)は、分散後、経時的に上昇するのが一般的である。しかし、例え最終的なG’が、0.3Pa以上であっても、分散後1hrの時点で0.3Pa未満であるものは、本発明のセルロースとしては好ましくなく、あくまでも分散後の1時間で、貯蔵弾性率(G’)が0.3Pa以上に上昇するものを用いることが好ましい。セルロースの乳飲料中の含有量は0.05〜0.4質量%である。セルロースが0.05質量%未満では十分な本発明の効果を付与することは難しく、0.4質量%を超えると、飲み口に影響が出てくる場合がある。好ましくは0.1〜0.2質量%である。 As the cellulose composite of the present invention, a dispersion having a storage elastic modulus (G ′) at 25 ° C. of 0.3 Pa or more of a dispersion liquid that is dispersed at 1% by mass with respect to water and left for 1 hour is used. It is advantageous. The measuring method of storage elastic modulus (G ') here is as follows. First, a cellulose composite is disperse | distributed to a pure water so that it may become 1 mass%. The method for dispersing in pure water is not particularly limited as long as the cellulose composite can be uniformly dispersed. For example, 15,000 rpm is obtained with Excel Auto Homogenizer ED-7 (product name, manufactured by Nippon Seiki Seisakusho Co., Ltd.). And a method of dispersing for 5 minutes. The obtained dispersion is allowed to stand in a thermostatic bath at 25 ° C. for 1 hr, and then the storage elastic modulus (G ′) is measured with a viscoelasticity measuring device. For example, it can measure using ARES 100FTRN1 type (made by Reometric Scientific. Ink). When the storage elastic modulus (G ′) of the cellulose composite is less than 0.3 Pa, the suspension stability may be insufficient. The upper limit is not particularly limited, but is usually less than 5 Pa. Preferably it is 0.4-3Pa. In general, the storage elastic modulus (G ′) of a cellulose composite increases with time after dispersion. However, even if the final G ′ is 0.3 Pa or more, those that are less than 0.3 Pa at the time of 1 hr after dispersion are not preferable as the cellulose of the present invention, and only after 1 hour after dispersion. It is preferable to use one whose storage elastic modulus (G ′) rises to 0.3 Pa or more. Content in the milk drink of a cellulose is 0.05-0.4 mass%. If the cellulose is less than 0.05% by mass, it is difficult to impart sufficient effects of the present invention, and if it exceeds 0.4% by mass, the drinking mouth may be affected. Preferably it is 0.1-0.2 mass%.
本発明の乳飲料の5℃におけるtanδは、1.55〜2.40であることが重要である。ここで言うtanδは、飲料を製造後、5℃で約12時間保存した後、容器を中身が泡立たない程度に振盪し、5℃で粘弾性測定装置によって測定する。例えば、ARES 100FTRN1型(Reometoric Scientific.Ink製)が当該測定に用いられ得る。乳飲料のtanδが1.55未満であると、急冷却で凝集が生じたり、長期保存での飲み口の変化が起こる場合がある。一方、2.40を越えると不溶性成分の沈降が生じる可能性が高い。より好ましいtanδは1.60〜2.00である。 It is important that tan δ at 5 ° C. of the milk beverage of the present invention is 1.55 to 2.40. The tan δ referred to here is measured by a viscoelasticity measuring device at 5 ° C. after the beverage is produced and stored at 5 ° C. for about 12 hours, and then the container is shaken to such an extent that the contents do not foam. For example, an ARES 100FTRN1 type (manufactured by Reometric Scientific. Ink) can be used for the measurement. If the tan δ of the milk drink is less than 1.55, aggregation may occur due to rapid cooling, or a change in the drinking mouth may occur during long-term storage. On the other hand, if it exceeds 2.40, there is a high possibility that insoluble components will precipitate. A more preferable tan δ is 1.60 to 2.00.
いかなる理論に拘束されるものではないが、通常、tanδの値が小さいほど、その流体は固体的な性質が強いため、結果として懸濁安定性が向上するものと考えられる。そのため、前記セルロースの貯蔵弾性率(G’)が高いものを多く添加するほど、飲料のtanδは小さく出来るため、懸濁安定性も良好な結果が得られるものと推定でき、実際にそのようなケースが多い。しかし、驚くべきことに乳飲料に関しては、tanδの値が小さすぎる場合は、飲料中で濃度にムラが起こりやすく、特に急冷却や5℃以下の保存ではゲル状物質が生じてしまいむしろ乳飲料としては好ましくない。飲料に適切なtanδや貯蔵弾性率(G’)を付与するためには、短期間で構造を形成(すなわち、分散後の1時間で、貯蔵弾性率(G’)が0.3Pa以上に上昇する。)させ、しかも、飲料のtanδを過大に低下させないことが重要である。 While not being bound by any theory, it is generally considered that the smaller the value of tan δ, the stronger the fluid is, so that the suspension stability is improved as a result. Therefore, it can be estimated that the tan δ of the beverage can be reduced as the amount of the cellulose having a high storage elastic modulus (G ′) is added, so that the suspension stability is also good. There are many cases. Surprisingly, however, for dairy beverages, if the value of tan δ is too small, the concentration tends to be uneven in the beverage, and a gel-like substance is produced in particular when rapidly cooled or stored at 5 ° C. or lower. It is not preferable. In order to give appropriate tan δ and storage elastic modulus (G ′) to the beverage, the structure is formed in a short period of time (that is, the storage elastic modulus (G ′) rises to 0.3 Pa or more in 1 hour after dispersion. It is important that the tan δ of the beverage is not excessively reduced.
本発明の乳飲料には、さらに二価の塩を0.15mmol/L以上添加することが好ましい。どのような理論によるものかは不明であるが、二価の塩を添加することにより、乳飲料のtanδが本発明の範囲に入りやすくなる。ここでいう二価の塩としては、例えば、塩化カルシウム、塩化マグネシウム、乳酸カルシウムなどが挙げられる。特に塩化カルシウムが好ましい。二価の塩は、乳飲料に直接添加しても良いし、セルロース複合体の成分に含まれていても良い。より好ましくは0.3mmol/L以上である。上限は、風味への影響等を考慮すると1mmol/L以下が現実的である。 It is preferable to further add 0.15 mmol / L or more of a divalent salt to the milk beverage of the present invention. It is unclear what the theory is based on, but by adding a divalent salt, the tan δ of the milk beverage easily falls within the scope of the present invention. Examples of the divalent salt here include calcium chloride, magnesium chloride, calcium lactate and the like. In particular, calcium chloride is preferable. The divalent salt may be added directly to the milk beverage, or may be included in the components of the cellulose composite. More preferably, it is 0.3 mmol / L or more. The upper limit is realistically 1 mmol / L or less considering the influence on the flavor and the like.
また、本発明の乳固形分中に含まれる乳タンパクのホエイ/カゼインの質量比は3/7〜2/1であると、本発明の効果がより顕著に現れやすいので好ましい。一般的に用いられる牛乳のタンパクはホエイ/カゼインの質量比が2/8程度である。一方、ホエイタンパクはアミノ酸バランス、体内への吸収が良い優れたタンパク源であるが、熱安定性が悪いという欠点があった。しかし、ホエイの比率を3/7〜2/1の範囲まで高めても本発明の乳飲料は高い安定性を示すため、本発明の有利な効果の一つといえる。 Moreover, it is preferable that the whey / casein mass ratio of the milk protein contained in the milk solid content of the present invention is 3/7 to 2/1 because the effects of the present invention are more apparent. Generally used milk protein has a whey / casein mass ratio of about 2/8. On the other hand, whey protein is an excellent protein source with good amino acid balance and absorption into the body, but has the disadvantage of poor thermal stability. However, even if the whey ratio is increased to a range of 3/7 to 2/1, the milk beverage of the present invention exhibits high stability, and thus can be said to be one of the advantageous effects of the present invention.
また、本発明の乳飲料は、振盪直後の5℃におけるtanδ(つまり、飲料を製造後、5℃で約12時間保存した後、容器を中身が泡立たない程度に振盪し、5℃で粘弾性測定装置によって測定したtanδ)が2.4以下で、かつ、当該振盪直後の乳飲料のG’と振盪後に5℃で5時間静置後の乳飲料のG’の比率を測定した時に、5時間後のG’/振盪直後のG’の値が0.95〜1.20にすることが好ましい。その比率が、0.95〜1.20に入らない場合、成分の偏りが生じて、長期保存では飲み口が悪くなることが多い。なお、乳飲料のG’の測定は、上記tanδの測定試料作成方法と同じ方法により測定試料を作成し、その直後(振盪直後の乳飲料のG’)と振盪後に5℃で5時間静置後の乳飲料のG’を、前記の粘弾性測定装置で測定すればよい。 In addition, the milk beverage of the present invention is tan δ at 5 ° C. immediately after shaking (that is, after the beverage is produced and stored at 5 ° C. for about 12 hours, the container is shaken to such an extent that the contents do not foam, and viscoelastic at 5 ° C. Tan δ) measured by the measuring apparatus is 2.4 or less, and when the ratio of G ′ of the milk drink immediately after shaking and G ′ of the milk drink after standing at 5 ° C. for 5 hours after shaking is measured, 5 The value of G ′ after time / G ′ immediately after shaking is preferably 0.95 to 1.20. When the ratio does not fall within the range of 0.95 to 1.20, the components are biased, and the mouth is often deteriorated during long-term storage. In addition, the measurement of G ′ of the milk beverage is performed by preparing a measurement sample by the same method as the measurement sample preparation method of tan δ, and immediately after that (G ′ of the milk drink immediately after shaking) and after shaking, left at 5 ° C. for 5 hours. What is necessary is just to measure G 'of a later milk drink with the said viscoelasticity measuring apparatus.
本発明のセルロースとしては、結晶セルロースが好ましい。また本発明のセルロース複合体も、結晶セルロースと前記親水性高分子との複合体であることが好ましい。結晶セルロースとは、例えば木材パルプ、精製リンターなどのセルロース系素材を、酸加水分解、アルカリ酸化分解、酵素分解などにより解重合処理して得られる平均重合度が30〜400であり、結晶性部分が10%を超えるものをいう。原料となる木材パルプや精製リンター等は、天然のものでよく、或いは市販もされている。 As the cellulose of the present invention, crystalline cellulose is preferable. The cellulose composite of the present invention is also preferably a composite of crystalline cellulose and the hydrophilic polymer. Crystalline cellulose, for example, has an average degree of polymerization of 30 to 400 obtained by depolymerizing cellulose-based materials such as wood pulp and refined linter by acid hydrolysis, alkaline oxidative decomposition, enzymatic decomposition, etc. Means over 10%. The wood pulp, refined linter, and the like that are raw materials may be natural or commercially available.
本発明の乳飲料には、必要に応じて、コーヒー抽出物、紅茶抽出物や、砂糖、液糖、異性化糖、果糖、麦芽糖、トレハロース、ソルビトール、キシリトール、エリスリトール、マルチトール、マンニトール、ラクチトール、アスパルテーム、アセスルファムK、スクラロース、ステビア、ネオテーム、ソーマチンなどの甘味料、フラクトオリゴ糖、マンノオリゴ糖、キシロオリゴ等、セロオリゴ糖などのオリゴ糖類、アミノ酸類、エキス類、食塩などの呈未成分、ピロリン酸鉄、ビタミン類、炭酸カルシウム、DHA、EPAなどの栄養成分、グリセリン脂肪酸エステル(モノグリセリド、ポリグリセリド、有機酸モノグリセリド)、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステル、レシチン、リゾレシチンなどの乳化剤、グアガム、ペクチン、ローカストビーンガム、タマリンドシードガム、サイリウムシードガム、カラギナン、アルギン酸及びその金属塩、アルギン酸エステル、キサンタンガム、ジェランガム、大豆多糖類、アラビアガム、寒天、グルコマンナンなどの増粘多糖類、澱粉、加工澱粉、香料などを含んでいても構わない。 In the milk beverage of the present invention, as necessary, coffee extract, tea extract, sugar, liquid sugar, isomerized sugar, fructose, maltose, trehalose, sorbitol, xylitol, erythritol, maltitol, mannitol, lactitol, Sweeteners such as aspartame, acesulfame K, sucralose, stevia, neotame, thaumatin, fructooligosaccharides, manno-oligosaccharides, xylo-oligo, etc., oligosaccharides such as cellooligosaccharides, amino acids, extracts, salt, etc., iron pyrophosphate, Nutritional ingredients such as vitamins, calcium carbonate, DHA, EPA, glycerin fatty acid ester (monoglyceride, polyglyceride, organic acid monoglyceride), sucrose fatty acid ester, sorbitan fatty acid ester, propylene glycol fatty acid ester, lecithin, li Increase of emulsifiers such as lecithin, guar gum, pectin, locust bean gum, tamarind seed gum, psyllium seed gum, carrageenan, alginic acid and its metal salts, alginate, xanthan gum, gellan gum, soybean polysaccharides, gum arabic, agar, glucomannan It may contain viscous polysaccharides, starch, modified starch, fragrance and the like.
本発明の実施形態の一つの乳飲料の好ましい製造方法の一例として、カルシウム強化乳を挙げる。まず、脱脂粉乳やミルクカルシウム、結晶セルロースなどの粉末原料を粉混ぜする。容器に生クリームや生乳のような液体原料と水を入れて、攪拌しながら、60〜80℃に加温して溶解(分散)する。この際、攪拌は、例えば、TKホモジナイザーで5,000rpmといった高速攪拌が好ましい。次に、得られた溶解(分散)液を、高圧ホモジナイザーを用いて均質化する。高圧ホモジナイザーは一連式でも多連式でも構わない。均質化圧力は10〜30MPaで、2段での均質化処理が好ましい。殺菌は製品の原料や容器(紙パック、缶、ビン、PETボトル、カップ、等)や、希望する保存条件(チルド、常温、加温、等)や賞味期限に応じて、HTST殺菌、UHT殺菌、ホットパック殺菌、レトルト殺菌などの方法を適宜選択できるが、HTST殺菌、UHT殺菌が好ましい。 Calcium enriched milk is mentioned as an example of the preferable manufacturing method of one milk drink of embodiment of this invention. First, powder raw materials such as skim milk powder, milk calcium, and crystalline cellulose are mixed. A liquid raw material such as fresh cream or raw milk and water are put in a container, and dissolved (dispersed) by heating to 60 to 80 ° C. while stirring. At this time, the stirring is preferably high-speed stirring such as 5,000 rpm with a TK homogenizer. Next, the obtained dissolved (dispersed) liquid is homogenized using a high-pressure homogenizer. The high-pressure homogenizer may be a series type or a multiple type. The homogenization pressure is 10 to 30 MPa, and homogenization treatment in two stages is preferable. Sterilization is HTST sterilization, UHT sterilization according to raw materials and containers of products (paper packs, cans, bottles, PET bottles, cups, etc.), desired storage conditions (chilled, normal temperature, heating, etc.) and shelf life. Although methods such as hot pack sterilization and retort sterilization can be appropriately selected, HTST sterilization and UHT sterilization are preferred.
本発明の乳飲料は、軽い飲み口を維持したままで、急冷却したり、5℃以下で長時間冷蔵保存してもゲルを生じにくく、均一で安定性が高いため、特に冷蔵保存を行うカルシウム強化乳、ミルクコーヒー、ミルクティー、抹茶ミルクなどに最も好適に利用できる。 The dairy drink of the present invention is particularly refrigerated because it keeps a light drinking mouth and is rapidly cooled or refrigerated at 5 ° C. or less for a long period of time, making it difficult to form a gel and being uniform and highly stable. It can be most suitably used for calcium-enriched milk, milk coffee, milk tea, matcha milk, and the like.
実施例により本発明をさらに具体的に説明するが、これらによって本発明は何ら制限されるものではない。
<セルロースの貯蔵弾性率(G’)の測定方法>
サンプルを、分散後の濃度が固形分換算で1質量%になるように、エクセルオートホモジナイザーED−7(製品名、(株)日本精機製作所製)で15,000rpm×5分間、分散してセルロース複合体の分散液を作製した。得られた分散液を25℃の恒温槽に1hr静置した後、粘弾性測定装置(ARES 100FTRN1型(Reometoric Scientific.Ink製))を用いて、Double Wall Couette Geometry、待機時間300秒、歪みを1〜500%、角周波数20rad/sで測定し、歪みが20%における貯蔵弾性率を測定した。
The present invention will be described more specifically with reference to examples, but the present invention is not limited to these examples.
<Measurement method of storage elastic modulus (G ′) of cellulose>
Cellulose was dispersed in 15,000 rpm for 5 minutes with Excel Auto Homogenizer ED-7 (product name, manufactured by Nippon Seiki Seisakusho Co., Ltd.) so that the concentration after dispersion was 1% by mass in terms of solid content. A composite dispersion was prepared. The obtained dispersion was allowed to stand in a thermostatic bath at 25 ° C. for 1 hr, and then, using a viscoelasticity measuring apparatus (ARES 100FTRN1 type (manufactured by Reometric Scientific. Ink)), a Double Wall Couette Geometry, a waiting time of 300 seconds, and a strain were set. The storage elastic modulus was measured at 1 to 500% and an angular frequency of 20 rad / s, and the strain was 20%.
<乳飲料のtanδ、貯蔵弾性率(G’)の測定方法>
5℃に冷却された乳飲料を、泡立たないように振盪し、直ちに(5分以内)乳飲料を液面から2cm程度下から少量をゆっくりと抜き出して、粘弾性測定装置(ARES 100FTRN1型(Reometoric Scientific.Ink製))を用いて、Double Wall Couette Geometry、待機時間300秒、歪みを1〜500%、角周波数20rad/sで測定し、歪みが20%、5℃におけるtanδ及び貯蔵弾性率を測定した。また、振盪後の乳飲料は、5℃の恒温層に静置し、振盪から5時間後に乳飲料の一部を抜き出して、同様に貯蔵弾性率(G’)を測定した。
<Measurement method of tan δ and storage elastic modulus (G ′) of milk beverage>
The milk drink cooled to 5 ° C. is shaken so as not to be foamed, and immediately (within 5 minutes), a small amount of the milk drink is slowly withdrawn from about 2 cm below the liquid surface, and a viscoelasticity measuring device (ARES 100FTRN1 type (Reometric) (Scientific. Ink)), Double Wall Couette Geometry, waiting time 300 seconds, strain measured 1-500%, angular frequency 20 rad / s, strain 20%, tan δ at 5 ° C. and storage modulus It was measured. Moreover, the milk drink after shaking was left still in a 5 degreeC constant temperature layer, a part of milk drink was extracted 5 hours after shaking, and the storage elastic modulus (G ') was measured similarly.
<飲料の評価方法>
試作した飲料の、5℃への急冷時のモヤの発生並びに3週間保存後の凝集、沈降及び風味を評価した。それぞれの評価方法及び評価基準について下記に示す。
<Beverage evaluation method>
Generation of haze when rapidly cooling to 5 ° C. and aggregation, sedimentation and flavor after storage for 3 weeks of the prototyped beverage were evaluated. Each evaluation method and evaluation criteria are shown below.
・急冷時のモヤ
試作した乳飲料を5℃の冷水に2時間付けて、急冷した液の状態を目視で観察した。
◎(優):均一である。
○(良):近くから目を凝らしてみると、僅かにモヤが認められる。
△(可):普通に見ても、僅かにモヤが認められる。
×(不可):モヤが明確に確認できる。
-Moya at the time of rapid cooling The prototype milk drink was attached to 5 degreeC cold water for 2 hours, and the state of the rapidly cooled liquid was observed visually.
A (Excellent): Uniform.
○ (Good): If you look closely, you may notice a slight haze.
Δ (possible): Slight haze is observed even when viewed normally.
X (impossible): Complicated feeling can be confirmed.
・凝集
5℃で3週間保存後の飲料の状態を目視で観察後、容器の上部を開け、ゆっくりと他の容器に移した際(牛乳をコップに入れるイメージ)出てくる液の状態を目視で観察した。
◎(優):静置状態で凝集は認められず、移す液も最初から最後まで均一である。
○(良):静置状態で凝集は認められないが、移す液は、後半になると液が若干、
重く(濃く)なった感じがする。
△(可):静置状態で僅かに凝集が確認でき、移す液も明らかに、最初と最後では
液の濃度が違う。
×(不可):静置状態で凝集が明確に確認できる。
・ Agglomeration After visually observing the state of the beverage after storage at 5 ° C for 3 weeks, open the top of the container and slowly move it to another container (image of putting milk in a cup). Observed at.
A (excellent): No aggregation is observed in a stationary state, and the liquid to be transferred is uniform from the beginning to the end.
○ (Good): Although no aggregation is observed in the stationary state, the liquid to be transferred is slightly in the second half,
I feel heavier (darker).
△ (possible): Slight agglomeration can be confirmed in a stationary state, and the liquid to be transferred is also clearly shown.
The liquid concentration is different.
X (impossible): Aggregation can be clearly confirmed in a stationary state.
・沈降
容器をゆっくりと半回転させた際に、容器の底部に付着した沈降物の状態を目視で観察した。その際の評価基準は下記の通り。
◎(優):沈降物の付着がない。
○(良):沈降物の付着が極わずかである。(付着物が底部面積の1割未満)
△(可):沈降物の付着が少しある。(底部面積の1割以上5割未満)
×(不可):沈降物が完全に付着している。(底部面積の5割以上)
-Sedimentation When the container was slowly rotated half a turn, the state of sediment deposited on the bottom of the container was visually observed. The evaluation criteria at that time are as follows.
A (excellent): There is no deposit of sediment.
○ (good): Sediment adheres very little. (The deposit is less than 10% of the bottom area)
Δ (possible): Sediment is slightly adhered. (The bottom area is 10% or more and less than 50%)
X (impossible): The sediment has adhered completely. (More than 50% of the bottom area)
・風味
20代女性1名、50代女性1名、30代男性1名、40代男性1名の計4名で官能評価を行い、下記の基準で評価した。実施例1を基準として、飲み口を比較した。
◎(優):軽い飲み口で、とても飲みやすい。
○(良):僅かに飲み口が重いが、問題のないレベルである。
△(可):飲料中で、わずかではあるが、濃度の濃淡を感じる。
×(不可):一部ゲル化しているかのような食感、又は成分が完全に分離しており、 味が明らかに薄い又は濃い。
-Flavor A sensory evaluation was performed on a total of four people: one female in their 20s, one female in their 50s, one male in their 30s, and one male in their 40s, and evaluated according to the following criteria. The mouthfuls were compared using Example 1 as a reference.
◎ (excellent): Light drinking mouth and very easy to drink.
○ (good): The drinking mouth is slightly heavy, but there is no problem.
Δ (possible): In the beverage, a slight level of density is felt.
X (impossible): Texture as if it was partially gelled, or components are completely separated, and taste is clearly light or dark.
[製造例1:セルロース複合体Aの製造例]
市販DPパルプを裁断後、0.5mol/L塩酸中で121℃、60分間加水分解した後、水洗・濾過を行い固形分が50質量%のウェットケーキ状のセルロースを作製した。プラネタリーミキサー((株)品川工業所製、5DM−03−R、撹拌羽根はフック型)に、セルロース、CMC・Naを、セルロース/CMC・Naとの質量比が92/8となるように投入し、固形分46質量%となるように加水した。その後、126rpmで2hr混練し、乾燥・粉砕してセルロース複合体Aを得た。セルロース複合体Aの貯蔵弾性率(G’)は2.3Paであった。
[Production Example 1: Production Example of Cellulose Composite A]
After cutting the commercially available DP pulp, it was hydrolyzed in 0.5 mol / L hydrochloric acid at 121 ° C. for 60 minutes, then washed with water and filtered to produce wet cake-like cellulose having a solid content of 50 mass%. To a planetary mixer (manufactured by Shinagawa Kogyo Co., Ltd., 5DM-03-R, stirring blade is hook type), cellulose, CMC · Na, and the mass ratio of cellulose / CMC · Na to 92/8 It was added and watered to a solid content of 46% by mass. Thereafter, the mixture was kneaded at 126 rpm for 2 hours, dried and pulverized to obtain a cellulose composite A. The storage elastic modulus (G ′) of the cellulose composite A was 2.3 Pa.
[製造例2:セルロース複合体Bの製造例]
市販DPパルプを裁断後、2.5mol/L塩酸中で105℃、15分間加水分解した後、水洗・濾過を行い固形分が50質量%のウェットケーキ状のセルロースを作製した。プラネタリーミキサー((株)品川工業所製、5DM−03−R、撹拌羽根はフック型)に、セルロース、CMC・Na、塩化カルシウムを、セルロース/CMC・Na/塩化カルシウムとの質量比が80/16/4となるように投入し、固形分40質量%となるように加水した。その後、126rpmで1hr混練し、乾燥・粉砕してセルロース複合体Bを得た。セルロース複合体Bの貯蔵弾性率(G’)は0.5Paであった。
[Production Example 2: Production Example of Cellulose Composite B]
After cutting the commercially available DP pulp, it was hydrolyzed in 2.5 mol / L hydrochloric acid at 105 ° C. for 15 minutes, then washed with water and filtered to produce wet cake-like cellulose having a solid content of 50 mass%. Planetary mixer (made by Shinagawa Kogyo Co., Ltd., 5DM-03-R, stirring blade hook type), cellulose, CMC · Na, calcium chloride, mass ratio of cellulose / CMC · Na / calcium chloride is 80 / 16/4 was added, and water was added so that the solid content was 40% by mass. Thereafter, the mixture was kneaded at 126 rpm for 1 hr, dried and pulverized to obtain a cellulose composite B. The storage elastic modulus (G ′) of the cellulose composite B was 0.5 Pa.
[製造例3:セルロース複合体Cの製造例]
市販DPパルプを裁断後、2.5mol/L塩酸中で105℃、15分間加水分解した後、水洗・濾過を行い固形分が50質量%のウェットケーキ状のセルロースを作製した。プラネタリーミキサー((株)品川工業所製、5DM−03−R、撹拌羽根はフック型)に、セルロース、CMC・Na、キサンタンガム、デキストリン、食用油脂を、セルロース/CMC・Na/キサンタンガム/デキストリン/食用油脂との質量比が73.0/5.0/2.8/19.0/0.2となるように投入し、固形分40質量%となるように加水した。その後、126rpmで1hr混練し、乾燥・粉砕してセルロース複合体Cを得た。セルロース複合体Cの貯蔵弾性率(G’)は0.2Paであった。
[Production Example 3: Production Example of Cellulose Composite C]
After cutting the commercially available DP pulp, it was hydrolyzed in 2.5 mol / L hydrochloric acid at 105 ° C. for 15 minutes, then washed with water and filtered to produce wet cake-like cellulose having a solid content of 50 mass%. In a planetary mixer (made by Shinagawa Kogyo Co., Ltd., 5DM-03-R, stirring blade hook type), cellulose, CMC · Na, xanthan gum, dextrin, edible oil and fat, cellulose / CMC · Na / xanthan gum / dextrin / It poured so that mass ratio with edible oil and fat might be 73.0 / 5.0 / 2.8 / 19.0 / 0.2, and it added water so that it might become 40 mass% of solid content. Thereafter, the mixture was kneaded at 126 rpm for 1 hr, dried and pulverized to obtain a cellulose composite C. The storage elastic modulus (G ′) of the cellulose composite C was 0.2 Pa.
[実施例1〜4、比較例1〜3]
表1の組成に従い、カルシウム強化乳を試作した。なお、生クリームは(株)明治製(乳固形分51質量%)、全脂粉乳は南日本酪農(株)製、ミルクカルシウムは森永乳業(株)製、ホエイ蛋白(WPC)は、フォンテラ(株)製、乳化剤は、製品名:ショ糖脂肪酸エステルP1670(三菱化学フーズ(株)製)をそれぞれ用いた。なお、それぞれの乳固形分は、実施例1、実施例2、比較例1については、11.9質量%であり、実施例3、実施例4、比較例2、比較例3では、23.9質量%である。
[Examples 1-4, Comparative Examples 1-3]
According to the composition of Table 1, a calcium-enriched milk was prototyped. In addition, fresh cream is manufactured by Meiji Co., Ltd. (milk solid content 51 mass%), whole milk powder is manufactured by Minami Nippon Dairy Co., Ltd., milk calcium is manufactured by Morinaga Milk Industry Co., Ltd., whey protein (WPC) is Fontera ( The product name: Sucrose fatty acid ester P1670 (Mitsubishi Chemical Foods Co., Ltd.) was used for the emulsifier. In addition, each milk solid content is 11.9 mass% about Example 1, Example 2, and the comparative example 1, and in Example 3, Example 4, the comparative example 2, and the comparative example 3, it is 23. 9% by mass.
飲料の製法は全て同じのため、代表例として実施例1の製法について述べる。表1の実施例1の組成に従って測り取った粉末原料(生クリーム、水以外の全て)をビニール袋の中で混合した。容器に水と生クリームを入れ、TKホモミキサー(プライミクス(株)製)で25℃、6,000rpmで撹拌し、そこに、先にブレンドした粉末原料を加え、10分間そのまま撹拌を続けた。その後、80℃に加温し、MGホモジナイザーで一次均質化圧15MPa、二次均質化圧5MPaの条件で均質化し、UHT殺菌機で130℃、3秒殺菌した後、500mlの透明な耐熱瓶に充填して蓋をして、カルシウム強化乳飲料を試作した。得られた乳飲料の入った耐熱瓶は、5℃の冷水に2時間つけて急冷却した後、5℃の保冷庫に保存した。実施例2〜4及び比較例1〜3も、それぞれ表1の処方に従い同様に試作した。 Since all the beverage production methods are the same, the production method of Example 1 will be described as a representative example. Powder raw materials (all except fresh cream and water) measured according to the composition of Example 1 in Table 1 were mixed in a plastic bag. Water and fresh cream were placed in a container, and the mixture was stirred at 25 ° C. and 6,000 rpm with a TK homomixer (Primics Co., Ltd.). The previously blended powder material was added thereto, and stirring was continued for 10 minutes. Thereafter, the mixture is heated to 80 ° C., homogenized with an MG homogenizer under conditions of a primary homogenization pressure of 15 MPa and a secondary homogenization pressure of 5 MPa. A calcium-fortified milk drink was prototyped after filling and capping. The heat-resistant bottle containing the obtained milk drink was placed in 5 ° C. cold water for 2 hours and rapidly cooled, and then stored in a 5 ° C. cool box. Examples 2 to 4 and Comparative Examples 1 to 3 were also produced in the same manner according to the formulations in Table 1.
試作した飲料の評価結果を表2に示す。
実施例1および実施例2の乳飲料は、tanδがそれぞれ1.62、1.72と本発明の範囲を満たしているので、急冷してもモヤは全く認められず、凝集、沈降、風味すべてが良好であった。 The milk beverages of Example 1 and Example 2 satisfy the scope of the present invention with tan δ of 1.62 and 1.72, respectively. Therefore, no moisture is observed even when rapidly cooled, and all flocculation, sedimentation and flavor are observed. Was good.
また、実施例1や2に比べて、成分量が倍でより凝集が生じやすい実施例3および実施例4についても、tanδがそれぞれ0.997、0.955と本発明の範囲を満たしているので、急冷してもモヤは全く認められず、風味は全成分の濃度が濃いことから、実施例1や実施例2に比べると濃厚ではあったものの悪印象ではく、凝集、沈降、風味すべてが良好という評価であった。 Also, in Examples 3 and 4 in which the amount of components is twice as much as in Examples 1 and 2 and aggregation is more likely to occur, tan δ is 0.997 and 0.955, respectively, which satisfies the scope of the present invention. So, even if cooled rapidly, no haze is observed, and the flavor is concentrated in all components, so it is thicker than in Example 1 and Example 2, but it is not a bad impression. It was evaluation that it was favorable.
一方、比較例では、tanδが1.35と本発明の範囲を外れており、ほぼ同じ組成の実施例1と比較すると、評価項目の全てが少しずつ悪く、特に沈降が多いという評価であった。成分の濃い比較例2もtanδが1.53と本発明の範囲を外れており、乳飲料中で成分の濃淡が感じられるものとなった。また、セルロースを含んでいない比較例3では、特に沈降が激しく、一部、タンパク等も巻き込んで沈降しているためか、味が薄く風味が悪いという結果であった。 On the other hand, in the comparative example, tan δ is 1.35, which is out of the range of the present invention, and when compared with Example 1 having almost the same composition, all of the evaluation items are a little worse and particularly the sedimentation is high. . In Comparative Example 2 in which the components were dark, tan δ was 1.53, which was outside the range of the present invention, and the darkness of the components was felt in the milk beverage. Moreover, in Comparative Example 3 containing no cellulose, the result was that the sedimentation was particularly intense, and partly because protein or the like was involved in the sedimentation.
以上の様に、セルロースを用いて、乳飲料のtanδをある特定に範囲にすることにより、急冷時や冷蔵保存時の成分の偏りが抑えられ、良好な風味の乳飲料とすることが出来た。 As described above, by using cellulose to make the tan δ of milk drinks in a certain range, the bias of ingredients during rapid cooling and refrigerated storage can be suppressed, and a milk beverage with good flavor can be obtained. .
本発明により、風味が良く、急冷却したり、5℃以下で長時間冷蔵保存してもゲルを生じにくく、均一で安定性の高い乳飲料を提供できるため、食品製造業に好適に利用できる。 According to the present invention, it can be suitably used in the food manufacturing industry because it has a good flavor, is rapidly cooled, and is less likely to form a gel even when stored at 5 ° C. or lower for a long period of time, and can provide a uniform and highly stable milk beverage. .
Claims (7)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012272397A JP6150511B2 (en) | 2012-12-13 | 2012-12-13 | Dairy beverages with less component bias during refrigerated storage |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012272397A JP6150511B2 (en) | 2012-12-13 | 2012-12-13 | Dairy beverages with less component bias during refrigerated storage |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014117186A true JP2014117186A (en) | 2014-06-30 |
JP6150511B2 JP6150511B2 (en) | 2017-06-21 |
Family
ID=51172620
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012272397A Active JP6150511B2 (en) | 2012-12-13 | 2012-12-13 | Dairy beverages with less component bias during refrigerated storage |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP6150511B2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016084397A (en) * | 2014-10-24 | 2016-05-19 | 旭化成ケミカルズ株式会社 | Cellulose composite |
JP2019092415A (en) * | 2017-11-21 | 2019-06-20 | 株式会社大塚製薬工場 | Stabilizer, beverage and production method of the same |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11187826A (en) * | 1997-12-25 | 1999-07-13 | Sanei Gen Ffi Inc | Dispersion-stabilizing composition and dispersion-stabilized food using the same |
JP2000041627A (en) * | 1998-07-30 | 2000-02-15 | Asahi Chem Ind Co Ltd | Food composition containing plural dispersible cellulose composite materials |
JP2011162700A (en) * | 2010-02-12 | 2011-08-25 | Asahi Kasei Chemicals Corp | Crystalline cellulose composite |
-
2012
- 2012-12-13 JP JP2012272397A patent/JP6150511B2/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11187826A (en) * | 1997-12-25 | 1999-07-13 | Sanei Gen Ffi Inc | Dispersion-stabilizing composition and dispersion-stabilized food using the same |
JP2000041627A (en) * | 1998-07-30 | 2000-02-15 | Asahi Chem Ind Co Ltd | Food composition containing plural dispersible cellulose composite materials |
JP2011162700A (en) * | 2010-02-12 | 2011-08-25 | Asahi Kasei Chemicals Corp | Crystalline cellulose composite |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016084397A (en) * | 2014-10-24 | 2016-05-19 | 旭化成ケミカルズ株式会社 | Cellulose composite |
JP2019092415A (en) * | 2017-11-21 | 2019-06-20 | 株式会社大塚製薬工場 | Stabilizer, beverage and production method of the same |
JP7052997B2 (en) | 2017-11-21 | 2022-04-12 | 株式会社大塚製薬工場 | Stabilizers, beverages and their manufacturing methods |
Also Published As
Publication number | Publication date |
---|---|
JP6150511B2 (en) | 2017-06-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5665141B2 (en) | Method for producing tromomi yogurt | |
US20140044855A1 (en) | Creamers and methods of making same | |
US20120114795A1 (en) | Dairy product and process | |
JP2009082023A (en) | Method for producing thick yoghurt | |
JPH11332476A (en) | Acidic protein food and its production | |
JPWO2016068276A1 (en) | Liquid fermented milk and method for producing the same | |
JP5132539B2 (en) | Concentrated milk and emulsifier for concentrated milk | |
JP4242671B2 (en) | Beverage composition | |
JP6150511B2 (en) | Dairy beverages with less component bias during refrigerated storage | |
JP2007159573A (en) | Emulsion stabilizer for milk-containing beverage | |
JP3939675B2 (en) | Layered milk component-containing gel food that can be distributed at room temperature and method for producing the same | |
JP2010004827A (en) | Frothable green tea drink containing milk component | |
JP2010259425A (en) | Yogurt | |
JP4354352B2 (en) | Stabilizer for milk beverage and its application | |
JP4042977B2 (en) | Method for producing food additive composition | |
JPH07284383A (en) | Production of calcium-enriched acid protein beverage | |
US20160192692A1 (en) | Froth beverage composition and preparation method therefor | |
JP4462623B2 (en) | Method for producing weakly acidic milk protein-containing beverage | |
JP5904700B2 (en) | Emulsified composition for food and drink | |
JP6705635B2 (en) | Fermented milk manufacturing method | |
JP2015500654A (en) | Liquid creamer and method for producing the same | |
JP2006034112A (en) | Solid food-containing yoghurt | |
JP4354351B2 (en) | Stabilizer for milk beverage and its application | |
JP4664244B2 (en) | Protein reaggregation inhibitor | |
JP2004344042A (en) | Gelatinous food applicable to normal-temperature distribution |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20150928 |
|
A711 | Notification of change in applicant |
Free format text: JAPANESE INTERMEDIATE CODE: A712 Effective date: 20160401 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160516 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20160720 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20160726 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20160916 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20170207 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170329 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20170410 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20170425 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20170523 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6150511 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |