JP2000041627A - Food composition containing plural dispersible cellulose composite materials - Google Patents

Food composition containing plural dispersible cellulose composite materials

Info

Publication number
JP2000041627A
JP2000041627A JP10215621A JP21562198A JP2000041627A JP 2000041627 A JP2000041627 A JP 2000041627A JP 10215621 A JP10215621 A JP 10215621A JP 21562198 A JP21562198 A JP 21562198A JP 2000041627 A JP2000041627 A JP 2000041627A
Authority
JP
Japan
Prior art keywords
cellulose
dispersible
food composition
gum
composite materials
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10215621A
Other languages
Japanese (ja)
Other versions
JP3522115B2 (en
Inventor
Yoshihito Yaginuma
義仁 柳沼
Koichi Noda
考一 野田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Asahi Chemical Industry Co Ltd
Original Assignee
Asahi Chemical Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd
Priority to JP21562198A priority Critical patent/JP3522115B2/en
Publication of JP2000041627A publication Critical patent/JP2000041627A/en
Application granted granted Critical
Publication of JP3522115B2 publication Critical patent/JP3522115B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Coloring Foods And Improving Nutritive Qualities (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a food composition having high suspension stability, high emulsion stability, characteristic tissue, characteristic cloudy property, characteristic dietary fiber effect and low calorie by adding a specific combination of water-dispersible cellulose composite materials. SOLUTION: This food composition contains (A) a dispersible composite material comprising cellulose and sodium carboxylmethylcellulose (preferably having a carboxymethyl group substitution degree of 0.20-1.50, a polymerization degree of 200-500 and a 2 wt.% aqueous solution viscosity of 10-1,000 mPa.s) and (B) a dispersible composite material comprising cellulose and an original hydrophilic polymer (preferably comprising karaya gum, xanthane gum, digestion-resistant dextrin, etc.).

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、複数の分散性セル
ロース複合体を含有する食品組成物に関するものであ
り、食品用途分野において、高懸濁安定性食品、高乳化
安定性食品、独特な組織を有する食品、クラウディー性
を有する食品、食物繊維効果を有する食品、低脂肪食
品、等に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a food composition containing a plurality of dispersible cellulose composites, and in the field of food applications, a highly suspension-stable food, a highly emulsion-stable food, and a unique tissue. The present invention relates to a food having a high quality, a food having a cloudy property, a food having a dietary fiber effect, a low fat food, and the like.

【0002】[0002]

【従来の技術】これまでセルロースと親水性高分子から
なる分散性の複合体を含有する食品としては、特公昭4
0−14174号公報、特公昭62−43661号公
報、特開平6−335365号公報等に記載があるよう
に、多数知られている。これらのうち、カルボキシメチ
ルセルロース・ナトリウムを含有してなる分散性の複合
体は、例えばココア飲料に使用すると、殺菌等の熱処理
によって軟凝集が発生し、これを製品とするためには強
く振盪するなどして凝集を解消させる必要があった。ま
た、軟凝集を生じない程度の緩和な条件で熱処理する
と、底部にココア末が沈積する場合があった。
2. Description of the Related Art Hitherto, as a food containing a dispersible complex comprising cellulose and a hydrophilic polymer, Japanese Patent Publication No. Sho 4
As described in JP-A No. 0-14174, JP-B-62-43661, and JP-A-6-335365, many are known. Of these, dispersible composites containing sodium carboxymethylcellulose, for example, when used in cocoa beverages, cause soft coagulation due to heat treatment such as sterilization, and to vigorously shake the product to make it a product It was necessary to eliminate aggregation. Further, when heat treatment is performed under mild conditions that do not cause soft aggregation, cocoa powder may be deposited on the bottom in some cases.

【0003】一方、カルボキシメチルセルロース・ナト
リウム以外の、天然由来の親水性高分子からなる分散性
の複合体は、加熱による軟凝集は発生せず、また、ココ
ア末が底部に沈積することはないが、層分離が生じ、コ
コアが少なくて色が薄い上層が生じてしまう場合があっ
た。
On the other hand, a dispersible composite made of a naturally-occurring hydrophilic polymer other than sodium carboxymethylcellulose does not cause soft agglomeration by heating, and cocoa powder does not deposit on the bottom. In some cases, layer separation occurs, resulting in an upper layer having little cocoa and a light color.

【0004】[0004]

【発明が解決しようとする課題】本発明は、緩和な殺菌
条件でも懸濁安定性等の充分な安定性を有する飲料等の
食品組成物を提供することを目的とする。
SUMMARY OF THE INVENTION It is an object of the present invention to provide a food composition such as a beverage having sufficient stability such as suspension stability even under mild sterilization conditions.

【0005】[0005]

【課題を解決するための手段】本発明者らは、分散性の
セルロース複合体を特定の組み合わせで併用することに
より、課題を解決できることを見出し、本発明をなすに
至った。すなわち本発明は、セルロースとカルボキシメ
チルセルロース・ナトリウムからなる分散性の複合体
と、セルロースと天然由来の親水性高分子からなる分散
性の複合体を含有することを特徴とする食品組成物に関
する。
Means for Solving the Problems The present inventors have found that the problem can be solved by using a specific combination of dispersible cellulose composites, and have accomplished the present invention. That is, the present invention relates to a food composition comprising a dispersible composite comprising cellulose and sodium carboxymethylcellulose, and a dispersible composite comprising cellulose and a hydrophilic polymer derived from nature.

【0006】以下、本発明につき詳しく説明する。本発
明に使用されるセルロースとカルボキシメチルセルロー
ス・ナトリウムからなる分散性の複合体、および、セル
ロースと天然由来の親水性高分子からなる分散性の複合
体は、例えば、パルプを磨砕して得られた微細セルロー
スを水溶性カルボキシメチルセルロース・ナトリウムも
しくは天然由来の親水性高分子と均一に混合して均質な
スラリーとし、これを乾燥することによって得られる。
セルロース素材の磨砕前に予めカルボキシメチルセルロ
ース・ナトリウムもしくは天然由来の親水性高分子と混
合し、磨砕してスラリーとする方法でもよい。本発明の
複合体としては、公知のものを使用でき、具体的には特
公昭40−14174号公報、特公昭62−43661
号公報、特開平6−335365号公報に記載のものな
どが使用できる。
Hereinafter, the present invention will be described in detail. The dispersible composite composed of cellulose and sodium carboxymethylcellulose used in the present invention, and the dispersible composite composed of cellulose and a naturally occurring hydrophilic polymer are obtained, for example, by grinding pulp. The obtained fine cellulose is uniformly mixed with water-soluble sodium carboxymethylcellulose or a naturally-occurring hydrophilic polymer to form a homogeneous slurry, and the slurry is dried.
Before grinding the cellulose material, a method may be used in which the slurry is mixed with sodium carboxymethylcellulose or a naturally-occurring hydrophilic polymer in advance and ground to form a slurry. As the complex of the present invention, known ones can be used, and specifically, Japanese Patent Publication No. 40-14174 and Japanese Patent Publication No. 62-43661.
And JP-A-6-335365.

【0007】カルボキシメチルセルロース・ナトリウム
としてはカルボキシメチル基の置換度が0.20〜1.
50、重合度が200〜500、2重量%水溶液の粘度
が10〜1000mPa・s程度のものが使用される。
また、天然由来の親水性高分子としてはアラビアガム、
アラビノガラクタン、アルギン酸およびその塩、カード
ラン、ガッティーガム、カラギーナン、カラヤガム、寒
天、キサンタンガム、グアガム、酵素分解グアガム、ク
インスシードガム、ジェランガム、ゼラチン、タマリン
ドガム、難消化性デキストリン、トラガントガム、ファ
ーセラン、プルラン、ペクチン、ローカストビーンガム
などが使用される。これらは単独で使用しても良いし、
また複数を選択して使用してもよい。天然由来の親水性
高分子として好ましいのはカラギーナン、カラヤガム、
キサンタンガム、ジェランガム、難消化性デキストリ
ン、ペクチンである。特に好ましいのは、カラヤガム、
キサンタンガム、難消化性デキストリンである。
[0007] Sodium carboxymethylcellulose has a carboxymethyl group substitution degree of 0.20-1.
A polymer having a degree of polymerization of 200 to 500 and a viscosity of a 2% by weight aqueous solution of about 10 to 1000 mPa · s is used.
Also, as a naturally occurring hydrophilic polymer, gum arabic,
Arabinogalactan, alginic acid and its salts, curdlan, guttie gum, carrageenan, karaya gum, agar, xanthan gum, guar gum, enzymatically decomposed guar gum, quince seed gum, gellan gum, gelatin, tamarind gum, indigestible dextrin, tragacanth gum, furcellan, pullulan , Pectin, locust bean gum and the like are used. These may be used alone,
Alternatively, a plurality may be selected and used. Preferred as naturally occurring hydrophilic polymers are carrageenan, karaya gum,
Xanthan gum, gellan gum, indigestible dextrin and pectin. Particularly preferred are karaya gum,
Xanthan gum is an indigestible dextrin.

【0008】本発明の複合体は水中で機械的に攪拌する
と、平均粒径20μm以下、好ましくは10μm以下、
さらに好ましくは5μm以下のセルロース粒子に分散
し、安定な懸濁液となる特徴を有する。本発明に使用さ
れるセルロースとカルボキシメチルセルロース・ナトリ
ウムからなる分散性の複合体、および、セルロースと天
然由来の親水性高分子からなる分散性の複合体の配合量
はそれぞれ、0.01重量%以上配合する必要がある。
好ましくは0.1%重量以上配合する。特に好ましくは
セルロースと天然由来の親水性高分子からなる分散性の
複合体を0.3重量%以上配合する。0.01重量%未
満の配合量であると充分な懸濁安定性等が発揮されな
い。配合量は食品の種類、添加の目的によって適宜決め
られるものであるが、例えば飲料用途であれば0.05
〜1.0重量%程度が適当であるし、焼き菓子等の食品
であれば0.5〜15重量%程度が適当である。これら
は2種類以上の複合体を同時に使用しても良い。
When the composite of the present invention is mechanically stirred in water, the average particle size is 20 μm or less, preferably 10 μm or less.
More preferably, it is characterized in that it is dispersed in cellulose particles of 5 μm or less to form a stable suspension. The compounding amount of the dispersible composite composed of cellulose and sodium carboxymethylcellulose and the dispersible composite composed of cellulose and a naturally occurring hydrophilic polymer used in the present invention are each 0.01% by weight or more. It needs to be blended.
Preferably, 0.1% by weight or more is added. Particularly preferably, 0.3% by weight or more of a dispersible complex composed of cellulose and a naturally occurring hydrophilic polymer is blended. If the amount is less than 0.01% by weight, sufficient suspension stability and the like cannot be exhibited. The amount is appropriately determined depending on the type of food and the purpose of addition.
The appropriate amount is about 1.0 to 1.0% by weight, and about 0.5 to 15% by weight for food such as baked confectionery. These may use two or more kinds of composites simultaneously.

【0009】本発明の食品組成物とは乳成分を含む、あ
るいは含まないコーヒー、紅茶、抹茶、ココア、汁粉、
ジュース等の嗜好飲料、生乳、加工乳、乳酸菌飲料、豆
乳等の乳性飲料、カルシウム強化飲料等の栄養強化飲料
並びに食物繊維含有飲料等を含む各種の飲料類、アイス
クリーム、アイスミルク、ソフトクリーム、ミルクシェ
ーキ、シャーベット等の氷菓類、バター、チーズ、ヨー
グルト、コーヒーホワイトナー、ホイッピングクリー
ム、カスタードクリーム、プリン等の乳製品類、マヨネ
ーズ、マーガリン、スプレッド、ショートニング等の油
脂加工食品類、各種のスープ、シチュー、ソース、タ
レ、ドレッシング等の調味料類、練りがらしに代表され
る各種練りスパイス、ジャム、フラワーペーストに代表
される各種フィリング、各種のアン、ゼリーを含むゲル
・ペースト状食品類、パン、麺、パスタ、ピザ、各種プ
レミックスを含むシリアル食品類、キャンディー、クッ
キー、ビスケット、ホットケーキ、チョコレート、餅等
を含む和・洋菓子類、蒲鉾、ハンペン等に代表される水
産練り製品、ハム、ソーセージ、ハンバーグ等に代表さ
れる畜産製品、クリームコロッケ、中華用アン、グラタ
ン、ギョーザ等の各種の惣菜類、塩辛、カス漬等の珍味
類、ペットフード類及び経管流動食類等である。特に、
UHT殺菌、あるいはホットパック殺菌によって製造さ
れる、乳成分を含むココア飲料に適している。
[0009] The food composition of the present invention includes coffee, tea, matcha, cocoa, juice powder, with or without a milk component.
Juices and other beverages, raw milk, processed milk, lactic acid beverages, dairy beverages such as soy milk, fortified beverages such as calcium-enriched beverages, and various beverages including dietary fiber-containing beverages, ice cream, ice milk, soft cream Dairy products such as butter, cheese, yogurt, coffee whitener, whipping cream, custard cream, pudding, oil and fat processed foods such as mayonnaise, margarine, spread, shortening, and various soups , Stews, sauces, sauces, seasonings such as dressing, various dough spices represented by dough, jam, various fillings represented by flower paste, various annes, gel paste foods including jelly, Bread, noodles, pasta, pizza, and various premixes Foods, candy, cookies, biscuits, hot cakes, chocolates, Japanese and Western confectionery products including mochi, fish paste products such as kamaboko, hampen, livestock products such as ham, sausage, hamburgers, cream croquettes And various kinds of prepared foods such as Chinese ann, gratin, and gyoza; delicacies such as salted and pickled vegetables; pet foods; and tube foods. In particular,
It is suitable for cocoa beverages containing milk components, which are produced by UHT sterilization or hot pack sterilization.

【0010】これらの食品は懸濁安定性が高い、乳化安
定性が高い、独特な組織を有する、クラウディー性を有
する、食物繊維効果を有する、カロリーが低い、等の特
徴を有する。
These foods have characteristics such as high suspension stability, high emulsification stability, a unique structure, a cloudy property, a dietary fiber effect, and low calories.

【0011】[0011]

【発明の実施の形態】次に、実施例によって本発明をさ
らに詳細に説明する。
Now, the present invention will be described in further detail with reference to Examples.

【0012】[0012]

【実施例1】(1)セルロースとカルボキシメチルセル
ロース・ナトリウムからなる分散性のセルロース複合体
の調製 市販DPパルプ(平均重合度850)を0.8%塩酸中
で加水分解処理を行い、純水にて濾過洗浄し、ウェット
ケーキを得た。このウェットケーキに、セルロース/カ
ルボキシメチルセルロース・ナトリウムの比率が9/1
となるようにカルボキシメチルセルロース・ナトリウム
を加え、ニーダーにて練合・磨砕を行った。次いで、手
でもみほぐしてから熱風乾燥し、ハンマーミルにて粉砕
することにより、「セルロースとカルボキシメチルセル
ロース・ナトリウムからなる分散性のセルロース複合
体」を得た。これを水中に分散すると、平均粒径7.6
μmの微粒子に崩壊した。
Example 1 (1) Preparation of dispersible cellulose composite comprising cellulose and sodium carboxymethylcellulose Commercial DP pulp (average degree of polymerization: 850) was hydrolyzed in 0.8% hydrochloric acid, and purified with pure water. After washing by filtration, a wet cake was obtained. This wet cake has a cellulose / carboxymethylcellulose / sodium ratio of 9/1.
Sodium carboxymethylcellulose was added to the mixture, and kneading and grinding were performed in a kneader. Next, the mixture was loosened by hand, dried with hot air, and pulverized with a hammer mill to obtain a “dispersible cellulose composite comprising cellulose and sodium carboxymethylcellulose”. When this is dispersed in water, the average particle size is 7.6.
Disintegrated into fine particles of μm.

【0013】(2)セルロースと天然由来の親水性高分
子(キサンタンガム)からなる分散性のセルロース複合
体の調製 次に、上記と同様にして得たウェットケーキに水を加え
て固形分10重量%の水分散液を調製し、これを超高圧
ホモジナイザーで、1300kgf/cm2の圧力で2
回破砕処理を行い、ペースト状のセルロースを得た。こ
のペーストに、セルロース/キサンタンガム/澱粉加水
分解物の比率が75/5/20となるようにキサンタン
ガム(ビストップ、三栄化学工業製)と澱粉加水分解物
(パインデックス、松谷化学工業製)を配合し、水を加
えて、総固形分濃度が7重量%の分散液を調製した。こ
の分散液を平滑なアルミニウム板状に約3mmの厚さで
伸展し、熱風乾燥機で80℃60分間乾燥し、得られた
フィルム状物を手でもみほぐし、鱗片状の「セルロース
と天然由来の親水性高分子(キサンタンガム)からなる
分散性のセルロース複合体」乾燥物を得た。これを水中
に分散すると、平均粒径3.2μmの微粒子に崩壊し
た。
(2) Preparation of Dispersible Cellulose Composite Composed of Cellulose and Naturally Derived Hydrophilic Polymer (Xanthan Gum) Next, water was added to the wet cake obtained in the same manner as above to obtain a solid content of 10% by weight. the aqueous dispersion is prepared, this with ultra-high pressure homogenizer, 2 at a pressure of 1300 kgf / cm 2
Repeated crushing treatment was performed to obtain paste-like cellulose. Xanthan gum (bistop, manufactured by Sanei Chemical Industry) and starch hydrolyzate (Paindex, manufactured by Matsutani Chemical Industry) are mixed with this paste so that the ratio of cellulose / xanthan gum / starch hydrolyzate becomes 75/5/20. Then, water was added to prepare a dispersion having a total solid content of 7% by weight. This dispersion is spread on a smooth aluminum plate at a thickness of about 3 mm, dried with a hot air drier at 80 ° C. for 60 minutes, and the resulting film is disintegrated by hand to give a scale-like “cellulose and natural origin”. A dried dispersible cellulose composite comprising a hydrophilic polymer (xanthan gum) was obtained. When this was dispersed in water, it was broken down into fine particles having an average particle size of 3.2 μm.

【0014】(3)ココア飲料の調製 「セルロースとカルボキシメチルセルロース・ナトリウ
ムからなる分散性の複合体」1g、「セルロースと天然
由来の親水性高分子(キサンタンガム)からなる分散性
の複合体」3g、ココア粉末(バン・ホーテン製)5
g、グラニュー糖50g、全脂粉乳(南日本酪農製)8
g、食塩0.5g、乳化剤(エキセル150、花王製)
2gを混合し、75℃の温水に分散後、全量を1kgと
なるように温水を加える。次いで、マントンゴーリン型
ホモジナイザーにて、1回目150kgf/cm2、2
回目200kgf/cm2の圧力で均質化後(2パ
ス)、125℃で8秒間殺菌し、ガラスビンに充填し、
ココア飲料を得た。殺菌直後に軟凝集の発生は観察され
なかった。これを5℃で7日間保存したところ、沈降も
凝集も層分離も見られず、製造直後の均質な状態を保っ
ていた。
(3) Preparation of Cocoa Beverage 1 g of “dispersible complex composed of cellulose and sodium carboxymethylcellulose”, 3 g of “dispersible complex composed of cellulose and a naturally occurring hydrophilic polymer (xanthan gum)” Cocoa powder (made by Van Houten) 5
g, granulated sugar 50 g, whole milk powder (South Japan Dairy) 8
g, salt 0.5 g, emulsifier (Exel 150, manufactured by Kao)
After mixing 2 g and dispersing in hot water at 75 ° C., hot water is added so that the total amount becomes 1 kg. Next, the first 150 kgf / cm 2 , 2 using a Menton-Gaulin type homogenizer
The second time, after homogenizing at a pressure of 200 kgf / cm 2 (2 passes), sterilizing at 125 ° C. for 8 seconds, filling a glass bottle,
I got a cocoa drink. Immediately after sterilization, the occurrence of soft agglomeration was not observed. When this was stored at 5 ° C. for 7 days, no sedimentation, aggregation, or layer separation was observed, and a homogeneous state immediately after the production was maintained.

【0015】[0015]

【比較例1】分散性の複合体として「セルロースとカル
ボキシメチルセルロース・ナトリウムからなる分散性の
複合体」のみを4g用い、それ以外は実施例1と同様の
操作を行って、ココア飲料を得た。殺菌直後に軟凝集の
発生が見られたので、手で強く振盪し、軟凝集を解消し
てから、5℃で7日間保存したところ、層分離は見られ
なかったが、体積として約1%のココア末の沈積が底部
に観察された。
Comparative Example 1 Only 4 g of "dispersible composite comprising cellulose and sodium carboxymethylcellulose" was used as a dispersible composite, and otherwise the same operation as in Example 1 was performed to obtain a cocoa drink. . Since soft coagulation occurred immediately after sterilization, the mixture was vigorously shaken by hand to eliminate soft coagulation and stored at 5 ° C. for 7 days. No layer separation was observed, but about 1% by volume. Of cocoa powder was observed at the bottom.

【0016】[0016]

【比較例2】分散性の複合体として「セルロースと天然
由来の親水性高分子(キサンタンガム)からなる分散性
の複合体」のみを4g用い、それ以外は実施例1と同様
の操作を行って、ココア飲料を得た。殺菌直後におい
て、軟凝集は観察されなかった。これを5℃で7日間保
存したところ、ココア末の沈積は観察されなかったが、
上部35%に希薄な層が観察された。
Comparative Example 2 Only 4 g of “dispersible composite comprising cellulose and a naturally occurring hydrophilic polymer (xanthan gum)” was used as a dispersible composite, and the same operation as in Example 1 was carried out except for that. , Got a cocoa drink. Immediately after sterilization, no soft aggregation was observed. When this was stored at 5 ° C. for 7 days, no cocoa powder deposition was observed,
A dilute layer was observed in the upper 35%.

【0017】[0017]

【発明の効果】本発明の食品は、特定の組み合わせの水
分散性セルロース複合体を含有するものであり、懸濁安
定性が高い、乳化安定性が高い、独特な組織を有する、
クラウディー性を有する、食物繊維効果を有する、カロ
リーが低い、等の特徴を有する。
The food of the present invention contains a specific combination of a water-dispersible cellulose complex, and has a high suspension stability, a high emulsification stability, and a unique structure.
It has features such as cloudiness, a dietary fiber effect, and low calories.

フロントページの続き Fターム(参考) 4B017 LC04 LC10 LE02 LE06 LG05 LK01 LK12 LK13 LL04 LL06 LL09 LP03 LP13 LP16 LP18 LT05 4B018 LB01 LB02 LB03 LB04 LB05 LB06 LB07 LB08 LB09 LB10 LE04 LE05 MS06 MS11 MS13Continued on the front page F term (reference) 4B017 LC04 LC10 LE02 LE06 LG05 LK01 LK12 LK13 LL04 LL06 LL09 LP03 LP13 LP16 LP18 LT05 4B018 LB01 LB02 LB03 LB04 LB05 LB06 LB07 LB08 LB09 LB10 LE04 LE05 MS06 MS11 MS13

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 セルロースとカルボキシメチルセルロー
ス・ナトリウムからなる分散性の複合体と、セルロース
と天然由来の親水性高分子からなる分散性の複合体を含
有することを特徴とする食品組成物
1. A food composition comprising a dispersible composite comprising cellulose and sodium carboxymethylcellulose, and a dispersible composite comprising cellulose and a hydrophilic polymer of natural origin.
JP21562198A 1998-07-30 1998-07-30 Food composition containing a plurality of dispersible cellulose composites Expired - Lifetime JP3522115B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
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Publications (2)

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JP2000041627A true JP2000041627A (en) 2000-02-15
JP3522115B2 JP3522115B2 (en) 2004-04-26

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Country Status (1)

Country Link
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