JP2014114483A - Snout floating scum removal device for molten zinc plating line - Google Patents

Snout floating scum removal device for molten zinc plating line Download PDF

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JP2014114483A
JP2014114483A JP2012269409A JP2012269409A JP2014114483A JP 2014114483 A JP2014114483 A JP 2014114483A JP 2012269409 A JP2012269409 A JP 2012269409A JP 2012269409 A JP2012269409 A JP 2012269409A JP 2014114483 A JP2014114483 A JP 2014114483A
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discharge
snout
molten zinc
flow
scum
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JP6007764B2 (en
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Yusuke Irie
祐輔 入江
Mikio Kawamura
三喜夫 川村
Keisuke Yoshida
圭佑 吉田
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Nippon Steel Corp
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Nippon Steel and Sumitomo Metal Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a technique suppressing dispersion of a discharge flow and reducing quality defects of a steel plate due to the dispersion of the discharge flow in removing scum in a snout by arranging a discharge nozzle and a suction nozzle in the snout to form a discharge flow and using the discharge flow in scum removal.SOLUTION: A discharge nozzle 5 of a snout floating scum removal device is composed of a vertical cylindrical part 8 and a discharge part 9 arranged in the upper end part of the vertical cylindrical part, and the discharge part 9 includes a molten zinc flow inlet 10 connected to the vertical cylindrical part, a box-shaped rectification space 11 rectifying the flow of molten zinc flowing in from the molten zinc flow inlet in the vertically upward direction to in the horizontal direction, a discharge outlet 12 discharging molten zinc toward the inside of the snout in the horizontal direction and a guide space 13 guiding molten zinc from the rectification space to the discharge outlet. The discharge part 9 meets the condition: (the vertical height of the rectification space-the vertical height of the discharge outlet)/the vertical height of the discharge outlet≥0.2.

Description

本発明は、溶融亜鉛めっきラインにおけるスナウト内浮遊スカム除去装置に関するものである。   The present invention relates to a device for removing floating scum in a snout in a hot dip galvanizing line.

図１１に示すように、溶融亜鉛めっきラインは、還元焼鈍炉１と溶融亜鉛ポット３の間を連結する筒状のスナウト４を備えている。スナウト４は、還元焼鈍炉１で処理された鋼帯２を還元性雰囲気で保護したまま、溶融亜鉛ポット３中に浸漬するための機能を有するものであり、その一端部は、還元焼鈍炉１に接続され、他端部は溶融亜鉛ポット３中に部分的に浸漬されており、スナウト４内部には、還元性雰囲気ガスが満たされている。   As shown in FIG. 11, the hot dip galvanizing line includes a cylindrical snout 4 that connects between the reduction annealing furnace 1 and the hot dip zinc pot 3. The snout 4 has a function of immersing the steel strip 2 treated in the reduction annealing furnace 1 in the molten zinc pot 3 while protecting the steel strip 2 in a reducing atmosphere, and one end thereof is the reduction annealing furnace 1. The other end is partially immersed in the molten zinc pot 3, and the inside of the snout 4 is filled with a reducing atmosphere gas.

スナウト４内では、亜鉛浴の表面から蒸発した亜鉛が内壁に凝縮付着して粉末状のスカムとなる現象が不可避的に生じている。スナウト４内で内壁に付着したスカムが、振動等によって浴表面に落下して、鋼帯２に付着すると、品質欠陥の要因となる。そこで、従来、図１２に示すように、スナウト４内で、亜鉛浴の表面に流動を形成させて、浴面に浮遊する浮遊スカムを系外に排出する手法が広く採用されている。特許文献１には、溶融亜鉛を吐出する吐出ノズル５と、溶融亜鉛と共にスカムを吸引する吸込ノズル６を、スナウト４内の溶融亜鉛ポット表面近傍に対向配置することにより亜鉛浴の表面に流動を形成させる技術が開示されている。従来の吐出ノズル５は、図１３に示すように、垂直に配置した管状部材の先端を吐出方向に向けて開口させた単純形状からなるものが一般的である。   In the snout 4, a phenomenon in which zinc evaporated from the surface of the zinc bath condenses and adheres to the inner wall to form powdery scum is unavoidable. If the scum adhering to the inner wall in the snout 4 falls on the bath surface due to vibration or the like and adheres to the steel strip 2, it causes a quality defect. Therefore, conventionally, as shown in FIG. 12, a method of forming a flow on the surface of the zinc bath in the snout 4 and discharging the floating scum floating on the bath surface to the outside of the system has been widely adopted. In Patent Document 1, a discharge nozzle 5 that discharges molten zinc and a suction nozzle 6 that sucks scum together with molten zinc are arranged in the vicinity of the surface of the molten zinc pot in the snout 4 so as to flow on the surface of the zinc bath. Techniques for forming are disclosed. As shown in FIG. 13, the conventional discharge nozzle 5 generally has a simple shape in which the tip of a vertically arranged tubular member is opened in the discharge direction.

しかし、図１３に示すような吐出ノズル５を用いると、図１４に示すように、吐出流が浴内部に分散してしまい、この吐出流の分散が、新たな品質欠陥の要因となる問題があった。具体的には、スナウト内壁方向に吐出流が分散すると、スナウト内壁付近の流速が高くなり、壁面に付着したスカムが剥離して浴表面の清浄度が低下し、鋼板の品質欠陥の要因となる問題があった。また、吐出流が浴内部に分散して浴表面が波立つと、鋼板に波目上の模様が発生して品質欠陥となる問題があった。更に、吐出流が浴内部に分散すると、浴表面流速が低下して、スカムが排出される前に鋼板に付着して品質欠陥となる問題があった。   However, when the discharge nozzle 5 as shown in FIG. 13 is used, as shown in FIG. 14, the discharge flow is dispersed inside the bath, and this dispersion of the discharge flow causes a new quality defect. there were. Specifically, when the discharge flow is dispersed in the direction of the inner wall of the snout, the flow velocity near the inner wall of the snout is increased, the scum adhering to the wall surface is peeled off, and the cleanliness of the bath surface is lowered, which causes the quality defect of the steel sheet. There was a problem. In addition, when the discharge flow is dispersed inside the bath and the bath surface undulates, there is a problem that a wavy pattern is generated on the steel sheet, resulting in a quality defect. Furthermore, when the discharge flow is dispersed inside the bath, the bath surface flow velocity is lowered, and there is a problem that the scum is adhered to the steel plate before being discharged, resulting in a quality defect.

なお、浴表面流速の低下を補って目的の浴表面流速を得るためには、大型の吐出ポンプを用いて吐出流量を多くする必要があり、吐出流量を多くすると前記の各問題が助長される悪循環となる問題や、設備コストが増大するといった問題もあった。   In order to compensate for the decrease in bath surface flow velocity and obtain the desired bath surface flow velocity, it is necessary to increase the discharge flow rate using a large discharge pump, and increasing the discharge flow rate promotes each of the above problems. There were also problems such as vicious circles and increased equipment costs.

特開平８−２６９６５９号公報JP-A-8-269659

本発明の目的は前記問題を解決し、スナウト内に吐出ノズルと吸込ノズルを設けて吐出流を形成し、この吐出流を用いてスナウト内のスカム除去を行う際に、吐出流の分散を抑え、吐出流の分散に起因して生じていた鋼板の品質欠陥を低減する技術を提供することである。   The object of the present invention is to solve the above-mentioned problems, and to form a discharge flow by providing a discharge nozzle and a suction nozzle in the snout, and to suppress the dispersion of the discharge flow when removing the scum in the snout using this discharge flow. Another object of the present invention is to provide a technique for reducing the quality defect of the steel sheet that has been caused by the dispersion of the discharge flow.

上記課題を解決するためになされた本発明の溶融亜鉛めっきラインにおけるスナウト内浮遊スカム除去装置は、溶融亜鉛めっきラインにおいて、還元焼鈍炉と溶融亜鉛ポットを連結するスナウト内の亜鉛浴表面近傍で、スナウト内を通過する鋼帯の両側付近に、各々、溶融亜鉛を吐出する吐出ノズルと、溶融亜鉛と共にスカムを吸引する吸込ノズルを対向配置し、吐出ノズルから吸込ノズルに向かう流動を形成しながらスナウト内を浮遊するスカムを除去するスナウト内浮遊スカム除去装置であって、該吐出ノズルは、垂直筒部と、該垂直筒部の上端部に配置された吐出部からなり、該吐出部は、垂直筒部と接続する溶融亜鉛流入口と、該溶融亜鉛流入口から垂直上向きに流入してくる溶融亜鉛の流れを水平方向に整流する箱状の整流空間と、スナウト内に向けて水平方向に溶融亜鉛を吐出する吐出口と、整流空間から吐出口へと溶融亜鉛の流れをガイドするガイド空間を有し、（整流空間の垂直高さ―吐出口の垂直高さ）／吐出口の垂直高さ ≧ ０．２を満足することを特徴とするものである。   In the hot dip galvanizing line, the apparatus for removing floating scum in the hot dip galvanizing line of the present invention, which has been made to solve the above-mentioned problems, is near the zinc bath surface in the snout connecting the reduction annealing furnace and the hot dip zinc pot in the hot dip galvanizing line. In the vicinity of both sides of the steel strip passing through the snout, a discharge nozzle that discharges molten zinc and a suction nozzle that sucks scum together with the molten zinc are arranged oppositely to form a flow from the discharge nozzle to the suction nozzle. A device for removing floating scum in a snout that removes scum floating inside, wherein the discharge nozzle includes a vertical tube portion and a discharge portion disposed at an upper end portion of the vertical tube portion. A molten zinc inlet connected to the cylindrical portion, and a box-shaped rectifying space for horizontally rectifying the flow of molten zinc flowing vertically upward from the molten zinc inlet. It has a discharge port that discharges molten zinc horizontally into the snout and a guide space that guides the flow of molten zinc from the rectifying space to the discharge port (vertical height of the rectifying space-vertical height of the discharge port Sa) / vertical height of discharge port ≧ 0.2 is satisfied.

請求項２記載の発明は、請求項1記載の溶融亜鉛めっきラインにおけるスナウト内浮遊スカム除去装置において、ガイド空間の水平方向距離／整流空間の方向距離≧ ０．２を満足することを特徴とするものである。   The invention described in claim 2 is characterized in that, in the apparatus for removing floating scum in the snout in the hot dip galvanizing line according to claim 1, the horizontal distance of the guide space / the directional distance of the rectifying space ≧ 0.2. Is.

吐出ノズルを、垂直筒部と、該垂直筒部の上端部に配置された吐出部から構成し、該吐出部は、垂直筒部と接続する溶融亜鉛流入口と、該溶融亜鉛流入口から垂直上向きに流入してくる溶融亜鉛の流れを水平方向に整流する箱状の整流空間と、スナウト内に向けて水平方向に溶融亜鉛を吐出する吐出口と、整流空間から吐出口へと溶融亜鉛の流れをガイドするガイド空間を有し、（整流空間の垂直高さ―吐出口の垂直高さ）／吐出口の垂直高さ ≧ ０．２を満足するものとすることにより、吐出ノズル内で、溶融亜鉛流入口から高速で流入してくる溶融亜鉛の垂直流れを、吐出口上端よりも高い位置にある整流空間上面に流路を長くとりながら衝突させることで、水平方向に整流して吐出することができ、従来技術に比べて、スナウト内浴表面の波立ちが低減し、かつ鋼板幅方向の（平均）流速が増加する。また、ガイド空間を有することにより、吐出流をガイドすることができ、図７に示すように、従来技術に比べて、吐出流の分散が抑制される。   The discharge nozzle is composed of a vertical cylinder part and a discharge part disposed at the upper end of the vertical cylinder part, and the discharge part is connected to the vertical cylinder part and is perpendicular to the molten zinc inlet. A box-shaped rectifying space that rectifies the flow of molten zinc flowing upward upward in the horizontal direction, a discharge port that discharges molten zinc horizontally into the snout, and a flow of molten zinc from the rectifying space to the discharge port By having a guide space for guiding the flow and satisfying (vertical height of rectifying space−vertical height of discharge port) / vertical height of discharge port ≧ 0.2, in the discharge nozzle, The vertical flow of molten zinc flowing in at high speed from the molten zinc inflow port is rectified in the horizontal direction and discharged by colliding with the upper surface of the rectifying space that is higher than the upper end of the discharge port while taking a long flow path. Compared to the prior art, the bath inside the snout table Surface waviness is reduced and the (average) flow velocity in the width direction of the steel sheet is increased. Moreover, by having a guide space, it is possible to guide the discharge flow, and as shown in FIG. 7, dispersion of the discharge flow is suppressed as compared with the conventional technique.

本発明のスナウト内浮遊スカム除去装置の要部正面図である。It is a principal part front view of the floating scum removal apparatus in the snout of this invention. 吐出ノズルの正面図である。It is a front view of a discharge nozzle. 吐出ノズルの前側面図である。It is a front side view of a discharge nozzle. 吐出ノズルの上面図である。It is a top view of a discharge nozzle. 吐出ノズル内の整流作用を説明する図（吐出ノズルの正面図）である。It is a figure (front view of a discharge nozzle) explaining the rectification | straightening effect | action in a discharge nozzle. 吐出ノズル内の整流作用を説明する図（吐出ノズルの上面図）である。It is a figure (top view of a discharge nozzle) explaining the rectification | straightening effect | action in a discharge nozzle. 吐出流の流速分布を、従来技術と本発明で対比して示す図であるIt is a figure which shows the flow velocity distribution of a discharge flow in contrast with a prior art and this invention. 本発明の効果を示す図である（波立ち低減）。It is a figure which shows the effect of this invention (reduction of a wave). 本発明の効果を示す図である（内壁付近流速低減）。It is a figure which shows the effect of this invention (inner wall vicinity flow velocity reduction). 本発明の効果を示す図である（平均流速増加）。It is a figure which shows the effect of this invention (average flow velocity increase). 溶融亜鉛めっきラインの説明図である。It is explanatory drawing of a hot dip galvanizing line. 従来のスナウト内浮遊スカム除去装置の要部正面図である。It is a principal part front view of the conventional floating scum removal apparatus in a snout. 従来の吐出ノズルの正面図である。It is a front view of the conventional discharge nozzle. 従来の吐出流の流速分布を示す図である。It is a figure which shows the flow velocity distribution of the conventional discharge flow.

以下に本発明の好ましい実施形態を示す。   Preferred embodiments of the present invention are shown below.

図１１に示したように、スナウト４の一端部は、還元焼鈍炉１に接続され、他端部は溶融亜鉛ポット３中に部分的に浸漬されている。スナウト４の溶融亜鉛ポット３中に浸漬されている部分は、亜鉛に対する耐食性に優れた材料（セラミックス、または耐熱鋼鋳鋼品など）によって構成されている。スナウト４の内部には、還元性雰囲気ガス（たとえば５０％Ｈ2−５０％Ｎ2）が導入されている。 As shown in FIG. 11, one end portion of the snout 4 is connected to the reduction annealing furnace 1, and the other end portion is partially immersed in the molten zinc pot 3. The portion immersed in the molten zinc pot 3 of the snout 4 is made of a material (ceramics, heat-resistant steel cast steel product, etc.) having excellent corrosion resistance against zinc. A reducing atmosphere gas (for example, 50% H 2 -50% N 2 ) is introduced inside the snout 4.

本発明のスナウト内浮遊スカム除去装置は、スナウト４内の亜鉛浴表面近傍に流動を形成させ、スナウト４内で発生したスカムを鋼帯に付着させずに系外に排出する機能を有するものであり、図１に示すように、溶融亜鉛を吐出する吐出ノズル５と、溶融亜鉛と共にスカムを吸引する吸込ノズル６を有し、その他は、図示を省略した供給管路や吸込管路やポンプ等、従来技術と同様に構成されている。   The in-snout floating scum removing device of the present invention has a function of forming a flow near the surface of the zinc bath in the snout 4 and discharging the scum generated in the snout 4 out of the system without adhering to the steel strip. Yes, as shown in FIG. 1, it has a discharge nozzle 5 for discharging molten zinc, and a suction nozzle 6 for sucking scum together with molten zinc, and the others are a supply line, a suction line, a pump, etc. (not shown) The configuration is the same as in the prior art.

図１４に示したように、図１３に示す吐出ノズルを用いる従来技術では、吐出流が浴内部に分散し、特に、スナウト内壁付近の流速が高くなるとともに、浴表面流速が低下する現象が観察されたが、本発明では、吐出ノズル５を、図２〜図４に示す形状とすることにより、吐出流の分散を抑制することができる。   As shown in FIG. 14, in the prior art using the discharge nozzle shown in FIG. 13, the discharge flow is dispersed inside the bath, and in particular, a phenomenon is observed in which the flow velocity near the inner wall of the snout increases and the bath surface flow velocity decreases. However, in the present invention, the discharge nozzle 5 is formed in the shape shown in FIGS.

本発明の吐出ノズル５は、図２〜図４に示すように、垂直筒部８と、該垂直筒部の上端部に配置された吐出部９から構成されている。   As shown in FIGS. 2 to 4, the discharge nozzle 5 of the present invention includes a vertical cylinder portion 8 and a discharge portion 9 disposed at the upper end portion of the vertical cylinder portion.

吐出部９は、垂直筒部８と接続する溶融亜鉛流入口１０と、該溶融亜鉛流入口１０から垂直上向きに流入してくる溶融亜鉛の流れを水平方向に整流する箱状の整流空間１１と、スナウト４内に向けて水平方向に溶融亜鉛を吐出する吐出口１２と、整流空間１１から吐出口１２へと溶融亜鉛の流れをガイドするガイド空間１３を有し、図２に示すように、（整流空間の垂直高さ―吐出口の垂直高さ）＝Ｈ２、吐出口の垂直高さ ＝Ｈ１、ガイド空間の水平方向距離＝Ｌ１、整流空間の方向距離＝Ｌ２としたとき、Ｈ２／Ｈ１≧ ０．２およびＬ１／Ｌ２≧ ０．２の関係を満足している。尚、Ｈ２は、流れを確実に整流するために整流空間上部に一定以上の空間が必要なため１０ｍｍ以上であることが好ましい。Ｈ２の上限は特に規定しないが、あまり寸法を取りすぎると吐出部９上方でよどみが生じることもあるので２００ｍｍ以下であれば好ましい。またＬ１は、流れの分散を抑制するために１０ｍｍ以上であることが好ましい。Ｌ１の上限は特に規定しないが、あまり寸法を取りすぎると鋼板や周辺機器との干渉もあるので３００ｍｍ以下であれば好ましい。Ｈ１、Ｌ２は吐出させる溶融亜鉛の量や垂直筒部８のサイズなどに応じ、適宜決める。   The discharge part 9 includes a molten zinc inlet 10 connected to the vertical cylinder part 8, and a box-shaped rectifying space 11 that rectifies the flow of molten zinc flowing vertically upward from the molten zinc inlet 10 in the horizontal direction. , Having a discharge port 12 that discharges molten zinc horizontally into the snout 4 and a guide space 13 that guides the flow of molten zinc from the rectifying space 11 to the discharge port 12, as shown in FIG. (Vertical height of rectifying space−vertical height of discharge port) = H2, vertical height of discharge port = H1, horizontal distance of guide space = L1, and direction distance of rectifying space = L2, H2 / H1 The relationship of ≧ 0.2 and L1 / L2 ≧ 0.2 is satisfied. H2 is preferably 10 mm or more because a certain amount of space is required above the rectifying space in order to reliably rectify the flow. The upper limit of H2 is not particularly defined, but if the dimension is too large, stagnation may occur above the discharge unit 9, so 200 mm or less is preferable. Further, L1 is preferably 10 mm or more in order to suppress flow dispersion. The upper limit of L1 is not particularly defined, but if it is too large, there is interference with the steel plate and peripheral devices, so 300 mm or less is preferable. H1 and L2 are appropriately determined according to the amount of molten zinc to be discharged, the size of the vertical cylindrical portion 8, and the like.

吐出ノズル５を上記構成とすることにより、図５〜６に示すように、溶融亜鉛流入口１０から高速で流入してくる溶融亜鉛の垂直流れを、整流空間１１とガイド空間１３を介して、流路を長くとりながら水平方向に整流して吐出させることができ、図７に示すように、従来技術に比べて、吐出流の分散が抑制することができる。   By setting the discharge nozzle 5 to the above configuration, as shown in FIGS. 5 to 6, the vertical flow of molten zinc flowing at high speed from the molten zinc inflow port 10 is caused to flow through the rectifying space 11 and the guide space 13. Rectification in the horizontal direction and discharge can be performed while taking a long flow path, and as shown in FIG. 7, dispersion of the discharge flow can be suppressed as compared with the prior art.

本発明の効果を、模擬試験機（実機１／２サイズ）で検証した結果、図８に示すように浴表面の波立ちが低減され、図９に示すようにスナウト内壁付近の流速が低減し、図１０に示すように鋼板幅方向の（平均）流速が増加することが確認された。   As a result of verifying the effect of the present invention with a simulation test machine (actual machine 1/2 size), the ripple on the bath surface is reduced as shown in FIG. 8, and the flow velocity near the inner wall of the snout is reduced as shown in FIG. As shown in FIG. 10, it was confirmed that the (average) flow velocity in the width direction of the steel sheet increased.

更に、本発明の効果を、実機試験で検証したところ、鋼板へのスナウト内浴面浮遊スカムの付着量が約半分に低減することが確認された。   Furthermore, when the effect of the present invention was verified by an actual machine test, it was confirmed that the adhesion amount of the bath surface floating scum in the snout to the steel sheet was reduced to about half.

１ 還元焼鈍炉
２ 鋼帯
３ 溶融亜鉛ポット
４ スナウト
５ 吐出ノズル
６ 吸込ノズル
８ 垂直筒部
９ 吐出部
１０ 溶融亜鉛流入口
１１ 整流空間
１２ 吐出口
１３ ガイド空間 DESCRIPTION OF SYMBOLS 1 Reduction annealing furnace 2 Steel strip 3 Molten zinc pot 4 Snout 5 Discharge nozzle 6 Suction nozzle 8 Vertical cylinder part 9 Discharge part 10 Molten zinc inlet 11 Rectification space 12 Discharge opening 13 Guide space

Claims (2)

溶融亜鉛めっきラインにおいて、還元焼鈍炉と溶融亜鉛ポットを連結するスナウト内の溶融亜鉛ポット表面近傍で、スナウト内を通過する鋼帯の両側付近に、各々、溶融亜鉛を吐出する吐出ノズルと、溶融亜鉛と共にスカムを吸引する吸込ノズルを対向配置し、吐出ノズルから吸込ノズルに向かう流動を形成しながらスナウト内を浮遊するスカムを除去するスナウト内浮遊スカム除去装置であって、
該吐出ノズルは、垂直筒部と、該垂直筒部の上端部に配置された吐出部からなり、
該吐出部は、垂直筒部と接続する溶融亜鉛流入口と、該溶融亜鉛流入口から垂直上向きに流入してくる溶融亜鉛の流れを水平方向に整流する箱状の整流空間と、スナウト内に向けて水平方向に溶融亜鉛を吐出する吐出口と、整流空間から吐出口へと溶融亜鉛の流れをガイドするガイド空間を有し、
（整流空間の垂直高さ―吐出口の垂直高さ）／吐出口の垂直高さ ≧ ０．２を満足することを特徴とする溶融亜鉛めっきラインにおけるスナウト内浮遊スカム除去装置。 In the hot dip galvanizing line, in the vicinity of the surface of the hot dip zinc pot in the snout connecting the reduction annealing furnace and the hot dip zinc pot, in the vicinity of both sides of the steel strip passing through the snout, respectively, a discharge nozzle for discharging hot zinc, and melting An in-snout floating scum removing device that disposes a suction nozzle that sucks scum together with zinc and removes scum floating in the snout while forming a flow from the discharge nozzle to the suction nozzle,
The discharge nozzle is composed of a vertical tube portion and a discharge portion disposed at an upper end portion of the vertical tube portion,
The discharge section includes a molten zinc inlet connected to the vertical cylinder section, a box-shaped rectifying space for horizontally rectifying the flow of molten zinc flowing vertically upward from the molten zinc inlet, and a snout A discharge port that discharges molten zinc in a horizontal direction toward the discharge port, and a guide space that guides the flow of molten zinc from the rectifying space to the discharge port,
A vertical scum removal device in a hot dip galvanizing line that satisfies (vertical height of flow straightening space−vertical height of discharge port) / vertical height of discharge port ≧ 0.2. ガイド空間の水平方向距離／整流空間の方向距離≧ ０．２を満足することを特徴とする請求項1記載の溶融亜鉛めっきラインにおけるスナウト内浮遊スカム除去装置。   2. The apparatus for removing floating scum in a snout in a hot dip galvanizing line according to claim 1, wherein the horizontal distance of the guide space / the direction distance of the rectifying space ≧ 0.2.
JP2012269409A 2012-12-10 2012-12-10 Floating scum removal device in snout in hot dip galvanizing line Active JP6007764B2 (en)

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