JP2008024970A - Method of manufacturing galvanized steel sheet having excellent appearance - Google Patents

Method of manufacturing galvanized steel sheet having excellent appearance Download PDF

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JP2008024970A
JP2008024970A JP2006196736A JP2006196736A JP2008024970A JP 2008024970 A JP2008024970 A JP 2008024970A JP 2006196736 A JP2006196736 A JP 2006196736A JP 2006196736 A JP2006196736 A JP 2006196736A JP 2008024970 A JP2008024970 A JP 2008024970A
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snout
flow
steel sheet
pump
plating bath
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JP4855166B2 (en
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Tatsuya Kuwana
達也 桑名
Hiroyuki Tanaka
博之 田中
Kengo Noma
憲吾 野間
Takaatsu Tanaka
孝篤 田中
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Nippon Steel Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To manufacture a galvanized steel sheet having excellent appearance by preventing occurrence of surface defects and surface appearance defects caused by the stagnation of a molten zinc and foreign matters on a plating bath surface. <P>SOLUTION: In the method of manufacturing the galvanized steel sheet, by which a steel sheet is entered into a plating bath by being passed through a snout, the lower end of which is immersed in the plating bath, (a) a metal pump is arranged below a plating bath surface inside the snout across the steel plate, (b) (b-1) a fairing member with its lower end being immersed in the plating bath at least over the width of the steel plate (b-3) is installed while keeping a predetermined space from the metal pump (b-2) with a space equivalent to or smaller than the width of a discharge port or a suction port of the metal pump. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、美麗で鮮明な表面外観を備える溶融亜鉛めっき鋼板の製造方法に関するものである。   The present invention relates to a method for producing a hot-dip galvanized steel sheet having a beautiful and clear surface appearance.

従来から、溶融亜鉛めっき鋼板(合金化溶融亜鉛めっき鋼板を含む)は、自動車、家庭電気製品等用の鋼板として、汎用的に使用されてきたが、近年、製品の付加価値をより高め、他製品との差別化を図る観点から、美麗で鮮明な外観を備える溶融亜鉛めっき鋼板の需要が急増する傾向にある。   Conventionally, hot-dip galvanized steel sheets (including alloyed hot-dip galvanized steel sheets) have been used for general purposes as steel sheets for automobiles, household electrical products, etc. From the viewpoint of differentiation from products, the demand for hot dip galvanized steel sheets with a beautiful and clear appearance tends to increase rapidly.

美麗で鮮明な表面外観を備える溶融亜鉛めっき鋼板を製造するためには、製造工程において工程管理を厳格に行うことにより微小な表面欠陥を極力低減し、表面性状を従来以上に高める必要がある。   In order to produce a hot-dip galvanized steel sheet having a beautiful and clear surface appearance, it is necessary to reduce surface defects as much as possible by reducing strict surface defects as much as possible by strictly controlling the process in the production process.

通常、溶融亜鉛めっきにおいては、図1に示すように、焼鈍後の鋼板1を、上部が焼鈍炉(図示なし)に接続され、下端が、めっき槽5のめっき浴3に浸漬されたスナウト2の内部を通して、めっき浴3に浸入せしめ、浴中のポットロール4で進行方向を変えて上方に引上げ、ガスワイピングノズル6からガスを噴出して溶融亜鉛の付着量を調整する。   Normally, in hot dip galvanizing, as shown in FIG. 1, the steel plate 1 after annealing is connected to an annealing furnace (not shown), and the lower end is immersed in a plating bath 3 of a plating tank 5. Into the plating bath 3, the pot roll 4 in the bath changes the advancing direction and pulls upward, and the gas wiping nozzle 6 ejects gas to adjust the adhesion amount of molten zinc.

しかし、スナウト2内部のめっき浴面にはスカム、ドロス等の液状異物7が浮遊していて、液状異物7が、鋼板をめっき浴に浸漬する際、鋼板表面に付着すると表面欠陥が形成される。それ故、これまで、スカム、ドロス等の生成を抑制する方法や、スカム、ドロス等の鋼板表面への付着を抑制する方法が数多く提案された(特許文献1〜6、参照)。   However, liquid foreign matters 7 such as scum and dross are floating on the plating bath surface inside the snout 2, and surface defects are formed when the liquid foreign matters 7 adhere to the steel plate surface when the steel plate is immersed in the plating bath. . Therefore, many methods have been proposed so far for suppressing the generation of scum, dross and the like and for suppressing the adhesion of scum and dross to the steel sheet surface (see Patent Documents 1 to 6).

特許文献1〜3には、めっき浴面で鋼板にガスを噴きつけ、スカム、ドロス等の液状異物を、鋼板周囲から排除する方法が開示されている。この方法によれば、鋼板周囲から液状異物を全面的にかつ継続的に排除することができるので、鋼板表面の欠陥を顕著に低減することができる。   Patent Documents 1 to 3 disclose a method in which gas is sprayed onto a steel sheet on the plating bath surface to exclude liquid foreign matters such as scum and dross from the periphery of the steel sheet. According to this method, liquid foreign substances can be eliminated entirely and continuously from the periphery of the steel sheet, so that defects on the surface of the steel sheet can be significantly reduced.

しかし、噴出ガスにより、スナウト内部の雰囲気温度が低下し、この温度低下は、蒸発した亜鉛ヒュームの凝結を促進するので、特許文献1〜3開示の方法は、スカムやドロスを低減することができても、ガス噴出による雰囲気温度の低下により、付着物がスナウト壁面から落下するのを抑制することができず、実用的な方法でない。   However, the atmospheric temperature inside the snout is lowered by the jet gas, and this temperature reduction promotes the condensation of the evaporated zinc fume. Therefore, the methods disclosed in Patent Documents 1 to 3 can reduce scum and dross. However, it is not a practical method because it is not possible to suppress the deposit from dropping from the wall surface of the snout due to a decrease in the atmospheric temperature due to gas ejection.

また、特許文献1〜3記載の方法においては、噴出ガスにより、めっき浴面が乱され、この乱れが、流れ模様として、鋼板表面に転写されることがある。このめっき面上の流れ模様は、表面外観欠陥であり、スカム、ドロス等に起因する表面欠陥が顕著に低減されていても、めっき鋼板の商品価値を大きく損なうことになる。   Moreover, in the method of patent documents 1-3, a plating bath surface is disturbed by jet gas, and this disorder may be transcribe | transferred on the steel plate surface as a flow pattern. This flow pattern on the plated surface is a surface appearance defect, and even if the surface defect due to scum, dross or the like is significantly reduced, the commercial value of the plated steel sheet is greatly impaired.

特許文献4には、スナウト内部において、めっき浴面上にスカムが生成しても、スカムが鋼板表面に付着する前に、メタルポンプでスカムを吸引、除去する装置が開示されている。しかし、上記装置においては、メタルポンプの吸引能力を増強するとともに、常時、稼動しておくことが必要であるので、メタルポンプの寿命が短い。また、鋼板の幅、通板速度などの製造条件が変わった時には、メタルポンプの新設が、その都度必要になるので、特許文献4開示の装置は経済的でない。   Patent Document 4 discloses a device that sucks and removes scum with a metal pump before the scum adheres to the steel plate surface even if scum is generated on the plating bath surface inside the snout. However, in the above-described apparatus, it is necessary to enhance the suction capability of the metal pump and to always operate it, so that the life of the metal pump is short. In addition, when manufacturing conditions such as the width of the steel plate and the plate passing speed change, a new metal pump is required each time, so the apparatus disclosed in Patent Document 4 is not economical.

特許文献5には、スナウトの下端にヒーターを設置して、スタウト内壁を、所定温度に加熱し、めっき浴面上での亜鉛凝固膜の生成と、浮遊ドロスのスタウト内壁面への固着を防止するとともに、浮遊ドロスを、スナウトポンプで、適時、吸引、除去する方法が開示されている。   In Patent Document 5, a heater is installed at the lower end of the snout, and the inner wall of the stout is heated to a predetermined temperature to prevent the formation of a solidified zinc film on the plating bath surface and the sticking of floating dross to the inner wall of the stout. At the same time, a method for sucking and removing floating dross with a snout pump in a timely manner is disclosed.

特許文献5開示の方法は、浮遊ドロスの吸引、除去を、生成量に応じて、適時、実施すればよい点で、効率的な方法であり、また、スナウトポンプの寿命も長い方法である。しかし、特許文献5開示の方法においては、スナウト内のドロス量や、澱み発生量を、外から把握することが困難であり、メタルポンプが短時間でも停止し、溶融金属の流れが中断すると、めっき面の外観は大きく影響を受けるので、設備として適用することはできない。   The method disclosed in Patent Document 5 is an efficient method in that the suction and removal of the floating dross may be performed in a timely manner according to the generation amount, and the method also has a long life of the snout pump. However, in the method disclosed in Patent Document 5, it is difficult to grasp the amount of dross in the snout and the amount of stagnation from the outside, the metal pump stops even for a short time, and the flow of the molten metal is interrupted, Since the appearance of the plated surface is greatly affected, it cannot be applied as equipment.

また、特許文献5開示の方法は、スナウトポンプを適時駆動する制御装置が必要となる点で、設備的に経済的でないし、さらに、鋼板の幅、通板速度などの製造条件が変わった時には、メタルポンプの新設が、その都度必要になるので、経済的でない。   In addition, the method disclosed in Patent Document 5 is not economical in terms of equipment because it requires a control device that drives the snout pump in a timely manner. Further, when manufacturing conditions such as the width of the steel plate and the plate passing speed change. Since a new metal pump is required each time, it is not economical.

また、特許文献6には、めっき浴面近傍で、溶融亜鉛の横方向の流れ(鋼板表面に沿う流れ)を形成する際にプッシュポンプの吐出口を2つにして吐出させ、鋼板表面の流れを小さくすると、鋼板表面の流れ模様が発生しないこと、スカム、ドロス膜の鋼板表面への付着を防止するとともに、該スカム、ドロス膜を除去する方法及び装置が開示されている。   Further, in Patent Document 6, when forming a lateral flow (flow along the steel plate surface) of molten zinc in the vicinity of the plating bath surface, the discharge of the push pump is made to be two, and the flow on the steel plate surface is discharged. A method and apparatus for removing the scum and dross film as well as preventing the flow pattern on the steel sheet surface from being reduced and preventing the scum and dross film from adhering to the steel sheet surface are disclosed.

特許文献6開示の方法を効果的に実施するためには、吐出側のメタルポンプの吐出能力を増強し、吐出量を増大する必要がある。また、安定した流れを確保して湯面変動に対応するためには、吐出口及び吸引口を上下に可動可能に設ける必要がある。   In order to effectively implement the method disclosed in Patent Document 6, it is necessary to increase the discharge capacity of the metal pump on the discharge side and increase the discharge amount. Moreover, in order to ensure a stable flow and cope with fluctuations in the molten metal surface, it is necessary to provide the discharge port and the suction port so as to be movable up and down.

吐出口及び吸入口が上下に可動しない現状使用のプッシュポンプとプルポンプを用いて特許文献6開示の方法を実施しようとすると、湯面に変動が有る場合には、安定した流れが得られず、模様性欠陥やドロス性欠陥が発生する。   When trying to carry out the method disclosed in Patent Document 6 using a push pump and a pull pump that are currently used in which the discharge port and the suction port do not move up and down, a stable flow cannot be obtained if there is fluctuation in the molten metal surface, Pattern defects and dross defects occur.

さらに、現状で使用しているプッシュポンプとプルポンプを用いて、流れ模様の発生を抑制することは、特許文献6に記載されていない。   Furthermore, it is not described in Patent Document 6 to suppress the occurrence of a flow pattern using a push pump and a pull pump that are currently used.

したがって、溶融亜鉛めっき技術においては、めっき浴面にガスを吹き付けなくても、また、メタルポンプの能力を増強しなくても、鋼板表面に沿って、所要流速の溶融亜鉛の整流を適確な幅で形成して、スカム、ドロス等の鋼板表面への付着を防止し、かつ、スナウト内の溶融金属の流れに起因する模様性欠陥を防止して、表面欠陥及び表面外観欠陥が皆無の鮮麗なめっき面を得ることが求められている。   Therefore, in hot dip galvanizing technology, it is possible to accurately rectify molten zinc at the required flow rate along the surface of the steel sheet without blowing gas on the plating bath surface and without increasing the capacity of the metal pump. It is formed with a width to prevent adhesion of scum, dross, etc. to the surface of the steel sheet, and to prevent pattern defects caused by the flow of molten metal in the snout. It is required to obtain a smooth plating surface.

特開平07−150323号公報Japanese Patent Laid-Open No. 07-150323 特開平09−228016号公報JP 09-228016 A 特開2000−64015号公報JP 2000-64015 A 特開2001−049412号公報JP 2001-049412 A 特開2002−275606号公報JP 2002-275606 A 特開2003−293107号公報JP 2003-293107 A

本発明は、上記要望に鑑み、(i)めっき浴面にガスを吹き付ける手法を採用せず、鋼板の両側に配置した現状のメタルポンプ(プッシュポンプとプルポンプ)をなるべく使用して、横方向の溶融亜鉛の整流を形成する手法を採用することを前提に、(ii)横方向の溶融亜鉛の整流を形成して、めっき浴面に生成するスカム、ドロス等の薄層が、めっき浴に侵入する鋼板の表面に付着するのを防止し、併せて、(iii)溶融亜鉛の淀みと、めっき浴面上の異物に起因する模様性欠陥を防止して、表面欠陥及び表面外観欠陥の発生を防止する技術を確立することを課題とする。   In view of the above demands, the present invention (i) does not employ a method of blowing gas to the plating bath surface, and uses the current metal pumps (push pump and pull pump) arranged on both sides of the steel plate as much as possible, and in the lateral direction. Assuming that the method of forming the rectification of molten zinc is adopted, (ii) the rectification of the molten zinc in the lateral direction is formed, and thin layers such as scum and dross generated on the plating bath surface enter the plating bath. (Iii) preventing stagnation of molten zinc and pattern defects caused by foreign matter on the plating bath surface, and generating surface defects and surface appearance defects. The objective is to establish technology to prevent this.

なお、本発明で用いるメタルポンプは、現状用いている通常のメタルポンプであり、溶融亜鉛は、スナウトの外部から供給され、プッシュ側のポンプ(プッシュポンプ)の吐出口は、長方形又は楕円形の形状を持ち、スナウト内の溶融亜鉛の表面近傍に位置している。上記吐出口は、湯面変動により、全体が浸漬したり、一部が表面より上に位置したりする。   The metal pump used in the present invention is a normal metal pump that is currently used. Molten zinc is supplied from the outside of the snout, and the discharge port of the push-side pump (push pump) has a rectangular or elliptical shape. It has a shape and is located near the surface of the molten zinc in the snout. The discharge port may be entirely immersed or partly positioned above the surface due to fluctuations in the molten metal surface.

また、プル側のポンプ(プルポンプ)の吸引口も、長方形又は楕円形の形状を持ち、スナウト内の溶融亜鉛の表面近傍に位置している。上記吸引口は、プッシュポンプの吐出口と同様に、湯面変動により、全体が浸漬したり、一部が表面より上に位置したりする。なお、プルポンプの吸引口は、スカムを吸い取り除去し易いように、斜めに切り欠いた形状を有していてもよい。   The suction port of the pump on the pull side (pull pump) also has a rectangular or elliptical shape and is located near the surface of the molten zinc in the snout. Similar to the discharge port of the push pump, the suction port is entirely immersed or partly positioned above the surface due to fluctuations in the molten metal surface. Note that the suction port of the pull pump may have a shape that is obliquely cut out so that the scum can be easily sucked and removed.

プルポンプの吸引口から吸引された溶融亜鉛は、ポンプにより、スナウトの外部に排出される。   Molten zinc sucked from the suction port of the pull pump is discharged out of the snout by the pump.

本発明者は、スナウト内部において、鋼板の両側に配置した、上記通常のメタルポンプ(プッシュポンプとメタルポンプ)を使用し、(i)プッシュポンプの吐出口近傍、及び、プルポンプ吸引口近傍で、溶融亜鉛の淀み又は乱流が発生せず、かつ、(ii)鋼板の通板に伴い必然的に発生する随伴流により発生する反転流の影響を受けない、流速が一定の横方向の溶融亜鉛の整流を形成する手法について、鋭意研究した。   The inventor uses the normal metal pump (push pump and metal pump) arranged on both sides of the steel plate inside the snout, and (i) in the vicinity of the discharge port of the push pump and in the vicinity of the pull pump suction port, Zinc or turbulence of molten zinc does not occur, and (ii) laterally molten zinc with a constant flow velocity that is not affected by the reverse flow generated by the accompanying flow that is inevitably generated as the steel plate passes We have intensively studied the method of forming the rectification of

その結果、本発明者は、スナウト内壁に、鋼板表面に平行に、少なくとも鋼板の全幅に渡る整流形成部材を、プッシュポンプの吐出口の幅、及び、プルポンプの吸引口の幅との関係で、所要の間隔で設置すると、所望の溶融亜鉛の整流を形成することができることを見出した。   As a result, the present inventor, on the inner wall of the snout, in parallel with the steel plate surface, the rectification forming member over at least the entire width of the steel plate, in relation to the width of the discharge port of the push pump and the width of the suction port of the pull pump, It has been found that the desired molten zinc rectification can be formed when installed at the required intervals.

本発明は、上記知見に基づいてなされたもので、その要旨は以下のとおりである。   This invention was made | formed based on the said knowledge, and the summary is as follows.

(1) 鋼板を、下端がめっき浴に浸漬するスナウトを通して、めっき浴に浸入させる溶融亜鉛めっき鋼板の製造方法において、
(a)スナウト内部のめっき浴面下に、メタルポンプを、鋼板を挟んで配置し、
(b)スナウト下端に、(b-1)下端部が少なくとも鋼板幅に渡りめっき浴に浸漬する整流形成部材を、(b-2)メタルポンプの吐出口及び吸引口の幅と同等又は同等以下の間隔をもって、かつ、(b-3)メタルポンプから所要の間隔を保持して設置した
ことを特徴とする鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。
(1) In the method for producing a hot dip galvanized steel sheet, the steel sheet is allowed to enter the plating bath through a snout whose lower end is immersed in the plating bath.
(A) A metal pump is disposed below the plating bath surface inside the snout with the steel plate sandwiched between them,
(B) At the lower end of the snout, (b-1) A rectifying member whose lower end is immersed in the plating bath over at least the width of the steel plate, (b-2) Equal to or less than the width of the discharge port and suction port of the metal pump (B-3) A method for producing a hot-dip galvanized steel sheet having a clean appearance, characterized by being installed with a predetermined distance from the metal pump.

(2) 前記整流形成部材が、平板状の部材で構成されていることを特徴とする前記(1)に記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   (2) The method for producing a hot-dip galvanized steel sheet having a clean appearance according to the above (1), wherein the rectification forming member is a flat member.

(3) 前記整流形成部材の端部が、傾斜度45〜90°の斜面で形成されていることを特徴とする前記(1)又は(2)に記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   (3) An end portion of the rectification forming member is formed as an inclined surface having an inclination of 45 to 90 °. The hot-dip galvanized steel sheet having a clean appearance according to (1) or (2), Production method.

(4) 前記整流形成部材の間隔が250mm以下であることを特徴とする前記(1)〜(3)のいずれかに記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   (4) The method for producing a hot-dip galvanized steel sheet having a clean appearance according to any one of (1) to (3), wherein the interval between the rectification forming members is 250 mm or less.

(5) 前記整流形成部材を、その端部がメタルポンプから30mm以下の領域に位置するように設置することを特徴とする前記(1)〜(4)のいずれかに記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   (5) The rectification forming member is installed so that an end portion thereof is located in an area of 30 mm or less from the metal pump, and has a clean appearance according to any one of (1) to (4), Manufacturing method of hot dip galvanized steel sheet.

(6) 前記整流形成部材の下端部を、めっき浴の浴面下100〜650mmの範囲に浸漬することを特徴とする前記(1)〜(5)のいずれかに記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   (6) Melting with a clean appearance according to any one of (1) to (5), wherein the lower end portion of the rectification forming member is immersed in a range of 100 to 650 mm below the bath surface of the plating bath. Manufacturing method of galvanized steel sheet.

本発明によれば、溶融亜鉛の淀みと、めっき浴面上の異物に起因する表面欠陥及び表面外観欠陥がない、鮮麗な外観を備える溶融亜鉛めっき鋼板を製造することができる。   ADVANTAGE OF THE INVENTION According to this invention, the hot dip galvanized steel plate provided with the clear external appearance which does not have the surface defect and surface external appearance defect resulting from the stagnation of the hot dip zinc and the foreign material on the plating bath surface can be manufactured.

本発明者は、まず、鋼板の両側に配置したプッシュポンプとプルポンプ(以下「メタルポンプ」と総称することがある。)で、横方向の溶融亜鉛の整流を形成する手法について鋭意研究した。   First, the inventor has intensively studied a method for forming a rectification of molten zinc in a lateral direction by using a push pump and a pull pump (hereinafter sometimes collectively referred to as “metal pump”) arranged on both sides of a steel plate.

その結果、本発明者は、
(i)スナウト下端に、(b-1)下端部が少なくとも鋼板幅に渡りめっき浴に浸漬する整流形成部材を、(b-2)メタルポンプの吐出口及び吸引口の幅と同等又は同等以下の間隔をもって、かつ、(b-3)メタルポンプから所要の間隔を保持して設置すると、
(ii)メタルポンプの能力を増強することなく、スナウト内において横方向の溶融亜鉛流を整流とし、かつ、その流速を“所定の流速”以上に維持できて、
(iii)めっき浴面上のスカム、ドロス等の異物薄層が、めっき浴に侵入する鋼板の表面に付着するのを防止できることを見出した。
As a result, the present inventor
(I) At the lower end of the snout, (b-1) A rectifying member whose lower end is immersed in the plating bath over at least the width of the steel plate, (b-2) Equivalent to or less than the width of the discharge port and suction port of the metal pump And with (b-3) the required distance from the metal pump,
(Ii) Without increasing the capacity of the metal pump, the flow of the molten zinc in the lateral direction can be rectified in the snout, and the flow rate can be maintained at or above the "predetermined flow rate"
(Iii) It has been found that a thin layer of foreign matter such as scum and dross on the plating bath surface can be prevented from adhering to the surface of the steel sheet entering the plating bath.

ここで、整流とは、スナウト内の横方向の表面流れの流速が、鋼板とスナウト壁の間で、略一定の大きさの流れであることを意味する。また、所定の流速とは、0.5〜1.5m/sの範囲の流速であるが、後述するところの、スナウト内のめっき浴面が淀むことで生じる酸化亜鉛膜の生成を抑制するためには、1m/s程度以上の流速が好ましい。   Here, the rectification means that the flow velocity of the lateral surface flow in the snout is a substantially constant flow between the steel plate and the snout wall. In addition, the predetermined flow rate is a flow rate in the range of 0.5 to 1.5 m / s. In order to suppress the formation of a zinc oxide film that occurs when the plating bath surface in the snout stagnates as described later. Is preferably a flow rate of about 1 m / s or more.

以下、本発明について、図面に基づいて詳細に説明する。   Hereinafter, the present invention will be described in detail with reference to the drawings.

図2に、スナウト2内のめっき浴3の浴面下に、プッシュポンプP1とプルポンプP2を配置し、鋼板1の表面に沿う横方向(P1→P2)の溶融金属流(以下「横向き流」ということがある。)Pを形成する態様を示す。   In FIG. 2, a push pump P1 and a pull pump P2 are arranged under the bath surface of the plating bath 3 in the snout 2, and a molten metal flow in the lateral direction (P1 → P2) along the surface of the steel plate 1 (hereinafter referred to as “lateral flow”). An embodiment of forming P is shown.

通常、めっき浴3においては、鋼板1の侵入に随伴して鋼板侵入方向(図中、下向き矢印)の流れ(以下「随伴流」ということがある。)が必然的に生じる。さらに、随伴流の発生に伴い、鋼板に引き込まれる溶融金属の質量の損失を補償するように、上向きの反転流(以下「反転流」ということがある。)Fが発生する。   Usually, in the plating bath 3, a flow in the steel sheet intrusion direction (downward arrow in the figure) (hereinafter also referred to as “accompanied flow”) inevitably occurs with the intrusion of the steel sheet 1. Further, accompanying the occurrence of the accompanying flow, an upward reverse flow (hereinafter sometimes referred to as “reverse flow”) F is generated so as to compensate for the loss of mass of the molten metal drawn into the steel plate.

反転流Fは、プッシュポンプP1側では、横向き流Pに合流するが、流速が異なるので横向き流Pを撹乱し、また、プルポンプP2側では、横向き流Pに浸入し流れを撹乱する。反転流が生じると、後述するように、スナウト内部のめっき浴表面に、溶融金属が湧き出す湧出し部分が発生し、少なくとも鋼板の全幅に渡り、横向き流Pを、一定流速の整流に維持することが困難になる。   The reverse flow F joins the lateral flow P on the push pump P1 side, but disturbs the lateral flow P because the flow velocity is different, and permeates the lateral flow P on the pull pump P2 side to disturb the flow. When the reverse flow is generated, as will be described later, an outflow portion where the molten metal springs out is generated on the surface of the plating bath inside the snout, and the lateral flow P is maintained at a constant flow velocity at least over the entire width of the steel plate. It becomes difficult.

そこで、本発明者は、スナウト下端に、整流形成部材を設置し、反転流が発生しても、横向き流Pに流入しないよう、横向き流Pの流域を狭くすることを発想した。   In view of this, the present inventor has conceived that a rectification forming member is installed at the lower end of the snout to narrow the flow area of the lateral flow P so that it does not flow into the lateral flow P even if a reverse flow occurs.

しかし、反転流自体は、スナウト内壁と鋼板との間隔の広狭によらず発生するので、スナウト下端に、単に、整流形成部材を設置して横向き流Pの流域を狭くしても、一定流速の横向き流Pが得られないことが想定される。   However, since the reverse flow itself occurs regardless of the distance between the inner wall of the snout and the steel plate, even if the rectification forming member is simply installed at the lower end of the snout to narrow the basin of the lateral flow P, the constant flow rate is maintained. It is assumed that the lateral flow P cannot be obtained.

そこで、本発明者は、スナウト下端に、整流形成部材として所定厚の整流板を設置した場合における鋼板周囲の溶融金属流について、スナウト内の流れを観察した。図3(a)及び(b)に、スナウト内の流れを観察した結果の一例を模式的に示す。図3(a)及び(b)は、スナウトを上面から観察し、その結果を、上から見た断面の形に表現し直して図示したものである。   Then, this inventor observed the flow in a snout about the molten metal flow around a steel plate in the case of installing a baffle plate of a predetermined thickness as a baffle forming member at the lower end of the snout. FIGS. 3A and 3B schematically show an example of the result of observing the flow in the snout. 3 (a) and 3 (b) show the snout observed from the top, and the result is shown in the form of a cross section viewed from above.

上記、スナウト内の観察の結果、次ぎのことが判明した。   As a result of the above observation in the snout, the following was found.

図3(a)に、整流板がない場合におけるスナウト内の流れの観察結果を示す。   FIG. 3A shows an observation result of the flow in the snout when there is no current plate.

プッシュポンプ(図中、吐出側Px)から、溶融金属が吐き出されて、プルポンプ(図中、吸込側Py)で溶融金属が吸い込まれる(図中、矢印P1、P2、P3、参照)が、その横向きの流れ(横向き流)は、プッシュポンプから離れてプルポンプに近づくにつれて、流れの周囲の溶融金属を取り込んで、壁面へ広がる(図中、点線の矢印P1'、P2'、P3'、参照)ので、横向き流は、矢印P1、P2、P3の太さに示すように、プルポンプに近づくにつれて減衰する。 Molten metal is discharged from the push pump (in the drawing, discharge side Px), and the molten metal is sucked in by the pull pump (in the drawing, suction side Py) (refer to arrows P 1 , P 2 , P 3 in the drawing) However, as the lateral flow (lateral flow) moves away from the push pump and approaches the pull pump, it takes in molten metal around the flow and spreads to the wall surface (in the figure, dotted arrows P 1 ′, P 2 ′, P 3 ', the reference), so lateral flow, as shown in the thickness of the arrow P 1, P 2, P 3 , decays as it approaches the Puruponpu.

また、鋼板1は、スナウト2内の溶融金属に侵入するので、鋼板の進行方向(紙面に垂直な方向)に向かって、鋼板周囲の溶融金属が引き込まれ、別の流れ(引込流f)が形成される。引込流fは、スナウト表面では、鋼板の両面において、鋼板に垂直な向きに発生する(図中、鋼板に沿う“小さい矢印f”、参照)。   Moreover, since the steel plate 1 penetrates into the molten metal in the snout 2, the molten metal around the steel plate is drawn toward the traveling direction of the steel plate (direction perpendicular to the paper surface), and another flow (drawing flow f) is generated. It is formed. The entrainment flow f is generated on the both sides of the steel plate in a direction perpendicular to the steel plate on the snout surface (see “small arrow f” along the steel plate in the figure).

これらの流れの内で、特に、プッシュポンプ(図中、吐出側Px)から、プルポンプ(図中、吸込側Py)に向かう横向き流(図中、矢印P1、P2、P3)の減衰と、鋼板の両面で発生する、鋼板に垂直な引込流fにより、溶融金属が、スナウトの先端部から吸い込まれて、スナウト内部の溶融金属表面に湧き出すという溶融金属湧出部Fo(図中、矢印付の楕円形部、参照)が発生する。 Among these flows, in particular, attenuation of a lateral flow (arrows P 1 , P 2 , P 3 in the figure) from the push pump (in the figure, discharge side Px) to the pull pump (in the figure, suction side Py). The molten metal fountain Fo, in which the molten metal is sucked from the tip of the snout and flows out to the surface of the molten metal inside the snout by the drawing flow f generated on both surfaces of the steel plate and perpendicular to the steel plate. Oval with an arrow (see).

この溶融金属湧出部Fo(以下「湧出部Fo」という。)からの流れ(図中、湧出部Foから出る“矢印”、参照)は、横向き流P1、P2、P3と、鋼板の両面で発生する引込流fに影響を与えるので、鋼板表面に、不均一な流れを生じさせることになる。その結果、鋼板表面に、模様性欠陥が生じることになる。 The flow from the molten metal fountain Fo (hereinafter referred to as “the fountain Fo”) (see “arrow” coming out of the fountain Fo in the figure) is a lateral flow P 1 , P 2 , P 3 , Since it influences the entrainment flow f generated on both sides, a non-uniform flow is generated on the steel plate surface. As a result, a pattern defect occurs on the surface of the steel plate.

プッシュポンプ(図中、吐出側Px)からの溶融金属の吐出量を増加し、プルポンプ(図中、吸込側Py)の溶融金属の吸込量を同じだけ増加して、横向き流の流れを強くすると、流れが壁面へ広がる(図中、点線の矢印P1'、P2'、P3'、参照)際に取り込む周囲の溶融金属の量が増えるので、スナウト2内部の溶融金属表面に発生した湧出部Foから湧き出す溶融金属の量も増加する。 Increasing the amount of molten metal discharged from the push pump (discharge side Px in the figure) and increasing the amount of molten metal suction from the pull pump (suction side Py in the figure) by the same amount Since the amount of molten metal taken around when the flow spreads to the wall surface (see dotted arrows P 1 ′, P 2 ′, P 3 ′ in the figure) increases, it occurs on the surface of the molten metal inside the snout 2 The amount of molten metal that springs out from the spring part Fo also increases.

したがって、従来構造のスナウト内部に、プッシュポンプとプルポンプを設けて、これらの溶融金属の流量(吐出量と吸引量)を単に増加しても、鋼板表面に、模様性欠陥が、さらに発生する事態を招くことになり、「表面模様を発生させずに、スカム付着を防止する」という本発明の課題を解決することはできない。   Therefore, even if a push pump and a pull pump are provided inside a conventional snout and the flow rate (discharge amount and suction amount) of these molten metals is simply increased, pattern defects will further occur on the surface of the steel sheet. Therefore, it is impossible to solve the problem of the present invention that “scum adhesion is prevented without generating a surface pattern”.

ここで、図3(b)に、スナウト2の内壁に整流板9を設置した場合において、スナウト内の流れを観察した結果を、模式的に示す。   Here, FIG. 3B schematically shows the result of observing the flow in the snout when the rectifying plate 9 is installed on the inner wall of the snout 2.

この場合にも、整流板がない場合と同様に、プッシュポンプ(図中、吐出側Px)から、溶融金属が吐き出されて、プルポンプ(図中、吸込側Py)で溶融金属が吸い込まれる横向き流P1、P2、P3、及び、溶融金属が引き込まれて、スナウト表面で、鋼板1の両側で発生する、鋼板1に垂直な引込流fは存在するが、スナウト2内に整流板9が設置されているので、横向き流が壁に向かって拡散する流量が小さくなり、その結果、横向き流がプッシュポンプからプルポンプに流れる間に減衰する量は、かなり小さくなる(図中、矢印P1、P2、P3の太さ、参照)。 In this case as well, as in the case where there is no flow straightening plate, the molten metal is discharged from the push pump (discharge side Px in the figure), and the molten metal is sucked in by the pull pump (suction side Py in the figure). P 1 , P 2 , P 3 , and molten metal are drawn into the snout surface, and there is a drawing flow f perpendicular to the steel plate 1 generated on both sides of the steel plate 1, but the rectifying plate 9 is in the snout 2. Is installed, the flow rate at which the lateral flow diffuses toward the wall is reduced, and as a result, the amount of attenuation while the lateral flow flows from the push pump to the pull pump is considerably reduced (in the figure, arrow P 1). , P 2 , P 3 thickness, see).

その結果、スナウト2の内部における溶融金属の表面に生じる湧出部Foの領域が小さくなって、鋼板1の表面に、不均一な流れが生じなくなり、鋼板表面に模様性欠陥を発生させることなく、かつ、スカムを除去することが可能になる。   As a result, the region of the spring portion Fo generated on the surface of the molten metal in the inside of the snout 2 is reduced, and a non-uniform flow is not generated on the surface of the steel plate 1, without causing pattern defects on the surface of the steel plate, In addition, the scum can be removed.

そして、上記観察結果から、以下の結論を導きだすことができる。   And the following conclusion can be drawn from the said observation result.

(a)プルポンプで吸い込む溶融金属を補うため、スナウトの下部から侵入し、溶融金属表面に湧き出すことにより、プルポンプ側の吸込口付近の溶融金属の表面に形成される湧出部からの湧出流は、溶融金属の横向き流を遮り、鋼板表面に、模様性欠陥が生成する原因となる。   (A) In order to make up for the molten metal sucked by the pull pump, the inflow from the lower part of the snout and springing out to the surface of the molten metal, the outflow from the spring part formed on the surface of the molten metal near the suction port on the pull pump side is This obstructs the lateral flow of the molten metal and causes pattern defects on the surface of the steel sheet.

(b)スナウト内部に設置する整流板(整流形成部材)の間隔を小さくし、横向き流の流幅を小さくすると、上記湧出流は、ほぼ消滅して、鋼板表面に、上記湧出流に起因する模様性欠陥は発生しなくなる。   (B) When the interval between the rectifying plates (rectification forming members) installed inside the snout is reduced and the flow width of the lateral flow is reduced, the erupting flow is almost extinguished and is caused on the steel plate surface by the erupting flow. Pattern defects do not occur.

(c)上記湧出流を抑制し、鋼板表面に模様性欠陥が発生しない整流板の間隔は、鋼板の通板速度に依存する。(c1)一般的な鋼板の通板速度50〜150mpmを前提にすると、模様性欠陥が発生しない整流板の間隔は、250mm以下である。(c2)整流板の間隔が250mmを超えると、上記湧出流が起き易くなり、鋼板表面に模様性欠陥が発生する。   (C) The spacing between the rectifying plates that suppresses the above-described flow and does not cause pattern defects on the steel plate surface depends on the plate passing speed of the steel plate. (C1) Assuming a general steel plate passing speed of 50 to 150 mpm, the interval between the rectifying plates where pattern defects do not occur is 250 mm or less. (C2) When the distance between the current plates exceeds 250 mm, the above-mentioned rushing current easily occurs, and a pattern defect occurs on the steel plate surface.

(d)スナウト内に設置する整流板の間隔を250mm以下とした場合、整流板の浴面下の長さ(浸漬部分の長さ)を、プッシュポンプとプルポンプで形成される横向き流が存在する部分を含む所定区間の長さ以上、650mm以下にすれば、鋼板の周囲に引き込まれる流れを充分に発達させることなく、鋼板をスナウト外に引き出すことができので、上記湧出流を、さらに小さくすることができる。   (D) When the distance between the rectifying plates installed in the snout is 250 mm or less, the length of the rectifying plate below the bath surface (the length of the immersion part) is a lateral flow formed by a push pump and a pull pump. If the length of the predetermined section including the portion is not less than 650 mm, the steel plate can be drawn out of the snout without sufficiently developing the flow drawn around the steel plate, thereby further reducing the above-mentioned squirt flow. be able to.

(e)一方、整流板の浴面下の長さが650mmを超えると、鋼板の随伴流が大きくなり、スナウト内へ吸い込まれる流れが大きくなる。(e1)その結果、溶融金属の表面に、湧出部から湧き出す湧出流が大きくなることもある。(e2)その場合、通板速度が大きいと、例えば、通板速度が120mpm以上であると、安定的に、鋼板表面の模様性欠陥を解消することができない恐れがある。   (E) On the other hand, when the length of the rectifying plate below the bath surface exceeds 650 mm, the accompanying flow of the steel plate increases, and the flow sucked into the snout increases. (E1) As a result, there may be an increase in the flow of the spring flowing out from the spring on the surface of the molten metal. (E2) In that case, if the plate passing speed is high, for example, if the plate passing speed is 120 mpm or more, there is a possibility that pattern defects on the surface of the steel sheet cannot be stably eliminated.

(f)メタルポンプを用い、整流板と鋼板の間に、スナウト表面に湧き出す湧出流の影響がない、一定流速の横向き流を形成するためには、整流板と整流板の間隔を、プッシュポンプの吐出口及びプルポンプの吸引口の幅と同じにするか、又は、該幅より小さくすることが有効である。   (F) Use a metal pump to push the gap between the rectifying plate and the rectifying plate between the rectifying plate and the steel plate in order to form a lateral flow with a constant flow rate that is not affected by the outflow of the snout surface. It is effective to make the width equal to or smaller than the width of the discharge port of the pump and the suction port of the pull pump.

(g)さらに、整流板の端部を適正な角度(傾斜度)で切り欠くと、横向き流の整流化の促進と、整流板端部近傍における渦流の発生の防止に効果がある。   (G) Further, notching the end portion of the rectifying plate at an appropriate angle (inclination) is effective in promoting the rectification of the lateral flow and preventing the generation of eddy currents in the vicinity of the rectifying plate end portion.

(g1)整流板の間隔を、メタルポンプの吐出口及び吸引口の幅250mmと同じにし、整流板の端部を45°(傾斜度)で切り欠いた形状とした場合(後述する)における横向き流の流速は、メタルポンプの吐出口及び吸引口の幅が250mmで、整流板を設置しない(即ち、図3(a)のスナウト両内壁面の間隔が460mmである)場合における横向き流の流速の約1.4倍である。   (G1) Sideways when the distance between the current plates is the same as the width of the discharge port and suction port of the metal pump and the end of the current plate is cut out at 45 ° (inclination) (described later) As for the flow velocity of the flow, the width of the discharge port and the suction port of the metal pump is 250 mm, and the current plate is not installed (that is, the distance between the inner wall surfaces of the snout in FIG. 3A is 460 mm). It is about 1.4 times that.

(g2)また、整流板の端部を90°に切り欠いた場合(後述する)には、横向き流の流速を、整流板を設置しない場合における横向き流の流速の1.5倍にすることができる。   (G2) If the end of the rectifying plate is notched at 90 ° (described later), the lateral flow velocity should be 1.5 times the lateral flow velocity when no rectifying plate is installed. Can do.

(h)整流板の間隔を、プッシュプルポンプの吐出口の幅より狭くすると、横向き流の流速は増加する。   (H) When the interval between the rectifying plates is narrower than the width of the discharge port of the push-pull pump, the flow velocity of the lateral flow increases.

本発明者は、スナウト内における溶融金属の流れを観察して得た上記結論に基づいて、内壁間隔が460mmのスナウトの下端に、図4(a)及び(b)に示ように、整流板の間隔W1が、プッシュポンプP1の吐出口の幅W2、及び、プルポンプP2の吸引口の幅W2と略同じになるように、整流板を設置し、実機試験を行った。   Based on the above conclusion obtained by observing the flow of molten metal in the snout, the present inventor has a current plate at the lower end of the snout having an inner wall interval of 460 mm, as shown in FIGS. 4 (a) and 4 (b). The rectifying plate was installed so that the interval W1 was approximately the same as the width W2 of the discharge port of the push pump P1 and the width W2 of the suction port of the pull pump P2.

なお、図4(a)に示す整流板は、その端部を角度αで切り欠いた整流板である。図4(b)に示す整流板は、その端部をα=90°で切り欠いた整流板である。   Note that the rectifying plate shown in FIG. 4A is a rectifying plate whose end is notched at an angle α. The rectifying plate shown in FIG. 4B is a rectifying plate having its end cut out at α = 90 °.

図4に示すように、プッシュポンプP1の吐出口、及び、プルポンプP2の吸引口のそれぞれの側面に所要の隙間を設けている。この理由は、操業時に、鋼板のパスラインが変わる際、スナウトは、鋼板の表面に対して垂直な方向に微動するが、一方、プッシュポンプP1及びプルポンプP2は、浴中に固定されているので、これらメタルポンプとスナウト壁が接触する可能性があり、これを確実に避けるためである。   As shown in FIG. 4, required gaps are provided on the side surfaces of the discharge port of the push pump P1 and the suction port of the pull pump P2. The reason for this is that during operation, when the steel plate pass line changes, the snout finely moves in a direction perpendicular to the surface of the steel plate, while the push pump P1 and the pull pump P2 are fixed in the bath. This is because the metal pump and the snout wall may come into contact with each other, and this is surely avoided.

しかし、上記メタルポンプとスナウトとの所要の隙間が適正でないと、この隙間領域に、図4(a)に示すように、溶融金属の淀み領域10が生成して、鋼板端部にめっき模様が発現することがある。この模様の発現を避けるため、本発明者は、実機試験において、淀み領域が生成しない、整流板とメタルポンプ間の適正間隔、及び、整流板の端部の適正形状について検討した。   However, if the required gap between the metal pump and the snout is not appropriate, a stagnation region 10 of molten metal is generated in this gap region, as shown in FIG. May develop. In order to avoid the appearance of this pattern, the present inventor examined the proper interval between the rectifying plate and the metal pump and the appropriate shape of the end of the rectifying plate, in which the stagnation region is not generated, in the actual machine test.

実機試験の結果を、他の条件と併せて表1に示す。   The results of the actual machine test are shown in Table 1 together with other conditions.

実機試験条件は、以下のとおりである。   The actual machine test conditions are as follows.

板幅:1500mm以上
板厚:0.8mm以下
鋼種:IF鋼
通板速度:50〜135mpm
メッキ浴:Zn−Al(Al:0.1〜0.15%)
侵入板温:450〜470℃
スナウト内の加熱の有無:なし
スナウト内の雰囲気温度:200℃
合金化工程の有無:あり
Sheet width: 1500mm or more Sheet thickness: 0.8mm or less Steel type: IF steel Sheet feeding speed: 50 to 135 mpm
Plating bath: Zn—Al (Al: 0.1 to 0.15%)
Intrusion plate temperature: 450-470 ° C
Presence / absence of heating in snout: None Atmosphere temperature in snout: 200 ° C
Presence or absence of alloying process: Yes

Figure 2008024970
Figure 2008024970

表1から、以下の知見を得ることができる。   From Table 1, the following knowledge can be obtained.

(x1)整流板の両端部を、45°未満の角度(α)で切り欠いた形状にすると、切欠き部分の溶融金属表面に淀み領域(図4(a)中「10」、参照)が生成する。この淀み領域が生成すると、鋼板端部には、溶融金属の淀みに起因する表面外観欠陥が発現する。したがって、整流板の端部は、45〜90°の角度で切り欠いた形状が好ましい。   (X1) If both ends of the current plate are cut out at an angle (α) of less than 45 °, a stagnation region (see “10” in FIG. 4A) is formed on the surface of the molten metal at the cutout. Generate. When this stagnation region is generated, surface appearance defects due to stagnation of the molten metal appear at the end of the steel plate. Therefore, it is preferable that the end of the current plate is cut out at an angle of 45 to 90 °.

(x2)整流板の端部を45°の角度で切り欠いた形状とした場合における横向き流の流速は、メタルポンプの吐出口及び吸引口の幅が250mmで、整流板を設置していない(即ち、図3(a)のスナウト両内壁面の間隔が460mmである)場合における横向き流の流速の約1.4倍である。   (x2) The flow rate of the lateral flow when the end of the rectifying plate is notched at an angle of 45 ° is 250 mm for the discharge port and suction port of the metal pump, and no rectifying plate is installed ( That is, it is about 1.4 times the flow velocity of the lateral flow in the case where the distance between both inner wall surfaces of the snout in FIG. 3A is 460 mm.

(x3)整流板の端部を垂直面(α=90°)で形成すると、淀み領域が全く生成しないので、横向き流の流速を、従来の流速の1.5にすることができる。   (X3) If the end portion of the current plate is formed with a vertical surface (α = 90 °), no stagnation region is generated, so that the flow rate of the lateral flow can be made 1.5, which is the conventional flow rate.

(y1)整流板はスナウト下端に設置し、メタルポンプはめっき浴面下に固定して配置するが、スナウトは、操業中、前後に傾動する必要があるので、整流板とメタルポンプの間には、所要の間隙を設ける必要がある。   (Y1) The rectifying plate is installed at the lower end of the snout, and the metal pump is fixed below the plating bath surface, but the snout must be tilted back and forth during operation. It is necessary to provide a necessary gap.

(y2)上記間隔が30mmを超えて広くなると、鋼板端部の周辺に反転流が流入したり、淀み領域が発生したりして、横向き流の流速が低下するので、上記間隔は30mm以下が好ましい。なお、上記間隔は、狭いほうが好ましいが、スナウトの前後の傾動に支障のない範囲で適宜設定すればよく、下限を特に設定する必要はない。   (Y2) When the interval is wider than 30 mm, a reverse flow flows around the edge of the steel plate or a stagnation region is generated, and the flow velocity of the lateral flow is reduced. Therefore, the interval is 30 mm or less. preferable. In addition, although the one where the said space | interval is narrow is preferable, what is necessary is just to set suitably in the range which does not have trouble in the tilting forward and backward of a snout, and it is not necessary to set a minimum in particular.

(z1)スナウト内に設置する整流板の通板方向の長さは、600mm以下が好ましい。600mmを超えると、鋼板の移動に伴う随伴流がスナウト内で発達し過ぎ、その結果、スナウト内の溶融金属表面に湧き出す湧出流が生じ、鋼板表面に流れ模様が発現する。   (Z1) The length of the rectifying plate installed in the snout in the plate passing direction is preferably 600 mm or less. If it exceeds 600 mm, the accompanying flow accompanying the movement of the steel sheet develops too much in the snout, and as a result, a squirt flow that swells on the surface of the molten metal in the snout occurs, and a flow pattern appears on the surface of the steel sheet.

(z2)さらに、スナウト内に設置する整流板の通板方向の長さは、プッシュポンプとプルポンプで形成される横向き流が、鋼板の幅方向に直角な方向に拡散しない長さであればよい。例えば、整流板の長さが100mmでも、横向き流が、鋼板の幅方向に直角な方向に拡散しない長さであれば、整流板よる整流化効果を発揮することができる。   (Z2) Further, the length of the flow straightening plate installed in the snout may be long enough so that the lateral flow formed by the push pump and the pull pump does not diffuse in the direction perpendicular to the width direction of the steel plate. . For example, even if the length of the rectifying plate is 100 mm, the rectifying effect by the rectifying plate can be exhibited as long as the lateral flow does not diffuse in the direction perpendicular to the width direction of the steel plate.

本発明においては、上記要件に基づいて、溶融亜鉛の淀み、及び、めっき浴面上の異物に起因する表面欠陥及び表面外観欠陥がない、鮮麗な外観を備える溶融亜鉛めっき鋼板を製造することができるが、さらに、スナウト内部を加熱し、亜鉛ヒュームがスナウト内壁に付着するのを防止して、スカム、ドロス等の生成量を低減すると、より表面欠陥及び表面外観欠陥のない、鮮麗な外観を備える溶融亜鉛めっき鋼板を製造することができる。   In the present invention, based on the above requirements, it is possible to produce a hot dip galvanized steel sheet having a clean appearance, free from stagnation of molten zinc and surface defects and surface appearance defects caused by foreign matters on the plating bath surface. However, if the inside of the snout is heated to prevent zinc fume from adhering to the inner wall of the snout and the generation amount of scum, dross, etc. is reduced, a more beautiful appearance without surface defects and surface appearance defects can be obtained. A hot-dip galvanized steel sheet can be manufactured.

表1において、スカム巻き込み性欠陥の合格とは、5〜10トンのコイルの表面に存在するスカム巻き込み性欠陥の有無を評価し、コイルの内に、1つでもスカム巻き込み性欠陥が存在する場合には不合格コイルとし、約1日間、同じ水準で試験して集計した結果、不合格コイルの発生率が8%以下であることを意味する。   In Table 1, the acceptance of a scum entrainment defect means that the presence or absence of a scum entrainment defect existing on the surface of a coil of 5 to 10 tons is evaluated, and at least one scum entrainment defect exists in the coil. This means that the coil is a rejected coil and tested at the same level for about one day, and as a result, the generation rate of the rejected coil is 8% or less.

なお、表1において、鋼板の板幅は、すべて、1500mm以上と記載しているが、1500mm以上の鋼板には、例えば、1750mm幅の鋼板も含まれる。また、表面模様疵(表面模様性欠陥)は、一つの試験水準で発生する場合には、その試験水準で安定して発生するので、その試験水準を不合格とした。   In Table 1, all the plate widths of the steel plates are described as 1500 mm or more, but the steel plates of 1500 mm or more include, for example, steel plates having a width of 1750 mm. Further, when surface pattern defects (surface pattern property defects) occur at one test level, they are stably generated at that test level.

次に、本発明の実施例について説明するが、実施例の条件は、本発明の実施可能性及び効果を確認するために採用した一条件例であり、本発明は、この一条件例に限定されるものではない。本発明は、本発明の要旨を逸脱せず、本発明の目的を達成する限りにおいて、種々の条件を採用し得るものである。   Next, examples of the present invention will be described. The conditions of the examples are one example of conditions adopted for confirming the feasibility and effects of the present invention, and the present invention is limited to this one example of conditions. Is not to be done. The present invention can adopt various conditions as long as the object of the present invention is achieved without departing from the gist of the present invention.

(実施例)   (Example)

Figure 2008024970
Figure 2008024970

試験方法は、表1の場合と同様にして、表1に示す水準以外の水準にして試験した結果を、表2に示す。表2に示すように、スカム巻き込み性欠陥の発生については合格であるが、表面模様疵(表面模様性欠陥)の発生については、条件によって不合格となる水準がある。   The test method is the same as in Table 1, and the results of testing at a level other than the level shown in Table 1 are shown in Table 2. As shown in Table 2, the generation of scum entrainment defects is acceptable, but the occurrence of surface pattern defects (surface pattern defects) is unacceptable depending on conditions.

前述したように、本発明によれば、鮮麗な外観を備える溶融亜鉛めっき鋼板を製造することができる。したがって、本発明は、需要者の厳しい要望に応えるとともに、溶融亜鉛めっき鋼板の用途を拡大するものであり、溶融亜鉛めっき鋼板を素材とする製造産業において利用可能性が大きいものである。   As described above, according to the present invention, a hot-dip galvanized steel sheet having a clean appearance can be produced. Therefore, this invention responds to a severe demand of a customer, expands the use of a hot dip galvanized steel sheet, and has a great applicability in the manufacturing industry using hot dip galvanized steel sheets.

溶融亜鉛めっき装置の従来態様を示す図である。It is a figure which shows the conventional aspect of the hot dip galvanizing apparatus. 鋼板の表面に沿う横方向の溶融亜鉛流(横向き流)を形成する態様を示す図である。It is a figure which shows the aspect which forms the molten zinc flow (transverse flow) of the horizontal direction along the surface of a steel plate. スナウト内の流れを観察した結果を模式的に示す図である。(a)は、スナウト内に整流板を設置していない場合における流れを模式的示し、(b)は、スナウト内に整流板を設置した場合における流れを模式的示す。It is a figure which shows typically the result of having observed the flow in a snout. (A) shows typically the flow in the case where the current plate is not installed in the snout, and (b) schematically shows the flow in the case where the current plate is installed in the snout. 整流板の設置態様を示す図である。(a)は、整流板の端部が、角度αで切り欠かれている場合を示し、(b)は、整流板の端部が垂直面(角度α=90°)で形成されている場合を示す。It is a figure which shows the installation aspect of a baffle plate. (A) shows the case where the end of the current plate is cut out at an angle α, and (b) shows the case where the end of the current plate is formed by a vertical surface (angle α = 90 °). Indicates.

符号の説明Explanation of symbols

1 鋼板
2 スナウト
3 めっき浴
4 ポットロール
5 めっき槽
6 ガスワイピングノズル
7 液状異物
8 酸化亜鉛
9 整流板
10 淀み領域
P、P1、P2、P3 横向き流
1'、P2'、P3' 広がり流
P1 プッシュポンプ
P2 プルポンプ
Px 吐出側
Py 吸込側
F 反転流
Fo 溶融金属湧出部
f 引込流
W1 整流板の間隔
W2 プッシュポンプの吐出口の幅
DESCRIPTION OF SYMBOLS 1 Steel plate 2 Snout 3 Plating bath 4 Pot roll 5 Plating tank 6 Gas wiping nozzle 7 Liquid foreign substance 8 Zinc oxide 9 Current plate 10 Stagnation area P, P 1 , P 2 , P 3 Lateral flow P 1 ', P 2 ', P 3 'Spreading flow P1 Push pump P2 Pull pump Px Discharge side Py Suction side F Reverse flow Fo Molten metal outflow part f Inlet flow W1 Rectifier plate spacing W2 Push pump discharge port width

Claims (6)

鋼板を、下端がめっき浴に浸漬するスナウトを通して、めっき浴に浸入させる溶融亜鉛めっき鋼板の製造方法において、
(a)スナウト内部のめっき浴面下に、メタルポンプを、鋼板を挟んで配置し、
(b)スナウト下端に、(b-1)下端部が少なくとも鋼板幅に渡りめっき浴に浸漬する整流形成部材を、(b-2)メタルポンプの吐出口及び吸引口の幅と同等又は同等以下の間隔をもって、かつ、(b-3)メタルポンプから所要の間隔を保持して設置した
ことを特徴とする鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。
In the method for producing a hot dip galvanized steel sheet, the steel sheet is infiltrated into the plating bath through a snout whose lower end is immersed in the plating bath.
(A) A metal pump is disposed below the plating bath surface inside the snout with the steel plate sandwiched between them,
(B) At the lower end of the snout, (b-1) A rectifying member whose lower end is immersed in the plating bath over at least the width of the steel plate, (b-2) Equal to or less than the width of the discharge port and suction port of the metal pump (B-3) A method for producing a hot-dip galvanized steel sheet having a clean appearance, characterized by being installed with a predetermined distance from the metal pump.
前記整流形成部材が、平板状の部材で構成されていることを特徴とする請求項1に記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   The said rectification | straightening formation member is comprised with the flat member, The manufacturing method of the hot dip galvanized steel plate provided with the clean appearance of Claim 1 characterized by the above-mentioned. 前記整流形成部材の端部が、傾斜度45〜90°の斜面で形成されていることを特徴とする請求項1又は2に記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   The method for producing a hot-dip galvanized steel sheet having a clean appearance according to claim 1 or 2, wherein an end portion of the rectification forming member is formed with an inclined surface having an inclination of 45 to 90 °. 前記整流形成部材の間隔が250mm以下であることを特徴とする請求項1〜3のいずれか1項に記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   The method for producing a hot-dip galvanized steel sheet having a clean appearance according to any one of claims 1 to 3, wherein a distance between the rectification forming members is 250 mm or less. 前記整流形成部材を、その端部がメタルポンプから30mm以下の領域に位置するように設置することを特徴とする請求項1〜4のいずれか1項に記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   The hot-dip galvanized steel sheet having a clean appearance according to any one of claims 1 to 4, wherein the rectifying member is installed such that an end thereof is located in an area of 30 mm or less from a metal pump. Manufacturing method. 前記整流形成部材の下端部を、めっき浴の浴面下100〜650mmの範囲に浸漬することを特徴とする請求項1〜5のいずれか1項に記載の鮮麗外観を備える溶融亜鉛めっき鋼板の製造方法。   6. The hot-dip galvanized steel sheet having a clean appearance according to claim 1, wherein a lower end portion of the rectification forming member is immersed in a range of 100 to 650 mm below the bath surface of the plating bath. Production method.
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JP2014114483A (en) * 2012-12-10 2014-06-26 Nippon Steel & Sumitomo Metal Snout floating scum removal device for molten zinc plating line
JP2014114484A (en) * 2012-12-10 2014-06-26 Nippon Steel & Sumitomo Metal Snout floating scum removal device for molten zinc plating line

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JPH07150321A (en) * 1993-11-30 1995-06-13 Nippon Steel Corp Hot dip metal coating device
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014114483A (en) * 2012-12-10 2014-06-26 Nippon Steel & Sumitomo Metal Snout floating scum removal device for molten zinc plating line
JP2014114484A (en) * 2012-12-10 2014-06-26 Nippon Steel & Sumitomo Metal Snout floating scum removal device for molten zinc plating line

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