JP2013515819A5 - - Google Patents
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- JP2013515819A5 JP2013515819A5 JP2012546026A JP2012546026A JP2013515819A5 JP 2013515819 A5 JP2013515819 A5 JP 2013515819A5 JP 2012546026 A JP2012546026 A JP 2012546026A JP 2012546026 A JP2012546026 A JP 2012546026A JP 2013515819 A5 JP2013515819 A5 JP 2013515819A5
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- Prior art keywords
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- crosslinkable composition
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- monomer
- Prior art date
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- 239000000203 mixture Substances 0.000 claims 13
- 239000000178 monomer Substances 0.000 claims 10
- 239000002253 acid Substances 0.000 claims 7
- 229920001577 copolymer Polymers 0.000 claims 5
- 150000003509 tertiary alcohols Chemical class 0.000 claims 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 4
- SCMVPOVMOHQFKU-UHFFFAOYSA-N 1-(aziridin-1-yl)prop-2-en-1-one Chemical compound C=CC(=O)N1CC1 SCMVPOVMOHQFKU-UHFFFAOYSA-N 0.000 claims 3
- 239000004971 Cross linker Substances 0.000 claims 3
- 125000005396 acrylic acid ester group Chemical group 0.000 claims 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- PRNCMAKCNVRZFX-UHFFFAOYSA-N 3,7-dimethyloctan-1-ol Chemical compound CC(C)CCCC(C)CCO PRNCMAKCNVRZFX-UHFFFAOYSA-N 0.000 claims 1
- 229920001567 Vinyl ester Polymers 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 125000005529 alkyleneoxy group Chemical group 0.000 claims 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical class CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 claims 1
- 125000005842 heteroatoms Chemical group 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 150000003440 styrenes Chemical class 0.000 claims 1
- 239000006188 syrup Substances 0.000 claims 1
- 235000020357 syrup Nutrition 0.000 claims 1
- -1 vinyl halides Chemical class 0.000 claims 1
Claims (10)
- R2が、−CH2−CH(OH)CH2−である、請求項1に記載の架橋性組成物。
- R2が、アルキレン基である、請求項1に記載の架橋性組成物。
- R2が、ポリ(アルキレンオキシ)基である、請求項1に記載の架橋性組成物。
- 前記酸官能性(メタ)アクリレートコポリマーが、100重量部の総モノマーを基準として
i.85〜99.5重量部の非第三級アルコールの(メタ)アクリル酸エステルと、
ii.0.5〜15重量部の酸官能性エチレン性不飽和モノマーと、
iii.0〜10重量部の非酸官能性エチレン性不飽和極性モノマーと、
iv.0〜5部のビニルモノマーと、
v.0〜5部の多官能性(メタ)アクリレートと、を含む、請求項1に記載の架橋性組成物。 - 100部のコポリマーに対して0.005〜5.0重量部の(メタ)アクリロイルアジリジン架橋剤を含む、請求項1に記載の架橋性組成物。
- 前記コポリマーが、0.5〜5重量部のアクリル酸と1〜5重量部の非酸官能性エチレン性不飽和モノマーとを含む、請求項5に記載の架橋性組成物。
- ビニルエステル、スチレン、置換スチレン、ビニルハロゲン化物、プロピオン酸ビニル、及びこれらの混合物から選択される、1〜5部のビニルモノマーを含む、請求項5に記載の架橋性組成物。
- 前記非第三級アルコールの(メタ)アクリル酸エステルの前記非第三級アルコールが、2−オクタノール又はジヒドロシトロネロールから選択される、請求項5に記載の架橋性組成物。
- a)
i.85〜99.5重量部の非第三級アルコールの(メタ)アクリル酸エステルと、
ii.0.5〜15重量部の酸官能性モノマーと、
iii.0〜10重量部の非酸官能性エチレン性不飽和極性モノマーと、
iv.0〜5部のビニルモノマーと、を含む、第1の構成成分である溶質コポリマーと、
b)少なくとも1つのフリーラジカル重合性溶媒モノマーを含む第2の構成成分と、
c)0.005〜5.0重量部の前記(メタ)アクリロイルアジリジン架橋剤と、を含む、シロップポリマー組成物を含む、請求項5に記載の架橋性組成物。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200910261937.3 | 2009-12-23 | ||
CN200910261937.3A CN102108133B (zh) | 2009-12-23 | 2009-12-23 | (甲基)丙烯酰基-氮丙啶交联剂和粘合剂聚合物 |
US12/849,878 US8263711B2 (en) | 2009-12-23 | 2010-08-04 | (Meth)acryloyl-aziridine crosslinking agents and adhesive polymers |
US12/849,878 | 2010-08-04 | ||
PCT/US2010/060219 WO2011087664A1 (en) | 2009-12-23 | 2010-12-14 | (meth)acryloyl-aziridine crosslinking agents and adhesive polymers |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2013515819A JP2013515819A (ja) | 2013-05-09 |
JP2013515819A5 true JP2013515819A5 (ja) | 2014-02-06 |
Family
ID=44151985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2012546026A Pending JP2013515819A (ja) | 2009-12-23 | 2010-12-14 | (メタ)アクリロイル−アジリジン架橋剤及び接着剤ポリマー |
Country Status (6)
Country | Link |
---|---|
US (1) | US8263711B2 (ja) |
EP (1) | EP2516391B1 (ja) |
JP (1) | JP2013515819A (ja) |
KR (1) | KR20120112607A (ja) |
CN (1) | CN102108133B (ja) |
WO (1) | WO2011087664A1 (ja) |
Families Citing this family (18)
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US8067504B2 (en) * | 2009-08-25 | 2011-11-29 | 3M Innovative Properties Company | Acrylic pressure-sensitive adhesives with acylaziridine crosslinking agents |
US10029816B2 (en) | 2010-05-26 | 2018-07-24 | Avery Dennison Retail Information Services, Llc | Pressure sensitive labels for use in a cold transfer method and process for making |
EP2658921B1 (en) | 2010-12-29 | 2016-04-06 | 3M Innovative Properties Company | Pressure-sensitive adhesives with triazine-epoxy crosslinking system |
WO2014070230A1 (en) | 2012-10-31 | 2014-05-08 | Avery Dennison Corporation | Wash durable cold apply adhesive for apparel labeling and embellishment |
KR20150095811A (ko) * | 2012-12-14 | 2015-08-21 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 이온화 방사선을 사용하여 에틸렌계 불포화 재료를 중합함으로써 패키징된 점탄성 조성물을 제조하는 방법 |
WO2014116461A1 (en) | 2013-01-24 | 2014-07-31 | 3M Innovative Properties Company | Photoinitiated oligomerization of methacrylate esters |
JP2016521306A (ja) | 2013-04-15 | 2016-07-21 | スリーエム イノベイティブ プロパティズ カンパニー | (メタ)アクリレート基及びオレフィン基を有する架橋剤を含む接着剤並びに方法 |
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JP6369023B2 (ja) * | 2014-01-08 | 2018-08-08 | 東洋インキScホールディングス株式会社 | 反応性モノマーおよびそれを用いてなる樹脂組成物 |
WO2015143649A1 (en) | 2014-03-26 | 2015-10-01 | 3M Innovative Properties Company | Ultraviolet cured (meth)acrylate pressure-sensitive adhesive composition and process for producing thereof |
CN104449426B (zh) * | 2014-11-20 | 2016-07-06 | 北京天山新材料技术有限公司 | 一种可紫外光固化耐高温压敏胶 |
CN104559827B (zh) * | 2014-12-29 | 2017-11-21 | 3M创新有限公司 | 可压缩的微米级聚合物颗粒及其用途、可固化组合物及其制备方法、压敏粘合剂、胶带 |
US10920116B2 (en) * | 2015-04-13 | 2021-02-16 | 3M Innovative Properties Company | Method of preparing crosslinked pressure-sensitive adhesives using a light-emitting diode for crosslinking |
WO2016209916A1 (en) * | 2015-06-22 | 2016-12-29 | 3M Innovative Properties Company | Pressure sensitive adhesive comprising (meth)acrylic polymer and amino acid crosslinker |
KR102126094B1 (ko) * | 2015-11-19 | 2020-06-23 | 주식회사 엘지화학 | 라디칼 경화형 접착제 조성물 및 이를 포함하는 편광판 |
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WO2020020714A1 (en) | 2018-07-23 | 2020-01-30 | Dsm Ip Assets B.V. | Multi-aziridine compound |
KR102495336B1 (ko) * | 2021-11-26 | 2023-02-06 | 울산과학기술원 | 아지리딘기를 함유하는 고분자 브러시를 포함하는 가교제, 이의 제조방법 및 이의 용도 |
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-
2009
- 2009-12-23 CN CN200910261937.3A patent/CN102108133B/zh not_active Expired - Fee Related
-
2010
- 2010-08-04 US US12/849,878 patent/US8263711B2/en not_active Expired - Fee Related
- 2010-12-14 WO PCT/US2010/060219 patent/WO2011087664A1/en active Application Filing
- 2010-12-14 EP EP10795179.0A patent/EP2516391B1/en not_active Not-in-force
- 2010-12-14 KR KR1020127018975A patent/KR20120112607A/ko not_active Application Discontinuation
- 2010-12-14 JP JP2012546026A patent/JP2013515819A/ja active Pending