JP2013022586A - Oil-containing waste water treatment system using yeast - Google Patents

Oil-containing waste water treatment system using yeast Download PDF

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JP2013022586A
JP2013022586A JP2011176365A JP2011176365A JP2013022586A JP 2013022586 A JP2013022586 A JP 2013022586A JP 2011176365 A JP2011176365 A JP 2011176365A JP 2011176365 A JP2011176365 A JP 2011176365A JP 2013022586 A JP2013022586 A JP 2013022586A
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oil
yeast
carrier
bag
porous carrier
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Emiko Yagi
恵美子 八木
Koji Kitamura
幸司 北村
Mitsuaki Matsugu
光明 真次
Takeshi Taji
剛 田路
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Daiwa Chemical Industries Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
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Abstract

PROBLEM TO BE SOLVED: To efficiently and microbiologically treat waste edible oil contained in oil-containing sewage in a grease trap or a sewage treatment tank, installation of which is obligation of food plants and commercial kitchens, without spending time and effort like continuously charging microorganism.SOLUTION: Candida lipolytica, which is a yeast having high oil-decomposition performance, is made to be contained in a cellulosic porous carrier. After the carrier is put into a bag made of nonwoven fabric made of material which does not let the carrier pass through and processed to have a shape of a bag, the bag is sealed to form a porous carrier pack. The porous carrier pack is charged into the grease trap or the sewage treatment layer. A microbubble generator is concurrently used in place of a normal aeration.

Description

本発明はグリーストラップまたは汚水処理槽内で分離浮上する廃食用油脂を油分解酵母によって分解除去させるために必要な酵母を煩雑な手間を必要としない方法でグリーストラップまたは汚水処理槽内に供給し、マイクロバブルによって空気を槽内に供給することにより効率的に油含有汚水の浄化をおこなう油含有汚水微生物処理システムに関するものである。    The present invention supplies yeast necessary for decomposing and removing waste edible fats and oils separated and floated in a grease trap or sewage treatment tank into the grease trap or sewage treatment tank in a method that does not require complicated labor. The present invention relates to an oil-containing sewage microbial treatment system that efficiently purifies oil-containing sewage by supplying air into the tank using microbubbles.

食品工場や業務用厨房など油を含んだ廃水を多量に排出する施設には、廃食用油脂が公共の下水管に直接流れ込まないようにするためにグリーストラップまたは汚水処理槽の設置が下水道法で義務つけられている。グリーストラップまたは汚水処理槽中とは、液槽の一側部から廃食用油脂を含んだ油含有廃水を流入させ、液槽内で廃食用油脂をその比重差により浮上させて分離し、液槽の他側部から徐油液を排出するもので、廃水に含まれる廃食用油脂の物理的除去を目的としている。グリーストラップまたは汚水処理槽内に溜まった廃食用油脂や汚泥は槽内に滞留し、残りの徐油液はトラップ管を経て下水管へ排水される。  In facilities that discharge large amounts of oil-containing wastewater, such as food factories and commercial kitchens, the sewerage law requires the installation of grease traps or sewage treatment tanks to prevent waste edible oils from flowing directly into public sewers. It is obliged. In the grease trap or sewage treatment tank, oil-containing wastewater containing waste edible fats and oils flows from one side of the liquid tank, and the waste edible fats and oils float in the liquid tank due to the difference in specific gravity. It discharges the gradual oil solution from the other side, and is intended for the physical removal of the edible fat and oil contained in the wastewater. Waste edible oil and sludge accumulated in the grease trap or sewage treatment tank stays in the tank, and the remaining gradual oil is drained to the sewer pipe through the trap pipe.

一般にグリーストラップまたは汚水処理槽で分離された廃食用油脂はひしゃくなどですくい上げて回収し産業廃棄物として処分される。分離した廃食用油脂やスラッジを液槽内に放置しておくと、嫌気性微生物により油脂類の分解性成分であるアンモニアや硫化水素が発生し猛烈な悪臭の原因となる。また、トラップ管を超えて外部へ流出した廃食用油脂が下水管を詰まらせたりする。悪臭などにより厨房内環境が悪化し、害虫発生など衛生面においても深刻な問題となり得るため、通常1ヶ月に1度程度汲み取り廃棄処分をするのが一般的とされる。In general, waste edible oils and fats separated in a grease trap or sewage treatment tank are scooped up with a ladle and collected and disposed as industrial waste. If the separated waste edible oil and sludge are left in the liquid tank, ammonia and hydrogen sulfide, which are degradable components of the oil and fat, are generated by anaerobic microorganisms, causing a severe odor. Moreover, the waste edible oil and oil which flowed out beyond the trap pipe may clog the sewer pipe. The kitchen environment is deteriorated due to bad odors and can cause serious problems in terms of hygiene such as the generation of pests. Therefore, it is generally taken up and disposed of about once a month.

ところが、この清掃作業は、腐敗臭の中で行う汚い作業であるため、従業員も敬遠しがちになり、定期的な清掃やメンテナンスが行われていないことが多い。
また、グリーストラップまたは汚水処理槽を経て排出される徐油液中には多少の廃食用油脂が残留しており、この廃食用油脂が排水管内壁に付着して凝固し、排水管を詰まらせ、廃水が逆流する場合があり、逆流廃水により汚染された範囲の浄化や詰まった配水管の復旧には膨大な費用がかかる。
However, since this cleaning work is a dirty work performed in a rotting odor, employees tend to avoid it, and regular cleaning and maintenance are often not performed.
Also, some waste edible oil and fat remains in the gradual oil discharged through the grease trap or sewage treatment tank, and this waste edible oil and fat adheres to the inner wall of the drain pipe and solidifies, clogging the drain pipe. In some cases, wastewater flows backward, and it is very expensive to purify the area contaminated by the backflow wastewater and restore clogged water pipes.

グリーストラップの有する問題を解決するために油分解能を持った微生物製剤を用いて液槽内の油を分解させるシステムが報告されている。(特開2005−230706バイオ型グリーストラップ、特開2004−346695グリーストラップ槽の浄化方法と浄化装置)
これは粉末状もしくは液体状の微生物製剤を一定時間ごとにグリーストラップの液槽に注入する微生物供給装置と、微生物が酸素を吸収して活性化しやすいように液槽内に空気を供給するエアブロアを備えたエアレーション装置とで構成されている。
In order to solve the problem of the grease trap, a system for decomposing oil in a liquid tank using a microbial preparation having oil decomposability has been reported. (Japanese Patent Laid-Open No. 2005-230706 Bio-type Grease Trap, Japanese Patent Laid-Open No. 2004-346695 Grease Trap Tank Purification Method and Purification Device)
This consists of a microbial supply device that injects powdered or liquid microbial preparations into the grease trap liquid tank at regular intervals, and an air blower that supplies air into the liquid tank so that the microorganisms can absorb oxygen and be activated easily. It is comprised with the aeration apparatus provided.

しかし、厨房廃水の流入により槽内の廃水が流出することにより注入した微生物がすぐに流失するため、常に菌を必要量注入して槽内の油分解微生物生菌数を一定以上に維持しなければならない。However, since the injected microorganisms are washed away by the outflow of the wastewater in the tank due to the inflow of kitchen wastewater, the necessary amount of bacteria must always be injected to maintain the number of live oil-decomposing microorganisms in the tank above a certain level. I must.

本発明が解決しようとする課題Problems to be solved by the present invention

本発明は前述のごとく微生物を絶えず注入するような手間をかけず、食品工場や業務用厨房に設置が義務付けられているグリーストラップ又は汚水処理槽中の油含有汚水に含まれる廃食用油脂を効率よく微生物学的処理することを課題とする。As described above, the present invention eliminates the trouble of constantly injecting microorganisms, and efficiently uses waste edible fats and oils contained in oil-containing sewage in grease traps or sewage treatment tanks that are obliged to be installed in food factories or commercial kitchens The problem is to perform microbiological treatment well.

課題を解決するための手段Means for solving the problem

前記目的を達成するため鋭意研究を重ねた結果本発明にいたったので以下に詳細を述べる。As a result of intensive studies to achieve the above object, the present invention has been reached, and details will be described below.

本発明は油分解性能の高い酵母Candida lipolyticaをセルロース系多孔質担体に含有させ、これをその担体を通さない材質からなる不織布を袋状に加工した袋に投入後、密閉することにより形成した多孔質担体パックを汚水処理層に投入することにより、また通常のエアレーションに代えてマイクロバブル発生装置を併用することにより、毎日の頻繁な酵母の添加を必要とせず、月に1回程度のパックの交換又は担体への酵母補充で効率よく油含有廃水を処理することを見出した。The present invention contains a yeast Candida lipolytica having a high oil-decomposing performance in a cellulosic porous carrier, and a porous material formed by sealing the nonwoven fabric made of a material that does not pass through the carrier into a bag processed into a bag shape. By introducing the quality carrier pack into the sewage treatment layer, and by using a microbubble generator in combination with normal aeration, it is not necessary to add yeast frequently every day, It has been found that oil-containing wastewater can be efficiently treated by exchange or yeast supplementation of the carrier.

本発明に使用する油分解性の高い酵母はCandida lipolyticaであり、種々の微生物を検討したがこのものが一番優れていた。The highly oil-degradable yeast used in the present invention is Candida lipolytica, and various microorganisms have been examined, and this was the most excellent.

本発明に使用する酵母Candida lipolyticaは液状であっても粉末状であってもかまわないが、保存安定性を考えた時粉末品が望ましい。The yeast Candida lipolytica used in the present invention may be in the form of a liquid or a powder, but is preferably a powder product in view of storage stability.

本発明に用いる多孔質担体の素材はセルロース系のものが優れており、適当な大きさの粒状で、直径3mm〜20mmのものが望ましい。The material of the porous carrier used in the present invention is preferably a cellulose-based material, and it is desirable that the material has an appropriate size and a diameter of 3 mm to 20 mm.

本発明において、多孔質担体は廃食用油脂を含む油含有汚水の微生物学的処理に使用するとき、以下に述べる特性を有する。
▲1▼表面は多孔質構造に由来する油脂の吸着能または吸油性を持っていること
▲2▼上記多孔質構造は汚水処理用微生物を多量に固定できる微生物担体として機能すること。
▲3▼見かけのかさ比重が小さく、汚水面に常に浮かぶゆえに汚水面の廃食用油脂を吸着するに適した場を確保出来ること。
In the present invention, the porous carrier has the characteristics described below when used for the microbiological treatment of oil-containing wastewater containing waste edible fats and oils.
(1) The surface has an adsorption capacity or oil absorption of fats and oils derived from the porous structure. (2) The porous structure functions as a microorganism carrier capable of immobilizing a large amount of sewage treatment microorganisms.
(3) Since the apparent bulk specific gravity is small and it always floats on the sewage surface, it is possible to secure a place suitable for adsorbing waste edible oil on the sewage surface.

本発明における酵母含有担体の製造方法はセルロース系担体に液状又は粉末状の酵母を必要量含浸又は散布し均一に担持させることにより作製する。The method for producing a yeast-containing carrier in the present invention is prepared by impregnating or spraying a cellulose-based carrier with a required amount of liquid or powdery yeast and uniformly carrying it.

本発明にて使用する不織布袋の素材としては、ポリエチレン、ポリプロピレン、セルロース、ポリ乳酸、脂肪酸誘導ポリウレタン、およびこれらのハイブリッド品等が使用でき、袋状に形成した際に多孔質担体や酵母増殖拠点が容易には外部廃水に流出してしまわないような適切な組織であることが望ましい。As the material for the non-woven bag used in the present invention, polyethylene, polypropylene, cellulose, polylactic acid, fatty acid-derived polyurethane, and hybrid products thereof can be used. However, it is desirable to have an appropriate organization that does not easily leak into external wastewater.

本発明において、上記素材よりなる不織布は廃食用油脂を含む汚水の微生物学的処理に使用するとき、以下に述べる特性を有する。
▲1▼不織布の繊維自体、完全には多孔質構造とはいえないが、不織布の単位堆積あたりの繊維密度を高くすることによって多孔質構造に似た比表面積を有し、廃食用油脂の吸着能を向上させることができる。
▲2▼汚水処理用微生物を多量に固定できる微生物担体として機能できる。
In this invention, the nonwoven fabric which consists of the said raw material has the characteristic described below, when using it for the microbiological process of the wastewater containing waste edible fats and oils.
(1) Non-woven fabric fiber itself is not completely porous, but has a specific surface area similar to the porous structure by increasing the fiber density per unit pile of non-woven fabric, and adsorbs waste edible fats and oils. Performance can be improved.
(2) It can function as a microorganism carrier capable of fixing a large amount of sewage treatment microorganisms.

本発明の酵母含有担体パックの製造方法は酵母含有担体を袋状の不職布に投入後、入り口をヒートシール、ファスナー(面ファスナーを含む)または接着剤などによる接着にて密封し製造する。すなわち使い捨ての用途の場合ヒートシール、接着剤で密封するが、再使用の場合、担体の交換、酵母の追加が容易にできるファスナーによる密封を行う。In the method for producing a yeast-containing carrier pack of the present invention, the yeast-containing carrier is put into a bag-like unwoven cloth, and then the entrance is sealed by heat sealing, bonding with a fastener (including a hook-and-loop fastener) or an adhesive. That is, in the case of a disposable application, it is sealed with a heat seal or an adhesive, but in the case of reuse, it is sealed with a fastener that can easily replace the carrier and add yeast.

本発明の実施の形態を実施例に基づいて説明するが、本発明はこれらに限定されない。Embodiments of the present invention will be described based on examples, but the present invention is not limited thereto.

実施例1
30Lの模擬廃水(食用油5,000mg/L含有、約30℃)の入ったの水槽にマイクロバブル発生装置を施し、ここに弊社保管油分解枯草菌(Bacillus subtilis)、弊社保管油分解酵母(Pichia farinosa)、弊社保管油分解酵母(Candida lipolytica)をそれぞれ10生菌数/廃水1L添加し、模擬廃水中の油脂分(ノルマルヘキサン抽出物質量mg/L)の経時的変化を測定した。結果を表−1に示す。
弊社保管油分解酵母であるCandida lipolyticaにおいて優位な油分解性能を確認した。

Figure 2013022586
Example 1
A microbubble generator is applied to a water tank containing 30 L of simulated waste water (containing edible oil 5,000 mg / L, about 30 ° C.), and our stored oil-degrading Bacillus subtilis (Bacillus subtilis), our stored oil-degrading yeast ( Pichia farinosa) and our stored oil-degrading yeast (Candida lipolytica) were each added with 10 8 viable bacteria / 1 L of waste water, and the change over time in the fat and oil content in the simulated waste water (normal hexane extract substance amount mg / L) was measured. The results are shown in Table-1.
In Candida lipolytica which is our stored oil-decomposing yeast, we confirmed superior oil-decomposing performance.
Figure 2013022586

実施例2
多孔質担体としてポリウレタンビーズ(BCN:日清紡(株)製)、ポリビニルアルコール(PVA)スポンジ(マイクロブレス:アイオン(株)製)、セルロースビーズ(ビスコパール:レンゴー(株)製)の3種を選び、それぞれの担体1gに酵母Candida lipolyticaが生菌数として10生菌数付着させたものを作製した。
別途目付け75g/mのポリプロピレン製不織布を加工して幅170mm、長さ300mmの袋を形成する。この袋の中に先に作製した酵母Candida lipolyticaを付着させた担体30gを封入したものを酵母含有多孔質担体パックとする(斜視図:図1、断面図:図2)。この酵母含有多孔質担体パックをそれぞれ30Lの模擬廃水(食用油5,000mg/L含有、約30℃)の入った水槽に設置し、底部にマイクロバブル発生装置を施した。
模擬廃水中の油脂分(ノルマルヘキサン抽出物質量mg/L)の経時的変化を測定した。結果を表2に示す。担体素材としてセルロースビーズを用いたものにおいて優位な油分解性能を確認した。

Figure 2013022586
Example 2
Three types of porous carriers are selected: polyurethane beads (BCN: manufactured by Nisshinbo Co., Ltd.), polyvinyl alcohol (PVA) sponge (Micro Breath: manufactured by Aion Co., Ltd.), and cellulose beads (Visco Pearl: manufactured by Rengo Co., Ltd.). Then, 1 g of each carrier was prepared by adhering 10 8 viable cell counts as the viable cell count of yeast Candida lipolytica.
Separately, a polypropylene nonwoven fabric having a basis weight of 75 g / m 2 is processed to form a bag having a width of 170 mm and a length of 300 mm. A bag containing 30 g of a carrier to which the yeast Candida lipolytica previously prepared is encapsulated in this bag is used as a yeast-containing porous carrier pack (perspective view: FIG. 1, sectional view: FIG. 2). Each of the yeast-containing porous carrier packs was placed in a water tank containing 30 L of simulated waste water (containing edible oil 5,000 mg / L, about 30 ° C.), and a microbubble generator was applied to the bottom.
The time-dependent change of fats and oils in the simulated wastewater (normal hexane extract substance amount mg / L) was measured. The results are shown in Table 2. The oil decomposition performance superior in cellulose beads as the carrier material was confirmed.
Figure 2013022586

実施例3
エアレーションについて異なる条件で比較した。比較するエアレーション条件としては、エアレーション無し、一般的なエアレーション装置(HIBLOW HP20:(株)テクノ高槻製)使用、マイクロバブル発生装置(YJノズル:エンバイロビジョン(株)製)使用の3条件とした。実施例2で作製したセルロースビーズを担体とした酵母含有多孔質担体パックを使用し、これを30Lの模擬廃水(食用油5,000mg/L含有、約30℃)の入った水槽に設置し、その底部に各エアレーション装置を施した。
模擬廃水中の油脂分(ノルマルヘキサン抽出物質量mg/L)の経時的変化を測定した。結果を表−3に示す。マイクロバブル発生装置を用いたものにおいて優位な油分解性能を確認した。

Figure 2013022586
Example 3
Aeration was compared under different conditions. The aeration conditions to be compared were three conditions: no aeration, use of a general aeration apparatus (HIBLOW HP20: manufactured by Techno Takatsuki), and use of a microbubble generator (YJ nozzle: manufactured by Envirovision). Using the yeast-containing porous carrier pack using the cellulose beads prepared in Example 2 as a carrier, this was installed in a water tank containing 30 L of simulated waste water (containing edible oil 5,000 mg / L, about 30 ° C.), Each aeration apparatus was applied to the bottom.
The time-dependent change of fats and oils in the simulated wastewater (normal hexane extract substance amount mg / L) was measured. The results are shown in Table-3. The oil decomposition performance superior in the one using the microbubble generator was confirmed.
Figure 2013022586

本考案多孔質担持パックの実施例を示す斜視図である。It is a perspective view which shows the Example of the porous support pack of this invention. 図1の(A)ー(A´)線に沿った断面図である。It is sectional drawing along the (A)-(A ') line | wire of FIG. 本発明実施例の断面図であるIt is sectional drawing of an Example of this invention.

この発明の実施形態を図3に示す。An embodiment of the present invention is shown in FIG.

1:不職布 2:ヒートシール部 3:微生物担持体
4:グリーストラップ 5:ストレーナー 6:隔壁
7:トラップ管 8:マイクロバブル発生装置 9:ブロア
1: Unemployed cloth 2: Heat seal part 3: Microorganism carrier 4: Grease trap 5: Strainer 6: Partition wall 7: Trap tube 8: Microbubble generator 9: Blower

Claims (2)

油分解性能の高い酵母を含有した多孔性担体を不織布袋に封入したパックを用いた油含有廃水処理方法で、
上記多孔性担体が多孔性セルロース粒子であり、
上記油分解性能の高い酵母がCandida lipolyticaであることを特徴とした油含有廃水処理システム。
In an oil-containing wastewater treatment method using a pack in which a porous carrier containing yeast with high oil-decomposing performance is enclosed in a non-woven bag,
The porous carrier is porous cellulose particles;
The oil-containing wastewater treatment system, wherein the yeast having high oil-decomposing performance is Candida lipolytica.
マイクロバブル発生装置を使用する請求項1の油含有廃水処理システム。  The oil-containing wastewater treatment system according to claim 1, wherein a microbubble generator is used.
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JP2016203040A (en) * 2015-04-16 2016-12-08 王子ホールディングス株式会社 Filter device and filtration method
JP2017020100A (en) * 2015-07-09 2017-01-26 公立大学法人大阪府立大学 Bag for metal recovery, package boody for metal recovery and method for recovering metal
US9889392B2 (en) 2016-06-03 2018-02-13 Teik Sim Quah Grease separator
JP2020191802A (en) * 2019-05-27 2020-12-03 三菱ケミカルアクア・ソリューションズ株式会社 Microorganisms, agents and methods for decomposing oil components

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016203040A (en) * 2015-04-16 2016-12-08 王子ホールディングス株式会社 Filter device and filtration method
JP2017020100A (en) * 2015-07-09 2017-01-26 公立大学法人大阪府立大学 Bag for metal recovery, package boody for metal recovery and method for recovering metal
US9889392B2 (en) 2016-06-03 2018-02-13 Teik Sim Quah Grease separator
JP2020191802A (en) * 2019-05-27 2020-12-03 三菱ケミカルアクア・ソリューションズ株式会社 Microorganisms, agents and methods for decomposing oil components
JP7258658B2 (en) 2019-05-27 2023-04-17 三菱ケミカルアクア・ソリューションズ株式会社 Microorganism, oil decomposition agent, and oil decomposition method

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