JP2012530352A - 燃料電池システムを運転するためのシステムおよび方法 - Google Patents
燃料電池システムを運転するためのシステムおよび方法 Download PDFInfo
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- JP2012530352A JP2012530352A JP2012516163A JP2012516163A JP2012530352A JP 2012530352 A JP2012530352 A JP 2012530352A JP 2012516163 A JP2012516163 A JP 2012516163A JP 2012516163 A JP2012516163 A JP 2012516163A JP 2012530352 A JP2012530352 A JP 2012530352A
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- hydrogen
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- molten carbonate
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- 239000000446 fuel Substances 0.000 title claims abstract description 464
- 238000000034 method Methods 0.000 title claims abstract description 71
- 239000001257 hydrogen Substances 0.000 claims abstract description 396
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 396
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 366
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 176
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 159
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 157
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 206
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 98
- 239000001569 carbon dioxide Substances 0.000 claims description 96
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 83
- 239000007800 oxidant agent Substances 0.000 claims description 72
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 15
- 229910052799 carbon Inorganic materials 0.000 claims description 15
- 229910002090 carbon oxide Inorganic materials 0.000 claims description 12
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 42
- 238000006243 chemical reaction Methods 0.000 description 38
- 239000000047 product Substances 0.000 description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 30
- 239000001301 oxygen Substances 0.000 description 30
- 229910052760 oxygen Inorganic materials 0.000 description 30
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 27
- 229910002091 carbon monoxide Inorganic materials 0.000 description 25
- 239000002737 fuel gas Substances 0.000 description 25
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- 238000002485 combustion reaction Methods 0.000 description 20
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- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- -1 carbonate anions Chemical class 0.000 description 8
- 238000003487 electrochemical reaction Methods 0.000 description 8
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- 239000003345 natural gas Substances 0.000 description 8
- 238000004088 simulation Methods 0.000 description 8
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 239000000571 coke Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
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- 239000000567 combustion gas Substances 0.000 description 6
- 229910001882 dioxygen Inorganic materials 0.000 description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
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- 239000000956 alloy Substances 0.000 description 3
- 150000002483 hydrogen compounds Chemical class 0.000 description 3
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 229910001260 Pt alloy Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000005587 carbonate group Chemical group 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 230000008713 feedback mechanism Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- HDBYNYITZLDJDW-UHFFFAOYSA-N [O-2].[Fe+2].[Ni+2].[Li+] Chemical compound [O-2].[Fe+2].[Ni+2].[Li+] HDBYNYITZLDJDW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000002453 autothermal reforming Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- PJDBNXBGLPONPX-UHFFFAOYSA-J calcium lithium sodium dicarbonate Chemical compound C([O-])([O-])=O.[Ca+2].[Na+].[Li+].C([O-])([O-])=O PJDBNXBGLPONPX-UHFFFAOYSA-J 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 description 1
- 125000005586 carbonic acid group Chemical group 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical group CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000002001 electrolyte material Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- LCBKDULHZJKFJQ-UHFFFAOYSA-N lithium chromium(3+) oxygen(2-) Chemical compound [Li+].[O--].[O--].[Cr+3] LCBKDULHZJKFJQ-UHFFFAOYSA-N 0.000 description 1
- HAZVUEHTVZUNHT-UHFFFAOYSA-J lithium sodium barium(2+) dicarbonate Chemical compound C([O-])([O-])=O.[Ba+2].[Na+].[Li+].C([O-])([O-])=O HAZVUEHTVZUNHT-UHFFFAOYSA-J 0.000 description 1
- VMJMQRNRWGOEAE-UHFFFAOYSA-L lithium;potassium;carbonate Chemical compound [Li+].[K+].[O-]C([O-])=O VMJMQRNRWGOEAE-UHFFFAOYSA-L 0.000 description 1
- STJUJXONQFLCOP-UHFFFAOYSA-L lithium;sodium;carbonate Chemical compound [Li+].[Na+].[O-]C([O-])=O STJUJXONQFLCOP-UHFFFAOYSA-L 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
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- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
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- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
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- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
- C01B2203/0827—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
- C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/08—Methods of heating or cooling
- C01B2203/0872—Methods of cooling
- C01B2203/0883—Methods of cooling by indirect heat exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/12—Feeding the process for making hydrogen or synthesis gas
- C01B2203/1205—Composition of the feed
- C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
- C01B2203/1235—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/142—At least two reforming, decomposition or partial oxidation steps in series
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/14—Details of the flowsheet
- C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/16—Controlling the process
- C01B2203/169—Controlling the feed
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M2008/147—Fuel cells with molten carbonates
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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US18752609P | 2009-06-16 | 2009-06-16 | |
US61/187,526 | 2009-06-16 | ||
PCT/US2010/038495 WO2010147886A1 (en) | 2009-06-16 | 2010-06-14 | Systems and processes for operating fuel cell systems |
Publications (2)
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JP2012530352A true JP2012530352A (ja) | 2012-11-29 |
JP2012530352A5 JP2012530352A5 (enrdf_load_stackoverflow) | 2013-06-20 |
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JP2012516163A Pending JP2012530352A (ja) | 2009-06-16 | 2010-06-14 | 燃料電池システムを運転するためのシステムおよび方法 |
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Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
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US9077008B2 (en) | 2013-03-15 | 2015-07-07 | Exxonmobil Research And Engineering Company | Integrated power generation and chemical production using fuel cells |
KR102222295B1 (ko) | 2013-03-15 | 2021-03-03 | 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 | 연료 전지를 사용한 통합된 발전 및 화합물 생산 |
US9819042B2 (en) | 2013-09-30 | 2017-11-14 | Exxonmobil Research And Engineering Company | Fuel cell integration within a heat recovery steam generator |
US9755258B2 (en) | 2013-09-30 | 2017-09-05 | Exxonmobil Research And Engineering Company | Integrated power generation and chemical production using solid oxide fuel cells |
US9556753B2 (en) | 2013-09-30 | 2017-01-31 | Exxonmobil Research And Engineering Company | Power generation and CO2 capture with turbines in series |
KR20190070565A (ko) | 2017-12-13 | 2019-06-21 | 주식회사 모컴테크 | 광범위 집음 장치 시스템 |
JP6664423B2 (ja) * | 2018-02-06 | 2020-03-13 | 東京瓦斯株式会社 | 二酸化炭素製造システム |
SG11202105643TA (en) | 2018-11-30 | 2021-06-29 | Exxonmobil Res & Eng Co | Cathode collector structures for molten carbonate fuel cell |
KR102774870B1 (ko) | 2018-11-30 | 2025-02-27 | 퓨얼셀 에너지, 인크 | 심층 co2 포획을 위한 용융 탄산염 연료전지들의 재생성 |
WO2020112774A1 (en) | 2018-11-30 | 2020-06-04 | Exxonmobil Research And Engineering Company | Elevated pressure operation of molten carbonate fuel cells with enhanced co2 utilization |
WO2020112834A1 (en) | 2018-11-30 | 2020-06-04 | Exxonmobil Research And Engineering Company | Fuel cell staging for molten carbonate fuel cells |
KR102610181B1 (ko) | 2018-11-30 | 2023-12-04 | 퓨얼셀 에너지, 인크 | 향상된 co2 이용률로 작동되는 연료 전지를 위한 촉매 패턴의 개질 |
US11695122B2 (en) | 2018-11-30 | 2023-07-04 | ExxonMobil Technology and Engineering Company | Layered cathode for molten carbonate fuel cell |
SG11202105644RA (en) | 2018-11-30 | 2021-06-29 | Exxonmobil Res & Eng Co | Flow field baffle for molten carbonate fuel cell cathode |
WO2020112812A1 (en) | 2018-11-30 | 2020-06-04 | Exxonmobil Research And Engineering Company | Operation of molten carbonate fuel cells with enhanced co 2 utilization |
WO2021107935A1 (en) | 2019-11-26 | 2021-06-03 | Exxonmobil Research And Engineering Company | Operation of molten carbonate fuel cells with high electrolyte fill level |
KR20220113681A (ko) | 2019-11-26 | 2022-08-16 | 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 | 연료 전지 모듈 조립체 및 이를 사용하는 시스템 |
KR20220107179A (ko) | 2019-11-26 | 2022-08-02 | 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 | 병렬 유동을 위한 외부 매니폴드를 갖는 연료 전지 어셈블리 |
US11978931B2 (en) | 2021-02-11 | 2024-05-07 | ExxonMobil Technology and Engineering Company | Flow baffle for molten carbonate fuel cell |
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- 2010-06-14 KR KR1020117030076A patent/KR20120028927A/ko not_active Withdrawn
- 2010-06-14 EP EP10789996.5A patent/EP2443689A4/en not_active Withdrawn
- 2010-06-14 WO PCT/US2010/038495 patent/WO2010147886A1/en active Application Filing
- 2010-06-14 TW TW099119318A patent/TWI479729B/zh not_active IP Right Cessation
- 2010-06-14 CN CN2010800271573A patent/CN102460808A/zh active Pending
- 2010-06-14 JP JP2012516163A patent/JP2012530352A/ja active Pending
- 2010-06-14 CA CA2764207A patent/CA2764207A1/en not_active Abandoned
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Also Published As
Publication number | Publication date |
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EP2443689A1 (en) | 2012-04-25 |
CN102460808A (zh) | 2012-05-16 |
KR20120028927A (ko) | 2012-03-23 |
CA2764207A1 (en) | 2010-12-23 |
WO2010147886A1 (en) | 2010-12-23 |
TW201112487A (en) | 2011-04-01 |
TWI479729B (zh) | 2015-04-01 |
EP2443689A4 (en) | 2013-10-23 |
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