JP2012529358A - 選択された細孔サイズ分布を有する触媒、このような触媒の製造方法、原油生成物の製造方法、このような方法から得られる生成物および得られる生成物の使用 - Google Patents
選択された細孔サイズ分布を有する触媒、このような触媒の製造方法、原油生成物の製造方法、このような方法から得られる生成物および得られる生成物の使用 Download PDFInfo
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- JP2012529358A JP2012529358A JP2011504245A JP2011504245A JP2012529358A JP 2012529358 A JP2012529358 A JP 2012529358A JP 2011504245 A JP2011504245 A JP 2011504245A JP 2011504245 A JP2011504245 A JP 2011504245A JP 2012529358 A JP2012529358 A JP 2012529358A
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- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
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- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000001935 peptisation Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- VSAISIQCTGDGPU-UHFFFAOYSA-N tetraphosphorus hexaoxide Chemical compound O1P(O2)OP3OP1OP2O3 VSAISIQCTGDGPU-UHFFFAOYSA-N 0.000 description 1
- 238000010977 unit operation Methods 0.000 description 1
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Abstract
Description
Application No.11/866,909;U.S.Patent Application No.11/866,916;U.S.Patent Application No.11/866,921からU.S.Patent Application No.11/866,923まで;U.S.Patent Application No.11/866,926;U.S.Patent Application No.11/866,929およびU.S.Patent Application No.11/855,932は関連特許出願であり、原油および/または不利な原油を処理するための様々な方法、システムおよび触媒を記載する。
周期律表の6から10列からの1以上の金属および/または周期律表の6から10列からの1以上の金属の1以上の化合物を支持体と共混練(co−mulling)して金属/支持体組成物を生成し;並びに
金属/支持体組成物を315℃から760℃の範囲の温度で焼成して、細孔サイズ分布が105Åから150Åの範囲のメジアン細孔径を有し、細孔サイズ分布における細孔の総数の少なくとも60%がメジアン細孔径60Å以内の細孔径を有し、細孔内のこの細孔容積の少なくとも50%が多くとも600Åの細孔径を有し、および細孔内のこの細孔容積の5%から25%が1000Åから5000Åの細孔径を有する焼成触媒を得る、
ことを含み、細孔径および細孔容積はASTM法D4284によって測定される、触媒の製造方法を提供する。
周期律表の6から10列からの1以上の金属および/または周期律表の6から10列からの1以上の金属の1以上の化合物を含む触媒であって;
105Åから150Åの範囲のメジアン細孔径を有し、細孔サイズ分布における細孔の総数の少なくとも60%がメジアン細孔径少なくとも60Å以内の細孔径を有し、細孔内のこの細孔容積の少なくとも50%が多くとも600Åの細孔径を有し、および細孔内のこの細孔容積の5%から25%が1000Åから5000Åの細孔径を有し、細孔径および細孔容積はASTM法D4284によって測定される、
触媒を提供する。
炭化水素供給物を1以上の触媒と接触させて原油生成物を含む全生成物を生成することを含み、触媒の少なくとも1つは周期律表の6から10列からの1以上の金属および/または周期律表の6から10列からの1以上の金属の1以上の化合物を含み;6から10列金属触媒は105Åから150Åの範囲のメジアン細孔径を有し、細孔サイズ分布における細孔の総数の少なくとも60%がメジアン細孔径少なくとも60Å以内の細孔径を有し、細孔内のこの細孔容積の少なくとも50%が多くとも600Åの細孔径を有し、および細孔内のこの細孔容積の5%から25%が1000Åから5000Åの細孔径を有し、表面積がASTM法D3663によって決定され、および細孔径および細孔容積はASTM法D4284によって測定され;並びに
細孔径および細孔容積はASTM法D4284によって測定される、
方法を提供する。
ASTM法D5708による決定で少なくとも150重量ppmの合計Ni/Fe/V含有量;
ASTM法D5307による決定で炭化水素組成物のグラムあたり少なくとも0.1グラムの残滓含有量;
ASTM法D5307による決定で炭化水素組成物のグラムあたり少なくとも0.1グラムの蒸留物含有量;
ASTM法E385による決定で炭化水素組成物のグラムあたり多くとも0.1グラムの酸素含有量;および
ASTM法D4530による決定で炭化水素組成物のグラムあたり少なくとも0.05グラムの微小炭素残滓含有量
を含み、並びに37.8℃で多くとも100cStの粘度を有し、粘度はASTM法D445によって決定される、炭化水素組成物を提供する。
原油供給物のような炭化水素供給物は炭化水素供給物のグラムあたりヘテロ原子少なくとも0.005グラムの合計へテロ原子含有量を有し得る。
原油供給物のような炭化水素供給物は上記特性の組み合わせのあらゆる種類をさらに有し得る。
触媒調製およびこのような触媒を制御された接触条件下で用いる方法の非限定的な実施例を以下に示す。
炭化水素供給物、接触条件および硫化は実施例2と同じであった。
Claims (14)
- 周期律表の6から10列からの1以上の金属および/または周期律表の6から10列からの1以上の金属の1以上の化合物を支持体と共混練して金属/支持体組成物を生成し;並びに
金属/支持体組成物を315℃から760℃の範囲の温度で焼成して、105Åから150Åの範囲のメジアン細孔径を有し、細孔サイズ分布における細孔の総数の少なくとも60%がメジアン細孔径60Å以内の細孔径を有し、細孔におけるこの細孔容積の少なくとも50%が多くとも600Åの細孔径を有し、および細孔におけるこの細孔容積の5%から25%が1000Åから5000Åの細孔径を有する細孔サイズ分布を有する焼成触媒を得る、
ことを含み、細孔径および細孔容積はASTM法D4284によって測定される、触媒の製造方法。 - 周期律表の6から10列からの1以上の金属および/または周期律表の6から10列からの1以上の金属の1以上の化合物を含む触媒であって;105Åから150Åの範囲のメジアン細孔径を有し、細孔サイズ分布における細孔の総数の少なくとも60%がメジアン細孔径少なくとも60Å以内の細孔径を有し、細孔におけるこの細孔容積の少なくとも50%が多くとも600Åの細孔径を有し、および細孔におけるこの細孔容積の5%から25%が1000Åから5000Åの細孔径を有し、細孔径および細孔容積はASTM法D4284によって測定される触媒。
- 触媒が二峰性である請求項2に記載の触媒。
- 触媒が支持体を含み、この支持体がシリカ0.0001グラムから0.10グラム;およびアルミナ0.90グラムから0.9999グラムを含む、請求項2に記載の触媒。
- 原油生成物の製造方法であって:
炭化水素供給物を1以上の触媒と接触させて原油生成物を含む全生成物を生成することを含み、触媒の少なくとも1つは周期律表の6から10列からの1以上の金属および/または周期律表の6から10列からの1以上の金属の1以上の化合物を含み;6から10列金属触媒は105Åから150Åの範囲のメジアン細孔径を有し、細孔サイズ分布における細孔の総数の少なくとも60%はメジアン細孔径少なくとも60Å以内の細孔径を有し、細孔におけるこの細孔容積の少なくとも50%は多くとも600Åの細孔径を有し、および細孔におけるこの細孔容積の5%から25%は1000Åから5000Åの細孔径を有し、表面積はASTM法D3663によって決定され、並びに細孔径および細孔容積はASTM法D4284によって測定され;並びに
細孔径および細孔容積はASTM法D4284によって測定される、
方法。 - 原油生成物が25℃および0.101Mpaで液体混合物である、請求項5に記載の方法。
- 炭化水素供給物が37.8℃で少なくとも100cStの粘度を有し、原油生成物が25℃および0.101MPaで液体混合物であり、並びに原油生成物が37.8℃の炭化水素供給物の粘度の多くとも90%の37.8℃での粘度を有するように接触条件を制御することをさらに含み、粘度はASTM法D445によって測定される、請求項5に記載の方法。
- 多くとも5MPaの全圧および少なくとも200℃の温度で接触条件を制御することをさらに含む、請求項5に記載の方法。
- 原油生成物が原油生成物のグラムあたり多くとも0.01グラムの沈殿含有量を有する、請求項5に記載の方法。
- 原油生成物を1以上の蒸留物画分に分画し、蒸留物画分の少なくとも1つから輸送燃料を生成することをさらに含む、請求項5に記載の方法。
- 請求項5から10のいずれかにおいて請求される方法によって生成される原油生成物。
- 炭化水素組成物であって:
ASTM法D5708による決定で少なくとも150重量ppmの合計Ni/Fe/V含有量;
ASTM法D5307による決定で炭化水素組成物のグラムあたり少なくとも0.1グラムの残滓含有量;
ASTM法D5307による決定で炭化水素組成物のグラムあたり少なくとも0.1グラムの蒸留物含有量;
ASTM法E385による決定で炭化水素組成物のグラムあたり多くとも0.1グラムの酸素含有量;および
ASTM法D4530による決定で炭化水素組成物のグラムあたり少なくとも0.05グラムの微小炭素残滓含有量、
を含み、並びに37.8℃で多くとも100cStの粘度を有し、粘度はASTM法D445によって決定される、炭化水素組成物。 - 請求項11において主張される原油生成物または請求項12において主張される炭化水素組成物から製造される1以上の蒸留物画分を含む輸送燃料。
- 請求項11において主張される原油生成物または請求項12において主張される炭化水素組成物から製造される1以上の蒸留物画分を含む希釈剤。
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JP2018086656A (ja) * | 2011-10-27 | 2018-06-07 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 重質炭化水素原料を処理するための自己活性化水素化触媒および方法 |
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US8450538B2 (en) | 2013-05-28 |
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US8318000B2 (en) | 2012-11-27 |
US20120116145A1 (en) | 2012-05-10 |
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WO2009126973A3 (en) | 2010-10-07 |
CA2904552A1 (en) | 2009-10-15 |
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