JP2012193148A - Aqueous makeup cosmetic - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide an aqueous makeup cosmetic having excellent cosmetic effect, which has satisfactory cosmetic retainability, excellent adhesion, high shiny appearance of pearls and is finished into a uniform cosmetic film.SOLUTION: The aqueous makeup cosmetic is blended with: (A) gellan gum and/or pectin; (B) a specified fluorine-containing copolymer; (C) water; and (D) photoluminescent powder.

Description

  The present invention relates to a makeup cosmetic, and more specifically, blending gellan gum and / or pectin, a specific fluorine-containing copolymer, water, and a glitter powder so that the makeup lasts well and adheres to the skin. The present invention relates to a water-based makeup cosmetic that is excellent in cosmetic properties, has an excellent pearly luster, and has a cosmetic effect that is finished into a uniform cosmetic film.

  Makeup cosmetics are required to have a high pearly luster for application to the eyelids and cheeks, shading, and producing a cosmetic effect. Aqueous makeup cosmetics, in which glittering powder is blended with a base that forms a gel using water and an aqueous gelling agent, can produce the transparent glossiness and wateriness of the base. Can and is preferred by the market. Aqueous makeup cosmetics are composed of an aqueous gelling agent, powder, and water. In order to improve the feeling of use and functionality required for cosmetics, formulation studies of dosage forms and components have been conducted.

As aqueous makeup cosmetics, gelling gum or pectin as a gelling agent have been studied so far because they are excellent in terms of transparency and wateriness. For example, there is a technique (Patent Document 1) that obtains an optical effect of pearly luster powder by blending an aqueous thickening / gelling agent such as gellan gum or alkyl acrylate copolymer polymer emulsion with pearly luster powder. is there.
However, such cosmetics tend to have poor makeup because they are weakly adhered to the skin and are sensitive to sweat. Particularly, the pearly luster powder having a large particle size is not satisfactory because it peels off. As a study to improve the longevity of cosmetics, for example, in the technology (Patent Document 3) in which a film forming agent such as polyether-modified silicone is blended with native gellan gum and a pearl color material, the cosmetic longevity is improved. There was a tendency for the cosmetic film to become non-uniform because it was difficult to disperse in an aqueous system. The technique of blending gellan gum and glycerin (Patent Document 2) has good dispersibility in water and a uniform makeup film is obtained, but it is weak against sweat and lacks satisfaction.

JP-A-2005-97148 JP 2004-292375 A JP 2008-273877 A

  In view of the above circumstances, it is an object of the present invention to provide an aqueous makeup cosmetic that has a good makeup, excellent adhesion, high gloss of pearl, and excellent makeup effect that is finished in a uniform cosmetic film. To do.

  The inventors of the present invention formulate an aqueous makeup cosmetic using gellan gum with an adhesive component that has high adhesion to the skin, is resistant to sweat and sebum, and has good dispersibility in aqueous systems. As a result, it was considered that the makeup-holding effect could be enhanced, and as a result of investigating the blending of various components, by blending a specific fluorine-containing copolymer having a hydrophilic group, the adhesion to the skin was high and flexible. The present invention has been completed by finding that it is excellent in long-lasting makeup because it forms a beautiful decorative film and that it is finished in a uniform decorative film due to its good dispersibility in water.

  That is, the present invention provides an aqueous makeup makeup comprising (A) gellan gum and / or pectin, (B) a specific fluorine-containing copolymer, (C) water, and (D) a glitter powder. A fee is provided.

  The present invention provides an aqueous makeup cosmetic that has good makeup, has high adhesion to the skin, has a high gloss of pearl, and has an excellent cosmetic effect that is finished into a uniform cosmetic film.

The present invention will be described in detail below.
The component (A) gellan gum and / or pectin used in the aqueous makeup cosmetic of the present invention is a polysaccharide aqueous gelling agent that forms an elastic gel by swelling with water. Gellan gum includes deacylated gellan gum and native gellan gum, both of which can be suitably used. Gellan gum and pectin are used in foods, cosmetics, etc., and commercially available gellan gum products such as Kelcogel, Kelcogel LT100, Kelcogel HM (manufactured by Dainippon Sumitomo Pharma Co., Ltd.), and the like, Genupectin LM- 104AS-J (manufactured by CP Kelco Co., Ltd.) and the like, and one or more of these may be combined.

  The amount of component (A) used in the present invention is not particularly limited as long as it is an amount sufficient to form a gel, but is preferably 0.1 to 5% by mass (hereinafter referred to as%), more preferably. 0.2-2%. Within this range, a gel with a good pearl feeling can be formed.

  The specific fluorine-containing copolymer of the component (B) in the present invention contains a fluorine-containing monomer (b1) represented by the following general formula (1) and an alkoxy group represented by the following general formula (2). It is obtained by copolymerizing a monomer essentially containing the monomer (b2).

  The fluorine-containing monomer (b1) is represented by the following general formula (1).

_{CH 2 = C (-X) -C} (= O) -Y - [- (CH 2) m -Z-] p - (CH 2) n -Rf · (1)
[Wherein, X represents a hydrogen atom, a linear or branched alkyl group having 1 to 21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or a CFX ¹ X ² group (where X ¹ and X ² is a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, respectively), a cyano group, a linear or branched fluoroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted benzyl group. A substituted or unsubstituted phenyl group; Y is —O— or —NH—; Z is a direct bond, —S— or —SO ₂ —; Rf has 1 to 6 carbon atoms; A fluoroalkyl group; m is 1 to 10, n is 0 to 10, and p is 0 or 1. ]

The alkoxy group-containing monomer (b2) is represented by the following general formula (2).
^{_{CH 2 = C (R 1)}} -C (= O) -O- (R 2 O) q -R 3 ··· (2)
[In the formula, R ¹ is a hydrogen atom or a methyl group; R ² is an alkylene group having some or all carbon atoms which may be substituted with a hydroxyl group of 2 to 4 hydrogen atoms; R ³ is hydrogen An atom or an unsaturated or saturated hydrocarbon group having 1 to 22 carbon atoms; q is an integer of 1 to 50; ]

  In the general formula (1), p is preferably 0. A preferred example of X is a hydrogen atom.

In the general formula (1), Rf generally represents a perfluoroalkyl group and / or a partially fluorinated fluoroalkyl group, and is preferably a perfluoroalkyl group. The alkyl group of Rf has 1 to 6 carbon atoms, preferably 4, 5 or 6, and particularly preferably 6. Examples of Rf _{are, -CF 3, -CF 2 CF 3} , -CF 2 CF 2 CF 3, CF (CF 3) 2, -CF 2 CF 2 CF 2 CF 3, -CF 2 CF (CF 3) 2, _{-C (CF 3) 3, -} (CF 2) 4 CF 3, - (CF 2) 2 CF (CF 3) 2, -CF 2 C (CF 3) 3, -CF (CF 3) CF 2 CF 2 _{CF 3, - (CF 2)} 5 CF 3 , and the like.

The fluorine-containing monomer (b1) may be used alone or in combination of two or more.

As a fluorine-containing monomer (b1), the following are mentioned, for example.
_{CH 2 = C (-X) -COO-} (CH 2) m -S- (CH 2) n -Rf
_{CH 2 = C (-X) -COO-} (CH 2) m -SO 2 - (CH 2) n -Rf
_{CH 2 = C (-X) -COO-} (CH 2) n -Rf
_{CH 2 = C (-X) -CO} -NH- (CH 2) n -Rf
[Wherein, X represents a hydrogen atom, a linear or branched alkyl group having 1 to 21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or a CFX ¹ X ² group (where X ¹ and X ² is a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, respectively), a cyano group, a linear or branched fluoroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted benzyl group. A substituted or unsubstituted phenyl group; Y is —O— or —NH—; Z is a direct bond, —S— or —SO ₂ —; Rf has 1 to 6 carbon atoms; A fluoroalkyl group; m is 1 to 10, n is 0 to 10, and p is 0 or 1. ]

Specific examples of the general formula (1) include the following, but are not limited thereto.
_{CH 2 = C (-H) -COO-} (CH 2) 2 -S-Rf
_{CH 2 = C (-H) -COO-} (CH 2) 2 -S- (CH 2) 2 -Rf
_{CH 2 = C (-H) -COO-} (CH 2) 3 -SO 2 -Rf
_{CH 2 = C (-H) -COO-} (CH 2) 2 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-H) -COO-} (CH 2) 2 -Rf
_{CH 2 = C (-H) -CO} -NH- (CH 2) 2 -Rf
_{CH 2 = C (-H) -COO} -CH 2 CH 2 N (C 2 H 5) SO 2 -Rf
_{CH 2 = C (-H) -COO} -CH 2 CH 2 N (CH 3) SO 2 -Rf
_{CH 2 = C (-H) -COO} -CH 2 CH (OCOCH 3) SO 2 -Rf
_{CH 2 = C (-CH 3)} -COO- (CH 2) 2 -S-Rf
_{CH 2 = C (-CH 3)} -COO- (CH 2) 2 -S- (CH 2) 2 -Rf
_{CH 2 = C (-CH 3)} -COO- (CH 2) 3 -SO 2 -Rf
_{CH 2 = C (-CH 3)} -COO- (CH 2) 2 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-CH 3)} -COO- (CH 2) 2 -Rf
_{CH 2 = C (-CH 3)} -CO-NH- (CH 2) 2 -Rf
_{CH 2 = C (-CH 3)} -COO-CH 2 CH 2 N (C 2 H 5) SO 2 -Rf
_{CH 2 = C (-CH 3)} -COO-CH 2 CH 2 N (CH 3) SO 2 -Rf
_{CH 2 = C (-CH 3)} -COO-CH 2 CH (OCOCH 3) CH 2 -Rf

_{CH 2 = C (-F) -COO-} (CH 2) 2 -S-Rf
_{CH 2 = C (-F) -COO-} (CH 2) 2 -S- (CH 2) 2 -Rf
_{CH 2 = C (-F) -COO-} (CH 2) 2 -SO 2 -Rf
_{CH 2 = C (-F) -COO-} (CH 2) 2 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-F) -COO-} (CH 2) 2 -Rf
_{CH 2 = C (-F) -CO} -NH- (CH 2) 2 -Rf
_{CH 2 = C (-Cl) -COO-} (CH 2) 2 -S-Rf
_{CH 2 = C (-Cl) -COO-} (CH 2) 2 -S- (CH 2) 2 -Rf
_{CH 2 = C (-Cl) -COO-} (CH 2) 2 -SO 2 -Rf
_{CH 2 = C (-Cl) -COO-} (CH 2) 2 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-Cl) -COO-} (CH 2) 2 -Rf
_{CH 2 = C (-Cl) -CO} -NH- (CH 2) 2 -Rf

_{CH 2 = C (-CF 3)} -COO- (CH 2) 2 -S-Rf
_{CH 2 = C (-CF 3)} -COO- (CH 2) 2 -S- (CH 2) 2 -Rf
_{CH 2 = C (-CF 3)} -COO- (CH 2) 2 -SO 2 -Rf
_{CH 2 = C (-CF 3)} -COO- (CH 2) 2 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-CF 3)} -COO- (CH 2) 2 -Rf
_{CH 2 = C (-CF 3)} -CO-NH- (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 H} ) -COO- (CH 2) 2 -S-Rf
_{CH 2 = C (-CF 2 H} ) -COO- (CH 2) 2 -S- (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 H} ) -COO- (CH 2) 2 -SO 2 -Rf
_{CH 2 = C (-CF 2 H} ) -COO- (CH 2) 2 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 H} ) -COO- (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 H} ) -CO-NH- (CH 2) 2 -Rf
_{CH 2 = C (-CN) -COO-} (CH 2) 2 -S-Rf
_{CH 2 = C (-CN) -COO-} (CH 2) 2 -S- (CH 2) 2 -Rf
_{CH 2 = C (-CN) -COO-} (CH 2) 2 -SO 2 -Rf
_{CH 2 = C (-CN) -COO-} (CH 2) 2 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-CN) -COO-} (CH 2) 2 -Rf
_{CH 2 = C (-CN) -CO} -NH- (CH 2) 2 -Rf

_{CH 2 = C (-CF 2 CF} 3) -COO- (CH 2) 2 -S-Rf
_{CH 2 = C (-CF 2 CF} 3) -COO- (CH 2) 2 -S- (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 CF} 3) -COO- (CH 2) 2 -SO 2 -Rf
_{CH 2 = C (-CF 2 CF} 3) -COO- (CH 2) 2 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 CF} 3) -COO- (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 CF} 3) -CO-NH- (CH 2) 2 -Rf
_{CH 2 = C (-F) -COO-} (CH 2) 3 -S-Rf
_{CH 2 = C (-F) -COO-} (CH 2) 3 -S- (CH 2) 2 -Rf
_{CH 2 = C (-F) -COO-} (CH 2) 3 -SO 2 -Rf
_{CH 2 = C (-F) -COO-} (CH 2) 3 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-F) -COO-} (CH 2) 3 -Rf
_{CH 2 = C (-F) -CO} -NH- (CH 2) 3 -Rf

_{CH 2 = C (-Cl) -COO-} (CH 2) 3 -S-Rf
_{CH 2 = C (-Cl) -COO-} (CH 2) 3 -S- (CH 2) 2 -Rf
_{CH 2 = C (-Cl) -COO-} (CH 2) 3 -SO 2 -Rf
_{CH 2 = C (-Cl) -COO-} (CH 2) 3 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-CF 3)} -COO- (CH 2) 3 -S-Rf
_{CH 2 = C (-CF 3)} -COO- (CH 2) 3 -S- (CH 2) 2 -Rf
_{CH 2 = C (-CF 3)} -COO- (CH 2) 3 -SO 2 -Rf
_{CH 2 = C (-CF 3)} -COO- (CH 2) 3 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 H} ) -COO- (CH 2) 3 -S-Rf
_{CH 2 = C (-CF 2 H} ) -COO- (CH 2) 3 -S- (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 H} ) -COO- (CH 2) 3 -SO 2 -Rf
_{CH 2 = C (-CF 2 H} ) -COO- (CH 2) 3 -SO 2 - (CH 2) 2 -Rf

_{CH 2 = C (-CN) -COO-} (CH 2) 3 -S-Rf
_{CH 2 = C (-CN) -COO-} (CH 2) 3 -S- (CH 2) 2 -Rf
_{CH 2 = C (-CN) -COO-} (CH 2) 3 -SO 2 -Rf
_{CH 2 = C (-CN) -COO-} (CH 2) 3 -SO 2 - (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 CF} 3) -COO- (CH 2) 3 -S-Rf
_{CH 2 = C (-CF 2 CF} 3) -COO- (CH 2) 3 -S- (CH 2) 2 -Rf
_{CH 2 = C (-CF 2 CF} 3) -COO- (CH 2) 3 -SO 2 -Rf
_{CH 2 = C (-CF 2 CF} 3) -COO- (CH 2) 2 -SO 2 - (CH 2) 2 -Rf
[In the above formula, Rf is a 1-6 fluoroalkyl group. ]

Of these, in particular CH ₂ ═C (—H) —COO— (CH ₂ ) ₂ —Rf
_{CH 2 = C (-CH 3)} -COO- (CH 2) 2 -Rf
Is preferred.

  The alkoxy group-containing monomer (b2) is a non-fluorine monomer and is a compound (alkylene glycol (meth) acrylate) represented by the following general formula (2).

^{_{CH 2 = C (R 1)}} -C (= O) -O- (R 2 O) q -R 3 ··· (2)
[In the formula, R ¹ is a hydrogen atom or a methyl group; R ² is an alkylene group having some or all carbon atoms which may be substituted with a hydroxyl group of 2 to 4 hydrogen atoms; R ³ is hydrogen An atom or an unsaturated or saturated hydrocarbon group having 1 to 22 carbon atoms; q is an integer of 1 to 50; ]

In the general formula (2), R ³ is preferably a hydrogen atom.
Further, q is preferably 1 to 30, more preferably 2 to 10, and particularly preferably 2 to 5.

Furthermore, in the general formula (2), R ² is preferably ethylene or propylene, and particularly preferably ethylene. R ² in the general formula (2) may be a combination of one kind or two or more kinds of alkylene. In that case, at least one of R ² is preferably ethylene. Examples of the combination of R ² include a combination of ethylene group / propylene group and a combination of ethylene group / butylene group.

  The alkoxy group-containing monomer (b2) may be a mixture of two or more types.

Specific examples of the alkoxy group-containing monomer (b2) include, for example, the following, but are not limited thereto.
^{_{CH 2 = C (R 1)}} -COO- (CH 2 CH 2 O) q -R 3
(Hereinafter, “CH ₂ CH ₂ O” may be described as “C ₂ H ₄ O”.)
^{_{CH 2 = C (R 1)}} COO- (CH 2 CH (CH 3) O) q -R 3
^{_{CH 2 = C (R 1)}} COO- (C 2 H 4 O) q '- (CH 2 CH (CH 3) O) q "-R 3
[Where q ′ + q ″ = q]

More specific examples include the following.
_{CH 2 = C (H) COO} -CH 2 CH 2 O-H
_{CH 2 = C (H) COO-} (CH 2 CH 2 O) 4 -H
_{CH 2 = C (H) COO-} (CH 2 CH 2 O) 5 -H
_{CH 2 = C (H) COO-} (CH 2 CH 2 O) 9 -H
_{CH 2 = C (H) COO-} (CH 2 CH 2 O) 30 -H
_{CH 2 = C (CH 3)} COO- (CH 2 CH 2 O) 9 -H
_{CH 2 = C (CH 3)} COO- (CH 2 CH 2 O) 23 -H
_{CH 2 = C (CH 3)} COO- (CH 2 CH 2 O) 50 -H
_{CH 2 = C (CH 3)} COO- (CH 2 CH (CH 3) O) 9 -H
_{CH 2 = C (CH 3)} COO- (CH 2 CH 2 CH 2 O) 9 -H
_{CH 2 = C (H) COO-} (CH 2 CH (CH 3) O) 9 -H
_{CH 2 = C (CH 3)} COO- (CH 2 CH (CH 3) O) 9 -H
_{CH 2 = C (CH 3)} COO- (C 2 H 4 O) 5 - (CH 2 CH (CH 3) O) 2 -H
_{CH 2 = C (CH 3)} COO- (C 2 H 4 O) 8 - (CH 2 CH (CH 3) O) 6 -H
_{CH 2 = C (H) COO-} (C 2 H 4 O) 5 - (CH 2 CH (CH 3) O) 3 -CH 3

Of these, CH ₂ ═C (H) COO—CH ₂ CH ₂ O—H
_{CH 2 = C (H) COO-} (CH 2 CH 2 O) 4 -H
_{CH 2 = C (H) COO-} (CH 2 CH 2 O) 5 -H
_{CH 2 = C (CH 3)} COO-CH 2 CH 2 O-H
_{CH 2 = C (CH 3)} COO- (CH 2 CH 2 O) 4 -H
_{CH 2 = C (CH 3)} COO- (CH 2 CH 2 O) 5 -H
Is preferred.

If the specific fluorine-containing copolymer of the component (B) of the present invention is within a range not impairing the effects of the present invention, the fluorine-containing monomer (b1) represented by the general formula (1) and the above It may be a copolymer obtained by copolymerizing the alkoxy group-containing monomer (b2) represented by the general formula (2) and another copolymerizable monomer (b3).
Although it does not specifically limit as another copolymerizable monomer (b3), For example, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, isocrotonic acid, maleic acid, vinyl sulfonic acid, allyl sulfonic acid, acrylic acid Polymerizable acids such as amidomethylpropanesulfonic acid and acid phosphoaxalkyl alkyl acrylate, polymerizable esters such as alkyl acrylate and alkyl methacrylate, polymerizable vinyl derivatives such as N-vinylformamide and N-vinylpyrrolidone, silicone macromers, Examples thereof include polymerizable macromonomers such as polyacryl macromonomer, polyester macromonomer, polyamide macromonomer, and polyoxyalkylene macromonomer, polymerizable sugar, and styrene.

Further, the other copolymerizable monomer (b3) may further contain a crosslinkable monomer.
The crosslinkable monomer may be a compound having at least two reactive groups and / or carbon-carbon double bonds and not containing fluorine. The crosslinkable monomer can be a compound having at least two carbon-carbon double bonds, or a compound having at least one carbon-carbon double bond and at least one reactive group. Examples of reactive groups are hydroxyl groups, epoxy groups, chloromethyl groups, blocked isocyanates, carboxyl groups and the like. In the present invention, a monomer having an amino group is not used.

  The crosslinkable monomer is preferably a non-fluorine crosslinkable monomer, and more preferably di (meth) acrylate.

The crosslinkable monomer is represented by the following general formula (3):
^{_{CH 2 = C (R 4)}} -COO- (R 5 O) s -CO-C (R 4) = CH 2 ·· (3)
[Wherein, each R ⁴ represents a hydrogen atom or a methyl group; R ⁵ represents an alkylene group having 2 to 10 carbon atoms in which part or all of the hydrogen atoms may be substituted with a hydroxyl group; It is an integer of ~ 50. ]
It is particularly preferable that the compound represented by the formula (alkylene glycol di (meth) acrylate).
The number of carbon atoms of ^{R 5} may, 2-10, for example 2-6, preferably in particular 2 to 4, ^{R 5} is preferably an ethylene group.

  By controlling the molecular weight and molar ratio of each monomer constituting the component (B) of the present invention, solubility and viscosity can be adjusted. The weight average molecular weight of the fluorine-containing copolymer of the component (B) can be about 1000 to 1000000, preferably about 5000 to 500000. If it is less than 1000, the film-forming ability is weak and not suitable for the surface treatment having the effects of the present invention, and if it is more than 1000000, the solubility of the polymer may deteriorate and the dispersibility of the surface-treated powder may deteriorate. In addition, this weight average molecular weight is the value calculated | required in polystyrene conversion by the gel permeation chromatography.

In the fluorine-containing copolymer of the component (B) of the present invention, the amount of the alkoxy group-containing monomer (b2) with respect to 100 parts by mass of the fluorine-containing monomer (b1) is 10 to 400 parts by mass, preferably 25 to 150 parts. It is mass parts, More preferably, it is 43-100 mass parts.
If the amount of (b2) is small, hydrophilicity may not be obtained, and if it is large, oil repellency may be reduced.
Moreover, when using another copolymerizable monomer (b3), the ratio is less than 30 mass% with respect to a copolymer.
In particular, when a crosslinkable monomer is contained, the amount of the crosslinkable monomer is 30 parts by mass or less, for example, 0.1 to 20 parts by mass, particularly 100 parts by mass of the fluorine-containing monomer (b1). 0.5-10 mass parts is preferable. If it is larger than 30 parts by mass, a hard film may be formed and the feeling in use may be deteriorated.

The polymerization method of the fluorine-containing copolymer used for the component (B) is not particularly limited, and various methods such as bulk polymerization, solution polymerization, emulsion polymerization, and radiation polymerization can be selected. For example, solution polymerization using an organic solvent or emulsion polymerization using water or an organic solvent and water in combination is generally selected. More generally, it is prepared into a treatment liquid by diluting with water after polymerization or emulsifying in water by adding an emulsifier.
Specifically, for example, it can be produced by a method disclosed as a production example of a copolymer in JP 2000-290640 A or WO 2009/142047 pamphlet, but is not limited thereto.

  0.1 to 10% is preferable and, as for the compounding quantity of the fluorine-containing copolymer of the component (B) used for this invention, 1 to 5% is more preferable. If it is this range, while being excellent in the solubility and dispersibility in water and ethanol, since it has high adhesiveness to the skin, good makeup lastingness and excellent dispersibility, a uniform cosmetic film can be obtained.

  The water of component (C) used in the present invention is a base and an essential component for forming gel with the gellan gum of component (A).

  The glitter powder of component (D) used in the present invention is not particularly limited as long as it is a glitter powder commonly used in cosmetics. For example, mica, sericite, synthetic mica, synthetic sericite, Body powders such as aluminum silicate, magnesium silicate, magnesium aluminum silicate, cleaved talc, plate-like anhydrous silicic acid, plate-like aluminum oxide, plate-like kaolin, plate-like boron nitride, plate-like titanium oxide, plate-like cellulose, Mica titanium, bismuth oxychloride, organic pigment-treated mica titanium, titanium dioxide coated mica, titanium dioxide coated synthetic phlogopite, titanium dioxide coated bismuth oxychloride, iron oxide mica titanium, bituminized mica titanium, carmine treated mica titanium, fish scale foil, Titanium dioxide coated glass powder, polyethylene terephthalate / aluminum / epoxy laminated powder, polyethylene terf Rate polyolefin laminated film powder, bright powders of the resin laminate powder such as powder of polyethylene terephthalate polymethyl methacrylate laminated film and the like, may be used in combination of two or more thereof. Among these, the glitter powder of mica and synthetic mica has good gloss, and the average particle diameter is preferably 30 μm or more. These components (D) are 1 compound such as fluorine compound, silicone compound, metal soap, lecithin, hydrogenated lecithin, collagen, hydrocarbon, higher fatty acid, higher alcohol, ester, wax, wax, surfactant, etc. You may surface-treat using seed | species or 2 or more types.

As a compounding quantity of a component (D), 0.1 to 60% is preferable and 5 to 40% is more preferable. If it is this range, sufficient makeup | decoration effect will be acquired and the makeup | decoration film | membrane with a watery and high glossiness will be obtained.

  The component (D) in the present invention preferably contains a water- and oil-repellent treated product from the viewpoint of cosmetic durability, and may be from the viewpoint of the stability of the cosmetic. Examples of the water / oil repellent treatment include perfluoroalkyl phosphate diethanolamine salt and perfluorooctyltriethoxysilane. When the water- and oil-repellent-treated material is included, the blending amount thereof is preferably 15% or more in the component (D), more preferably 30% or more.

In the present invention, when a finely pulverized polyethylene terephthalate powder of component (E) is further blended, the adhesion to the skin is improved and the unevenness of the skin is corrected to effectively exhibit the pearly luster of the glittering powder. be able to. Component (E) is a finely pulverized polyethylene terephthalate powder characterized by having an irregular shape, and is obtained by pulverizing polyethylene terephthalate in the form of powder, pellets, flakes, and the like. In particular, a finely pulverized polyethylene terephthalate powder prepared by pulverizing polyethylene terephthalate composed mainly of crystalline material, in which an amorphous part of polyethylene terephthalate is dissolved and removed, is preferably used. Since this polyethylene terephthalate finely pulverized powder is made into a fine powder by pulverization, the shape of the particles is not constant, that is, indefinite. In this invention, 1-30 micrometers is preferable and, as for the average particle diameter of a component (E), 2-15 micrometers is more preferable.

  Although it does not specifically limit, a component (E) can be manufactured by a method as described in Unexamined-Japanese-Patent No. 2008-063305. For example, pellet-shaped polyethylene terephthalate is brought into contact with ethylene glycol in the presence or absence of a depolymerization catalyst such as sodium hydroxide, and the amorphous part is eluted to form porous polyethylene terephthalate. The porous polyethylene terephthalate is washed and dried, and then finely pulverized to a mean particle size of 1 to 30 μm by a pulverizer such as a rod mill, ball mill, hammer mill, disk type mill, jet mill or the like. As this finely pulverized polyethylene terephthalate powder, those described in Patent Document 5 can be used. As a commercially available product of such finely pulverized polyethylene terephthalate powder, there is Snowleaf P (particle diameter 7.0 ± 5 μm) (manufactured by Oken).

  1-30% of the compounding quantity of the component (E) in this invention is preferable, and 2-15% is more preferable. Within this range, the unevenness of the skin is corrected and the decorative film becomes uniform, so that the brightness of the pearl increases.

  In addition to the above components (A) to (E), the aqueous makeup cosmetics of the present invention are components, oily components, powders and powders that are usually used in cosmetics as long as they do not interfere with the effects of the present invention. The effects of the present invention include surfactants, film forming agents, aqueous components, UV absorbers, moisturizers, anti-fading agents, antioxidants, antifoaming agents, cosmetic ingredients, preservatives, and fragrances for body dispersion and feel adjustment. Can be suitably blended within a range not impairing the above.

Oily components include hydrocarbons, oils and fats, waxes, hardened oils, ester oils, regardless of the origin, such as animal oils, vegetable oils, synthetic oils, and solid oils, semisolid oils, liquid oils, etc. , Fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents, oil-soluble resins, volatile oils and the like.
Specifically, hydrocarbons such as liquid paraffin, squalane, petrolatum, paraffin wax, ceresin wax, microcrystalline wax, ethylene propylene copolymer, montan wax, fisher trops wax, molasses, olive oil, castor oil, mink oil, macadamia Oils such as peanut oil, beeswax, carnauba wax, candelilla wax, waxes such as gay wax, jojoba oil, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, diisostearate Polyglyceryl acid, diglyceryl triisostearate, glyceryl tribehenate, diisostearyl malate, neopentyl glycol dioctanoate, cholesterol fat Acid esters, esters such as N-lauroyl-L-glutamate di (cholesteryl, behenyl, octyldodecyl), stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, isostearyl alcohol, behenyl alcohol and other higher alcohols, methylphenyl poly Silicones such as siloxane and fluorine-modified organopolysiloxane, fluorinated oils such as perfluorodecane, perfluorooctane and perfluoropolyether, lanolin, lanolin acetate, lanolin fatty acid isopropyl, lanolin derivatives such as lanolin alcohol, dextrin octoate , Dextrin laurate, dextrin palmitate, dextrin myristate, dextrin stearate, dextrin behenate, coconut oil Fatty acid dextrin, (palmitic acid / octanoic acid) dextrin, sucrose fatty acid ester, starch fatty acid ester, 12-hydroxystearic acid, calcium stearate and other oily gelling agents, hydrogenated rosin acid pentaerythrityl, specific alkyl acrylate Volatilization of oil-soluble resins such as methylpolysiloxane esters, hydrocarbon oils such as light liquid isoparaffin and isododecane, silicones such as decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, methyltrimethicone, and low polymerization degree dimethylpolysiloxane Oily agents and the like.

  The powders other than the component (D) are particularly in the form of spindles, needles, fibers, spheres, etc., fumes, fine particles, particle sizes such as pigment grades, porous, non-porous particle structures, etc. Without being limited, inorganic powders, composite powders and the like can be mentioned. Specifically, inorganic powders such as aluminum oxide, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, talc, kaolin, silica, silicon carbide, boron nitride, magnesium stearate, zinc stearate, N-acyl lysine, Organic powders such as nylon, white inorganic pigments such as titanium oxide, zinc oxide, cerium oxide, and barium sulfate, colored inorganic pigments such as iron oxide, carbon black, chromium oxide, chromium hydroxide, bitumen, ultramarine, and red rose, red 201, red 202, red 205, red 226, red 228, orange 203, orange 204, blue 404, yellow 401 organic pigment powder, red 3, red 104, red 106, orange 205, yellow 4, yellow 5, green 3, blue 1, etc. zirconium, barium or aluminum Organic pigment powders or even aluminum powders such Miniumureki, gold powder, include metal powders such as silver, it can be used more than those one or. In addition, these powders may be used singly or in combination of two or more, and by a known method using a fluorine compound, a silicone-based oil agent, a metal soap, a surfactant, fats and oils, etc. It may be surface-treated.

Any surfactant can be used as a surfactant to be added for the purpose of improving the dispersibility of the powder, as long as it is a surfactant generally used in cosmetics. Nonionic surfactants and anionic surfactants can be used. , Cationic surfactants, amphoteric surfactants and the like. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerin fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, sucrose fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyalkylene alkyl co-modified Examples thereof include organopolysiloxane, polyether-modified organopolysiloxane, and lecithin.
Examples of the film forming agent include alkyl acrylate polymers, alkyl methacrylate polymers, and alkyl methacrylate copolymers.
The aqueous component may be any component that is soluble in water, for example, lower alcohols such as ethyl alcohol and butyl alcohol, glycols such as propylene glycol, 1,3-butylene glycol, dipropylene glycol, and polyethylene glycol. Glycerols such as glycerin, diglycerin and polyglycerin, and plant extracts such as aloe vera, witch hazel, hamamelis, cucumber, lemon, lavender and rose. Examples of water-soluble polymers include guar gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, carrageenan and other semi-synthetic compounds such as methyl cellulose, hydroxyethyl cellulose, carboxymethyl cellulose, carboxyvinyl polymer, Synthetic compounds such as alkyl-added carboxyvinyl polymer and sodium polyacrylate can be mentioned. Other moisturizing agents such as protein, mucopolysaccharide, collagen, elastin, keratin and the like can also be contained.
Examples of ultraviolet absorbers include benzophenone-based, PABA-based, cinnamic acid-based, salicylic acid-based, 4-tert-butyl-4'-methoxydibenzoylmethane, and oxybenzone. Examples of humectants include protein, mucopolysaccharide, and collagen. , Elastin, keratin, etc., antioxidants such as α-tocopherol, ascorbic acid, etc., cosmetic ingredients such as vitamins, anti-inflammatory agents, herbal medicines, etc., antiseptics such as paraoxybenzoic acid esters, phenoxyethanol, 1 , 2-pentanediol and the like.

  The aqueous makeup cosmetic of the present invention is not particularly limited, but can be applied to eye color, face color, cheek color, eyeliner and the like, and examples of the shape include solid, cream, gel, and liquid. Among them, a solid gel shape having no fluidity is preferred from one having a viscosity of 50,000 mm 2 / s or more. Appearance can be used as transparent, translucent and opaque cosmetics. Examples of the dosage form include aqueous and oil-in-water types having water as a main component and an aqueous phase as a continuous phase.

  Hereinafter, the present invention will be described in detail with reference to examples. Note that these do not limit the present invention.

Synthesis examples of the fluorine-containing copolymer of the component (A) in the present invention are shown below.
[Synthesis Example 1]
In a 100 ml four-necked flask equipped with a reflux condenser, a nitrogen inlet tube, a thermometer, and a stirrer, a fluorine-containing monomer —CH ₂ ═C (H) COO—CH ₂ CH ₂ C ₆ F ₁₃ (hereinafter referred to as “C6FA ( a1) ”) and 18.6 g of polyethylene glycol acrylate CH ₂ ═C (H) COO— (CH ₂ CH ₂ O) _n —H (BLEMMER AE90, manufactured by NOF CORPORATION, the average value of n is 2 0.0, hereinafter referred to as “AE90 (a2)”) and 11.4 g of methyl ethyl ketone (hereinafter referred to as “MEK”) 45 g were charged, and nitrogen bubbling was performed for 30 minutes. After raising the internal temperature to 50 to 65 ° C. under a nitrogen stream, 0.4 g of perbutyl PV (hereinafter referred to as “PV”) was added and reacted at 60 to 65 ° C. for 6 hours. After the MEK was distilled off at about 70 ° C. under reduced pressure to obtain a pale yellow polymer residue, 122.4 g of purified water was added, and the internal temperature was kept at about 80 ° C. for 1 hour or longer. Thereafter, the mixture was cooled to prepare an aqueous dispersion having a solid concentration of about 20%. The weight average molecular weight (Mw) of the obtained copolymer was 18200 by GPC measurement in terms of polystyrene.

[Synthesis Example 2]
AE90 the polyethylene glycol in Synthesis Example 1 - Rumetaakurire - DOO _{CH 2 = C (CH 3)} COO- (CH 2 CH 2 O) n -H (BLEMMER PE350 days oil average value of KK n is 8.0, or less The polymerization reaction was carried out in the same manner as in Synthesis Example 1 by replacing with “PE350 (a2)” to prepare an aqueous dispersion having a solid content concentration of about 20%. The weight average molecular weight (Mw) of the obtained copolymer was 16400 by GPC measurement in terms of polystyrene.

[Synthesis Example 3]
In a 100 ml four-necked flask equipped with a reflux condenser, a nitrogen inlet tube, a thermometer and a stirrer, 18.6 g of C6FA (a1), 5.7 g of AE90 (a2), polyethylene glycol acrylate CH ₂ = 5.7 g of C (H) COO— (CH ₂ CH ₂ O) _n —H (BLEMMER AE200, manufactured by NOF Corporation, n is 4.5, hereinafter referred to as “AE200 (a2)”) and MEK And the same polymerization reaction as in Synthesis Example 1 was performed to prepare an aqueous dispersion having a solid content of about 20%. The weight average molecular weight (Mw) of the obtained copolymer was 15500 by GPC measurement in terms of polystyrene.

[Synthesis Example 4]
In a 100 ml four-necked flask equipped with a reflux condenser, a nitrogen inlet, a thermometer and a stirrer, 18.6 g of C6FA (a1), 10.5 g of PE350 (a2), polyethylene glycol diacrylate CH ₂ = C (H) COO— (CH ₂ CH ₂ O) _n —CO—CH═CH ₂ (BLEMMER ADE300 manufactured by NOF Corporation has an average value of 7.0, hereinafter referred to as “ADE300 (a3)”) 0.9 g and 45.0 g of isopropanol (hereinafter referred to as “IPA”) were charged, and the same polymerization reaction as in Synthesis Example 1 was performed to prepare an aqueous dispersion having a solid content concentration of about 20%. The weight average molecular weight (Mw) of the obtained copolymer was 16400 by GPC measurement in terms of polystyrene.

[Synthesis Example 5]
In a 100 ml four-necked flask equipped with a reflux condenser, a nitrogen inlet tube, a thermometer and a stirrer, 18.6 g of C6FA (a1), hydroxyethyl acrylate (manufactured by Tokyo Chemical Industry Co., Ltd., hereinafter “HEA (a3 ) "), 2.5 g of AE200 (a2), 0.9 g of ADE300 (a3), and 45 g of IPA, and bubbled with nitrogen for 30 minutes. After raising the internal temperature to 50-65 ° C. under a nitrogen stream, 0.4 g of PV was added and reacted at 60-65 ° C. for 6 hours. From the obtained solution, IPA was removed at 70 ° C. under reduced pressure to obtain a pale yellow copolymer. The weight average molecular weight (Mw) of the obtained copolymer was 16280 by GPC measurement in terms of polystyrene. This copolymer was washed with purified water, and then IPA was added to prepare a solution having a solid content concentration of 30%.

[Synthesis Example 6]
In a 100 ml four-necked flask equipped with a reflux condenser, a nitrogen inlet tube, a thermometer and a stirrer, 18.6 g of C6FA (a1), 2.5 g of HEA (a3), 8.0 g of AE90 (a2), 0.9 g of ADE300 (a3) and 45 g of IPA were charged, and the same polymerization reaction as in Synthesis Example 5 was performed to obtain a pale yellow copolymer. The weight average molecular weight (Mw) of the obtained copolymer was 17900 by GPC measurement in terms of polystyrene. This copolymer was washed with purified water in the same manner as in Synthesis Example 5, and then IPA was added to prepare a solution having a solid content concentration of 30%.

[Synthesis Example 7]
In a 100 ml four-necked flask equipped with a reflux condenser, a nitrogen inlet tube, a thermometer and a stirrer, 18.6 g of C6FA (a1), 3.5 g of HEA, 7.2 g of AE200 (a2), ADE300 (a3 ) And 45 g of IPA were charged, and the same polymerization reaction as in Synthesis Example 5 was performed to obtain a pale yellow copolymer. The weight average molecular weight (Mw) of the obtained copolymer was 17200 by GPC measurement in terms of polystyrene. This copolymer was washed with purified water in the same manner as in Synthesis Example 5, and then IPA was added to prepare an IPA solution having a solid concentration of 40%.

Examples 1 to 15 and Comparative Examples 1 to 7: Eye color (aqueous gel)
Prepare eye colors of the formulation shown in Table 1, a. Having makeup, b. Adhesion to skin, c. Gloss of pearl, d. The uniformity of the decorative film was evaluated by the following method. The results are shown in Table 1.

* 1: Kelcogel LT100 (Dainippon Sumitomo Pharma Co., Ltd.)
* 2: GENU pectin type LM-104AS-J (CP Kelco)
* 3: Cosmall 168ARNV (Nisshin Oillio Group)
* 4: Pearl Dream 46 (manufactured by NOF Corporation)
* 5: YODOSOL GH800F (manufactured by Akzo Nobel) 45% solid content
* 6: TORNARE (produced by Hayashibara Biochemical Research Institute)
* 7: CMC Daicel 1170 (manufactured by Daicel Chemical Industries)
* 8: CARBOPOL 980 (manufactured by LUBRIZOL ADVANCED MATERIALS A)
* 9: Snow Reef P Average particle size 7 ± 5μm (Oken)
* 10: PDM-40L average particle size 35-45 μm (Topy)
* 11: FLAMENCO ULTRA SPARKLE 4500 with an average particle size of 50μm (manufactured by BASF) and 3% perfluorooctyltriethoxysilane treatment * 12: Metashine MC1080RC-S with an average particle size of 80μm (manufactured by Nippon Sheet Glass) Treated with 2% fluorooctyltriethoxysilane * 13: Aluminum flake silver 0.15mm Average particle size 150μm (Kakuhachi Fish Scale)

(Production method)
A. Ingredients (1) and (2) are uniformly heated and swollen with a part of ingredient (12).
B. Add (3) to (11) and the remainder of (12) and (13) to (21) to A and mix uniformly.
C. B was filled in a container to obtain an eye color (aqueous gel).

(Evaluation method)
The following evaluation items were evaluated by the following methods.
(Evaluation item)
a. Makeup b. Adhesion to skin c. Glossy pearl d. About the item of uniformity of decorative film ad, the usage test by 20 expert panels was done about each sample. Each panel person uses each eye color of Examples 1 to 15 and Comparative Examples 1 to 7 with their fingers, evaluates it according to the following absolute evaluation criteria in 7 levels, and gives a score from the total score of all panel members The average value was calculated and judged according to the following criteria. Whether an appropriate amount could be taken when taking a sample filled in the container with a finger a. Regarding makeup holding, each sample was applied, and after having a normal life on the panel, it was evaluated whether the makeup film was broken by tears or sweat after 6 hours. Whether there is a feeling of adhesion to the skin, a high gloss of pearl, or a uniform application of the cosmetic film, b. Adhesion to skin, c. Pearl luster, d. The uniformity of the decorative film was evaluated.

Absolute evaluation criteria (score): (Evaluation)
6: Very good 5: Good 4: Somewhat good 3: Normal 2: Somewhat bad 1: Bad 0: Very bad

Judgment criteria (judgment): (average score)
A: 5 points or more: Very good A: 4 points or more to less than 5 points: Good B: 3 points or more to less than 4 points: Slightly good C: 2 points or more to less than 3 points: Slightly poor D: 1 point or more Less than 2 points: Bad E: Less than 1 point: Very bad

As is clear from the results in Table 1, the aqueous eye colors of Examples 1 to 15 of the present invention have makeup lastingness, adhesion to the skin, glossiness of pearl, and uniformity of the makeup film as compared with Comparative Examples 1 to 7. It was excellent in all. On the other hand, Comparative Example 1 in which sodium carboxymethylcellulose, which is an aqueous gelling agent, is used instead of component (A) loses its watery feel and the pearly luster is satisfactory. Although it was not obtained, Comparative Example 2 in which carboxyvinyl polymer was blended had a watery touch, but had no feeling of adhesion to the skin and the makeup film was not uniform, and the makeup lasting was poor. Comparative Example 3 containing hexa (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl instead of component (B) and Comparative Example 4 containing hydrogenated polyisobutene are cosmetics because of poor dispersibility. Since the film was not uniform and was weak against sebum, the makeup lasting was poor. The comparative example 5 which mix | blended glycerin was a thing with poor makeup lasting because it was weak with sweat and sebum. In Comparative Example 6 in which the alkyl acrylate copolymer emulsion was blended, the film had no flexibility to form a film, and the makeup lasted poorly because pearls fell off. In Comparative Example 7 in which the glycosyl trehalose / hydrogenated starch degradation product was blended, the makeup lasting was poor because it was weak against sweat and sebum.

Example 11 Blusher (aqueous solid gel)
(Ingredient) (%)
1. Deacylated gellan gum 0.6
2. Water remaining amount 3. Triethanolamine 0.1
4). EDTA-2Na 0.05
5. Dibutylene glycol 15
6). Lecithin 0.2
7). Polyoxyethylene sorbitan monooleate 0.15
8). Talc 2
9. Perfluorooctyltriethoxysilane 5% treated yellow iron oxide 0.2
10. Perfluorooctyltriethoxysilane 5% black iron oxide 0.02
11. Perfluorooctyltriethoxysilane 5% treated bengara 0.1
12 Perfluoroalkyl phosphate diethanolamine 5% treatment
Titanium oxide 0.05
13. Synthetic phlogopite * 10 14
14 Perfluoroalkyl phosphate diethanolamine 3% treatment
Titanium oxide coated mica * 11 10
15. Silicone 2% treated titanium oxide coated synthetic phlogopite * 14 1
16. Fluorine-containing copolymer of Synthesis Example 7 2
17. Polyethylene terephthalate fine powder * 9 5
* 14: HELIOS R100S (S) (average particle size 105 μm, Topy Industries, Ltd.) treated with 2% methylhydrogenpolysiloxane (manufacturing method)
A. Ingredient (1) is uniformly swollen with part of ingredient (2).
B. Ingredients (3) to (12) are uniformly dispersed.
C. Add B and components (13) to (17) to A and mix uniformly.
D. C was filled into a container to obtain blusher (aqueous gel).
The blusher of Example 5 was excellent in all aspects of makeup holding, adhesion to the skin, glossiness of pearl, and uniformity of the makeup film.

Example 6 Foundation (oil-in-water solid gel)
(Ingredient) (%)
1. Native gellan gum * 1 0.5
2. Water remaining amount 3. L-Arginine 0.3
4). EDTA-2Na 0.05
5. Calcium chloride 0.03
6). Phenoxyethanol 0.3
7.1,3-Butylene glycol 15
8). Polyoxyethylene polyoxypropylene glycol * 15 0.3
9. Sodium polyoxyethylene alkyl ether phosphate 0.3
10. Dimethylpolysiloxane 2% treated talc 3.5
11. Dimethylpolysiloxane 2% treated yellow iron oxide 1.5
12 Dimethylpolysiloxane 2% black iron oxide 0.1
13. Dimethylpolysiloxane 2% treated bengara 0.1
14 Dimethylpolysiloxane 2% treated plate-like titanium oxide 7
15. Dimethylpolysiloxane 2% treated plate barium sulfate 3
16. Polyethylene terephthalate fine powder * 9 10
17. Glycerol monostearate 1.5
18. Cetanol 1.5
19. Liquid paraffin 1
20. Squalane 2
21. Glyceryl trioctanoate 3
22. Dipentaerythritol tetra 12-hydroxystearic acid sesquistearic acid hemirosin ester 0.5
23. Dimethylpolysiloxane (20CS) 0.5
24. Fluorine-containing copolymer of Synthesis Example 4 3
25. Alkyl acrylate / styrene copolymer emulsion 3
* 15: Unilube 70DP-950B (Nippon Yushi Co., Ltd.)
(Production method)
A. Ingredient (1) is uniformly swollen with ingredient (2).
B. Ingredients (3) to (16) are uniformly dispersed.
C. Components (17) to (23) are dissolved by heating at 70 ° C.
D. A and B are mixed, and C is added thereto to emulsify.
E. Add components (24) and (25) to D and mix.
F. E was heated and dissolved, filled into a container, and then cooled to room temperature to obtain a gel-like foundation.
The gel-like foundation of Example 6 was excellent in all aspects of makeup holding, adhesion to the skin, glossiness of pearl, and uniformity of the cosmetic film.

Example 7 Base (oil-in-water cream))
(Ingredient) (%)
1. Pectin * 2 0.3
2. Locust bean gum 0.1
3. Xanthan gum 0.1
4. 1,2-pentylene glycol 5
5. 5. Water remaining amount Fluorine-containing copolymer of Synthesis Example 7 3
7. 2-Amino-2-methyl-1-propanol 0.3
8). EDTA-2Na 0.05
9. Calcium chloride 0.03
10. Methyl paraoxybenzoate 0.1
11. Sodium polyoxyethylene alkyl ether phosphate 0.3
12 Dimethylpolysiloxane 2% treated talc 3.5
13. Dimethylpolysiloxane 2% treated yellow iron oxide 1.5
14 Dimethylpolysiloxane 2% black iron oxide 0.1
15. Dimethylpolysiloxane 2% treated bengara 0.1
16. Dimethylpolysiloxane 2% treated plate-like titanium oxide 7
17. Polyethylene terephthalate fine powder * 9 7
18. Polyglyceryl monostearate 1.5
19. Cetanol 1.5
20. Polyoxyethylene (60) hydrogenated castor oil 1
21. Squalane 3
22. Glyceryl trioctanoate 5
23. Glyceryl monostearate 0.5
24. Dimethylpolysiloxane (100CS) 0.5
25. Vaseline 0.5
(Production method)
A. Components (1) to (3) and (7) to (11) are uniformly swollen with a part of components (4) and (5).
B. Components (18) to (25) are dissolved by heating at 70 ° C.
C. The remainder of component (5), (6), and components (12) to (17) are uniformly dispersed.
D. B is added to C and emulsified.
E. Add A and component (6) to D and mix.
F. After E was melt-filled in the container, it was cooled to room temperature to obtain a gel-like substrate.
The gel-like substrate of Example 7 was excellent in all aspects of makeup holding, adhesion to the skin, pearly luster, and uniformity of the decorative film.

Example 8 Eyeliner (aqueous liquid)
(Ingredient) (%)
1. Native gellan gum * 1 0.1
2. Water remaining amount 3. EDTA-2Na 0.05
4). Triethanolamine 0.1
5.1,3-Butylene glycol 15
6). Lecithin 0.2
7). Polyoxyethylene sorbitan monooleate 0.15
8). Sericite 2
9. Plate cellulose 2
10. Perfluorooctyltriethoxysilane 3% treated black iron oxide 5
11. Synthetic phlogopite * 8 5
12 Black iron oxide coated mica * 16 20
13. Fluorine-containing copolymer of Synthesis Example 3 10
* 16: COLORONA MICA BLACK (Merck)
(Production method)
A. Ingredient (1) is uniformly swollen with ingredient (2).
B. Ingredients (3) to (10) are uniformly dispersed.
C. Add B and components (11) to (13) to A and mix uniformly.
D. C was filled into a container to obtain an eyeliner (aqueous gel).
The eyeliner of Example 8 was excellent in all aspects of makeup holding, adhesion to the skin, glossiness of pearl, and uniformity of the decorative film.

Example 9 Mascara (aqueous paste)
(Ingredient) (%)
1. Native gellan gum * 1 0.2
2. Water remaining amount 3. Ethanol 15
4). L-Arginine 0.1
5. EDTA-2Na 0.05
6). Lecithin 0.2
7). Polyoxyethylene sorbitan monooleate 0.15
8). Cleaved talc 2
9. Perfluorooctyltriethoxysilane 3% black iron oxide 0.5
10 perfluoroalkyl phosphate diethanolamine 3% treatment
Titanium oxide coated mica * 11 2
11. Perfluoroalkyl phosphate diethanolamine 3% treatment
Titanium oxide coated synthetic phlogopite * 14 3
12 Perfluoroalkyl phosphate diethanolamine salt 2% treatment
Titanium oxide coated glass powder * 12 5
13. (PET / Al / epoxy resin) laminate * 13 3
14 Polyethylene terephthalate fine powder * 9 10
15. Fluorine-containing copolymer of Synthesis Example 5 5
(Production method)
A. Ingredient (1) is uniformly swollen with part of ingredient (2).
B. The remainder of the component (2) and the components (6) to (9) are uniformly dispersed.
C. Add B and components (3) to (5) and (10) to (15) to A and mix uniformly.
D. C was filled into a container to obtain a mascara (aqueous paste).
The mascara of Example 9 was excellent in all aspects of makeup holding, adhesion to the skin, pearly luster, and uniformity of the cosmetic film.

Example 10 Eye color base (aqueous solid gel)
(Ingredient) (%)
1. Native gellan gum * 1 0.5
2. Water remaining amount 3. Triethanolamine 1
4). Phenylbenzimizosulfonic acid 2
5. Dipropylene glycol 15
6). Ethanol 5
7). Fluorine-containing copolymer of Synthesis Example 5 10
8). Perfluorooctyltriethoxysilane 3% treatment
Black iron oxide 0.5
9. Perfluorooctyltriethoxysilane 3% treatment
Titanium oxide coated mica * 11 2
10. Methyl hydrogen polysiloxane 3% treatment
Titanium oxide coated synthetic phlogopite * 14 3
11. Polyethylene terephthalate fine powder * 9 10
12 Hyaluronic acid 5
13. Novara extract 0.1
14 Licorice extract 0.1
15. Yokuinin extract 0.1
(Production method)
A. Ingredient (1) is uniformly swollen with part of ingredient (2).
B. The remainder of component (2) and components (3) and (4) are mixed and dissolved uniformly.
C. Add B and components (5) to (15) to A and mix uniformly.
D. C was filled into a container to obtain an eye color base (aqueous solid gel).
The eye color base of Example 10 was excellent in all aspects of makeup holding, adhesion to the skin, gloss of pearl, and uniformity of the decorative film.

Claims (6)

The following components (A) to (D);
(A) gellan gum and / or pectin;
(B) A monomer that essentially contains a fluorine-containing monomer (b1) represented by the following general formula (1) and an alkoxy group-containing monomer (b2) represented by the following general formula (2) A fluorine-containing copolymer obtained by copolymerizing
_{CH 2 = C (-X) -C} (= O) -Y - [- (CH 2) m -Z-] p - (CH 2) n -Rf · (1)
[Wherein, X represents a hydrogen atom, a linear or branched alkyl group having 1 to 21 carbon atoms, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or a CFX ¹ X ² group (where X ¹ and X ² is a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, respectively), a cyano group, a linear or branched fluoroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted benzyl group. A substituted or unsubstituted phenyl group; Y is —O— or —NH—; Z is a direct bond, —S— or —SO ₂ —; Rf has 1 to 6 carbon atoms; A fluoroalkyl group; m is 1 to 10, n is 0 to 10, and p is 0 or 1. ]
^{_{CH 2 = C (R 1)}} -C (= O) -O- (R 2 O) q -R 3 ··· (2)
[In the formula, R ¹ is a hydrogen atom or a methyl group; R ² is an alkylene group having some or all carbon atoms which may be substituted with a hydroxyl group of 2 to 4 hydrogen atoms; R ³ is hydrogen An atom or an unsaturated or saturated hydrocarbon group having 1 to 22 carbon atoms; q is an integer of 1 to 50; ]
(C) water;
(D) glitter powder;
An aqueous makeup cosmetic characterized by comprising Furthermore, component (E) polyethylene terephthalate fine ground powder is mix | blended, The aqueous makeup cosmetics of Claim 1 characterized by the above-mentioned.   The aqueous makeup cosmetic according to claim 1 or 2, wherein 0.1 to 10% by mass of the component (B) is blended.   The aqueous makeup cosmetic according to any one of claims 1 to 3, wherein 0.1 to 5% by mass of the component (A) is blended.   The aqueous makeup cosmetic according to any one of claims 1 to 4, wherein 0.1 to 60% by mass of the component (D) is blended. The aqueous makeup cosmetic according to any one of claims 1 to 5, wherein 0.1 to 15% by mass of the component (E) is blended.