JP2012095645A - Gel-like nutritional food - Google Patents

Gel-like nutritional food Download PDF

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JP2012095645A
JP2012095645A JP2011219210A JP2011219210A JP2012095645A JP 2012095645 A JP2012095645 A JP 2012095645A JP 2011219210 A JP2011219210 A JP 2011219210A JP 2011219210 A JP2011219210 A JP 2011219210A JP 2012095645 A JP2012095645 A JP 2012095645A
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gel
carrageenan
gelatin
nutritional food
content
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JP5884382B2 (en
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Naoto Otsuka
直人 大塚
Tomoyasu Moriyama
友庸 守山
Anri Yamazaki
安里 山崎
Tatsuichi Shoji
龍市 庄司
Manabu Nagano
学 長野
Hanayo Sugiura
華代 杉浦
Hiroshi Nishiyama
博 西山
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MORIYAMA NYUGYO KK
Morinaga Milk Industry Co Ltd
QP Corp
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Morinaga Milk Industry Co Ltd
QP Corp
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Abstract

PROBLEM TO BE SOLVED: To provide a high-protein and high-lipid gel-like nutritional food which is soft, has good mouth meltability, and hardly causes syneresis even when preserved for six months or more at normal temperature by mainly including gelatin.SOLUTION: The gel-like nutritional food includes: oils and fats; the gelatin; carrageenan; a casein salt; and an emulsifier. The mass ratio (gelatin/carrageenan) of gelatin to carrageenan is 10-25, and the mass ratio (casein salt/carrageenan) of casein salt to carrageenan is >25 and ≤100. The content of the carrageenan is ≥0.04 mass%.

Description

本発明は、嚥下機能の低下した者でも蛋白質、脂質等を効率よく摂取できるようにするゲル状栄養食品に関する。   The present invention relates to a gel-like nutritional food that enables a person with a reduced swallowing function to efficiently take proteins, lipids, and the like.

高齢、疾病などにより嚥下機能が低下している者にとって食べやすく、脂質や蛋白質の含有量が高く、エネルギーを効率よく摂取できるようにする食品として、ゼリーやプリン等のゲル状食品に油脂類を配合したゲル状栄養食品が利用されている。   Fats and oils are added to gelled foods such as jelly and pudding as foods that are easy to eat for those who are swallowed due to age, illness, etc., are high in lipid and protein content, and can consume energy efficiently. Mixed gel nutritional foods are used.

このようなゲル状栄養食品を構成するゲルとしては、ゼラチンを主体としたものと寒天を主体としたものとがあるが(特許文献1)、ゼラチンを主体としたものは、ゼラチン特有の柔らかさと変形のしやすさを有し、口腔内で咽せを引き起こす食品の砕片が生じにくいこと、ゲルの表面が体温で溶け始めることにより溶けた液状物が嚥下時の潤滑油として働くことから、嚥下困難者には特に適したものとなる。   Gels constituting such a gel-like nutritional food include gelatin-based ones and agar-based ones (Patent Document 1). Gelatin-based ones have gelatin-specific softness. Swallowing because it is easy to deform, it is difficult to produce food fragments that cause soreness in the oral cavity, and the melted liquid material works as a lubricating oil during swallowing because the gel surface starts to melt at body temperature It is especially suitable for people with difficulties.

特開平10−155433号公報Japanese Patent Laid-Open No. 10-155433

しかしながら、ゼラチンを主体とした従来のゲル状栄養食品を常温で保存すると、ゲルのネットワークが経時的に加水分解で切れて離水が起こり、その水が嚥下困難者に咽せや誤嚥を引き起こす。そのため、ゼラチンを主体とした従来のゲル状栄養食品の常温保存可能期間は4ヶ月程度が限界であった。   However, when a conventional gel-like nutritional food mainly composed of gelatin is stored at room temperature, the gel network cuts by hydrolysis over time, causing water separation, and the water causes throat and aspiration to those who have difficulty swallowing. For this reason, the conventional shelf life of gelatinous nutritional foods mainly composed of gelatin has a limit of about 4 months.

また、ゼラチンを主体としたゲル状栄養食品を1kcal/g以上の高カロリー食品とするために油脂、乳化油脂といった油脂類の含有量を、水不溶性の脂質として10wt%以上に高めると、ゲルのネットワークの形成が脂質で阻害されることによって離水しやすくなるという問題があり、蛋白質の含有量5wt%程度に高めると加熱殺菌や保存時にゲルが変性して凝集し、これによっても離水しやすくなるという問題があった。   Moreover, when the content of fats and oils such as fats and emulsified fats and oils is increased to 10 wt% or more as water-insoluble lipids in order to make gelatinous nutritional foods mainly composed of gelatin into high-calorie foods of 1 kcal / g or more, There is a problem that the formation of the network is easily inhibited by lipid formation, so that it is easy to release water, and if the protein content is increased to about 5 wt%, the gel is denatured and aggregated during heat sterilization and storage, which also facilitates water separation. There was a problem.

これに対し、本発明は、ゼラチンを主体とすることにより、柔らかく、口溶けが良好で、かつ常温で6ヶ月以上保存しても離水しにくい、高蛋白、高脂質のゲル状栄養食品の提供を目的とする。   On the other hand, the present invention provides a gel-like nutritional food of high protein and high lipid, which is mainly gelatin, is soft, melts well in the mouth, and does not easily release even after being stored at room temperature for 6 months or more. Objective.

本発明者は、ゼラチンを主体としたゲルにカラギナンを特定の比率で添加すると、脂質や蛋白質の含有量を高めても、ゼラチンのゲルを常温保存したときに経時的に生じる加水分解を抑えて離水を顕著に低減できること、カラギナンの添加によりゼラチンのゲルは硬くなり、体温で溶けにくくなるが、これに対してカゼイン塩を添加するとゲルが柔らかくなり、口腔内で速やかに変形するため、ゲルに効率よく体温が伝わり、溶けやすさが保持されることを見出した。   When the present inventors added carrageenan to a gelatin-based gel at a specific ratio, even if the content of lipid or protein is increased, hydrolysis that occurs over time when the gelatin gel is stored at room temperature is suppressed. The ability to significantly reduce water separation and the addition of carrageenan harden the gelatin gel and make it difficult to dissolve at body temperature.On the other hand, the addition of casein salt softens the gel and quickly deforms in the oral cavity. It was found that body temperature was transmitted efficiently and the solubility was maintained.

即ち、本発明は、油脂類、ゼラチン、カラギナン、カゼイン塩及び乳化剤を含有し、
ゼラチンとカラギナンの質量比(ゼラチン/カラギナン)が10〜25、
カゼイン塩とカラギナンの質量比(カゼイン塩/カラギナン)が25超100以下、
カラギナンの含有量0.04質量%以上
であるゲル状栄養食品を提供する。
That is, the present invention contains fats and oils, gelatin, carrageenan, casein salt and emulsifier,
The mass ratio of gelatin and carrageenan (gelatin / carrageenan) is 10-25,
The mass ratio of casein salt to carrageenan (casein salt / carrageenan) is more than 25 and less than 100,
A gel-like nutritional food having a carrageenan content of 0.04% by mass or more is provided.

本発明のゲル状栄養食品は、ゼラチンを主体としたゲルからなるので口溶けが良好であり、さらに、カラギナンを特定の比率で含有していることにより、ゲルのネットワークの経時的な安定性を高めることができる。そのため、脂質の含有量を高めても離水しにくくなり、例えば、1.6kcal/g以上の高カロリー食品となるように脂質含有量を高めても、常温で6ヶ月以上、実質的に離水を生じさせることなく保存することが可能となる。また、脂質だけでなく、蛋白質の添加に対してもゲルのネットワークの安定性が向上する。したがって、例えば蛋白質含有量0.05g/g以上の、脂質と蛋白質をバランスよく配合した高カロリー食品とすることができる。   Since the gel-like nutritional food of the present invention comprises a gel mainly composed of gelatin, it melts well in the mouth, and further contains carrageenan in a specific ratio, thereby improving the stability of the gel network over time. be able to. Therefore, even if the lipid content is increased, it becomes difficult to separate water. For example, even if the lipid content is increased so as to become a high calorie food of 1.6 kcal / g or more, water separation can be substantially performed for 6 months or more at room temperature. It can be stored without causing it. Moreover, the stability of the gel network is improved not only with lipids but also with the addition of proteins. Therefore, for example, a high-calorie food with a protein content of 0.05 g / g or more and a well-balanced blend of lipids and proteins can be obtained.

さらに、本発明のゲル状栄養食品は、カゼイン塩も含有することによりゲルが柔らかくなり、カラギナンを含有していてもゼラチン本来のゲルの柔らかさを有し、ゲル強度が1000〜15000N/mの範囲で安定し、保存期間中の物性変化がほとんどない。そのため、いつ食べても柔らかく、舌で潰して食べることが可能となり、さらに付着性が1000J/m以下で飲み込みやすいものとなる。 Furthermore, the gel-like nutritional food of the present invention softens the gel by containing the caseinate, and has the gel softness of gelatin even if it contains carrageenan, and the gel strength is 1000-15000 N / m 2. It is stable in the range, and there is almost no change in physical properties during the storage period. Therefore, it is soft whenever it is eaten, it can be crushed with the tongue, and it can be easily swallowed with an adhesion of 1000 J / m 2 or less.

以下、本発明を詳細に説明する。なお、本発明において、「%」は「質量%」を、「部」は「質量部」をそれぞれ意味する。また、数値範囲の「A〜B」という記載は、“A以上B以下”を意味する。   Hereinafter, the present invention will be described in detail. In the present invention, “%” means “mass%” and “part” means “part by mass”. The description “A to B” in the numerical range means “A or more and B or less”.

本発明は、油脂類、ゼラチン、カラギナン、カゼイン塩及び乳化剤を含有するゲル状栄養食品であるが、そのゲルはゼラチンを主体としたものである。これにより、ゲル状栄養食品に、ゼラチンゲル特有の柔らかさと変形のしやすさと口溶け感を付与することが可能となり、嚥下困難者がこのゲル状食品を舌で潰し、口腔内で溶けたゲル表面の液状物と共に嚥下することが容易となる。   The present invention is a gel-like nutritional food containing fats and oils, gelatin, carrageenan, casein salt and an emulsifier, and the gel is mainly composed of gelatin. As a result, the gel-like nutritional food can be given the softness, ease of deformation, and mouth-melting sensation unique to gelatin gel. It becomes easy to swallow with the liquid material.

ゼラチンとしては牛、豚、魚等いずれの由来のものを用いても良いが、その分子量は、ゲル状栄養食品にゼラチンゲル特有の柔らかさと変形のしやすさと口溶け感を付与するために30000〜100000が好ましい。なお、ゼラチンに代えて分子量500〜20000程度のコラーゲンペプチドを使用することは、ゲルを形成しにくくなるので好ましくない。   Gelatin derived from any of cows, pigs, fish and the like may be used, but the molecular weight is 30000 to give gel-like nutritional food the softness, ease of deformation and mouth-melting feeling peculiar to gelatin gel. 100000 is preferred. In addition, it is not preferable to use a collagen peptide having a molecular weight of about 500 to 20000 instead of gelatin because it is difficult to form a gel.

また、ゼラチンのゲル状栄養食品中の含有量は、0.5〜5%が好ましく、0.5〜1.3%がより好ましい。   The content of gelatin in the gel nutritional food is preferably 0.5 to 5%, more preferably 0.5 to 1.3%.

本発明のゲル状栄養食品においてカラギナンは、ゼラチンを主体とするゲルの経時的安定性を向上させ、常温保存した場合の離水を抑制する。これにより、常温で6ヶ月保存しても実質的に離水せず、離水による咽せや誤嚥の問題を解消することができる。   In the gel-like nutritional food of the present invention, carrageenan improves the time-dependent stability of a gel mainly composed of gelatin and suppresses water separation when stored at room temperature. Thereby, even if it preserve | saves at normal temperature for 6 months, it does not water substantially, but the problem of throat and aspiration by water separation can be eliminated.

カラギナンとしては、離水抑制の点からιカラギナン及びκカラギナンの両方を含有することが好ましく、特に、ιカラギナンとκカラギナンの質量比ι/κを0.5以上6以下とすることが好ましい。   The carrageenan preferably contains both ι carrageenan and κ carrageenan from the viewpoint of water separation inhibition, and particularly preferably the mass ratio ι / κ of ι carrageenan and κ carrageenan is 0.5 or more and 6 or less.

カラギナンのゲル状栄養食品中の含有量については、ゼラチンとカラギナンの質量比を10〜25、好ましくは14〜20とし、カラギナンの含有量を0.04%以上、好ましくは0.04〜0.1%、より好ましくは0.04〜0.07%とする。カラギナンの含有量が少なすぎるとゼラチンを主体とするゲルを常温保存した場合の経時的な加水分解を有効に抑制することが困難となり、カラギナンの含有量が多すぎるとゲルの柔軟性が乏しいため離水が多くなる場合があり、また嚥下機能が低下した者にとって嚥下しにくい物性になる場合がある。   Regarding the content of carrageenan in the gel-like nutritional food, the mass ratio of gelatin and carrageenan is 10 to 25, preferably 14 to 20, and the carrageenan content is 0.04% or more, preferably 0.04 to 0.00. 1%, more preferably 0.04 to 0.07%. If the carrageenan content is too low, it will be difficult to effectively suppress hydrolysis over time when the gel mainly composed of gelatin is stored at room temperature. If the carrageenan content is too high, the flexibility of the gel will be poor. There may be cases where weaning increases, and physical properties that are difficult for swallowing may occur for those who have reduced swallowing function.

このようにカラギナンを特定の含有量としても、ゼラチンのみから形成されるゲルと比べるとカラギナンを添加したゲルは硬くなるが、本発明のゲル状栄養食品はカゼイン塩も含有するので、ゼラチン特有の柔らかさと変形のしやすさを有し、口腔内で咽せを引き起こす食品の砕片が生じにくく、体温で溶けるという本来のゼラチンゲルの特徴を有するものとなる。また、カゼイン塩の含有により、ゲル状栄養食品は蛋白質含有量が高くなり、栄養価に優れたものとなる。この場合にゲル状栄養食品の味が損なわれることはない。これに対し、カゼイン塩に代えてコラーゲンペプチド、卵白ペプチド、脱脂粉乳などを使用すると、カラギナンを含有するゼラチンゲルを十分に柔らかくすることができず、さらにペプチドの場合はその苦みによりゲルの味が低下する。   Thus, even when carrageenan has a specific content, the gel added with carrageenan is harder than the gel formed only from gelatin, but the gel-like nutritional food of the present invention also contains casein salt, It has the characteristics of an original gelatin gel that has softness and ease of deformation, is unlikely to produce food fragments that cause soreness in the oral cavity, and melts at body temperature. Further, the inclusion of the casein salt increases the protein content of the gel-like nutritional food and makes it excellent in nutritional value. In this case, the taste of the gel nutritional food is not impaired. On the other hand, if collagen peptides, egg white peptides, skim milk powder or the like is used instead of casein salt, the gelatin gel containing carrageenan cannot be sufficiently softened. descend.

本発明において、カゼイン塩としては、牛乳に脂質、糖質及び乳清蛋白質除去処理を施して得られるものを使用することができ、より具体的には、脱脂乳に酸や酵素、乳酸菌等を作用させてカゼインを沈殿分離した後、水酸化ナトリウムや水酸化カルシウム、水酸化カリウム等のアルカリを加えてカゼインを溶解し、これを乾燥して製造されるカゼインナトリウム、カゼインカルシウム、カゼインカリウム、カゼインマグネシウム等が挙げられる。   In the present invention, the casein salt can be obtained by subjecting milk to a treatment for removing lipids, sugars and whey proteins, and more specifically, acid, enzyme, lactic acid bacteria, etc. are added to skim milk. After the casein is precipitated by separation, alkali such as sodium hydroxide, calcium hydroxide or potassium hydroxide is added to dissolve the casein and dried to produce sodium caseinate, calcium caseinate, potassium caseinate, casein Examples thereof include magnesium.

カゼイン塩の中では、柔らかく、離水を生じにくいゲルを形成する効果が高い点からカゼインナトリウムが好ましい。   Among the casein salts, sodium caseinate is preferable because it has a high effect of forming a gel that is soft and hardly causes water separation.

カゼイン塩のゲル状栄養食品中の含有量に関しては、カゼイン塩とカラギナンの質量比(カゼイン塩/カラギナン)を25超100以下、好ましくは30〜100、より好ましくは30〜65とし、カゼイン塩自体の含有量を1.5〜3%とすることが好ましい。カゼイン塩の含有量が少なすぎるとゲルが硬くなり、嚥下機能の低下した者が嚥下しにくくなり、反対に多すぎるとゲル状栄養食品を長期間保存したときのゲル物性の維持が困難となる。   Regarding the content of the casein salt in the gel-like nutritional food, the mass ratio of casein salt to carrageenan (casein salt / carrageenan) is more than 25 to 100 or less, preferably 30 to 100, more preferably 30 to 65, and the casein salt itself The content of is preferably 1.5 to 3%. If the content of caseinate is too low, the gel will become hard, and it will be difficult for those with reduced swallowing function to swallow. On the other hand, if the content is too high, it will be difficult to maintain gel properties when gel-like nutritional foods are stored for a long period of time. .

本発明において油脂類としては、例えば、パーム油、パーム核油、ヤシ油、コーン油、綿実油、大豆油、菜種油、米油、ヒマワリ油、サフラワー油、カカオ脂、サル脂、牛脂、豚脂、乳脂、魚油、鯨油等の各種の植物油脂及び動物油脂、並びにこれらに水素添加、分別及びエステル交換から選択された一又は二以上の処理を施した加工油脂や、MCT(中鎖脂肪酸トリグリセリド)等が挙げられ、本発明品においては、これらの中から選ばれた1種又は2種以上を用いることができる。また、油脂類として、マーガリン、バター、純生クリーム、コンパウンドクリーム等の乳化油脂、ショートニング、粉末油脂、液状油等の油脂組成物も挙げることができ、本発明においては、バター、マーガリン、生クリーム、コンパウンドクリーム等の乳化油脂を用いることが好ましい。   Examples of the fats and oils in the present invention include palm oil, palm kernel oil, coconut oil, corn oil, cottonseed oil, soybean oil, rapeseed oil, rice oil, sunflower oil, safflower oil, cacao butter, monkey butter, beef tallow, pork tallow , Various types of vegetable oils and animal fats such as milk fat, fish oil, whale oil, etc., and processed oils and fats subjected to one or more treatments selected from hydrogenation, fractionation and transesterification, and MCT (medium chain fatty acid triglyceride) In the product of the present invention, one or more selected from these can be used. Examples of the fats and oils include emulsified fats and oils such as margarine, butter, pure fresh cream, and compound cream, shortening, powdered fats and oils, and liquid oils. In the present invention, butter, margarine, fresh cream, It is preferable to use an emulsified oil such as a compound cream.

油脂類は、ゲル状栄養食品が好ましくは1.6kcal/g以上、より好ましくは2kcal/g以上の高カロリー食品となるように、好ましくは脂質として10%以上、より好ましくは12%以上含有される。一方、過度に油脂類を含有させると、殺菌時に分離や焦げ付きが起こるため、食感が悪くなる。また、分離や焦げ付きにより離水もおこりやすくなり、嚥下困難者が咽せや誤嚥を引き起こしやすくなる。そのため、油脂類の含有量は脂質として25%以下が好ましい。ここで、脂質としては、例えば、中性脂肪、リン脂質、ステロイド、ろう、脂溶性ビタミン等が挙げられ、脂質の含有量は、栄養表示基準(平成15年4月24日厚生省告示第176号)別表第2の第3欄記載の方法に準じて測定することができる。   The fats and oils are preferably contained in a form of lipids such that the nutritional food is preferably 1.6 kcal / g or more, more preferably 2 kcal / g or more, preferably 10% or more, more preferably 12% or more as a lipid. The On the other hand, when oils and fats are excessively contained, the texture becomes worse because separation or scorching occurs during sterilization. In addition, separation or scorching makes it easy for water to be removed, and a person with difficulty in swallowing easily causes throat or aspiration. Therefore, the content of fats and oils is preferably 25% or less as lipids. Examples of lipids include neutral fats, phospholipids, steroids, waxes, and fat-soluble vitamins, and the lipid content is based on nutrition labeling standards (April 24, 2003 Ministry of Health and Welfare Notification No. 176). ) It can be measured according to the method described in the third column of the appended table 2.

本発明において、乳化剤は上述の油脂類を安定に乳化分散させ、離水を抑制する。乳化剤としては、グリセリン脂肪酸エステル、ショ糖脂肪酸エステル、ソルビタン脂肪酸エステル、ポリグリセリン脂肪酸エステル、レシチン等を使用することが好ましい。また、そのゲル状栄養食品中の含有量は、0.05〜5%とすることが好ましい。   In the present invention, the emulsifier stably emulsifies and disperses the above fats and oils and suppresses water separation. As the emulsifier, glycerin fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polyglycerin fatty acid ester, lecithin and the like are preferably used. Moreover, it is preferable that content in the gel-like nutrient food shall be 0.05-5%.

本発明のゲル状栄養食品は、上述の成分に加えて、必要に応じてココア、コーヒーや果汁等の風味素材、乳製品、大豆蛋白質、糖類、甘味料、食物繊維、ビタミン類、ミネラル類、香料、色素、pH調整剤、リン酸塩等を含有することができる。   In addition to the above ingredients, the gel-like nutritional food of the present invention, if necessary, flavor materials such as cocoa, coffee and fruit juice, dairy products, soy protein, saccharides, sweeteners, dietary fiber, vitamins, minerals, A fragrance | flavor, a pigment | dye, a pH adjuster, a phosphate, etc. can be contained.

本発明のゲル状栄養食品は、上述の各原料を常法により混合して製造することができ、工業的に各原料の混合から個包装への充填まで行う場合には、例えば、各成分の撹拌混合、均質化、殺菌、均質化、容器への充填、冷却を順次行えばよい。この場合、離水をより効果的に抑制する点から、均質化を加圧下で行うこと、及び殺菌をスチームインジェクション方式やスチームインフュージョン方式等の直接殺菌方法で行うことが好ましい。   The gel-like nutritional food of the present invention can be produced by mixing the above-mentioned raw materials by a conventional method. When industrially mixing from raw materials to filling individual packages, for example, Stir mixing, homogenization, sterilization, homogenization, filling into a container, and cooling may be performed sequentially. In this case, from the viewpoint of more effectively suppressing water separation, it is preferable to perform homogenization under pressure and to perform sterilization by a direct sterilization method such as a steam injection method or a steam infusion method.

以下、実施例に基づいて本発明を具体的に説明する。   Hereinafter, the present invention will be specifically described based on examples.

実施例1〜13及び比較例1〜4
(1)ゲル状栄養食品の製造
表1に示す各原料をミキサーに投入して撹拌混合し、10MPaの圧力で均質化した後、スチームインジェクション式のUHT殺菌機にて142℃で4秒間殺菌し、再度10MPaの圧力で均質化後、底面積34.8cm、高さ14.5cmの長方形の紙容器に500mL充填し、5℃で24時間冷却してゲル状栄養食品を製造した。なお、乳化剤としては、グリセリン脂肪酸エステルを使用した。
Examples 1-13 and Comparative Examples 1-4
(1) Manufacture of gel-like nutritional foods Each raw material shown in Table 1 is put into a mixer, stirred and mixed, homogenized at a pressure of 10 MPa, and then sterilized at 142 ° C for 4 seconds with a steam injection type UHT sterilizer. After homogenization again at a pressure of 10 MPa, 500 mL of a rectangular paper container having a bottom area of 34.8 cm 2 and a height of 14.5 cm was filled and cooled at 5 ° C. for 24 hours to produce a gel-like nutritional food. In addition, glycerin fatty acid ester was used as an emulsifier.

また、原料組成から、次式により各ゲル状栄養食品の1g当たりのカロリー(kcal/g)を算出した。   Moreover, the calorie (kcal / g) per 1g of each gel-like nutritional food was computed from the raw material composition by following Formula.

Figure 2012095645
Figure 2012095645

各ゲル状栄養食品の蛋白質含有量(g/g)、脂質含有量(g/g)、カゼインNaとカラギナンの質量比、ゼラチンとカラギナンの質量比、ιカラギナンとκカラギナンの質量比(ι/κ)についてもそれぞれ算出した。これらの値を表1に示す。   Protein content (g / g), lipid content (g / g), mass ratio of casein Na and carrageenan, mass ratio of gelatin and carrageenan, mass ratio of ι carrageenan and κ carrageenan (ι / κ) was also calculated. These values are shown in Table 1.

(2)評価
(1)で得られた各容器詰めゲル状栄養食品を「保存前」の試料とし、25℃で6ヶ月間保存したものを「保存後」の試料とし、それぞれの離水状態、硬さ及び食感を品温10℃で次のように評価した。
(2) Evaluation Each container-packed gel-like nutritional food obtained in (1) is used as a “pre-storage” sample, and after 6 months storage at 25 ° C. is used as a “post-storage” sample. The hardness and texture were evaluated as follows at a product temperature of 10 ° C.

(2−1)離水状態
紙容器への充填時から評価の直前まで一貫して、各試料を底面積が34.8cmの面(以降、底面部)が底になるように静置し、開封直前に静かに横倒して底面部に隣接する容器の一側面を開封し、各試料の底面部を観察した。ここで、ゲルに離水が生じていると水は底面部側に溜まるため、底面部側のゲルは透明感を呈することとなる。そこで、この透明感を呈する部分を離水部とし、底面部側端面から透明感のない部分に至る離水部の長さを離水量の指標として、次の基準で4段階に評価した。なお、この評価時に試料がペースト状であれば、その試料は保存期間にゲル状態を維持できなかったということであるから、離水状態を評価するまでもなく、保存性は劣っていると評価できる。
(2-1) Water separation state From the time of filling into the paper container until immediately before the evaluation, each sample is left standing so that the surface (hereinafter referred to as the bottom portion) having a bottom area of 34.8 cm 2 is the bottom, Just before opening, the container was gently laid down to open one side of the container adjacent to the bottom, and the bottom of each sample was observed. Here, when water separation occurs in the gel, water accumulates on the bottom surface side, and thus the gel on the bottom surface side exhibits a sense of transparency. Then, the part which shows this transparency was made into the water separation part, and the length of the water separation part from the bottom face part side end surface to the part without a feeling of transparency was evaluated in four steps on the basis of the following criteria. Note that if the sample is pasty at the time of this evaluation, it means that the sample could not maintain the gel state during the storage period, so it can be evaluated that the storage stability is inferior without evaluating the water separation state. .

ランク 基準
×: 大量に水が分離しており、離水部の長さが1cmより長い場合
○: わずかに水が分離しており、離水部の長さが0.5〜1cmである場合
◎: 実質的に離水がない、乃至表面が水で濡れている程度であり、離水部の長さが0.5cm未満である場合
−: 透明感のない部分がゲル状態を保持していないため、離水部との界面が判然とせず測定不能である場合
Rank standard x: When water is separated in a large amount and the length of the water separation part is longer than 1 cm ○: When water is slightly separated and the length of the water separation part is 0.5 to 1 cm ◎: When there is substantially no water separation or when the surface is wet with water, and the length of the water separation part is less than 0.5 cm-: Since the part without transparency does not maintain the gel state, water separation When the interface with the part is unclear and cannot be measured

(2−2)硬さ
各試料を開封し、紙容器の中心部のゲルを直径40mm、高さ15mmの容器に充填し、容器の高さに合わせて試料を15mmの高さに切った。直径20mm、高さ8mmの樹脂製のプランジャーを用い、圧縮距離10mm/sec、クリアランス5mmで圧縮し、クリープメーター((株)山電社製、RE−3305 RHEONER)を用いてゲルの硬さを測定し、次の4段階で評価した。
(2-2) Hardness Each sample was opened, the gel at the center of the paper container was filled into a container with a diameter of 40 mm and a height of 15 mm, and the sample was cut to a height of 15 mm according to the height of the container. Using a resin plunger with a diameter of 20 mm and a height of 8 mm, compress with a compression distance of 10 mm / sec and a clearance of 5 mm, and use a creep meter (RE-3305 RHEONER, manufactured by Yamaden Co., Ltd.) Was measured and evaluated in the following four stages.

ランク 基準
×: 15000N/mより大である場合
○: 10000N/m以上15000N/m以下である場合
◎: 1000N/m以上10000N/m未満である場合
−: 試料がゲル状態を保持していないため、硬さの測定不能である場合
Rank criteria ×: 15000 N / m 2 when it is larger than ○: 10000 N / m 2 or more 15000 N / m 2 or less when ◎: 1000 N / m 2 or more 10000 N / m 2 less than in the case of -: sample the gel state If the hardness cannot be measured because it is not held

(2−3)食感
品温10℃の各試料を試食し、食感を次の基準で4段階に評価した。
(2-3) Food texture Each sample having a product temperature of 10 ° C. was sampled, and the food texture was evaluated in four stages according to the following criteria.

ランク 基準
×: 弾力があり、舌で押すと、砕ける又は押し戻り、ほとんどとろけない場合
○: 弾力があるものの柔らかく、舌で押すととろけるまたは砕けてとろけてしまう場合
◎: わずかな弾力があるものの柔らかく、舌で押すととろけてしまう場合
−: 試料がゲル状態を保持していない場合(評価から除外)
Rank Criteria x: Elasticity, when crushing or pushing back when pressed with tongue, almost unmeltable ○: Soft but soft, when melted or crushing and melting when pressed with tongue ◎: Although slightly elastic If it is soft and melts when pressed with the tongue −: If the sample does not maintain a gel state (excluded from evaluation)

Figure 2012095645
Figure 2012095645

表1から、ゼラチンとカラギナンの質量比が10〜25の範囲、カゼイン塩とカラギナンの質量比が25超100以下の範囲であり、カラギナンの含有量が0.04%以上の範囲にある実施例1〜13は、保存前だけでなく保存後においても離水が抑制されており、ゲルの硬さが柔らかく食感も良好であることがわかる。これに対してゼラチンの含有量が少なく、ゼラチンとカラギナンの質量比が2である比較例1はゲルにならず、カラギナンの含有量が0.03%と少なく、この比が33である比較例2、3は保存後の離水が抑制されておらず、また、カラギナンの含有量が比較的多いためにカゼイン塩とカラギナンの質量比が25と低い比較例4は保存後の離水が抑制されておらず、食感も劣っていることがわかる。   From Table 1, the mass ratio of gelatin to carrageenan is in the range of 10 to 25, the mass ratio of casein salt to carrageenan is in the range of more than 25 and 100 or less, and the content of carrageenan is in the range of 0.04% or more. Nos. 1 to 13 show that water separation is suppressed not only before storage but also after storage, and the gel has a soft hardness and good texture. In contrast, Comparative Example 1 in which the gelatin content is low and the mass ratio of gelatin to carrageenan is 2, does not become a gel, and the content of carrageenan is as low as 0.03%, and this ratio is 33. In Comparative Examples 4 and 3 where water separation after storage was not suppressed, and because the content of carrageenan was relatively large, the weight ratio of casein salt and carrageenan was as low as 25, so that water separation after storage was suppressed. It can be seen that the texture is poor.

さらに、実施例5、6から、カゼイン塩の含有量3%のゲルは、カゼイン塩の含有量4%のゲルよりも保存後の離水が抑制されて好ましいことがわかる。   Further, Examples 5 and 6 show that a gel with a casein salt content of 3% is more preferable than a gel with a casein salt content of 4% because water separation after storage is suppressed.

また、実施例1、7、8から、油脂類としては乳化油脂を使用するのが保存後の離水抑制の点から好ましいことがわかる。なお、特に油中水型であるバターを使用した実施例1は、水中油型である生クリームを使用した実施例7に比して、離水が一層抑制されていた。   Moreover, from Examples 1, 7, and 8, it is understood that it is preferable to use emulsified oils and fats as the fats and oils from the viewpoint of suppressing water separation after storage. In particular, in Example 1 using butter that is a water-in-oil type, water separation was further suppressed as compared to Example 7 using a fresh cream that was an oil-in-water type.

実施例1、9、10から、カラギナンとしては、ιカラギナンとκカラギナンの質量比を6以下にするのが好ましいことがわかる。   From Examples 1, 9, and 10 it can be seen that the carrageenan preferably has a mass ratio of ι carrageenan to κ carrageenan of 6 or less.

実施例1、11から、油脂類の含有量が多いと製造直後からゲルが柔らかくなり、嚥下困難者に、より好ましい食品となることがわかる。   From Examples 1 and 11, it can be seen that if the content of fats and oils is large, the gel becomes soft immediately after production, and it becomes a more preferable food for those who have difficulty swallowing.

本発明のゲル状食品は、口溶けが良好であり、しかも、ゲルのネットワークの経時的安定性が良好であるため、実質的に離水を生じさせることなく、脂質と蛋白質がバランスよく配合された高カロリー食品となる。更に、ゲルが柔らかいながらも、安定したゲル強度を示し、保存期間中の物性変化がほとんどなく、いつ食べても柔らかく、舌で潰して食べることが可能なものであり、飲み込みやすいものである。従って、高齢、疾病などにより嚥下機能が低下している者のための栄養食品として有用である。   The gel-like food of the present invention is well melted in the mouth and has good stability over time of the gel network, so that the lipid and protein are blended in a well-balanced manner without substantially causing water separation. It becomes a calorie food. Furthermore, although the gel is soft, it exhibits a stable gel strength, hardly changes in physical properties during the storage period, is soft whenever it is eaten, can be crushed with the tongue, and is easy to swallow. Therefore, it is useful as a nutritional food for those whose swallowing function is reduced due to aging or illness.

Claims (4)

油脂類、ゼラチン、カラギナン、カゼイン塩及び乳化剤を含有し、
ゼラチンとカラギナンの質量比(ゼラチン/カラギナン)が10〜25、
カゼイン塩とカラギナンの質量比(カゼイン塩/カラギナン)が25超100以下、
カラギナンの含有量0.04質量%以上
であるゲル状栄養食品。
Contains fats and oils, gelatin, carrageenan, caseinate and emulsifier,
The mass ratio of gelatin and carrageenan (gelatin / carrageenan) is 10-25,
The mass ratio of casein salt to carrageenan (casein salt / carrageenan) is more than 25 and less than 100,
A gel-like nutritional food having a carrageenan content of 0.04% by mass or more.
カゼイン塩とカラギナンの質量比(カゼイン塩/カラギナン)が30〜100である請求項1記載のゲル状栄養食品。   The gel-like nutritional food according to claim 1, wherein the mass ratio of casein salt to carrageenan (casein salt / carrageenan) is 30 to 100. 油脂類として乳化油脂を用いる請求項1または2記載のゲル状栄養食品。   The gel-like nutritional food according to claim 1 or 2, wherein emulsified fats and oils are used as the fats and oils. カゼイン塩の含有量が3質量%以下である請求項1〜3のいずれかに記載のゲル状栄養食品。   The gel-like nutritional food according to any one of claims 1 to 3, wherein the casein salt content is 3% by mass or less.
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