JP2012066161A5 - - Google Patents

Download PDF

Info

Publication number
JP2012066161A5
JP2012066161A5 JP2010210664A JP2010210664A JP2012066161A5 JP 2012066161 A5 JP2012066161 A5 JP 2012066161A5 JP 2010210664 A JP2010210664 A JP 2010210664A JP 2010210664 A JP2010210664 A JP 2010210664A JP 2012066161 A5 JP2012066161 A5 JP 2012066161A5
Authority
JP
Japan
Prior art keywords
dechlorination
acid
water
added
activated carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2010210664A
Other languages
Japanese (ja)
Other versions
JP2012066161A (en
JP5670685B2 (en
Filing date
Publication date
Application filed filed Critical
Priority to JP2010210664A priority Critical patent/JP5670685B2/en
Priority claimed from JP2010210664A external-priority patent/JP5670685B2/en
Publication of JP2012066161A publication Critical patent/JP2012066161A/en
Publication of JP2012066161A5 publication Critical patent/JP2012066161A5/ja
Application granted granted Critical
Publication of JP5670685B2 publication Critical patent/JP5670685B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Description

脱塩工程)
本工程において、逆浸透膜処理は、供給水を高圧下で膜透過水と濃縮水に膜分離する処理操作であり、逆浸透膜処理の方法及び装置は、現在公知のものを適宜採用すればよい。
( Desalting step)
In this step, the reverse osmosis membrane treatment is a treatment operation in which the feed water is membrane-separated into membrane permeate and concentrated water under high pressure, and a currently known method and apparatus for reverse osmosis membrane treatment can be appropriately employed. Good.

脱塩処理方法として、逆浸透膜処理を採用した場合、処理水回収率を向上させる上で最大の阻害因子となるのが、濃縮水中における溶性ケイ酸の析出である。
そこで、溶性ケイ酸の溶解度を高めるために、脱塩工程に供給する水のpHを高くして水回収率を高くするのが好ましい。この際、脱塩工程に供給する水のpHを9.0以上にすれば、溶性ケイ酸の溶解度を高める効果を得ることができる一方、pHを一定以上に高くし過ぎても、水回収率の向上に繋がらない反面、後工程において塩素の消毒効果が低下するため塩素濃度を高くする必要が生じる。かかる観点から、脱塩工程に供給する水のpHを9.0〜10.5、中でも9.5〜10.5に調整するのが好ましい。
この際、pH調整に用いるアルカリ剤としては、水酸化ナトリウムや水酸化カリウムなどの水酸化物、重炭酸ナトリウムなどの炭酸塩などを挙げることができる。これらに限定するものではない。特に水酸化ナトリウムが好適である。
When reverse osmosis membrane treatment is adopted as the desalting treatment method, precipitation of soluble silicic acid in the concentrated water is the largest inhibitory factor in improving the treated water recovery rate.
Therefore, in order to increase the solubility of the soluble silicic acid, it is preferable to increase the water recovery rate by increasing the pH of the water supplied to the desalting step. At this time, if the pH of the water supplied to the desalting step is set to 9.0 or higher, the effect of increasing the solubility of the soluble silicic acid can be obtained. On the other hand, the water recovery rate can be increased even if the pH is set higher than a certain level. However, since the disinfection effect of chlorine is lowered in the subsequent process, it is necessary to increase the chlorine concentration. From this point of view, it is preferable to adjust the pH of water supplied to the desalting step to 9.0 to 10.5, particularly 9.5 to 10.5.
At this time, examples of the alkali agent used for pH adjustment include hydroxides such as sodium hydroxide and potassium hydroxide, carbonates such as sodium bicarbonate, and the like. It is not limited to these. Sodium hydroxide is particularly preferred.

具体的には、図1〜4に示すように、アルカリ剤貯槽4、薬注ポンプ5、制御計6、pH計7から構成される装置によるアルカリ調整工程を、脱塩工程の前に配置し、溶性ケイ酸を含有する原水16にアルカリを添加してpHを9.0〜10.5に調整して溶性ケイ酸の溶解度を大きくした状態で、逆浸透膜処理装置1による脱塩工程に供給して溶解塩類を除去するようにすればよい。但し、このような具体的手段に限定するものではない。 Specifically, as shown in FIGS. 1 to 4, an alkali adjustment process using an apparatus composed of an alkaline agent storage tank 4, a chemical injection pump 5, a control meter 6, and a pH meter 7 is arranged before the desalting step. , in a state in which by adding an alkali to the raw water 16 containing soluble silicate to adjust the pH to 9.0 to 10.5 to increase the solubility of the soluble silicate, as desalting Engineering by reverse osmosis membrane treatment apparatus 1 The dissolved salt may be removed by supplying to the solution. However, it is not limited to such specific means.

具体的には、図1〜4に示すように、塩素剤貯槽8、薬注ポンプ9、制御計10、残留塩素計11から構成される装置による消毒工程を、脱塩工程の次に配し、塩素剤を添加して、用水貯留槽2及び配管などの装置による用水貯留工程における菌繁殖を防止するようにするのが好ましい。但し、このような具体的手段に限定するものではない。 Specifically, as shown in FIGS. 1 to 4, a disinfection process using a device composed of a chlorine storage tank 8, a chemical injection pump 9, a control meter 10, and a residual chlorine meter 11 is arranged next to the desalting step. It is preferable to add a chlorinating agent so as to prevent bacterial growth in the water storage step using the water storage tank 2 and piping. However, it is not limited to such specific means.

逆流洗浄の具体例としては、図1及び図2に示すように、通常状態、すなわち洗浄を行わない状態においては、切換バルブ21及び切換バルブ19を開、切換バルブ22及び切換バルブ20を閉として、脱塩素処理装置3による脱塩素処理工程に通水し、脱塩素処理を行うようにする。
そして、脱塩素処理装置3を洗浄する際には、切換バルブ21および切換バルブ19を閉とし、切換バルブ22及び切換バルブ20を開として、切換バルブ22と脱塩素処理装置3の間に設けた酸調整設備、すなわち酸剤貯槽12、薬注ポンプ13、制御計14及びpH計15から構成される酸調整設備又は炭酸ガス貯槽23、電磁流量計24、制御計14及びpH計15から構成される酸調整設備によって酸添加水を調製し、脱塩素処理装置3の逆流洗浄を行い、脱塩素処理装置充填剤の活性点の再生を行うようにすればよい。
但し、このような具体的手段に限定するものではない。
As a specific example of backflow cleaning, as shown in FIGS. 1 and 2, in a normal state, that is, in a state where cleaning is not performed, the switching valve 21 and the switching valve 19 are opened, and the switching valve 22 and the switching valve 20 are closed. Then, water is passed through the dechlorination process by the dechlorination apparatus 3 to perform the dechlorination process.
When the dechlorination apparatus 3 is cleaned, the switching valve 21 and the switching valve 19 are closed, the switching valve 22 and the switching valve 20 are opened, and the dechlorination apparatus 3 is provided between the switching valve 22 and the dechlorination apparatus 3. An acid adjustment facility, that is, an acid agent storage tank 12, a chemical injection pump 13, a controller 14 and a pH meter 15, an acid adjustment facility or a carbon dioxide gas storage tank 23, an electromagnetic flow meter 24, a controller 14 and a pH meter 15. The acid-added water is prepared by the acid adjusting equipment , the backwashing of the dechlorination apparatus 3 is performed, and the active point of the dechlorination apparatus filler is regenerated.
However, it is not limited to such specific means.

他方、順流洗浄の具体例としては、図3及び図4に示すように、通常状態、すなわち洗浄を行わない状態においては、切換バルブ19を開、切換バルブ20を閉として、脱塩素処理装置3による脱塩素処理工程に通水し、脱塩素処理を行うようにする。
そして、脱塩素処理装置3を洗浄する際には、切換バルブ19を閉、切換バルブ20を開として、用水貯留槽2と脱塩素処理装置3の間に設けた酸調整設備、すなわち酸剤貯槽12、薬注ポンプ13、制御計14及びpH計15から構成される酸調整設備又は炭酸ガス貯槽23、電磁流量計24、制御計14及びpH計15から構成される酸調整設備によってpH8.6以下とした酸添加水を調製し、脱塩素処理装置3の順流洗浄を行い、脱塩素処理装置充填剤の活性点の再生を行うようにすればよい。
但し、このような具体的手段に限定するものではない。
On the other hand, as a specific example of the forward flow cleaning, as shown in FIGS. 3 and 4, in the normal state, that is, in the state where cleaning is not performed, the switching valve 19 is opened and the switching valve 20 is closed, so that the dechlorination apparatus 3 Water is passed through the dechlorination process by, so that dechlorination is performed.
When the dechlorination apparatus 3 is washed, the switching valve 19 is closed and the switching valve 20 is opened, so that an acid adjustment facility provided between the water storage tank 2 and the dechlorination apparatus 3, that is, an acid agent storage tank. 12, pH 8.6 by an acid adjustment facility or a carbon dioxide gas storage tank 23, an electromagnetic flow meter 24, a control meter 14, and a pH meter 15 composed of a chemical injection pump 13, a control meter 14 and a pH meter 15. The following acid-added water is prepared, and the dechlorination apparatus 3 is washed in the forward direction to regenerate the active sites of the dechlorination apparatus filler.
However, it is not limited to such specific means.

Claims (7)

逆浸透膜処理された処理水に塩素剤を添加し、その後、活性炭を備えた脱塩素処理槽に通水することにより脱塩素処理する工程を備えた飲料用水の製造工程において、酸を添加した酸添加水で前記脱塩素処理槽を洗浄することにより、活性炭の脱塩素能力を回復させることを特徴とする、飲料用水の製造工程における活性炭の脱塩素能力回復方法。   In the manufacturing process of drinking water with a step of dechlorination by adding a chlorinating agent to the treated water treated with reverse osmosis membrane and then passing it through a dechlorination tank equipped with activated carbon, acid was added. A method for recovering the dechlorination capacity of activated carbon in a process for producing drinking water, wherein the dechlorination capacity of the activated carbon is recovered by washing the dechlorination tank with acid-added water. 酸を添加した酸添加水で脱塩素処理槽を洗浄する処理を、少なくとも1週間に1回以上の頻度で実施することを特徴とする請求項1に記載の活性炭の脱塩素能力回復方法。   2. The method for recovering the dechlorination ability of activated carbon according to claim 1, wherein the treatment for washing the dechlorination tank with acid-added water to which an acid has been added is performed at least once a week. 添加する酸は、硫酸、塩酸又は炭酸であることを特徴とする請求項1又は2に記載の活性炭の脱塩素能力回復方法。   The method for recovering the dechlorination ability of activated carbon according to claim 1 or 2, wherein the acid to be added is sulfuric acid, hydrochloric acid or carbonic acid. 原水を逆浸透膜処理する脱塩工程と、逆浸透膜処理された処理水に塩素剤を添加する消毒工程と、消毒工程で得られた消毒水を、活性炭を備えた脱塩素処理槽に通水することにより脱塩素処理する脱塩素工程とを備えた飲料用水の製造方法であって
酸を添加した酸添加水で前記脱塩素処理槽を洗浄することにより、活性炭の脱塩素能力を回復させることを特徴とする飲料用水の製造方法。
Desalination process for treating raw water with reverse osmosis membrane, disinfection process for adding chlorine agent to treated water treated with reverse osmosis membrane, and disinfecting water obtained in the disinfection process is passed through a dechlorination tank equipped with activated carbon. A method for producing drinking water comprising a dechlorination step of dechlorinating by hydrating,
A method for producing drinking water, wherein the dechlorination ability of activated carbon is recovered by washing the dechlorination tank with acid-added water to which an acid has been added.
酸を添加した酸添加水で脱塩素処理槽を洗浄する処理を、少なくとも1週間に1回以上の頻度で実施することを特徴とする請求項4に記載の飲料用水の製造方法。   The method for producing drinking water according to claim 4, wherein the treatment for washing the dechlorination tank with acid-added water to which an acid has been added is performed at least once a week. 添加する酸は、硫酸、塩酸又は炭酸であることを特徴とする請求項4又は5に記載の飲料用水の製造方法。   The method for producing drinking water according to claim 4 or 5, wherein the acid to be added is sulfuric acid, hydrochloric acid or carbonic acid. 原水を逆浸透膜処理する脱塩手段と、逆浸透膜処理された処理水に塩素剤を添加する消毒手段と、消毒手段で得られた消毒水を、活性炭を備えた脱塩素処理槽に通水することにより脱塩素処理する脱塩素手段と、酸添加水で前記脱塩素処理槽を洗浄することにより、活性炭の脱塩素能力を回復させる手段と、を備えた飲料用水の製造装置。Demineralization means for treating raw water with a reverse osmosis membrane, disinfection means for adding a chlorine agent to treated water treated with a reverse osmosis membrane, and disinfecting water obtained by the disinfection means passed through a dechlorination treatment tank equipped with activated carbon. An apparatus for producing drinking water, comprising: dechlorination means for dechlorination treatment by water; and means for recovering the dechlorination ability of activated carbon by washing the dechlorination tank with acid-added water.
JP2010210664A 2010-09-21 2010-09-21 Recovery method of dechlorination ability of activated carbon in the manufacturing process of drinking water Active JP5670685B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2010210664A JP5670685B2 (en) 2010-09-21 2010-09-21 Recovery method of dechlorination ability of activated carbon in the manufacturing process of drinking water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2010210664A JP5670685B2 (en) 2010-09-21 2010-09-21 Recovery method of dechlorination ability of activated carbon in the manufacturing process of drinking water

Publications (3)

Publication Number Publication Date
JP2012066161A JP2012066161A (en) 2012-04-05
JP2012066161A5 true JP2012066161A5 (en) 2013-11-07
JP5670685B2 JP5670685B2 (en) 2015-02-18

Family

ID=46164073

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2010210664A Active JP5670685B2 (en) 2010-09-21 2010-09-21 Recovery method of dechlorination ability of activated carbon in the manufacturing process of drinking water

Country Status (1)

Country Link
JP (1) JP5670685B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014103083A1 (en) * 2012-12-27 2014-07-03 株式会社レドックス Electrolyzed water conforming to standards for water used in soft-drink manufacturing, and method for manufacturing said electrolyzed water
JP2019130506A (en) * 2018-02-01 2019-08-08 アクアデザインシステム株式会社 Chlorine injection device for water purifier

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61242687A (en) * 1985-04-19 1986-10-28 Mitsubishi Rayon Co Ltd Purified water generator
JPH0712471B2 (en) * 1990-01-29 1995-02-15 荏原インフイルコ株式会社 How to sterilize and decontaminate activated carbon
JPH07121388B2 (en) * 1991-06-26 1995-12-25 株式会社荏原製作所 Sterilization and neutralization method of activated carbon with acid and alkali
JP2546750B2 (en) * 1991-06-28 1996-10-23 株式会社荏原製作所 How to sterilize activated carbon
JPH10202249A (en) * 1997-01-16 1998-08-04 Kurita Water Ind Ltd Deionizing method
JPH11262766A (en) * 1998-03-19 1999-09-28 Daisen Membrane Systems Kk Reverse osmosis membrane type water purifier

Similar Documents

Publication Publication Date Title
US20110056876A1 (en) Desalination system
KR101671168B1 (en) Slime control agent for activated carbon, method of passing water through activated-carbon device, and method and apparatus for treating organic-containing water
JP2005087887A (en) Membrane washing method
JP3870712B2 (en) Circulating cooling water treatment method and treatment apparatus
JP2010082610A (en) Method and system for producing pure water
JP5998929B2 (en) Membrane separation method
JP2017113729A (en) Membrane cleaning agent, membrane cleaning liquid and cleaning method of membrane
JP5609174B2 (en) Water treatment system
JP2011050843A (en) Method of and system for desalinating water to be treated
TWI381999B (en) Silica removing device and silica removing method
JP2007307561A (en) High-purity water producing apparatus and method
JP2012066161A5 (en)
JP4850467B2 (en) Cleaning method for membrane deaerator
JP2008086945A (en) Method for recovering performance of permselective membrane
JP5670685B2 (en) Recovery method of dechlorination ability of activated carbon in the manufacturing process of drinking water
CN218561247U (en) System for preparing water for preparing green hydrogen by utilizing sewage
JP5333486B2 (en) Water treatment method and water treatment system
KR102398703B1 (en) Method for Recycling Reverse Osmosis Membrane, Process for Producing Ultra Pure Water, and System for Manufacturing Ultra Pure Water
JP2005238135A (en) Washing method of membrane separation device
JP2012066160A5 (en)
JP2012183485A (en) Water treatment method and water treatment system
CN102076434A (en) Process for disinfecting a filtration works for pretreatment of saltwater, and installation for the implementation thereof
JP5569784B2 (en) Pure water production system
JP5670684B2 (en) Method for maintaining the recovery of dechlorination ability of activated carbon in the manufacturing process
JP2007175688A (en) Artificial mineral water production method and its system