JP2011513198A5 - - Google Patents
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- JP2011513198A5 JP2011513198A5 JP2010530920A JP2010530920A JP2011513198A5 JP 2011513198 A5 JP2011513198 A5 JP 2011513198A5 JP 2010530920 A JP2010530920 A JP 2010530920A JP 2010530920 A JP2010530920 A JP 2010530920A JP 2011513198 A5 JP2011513198 A5 JP 2011513198A5
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- JP
- Japan
- Prior art keywords
- mol
- iron
- stage
- manufacturing
- hydrocarbon compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 10
- 239000003054 catalyst Substances 0.000 claims 7
- 238000004519 manufacturing process Methods 0.000 claims 6
- 229910052742 iron Inorganic materials 0.000 claims 5
- 150000002430 hydrocarbons Chemical class 0.000 claims 4
- 239000010457 zeolite Substances 0.000 claims 4
- 150000001336 alkenes Chemical class 0.000 claims 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 230000015572 biosynthetic process Effects 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 238000003786 synthesis reaction Methods 0.000 claims 2
- 230000002194 synthesizing Effects 0.000 claims 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims 1
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- -1 olefin compound Chemical class 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium(0) Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Claims (8)
- 鉄触媒存在下で２００〜４００℃、５〜２５気圧、５００〜８，０００ＧＨＳＶの流速で合成ガスからフィッシャー・トロプシュ反応を行い炭化水素化合物を製造する第１段階と、
ゼオライト触媒存在下で３００〜７００℃、０．１〜５気圧で炭化水素化合物を分解してＣ2−Ｃ4の軽質オレフィンを製造する第２段階と、
を含む合成ガスから軽質オレフィンを製造する連続的な２段階方法。 - 前記第１段階反応で製造された炭化水素化合物はオレフィン化合物を５０〜９０炭素モル％含有する、請求項１記載の製造方法。
- 前記鉄触媒は鉄を６０〜９５重量％含有する、請求項１記載の製造方法。
- 前記鉄触媒は、鉄１モルに対して銅、マンガン、クロム、バナジウム及び亜鉛の中から選択される金属を０．０１〜０．１モル更に含有する、請求項１記載の製造方法。
- 前記ゼオライト触媒は、Ａｌ2Ｏ3１モルに対してＳｉＯ2を８０〜６，０００モル含有するＺＳＭ−５ゼオライト触媒である、請求項１記載の製造方法。
- 前記ゼオライト触媒は、リン（Ｐ）、ランタン（Ｌａ）またはそれらの混合物を０．０１〜１０重量％含有する、請求項１記載の製造方法。
- 前記第２段階反応において、炭化水素化合物１重量部に対して水０．０１〜１重量部が追加で添加される、請求項１記載の製造方法。
- 前記製造されたＣ2−Ｃ4の軽質オレフィンは、選択度が３０〜６５炭素モル％であり、プロピレンは１０〜３５炭素モル％である、請求項１記載の製造方法。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020070108494A KR100904297B1 (ko) | 2007-10-26 | 2007-10-26 | 연속적인 2단계 촉매 반응을 이용한 합성가스로부터 경질올레핀의 제조방법 |
| KR10-2007-0108494 | 2007-10-26 | ||
| PCT/KR2008/005606 WO2009054616A2 (en) | 2007-10-26 | 2008-09-22 | Process for producing light olefins from synthesis gas using dual sequential bed reactor |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2011513198A JP2011513198A (ja) | 2011-04-28 |
| JP2011513198A5 true JP2011513198A5 (ja) | 2011-06-16 |
| JP5518727B2 JP5518727B2 (ja) | 2014-06-11 |
Family
ID=40580208
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010530920A Active JP5518727B2 (ja) | 2007-10-26 | 2008-09-22 | 連続的な２段階反応を利用した合成ガスからの軽質オレフィンの製造方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8395004B2 (ja) |
| EP (1) | EP2215038B1 (ja) |
| JP (1) | JP5518727B2 (ja) |
| KR (1) | KR100904297B1 (ja) |
| CN (1) | CN101868434B (ja) |
| WO (1) | WO2009054616A2 (ja) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20110026709A (ko) * | 2009-09-08 | 2011-03-16 | 한국화학연구원 | 올레핀 크레킹 반응용 제올라이트계 성형촉매 및 합성가스로부터 경질 올레핀의 제조방법 |
| US20130046033A1 (en) * | 2010-05-10 | 2013-02-21 | Casale Chemicals Sa | Process for the Production of Light Olefins from Synthesis Gas |
| US9073804B2 (en) * | 2010-12-21 | 2015-07-07 | Dow Global Technologies Llc | Enhanced conversion of syngas to propylene |
| CN102442872A (zh) * | 2011-11-10 | 2012-05-09 | 北京化工大学 | 一种合成气直接合成低碳烯烃的方法 |
| CN105143157B (zh) * | 2013-04-24 | 2018-11-13 | 沙特基础工业公司 | 从天然资源产生产物 |
| WO2014174107A1 (en) * | 2013-04-26 | 2014-10-30 | Bp P.L.C. | Production of hydrocarbons from synthesis gas |
| CN108137431B (zh) * | 2015-10-30 | 2021-04-23 | 陶氏环球技术有限责任公司 | 使用双官能氧化铬/氧化锌-sapo-34催化剂将合成气体转化为烯烃的方法 |
| JP7492232B2 (ja) * | 2020-08-07 | 2024-05-29 | 三菱ケミカル株式会社 | 低級オレフィン製造用の触媒、及び低級オレフィンの製造方法 |
| KR102602154B1 (ko) * | 2021-08-03 | 2023-11-15 | 포항공과대학교 산학협력단 | Pst-32 및 pst-2 제올라이트 촉매를 이용한 탄화수소 전환방법 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2536488C2 (de) * | 1975-08-16 | 1977-08-25 | Ruhrchemie Ag | Verfahren zur herstellung ungesaettigter kohlenwasserstoffe |
| EP0109059B1 (en) * | 1982-11-10 | 1987-07-15 | MONTEDIPE S.p.A. | Process for converting olefins having 4 to 12 carbon atoms into propylene |
| US4544674A (en) * | 1983-12-14 | 1985-10-01 | Exxon Research And Engineering Co. | Cobalt-promoted fischer-tropsch catalysts |
| US5026936A (en) * | 1989-10-02 | 1991-06-25 | Arco Chemical Technology, Inc. | Enhanced production of propylene from higher hydrocarbons |
| GB9026775D0 (en) * | 1990-12-10 | 1991-01-30 | Shell Int Research | Process for the preparation of an olefins-containing mixture of hydrocarbons |
| CA2104044C (en) | 1992-08-25 | 2004-11-02 | Johan W. Gosselink | Process for the preparation of lower olefins |
| JP2952409B2 (ja) * | 1998-03-09 | 1999-09-27 | 工業技術院長 | 低級オレフィン製造用触媒 |
| US6106697A (en) | 1998-05-05 | 2000-08-22 | Exxon Research And Engineering Company | Two stage fluid catalytic cracking process for selectively producing b. C.su2 to C4 olefins |
| EP1116775A1 (en) | 2000-01-12 | 2001-07-18 | Akzo Nobel N.V. | Catalyst composition with high efficiency for the production of light olefins |
| JP4112943B2 (ja) * | 2002-10-28 | 2008-07-02 | 出光興産株式会社 | 炭化水素の接触分解によるオレフィンの製造方法 |
| US20040149629A1 (en) * | 2003-01-31 | 2004-08-05 | Dancuart Kohler Luis Pablo | Process for the preparation of and composition of a feedstock usable for the preparation of lower olefins |
| BRPI0514218A (pt) * | 2004-08-10 | 2008-06-03 | Shell Internationale Rsearch M | processo e aparelho para fabricar destilado médio e olefinas inferiores |
| KR100632563B1 (ko) * | 2004-09-10 | 2006-10-09 | 에스케이 주식회사 | 접촉 분해용 고체산 촉매 및 이를 이용하여 전범위납사로부터 경질 올레핀을 선택적으로 제조하는 공정 |
| WO2006070006A2 (en) | 2004-12-30 | 2006-07-06 | Shell Internationale Research Maatschappij B.V. | Process for the preparation of lower olefins from heavy wax |
| EP1907509B1 (en) * | 2005-06-29 | 2019-05-08 | W.R. Grace & Co.-Conn. | Pentasil catalyst for light olefins in fluidized catalytic units |
| KR100632571B1 (ko) * | 2005-10-07 | 2006-10-09 | 에스케이 주식회사 | 탄화수소 원료 혼합물로부터 접촉분해공정을 통해서 경질올레핀계 탄화수소 화합물을 증산하는 방법 |
-
2007
- 2007-10-26 KR KR1020070108494A patent/KR100904297B1/ko active IP Right Grant
-
2008
- 2008-09-22 CN CN200880113431.1A patent/CN101868434B/zh not_active Expired - Fee Related
- 2008-09-22 WO PCT/KR2008/005606 patent/WO2009054616A2/en active Application Filing
- 2008-09-22 EP EP08842028.6A patent/EP2215038B1/en not_active Not-in-force
- 2008-09-22 US US12/739,217 patent/US8395004B2/en not_active Expired - Fee Related
- 2008-09-22 JP JP2010530920A patent/JP5518727B2/ja active Active
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