JP2011504867A - 制御された構造及び粒子径を有するナノポーラスアルミナ系材料の製造方法及びその方法により得られたナノポーラスアルミナ - Google Patents
制御された構造及び粒子径を有するナノポーラスアルミナ系材料の製造方法及びその方法により得られたナノポーラスアルミナ Download PDFInfo
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- JP2011504867A JP2011504867A JP2010535249A JP2010535249A JP2011504867A JP 2011504867 A JP2011504867 A JP 2011504867A JP 2010535249 A JP2010535249 A JP 2010535249A JP 2010535249 A JP2010535249 A JP 2010535249A JP 2011504867 A JP2011504867 A JP 2011504867A
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- alumina
- inorganic porous
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- agent
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 87
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000000463 material Substances 0.000 title claims abstract description 31
- 239000002245 particle Substances 0.000 title claims description 35
- 238000004519 manufacturing process Methods 0.000 title abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- 238000001704 evaporation Methods 0.000 claims abstract description 18
- 239000002243 precursor Substances 0.000 claims abstract description 17
- 230000008569 process Effects 0.000 claims abstract description 14
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000003125 aqueous solvent Substances 0.000 claims abstract description 9
- 239000011541 reaction mixture Substances 0.000 claims abstract description 9
- 239000004088 foaming agent Substances 0.000 claims abstract description 6
- 239000004094 surface-active agent Substances 0.000 claims description 41
- -1 aluminum alkoxide Chemical class 0.000 claims description 18
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 230000008961 swelling Effects 0.000 claims description 9
- 239000000344 soap Substances 0.000 claims description 8
- 239000002019 doping agent Substances 0.000 claims description 7
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 claims description 6
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- WOZZOSDBXABUFO-UHFFFAOYSA-N tri(butan-2-yloxy)alumane Chemical group [Al+3].CCC(C)[O-].CCC(C)[O-].CCC(C)[O-] WOZZOSDBXABUFO-UHFFFAOYSA-N 0.000 claims description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 4
- 239000011260 aqueous acid Substances 0.000 claims description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims description 4
- 229910044991 metal oxide Inorganic materials 0.000 claims description 4
- 150000004706 metal oxides Chemical class 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical group Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 claims description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract description 9
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000011148 porous material Substances 0.000 description 47
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 28
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 20
- 230000015572 biosynthetic process Effects 0.000 description 20
- 238000003756 stirring Methods 0.000 description 16
- 239000005639 Lauric acid Substances 0.000 description 14
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 13
- 235000021355 Stearic acid Nutrition 0.000 description 13
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 13
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 13
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- 235000021314 Palmitic acid Nutrition 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 12
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 12
- 238000009826 distribution Methods 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 238000010304 firing Methods 0.000 description 8
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 7
- 239000004472 Lysine Substances 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 6
- 235000021360 Myristic acid Nutrition 0.000 description 6
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 6
- PDQICKRFOKDJCH-UHFFFAOYSA-N 6-amino-2-(dodecanoylamino)hexanoic acid Chemical compound CCCCCCCCCCCC(=O)NC(C(O)=O)CCCCN PDQICKRFOKDJCH-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910001593 boehmite Inorganic materials 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 4
- 239000004973 liquid crystal related substance Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- 229920000428 triblock copolymer Polymers 0.000 description 4
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 3
- 150000004703 alkoxides Chemical class 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 3
- 239000004064 cosurfactant Substances 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 239000013335 mesoporous material Substances 0.000 description 3
- 230000000877 morphologic effect Effects 0.000 description 3
- 239000007783 nanoporous material Substances 0.000 description 3
- 229910000480 nickel oxide Inorganic materials 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 2
- PVNIQBQSYATKKL-UHFFFAOYSA-N Glycerol trihexadecanoate Natural products CCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCC PVNIQBQSYATKKL-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- JOSJZPLSVYWPAG-UHFFFAOYSA-L dodecanoate;nickel(2+) Chemical compound [Ni+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O JOSJZPLSVYWPAG-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012847 fine chemical Substances 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
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- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 2
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- 238000001228 spectrum Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristin Chemical compound CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 2
- 238000004438 BET method Methods 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- PWKWDCOTNGQLID-UHFFFAOYSA-N [N].[Ar] Chemical compound [N].[Ar] PWKWDCOTNGQLID-UHFFFAOYSA-N 0.000 description 1
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- NDWWLJQHOLSEHX-UHFFFAOYSA-L calcium;octanoate Chemical compound [Ca+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O NDWWLJQHOLSEHX-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
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- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000010335 hydrothermal treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- HPBJPFJVNDHMEG-UHFFFAOYSA-L magnesium;octanoate Chemical compound [Mg+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O HPBJPFJVNDHMEG-UHFFFAOYSA-L 0.000 description 1
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- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000000696 nitrogen adsorption--desorption isotherm Methods 0.000 description 1
- 239000005519 non-carbonaceous material Substances 0.000 description 1
- 239000011824 nuclear material Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- VBECWDDSIMYVMN-UHFFFAOYSA-J octanoate silicon(4+) Chemical compound [Si+4].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O VBECWDDSIMYVMN-UHFFFAOYSA-J 0.000 description 1
- HDKCVDHYIIKWFM-UHFFFAOYSA-K octanoate;rhodium(3+) Chemical compound [Rh+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O HDKCVDHYIIKWFM-UHFFFAOYSA-K 0.000 description 1
- HAQNILKXKHODOO-UHFFFAOYSA-K octanoate;ruthenium(3+) Chemical compound [Ru+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O HAQNILKXKHODOO-UHFFFAOYSA-K 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
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- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/30—Preparation of aluminium oxide or hydroxide by thermal decomposition or by hydrolysis or oxidation of aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/44—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water
- C01F7/441—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by calcination
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
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Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2007/063107 WO2009068117A1 (en) | 2007-11-30 | 2007-11-30 | Method for manufacturing a nanoporous alumina based materials with controlled textural and particle size and nanoporous alumina obtained by said method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2011504867A true JP2011504867A (ja) | 2011-02-17 |
| JP2011504867A5 JP2011504867A5 (enExample) | 2011-03-31 |
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| JP2010535249A Pending JP2011504867A (ja) | 2007-11-30 | 2007-11-30 | 制御された構造及び粒子径を有するナノポーラスアルミナ系材料の製造方法及びその方法により得られたナノポーラスアルミナ |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20100310848A1 (enExample) |
| EP (1) | EP2222600A1 (enExample) |
| JP (1) | JP2011504867A (enExample) |
| CN (1) | CN101878186A (enExample) |
| WO (1) | WO2009068117A1 (enExample) |
| ZA (1) | ZA201004162B (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017214564A (ja) * | 2016-05-31 | 2017-12-07 | 延世大学校 産学協力団Ｉｎｄｕｓｔｒｙ−Ａｃａｄｅｍｉｃ Ｃｏｏｐｅｒａｔｉｏｎ Ｆｏｕｎｄａｔｉｏｎ，Ｙｏｎｓｅｉ Ｕｎｉｖｅｒｓｉｔｙ | 多孔性構造体及びその製造方法 |
| JP2023069549A (ja) * | 2021-11-05 | 2023-05-18 | 国立研究開発法人産業技術総合研究所 | ナノ複合材料およびナノ複合材料の製造方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8476187B2 (en) | 2010-01-06 | 2013-07-02 | General Electric Company | Process for preparing catalyst powder |
| WO2011113879A1 (en) | 2010-03-17 | 2011-09-22 | Nanologica Ab | Enhanced folic acid fluorescent material, multifluorescent porous compositions of matter and potential applications thereof. |
| CN102219242B (zh) * | 2010-04-15 | 2013-01-09 | 中国石油化工股份有限公司 | 制备介孔氧化铝的方法 |
| CN104971779B (zh) * | 2014-04-09 | 2017-08-22 | 中国石油化工股份有限公司 | 一种加氢催化剂及其应用 |
| CN104971693B (zh) * | 2014-04-09 | 2017-08-22 | 中国石油化工股份有限公司 | 一种含有非离子型表面活性剂的氧化铝成型物及其制备和应用 |
| CN110639491B (zh) * | 2018-06-26 | 2022-09-16 | 宁波市雨辰环保科技有限公司 | 一种用于剧毒废水无害化处理的催化剂及其制备方法和应用 |
| DK3894857T3 (da) * | 2019-04-15 | 2022-11-07 | Nanologica Ab | Tomme porøse partikler til anvendelse ved behandling, forebyggelse og/eller udskydelse af degeneration af neurodegenerative sygdomme, neuroner og glia |
| CN110433806A (zh) * | 2019-07-19 | 2019-11-12 | 福州大学 | 一种钴-铝复合氧化物催化剂及其制备方法和应用 |
| CN112744847B (zh) * | 2019-10-31 | 2023-03-10 | 中国石油化工股份有限公司 | 一种铝溶胶的生产工艺和该生产工艺制得的铝溶胶 |
| CN112744848B (zh) * | 2019-10-31 | 2023-03-10 | 中国石油化工股份有限公司 | 铝溶胶的生产工艺和该生产工艺制得的铝溶胶 |
| CN113213517B (zh) * | 2021-04-09 | 2023-04-07 | 珠海复旦创新研究院 | 一种介孔氧化铝微球及其制备方法 |
| CN113769723A (zh) * | 2021-09-18 | 2021-12-10 | 北京化工大学 | 一种低密度球形氧化铝及其制备方法 |
| CN114768784B (zh) * | 2022-02-28 | 2024-01-09 | 河南师范大学 | 一种片状氧化铝-炭复合材料的制备方法及应用 |
| CN114768756B (zh) * | 2022-02-28 | 2024-01-09 | 河南师范大学 | 一种厚度可控的氧化铝/炭纳米片及其在重金属吸附上的应用 |
| CN119500096B (zh) * | 2024-10-11 | 2025-09-30 | 中南大学 | 铈改性介孔铝及其制备方法和应用 |
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| US5731261A (en) * | 1995-06-01 | 1998-03-24 | Enichem S.P.A. | Process for the preparation of mixed porous silica-alumina oxides in a spherical form |
| JPH1111939A (ja) * | 1997-06-19 | 1999-01-19 | Agency Of Ind Science & Technol | アルミナ系調湿材料の製造方法 |
| JP2005015323A (ja) * | 2003-06-06 | 2005-01-20 | National Institute Of Advanced Industrial & Technology | 多孔性アルミナ結晶性粒子及びその製造方法 |
| WO2005092794A1 (ja) * | 2004-03-26 | 2005-10-06 | Japan Science And Technology Agency | 多孔質アルミナ粒子、その製造方法、およびその使用方法 |
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| ATE83222T1 (de) * | 1988-02-11 | 1992-12-15 | Vaw Ver Aluminium Werke Ag | Verfahren zur herstellung von fuellstoffen und flammschutzmitteln auf der basis von aluminiumhydroxid in form von hydrargillit. |
| US5840271A (en) * | 1996-02-09 | 1998-11-24 | Intevep, S.A. | Synthetic material with high void volume associated with mesoporous tortuous channels having a narrow size distribution |
| US5863515A (en) * | 1996-02-20 | 1999-01-26 | California Institute Of Technology | Mesoporous alumina and process for its preparation |
| US6027706A (en) * | 1998-05-05 | 2000-02-22 | Board Of Trustees Operating Michigan State University | Porous aluminum oxide materials prepared by non-ionic surfactant assembly route |
| DE19843241A1 (de) * | 1998-09-11 | 2000-03-16 | Inst Angewandte Chemie Berlin | Mesoporöse Aluminiumoxide und Verfahren zur Herstellung |
| US7172770B2 (en) * | 2001-02-19 | 2007-02-06 | Board Of Regents, The University Of Texas System | Mesoporous compositions for use in drug delivery |
| WO2004014799A1 (en) * | 2002-08-12 | 2004-02-19 | Postech Foundation | Method for manufacturing mesoporous alumina molecular sieve and alumina nanotube and use of the alumina nanotube for storage of h2 |
| JP5054921B2 (ja) * | 2004-02-05 | 2012-10-24 | 太陽化学株式会社 | 多孔質シリカを含有する吸着能付与剤 |
| EP1627682A1 (en) * | 2004-08-20 | 2006-02-22 | Nanologica AB | Method for manufacturing a nanoporous framework and a nanoporous framework thus produced |
-
2007
- 2007-11-30 EP EP07857237A patent/EP2222600A1/en not_active Withdrawn
- 2007-11-30 US US12/745,164 patent/US20100310848A1/en not_active Abandoned
- 2007-11-30 CN CN2007801017351A patent/CN101878186A/zh active Pending
- 2007-11-30 WO PCT/EP2007/063107 patent/WO2009068117A1/en not_active Ceased
- 2007-11-30 JP JP2010535249A patent/JP2011504867A/ja active Pending
-
2010
- 2010-06-10 ZA ZA2010/04162A patent/ZA201004162B/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5731261A (en) * | 1995-06-01 | 1998-03-24 | Enichem S.P.A. | Process for the preparation of mixed porous silica-alumina oxides in a spherical form |
| JPH1111939A (ja) * | 1997-06-19 | 1999-01-19 | Agency Of Ind Science & Technol | アルミナ系調湿材料の製造方法 |
| JP2005015323A (ja) * | 2003-06-06 | 2005-01-20 | National Institute Of Advanced Industrial & Technology | 多孔性アルミナ結晶性粒子及びその製造方法 |
| WO2005092794A1 (ja) * | 2004-03-26 | 2005-10-06 | Japan Science And Technology Agency | 多孔質アルミナ粒子、その製造方法、およびその使用方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017214564A (ja) * | 2016-05-31 | 2017-12-07 | 延世大学校 産学協力団Ｉｎｄｕｓｔｒｙ−Ａｃａｄｅｍｉｃ Ｃｏｏｐｅｒａｔｉｏｎ Ｆｏｕｎｄａｔｉｏｎ，Ｙｏｎｓｅｉ Ｕｎｉｖｅｒｓｉｔｙ | 多孔性構造体及びその製造方法 |
| JP2023069549A (ja) * | 2021-11-05 | 2023-05-18 | 国立研究開発法人産業技術総合研究所 | ナノ複合材料およびナノ複合材料の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20100310848A1 (en) | 2010-12-09 |
| WO2009068117A1 (en) | 2009-06-04 |
| ZA201004162B (en) | 2011-02-23 |
| CN101878186A (zh) | 2010-11-03 |
| EP2222600A1 (en) | 2010-09-01 |
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