JP2011228500A - Development processing method and development processing apparatus - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a development processing method and development processing apparatus for uniformizing development processing, reducing a pattern collapse by developing solution or generation of a development loading effect, and capable of acquiring a high-quality substrate without variations in size in the surface to be processed.SOLUTION: In a development processing method for an exposure-treated photomask substrate 1, the substrate is tilted at an angle of over 0° and less than 90° to a horizontal plane, the tilting direction of the substrate during the development of the same being successively controlled to vary by 360° in a rotational direction of vertical axis passing through the center of the substrate 1 during the development of the substrate. A nozzle device 5 formed by disposing multiple nozzles 7 on a flat plate-shaped nozzle holder 6 is used and the developing solution is fed from each nozzle 7 of the nozzle device 5 to form a developing solution paddle on the substrate and at the same time, the amount of the developing solution fed from the nozzle 7 is individually controlled.

Description

The present invention relates to a development processing method and a development processing apparatus for performing development processing by supplying a developing solution to a photomask substrate subjected to exposure processing.

  In the photolithographic process of the photomask, a series of processes are performed in which a resist solution is applied to a cleaned substrate to form a resist film, drawn on the resist film in a predetermined pattern, and developed. Drawing is performed with a laser or an electron beam. The development processing is performed by supplying a predetermined processing liquid while rotating the substrate in a plane by using a liquid processing apparatus generally called a spinner type.

  In recent years, semiconductor circuits to be formed have been miniaturized due to advances in photolithography technology, and there is a tendency to form patterns whose line width is shorter (smaller) than the exposure wavelength. Accordingly, there is a strict demand for uniformity of development processing and pattern resolution within the surface of the substrate to be processed.

  Therefore, for example, the exposed substrate is set on a spin chuck or the like and fixed, and a developing solution is deposited on the substrate, a paddle is formed to advance the developing reaction, and after a predetermined time has passed, the substrate is rotated. At the same time, a paddle development method is adopted in which the supply of the rinse liquid is started to shake off the developer and the rinse liquid, and then the rinse liquid supply is stopped, the substrate is rotated at high speed, and spin drying is performed.

  In such a paddle development method, since the developer is uniformly applied and supplied, there is a merit that variation in the pattern dimension in the surface is small and the pattern is not easily tilted, but there is a reaction reaction with the resist during the development process. Since the developer containing the product stays on the substrate, a development loading effect in which the development speed varies depending on the exposure density occurs, and there is a problem that the size varies due to the effect.

  In order to solve this problem, a method of constantly rotating the substrate and removing the developer by centrifugal force has been devised (see Patent Document 1). However, since the rotation always generates a flow in a specific direction, the pattern tends to collapse, and the old developer always moves from the center to the outside.

  As a method for efficiently stirring the developer, there is a method in which the developer is applied from above the paddle developer using a spray nozzle, but there is a risk that the pattern may collapse due to the pressure of the developer from the fan nozzle.

  Further, as a method for recovering the developer from the substrate, a method is known in which the developer on the substrate is caused to flow down by placing the substrate in an oblique posture (see Patent Document 2).

  However, in this method, since the developing solution always flows in only one direction, there is a concern that the development may be biased.

JP 2004-022764 A JP 2003-086488 A

  As described above, in the related art, there is a problem that the pattern is likely to collapse and development bias is likely to occur.

  In order to solve such a problem, the present invention tilts the substrate and changes the direction of the tilt by 360 degrees to stir and remove the developer without rotating the substrate. A development processing method and a development processing apparatus capable of obtaining a high-quality substrate free from dimensional variations in the processing surface by suppressing occurrence of pattern collapse and development bias due to a developer by making the thickness uniform. With the goal.

  In order to solve the above problems, the invention of claim 1 is a development processing method for a photomask substrate subjected to exposure processing, wherein the substrate is inclined at an angle not exceeding 90 degrees and not reaching 90 with respect to a horizontal plane, In the development processing method, the development is performed while continuously performing the control in which the inclination direction changes 360 degrees in the direction around the vertical axis passing through the center of the substrate during the development of the substrate.

  A second aspect of the present invention is the development processing method according to the first aspect, wherein a nozzle device in which a plurality of nozzles are disposed on a flat nozzle holding member is disposed above a substrate, and each nozzle of the nozzle device is disposed. The developing solution is supplied to form a developer paddle on the substrate, and the amount of the developer supplied from the nozzle is individually controlled.

  A third aspect of the present invention is the development processing method according to the second aspect, wherein the positions of the plurality of nozzles of the nozzle device always fluctuate within a distance within a nozzle arrangement interval. .

  According to a fourth aspect of the present invention, there is provided a development processing apparatus for developing a photomask substrate subjected to exposure processing, comprising a substrate holding unit for holding the substrate, and the substrate holding unit has an angle of 0 degrees with respect to a horizontal plane. The substrate can be tilted at an angle not exceeding 90 degrees, and the tilting direction can be changed by 360 degrees in the direction around the vertical axis passing through the center of the substrate holding unit. The substrate holding unit holds the substrate and develops the substrate. The development processing apparatus is characterized in that the substrate is tilted with respect to the horizontal plane by the operation of the substrate holding portion, and the tilt direction is changed by 360 degrees in the direction around the vertical axis passing through the center of the substrate.

  According to the present invention, by changing the tilt direction of the substrate, the developer can be stirred in all directions without rotating the substrate itself, and the removal can be performed efficiently. Further, since the positional relationship between the nozzle and the substrate in plan view does not change, the occurrence of development bias can be suppressed by individually controlling the amount of the developer discharged from each nozzle.

1 is a front view showing a development processing apparatus according to an embodiment of the present invention. The front view which shows a state when the substrate holding part of the developing device is inclined. The bottom view which shows the nozzle apparatus in the development processing apparatus. The front view which shows the state at the time of the image development process by the image development processing apparatus.

  Hereinafter, an embodiment of the present invention will be described with reference to the drawings.

  FIG. 1 shows a development processing apparatus according to an embodiment of the present invention, and the development processing apparatus includes a substrate holding unit 2 for holding a photomask substrate 1 after exposure processing. This board | substrate holding part 2 comprises flat form, and is supported by the three support | pillars 3 arrange | positioned at the lower surface side. In the figure, the third support column does not appear as a shadow of the other support columns 3.

  The substrate 1 on which the pattern is drawn is set on the substrate holding unit 2 by the transfer device. A pin 4 stands on an edge on the upper surface side of the substrate holding part 2, and has a structure in which the substrate 1 does not move or fall even when the substrate holding part 2 is inclined.

  The substrate holding unit 2 on which the substrate 1 is set is supported by three support columns 3 whose heights are controlled, and a ball joint is provided at the contact point between the substrate holding unit 2 and each support column 3, and the ball The substrate holding part 2 and each support column 3 are coupled via a joint, and by controlling the height of each support column 3, the angle of the substrate holding part 2 and the direction of the inclination thereof can be changed. . That is, by changing the height of the three support columns 3 in conjunction with each other, the angle of inclination of the substrate holder 2 with respect to the horizontal plane and the direction of the inclination are controlled. After the substrate 1 is set on the substrate holding part 2, the substrate holding part 2 is inclined at a set angle. The angle of inclination is arbitrarily set within a range that does not exceed 90 degrees and does not reach 90 degrees with respect to the horizontal plane.

  FIG. 2 shows a state in which the angle and direction of the inclination of the substrate 1 are changed by changing the height of each column 3. The height of the column 3 is controlled by a lifting device such as a ball screw. By changing the height of the three support columns 3 in conjunction with each other, the tilt angle of the substrate holding unit 2 is set to a predetermined angle, and further, the three support columns 3 are maintained in a state where the tilt angle is kept constant. When the height of 3 is changed in conjunction with the rotation, the substrate holding unit 2 is controlled to rotate 360 degrees in the direction around the vertical axis passing through the center of the substrate holding unit 2 without rotating. During the development, the direction of the inclination of the substrate holder 2 is controlled to continuously change 360 degrees. The speed for changing the direction of the inclination is arbitrarily set.

  FIG. 3 shows a nozzle device 5 for supplying a developing solution to the substrate 1. The nozzle device 5 has a plurality of nozzles 7 arranged in a matrix on the lower surface side of a square plate-like nozzle holder 6. Set up. For example, as shown in FIG. 3, the nozzle holder 6 has a total of 121 nozzles 11 of 11 × 11 arranged in a matrix at intervals of 15.4 mm. A developer is discharged from each nozzle 7.

  As shown in FIG. 4, the nozzle device 5 is disposed horizontally above the substrate 1 held by the substrate holding unit 2. The nozzle device 5 is arranged so that the center nozzle 7 of the nozzle holder 6 and the center of the substrate 1 coincide.

  A developer is discharged from each nozzle 7 toward the surface of the substrate 1. At this time, it is desirable to provide a buffer member in the middle so that the developer discharged from each nozzle 7 does not directly hit the substrate 1 and supply it while touching the buffer member. By providing the buffer member, the developer can be supplied to a wider area on the substrate 1 without being biased. In the figure, the buffer member is omitted.

  In addition, the position of the nozzle 7 can always be moved by a distance within the arrangement pitch interval of the nozzles 7, and the structure in which the location where the developer directly hits can be changed. With this configuration, it is possible to prevent the developer from continuing to hit the same position on the substrate 1 and to suppress the occurrence of bias in development due to the difference in development between the place where the developer directly hits and the place where the developer does not hit. The nozzle 7 may be moved either by moving the nozzle 7 alone or by moving the nozzle holder 6. Further, the place where the developer directly hits may be changed by always changing the angle of the nozzle 7 alone or the nozzle holder 6 with respect to the substrate 1.

  At the time of developing the substrate 1, the substrate holding unit 2 is not rotated, and the substrate holding unit 2 is operated so as to be inclined at a predetermined angle and the direction of the inclination is continuously changed by 360 degrees. The positions in plan view of the substrate 1 and the nozzles 7 on the substrate holding unit 2 are substantially the same regardless of the change in the tilt direction of the substrate 1, and when uneven development occurs at a specific position of the substrate 1. The amount of the developer discharged from the nozzle 7 is individually controlled and adjusted. In particular, when a concentric tendency occurs, adjustment is performed by changing the amount of the developer discharged from the central nozzle 7 and the amount of the developer discharged from the peripheral nozzle 7. When the drawing density varies greatly in the plane, the amount of the phenomenon liquid may be changed in advance according to the layout. Further, the amount of the developer may be changed in conjunction with the change in the inclination direction of the substrate 1.

  The developer on the substrate 1 is stirred without being biased in one direction when the substrate 1 tilts in any direction. The old developer is expelled from the edge by tilting the substrate 1 and supplying a new developer, and the developer is efficiently stirred and removed.

  Rinse can be performed without unevenness in the surface by applying a rinsing liquid after the development using the same technique as that for development.

  By processing the photomask substrate that has been exposed using the development processing method of the present invention, the developer can be efficiently stirred and removed, and the amount of the developer is partially adjusted. As a result, development unevenness can be reduced, and in the paddle development, the development loading effect can be suppressed, the pattern collapse hardly occurs, and a highly accurate photomask with little dimensional variation can be obtained.

DESCRIPTION OF SYMBOLS 1 ... Board | substrate 2 ... Board | substrate holding part 3 ... Support | pillar 4 ... Pin 5 ... Nozzle device 6 ... Nozzle holding body 7 ... Nozzle

Claims (4)

  A method for developing a photomask substrate subjected to exposure processing, wherein the substrate is tilted at an angle that does not exceed 90 degrees and does not reach 90 degrees with respect to a horizontal plane, and the tilting direction passes through the center of the substrate during development of the substrate. A development processing method characterized in that development is performed while continuously performing control that changes 360 degrees around the vertical axis.   2. The development processing method according to claim 1, wherein a nozzle device in which a plurality of nozzles are arranged on a flat nozzle holder is arranged above the substrate, and a developer is supplied from each nozzle of the nozzle device. A developing method comprising forming a developer paddle on a substrate and individually controlling the amount of developer supplied from the nozzle.   The development processing method according to claim 2, wherein the positions of the plurality of nozzles of the nozzle device always fluctuate within a distance within a nozzle arrangement interval.   A development processing apparatus that performs development processing on a photomask substrate that has been subjected to exposure processing, and includes a substrate holding unit that holds the substrate, and the substrate holding unit does not exceed 90 degrees and does not reach 90 degrees with respect to a horizontal plane And the tilting direction can be changed by 360 degrees in the direction around the vertical axis passing through the center of the substrate holder. The substrate holder holds the substrate, and the substrate is held during the development of the substrate. The development processing apparatus is characterized in that it is tilted with respect to a horizontal plane and the tilt direction is changed 360 degrees around a vertical axis passing through the center of the substrate.

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