JP2011219889A - Fabric woven from reinforced fiber yarn and method for manufacturing the same - Google Patents
Fabric woven from reinforced fiber yarn and method for manufacturing the same Download PDFInfo
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本発明は、方向指示糸条としての補助糸をたて糸又はよこ糸の一方のみに配置し、織物のたて及びよこ方向を容易に認識できる強化繊維糸織物とその製造方法に関する。 The present invention relates to a reinforcing fiber yarn woven fabric in which auxiliary yarns as direction indicating yarns are arranged only in one of a warp yarn and a weft yarn, and the warp direction and the weft direction of the fabric can be easily recognized, and a method for manufacturing the same.
強化繊維、例えば比強度・比弾性率等の機械的特性に優れる炭素繊維は、織物、織物プリプレグや一方向プリプレグ等の中間材料に加工され、これらが積層されて、マトリックス樹脂材料が含浸され成形された炭素繊維強化プラスチックは広い分野で使用されている。従来のたて糸・よこ糸ともに炭素繊維糸が使われた二方向性の炭素繊維織物や、織物プリプレグは、外観上、たて方向とよこ方向とを見分けることが難しい。
そのため、成形にあたって、織物、織物プリプレグを裁断して、その裁断片を複数枚積層するとき、織物片のたて・よこの方向性を認識することができず、予め決められた積層構成を誤ることがある。
Reinforcing fibers, such as carbon fibers with excellent mechanical properties such as specific strength and elastic modulus, are processed into intermediate materials such as woven fabrics, woven prepregs and unidirectional prepregs, and these are laminated and impregnated with a matrix resin material. Carbon fiber reinforced plastics are used in a wide range of fields. Conventionally, it is difficult to distinguish the warp direction from the weft direction in bi-directional carbon fiber fabrics and fabric prepregs in which carbon fiber yarns are used for both warp and weft.
Therefore, when cutting a fabric or a fabric prepreg and laminating a plurality of the cut pieces, it is not possible to recognize the direction of the warp and the width of the fabric piece, and the predetermined laminated configuration is wrong. Sometimes.
このような問題を解決するために、織物、織物プリプレグを裁断した後でも容易に織物片の方向が認識できるように補助糸を配置するなどの方法が従来も行われてきた。しかしながら、折角、補助糸を配置しても補助糸が強化繊維糸の中央からずれたり、或いは強化繊維糸に隠れて見え難くなることがあり、補助糸を強化繊維糸幅の中央に確実に表出させることが強く望まれていた。 In order to solve such a problem, a method of arranging an auxiliary yarn so that the direction of the fabric piece can be easily recognized even after cutting the fabric or the fabric prepreg has been conventionally performed. However, even if the auxiliary yarn is arranged, the auxiliary yarn may deviate from the center of the reinforcing fiber yarn or may be difficult to see because it is hidden behind the reinforcing fiber yarn, and the auxiliary yarn is surely displayed at the center of the reinforcing fiber yarn width. It was strongly desired to make it come out.
そこで、補助糸を目どめ剤として強化繊維糸に融着させて、たて糸又はよこ糸の上で、かつ糸幅のほぼ中央に配置した強化繊維糸織物が、例えば特開平10−317247号公報(特許文献1)に記載されている。この織物によれば、たて糸又はよこ糸の上で糸幅のほぼ中央に目どめ剤である補助糸が融着され、糸幅のほぼ中央からずれることはない。しかし、強化繊維糸と補助糸とが融着することにより、織物のせん断変形性能が低下し、フィット性が得られず、曲面等に沿い難い織物となる。ここで、目どめ剤としての材料として、特許文献1には低融点熱可塑性ポリマーを挙げられており、目どめ剤としての補助糸には低融点熱可塑性ポリマーからなる補助糸、或いはガラス繊維糸の回りに低融点熱可塑性ポリマーからなる目どめ剤を巻回した補助糸が使われることが記載されている。 Therefore, a reinforcing fiber yarn woven fabric obtained by fusing the auxiliary yarn as a sizing agent to the reinforcing fiber yarn and arranged on the warp yarn or the weft yarn and substantially at the center of the yarn width is disclosed in, for example, Japanese Patent Application Laid-Open No. 10-317247 ( Patent Document 1). According to this woven fabric, the auxiliary yarn which is a setting agent is fused on the warp yarn or the weft yarn at the approximate center of the yarn width and does not deviate from the approximate center of the yarn width. However, when the reinforcing fiber yarn and the auxiliary yarn are fused, the shear deformation performance of the fabric is lowered, the fitting property is not obtained, and the fabric is difficult to follow along the curved surface. Here, as a material as a squeezing agent, Patent Document 1 mentions a low-melting point thermoplastic polymer, and the auxiliary yarn as a squeezing agent is an auxiliary yarn made of a low-melting point thermoplastic polymer, or glass. It is described that an auxiliary yarn in which a clogging agent made of a low melting point thermoplastic polymer is wound around the fiber yarn is used.
このように、従来、裁断した後も容易に織物の方向が認識でき、且つ織物片を貼り付けながら成形する繊維強化プラスチックの曲面体の成形などに特に適した強化繊維糸織物の開発が強く要望されていた。
したがって本発明の課題は、強化繊維糸を用いた強化繊維糸織物において、該織物を裁断して貼り合わせながら曲面を有する複合成形体を製作する際に、織物の方向を容易に認識でき、所定の積層構成が確実に形成され、所望の形状をもつ繊維強化プラスチックが成形できるドレープ性に優れた強化繊維糸織物を提供することにある。
Thus, there has been a strong demand for the development of a reinforced fiber yarn fabric that can easily recognize the direction of the fabric after cutting and is particularly suitable for forming a curved surface of a fiber reinforced plastic that is molded while a fabric piece is attached. It had been.
Accordingly, an object of the present invention is to make it possible to easily recognize the direction of a woven fabric in a reinforcing fiber yarn woven fabric using reinforcing fiber yarns when manufacturing a composite molded body having a curved surface while cutting and bonding the woven fabric. It is an object of the present invention to provide a reinforced fiber yarn fabric excellent in drapability in which a laminated structure is reliably formed and a fiber reinforced plastic having a desired shape can be formed.
上記課題を解決するために、本発明の強化繊維糸織物は、強化繊維糸からなるたて糸とよこ糸が目止めされずに互いに交錯した強化繊維糸織物であって、非目どめ材からなる補
助糸が、選択されたたて糸又はよこ糸の上で糸長手方向に線状に配置され、方向指示糸条とされる。ここで、留意すべきは前記補助糸が、例えば成形時におけるマトリックス樹脂の熱硬化温度によっても溶融しないガラス繊維などの非目どめ材料から構成されている点にある。
In order to solve the above-mentioned problems, the reinforcing fiber yarn fabric of the present invention is a reinforcing fiber yarn fabric in which warp yarns and weft yarns made of reinforcing fiber yarns are interlaced with each other without being stopped, and is made of an auxiliary material made of non-awakening material. The yarn is linearly arranged in the longitudinal direction of the yarn on the selected warp yarn or weft yarn to form a direction indicating yarn. Here, it should be noted that the auxiliary yarn is made of a non-agitating material such as glass fiber that does not melt even at the thermosetting temperature of the matrix resin during molding.
好ましい態様によれば、補助糸は選択されたたて糸又はよこ糸の上を糸幅のほぼ中央に配置されており、30〜100mm間隔にある、たて糸又はよこ糸の上を糸長手方向に線状に配置されている。また、強化繊維糸が炭素繊維糸であることが望ましい。 According to a preferred embodiment, the auxiliary yarn is arranged on the selected warp or weft in the approximate center of the yarn width, and is arranged linearly in the longitudinal direction of the warp or weft at intervals of 30 to 100 mm. Has been. The reinforcing fiber yarn is preferably a carbon fiber yarn.
強化繊維糸織物の製造にあたっては、上下二段にメールを有するヘルドを使用し、同ヘルドの上段から非目どめ材からなり方向指示糸条となる補助糸を供給し、下段から強化繊維糸を供給し、補助糸を強化繊維糸の上で糸幅のほぼ中央に配置させるようにすることが望ましい。 In the manufacture of reinforced fiber yarn fabrics, healds with mails in the upper and lower stages are used, auxiliary yarns that are made of non-awakening material and serve as direction indicating yarns are supplied from the upper stage of the healds, and reinforcing fiber threads are supplied from the lower stage. It is desirable to supply the auxiliary yarn so that the auxiliary yarn is arranged approximately at the center of the yarn width on the reinforcing fiber yarn.
補助糸の配置はおよそ30〜100mm間隔とすることが好ましい。30mm未満だと織物のせん断変形性能が低下し、フィット性のない織物になってしまうだけでなく、補助糸の仕掛け作業が増え、製織準備作業性が悪くなる。間隔が100mmより広いと、小さく裁断する際に方向の認識ができなくなることがある。 The auxiliary yarns are preferably arranged at intervals of approximately 30 to 100 mm. If it is less than 30 mm, the shear deformation performance of the woven fabric will be reduced, resulting in a non-fit woven fabric, and the auxiliary yarn setting work will increase, resulting in poor weaving preparation workability. If the interval is larger than 100 mm, the direction may not be recognized when cutting to a small size.
補助糸は上下二段にメールをもつヘルドを使用し供給する。従来は1つのメールを持つヘルドで強化繊維糸と補助糸を引き揃えて供給するので、補助糸が隣り合う強化繊維糸との間にずれて入り込み外見からは認識し難くなってしまう。 Auxiliary yarns are supplied using healds with mails in the upper and lower two stages. Conventionally, since the reinforcing fiber yarn and the auxiliary yarn are supplied by being aligned with a heald having one mail, the auxiliary yarn is shifted between adjacent reinforcing fiber yarns, and it is difficult to recognize from the appearance.
本発明の強化繊維糸織物は、方向指示糸条としての補助糸が強化繊維糸の上で糸幅のほぼ中央に配置されているため、前記強化繊維糸織物またはそのプリプレグを所要の大きさに裁断して、その裁断片を曲面に沿って複数枚貼り合わせながら曲面を有する複合成形体を作製するにあたり、強化繊維糸織物の方向が容易に認識できるようになり、所定の積層構成が確実に得られる。その結果、複雑な形状をもつ複合成形体であっても所望の機械的特性が得られる。 In the reinforcing fiber yarn fabric of the present invention, since the auxiliary yarn as the direction indicating yarn is arranged on the reinforcing fiber yarn at approximately the center of the yarn width, the reinforcing fiber yarn fabric or its prepreg is sized to a required size. When producing a composite molded body having a curved surface while cutting and bonding a plurality of the cut pieces along the curved surface, the direction of the reinforcing fiber yarn fabric can be easily recognized, and the predetermined laminated structure is ensured. can get. As a result, desired mechanical characteristics can be obtained even with a complex molded body having a complicated shape.
以下に、本発明の強化繊維糸織物及び補助糸の配置の望ましい実施の形態の一例について、図面を参照しながら説明する。
図1は補助糸の配置例を示している。強化繊維糸からなるたて糸a1、a2、a3、a4、a5、・・・及びよこ糸b1、b2、b3、b4、b5、・・・からなる強化繊維糸織物は、たて糸a1、a2の2本とよこ糸b1、b2の2本から構成される部分が一つの完成された織物組織をなし、そのたて糸の任意の箇所に補助糸3を配置させたものである。
Below, an example of desirable embodiment of arrangement | positioning of the reinforcing fiber yarn fabric and auxiliary yarn of this invention is demonstrated, referring drawings.
FIG. 1 shows an example of the arrangement of auxiliary yarns. Reinforcing fiber yarns made of warp yarns a1, a2, a3, a4, a5,... And weft yarns b1, b2, b3, b4, b5,. A portion composed of the two weft yarns b1 and b2 constitutes one completed woven fabric structure, and the auxiliary yarn 3 is arranged at an arbitrary position of the warp yarn.
図2は補助糸を供給するヘルドのメール部の斜視図である。メール2は上下二段に形成されている。補助糸3は、上段のメール2aを通して、下段のメール2bに通された強化繊維強化繊維糸1の糸幅のほぼ中央に配置する。
補助糸3は方向指示糸条のため、全てのたて糸に供給する必要がなく、小さく裁断して
も織物の方向が認識できる30〜100mmピッチの範囲で配置する。
FIG. 2 is a perspective view of the mail portion of the heald that supplies the auxiliary yarn. The
Since the auxiliary yarn 3 is a direction indicating yarn, it is not necessary to supply it to all the warp yarns, and the auxiliary yarn 3 is arranged within a range of 30 to 100 mm pitch in which the direction of the fabric can be recognized even if it is cut into small pieces.
以下、実施例をもって本発明を具体的に説明する。
なお、以下の実施例では、たて糸に補助糸を添設する例を挙げているが、よこ糸に補助糸を添設してもよい。この種の強化繊維糸織物は、例えばレピア織機を使って製織される。よこ入れは、レピア織機の図示せぬよこ入れ装置により行われる。このよこ入れ装置は、通常、一対のレピアホイールにより駆動されるレピアバンドの端部によこ糸受け渡しヘッドと受け取りヘッドとが対向して固設されており、よこ糸は互いに接離方向に往復動する受け渡しヘッドと受け取りヘッドとの間で受け渡しがなされて、たて糸間に形成されるよこ糸挿入開口に挿入される。前記補助糸をよこ糸上に添設するときは、前記よこ入れ装置のよこ糸受け渡しヘッドの後退限位置の近傍であって、よこ糸供給路の糸幅方向中央部の上方に補助糸ガイドを配置し、該補助糸ガイドを介してよこ糸上に補助糸を供給するようにすればよい。他の種類の織機にあっても、前述と同様に、よこ入れ装置のよこ糸供給部の直上に補助糸ガイドを配置して、補助糸の供給を行うことができる。
Hereinafter, the present invention will be specifically described with reference to examples.
In the following embodiments, an example in which an auxiliary yarn is attached to the warp yarn is given, but an auxiliary yarn may be attached to the weft yarn. This type of reinforcing fiber yarn fabric is woven using, for example, a rapier loom. The weft insertion is performed by a not-shown weft insertion device of a rapier loom. In this weft insertion device, a weft yarn delivery head and a receiving head are usually fixed opposite to each other at the end of a rapier band driven by a pair of rapier wheels, and the weft yarn reciprocates in a contact and separation direction. And the receiving head are inserted into a weft insertion opening formed between the warp yarns. When the auxiliary yarn is attached on the weft yarn, an auxiliary yarn guide is disposed in the vicinity of the retreat limit position of the weft delivery head of the weft insertion device and above the center in the yarn width direction of the weft yarn supply path, The auxiliary yarn may be supplied onto the weft yarn through the auxiliary yarn guide. Even in other types of looms, as described above, an auxiliary yarn guide can be disposed immediately above the weft supply portion of the weft insertion device to supply the auxiliary yarn.
補助糸3として目どめ材料が使われていないため、たて糸a1、a2、a3、a4、a5、・・・及びよこ糸b1、b2、b3、b4、b5、・・・は硬直化せず、得られる強化繊維糸織物は全てドレープ性に優れている。 Since no squeezing material is used as the auxiliary yarn 3, the warp yarns a1, a2, a3, a4, a5,... And the weft yarns b1, b2, b3, b4, b5,. All the reinforcing fiber yarn fabrics obtained are excellent in drape.
フィラメント数が6000本からなる強化繊維糸である炭素繊維糸(三菱レイヨン(株)製パイロフィルTR50S 6L)をたて糸とよこ糸とした。補助糸としてガラス繊維(ECE225 1/2 4.4S:日本電気硝子(株)製ECE225 1/0 1.0Zの2本撚り4.4回/25mm品)を用いた。この補助糸は、通常のヘルドのメールを通して、およそ50mm間隔でたて糸上面の糸幅方向中央部に引き揃えた状態で供給し、織密度がたて・よこ共に3.5本/cm、炭素織物目付が288g/m2 の平織りを製織した。
得られた織物を観察したところ、補助糸が炭素繊維糸の上に配置されている部分と隣り合うたて糸の間にずれている部分とが見られたものの、ドレープ性が良好で取り扱いやすい強化繊維糸織物であった。
Carbon fiber yarns (Pyrofil TR50S 6L manufactured by Mitsubishi Rayon Co., Ltd.), which are reinforcing fiber yarns having 6,000 filaments, were used as warp yarns and weft yarns. Glass fiber (ECE225 1/2 4.4S: ECE225 1/0 1.0Z double twisted 4.4 times / 25 mm product manufactured by Nippon Electric Glass Co., Ltd.) was used as the auxiliary yarn. This auxiliary yarn is supplied through a normal heald mail in a state of being aligned at the center of the upper surface of the warp yarn at an interval of about 50 mm, and the weave density is 3.5 yarns / cm for both warp and weft. A plain weave with a basis weight of 288 g / m 2 was woven.
Observation of the resulting woven fabric revealed that a portion of the auxiliary yarn arranged on the carbon fiber yarn and a portion displaced between the adjacent warp yarns were reinforced, but the drapeability was good and easy to handle. It was a yarn fabric.
実施例1と同じたて糸とよこ糸の、よこ糸の給糸位置の上方に補助糸を供給するためのガイドを設け、補助糸をよこ糸の上に引き揃えながら、織密度がたて・よこ共に3.5本/cm、炭素織物目付304g/m2 の平織りを製織した。
得られた織物を観察したところ、補助糸は全てのよこ糸の上に配置され、織物のよこ方向を容易に認識できた。
2. A guide for supplying the auxiliary yarn above the weft supply position of the same warp and weft as in Example 1 is provided, and the weave density is adjusted for the warp and the weft while aligning the auxiliary yarn on the weft. A plain weave with 5 pieces / cm and a carbon fabric basis weight of 304 g / m 2 was woven.
When the obtained woven fabric was observed, the auxiliary yarn was arranged on all the weft yarns, and the weft direction of the woven fabric could be easily recognized.
補助糸のガラス繊維3を上下二段にメールを有するヘルドの上段から供給し、たて糸を下段から供給した以外は実施例1と同様に製織した。
得られた織物を観察したところ、補助糸はたて糸幅のほぼ中央に配置され、織物のたて方向を容易に認識できた。
Weaving was performed in the same manner as in Example 1 except that the glass fiber 3 of the auxiliary yarn was supplied from the upper stage of the heald having the mail in two upper and lower stages, and the warp was supplied from the lower stage.
When the obtained woven fabric was observed, the auxiliary yarn was arranged at the center of the warp yarn width, and the warp direction of the woven fabric could be easily recognized.
補助糸のガラス繊維を、およそ200mm間隔でたて糸上に供給した以外は実施例3と同様に製織した。
得られた織物を観察したところ、補助糸はたて糸幅のほぼ中央に配置され、織物のたて方向を容易に認識できた。しかしながら、この炭素繊維織物を100mm角に裁断したところ、補助糸が配置されていない炭素繊維織物ができてしまい、織物片の方向を認識する
ことができなかった。
Weaving was performed in the same manner as in Example 3 except that the glass fiber of the auxiliary yarn was supplied onto the warp yarn at intervals of approximately 200 mm.
When the obtained woven fabric was observed, the auxiliary yarn was arranged at the center of the warp yarn width, and the warp direction of the woven fabric could be easily recognized. However, when this carbon fiber woven fabric was cut into a 100 mm square, a carbon fiber woven fabric without auxiliary yarns was formed, and the direction of the fabric piece could not be recognized.
補助糸を配置しない以外は実施例1と同様に製織した。
得られた織物を観察したところ、方向指示糸条となる補助糸がないため、織物片の方向を認識できなかった。
Weaving was performed in the same manner as in Example 1 except that no auxiliary yarn was disposed.
When the obtained woven fabric was observed, the direction of the woven fabric piece could not be recognized because there was no auxiliary yarn serving as a direction indicating yarn.
1 強化繊維糸
2 メール
2a 上段のメール
2b 下段のメール
3 補助糸
a1、a2、a3、a4、a5、… たて糸
b1、b2、b3、b4、b5、… よこ糸
DESCRIPTION OF SYMBOLS 1 Reinforcing
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JPH03206148A (en) * | 1989-09-27 | 1991-09-09 | Kanebo Ltd | Resin-reinforcing glass fiber material containing tracer yarn for discriminating obverse and reverse |
JPH07243148A (en) * | 1994-03-07 | 1995-09-19 | Toray Ind Inc | Molding material for fiber-reinforced thermoplastic resin molding and method for producing the same |
JPH08312534A (en) * | 1995-05-18 | 1996-11-26 | Toray Ind Inc | Casing |
WO2000056539A1 (en) * | 1999-03-23 | 2000-09-28 | Toray Industries, Inc. | Composite reinforcing fiber base material, preform and production method for fiber reinforced plastic |
JP2004160927A (en) * | 2002-11-15 | 2004-06-10 | Toray Ind Inc | Preform substrate, preform, fiber-reinforced plastic molding and molding method |
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