JP2011161409A - Apparatus for producing pure water - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an apparatus for producing pure water, which has a simple and low-cost structure and in which consumption of chemicals and environmental loads are reduced, consumption of nitrogen gas is saved, a soluble gas component is highly efficiently removed and the running cost is reduced. <P>SOLUTION: The apparatus for producing the pure water includes: at least, a feed tank 2 which supplies raw water 1; an RO (reverse osmosis) unit 4 for passing the raw water 1 which is supplied from the feed tank 2 through an RO membrane 3 to purify the raw water; and a pure water tank 6 into which the pure water 5 purified by the RO unit 4 is introduced, and in which the purified water is stored and from which the purified water is served for use. A nitrogen microbubble supply means 8 for generating or injecting nitrogen gas at the particle size equal to or smaller than those of microbubbles is arranged in the upstream region of the RO unit 4. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a pure water production apparatus, and more particularly to a pure water production apparatus that produces pure water using a reverse osmosis membrane (RO membrane).

  This type of pure water production apparatus is already known from Patent Document 1 below. In Patent Document 1, as shown in a block diagram in FIG. 7, a pure water manufacturing apparatus b that manufactures pure water using the RO membrane a and pure water manufactured by the pure water manufacturing apparatus b are supplied to a water supply pipe. In addition, a pure water supply system and a gas dissolving device are disclosed that are supplied to the pure water use section c and used for pure water. The pure water production apparatus b disclosed in Patent Document 1 passes the water from the water supply tank d through a decarboxylation tower e that removes dissolved ion components and soluble gas components (oxygen, carbonic acid), and then RO apparatus f. The water has been purified. The pure water is further purified by degassing the soluble gas components (oxygen and carbonic acid) that could not be removed up to the previous stage by nitrogen bubbling in the nitrogen bubbling tower g. Further, the pure water produced in this way can be supplied to the use part c of pure water while being stored in the sub tank h, and the nitrogen supplied to the nitrogen bubbling tower g is reduced against the water level drop in the sub tank h due to the supply of pure water. Adjustments are made by introducing branches.

  In the RO apparatus f, since 90% or more of the dissolved ion component in the raw water is concentrated, the metal ions are scaled on the surface of the RO membrane a, and the permeability of the RO membrane a is reduced, but this scaling is suppressed. However, a decarboxylation tower e for the purpose of removing carbonate ions is provided, and a scale (cationic metal) dispersant is added before the RO device f. The scales are mainly calcium carbonate and magnesium silicate, but the dispersing agent in front of the RO device is combined with negatively charged ions such as bicarbonate ions and silicate ions such as calcium ions and magnesium ions. And suppressing the generation of scale. Microorganisms propagate on the surface of the RO membrane a and become slime, resulting in a decrease in permeability. However, the adhesion of this microorganism slime is suppressed by adding a slime control agent. On the other hand, the soluble gas component is removed by aeration, but after removal, re-dissolution of the gas is suppressed by nitrogen purge from below in the nitrogen bubbling tower g. In addition, the subtank h also purges nitrogen gas from above to suppress the dissolution of the gas component.

JP-A-11-99382

  However, in the technique disclosed in Patent Document 1, the running cost in the production of pure water becomes very high due to the use of various chemicals such as acid, scale dispersant, slime control agent. In addition, the environmental impact of chemicals is high. More specifically, the amount of nitrogen consumed by nitrogen purge to the nitrogen bubbling tower g and the sub tank h is high, and the cost is high because pure nitrogen is used. In particular, nitrogen purge is very inefficient because it is always injected at a constant flow rate regardless of the production amount of pure water and the supply flow rate of raw water. Furthermore, there are many incidental devices such as a decarbonation tower d and a nitrogen bubbling tower g, the facilities are complicated and large, and the initial cost is expensive.

  The present invention provides a pure water production apparatus that has a simple and low-cost structure and can achieve low chemical and low environmental impact, nitrogen-saving gas, high efficiency of removal of soluble gas components, and low running cost. Is an issue.

  In order to solve the above-described problems, a pure water production apparatus according to the present invention includes a feed water tank that supplies raw water, an RO device that purifies raw water supplied from the feed water tank through the RO membrane, and purified water using the RO device. Provided with at least a pure water tank for introducing and storing the purified water to be used for use, and providing nitrogen microbubble supply means for generating or injecting nitrogen gas with a particle size of microbubbles or less in the upstream region of the RO device It is characterized by that.

  In such a configuration, nitrogen microbubbles having a particle size equal to or smaller than microbubbles are generated or injected into the raw water upstream of the RO device from the nitrogen microbubble supply means. Nitrogen microbubbles with the following particle sizes depend on PH but negatively charged on the surface, attracted by positively charged metal ions in raw water, and electrically neutralized, and the slime of the bubble itself Since it has the action of adsorbing a hydrophobic substance containing, it is possible to suppress the generation of scale and the growth of slime on the surface of the water or the RO membrane. In addition, nitrogen microbubbles with a particle size smaller than microbubbles stably disperse metal ions without disappearing in the RO device due to long-term retention in water, and suppress adhesion of slime on the surface of RO membrane a. In addition, the self-pressurization action of the bubbles can increase the dissolution rate in the raw water during the disappearance process of the nitrogen microbubbles, so that the degassing rate, the gas component removal rate, and the effective rate of nitrogen gas are improved.

  In addition, by reducing oxygen and carbon dioxide in water with nitrogen microbubbles, a synergistic effect of suppressing the growth of slime such as bacteria and microorganisms that feed them can be obtained.

  In the above, the nitrogen microbubble supply unit may further supply nitrogen microbubbles having a particle size of 50 μm or less.

  In such a configuration, in addition to the above, when the particle size of the nitrogen microbubbles is 50 μm or less, the dissolution rate and the removal rate of the gas component due to the self-pressurizing action can be increased.

  In the above, the nitrogen microbubble supply means may be installed immediately before or inside the RO device.

  In such a configuration, in addition to the above, supply of nitrogen microbubbles immediately before or inside the RO device increases the residence time and the floating distance in the raw water area in the wide RO device, thereby increasing the dispersion effect of metal ions, The slime adsorption / removal effect can be enhanced.

  In the above, further, a pH adjusting means for adjusting the pH by supplying an acidic agent or an alkaline agent to the raw water upstream of the RO device may be provided.

  In such a configuration, in addition to the above, the pH of the raw water is further adjusted by the pH adjusting means, for example, pH 4 or higher at which the nitrogen microbubbles are negatively charged, and exceeds pH 9 at which metal ions are easily scaled. Therefore, it is possible to secure an optimum environment that excludes the pH range and the alkali range, further suppress the generation of scale, and adjust the charging potential and the zeta potential.

  In the above, a decarboxylation tower is further provided upstream of the RO device, and nitrogen microbubble supply means is provided immediately before or inside the decarboxylation tower.

  In such a configuration, in addition to the above, free carbonic acid in the raw water can be removed by a decarboxylation tower, but nitrogen microbubbles are injected or generated in the raw water from the nitrogen microbubble supply means provided immediately before or inside the raw water. As a result, the partial pressure of nitrogen gas increases, so that the decarboxylation effect can be enhanced.

  In the above, nitrogen microbubble supply means may be further provided inside the water supply tank.

  In such a configuration, in addition to the above, since degassing in the raw water can be achieved by supplying nitrogen microbubbles from the nitrogen microbubble supply means in the raw water supply source, the installation of the decarboxylation tower can be omitted.

  In the above, further, nitrogen supply means for supplying and filling nitrogen inside the pure water tank can be provided.

  In such a configuration, in addition to the above, it is necessary to further suppress contact between pure water and other gases, but nitrogen gas in which nitrogen microbubbles are excessively dissolved in the raw water passes through the RO membrane and the pressure is increased. Since nitrogen bubbles form in the downstream side of the lowered RO device, particularly in pure water in the pure water tank, the contact with the air is suppressed by the nitrogen bubbles in the RO water, where the RO water and air are likely to come into contact. Further, by increasing the nitrogen partial pressure in the RO water, it becomes possible to further remove soluble gas components (oxygen, carbonic acid).

  In addition, in the above, a nitrogen bubbling tower can also be provided with a decarboxylation tower, and thereby, deaeration when deaeration becomes insufficient can be promoted.

  Further objects and features of the present invention will become apparent from the following detailed description and drawings. Each feature of the present invention can be used alone or in combination in various combinations as much as possible.

  According to the pure water production apparatus of the present invention, nitrogen microbubbles having a particle size equal to or smaller than microbubbles are generated or injected into the raw water upstream of the RO apparatus, and the long-term retention and high contact rate reduce nitrogen. In addition, the nitrogen microbubbles can be degassed and gas components removed by the self-pressurizing action, and the nitrogen bubbling tower and decarboxylation tower can be omitted or the amount of bubbling nitrogen can be reduced. In addition, the neutralization of metal ions in the raw water suppresses the generation of scale on the surface of the water and the RO membrane, and adsorbs and removes slime as a hydrophobic substance and eliminates or reduces the slime control agent. Therefore, in addition to non-chemical or low chemical, simplification of equipment, low initial cost, low running, and low environmental load. In addition, the metal ions and slime adsorbed by the floating of the nitrogen microbubbles in the raw water area in the RO device can be easily removed by carrying them to the surface layer of the raw water and overflowing them, so that the processing costs can be reduced. .

  In addition to the above, the particle size of the nitrogen microbubbles is 50 μm or less, so that the dissolution rate and removal rate of the gas component by the self-pressurizing action can be further increased.

  In addition to the above, by supplying nitrogen microbubbles immediately before or inside the RO device, the residence time and the floating distance in the raw water area in the wide RO device are increased, so that metal ions and slime are adsorbed and carried to the surface of the raw water. Therefore, the generation of scale and slime on the RO membrane surface can be effectively suppressed.

  In addition to the above, the pH of the raw water is further adjusted by a pH adjusting means, for example, a pH range of 4 or more at which nitrogen microbubbles are negatively charged, and a pH range and alkali range exceeding pH 9 at which metal ions are easily scaled. The optimal environment with the removal of the distance can be secured, the generation of scale can be further suppressed, and the charging potential and the zeta potential can be adjusted.

  In addition to the above, free carbonic acid in the raw water can be removed by a decarboxylation tower. Nitrogen gas can be removed by injecting or generating nitrogen microbubbles in the raw water from the nitrogen microbubble supply means provided immediately before or inside thereof. Since the partial pressure of the gas increases, decarboxylation can be enhanced.

  In addition to the above, since the raw water can be degassed by supplying the nitrogen microbubbles from the nitrogen microbubble supply means in the raw water supply source, the installation of the decarboxylation tower can be omitted.

  In addition to the above, it is necessary to suppress contact between pure water and other gases, but nitrogen gas in which nitrogen microbubbles are excessively dissolved in the raw water passes through the RO membrane and is downstream of the RO device where the pressure is reduced. On the other hand, especially in the pure water of the pure water tank, where nitrogen bubbles are likely to come into contact with pure water, contact with air is suppressed by the nitrogen bubbles in the RO water, and the partial pressure of nitrogen in the RO water increases. This makes it possible to further remove soluble gas components (oxygen, carbonic acid).

  In addition, in the above, a nitrogen bubbling tower can also be provided with a decarboxylation tower, and thereby, deaeration when deaeration becomes insufficient can be promoted.

It is a schematic block diagram which shows one example of the pure water manufacturing apparatus of embodiment which concerns on this invention. It is a schematic block diagram which shows another example of the pure water manufacturing apparatus of embodiment which concerns on this invention. It is a schematic block diagram which shows the other example of the pure water manufacturing apparatus of embodiment which concerns on this invention. It is a schematic block diagram which shows another example of the pure water manufacturing apparatus of embodiment which concerns on this invention. It is a graph which shows the relationship between a bubble diameter and the rising speed of a bubble. It is a graph which shows the relationship between pH and the zeta potential of a bubble. It is a schematic block diagram which shows the example of the conventional pure water manufacturing apparatus.

Hereinafter, embodiments according to the present invention will be described in detail with reference to FIGS. 1 to 4 to provide an understanding of the present invention. The following description is a specific example of the present invention and does not limit the description of the scope of claims.
The pure water production apparatus 100 shown in FIG. 1, the pure water production apparatus 200 shown in FIG. 2, the pure water production measure 300 shown in FIG. 3, and the pure water production apparatus 400 shown in FIG. When the reference numeral is used for explanation, a water supply tank 2 for supplying raw water 1, an RO apparatus 4 for purifying raw water 1 supplied from the water supply tank 2 through an RO membrane (Reverse Osmosis Membrane) 3, and this RO apparatus 4 The deionized pure water 5 is introduced and stored, and is provided with at least a pure water tank 6 for various uses such as reprocessing and washing in the secondary device 500 connected downstream, and in the upstream area of the RO device 4 This is common in that nitrogen microbubble supply means 8 for generating or injecting nitrogen gas 7 with a particle size of microbubbles or less is provided. With such a basic configuration, the raw water 1 upstream of the RO device 4 is representatively represented in the raw water 1 of the RO device 4 of FIG. Nitrogen microbubbles 7 are generated or injected, so that nitrogen exerts a degassing action on the raw water 1, and the nitrogen microbubbles 7 having a particle size equal to or smaller than the microbubbles depend on PH but are negatively charged on the surface. In the raw water 1 or on the surface of the RO membrane 3, it is attracted by positively charged metal ions in the raw water and electrically neutralizes and adsorbs hydrophobic substances including slime in the bubble itself. Scale generation and slime growth can be suppressed. Nitrogen microbubbles 7 with a particle size smaller than microbubbles can stably disperse metal ions without disappearing in the RO device due to long-term retention in water, thereby suppressing the adhesion of slime on the surface of RO membrane a. In addition, since the dissolution rate in the raw water 1 during the disappearance process of the nitrogen microbubbles 7 can be increased by the self-pressurizing action of the bubbles, the degassing rate, the gas component removal rate, and the effective rate of nitrogen gas are improved.

  As a result, nitrogen microbubbles 7 having a particle size smaller than microbubbles are generated or injected into the raw water 1 upstream of the RO device 4, and the consumption of nitrogen is reduced due to its long-term retention and high contact rate. The example shown in FIG. 4 is the same as the pure water production apparatus 100 shown in FIG. 1 because the nitrogen microbubbles 7 can perform degassing and gas component removal with the self-pressurizing action. Both the nitrogen bubbling tower 11 employed in the pure water production apparatus 400, the pure water production apparatus 200 shown in FIG. 2, the pure water production apparatus 300 shown in FIG. 3, and the pure water apparatus 400 shown in FIG. The decarboxylation tower 12, the addition of acid (sulfuric acid) can be omitted, or the amount of bubbling nitrogen can be reduced, and the neutralization with the metal ions in the raw water 1 can be performed in the raw water 1 or on the RO membrane 3 surface. Scale generation can be suppressed and hydrophobic substances The slime control agent 13 employed by the pure water production apparatus 200 shown in FIG. 2, the pure water production apparatus 300 shown in FIG. 3, and the pure water apparatus 400 shown in FIG. 4 is omitted. In addition to the reduction of chemicals or chemicals, simplification of equipment, low initial cost, low running, and low environmental impact. Moreover, since the metal ions and slime adsorbed by the floating of the nitrogen microbubbles 7 in the raw water 1 area in the RO device 4 are easily removed by carrying them to the surface layer of the raw water 1 and overflowing them, their processing costs Can also be reduced.

  In the pure water production apparatus 100 shown in FIG. 1, in particular, the decarboxylation tower, the nitrogen field bling tower are omitted, and the supply of acid and slime control agent is omitted. The environmental impact has also been greatly reduced. Moreover, since the nitrogen microbubble supply means 8 is provided in the water supply tank 2, the carbon dioxide gas separation function of the decarbonation tower can be exerted on the raw water 1 in the water supply tank 2, so that the decarbonation tower is omitted. However, the generation of scale that binds to CO2 is suppressed, and the amount of scale dispersant consumed can be reduced without any problem. In addition, since the distance between the water tank 2 and the RO device 4 can be shortened, the slime adhesion suppressing effect is improved. In this respect, the slime control agent can be made unnecessary and even when used, the consumption can be reduced. As a result, both initial cost and running cost are reduced, and the environmental load is also reduced.

  Note that the RO membrane 3 may have pores having a size of 0.38 nanometers or more, which is the size of water molecules, in the production of pure water, and can be made larger depending on the particle size to be removed. . Although the microbubble supply means 8 is not specifically shown, Patent Document 2 (Japanese Patent Laid-Open No. 2009-97431), Patent Document 3 (Japanese Patent Laid-Open No. 2009-85048), and Patent Document 4 (Japanese Patent Laid-Open No. 2009). Since various techniques such as No. -82903 have already been proposed and put into practical use, the present invention can be realized by adopting these already known techniques, and therefore a detailed description thereof will be omitted.

Here, Non-Patent Document 1 (URL [http point //unit.aist.go.jp/emtech-ri/26env-fluid/takahashi.pdf] Research on microbubbles and nanobubbles National Institute of Advanced Industrial Science and Technology Department Masayoshi Takahashi) disclosed the graph shown in FIG. 5 as an experimental result regarding the relationship between the bubble diameter and the bubble rising speed. In the experiment of the present inventor, suppression of degassing action, scale and slime generation is disclosed. Moreover, since the upper limit of the allowable rising speed is about 1000 μm / s, the particle diameter of the nitrogen microbubbles 7 injected or generated in the raw water 1 is 50 μm or less from FIG. Therefore, the nitrogen microbubble supply means 8 supplies nitrogen microbubbles having a particle size of 50 μm or less. Thus, when the particle diameter of the nitrogen microbubbles 7 is 50 μm or less, the dissolution rate of the gas component due to the self-pressurizing action while floating in the wide water absorption tank 1 or the raw water 1 area in the RO device 4. The removal rate, the adsorption removal rate of metal ions and slime can be increased, low chemical and environmental impact, nitrogen saving, high efficiency of removal of soluble gas components, low initial cost, low running cost It will be excellent.

  Further, the nitrogen microbubbles 7 need to be negatively charged with respect to the fact that they are positively charged in order to adsorb and remove metal ions and slime. Non-Patent Document 1 discloses the graph shown in FIG. 6 as an experimental result regarding the relationship between the zeta potential (bubble potential / electrokinetic potential) of bubbles and pH. According to FIG. Since the zeta potential rises negatively until pH 9, the neutralization with positively charged cation metal or slime is at pH 4 or higher. The closer to pH 9, the higher the potential and the higher the cation Neutralizing action with metals is likely to occur. In particular, the present inventor has found that the pH is preferably in the range of about 6 to 8 because cationic metals and the like are easily combined with anions due to an increase in pH and are easily scaled.

  In order to satisfy this requirement, the pure water production apparatus 200 shown in FIG. 2, the pure water production apparatus 300 shown in FIG. 3, and the pure water production apparatus 400 shown in FIG. The pH adjusting means 16 may be provided for adjusting the pH by supplying the acid agent 14 typified by acid or sulfuric acid or the reducing agent 15 typified by sodium sulfite into the raw water 1. Thereby, the pH of the raw water 1 is adjusted by the pH adjusting means 16, for example, pH 4 or higher at which the nitrogen microbubbles 7 are negatively charged, and a pH range and pH exceeding pH 9 where metal ions and the like are easily scaled. By ensuring an optimal environment outside the range, the generation of scale can be further suppressed, and the charging potential and zeta potential can be adjusted.

  The pure water production apparatus 200 shown in FIG. 2 can connect the RO apparatus 4 directly to the pure water tank 6, that is, omit the nitrogen bubbling tower, but without purging the pure tank 6 with nitrogen, Nitrogen microbubble supply means 8 provided in a path partially bypassing raw water 1 supplied to 4 is supplied with nitrogen microbubbles 7 and aerated with nitrogen, and the partial pressure (for example, 4 atm) causes excessive water in raw water 1. By dissolving nitrogen and opening the downstream of the RO device 4 to the atmosphere, the nitrogen dissolved excessively in the branched pure water 1 is vaporized and the soluble gas component is removed. In addition, the nitrogen purge amount in the pure water tank 6 can be reduced or reduced.

  In this example, in addition to the fact that the pH adjusting means 16 described above may supply the acid agent 14, the decarboxylation tower 12 is not affected by the nitrogen microbubble supply means 8 so as not to affect the function of the nitrogen microbubble supply means 8. The microbubble supply means 8 is provided upstream of the branch point of the branch path so that soluble gas components such as acid and carbonic acid can be removed. Furthermore, in addition to the slime control agent 13, the scale dispersant 17 is also supplied, but any of them can be omitted or reduced as described above. Thus, the nitrogen microbubble supply means 8 can be installed immediately before the RO device 4, and can be installed inside the raw water 1 area of the RO device 4 in some cases. By supplying the nitrogen microbubbles 7 immediately before or inside the RO device 4 and increasing the residence time and the floating distance in the wide area of the raw water in the RO device, the adsorption of metal ions and slime and the raw water 1 are increased. The carrying effect on the surface layer can be enhanced.

The pure water production apparatus 300 of the example shown in FIG. 3 follows the technique in the pure water production apparatus 200 of the example shown in FIG. 2 in terms of the configuration other than the installation position of the nitrogen microbubble supply means 8. The difference is that a nitrogen microbubble supply means 8 is provided immediately before or inside the decarboxylation tower 12 provided upstream of the apparatus 4. In this way, free carbonic acid in the raw water 1 can be removed by the decarbonation tower 12, but nitrogen microbubbles 7 are injected or generated in the raw water 1 from the nitrogen microbubble supply means 8 provided immediately before or inside thereof. As a result, the partial pressure of nitrogen gas is increased, so that the decarboxylation effect can be enhanced. In some cases, nitrogen microbubble supply means 8 can be provided both immediately before and inside the decarboxylation tower 12.

  Furthermore, in addition to the configuration of the pure water production apparatus 200 of the example shown in FIG. 2, the pure water production apparatus 400 of the example shown in FIG. 4 further replaces the nitrogen bubbling tower 11 employed in Patent Document 1 with the RO apparatus 4. A nitrogen supply means 18 is provided between the pure water tank 6 and a nitrogen gas 19 for supplying and filling the nitrogen gas 19 inside the pure water tank 6. As described above, even when the nitrogen bubbling tower 11 is provided, it is possible to reduce the consumption of nitrogen, and it is necessary to suppress contact between the pure water 1 and other gases, so that the nitrogen microbubbles 7 are excessive in the raw water 1. The dissolved nitrogen gas is likely to come into contact with pure water in the form of nitrogen bubbles in the downstream side of the RO device 4 where the pressure has dropped to, for example, about atmospheric pressure through the RO membrane, particularly in the pure water 1 of the pure water tank 6. The nitrogen gas 19 is purged to ensure a predetermined pressure and suppress the generation of nitrogen bubbles.

  The present invention uses nitrogen microbubbles in the production of pure water, simplifies the device, reduces initial cost by miniaturization, non-chemical, low chemical, low environmental load, and low running cost. Can be manufactured.

100, 200, 300, 400 Pure water production device 500 Secondary device 1 Raw water 2 Water supply tank 3 Reverse osmosis membrane 4 RO device 5 Pure water 6 Pure water tank 7 Nitrogen microbubble 8 Nitrogen microvalve supply means 11 Nitrogen bubbling tower 12 Carbonic acid tower 13 Slime control agent 14 Acid 15 Reducing agent 16 pH adjusting means 17 Scale dispersant 18 Nitrogen supply means 19 Nitrogen gas

Claims (8)

  A water supply tank that supplies raw water, an RO device that purifies the raw water supplied from the water supply tank through an RO membrane, and a pure water tank that introduces and stores pure water purified by the RO device for use And a nitrogen microbubble supply means for generating or injecting nitrogen gas with a particle size of microbubbles or less in the upstream region of the RO device.   The pure water manufacturing apparatus according to claim 1, wherein the nitrogen microbubble supply means supplies nitrogen microbubbles having a particle size of 50 μm or less.   The said nitrogen microbubble supply means is a pure water manufacturing apparatus of any one of Claim 1, 2 installed in front of the said RO apparatus, or an inside.   The pure water manufacturing apparatus of any one of Claims 1-3 which provided the pH adjustment means which supplies an acidic agent or an alkaline agent to raw | natural water upstream from the said RO apparatus, and adjusts pH to 4-9. .   The pure water production apparatus according to any one of claims 1 and 2, wherein a decarboxylation tower is provided upstream of the RO device, and the nitrogen microbubble supply means is provided immediately before or inside the decarboxylation tower.   The pure water manufacturing apparatus according to any one of claims 1 and 2, wherein the nitrogen microbubble supply means is provided inside the water supply tank.   The pure water manufacturing apparatus of any one of Claims 1-6 which provided the nitrogen supply means to supply nitrogen and to fill the inside of the said pure water tank.   The pure water manufacturing apparatus of any one of Claim 5 and 7 which provided the nitrogen bubbling tower with the said decarboxylation tower.