JP2011132201A - Araneida-controlling composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an araneida-controlling composition having excellent efficacy on araneida. <P>SOLUTION: The araneida-controlling composition comprises 4-methoxymethyl-2,3,5,6-tetrafluorobenzyl=3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropane carboxylate as an effective ingredient. The method for controlling araneida comprises applying an effective amount of the araneida-controlling composition on araneida or a habitat of araneida. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

The present invention relates to a spider control composition and a spider control method.

It is known that 4-methoxymethyl-2,3,5,6-tetrafluorobenzyl = 3- (2-cyano-1-propenyl) -2,2-dimethylcyclopropanecarboxylate has a pest control effect. (See Patent Document 1).

JP 2004-2363 A

It is an object of the present invention to provide a spider control composition having excellent efficacy.

As a result of studies to find a composition having an excellent control effect against spiders, the present inventor has found 4-methoxymethyl-2,3,5,6-tetrafluorobenzyl = 3- (2-cyano-1-propenyl). ) -2,2-dimethylcyclopropanecarboxylate (hereinafter referred to as the present ester compound) as an active ingredient was found to have an excellent controlling effect, and the present invention was achieved.

That is, the present invention relates to the following inventions.
[1] Spider control containing 4-methoxymethyl-2,3,5,6-tetrafluorobenzyl = 3- (2-cyano-1-propenyl) -2,2-dimethylcyclopropanecarboxylate as an active ingredient Composition.
[2] The spider control composition according to [1], which is an aerosol.
[3] A method for controlling spiders, which comprises applying an effective amount of the spider control composition according to [1] or [2] to a spider or a habitat of the spiders.

Spiders can be controlled by using the spider control composition of the present invention. Moreover, nesting can be prevented by applying the spider control composition of the present invention to spiders or spider habitats.

This ester compound is, for example, a compound described in JP-A No. 2004-2363, and can be produced by a method described in the publication.
In the present ester compound, there are isomers derived from two asymmetric carbon atoms and a double bond existing on the cyclopropane ring. In the present invention, compounds each having an arbitrary isomer ratio are used. be able to.

Specific examples of the spiders having the control effect of the spider control composition of the present invention include the following.

Birch spider, red spider spider, white spider spider, spider spider, long-spider spider, giant spider, spider spider, long-tailed spider, black-tailed spider, white-tailed spider, large-spider spider, white-spider spider, jumping spider, etc.

In the spider control composition of the present invention, the present ester compound may be used as it is, but usually it is used as the following preparation. Examples of the preparation include oils, emulsions, wettable powders, granular wettable powders, flowables (suspensions in water, emulsions in water, etc.), microcapsules, gels, powders, granules, tablets, and coating preparations. , Aerosols, carbon dioxide preparations, heat transpiration agents (insecticide incense, electric insecticide mats, liquid core type heat transpiration insecticides, etc.), piezo insecticides, heating smokers (self-burning smokers, chemical reaction type) Smoke agent, porous ceramic plate smoke agent, etc.), non-heated transpiration agent (resin transpiration agent, paper transpiration agent, non-woven fabric transpiration agent, knitted fabric transpiration agent, sublimation tablet, etc.), and fumes (focking etc.) Is mentioned.

Examples of the formulation method include the following methods.
(1) A method in which the present ester compound is mixed with a solid carrier, liquid carrier, gaseous carrier, bait, etc., and if necessary, a surfactant or other formulation adjuvant is added and processed.
(2) A method of impregnating a base material containing no active ingredient with the ester compound.
(3) A method of molding after mixing the ester compound and the substrate.
These preparations usually contain 0.001 to 95% by weight of the present ester compound.

  Examples of solid carriers used for formulation include clays (kaolin clay, diatomaceous earth, bentonite, fusami clay, acidic clay), synthetic hydrous silicon oxide, talc, ceramics, and other inorganic minerals (sericite, quartz, sulfur). , Activated carbon, calcium carbonate, hydrated silica, etc.), fine powders and particulates such as chemical fertilizers (ammonium sulfate, phosphorous acid, ammonium nitrate, ammonium chloride, urea, etc.), substances that are solid at room temperature (2,4,6-triisopropyl) -1,3,5-trioxane, naphthalene, p-dichlorobenzene, camphor, adamantane, etc.), wool, silk, cotton, hemp, pulp, synthetic resin (for example, low density polyethylene, linear low density polyethylene, high Polyethylene resins such as density polyethylene; ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymers; ethylene-methyl methacrylate copolymers; Ethylene-methacrylic acid ester copolymer such as ethylene-ethyl methacrylate copolymer; Ethylene-acrylic acid ester copolymer such as ethylene-methyl acrylate copolymer, ethylene-ethyl acrylate copolymer; ethylene-acrylic Ethylene-vinylcarboxylic acid copolymers such as acid copolymers; ethylene-tetracyclododecene copolymers; polypropylene resins such as propylene homopolymers and propylene-ethylene copolymers; poly-4-methylpentene-1 , Polybutene-1, polybutadiene, polystyrene; acrylonitrile-styrene resin; styrene-based elastomer such as acrylonitrile-butadiene-styrene resin, styrene-conjugated diene block copolymer, hydrogenated styrene-conjugated diene block copolymer; fluorine resin; Polymethacryl Acrylic resins such as methyl; polyamide resins such as nylon 6 and nylon 66; polyester resins such as polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polycyclohexylene dimethylene terephthalate; polycarbonate, polyacetal, polyacrylic Phon, polyacrylate, hydroxybenzoic acid polyester, polyetherimide, polyester carbonate, polyphenylene ether resin, polyvinyl chloride, polyvinylidene chloride, polyurethane, foamed polyurethane, foamed polypropylene, foamed ethylene and other porous resins), glass, metal, Felt, fiber, cloth, knitted fabric, sheet, paper, thread, foam, porous body and multifilament made of one or more kinds of ceramics It is.

  Examples of the liquid carrier include aromatic or aliphatic hydrocarbons (xylene, toluene, alkylnaphthalene, phenylxylylethane, kerosene, light oil, hexane, cyclohexane, etc.), halogenated hydrocarbons (chlorobenzene, dichloromethane, dichloroethane, trichloroethane). Etc.), alcohols (methanol, ethanol, isopropyl alcohol, butanol, hexanol, benzyl alcohol, ethylene glycol, etc.), ethers (diethyl ether, ethylene glycol dimethyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, propylene glycol monomethyl ether, tetrahydrofuran) , Dioxane, etc.), esters (ethyl acetate, butyl acetate, etc.), ketones (aceto , Methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone), vegetable oils (soybean oil, cottonseed oil, etc.), vegetable essential oils (orange oil, hyssop oil, lemon oil), and water.

  Examples of the gaseous carrier include butane gas, chlorofluorocarbon gas, liquefied petroleum gas (LPG), dimethyl ether, and carbon dioxide gas.

  Surfactants include, for example, alkyl sulfate esters, alkyl sulfonates, alkyl aryl sulfonates, alkyl aryl ethers, polyarylethylenes of alkyl aryl ethers, polyethylene glycol ethers, polyhydric alcohol esters and sugars. Examples include alcohol derivatives.

  Other formulation adjuvants include fixing agents, dispersants and stabilizers, such as casein, gelatin, polysaccharides (starch, gum arabic, cellulose derivatives, alginic acid, etc.), lignin derivatives, bentonite, saccharides, Synthetic water-soluble polymers (polyvinyl alcohol, polyvinylpyrrolidone, polyacrylic acid, etc.), BHT (2,6-di-tert-butyl-4-methylphenol), and BHA (2-tert-butyl-4-methoxyphenol) 3-tert-butyl-4-methoxyphenol).

Examples of the insecticidal incense base material include a mixture of a vegetable powder such as wood powder and straw powder and a binder such as tab powder, starch and glutin.
Examples of the base material for the insecticidal electric mat include those obtained by solidifying a cotton linter into a plate shape and those obtained by solidifying a fillable of a mixture of cotton linter and pulp into a plate shape.
Examples of the base material of the self-combustion type smoke agent include nitrate, nitrite, guanidine salt, potassium chlorate, nitrocellulose, ethyl cellulose, wood powder and other combustion exothermic agents, alkali metal salts, alkaline earth metal salts, heavy metals. Examples thereof include pyrolysis stimulants such as chromate and chromate, oxygen supply agents such as potassium nitrate, flame retardants such as melamine and wheat starch, extenders such as diatomaceous earth, and binders such as synthetic glue.

  Examples of the base material for the chemical reaction type smoke agent include exothermic agents such as alkali metal sulfides, polysulfides, hydrosulfides, and calcium oxide, catalyst materials such as carbonaceous materials, iron carbide, and activated clay, azo Examples thereof include organic foaming agents such as dicarbonamide, benzenesulfonylhydrazide, dinitropentamethylenetetramine, polystyrene, and polyurethane, and fillers such as natural fiber pieces and synthetic fiber pieces.

  Examples of the resin used for the substrate such as a resin transpiration agent include polyethylene resins such as low density polyethylene, linear low density polyethylene, and high density polyethylene; and ethylene-vinyl ester copolymers such as ethylene-vinyl acetate copolymer. Polymer; ethylene-methacrylic acid ester copolymer such as ethylene-methyl methacrylate copolymer, ethylene-ethyl methacrylate copolymer; ethylene-methyl acrylate copolymer, ethylene-ethyl acrylate copolymer, etc. Ethylene-acrylic acid ester copolymer; ethylene-vinyl carboxylic acid copolymer such as ethylene-acrylic acid copolymer; ethylene-tetracyclododecene copolymer; propylene homopolymer, propylene-ethylene copolymer, etc. Polypropylene resin; poly-4-methylpentene-1, polybutene-1, Rebutadiene, polystyrene, acrylonitrile-styrene resin; styrene-based elastomers such as acrylonitrile-butadiene-styrene resin, styrene-conjugated diene copolymer, styrene-conjugated diene block copolymer hydrogenated product; fluororesin; polymethyl methacrylate, etc. Acrylic resins such as nylon 6, nylon 66, etc .; polyester resins such as polyethylene terephthalate, polyethylene naphthalate, polybutylene terephthalate, polycyclohexylene dimethylene terephthalate; polycarbonate, polyacetal, polyacrylsulfone, polyarylate , Hydroxybenzoic acid polyester, polyetherimide, polyester carbonate, polyphenylene ether resin, polyvinyl chloride, polyvinyl chloride These base materials may be used singly or as a mixture of two or more, and these base materials may be used for these base materials if necessary, such as phthalates (dimethyl phthalate, dioctyl phthalate, etc.) ), Plasticizers such as adipic acid esters and stearic acid may be added. The resin transpiration agent can be obtained by kneading the ester compound in the substrate and then molding it by injection molding, extrusion molding, press molding or the like. The obtained resin preparation can be further processed into a plate shape, a film shape, a tape shape, a net shape, a string shape or the like through steps such as molding and cutting if necessary. These resin preparations are processed, for example, as animal collars, animal ear tags, sheet preparations, attracting strings, or gardening supports.

「式中、Ｘ^a1はメチル基、塩素原子、臭素原子またはフッ素原子を表し、Ｘ^a2はフッ素原子、塩素原子、臭素原子、Ｃ１−Ｃ４ハロアルキル基またはＣ１−Ｃ４ハロアルコキシ基を表し、Ｘ^a3はフッ素原子、塩素原子または臭素原子を表し、Ｘ^a4は置換されていてもよいＣ１−Ｃ４アルキル、置換されていてもよいＣ３−Ｃ４アルケニル、置換されていてもよいＣ３−Ｃ４アルキニル、置換されていてもよいＣ３−Ｃ５シクロアルキルアルキルまたは水素原子を表し、Ｘ^a5は水素原子またはメチル基を表し、Ｘ^a6は水素原子、フッ素原子または塩素原子を表し、Ｘ^a7は水素原子、フッ素原子または塩素原子を表す。」で示されるいずれかの化合物、
下記式（Ｂ）

「式中、Ｘ^b1はＸ^b2−ＮＨ−Ｃ（＝Ｏ）基、Ｘ^b2−Ｃ（＝Ｏ）−ＮＨ−ＣＨ₂基、Ｘ^b3−Ｓ（Ｏ）基、置換されていてもよいピロール−１−イル基、置換されていてもよいイミダゾール−１−イル基、置換されていてもよいピラゾール−１−イル基または置換されていてもよい１，２，４−トリアゾール−１−イル基を表し、Ｘ^b2は２，２，２−トリフルオロエチル基等の置換されていてもよいＣ１−Ｃ４ハロアルキル基またはシクロプロピル基等の置換されていてもよいＣ３−Ｃ６シクロアルキル基を表し、Ｘ^b3はメチル等の置換されていてもよいＣ１−Ｃ４アルキル基を表し、Ｘ^b4は水素原子、塩素原子、シアノ基またはメチル基を表す。」
で示されるいずれかの化合物、下記式（Ｃ）

「式中、Ｘ^c1は３，３，３−トリフルオロプロピル基等の置換されていてもよいＣ１−Ｃ４アルキル基、２，２，２−トリクロロエトキシ基等の置換されていてもよいＣ１−Ｃ４アルコキシ基、４−シアノフェニル基等の置換されていてもよいフェニル基または２−クロロ−３−ピリジル基等の置換されていてもよいピリジル基を表し、Ｘ^c2はメチル基またはトリフルオロメチルチオ基を表し、Ｘ^c3はメチル基またはハロゲン原子を表す。」で示されるいずれかの化合物等が挙げられる。 The spider control composition of the present invention may be used in combination with or in combination with other repellents, pest control agents and the like in addition to the ester compound.
Examples of active ingredients of other pest control agents that can be used in combination or in combination include (1) synthetic pyrethroid compounds, acrinathrin, allethrin, beta-cyfluthrin, bifenthrin, Cycloprotorin, cyfluthrin, cyhalothrin, cypermethrin, empentrin, phenmetherine, fenfenate, fenfenate. (Fenpropath rin), fenvalerate, flucitrinate, flufenprox, flumethrin, fluvalinate, halfenprox, permethrin, permethrin. , Pyrethrins, sigma-cypermethrin, silafluofen, tefluthrin, tralomethrin, transfluthrin (transfluthrin) in), phenothrin, cyphenothrin, alpha cypermethrin, zeta-permethrin, lambda cihalothrin (lambda-cyhalothrin), lambda-cyhalothrin (lambda-cyhalothrin) ), Furamethrin, tau-fluvalinate, methfluthrin, dimethylfluthrin, profluthrin, 2,3,5,6-tetrafluoro-4- (methoxymethyl) benzyl 2 , 2,3,3-Tetramethylcyclopropanecal Kishireto and the like;
(2) Organic Phosphorus Compounds Acephate, Aluminum Phosphide, Butathiofos, Cadosafos, Chlorethoxyfos, Chlorfenvinphos, Chlorfenvinphos, Chlorfenphos Chlorpyrifos-methyl, cyanophos (CYAP), diazinon, DCIP (dichlorodipropionether), dichlorfenthion (ECP), dichlorvos (DichV) Dimethoate, dimethylvinphos, disulfoton, EPN, etion, ethoprofos, etrimfos, fenthion (MPP), fenitrothion (see, EPEP) fothiazate, formothion (formulation), hydrogen phosphide (isofenphos), isoxathion (isoxathion), malathion (malathion), mesulfenfos (meth) thiothion Monocrotophos, naled (BRP), oxydeprofos (ESP), parathion, fosarone, phosmet: PMP, pirimiphosmethylthiol (pirimifentiop) Quinalphos, phentoate (PAP), profenofos, propopafos, prothiofos, pyrachlorfos, salithion, sulprofos sulprofos upirimfos), temephos (temephos), tetrachlorvinphos bottle phosphite (tetrach1orvinphos), terbufos (terbufos), thiometon (thiometon), trichlorfon (trichlorphon: DEP), vamidothion (vamidothion), folate (phorate), cadusafos (cadusafos), and the like;
(3) Carbamate compounds alaniccarb, bendiocarb, benfuracarb, BPMC, carbaryl (carbary), carbofuran, carbosulfane, lofocarb, crofocarb ), Fenobucarb, phenothiocarb, phenoxycarb, furathiocarb, isoprocarb (MIPC), metocarbyl, metolcarb thiocarb), NAC, oxamyl (oxamyl), pirimicarb (pirimicarb), propoxur (propoxur: PHC), XMC, thiodicarb (thiodicarb), xylylcarb (xylylcarb), aldicarb (aldicarb) or the like;
(4) Nereistoxin compounds Cartap, bensultap, thiocyclam, monosultap, bisultap, etc .;
(5) Neonicotinoid compounds imidacloprid (imidac1oprid), nitenpyram (nitenpyram), acetamiprid (acetamipride), thiamethoxam (thiacloprid) (thiacloprid), dinotefur (din)
(6) Benzoylurea compounds Chlorfluazuron, bistrifluron, diafenthiuron, diflubenzuron, fluazuron, flucycloxuron, flucycloxuron Flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, trifluururon, trifluururon
(7) Phenylpyrazole compounds Acetoprole, etiprole, fipronil, vaniliprole, pyriprole, pyrafluprole, etc .;
(8) Bt toxin insecticide, live spores and produced crystal toxins derived from Bacillus thuringiensis, and mixtures thereof;
(9) Hydrazine-based compounds Chromafenozide, halofenozide, methoxyphenozide, tebufenozide and the like;
(10) Organochlorine compounds Aldrin, dieldrin, dienochlor, endosulfan, methoxychlor and the like;
(11) Natural insecticide machine oil, nicotine sulfate (nicotine-sulfate);
(12) Other insecticides avermectin (vermectin-B), bromopropyrate, buprofezin, chlorfenapyr, cyromazine, D-D (1, ro-dictin) emamectin-benzoate, fenazaquin, flupyrazofos, hydroprene, methoprene, indoxacarb, methoadiamycin pymetrozine, pyridalyl, pyriproxyfen, spinosad, sulfuramide, tolfenpyrad, triazemate, flubenamide, flubenamide, flubenamide, flubenamide Arsenic acid, Benclothiaz, lime nitrogen (Calcium polysulfide), chlordane, DDT, DSP, flufenerimide, flufenerimid Flurimfen, formatenate, metham-ammonium, metham-sodium, methyl bromide, potassium oleate, prototribute fate ), Spiromesifen, sulfur, metaflumizone, spirotetramat, pyrifluquinazone, spinetoril, chlorantirp rapylil), the following formula (A)

"Wherein, X ^a1 represents a methyl group, a chlorine atom, bromine atom or fluorine atom, X ^a2 represents fluorine atom, chlorine atom, bromine atom, C1-C4 haloalkyl group or a C1-C4 haloalkoxy group, X ^a3 Represents a fluorine atom, a chlorine atom or a bromine atom, and X ^a4 is an optionally substituted C1-C4 alkyl, an optionally substituted C3-C4 alkenyl, an optionally substituted C3-C4 alkynyl, substituted ^Optionally represents C3-C5 cycloalkylalkyl or a hydrogen atom, ^Xa5 represents a hydrogen atom or a methyl group, ^Xa6 represents a hydrogen atom, a fluorine atom or a chlorine atom, ^Xa7 represents a hydrogen atom, a fluorine atom or Any one of the compounds represented by “represents a chlorine atom”,
The following formula (B)

"Wherein, X ^b1 is ^{X b2 -NH-C (= O} ) ^{group, X b2 -C (= O)} -NH-CH 2 group, X ^b3 -S (O) group, may pyrrole substituted -1-yl group, optionally substituted imidazol-1-yl group, optionally substituted pyrazol-1-yl group or optionally substituted 1,2,4-triazol-1-yl group X ^b2 represents an optionally substituted C1-C4 haloalkyl group such as a 2,2,2-trifluoroethyl group or an optionally substituted C3-C6 cycloalkyl group such as a cyclopropyl group; X ^b3 represents an optionally substituted C1-C4 alkyl group such as methyl, and X ^b4 represents a hydrogen atom, a chlorine atom, a cyano group, or a methyl group.
Any compound represented by formula (C):

“In the formula, X ^c1 is an optionally substituted C1-C4 alkyl group such as a 3,3,3-trifluoropropyl group or an optionally substituted C1-C4 alkyl group such as a 2,2,2-trichloroethoxy group. C4 represents an optionally substituted phenyl group such as a C4 alkoxy group, a 4-cyanophenyl group or an optionally substituted pyridyl group such as a 2-chloro-3-pyridyl group, and X ^c2 represents a methyl group or a trifluoromethylthio group. Represents a group, and X ^c3 represents a methyl group or a halogen atom. ”

As an active ingredient of the repellent, for example, N, N-diethyl-m-toluamide, limonene, linalool, citronellal, menthol, menthone, hinokitiol, geraniol, eucalyptol, indoxacarb, caran-3,4-diol, MGK-R-326, MGK-R-874 and BAY-KBR-3023.
Examples of the synergist include 5- [2- (2-butoxyethoxy) ethoxymethyl] -6-propyl-1,3-benzodioxole, N- (2-ethylhexyl) bicyclo [2.2.1]. ] Hept-5-ene-2,3-dicarboximide, octachlorodipropyl ether, isobornyl thiocyanoacetate, N- (2-ethylhexyl) -1-isopropyl-4-methylbicyclo [2.2.2] Oct-5-ene-2,3-dicarboximide is mentioned.

The spider control method of the present invention is carried out by applying the spider control composition of the present invention to a spider or a spider habitat (plant, soil, house, vehicle interior, etc.). Moreover, nesting is prevented by applying the spider control composition of the present invention to spiders or spider habitats.
Specific examples of the application method of the spider control composition of the present invention include the following methods, which can be appropriately selected depending on the form, use place, and the like of the spider control composition of the present invention.
(1) A method of treating a spider or a spider habitat as it is with the spider control composition of the present invention.
(2) A method of spraying the spider or the spider habitat after diluting the spider control composition of the present invention with a solvent such as water.
In this case, the spider control composition of the present invention, which is usually formulated into an emulsion, wettable powder, flowable agent, microcapsule formulation, or the like, is adjusted so that the concentration of the ester compound is 0.01 to 10,000 ppm. Dilute.
(3) A method in which the active ingredient is volatilized by heating the spider control composition of the present invention in a habitat of the spider.
In this case, both the application amount and application concentration of the ester compound can be appropriately determined according to the form of the spider control composition of the present invention, the application time, the application location, the application method, the type of spider, the damage situation, etc. it can.

When the spider control composition of the present invention is used for prevention of epidemics, the application amount is usually 0.0001 to 1000 mg / m ³ as the amount of the ester compound when applied to a space, and when applied to a plane. Is 0.0001 to 1000 mg / m ² . Insecticidal incense sticks, electric insecticidal mats, and the like are applied by volatilizing active ingredients by heating in accordance with the formulation form. Resin transpiration agents, paper transpiration agents, non-woven fabric transpiration agents, knitted fabric transpiration agents, sublimable tablets and the like can be used, for example, by leaving them in the space where they are applied, and by placing the preparation under ventilation.
The space to which the spider control composition of the present invention is applied for prevention of epidemiology mainly includes outdoor open spaces, and further indoor spaces such as closets, closets, Japanese dance, cupboards, toilets, bathhouses, storerooms, living rooms. It can also be applied in cafeterias, warehouses, cars, etc.

Hereinafter, the present invention will be described in more detail with reference to formulation examples and test examples, but the present invention is not limited to these examples.
First, formulation examples of the spider control composition of the present invention are shown. In Examples, unless otherwise specified, parts means parts by mass.

Formulation Example 1
9.9 parts of the present ester compound is dissolved in 37.5 parts of xylene and 37.5 parts of N, N-dimethylformamide, and 9.1 parts of polyoxyethylene styryl phenyl ether and 6 parts of calcium dodecylbenzenesulfonate are added thereto. In addition, mix well with stirring to obtain an emulsion.

Formulation Example 2
To 40 parts of this ester compound, 5 parts of Solpol 5060 (registered trademark of Toho Chemical Co., Ltd.) is added and mixed well. Carplex # 80 (registered trademark of Shionogi & Co., synthetic silicon hydroxide fine powder) 32 parts, 300 mesh Add 23 parts of diatomaceous earth and mix with a juice mixer to obtain a wettable powder.

Formulation Example 3
To 3.3 parts of this ester compound, add 5 parts of synthetic silicon hydroxide fine powder, 5 parts of sodium dodecylbenzenesulfonate, 30 parts of bentonite, and 56.7 parts of clay, and mix well with stirring. Of water, further stirred, granulated with a granulator, and dried by ventilation to obtain granules.

Formulation Example 4
The ester compound 5.5 parts, 1 part of synthetic hydrous silicon oxide fine powder, 1 part of Doreles B (Sankyo) as a flocculant and 7 parts of clay are mixed well in a mortar, and then stirred and mixed in a juice mixer. 85.5 parts of cut clay is added to the resulting mixture and mixed well with stirring to obtain a powder.

Formulation Example 5
The preparation is obtained by mixing 11 parts of the present ester compound, 35 parts of white carbon containing half the amount of polyoxyethylene alkyl ether sulfate ammonium salt and 54 parts of water and finely pulverizing them by a wet pulverization method.

Formulation Example 6
0.15 part of this ester compound is mixed with 99.85 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registered Trademark) to obtain an oil agent.

Formulation Example 7
0.15 part of the present ester compound and 0.1 part of allethrin are dissolved in 10 parts of dichloromethane and mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 8
0.15 part of the present ester compound and 0.1 part of beta cyfluthrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registered Trademark) to obtain an oil agent. obtain.

Formulation Example 9
0.15 part of the present ester compound and 0.1 part of bifenthrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 10
0.15 part of the present ester compound and 0.1 part of cyfluthrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 11
0.15 part of the present ester compound and 0.1 part of cyhalothrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil.

Formulation Example 12
0.15 part of the present ester compound and 0.1 part of cypermethrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent. .

Formulation Example 13
0.15 part of the present ester compound and 0.1 part of empentrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 14
0.15 part of the present ester compound and 0.1 part of deltamethrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil.

Formulation Example 15
0.15 part of the present ester compound and 0.1 part of fenpropatoline are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registered Trademark) to obtain an oil agent. obtain.

Formulation Example 16
0.15 part of the present ester compound and 0.1 part of flumethrin are dissolved in 10 parts of dichloromethane and mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 17
0.15 part of the present ester compound and 0.1 part of permethrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 18
0.15 part of this ester compound and 0.1 part of tefluthrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 19
0.15 part of the present ester compound and 0.1 part of tralomethrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 20
0.15 part of the present ester compound and 0.1 part of transfluthrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registered Trademark) to obtain an oil agent. obtain.

Formulation Example 21
0.15 part of the present ester compound and 0.1 part of tetramethrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 22
0.15 part of the present ester compound and 0.1 part of phenothrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil.

Formulation Example 23
0.15 part of the present ester compound and 0.1 part of ciphenothrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent. .

Formulation Example 24
0.15 parts of the present ester compound and 0.1 parts of alpha cypermethrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registered Trade Name) to obtain an oil agent. obtain.

Formulation Example 25
0.15 part of this ester compound and 0.1 part of flamethrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of isoparaffin solvent (Isopar M, Exxon Chemical Registered Trademark) to obtain an oil agent.

Formulation Example 26
0.02 part of the present ester compound and 0.01 part of metfurthrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.97 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 27
0.05 part of the present ester compound and 0.05 part of dimefluthrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 28
0.15 part of the present ester compound and 0.1 part of profluthrin are dissolved in 10 parts of dichloromethane, and this is mixed with 89.75 parts of an isoparaffin solvent (Isopar M, Exxon Chemical Registration) to obtain an oil agent.

Formulation Example 29
Put 0.15 parts of this ester compound and 49.85 parts of Neothiozole (Chuo Kasei Co., Ltd.) into an aerosol can, and after mounting an aerosol valve, fill 25 parts of dimethyl ether and 25 parts of LPG, add shake, An oily aerosol is obtained by mounting.

Formulation Example 30
A mixture comprising 0.55 part of the present ester compound, 0.01 part of BHT, 5 parts of xylene, 3.44 parts of deodorized kerosene and 1 part of an emulsifier {Atmos 300 (registered trademark of Atlas Chemical Company)}, and 50 parts of distilled water Is filled into an aerosol container, a valve portion is attached, and 40 parts of propellant (LPG) is pressurized and filled through the valve to obtain an aqueous aerosol.

Formulation Example 31
A paper work piece having a honeycomb structure of 0.5 cm (thickness) × 69 cm (length) × 0.2 cm (width) is wound from one end to form a substantially cylindrical shape having a diameter of 5.5 cm and a height of 0.2 cm. A carrier is prepared. An appropriate amount of a solution obtained by dissolving 5.5 parts of the present ester compound in 94.5 parts of acetone is uniformly applied to the carrier, and then the acetone is air-dried to obtain a paper transpiration agent.

Formulation Example 32
A three-dimensional knitted fabric (trade name: Fusion, model number: AKE69440, distributor: Asahi Kasei Fibers Co., Ltd., thickness: 4.3 mm, basis weight: 321 g / m ² , made of polyamide) is cut into a substantially circular shape having a diameter of 5 cm. An appropriate amount of a solution obtained by dissolving 5.5 parts of the present ester compound in 94.5 parts of acetone is uniformly applied to the cut three-dimensional knitted fabric, and then acetone is air-dried to obtain a knitted fabric transpiration agent.

Formulation Example 33
97.8 parts by weight of ethylene-methyl methacrylate copolymer (methyl methacrylate content: 10% by weight, MFR = 2 [g / 10min]) and 2.2 parts of the ester compound were added to a 45 mmφ co-directional twin screw extruder. The mixture is melt-kneaded at 130 ° C. at 150 ° C., further melt-kneaded at 150 ° C. with a 40 mmφ extruder, extruded into a sheet form from a T die, and cooled with a cooling roll to obtain a resin transpiration agent.

Formulation Example 34
97.8 parts by weight of ethylene-vinyl acetate copolymer (vinyl acetate content: 10% by weight, MFR = 2 [g / 10min]) and 2.2 parts of the ester compound were mixed in a 45 mmφ co-directional twin screw extruder. It is melt-kneaded at 130 ° C., melt-kneaded at 150 ° C. with a 40 mmφ extruder, extruded into a sheet form from a T die, and cooled with a cooling roll to obtain a resin transpiration agent.

Formulation Example 35
5.5 parts of this ester compound is dissolved in 94.5 parts of acetone. An appropriate amount of this solution is applied to a paper (2000 cm ² ) having a foldable structure, and acetone is air-dried to obtain a paper transpiration agent.

Formulation Example 36
A solution is obtained by dissolving 3.3 parts of the ester compound in 14.6 parts of acetone. To this solution, add 0.2 parts of zinc oxide, 1.0 part of α starch and 42.8 parts of azodicarbonamide, add 38.1 parts of water, knead, shape into granules with an extruder, and dry. . A granule containing the compound of the present invention is placed in the upper space of a container whose central part is divided by an aluminum partition, and 50 g of calcium oxide is accommodated in the lower space of the container to obtain a smoke agent.

Formulation Example 37
Mix 0.5 parts of zinc oxide, 2 parts of α starch and 97.5 parts of azodicarbonamide, add water and knead the mixture, shape the kneaded product with an extruder and dry it to obtain granules. . 2 g of these granules are uniformly impregnated with an acetone solution containing 0.638 g of the present ester compound, and then dried to obtain granules. The granule and 50 g of calcium oxide are accommodated in the lower space of the container whose central part is divided by an aluminum partition wall to obtain a smoke agent.

Formulation Example 38
0.55 g of this ester compound is dissolved in 20 ml of acetone, and this solution is mixed with 99.4 g of a carrier for mosquito coils (mixed in a weight ratio of tab powder: straw powder: wood powder in a weight ratio of 4: 3: 3) and 0.3 g of green pigment. After adding to the mixture and stirring and mixing uniformly, 120 ml of water is added, and the kneaded mixture is molded and dried to obtain an insecticidal incense.

Formulation Example 39
A solution obtained by mixing 11 parts of this ester compound, 39.5 parts of acetyltributyl citrate, 39.5 parts of isononyl adipate, 5 parts of a blue pigment and 5 parts of a fragrance, 3.4 cm × 2.1 cm, thickness An electric insecticidal mat is obtained by uniformly impregnating a 0.22 cm electric mat substrate (a mixture of cotton linter and pulp mixture fibrils in a plate shape).

Formulation Example 40
Absorbent core (inorganic powder hardened with binder and sintered), 0.11 part of this ester compound dissolved in 99.89 parts of deodorized kerosene, placed in a vinyl chloride container, and heated at the top with a heater To obtain a part for a liquid absorption core type heat transpiration insecticide.

Formulation Example 41
Put 0.22 parts of this ester compound and 49.78 parts of neothiozole (Chuo Kasei Co., Ltd.) into an aerosol can, and after mounting an aerosol valve, fill 25 parts of dimethyl ether and 25 parts of LPG, add shake, and inject all An aerosol agent is obtained by mounting a type aerosol actuator.

  Next, it will be shown as a test example that the spider control composition of the present invention has an excellent control effect on spiders.

Test example 1
4-methoxymethyl-2,3,5,6-tetrafluorobenzyl = (1R) -trans-3- (2-cyano-1-propenyl (E / Z = 1/9))-2,2-dimethylcyclo Propanecarboxylate 0.05 part, Neothiozole (Chuo Kasei Co., Ltd.) 59.
95 parts are put into an aerosol can, and a valve part is attached to the can.
Liquefied petroleum gas) 40 parts was filled to obtain an aerosol (hereinafter referred to as the present spider control composition (1)).
One spider was released into a polyethylene cup (lower diameter 10.6 cm, upper diameter 12 cm, height 7 cm) and covered with 16 mesh nylon gorge. The cup was placed on the inner bottom of a cylindrical chamber having an inner diameter of 16.5 cm and a height of 60 cm. 500 mg of the spider control composition (1) was sprayed from the upper part of the cylindrical chamber toward the cup. The cup was removed while ventilating the cylindrical chamber 20 seconds after spraying, and the number of insects knocked down after 10 minutes was counted. As a result, the knockdown rate was 100%.

  Spiders can be controlled by using the spider control composition of the present invention.

Claims (3)

A spider control composition comprising 4-methoxymethyl-2,3,5,6-tetrafluorobenzyl = 3- (2-cyano-1-propenyl) -2,2-dimethylcyclopropanecarboxylate as an active ingredient. The spider control composition according to claim 1, which is an aerosol agent. A method for controlling spiders, comprising applying an effective amount of the spider control composition according to claim 1 or 2 to a spider or a habitat of a spider.