JP2011111705A - Machine sewing thread for down-containing textile product - Google Patents
Machine sewing thread for down-containing textile product Download PDFInfo
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- JP2011111705A JP2011111705A JP2009272302A JP2009272302A JP2011111705A JP 2011111705 A JP2011111705 A JP 2011111705A JP 2009272302 A JP2009272302 A JP 2009272302A JP 2009272302 A JP2009272302 A JP 2009272302A JP 2011111705 A JP2011111705 A JP 2011111705A
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- sewing thread
- water repellent
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- 239000005871 repellent Substances 0.000 claims abstract description 51
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- PEVRKKOYEFPFMN-UHFFFAOYSA-N 1,1,2,3,3,3-hexafluoroprop-1-ene;1,1,2,2-tetrafluoroethene Chemical group FC(F)=C(F)F.FC(F)=C(F)C(F)(F)F PEVRKKOYEFPFMN-UHFFFAOYSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical group [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- CARJPEPCULYFFP-UHFFFAOYSA-N 5-Sulfo-1,3-benzenedicarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(S(O)(=O)=O)=C1 CARJPEPCULYFFP-UHFFFAOYSA-N 0.000 description 1
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- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
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Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
Description
優れた伸縮性や軽量性を実現しつつ、羽毛の抜け出しやパッカリングを効果的に防止することが可能な羽毛入り繊維製品用ミシン糸、該羽毛入り繊維製品用ミシン糸を用いた羽毛入り繊維製品、及び、羽毛入り繊維製品の製造方法に関する。 Sewing thread for feathered fiber products that can effectively prevent feather pull-out and puckering while realizing excellent stretchability and light weight, and feathered fibers using the sewing thread for feathered textile products The present invention relates to a product and a method for producing a fiber product containing feathers.
従来より、ジャケット、ジャンパー、ブルゾン等の防寒具の内部に羽毛を使用することで、断熱効果の高い空気層を効率的に形成し、高い保温効果を得ることが行われている。
例えば、着用者と接する裏地と、外界と接する表地との間に羽毛を充填したダウンジャケットが良く知られている。
Conventionally, by using feathers inside a cold protection device such as a jacket, jumper, or blouson, an air layer having a high heat insulating effect is efficiently formed, and a high heat retaining effect is obtained.
For example, a down jacket in which feathers are filled between a lining in contact with the wearer and a surface in contact with the outside world is well known.
ダウンジャケットでは、表地と裏地の間に羽毛を詰め込んだ後、キルティングを行うのが一般的であるが、このような方法で作製されたダウンジャケットは、詰め込んだ羽毛の上からキルティングを行うので、キルティングの縫目から羽毛が脱離するという問題があった。羽毛の脱離が生じると、着用者に不快感を与えるだけでなく、ダウンジャケットの保温性や着心地が低下してしまうという事態を招いていた。 In the down jacket, it is common to quilt after stuffing feathers between the outer and lining, but the down jacket made by such a method quilts from above the stuffed feathers, There was a problem that feathers were detached from the quilting stitches. When the feathers are detached, not only does the wearer feel uncomfortable, but also the thermal insulation and comfort of the down jacket are reduced.
これに対しては、表地と羽毛の間、裏地と羽毛の間に袋状に縫ったダウンパックと呼ばれる中生地を設けることが一般的であるが、ダウンパックには、羽毛の脱離(抜け)防止のために高密度の織物が使用されることから、伸縮性が低下したり、重量が増加したりして、特にスポーツウェア等の用途には不向きであった。 For this, it is common to provide an intermediate fabric called a downpack that is sewn in a bag shape between the outer material and the feathers, and between the lining and the feathers. ) Since a high-density fabric is used for prevention, the stretchability is reduced and the weight is increased, so that it is not particularly suitable for applications such as sportswear.
例えば、特許文献1には、キルティング部分の縫目からの羽毛抜け出しを防止するために、中生地(ダウンパック)をあらかじめ2本の縫目で縫っておいて、後に中生地の上に表生地又は裏生地を重ねて、この2本の縫目の中心部分に縫目を形成して表生地又は裏生地と中生地を縫い合わせることにより、表側の縫目からの羽毛抜け出しを防止したダウンウエアが記載されている。
しかしながら、このような方法は、製造工程が極めて煩雑であり、中生地を使用することによる伸縮性の低下や、重量の増加といった問題も解決されていなかった。
For example, Patent Document 1 discloses that in order to prevent the quilting portion from coming out of the feathers, the intermediate fabric (down pack) is sewn in advance with two stitches, and later on the intermediate fabric on the intermediate fabric. Or down wear that prevents the feathers from slipping out from the front seam by stacking the back fabric and forming a seam at the center of these two stitches and stitching the front fabric or back fabric and the middle fabric together Are listed.
However, in such a method, the manufacturing process is extremely complicated, and problems such as a decrease in stretchability and an increase in weight due to the use of the inner fabric have not been solved.
また、特許文献2には、発泡エマルジョン樹脂を基布にコーティングし、コーティング層に、基布よりも伸縮性が小さいガーゼ等の布帛を重ね合わせ、該コーティング層を加熱架橋してなる羽毛の抜け防止生地が記載されている。
しかしながら、このような方法も、コーティング工程や加熱架橋工程を要することから、製造工程が極めて煩雑であり、伸縮性の小さい布帛を使用することで、伸縮性の低下や、重量の増加といった問題も解決されていなかった。
Patent Document 2 discloses that a foamed emulsion resin is coated on a base fabric, a fabric such as gauze having a lower stretchability than that of the base fabric is layered on the coating layer, and the coating layer is heated and cross-linked. Prevention fabric is described.
However, such a method also requires a coating process and a heat-crosslinking process, so that the manufacturing process is extremely complicated, and the use of a fabric having low stretchability causes problems such as a decrease in stretchability and an increase in weight. It was not solved.
本発明は、上記現状に鑑み、優れた伸縮性や軽量性を実現しつつ、羽毛の抜け出しやパッカリングを効果的に防止することが可能な羽毛入り繊維製品用ミシン糸、該羽毛入り繊維製品用ミシン糸を用いた羽毛入り繊維製品、及び、羽毛入り繊維製品の製造方法を提供することを目的とする。 SUMMARY OF THE INVENTION In view of the above situation, the present invention provides a sewing thread for a fiber product with feathers that can effectively prevent pull-out and puckering of feathers while realizing excellent stretchability and light weight, and the fiber products with feathers. It is an object of the present invention to provide a feathered fiber product using a sewing machine thread and a method for producing a feathered fiber product.
本発明は、ポリエステル繊維糸条に、撥水剤による撥水処理、及び、制電処理が施されている羽毛入り繊維製品用ミシン糸である。
以下に本発明を詳述する。
The present invention is a sewing thread for a fiber product with feathers, in which a polyester fiber yarn is subjected to a water repellent treatment with a water repellent and an antistatic treatment.
The present invention is described in detail below.
本発明者らは、鋭意検討した結果、ポリエステル繊維糸条に、撥水剤による撥水処理、及び、制電処理が施されているミシン糸を用いて羽毛入り繊維製品を製造する場合、縫製時に撥水効果と制電効果を発現することで、得られる羽毛入り繊維製品は、優れた伸縮性や軽量性を実現しつつ、羽毛の抜け出しやパッカリングを効果的に防止できることを見出し、本発明を完成するに至った。 As a result of intensive studies, the inventors have sewed polyester fiber yarns using a sewing thread that has been subjected to water repellent treatment with a water repellent and antistatic treatment, Occasionally, it is found that the resulting fiber product with feathers can effectively prevent feather pull-out and puckering while realizing excellent stretchability and light weight by expressing water repellent effect and antistatic effect. The invention has been completed.
本発明の羽毛入り繊維製品用ミシン糸は、ポリエステル繊維糸条に、撥水剤による撥水処理、及び、制電処理が施されたものである。なお、上記撥水処理及び制電処理はどちらが先にされていてもよい。 The sewing thread for a fiber product with feathers of the present invention is obtained by subjecting a polyester fiber yarn to a water repellent treatment with a water repellent and an antistatic treatment. Note that either the water repellent treatment or the antistatic treatment may be performed first.
上記ポリエステル繊維糸条を構成するポリエステルとしては、例えば、ポリエチレンテレフタレート、ポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンナフタレート等が挙げられる。また、これにイソフタル酸や5−スルホイソフタル酸金属塩等の芳香族ジカルボン酸やアジピン酸、セバシン酸等の脂肪族ジカルボン酸やε−カプロラクトン等のヒドロキシカルボン酸縮合物、ジエチレングリコールやトリメチレングリコール、テトラメチレングリコール、ヘキサメチレングリコール等のグリコール成分等を共重合した共重合ポリエステルを用いてもよい。本発明では、特にポリエチレンテレフタレート、ポリトリメチレンテレフタレート、ポリブチレンテレフタレート、ポリエチレンナフタレートを用いることが好ましい。 Examples of the polyester constituting the polyester fiber yarn include polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, and polyethylene naphthalate. In addition, aromatic dicarboxylic acids such as isophthalic acid and 5-sulfoisophthalic acid metal salts, aliphatic dicarboxylic acids such as adipic acid and sebacic acid, and hydroxycarboxylic acid condensates such as ε-caprolactone, diethylene glycol and trimethylene glycol, Copolyesters obtained by copolymerizing glycol components such as tetramethylene glycol and hexamethylene glycol may also be used. In the present invention, it is particularly preferable to use polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, or polyethylene naphthalate.
上記ポリエステル繊維糸条は、スパン糸であることが好ましい。上記スパン糸は、毛羽を有することから、羽毛入り繊維製品に用いた場合に効果的に羽毛の抜けを防止することができ、可縫性にも優れる。 The polyester fiber yarn is preferably a spun yarn. Since the above-mentioned spun yarn has fluff, when used in a fiber product containing feathers, the spun yarn can be effectively prevented from falling off and has excellent sewability.
上記スパン糸としては、市販のポリエステル100%紡績糸が例示できる。用いる繊維の繊度は150〜950dtexが好ましく、200〜600dtexがより好ましい。 Examples of the spun yarn include commercially available polyester 100% spun yarn. The fineness of the fiber used is preferably 150 to 950 dtex, more preferably 200 to 600 dtex.
上記ポリエステル繊維糸条は、フィラメント糸であることが好ましい。上記フィラメント糸は、剛性や寸法安定性を有することから、パッカリングの発生を効果的に防止することができる。 The polyester fiber yarn is preferably a filament yarn. Since the filament yarn has rigidity and dimensional stability, occurrence of puckering can be effectively prevented.
上記フィラメント糸としては、モノ又はマルチフィラメントを用いることができるが、マルチフィラメントを用いることが好ましい。 Monofilament or multifilament can be used as the filament yarn, but multifilament is preferably used.
上記フィラメント糸としては、毛羽加工が施されているものを用いることが好ましい。これにより、スパン糸の利点とフィラメント糸の利点とを両立させることが可能となる。
上記毛羽加工としては、具体的には例えば、特開2002−155444号公報に記載の上撚マルチフィラメント糸条の毛羽加工方法や、特開2002−61043号公報に記載の多数本の構成フィラメント単糸と、実撚りを加えた下撚マルチフィラメント糸条とを使用して毛羽加工を施す方法等が例示できる。
As the filament yarn, it is preferable to use one that has been subjected to fluff processing. This makes it possible to achieve both the advantages of the spun yarn and the advantages of the filament yarn.
Specific examples of the fluff processing include, for example, an upper twist multifilament yarn fluff processing method described in JP-A No. 2002-155444 and a plurality of constituent filament units described in JP-A No. 2002-61043. Examples thereof include a method of performing fluffing using a yarn and an under-twisted multifilament yarn to which an actual twist is added.
上記フィラメント糸を用いる場合、単糸繊度は1.0〜4.0dtexが好ましく、1.5〜3.5dtexであることがより好ましい。
また、上記フィラメント糸として、マルチフィラメントを用いる場合、フィラメント数は12〜400であることが好ましく、総繊度は120〜800dtexが好ましく、150〜300dtexであることがより好ましい。
When the filament yarn is used, the single yarn fineness is preferably 1.0 to 4.0 dtex, and more preferably 1.5 to 3.5 dtex.
When a multifilament is used as the filament yarn, the number of filaments is preferably 12 to 400, and the total fineness is preferably 120 to 800 dtex, and more preferably 150 to 300 dtex.
本発明の羽毛入り繊維製品用ミシン糸は、撥水剤による撥水処理が施されていることで、糸に撥水機能を付与することができる。一般的に羽毛は8%前後の水分を含んでいることから、本発明の羽毛入り繊維製品用ミシン糸を用いた羽毛入り繊維製品では、縫製時や着用時に羽毛を縫目に近づけないようにする効果があり、その結果、縫目部分からの羽毛の抜けを防止することができる。
また、本発明の羽毛入り繊維製品用ミシン糸を用いた羽毛入り繊維製品において、縫目からの水分の浸入を防止する吸水抑制効果を有する。
The sewing thread for a fiber product with feathers of the present invention can be imparted with a water repellent function by being subjected to a water repellent treatment with a water repellent. In general, since feathers contain about 8% of moisture, the feathered fiber product using the sewing thread for a fiber product with feathers of the present invention keeps the feathers away from the seam when sewing or wearing. As a result, it is possible to prevent the feathers from coming off from the seam portion.
Moreover, in the fiber product with feathers using the sewing thread for the fiber product with feathers of the present invention, it has a water absorption suppressing effect of preventing moisture from entering from the stitches.
上記撥水剤としては、フッ素系撥水剤、シリコーン系撥水剤等を用いることが好ましい。
上記フッ素系撥水剤としては、一般に撥水剤として使用されている化合物を使用することができ、例えば、ポリペンタデカフルオロオクチルアクリレート、ポリトリフルオロエチルアクリレート、テトラフルオロエチレン−ヘキサフルオロプロピレン等のフッ素系化合物等からなるものが挙げられる。
上記シリコーン系撥水剤としては、例えば、ジメチルポリシロキサン、ジメチルシロキサンの分子末端あるいは側鎖に水酸基、アミノ基、エポキシ基、ポリエーテル基等を導入した変性シリコーン化合物等を使用することができる。これらのフッ素系撥水剤やシリコーン系撥水剤は、単独又は2種類以上を混合して使用することができるが、シリコーン系撥水剤の単独使用では高いレベルの撥水性能を付与しにくい傾向がある。これらの撥水剤は、エマルジョンあるいは溶剤に溶解した状態で使用される。
As the water repellent, it is preferable to use a fluorine water repellent, a silicone water repellent or the like.
As the fluorine-based water repellent, a compound generally used as a water repellent can be used. For example, polypentadecafluorooctyl acrylate, polytrifluoroethyl acrylate, tetrafluoroethylene-hexafluoropropylene, etc. What consists of a fluorine-type compound etc. is mentioned.
As the silicone-based water repellent, for example, dimethylpolysiloxane, a modified silicone compound in which a hydroxyl group, an amino group, an epoxy group, a polyether group or the like is introduced into the molecular end or side chain of dimethylsiloxane can be used. These fluorine-based water repellents and silicone-based water repellents can be used alone or in admixture of two or more, but it is difficult to impart a high level of water-repellent performance when used alone. Tend. These water repellents are used in a state of being dissolved in an emulsion or a solvent.
本発明において、上記ポリエステル繊維糸条に撥水剤による撥水処理を施す方法としては、所定濃度の撥水剤を含有する水溶液又は溶剤溶液に上記ポリエステル繊維糸条を浸漬した後、マングル等で絞る方法や、所定濃度の撥水剤を含有する水溶液又は溶剤溶液をスプレーで塗布する等の方法を採用することができる。このように所定濃度の撥水剤を含有する水溶液又は溶剤溶液を付与した後、乾燥することにより撥水処理を行う。 In the present invention, the polyester fiber yarn may be subjected to a water repellent treatment with a water repellent, after immersing the polyester fiber yarn in an aqueous solution or solvent solution containing a predetermined concentration of water repellent, A method of squeezing, a method of applying an aqueous solution or a solvent solution containing a water repellent at a predetermined concentration by spraying, and the like can be employed. Thus, after providing the aqueous solution or solvent solution containing the water repellent of a predetermined density | concentration, water-repellent treatment is performed by drying.
上記撥水剤のポリエステル繊維への付着量は、繊維重量に対し0.5〜5重量%であることが好ましく、より好ましくは0.8〜1.8重量%、さらに好ましくは1.2〜1.6重量%である。上記撥水剤の付着量を上記範囲内とすることで、本発明の羽毛入り繊維製品用ミシン糸の撥水性を適度なものとすることができる。 The amount of the water repellent attached to the polyester fiber is preferably 0.5 to 5% by weight, more preferably 0.8 to 1.8% by weight, and still more preferably 1.2 to 1.6% by weight. By making the adhesion amount of the water repellent within the above range, the water repellency of the sewing thread for a fiber product with feathers of the present invention can be made appropriate.
本発明の羽毛入り繊維製品用ミシン糸は、制電処理が施されていることで、糸に制電性を付与して、帯電しにくくすることができる。羽毛や、表地、裏地は帯電しやすいが、羽毛入り繊維製品用ミシン糸が制電性を有することで、これらとの摩擦による摩擦帯電が低減され、静電気を帯びにくくなる。また、本発明の羽毛入り繊維製品用ミシン糸を用いた羽毛入り繊維製品において、縫目における摩擦による帯電を防止する帯電制効果を有する。
なお、本明細書において、「制電処理」とは、糸に制電性を付与する処理のことをいい、例えば、制電加工剤によって制電性を付与する方法や、導電性を有する糸と組み合わせることで導電複合糸とする方法等が挙げられる。
Since the sewing thread for a fiber product with feathers of the present invention is subjected to antistatic treatment, it is possible to impart antistaticity to the yarn and make it difficult to be charged. Feathers, outer fabrics and linings are easy to be charged. However, since the sewing yarn for feathered textile products has antistatic properties, frictional electrification due to friction with them is reduced, and it becomes difficult to be charged with static electricity. Moreover, the feathered fiber product using the sewing thread for a fiber product with feathers of the present invention has a charge control effect that prevents electrification due to friction at the stitches.
In the present specification, “antistatic treatment” refers to a treatment for imparting antistatic properties to the yarn. For example, a method of imparting antistatic properties to the yarn by an antistatic agent or a conductive yarn. And the like, and the like.
上記制電加工剤としては、例えば、高級炭化水素化合物、シリコーン、スルホン酸塩化合物、リン酸エステル塩等を混合したものを使用することが好ましい。特にシリコーンとパラフィン等の高級炭化水素化合物との混合物を用いることが好ましい。
また、ポリエチレングリコールを親水性成分とし、これをアクリル系やポリエステルにグラフト重合した樹脂タイプの制電加工剤や、ポリアルキレングリコール(例えば、ポリエチレングリコール)単位(基)と4級アンモニウム塩基等の制電性能を有する官能基を有し、かつ少なくとも2個のイソシアネート基を有する化合物からなる制電加工用ポリウレタン樹脂、スルホン酸塩と4級アンモニウム塩とイミダゾリニウム塩とからなる制電加工剤等が挙げられる。
As the antistatic processing agent, it is preferable to use, for example, a mixture of a higher hydrocarbon compound, silicone, sulfonate compound, phosphate ester salt, or the like. It is particularly preferable to use a mixture of silicone and a higher hydrocarbon compound such as paraffin.
In addition, polyethylene glycol is used as a hydrophilic component, and this is a resin-type antistatic agent obtained by graft polymerization to acrylic or polyester, and a polyalkylene glycol (for example, polyethylene glycol) unit (group) and a quaternary ammonium base. Antistatic processing polyurethane resin composed of a compound having a functional group having electrical performance and having at least two isocyanate groups, antistatic processing agent composed of sulfonate, quaternary ammonium salt and imidazolinium salt, etc. Is mentioned.
本発明において、上記ポリエステル繊維糸条に制電加工剤により制電処理を施す方法としては、所定濃度の制電加工剤を含有する水溶液又は溶剤溶液に上記ポリエステル繊維糸条を浸漬した後、マングル等で絞る方法や、所定濃度の制電加工剤を含有する水溶液又は溶剤溶液をスプレーで塗布する等の方法を採用することができる。このように所定濃度の制電加工剤を含有する水溶液又は溶剤溶液を付与した後、乾燥することにより撥水処理を行う。 In the present invention, the polyester fiber yarn is subjected to an antistatic treatment with an antistatic agent, and the polyester fiber yarn is immersed in an aqueous solution or a solvent solution containing the antistatic agent at a predetermined concentration, and then mangled. For example, a method of squeezing by a method such as spraying an aqueous solution or a solvent solution containing an antistatic agent at a predetermined concentration can be employed. Thus, after providing the aqueous solution or solvent solution containing the antistatic processing agent of a predetermined density | concentration, water-repellent treatment is performed by drying.
上記制電加工剤のポリエステル繊維への付着量は、繊維重量に対し0〜5重量%であることが好ましく、より好ましくは0.1〜1.8重量%、さらに好ましくは1.0〜1.5重量%である。上記制電加工剤の付着量を上記範囲内とすることで、本発明の羽毛入り繊維製品用ミシン糸の帯電防止性を適度なものとすることができる。 The adhesion amount of the antistatic agent to the polyester fiber is preferably 0 to 5% by weight, more preferably 0.1 to 1.8% by weight, and further preferably 1.0 to 1% with respect to the fiber weight. .5% by weight. By making the adhesion amount of the antistatic processing agent within the above range, the antistatic property of the sewing thread for a fiber product with feathers of the present invention can be made appropriate.
上記導電性を有する糸と組み合わせることで導電複合糸として使用する方法は、特にスパン糸やマルチフィラメント糸を使用する場合に有用であり、このような導電複合糸を用いることで、得られる羽毛入り繊維製品の摩擦帯電圧を低減させることができる。 The method used as a conductive composite yarn by combining with the above-mentioned conductive yarn is particularly useful when using a spun yarn or a multifilament yarn. The frictional voltage of the textile can be reduced.
上記導電性を有する糸としては、例えば、カーボンブラック、金属、金属化合物等の導電性微粒子や導電性高分子を繊維表面に付加した糸のほか、金属メッキ繊維、金属繊維、炭素繊維等が例示できる。また、カーボンブラック、金属、金属化合物等の導電性微粒子をブレンドした導電性を有するポリマーを用いて紡糸することにより繊維化したものや、導電性を有するポリマーと導電性微粒子をブレンドしていないポリマーとをコンジュゲート紡糸する方法により繊維化したもの等が例示できる。また、上記制電加工剤によって制電性を付与された糸も使用することができる。
なかでも、上記コンジュゲート紡糸によって得られる導電性を有する糸を用いた場合、別途組み合わせる繊維との物性差を小さくすることができ、組み合わされてなる導電複合糸としての取り扱いがしやすい点で特に好ましい。
Examples of the conductive thread include, for example, a thread obtained by adding conductive fine particles such as carbon black, metal, and metal compound, or a conductive polymer to the fiber surface, and metal plated fiber, metal fiber, carbon fiber, and the like. it can. Also, fibers that are made by spinning using conductive polymer blended with conductive fine particles such as carbon black, metal, metal compounds, etc., or polymers that are not blended with conductive polymer and conductive fine particles And the like that are made into fibers by the conjugate spinning method. Moreover, the thread | yarn provided with the antistatic property by the said antistatic processing agent can also be used.
In particular, when the conductive yarn obtained by the conjugate spinning is used, the difference in physical properties from the separately combined fiber can be reduced, particularly in terms of easy handling as a combined conductive composite yarn. preferable.
上記導電性を有する糸の電気抵抗値は、100〜1010Ω・cmであることが好ましく、105〜1010Ω・cmの範囲であることがより好ましい。
上記導電性を有する糸の繊度としては、10〜70dtexが好ましく、20〜40dtexがより好ましい。フィラメント数は1〜10が好ましく、3〜10がより好ましい。
上記スパン糸又はマルチフィラメント糸と、上記導電性を有する糸とを組み合わせる方法については特に限定されず、例えば、合撚、カバリング、複合紡績、単純に引き揃えての合糸等の公知の方法を使用することができる。
The electric resistance value of the conductive yarn is preferably 10 0 to 10 10 Ω · cm, and more preferably 10 5 to 10 10 Ω · cm.
The fineness of the conductive yarn is preferably 10 to 70 dtex, and more preferably 20 to 40 dtex. 1-10 are preferable and, as for the number of filaments, 3-10 are more preferable.
The method of combining the spun yarn or multifilament yarn and the conductive yarn is not particularly limited. For example, a known method such as twisting, covering, composite spinning, or simply spun together. Can be used.
本発明の羽毛入り繊維製品用ミシン糸を用いて、羽毛入り繊維製品を製造することができる。このような羽毛入り繊維製品もまた本発明の1つである。 Using the sewing thread for a fiber product with feathers of the present invention, a fiber product with feathers can be produced. Such a fiber product with feathers is also one aspect of the present invention.
上記羽毛入り繊維製品としては、寝具や、ジャケット、ジャンパー、ブルゾン等の衣料品、服飾小物類等が挙げられる。
なお、「羽毛」とは、一般的に、芯が小さく柔らかい、綿毛のような鳥羽のことを指し、衣料用途に使用される羽毛としては、ダウンとフェザーを混合したものが通常使用されている。ここでいうダウンとは、カモ、アヒル、ガチョウなど、水鳥の胸部分に生えている非常に柔らかい羽のことで、中央から柔らかい糸状の羽が放射線状に伸びた球形状をしているものである。また、フェザーとは水鳥の体を覆う羽のことで、羽軸があり、細い毛が木の枝のように生えている。ちょうど木の葉のような形状をしており、ダウンに比べると硬く嵩高性も劣る。
Examples of the fiber product with feathers include bedding, clothing such as a jacket, jumper, and blouson, and accessories.
In addition, "feather" generally refers to a feather with a small core and soft fluff, and as a feather used for clothing, a mixture of down and feather is usually used. . Down here means extremely soft feathers that grow on the chest of water birds, such as ducks, ducks, geese, etc., and they have a spherical shape with soft filamentous feathers extending radially from the center. is there. Feathers are wings that cover the body of a waterfowl. They have wing shafts and thin hairs grow like branches of a tree. It is shaped like a leaf, harder and less bulky than down.
本発明の羽毛入り繊維製品の製造方法は、表地と裏地との間に羽毛を有する羽毛入り繊維製品の製造方法であって、表地、羽毛、裏地の順に重ね合わせた後、本発明の羽毛入り繊維製品用ミシン糸を用いて、表地と裏地とを縫製する縫製工程を有する製造方法である。 The method for producing a feathered fiber product of the present invention is a method for producing a feathered fiber product having feathers between the outer material and the lining material, and after overlapping the outer material, the feather material, and the lining material in this order, It is a manufacturing method which has the sewing process which sew a surface material and a lining using the sewing thread for textiles.
本発明の製造方法では縫製工程において、中心部から外周面部に向かって漸次硬度が高くなっているミシン針を用いることが好ましい。
上記ミシン針は、生地を貫通する際の抵抗が少ないことから、針穴を小さくすることができ、また、粘着物等の付着を抑えることができることから、パッカリングを抑制することが可能となる。
In the manufacturing method of the present invention, it is preferable to use a sewing needle having a gradually increasing hardness from the center portion toward the outer peripheral surface portion in the sewing step.
Since the sewing needle has little resistance when penetrating the cloth, the needle hole can be made small, and adhesion of an adhesive or the like can be suppressed, so that puckering can be suppressed. .
上記ミシン針としては、金属針素材の最外表面に耐摩耗、摩擦軽減等の表面処理を行ったものが好ましい。例えば、硬質クロムメッキ層を備え、その表面を金属針素材と同等以上の硬度を有するショットによるショットピーニング処理されたもの、硬質クロムメッキ表面に凹凸を形成しフッ素樹脂をその凹部に埋め込み形成したもの、硬質クロムメッキに代えてフッ素樹脂含有ニッケル系メッキまたはセラミック微粒子含有ニッケル系メッキ処理を施したもの、セラミックコーティングを施したもの等が挙げられる。上記セラミックとしては窒化ホウ素、炭化珪素、アルミナ等が好ましい。 As the above-mentioned sewing needles, those obtained by subjecting the outermost surface of the metal needle material to surface treatment such as wear resistance and friction reduction are preferable. For example, a hard chrome plated layer with a surface that has been shot peened with a shot that has a hardness equal to or greater than that of a metal needle material, or a hard chrome plated surface with irregularities and fluorine resin embedded in the recesses In addition to the hard chrome plating, those subjected to fluorine resin-containing nickel-based plating or ceramic fine particle-containing nickel-based plating treatment, those subjected to ceramic coating, and the like. As the ceramic, boron nitride, silicon carbide, alumina and the like are preferable.
上記金属針素材の最外表面に耐摩耗、摩擦軽減等の表面処理を行ったミシン針は、耐久性が大幅に向上し、針類として充分な座屈剛性を持つことから、折損事故が殆どない高品質のミシン針として使用することができる。また、摩擦軽減により摩擦熱による針穴の拡大や、生地のばたつき、パッカリング等の縫製トラブルを軽減することができ、安定した縫製作業が行え、高速度運転が可能となる。 Sewing needles with surface treatments such as wear resistance and friction reduction on the outermost surface of the metal needle material have greatly improved durability and sufficient buckling rigidity as needles. Can not be used as a high quality sewing needle. Further, by reducing friction, it is possible to reduce needle holes due to frictional heat, flapping fabric, puckering, and other sewing troubles, so that stable sewing work can be performed and high-speed operation is possible.
上記ミシン針としては、工業用DBミシン針を例にすると、JIS規格の8〜11番手の針を用いることが好ましく、8〜9番手の針を用いることがより好ましい。 As the sewing needle, when an industrial DB sewing needle is taken as an example, it is preferable to use a JIS standard 8-11 needle, and more preferably an 8-9 needle.
上記縫製工程は、具体的には例えば、本発明の羽毛入り繊維製品用ミシン糸を下糸或いは上糸、又は、両方で使用して、上記ミシン針をミシンに装着し、表地と裏地とを縫製する方法等が挙げられる。 Specifically, the sewing step is, for example, using the sewing thread for a fiber product with feathers of the present invention as a lower thread or an upper thread, or both, attaching the sewing needle to the sewing machine, and attaching the outer material and the lining material. Examples include a sewing method.
本発明の羽毛入り繊維製品用ミシン糸を用いて羽毛入り繊維製品を製造した場合、縫製時に撥水効果と制電効果を発現することで、得られる羽毛入り繊維製品は、羽毛の抜け出しやパッカリングを効果的に防止することができる。
また、本発明の羽毛入り繊維製品用ミシン糸を用いることで、従来のようにダウンパック等の中生地を使用することなく、優れた伸縮性や軽量性を有する羽毛入り繊維製品を提供することができ、特にスポーツウェア等の用途に好適に使用することができる。
When a fiber product with feathers is produced using the sewing thread for fiber products with feathers of the present invention, the resulting fiber product with feathers exhibits a water-repellent effect and an antistatic effect during sewing, so Rings can be effectively prevented.
In addition, by using the sewing thread for a fiber product with feathers of the present invention, it is possible to provide a fiber product with feathers having excellent stretchability and light weight without using an inner fabric such as a downpack as in the prior art. In particular, it can be suitably used for sportswear.
以下に実施例を掲げて本発明を更に詳しく説明するが、本発明はこれら実施例のみに限定されるものではない。 Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to these examples.
(スパン糸1の作製)
ポリエステル100%紡績糸(305dtex)をフッ素系撥水剤(アサヒガードAG−E061、旭硝子社製)に40℃で20分間浸漬し、80℃で乾燥することにより、撥水処理を行った。このとき、フッ素系撥水剤付着量は1.6重量%、フッ素系撥水剤処理後の繊度は約310dtexであった。
次いで、パラフィンワックス130°F(新日本石油社製)、モノオレイン酸ソルビタンエステル(SO−10、日光ケミカルズ社製)、ポリオキシエチレンオレイルエーテル(エマルゲン430、花王社製)、ポリオキシエチレンオレイルエーテル(エマルゲン420、花王社製)、エチレングリコール、変性ポリシロキサン(BY16−880、東レ・ダウコーニング・シリコーン社製)及び熱水(95℃)を下記の組成で添加した後、95℃で攪拌混合し乳化させることにより混合液を得た。得られた混合液を制電加工剤として用い、上記のポリエステル紡績糸に60℃で5分間浸漬し、80℃で乾燥することにより、制電加工を行い、スパン糸1を得た。このとき、制電加工剤付着量は1.0重量%、スパン糸1の繊度は約313dtexであった。
また、糸引張試験機(ウスターテクノロジーズ社製、商品名「テンソラピッド3」)を用いて、JIS L 1013に準拠した方法で強力値(切断時の引張強さ)および引張伸度(切断時の伸び率)を測定したところ、強力1070cN、伸度17%であった。
(Preparation of spun yarn 1)
A 100% polyester spun yarn (305 dtex) was immersed in a fluorine-based water repellent (Asahi Guard AG-E061, manufactured by Asahi Glass Co., Ltd.) for 20 minutes at 40 ° C., and dried at 80 ° C. to perform a water repellent treatment. At this time, the adhesion amount of the fluorine-based water repellent was 1.6% by weight, and the fineness after the treatment with the fluorine-based water repellent was about 310 dtex.
Next, paraffin wax 130 ° F. (manufactured by Nippon Oil Corporation), sorbitan monooleate (SO-10, manufactured by Nikko Chemicals), polyoxyethylene oleyl ether (Emulgen 430, manufactured by Kao Corporation), polyoxyethylene oleyl ether (Emulgen 420, manufactured by Kao Corporation), ethylene glycol, modified polysiloxane (BY16-880, manufactured by Toray Dow Corning Silicone Co., Ltd.) and hot water (95 ° C.) were added with the following composition, followed by stirring and mixing at 95 ° C. And then emulsified to obtain a mixed solution. Using the obtained mixed liquid as an antistatic processing agent, the antistatic processing was performed by immersing in the above-mentioned polyester spun yarn at 60 ° C. for 5 minutes and drying at 80 ° C. to obtain a spun yarn 1. At this time, the adhesion amount of the antistatic processing agent was 1.0% by weight, and the fineness of the spun yarn 1 was about 313 dtex.
In addition, using a yarn tensile tester (trade name “Tensolapid 3” manufactured by Worcester Technologies, Inc.), the strength value (tensile strength at the time of cutting) and the tensile elongation (at the time of cutting) were measured in accordance with JIS L 1013. As a result, the strength was 1070 cN and the elongation was 17%.
[スパン糸1用制電加工剤の組成]
パラフィンワックス130°F 15部
モノオレイン酸ソルビタンエステル 3部
ポリオキシエチレンオレイルエーテル(エマルゲン430) 4部
ポリオキシエチレンオレイルエーテル(エマルゲン420) 2部
エチレングリコール 2部
変性ポリシロキサン 40部
熱水 34部
[Composition of antistatic agent for spun yarn 1]
Paraffin wax 130 ° F 15 parts Monooleic acid sorbitan ester 3 parts Polyoxyethylene oleyl ether (Emulgen 430) 4 parts Polyoxyethylene oleyl ether (Emulgen 420) 2 parts Ethylene glycol 2 parts Modified polysiloxane 40 parts Hot water 34 parts
(スパン糸2の作製)
ポリエステル100%紡績糸(439dtex)を、フッ素系撥水剤(NKガードNDN−1000E、日華化学社製)に40℃で20分間浸漬し、80℃で乾燥することにより、撥水処理を行った。このとき、フッ素系撥水剤付着量は1.2重量%、フッ素系撥水剤処理後の繊度は約444dtexであった。
次いで、変性ポリシロキサン(BY16−880、東レ・ダウコーニング・シリコーン社製)、パラフィン系乳化物(NKオイル AW−20、日華化学社製)を下記の組成で添加した後、95℃で攪拌混合することにより、混合液を得た。得られた混合液を制電加工剤として用い、ポリエステル紡績糸に60℃で5分間浸漬し、80℃で乾燥することにより、制電加工を行い、スパン糸2を作製した。このとき、制電加工剤付着量は1.5重量%、スパン糸2の繊度は約451dtexであった。また、強力値及び引張伸度についてもスパン糸1の場合と同様に測定し、結果を表1に示した。
(Preparation of spun yarn 2)
A 100% polyester spun yarn (439 dtex) is dipped in a fluorine-based water repellent (NK Guard NDN-1000E, manufactured by Nikka Chemical Co., Ltd.) at 40 ° C. for 20 minutes and dried at 80 ° C. to perform a water repellent treatment. It was. At this time, the adhesion amount of the fluorine-based water repellent was 1.2% by weight, and the fineness after the treatment with the fluorine-based water repellent was about 444 dtex.
Next, a modified polysiloxane (BY16-880, manufactured by Toray Dow Corning Silicone) and a paraffin emulsion (NK Oil AW-20, manufactured by Nikka Chemical Co., Ltd.) were added with the following composition, followed by stirring at 95 ° C. By mixing, a liquid mixture was obtained. The obtained mixed liquid was used as an antistatic processing agent, immersed in a polyester spun yarn at 60 ° C. for 5 minutes, and dried at 80 ° C. to perform antistatic processing, whereby a spun yarn 2 was produced. At this time, the adhesion amount of the antistatic processing agent was 1.5% by weight, and the fineness of the spun yarn 2 was about 451 dtex. Further, the strength value and the tensile elongation were also measured in the same manner as in the case of the spun yarn 1, and the results are shown in Table 1.
[スパン糸2用制電加工剤の組成]
変性ポリシロキサン 40部
パラフィン系乳化物 60部
[Composition of antistatic agent for spun yarn 2]
Modified polysiloxane 40 parts Paraffin emulsion 60 parts
(スパン糸3の作製)
ポリエステル100%紡績糸(305dtex)の制電処理として、市販の導電性コンジュゲート紡糸マルチフィラメント(ベルトロン(登録商標)B68タイプ、22dtex、3フィラメント、KBセーレン社製)と合糸することにより、ポリエステル導電複合糸(327dtex)を得た。
次いで、フッ素系撥水剤(アサヒガードAG−E061、旭硝子社製)に40℃で20分間浸漬し、80℃で乾燥することにより、撥水処理を行いスパン糸3を作製した。このとき、フッ素系撥水剤付着量は1.5重量%、スパン糸3の繊度は約332dtexであった。また、強力値及び引張伸度についてもスパン糸1の場合と同様に測定し、結果を表1に示した。
(Preparation of span yarn 3)
As an antistatic treatment of 100% polyester spun yarn (305 dtex), by combining with a commercially available conductive conjugate spun multifilament (Bertron (registered trademark) B68 type, 22 dtex, 3 filament, KB Selen), polyester A conductive composite yarn (327 dtex) was obtained.
Subsequently, the spun yarn 3 was produced by dipping in a fluorine-based water repellent (Asahi Guard AG-E061, manufactured by Asahi Glass Co., Ltd.) at 40 ° C. for 20 minutes and drying at 80 ° C. to perform water repellent treatment. At this time, the adhesion amount of the fluorine-based water repellent was 1.5% by weight and the fineness of the spun yarn 3 was about 332 dtex. Further, the strength value and the tensile elongation were also measured in the same manner as in the case of the spun yarn 1, and the results are shown in Table 1.
(スパン糸4の作製)
(スパン糸1の作製)で使用したポリエステル100%紡績糸(305dtex)をスパン糸4とした。
(Preparation of span yarn 4)
The spun yarn 4 was the 100% polyester spun yarn (305 dtex) used in (Preparation of the spun yarn 1).
(フィラメント糸1の作製)
毛羽加工が施されたポリエステルマルチフィラメント(265dtex、144フィラメント)を、フッ素系撥水剤(NKガードNDN−1000E、日華化学社製)に40℃で20分間浸漬し、80℃で乾燥することにより、撥水処理を行った。このとき、フッ素系撥水剤付着量は1.4重量%、フッ素系撥水剤処理後の繊度は約269dtexであった。
次いで、(スパン糸2の作製)で用いたのと同じ制電加工剤を用い、60℃で5分間浸漬し、80℃で乾燥することにより、制電加工を行い、フィラメント糸1を作製した。このとき、制電加工剤付着量は1.5重量%、フィラメント糸1の繊度は約273dtexであった。また、強力値及び引張伸度についてもスパン糸1の場合と同様に測定し、結果を表1に示した。
(Preparation of filament yarn 1)
Immerse polyester multifilament (265 dtex, 144 filament) that has been subjected to fluff processing in a fluorine-based water repellent (NK Guard NDN-1000E, manufactured by Nikka Chemical Co., Ltd.) at 40 ° C. for 20 minutes and dry at 80 ° C. Thus, a water repellent treatment was performed. At this time, the adhesion amount of the fluorine-based water repellent was 1.4% by weight, and the fineness after the treatment with the fluorine-based water repellent was about 269 dtex.
Next, using the same antistatic processing agent as used in (Preparation of Spun Yarn 2), the antistatic processing was performed by immersing at 60 ° C. for 5 minutes and drying at 80 ° C. to produce filament yarn 1. . At this time, the amount of antistatic processing agent attached was 1.5% by weight, and the fineness of the filament yarn 1 was about 273 dtex. Further, the strength value and the tensile elongation were also measured in the same manner as in the case of the spun yarn 1, and the results are shown in Table 1.
(フィラメント糸2の作製)
(フィラメント糸1の作製)で使用したポリエステルマルチフィラメント(265dtex、144フィラメント)をフィラメント糸2とした。また、強力値及び引張伸度についてもスパン糸1の場合と同様に測定し、結果を表1に示した。
(Preparation of filament yarn 2)
The polyester multifilament (265 dtex, 144 filament) used in (Preparation of filament yarn 1) was designated as filament yarn 2. Further, the strength value and the tensile elongation were also measured in the same manner as in the case of the spun yarn 1, and the results are shown in Table 1.
(織生地の作成)
タテ糸、ヨコ糸共に、ポリエステル100%のマルチフィラメント糸(84dtex、72フィラメント)を用いて製織された生機を精練・リラックス工程にて40〜98℃の浴槽で油剤を除去し、プレセット工程で乾熱による幅出しセットを行い、続いて液流染色機にて130℃分散染料によるポリエステル染色を行い、最後に乾熱による最終セット工程にて経糸175本/2.54cm、緯糸95本/2.54cmに仕上げた織物の裏面にシレ加工を施し、通気量を0.78cc/cm2/secとした。こうして得られた織物を全ての実施例及び比較例の表生地及び裏生地として使用した。なお、本発明におけるシレ加工とは、織物の糸を物理的に平に潰すことにより、タテ糸とヨコ糸の隙間を埋め、ダウンの抜けを防止している織り目つぶし加工のことである。
(Create woven fabric)
In both the warp and weft yarns, the raw material woven using 100% polyester multifilament yarn (84 dtex, 72 filaments) is scoured and relaxed to remove the oil in a 40-98 ° C bath, The width is set by dry heat, then polyester dyed by 130 ° C disperse dye in a liquid dyeing machine, and finally in the final setting process by dry heat, 175 warps / 2.54 cm, 95 wefts / 2 The back surface of the woven fabric finished to .54 cm was subjected to sille processing, and the air flow rate was set to 0.78 cc / cm 2 / sec. The woven fabric thus obtained was used as the front and back fabrics of all Examples and Comparative Examples. Note that the fillet processing in the present invention is a weaving processing that fills the gap between the warp yarn and the weft yarn by physically crushing the yarn of the woven fabric, thereby preventing the falling out.
(実施例1)
表生地及び裏生地としてポリエステル100%の上記織生地を用いた。中生地は設けず、表生地及び裏生地はそれぞれシレ加工面を羽毛側に、構造的には上から、表生地、羽毛、裏生地の順に重ね合わせ、生地外縁を2.5mmピッチで一周縫製し、縫い上がり寸法タテ35cm、ヨコ35cmの大きさの評価用サンプルを作成した。このとき羽毛にはダウン80%、フェザー20%のものを用いた。
なお、ミシンには、上糸としてスパン糸1、下糸としてスパン糸1をセットした。ミシン針としては、最外表面が硬質クロムメッキされており、表面がショットピーニング処理されたミシン針(DB×1#9、ミシン針1)を使用した。
Example 1
The woven fabric of 100% polyester was used as the front fabric and the back fabric. No inner fabric is provided, and the front and back fabrics are each laid on the feather side, and from the top, the top fabric, the feathers and the back fabric are stacked in this order, and the outer edge of the fabric is sewn at a pitch of 2.5 mm. Then, a sample for evaluation having a size of a stitch length of 35 cm and a width of 35 cm was prepared. At this time, a feather with 80% down and 20% feather was used.
In the sewing machine, the spun yarn 1 was set as the upper yarn and the spun yarn 1 was set as the lower yarn. As the sewing needle, a sewing needle (DB × 1 # 9, sewing needle 1) whose outermost surface was plated with hard chrome and whose surface was shot peened was used.
(実施例2)
ミシン針としては、最外表面がセラミック微粒子含有無電解ニッケル−燐メッキされており、表面がショットピーニング処理されたミシン針(DB×1#8、ミシン針2)を用いた以外は実施例1と同様にして評価用サンプルを作製した。
(Example 2)
Example 1 except that a sewing needle (DB × 1 # 8, sewing needle 2) whose outermost surface is plated with electroless nickel-phosphorus containing ceramic fine particles and whose surface is shot peened is used as the sewing needle. An evaluation sample was prepared in the same manner as described above.
(実施例3〜10、比較例1〜4)
上糸、下糸及びミシン針として、表2に示すものを使用した以外は実施例1と同様にして評価用サンプルを作製した。
(Examples 3 to 10, Comparative Examples 1 to 4)
An evaluation sample was prepared in the same manner as in Example 1 except that the upper thread, the lower thread, and the sewing needle shown in Table 2 were used.
(評価)
(1)羽毛抜け評価
実施例及び比較例で得られた評価用サンプルについて、羽毛入り衣料品(ダウンウエア)グリーンゴールドラベル品質表示管理規定第4条に準拠した方法でダウンウエア吹き出し試験を行い、以下の基準で評価した。
具体的には、JIS L 1096 8.64.4に定めるタンブル乾燥機(直径66cm、奥行46cm、回転約50rpm)使用、設定温度40℃、ICI型ピリング試験用ゴム管(JIS L 1076)10本を負荷として評価用サンプルと一緒に乾燥機内に入れ、60分間運転した。乾燥機内の温度が通常温度に低下するのを待って前記評価用サンプルを取り出し、吹き出したダウン及びフェザーの個数をカウントした。
(Evaluation)
(1) Feather drop evaluation For the samples for evaluation obtained in the examples and comparative examples, a down wear blowing test was performed by a method in accordance with Article 4 of the down clothing clothing label (down wear) Green Gold Label Quality Labeling Management Regulations, Evaluation was made according to the following criteria.
Specifically, using a tumble dryer (diameter 66 cm, depth 46 cm, rotation about 50 rpm) as defined in JIS L 1096 8.64.4, set temperature 40 ° C., 10 ICI pilling test rubber tubes (JIS L 1076) Was loaded into the dryer together with the sample for evaluation and operated for 60 minutes. The sample for evaluation was taken out after waiting for the temperature in the dryer to fall to the normal temperature, and the number of downs and feathers blown out was counted.
5:吹き出し無し
4:吹き出し個数1〜5個
3:吹き出し個数6〜10個
2:吹き出し個数11〜15個
1:吹き出し個数16個以上
5: No balloon 4: Number of balloons 1 to 5 3: Number of balloons 6 to 10 2: Number of balloons 11 to 15 1: Number of balloons 16 or more
(2)パッカリング評価
実施例及び比較例で得られた評価用サンプルについて、JIS L 1905(繊維製品のシームパッカリング評価方法)に準拠した方法でパッカリング評価を行い、判定用標準立体レプリカを用い、5級〜1級で評価した。
(2) Evaluation of puckering evaluation Samples for evaluation obtained in Examples and Comparative Examples are subjected to puckering evaluation in accordance with JIS L 1905 (Seam puckering evaluation method for textile products), and a standard three-dimensional replica for determination is obtained. It was used and evaluated from the fifth grade to the first grade.
(3)防水性試験
実施例及び比較例で得られた評価用サンプルについて、JIS L 1092(繊維製品の防水性試験方法 耐水度試験(静水圧法))に準拠した方法で防水性試験を行い、縫目のうち2カ所から水滴が出た時点の水位を測定し、以下の基準で評価した。
(3) Waterproof test For the samples for evaluation obtained in Examples and Comparative Examples, a waterproof test is performed by a method in accordance with JIS L 1092 (waterproof test method for water resistance (hydrostatic pressure method) of textile products). The water level at the time when water droplets emerged from two of the stitches was measured and evaluated according to the following criteria.
○:249mmを超える
△:150mm〜249mm
×:150mm未満
○: Over 249 mm
Δ: 150 mm to 249 mm
X: less than 150 mm
(4)摩擦帯電圧試験
実施例及び比較例で得られた評価用サンプルの縫製部分について、JIS L 1094(織物及び編物の帯電性試験方法 摩擦帯電放電曲線測定法)に準拠した方法で摩擦帯電圧試験を行い、帯電圧のn=10平均値を以下の基準で評価した。
このとき、温湿度状態20℃40%RH、ナイロン摩擦布使用、洗濯処理JIS L 0217 103法 3回、試験方向は縫い目方向とした。
(4) Friction band voltage test The sewn part of the sample for evaluation obtained in the examples and comparative examples was subjected to a friction band by a method in accordance with JIS L 1094 (a method for measuring the charging property of fabrics and knitted fabrics by a triboelectric discharge curve measurement method). A voltage test was conducted, and an average value of n = 10 of the charged voltage was evaluated according to the following criteria.
At this time, temperature / humidity state 20 ° C. 40% RH, use of nylon friction cloth, washing treatment JIS L 0217 103 method 3 times, the test direction was the stitch direction.
○:2.6kVを超える
△:12.9〜2.6kV
×:12.9kV未満
○: Over 2.6 kV
Δ: 12.9 to 2.6 kV
X: Less than 12.9 kV
本発明によれば、優れた伸縮性や軽量性を実現しつつ、羽毛の抜け出しやパッカリングを効果的に防止することが可能な羽毛入り繊維製品用ミシン糸、該羽毛入り繊維製品用ミシン糸を用いた羽毛入り繊維製品、及び、羽毛入り繊維製品の製造方法を提供できる。 ADVANTAGE OF THE INVENTION According to this invention, the sewing thread | yarn for feathered fiber products which can prevent the pulling-out and puckering of feathers effectively, implement | achieving the outstanding elasticity and light weight, This sewing thread | yarn for feathered fiber products And a method for producing a fiber product with feathers.
Claims (7)
表地、羽毛、裏地の順に重ね合わせた後、請求項1、2、3、4又は5記載の羽毛入り繊維製品用ミシン糸を用いて、表地と裏地とを縫製する縫製工程を有することを特徴とする羽毛入り繊維製品の製造方法。 A method for producing a fiber product with feathers having a feather between an outer material and a lining material,
It has a sewing process of sewing the outer material and the lining with the sewing thread for a fiber product with feathers according to claim 1, after overlapping the outer material, the feather and the lining in this order. The manufacturing method of the fiber product containing feather.
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CN201210287225.0A CN102864638B (en) | 2009-11-30 | 2010-04-23 | Sewing thread for products filled with feather fibers |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011168901A (en) * | 2010-02-17 | 2011-09-01 | Gunze Ltd | Machine sewing thread for feather-containing textile product |
JP2012102456A (en) * | 2012-02-15 | 2012-05-31 | Gunze Ltd | Machine sewing thread for feather-containing textile product |
WO2021235051A1 (en) * | 2020-05-19 | 2021-11-25 | 竹本油脂株式会社 | Sewing machine thread treatment agent and sewing machine thread |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5887825U (en) * | 1981-12-03 | 1983-06-14 | 日東電工株式会社 | Structure of quilting sewing part |
JPS58136807A (en) * | 1982-02-08 | 1983-08-15 | ユニチカ株式会社 | Prevention of padding and feather from flying-out |
JPS5969093A (en) * | 1982-10-14 | 1984-04-19 | ユニチカ株式会社 | Prevention of fly-out of padding or feather from seam part |
JPH02307980A (en) * | 1989-05-18 | 1990-12-21 | Shikishima Boseki Kk | Antistatic silicon oil for machine sewing polyester spun yarn |
JPH0317937U (en) * | 1989-07-05 | 1991-02-21 | ||
JPH03152278A (en) * | 1989-11-10 | 1991-06-28 | France Bed Co Ltd | Treatment of feather |
-
2009
- 2009-11-30 JP JP2009272302A patent/JP4981881B2/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5887825U (en) * | 1981-12-03 | 1983-06-14 | 日東電工株式会社 | Structure of quilting sewing part |
JPS58136807A (en) * | 1982-02-08 | 1983-08-15 | ユニチカ株式会社 | Prevention of padding and feather from flying-out |
JPS5969093A (en) * | 1982-10-14 | 1984-04-19 | ユニチカ株式会社 | Prevention of fly-out of padding or feather from seam part |
JPH02307980A (en) * | 1989-05-18 | 1990-12-21 | Shikishima Boseki Kk | Antistatic silicon oil for machine sewing polyester spun yarn |
JPH0317937U (en) * | 1989-07-05 | 1991-02-21 | ||
JPH03152278A (en) * | 1989-11-10 | 1991-06-28 | France Bed Co Ltd | Treatment of feather |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011168901A (en) * | 2010-02-17 | 2011-09-01 | Gunze Ltd | Machine sewing thread for feather-containing textile product |
JP2012102456A (en) * | 2012-02-15 | 2012-05-31 | Gunze Ltd | Machine sewing thread for feather-containing textile product |
WO2021235051A1 (en) * | 2020-05-19 | 2021-11-25 | 竹本油脂株式会社 | Sewing machine thread treatment agent and sewing machine thread |
CN114072552A (en) * | 2020-05-19 | 2022-02-18 | 竹本油脂株式会社 | Treating agent for sewing thread and sewing thread |
CN114072552B (en) * | 2020-05-19 | 2023-08-29 | 竹本油脂株式会社 | Treatment agent for sewing thread and sewing thread |
US11952711B2 (en) | 2020-05-19 | 2024-04-09 | Takemoto Yushi Kabushiki Kaisha | Sewing thread treatment agent and sewing thread |
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