JP2010006751A - Hair cosmetic - Google Patents
Hair cosmetic Download PDFInfo
- Publication number
- JP2010006751A JP2010006751A JP2008168519A JP2008168519A JP2010006751A JP 2010006751 A JP2010006751 A JP 2010006751A JP 2008168519 A JP2008168519 A JP 2008168519A JP 2008168519 A JP2008168519 A JP 2008168519A JP 2010006751 A JP2010006751 A JP 2010006751A
- Authority
- JP
- Japan
- Prior art keywords
- group
- hair
- alkyl
- carbon atoms
- trimonium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 24
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001768 cations Chemical class 0.000 claims abstract description 10
- 125000005843 halogen group Chemical group 0.000 claims abstract description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 8
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 125000005526 alkyl sulfate group Chemical group 0.000 claims abstract description 7
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 4
- 125000005020 hydroxyalkenyl group Chemical group 0.000 claims abstract description 4
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 4
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims abstract description 4
- -1 Alkyl cation Chemical class 0.000 claims description 40
- 229920001296 polysiloxane Polymers 0.000 claims description 37
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 24
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 22
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 15
- 229940106189 ceramide Drugs 0.000 claims description 8
- 150000003408 sphingolipids Chemical class 0.000 claims description 7
- 150000001841 cholesterols Chemical class 0.000 claims description 5
- 239000003676 hair preparation Substances 0.000 claims description 5
- YDNKGFDKKRUKPY-JHOUSYSJSA-N C16 ceramide Natural products CCCCCCCCCCCCCCCC(=O)N[C@@H](CO)[C@H](O)C=CCCCCCCCCCCCCC YDNKGFDKKRUKPY-JHOUSYSJSA-N 0.000 claims description 4
- CRJGESKKUOMBCT-VQTJNVASSA-N N-acetylsphinganine Chemical compound CCCCCCCCCCCCCCC[C@@H](O)[C@H](CO)NC(C)=O CRJGESKKUOMBCT-VQTJNVASSA-N 0.000 claims description 4
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 4
- ZVEQCJWYRWKARO-UHFFFAOYSA-N ceramide Natural products CCCCCCCCCCCCCCC(O)C(=O)NC(CO)C(O)C=CCCC=C(C)CCCCCCCCC ZVEQCJWYRWKARO-UHFFFAOYSA-N 0.000 claims description 4
- VVGIYYKRAMHVLU-UHFFFAOYSA-N newbouldiamide Natural products CCCCCCCCCCCCCCCCCCCC(O)C(O)C(O)C(CO)NC(=O)CCCCCCCCCCCCCCCCC VVGIYYKRAMHVLU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 230000002265 prevention Effects 0.000 abstract description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 19
- 229930195729 fatty acid Natural products 0.000 description 19
- 239000000194 fatty acid Substances 0.000 description 19
- 239000007788 liquid Substances 0.000 description 14
- 239000003921 oil Substances 0.000 description 14
- 235000019198 oils Nutrition 0.000 description 14
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 13
- 150000004665 fatty acids Chemical class 0.000 description 13
- 238000002156 mixing Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- 239000004205 dimethyl polysiloxane Substances 0.000 description 11
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 10
- 238000011282 treatment Methods 0.000 description 10
- 230000014759 maintenance of location Effects 0.000 description 9
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical compound O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 8
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 8
- 238000013329 compounding Methods 0.000 description 8
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 8
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 125000005645 linoleyl group Chemical group 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 235000019774 Rice Bran oil Nutrition 0.000 description 6
- 125000004122 cyclic group Chemical group 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 239000008165 rice bran oil Substances 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 239000003205 fragrance Substances 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000008213 purified water Substances 0.000 description 5
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 4
- 150000005215 alkyl ethers Chemical class 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- 239000003093 cationic surfactant Substances 0.000 description 4
- 229940082500 cetostearyl alcohol Drugs 0.000 description 4
- 229960000735 docosanol Drugs 0.000 description 4
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 4
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 229960005323 phenoxyethanol Drugs 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 4
- ZPFAVCIQZKRBGF-UHFFFAOYSA-N 1,3,2-dioxathiolane 2,2-dioxide Chemical compound O=S1(=O)OCCO1 ZPFAVCIQZKRBGF-UHFFFAOYSA-N 0.000 description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 3
- 240000000912 Macadamia tetraphylla Species 0.000 description 3
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 150000001783 ceramides Chemical class 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- 239000010466 nut oil Substances 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- JSPNNZKWADNWHI-PNANGNLXSA-N (2r)-2-hydroxy-n-[(2s,3r,4e,8e)-3-hydroxy-9-methyl-1-[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoctadeca-4,8-dien-2-yl]heptadecanamide Chemical compound CCCCCCCCCCCCCCC[C@@H](O)C(=O)N[C@H]([C@H](O)\C=C\CC\C=C(/C)CCCCCCCCC)CO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O JSPNNZKWADNWHI-PNANGNLXSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- QNAYBMKLOCPYGJ-UHFFFAOYSA-N Alanine Chemical compound CC([NH3+])C([O-])=O QNAYBMKLOCPYGJ-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
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- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
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- RJECHNNFRHZQKU-UHFFFAOYSA-N Oelsaeurecholesterylester Natural products C12CCC3(C)C(C(C)CCCC(C)C)CCC3C2CC=C2C1(C)CCC(OC(=O)CCCCCCCC=CCCCCCCCC)C2 RJECHNNFRHZQKU-UHFFFAOYSA-N 0.000 description 2
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- MIUIRGGKIICMBP-NFOZDHADSA-N [27-oxo-27-[[(2s,3s,4r)-1,3,4-trihydroxyoctadecan-2-yl]amino]heptacosyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCCCCCCCCCCCCC(=O)N[C@@H](CO)[C@H](O)[C@H](O)CCCCCCCCCCCCCC MIUIRGGKIICMBP-NFOZDHADSA-N 0.000 description 2
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- 125000001309 chloro group Chemical group Cl* 0.000 description 2
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- OQMZNAMGEHIHNN-UHFFFAOYSA-N 7-Dehydrostigmasterol Natural products C1C(O)CCC2(C)C(CCC3(C(C(C)C=CC(CC)C(C)C)CCC33)C)C3=CC=C21 OQMZNAMGEHIHNN-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
本発明は、毛髪化粧料に関し、詳しくは毛髪の水分保持力を高め、その結果毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができ、かつ低湿度下でのパサツキ防止とうるおい感に優れた毛髪化粧料に関する。 The present invention relates to a hair cosmetic, and in particular, increases the moisture retention of the hair, and as a result, can give the hair a supple and moist finish without feeling sticky or heavy, and low The present invention relates to a hair cosmetic that is excellent in preventing rustiness and moisture in humidity.
女性のヘアスタイルの流行に伴って、求められる髪の仕上がりや感触も並行して変化している。最近では、シャギーやレイヤーカットなどの毛先のボリュームを落としたヘアスタイルが一般的であり、また一方、カラーリングやパーマ等の施術により、しなやかでしっとりした仕上がり感のみならず、べたつき感や髪が重くならずにボリュームが出る質感が求められている。また、さらに冬場の低湿度環境下においても、それらの機能が持続することが望まれている。ヘアリンスやヘアトリートメント等の毛髪化粧料においては、従来、毛髪を柔軟にして櫛通りをよくする目的で、カチオン性界面活性剤やシリコーン等の配合、或いは、しっとりとした感触を与えるために液状や固形状の油剤の配合が試みられているが、これら従来の技術では、近年のヘアスタイルにおいて要求されているニーズを満足させることは困難であり、しっとりとした仕上がり感とべたつきや重さのなさを両立することが課題であった。 With the trend of women's hairstyles, the required finish and feel of hair are changing in parallel. Recently, hair styles with reduced hair volume such as shaggy and layer cut are common, and on the other hand, treatment such as coloring and perm, as well as a supple and moist finish, as well as a sticky feeling and hair There is a need for a texture that produces volume without increasing weight. In addition, it is desired that these functions continue even in a low humidity environment in winter. In hair cosmetics such as hair rinses and hair treatments, conventionally, for the purpose of softening the hair and improving the combing, it is possible to add a cationic surfactant, silicone, etc., or to give a moist feel. Attempts have been made to blend solid oils, but with these conventional technologies, it is difficult to satisfy the needs required in recent hairstyles, with a moist finish and no stickiness or weight. It was a challenge to achieve both.
これらの課題を解決する方法として、例えば、脂肪酸アミドアミン化合物やヒドロキシエーテルアミン化合物を用いることにより、毛髪に滑らかさや柔軟性を付与する毛髪化粧料が提案されている(例えば、特許文献1〜4参照。)。これらの技術は、いずれも一定の改善がなされているが、洗髪した翌日には毛髪の保湿性が低下しており、髪がパサついて違和感のある手触りとなり、セットが上手にできないなどの問題点を有し、特に冬場の低湿度環境下においては、パサツキが激しく生じ、滑らかさやしっとり感の効果が持続しないなど、充分満足できるものではなかった。 As a method for solving these problems, for example, a hair cosmetic that imparts smoothness and flexibility to hair by using a fatty acid amidoamine compound or a hydroxyetheramine compound has been proposed (see, for example, Patent Documents 1 to 4). .) All of these technologies have been improved to some extent, but the moisture retention of the hair has been reduced the next day after washing the hair, causing the hair to feel dry and uncomfortable, making it difficult to set. In particular, in a low humidity environment in winter, it was not sufficiently satisfactory, for example, the rustling was intense and the effect of smoothness and moistness was not sustained.
また、新たな抱水性の高い油剤やシリコーン類を配合することによって、毛髪に滑らかさや柔軟性を付与する試みがなされ、例えば、各種シリコーン化合物を配合して、柔らかさとしっとり感を付与する方法(例えば、特許文献5参照。)、ダイマージリノール酸ダイマー酸リノレイルビス(フィトステリル/ベヘニル/イソステアリル)を配合したなじみや伸びに優れべたつきの少ない化粧料(例えば、特許文献6参照。)、分岐脂肪酸コレステリルエステルを配合してしっとり感、さらさら感、柔軟性を付与する毛髪化粧料(例えば、特許文献7参照。)が開示されている。しかしながら、これらの発明においても、しなやかさやしっとり感は実現できるものの、髪がべたつき、重くなり、また低湿度環境下では、パサツキを生じ、うるおい感の持続性において充分満足できるものではなかった。 In addition, attempts have been made to impart smoothness and flexibility to hair by blending new oils and silicones with high water-holding properties. For example, a method of blending various silicone compounds to impart softness and moist feeling ( For example, refer to Patent Document 5), dimerinolinoleic acid dimer acid linoleyl bis (phytosteryl / behenyl / isostearyl) blended cosmetics with excellent fit and elongation (see Patent Document 6, for example), branched fatty acid cholesteryl. A hair cosmetic (for example, see Patent Document 7) that imparts a moist feeling, a smooth feeling, and flexibility by blending an ester is disclosed. However, even in these inventions, although a supple, moist feeling can be realized, the hair becomes sticky and heavy, and under low-humidity environment, it is soft and not sufficiently satisfactory in the sustainability of moisture.
本発明の目的は、毛髪の水分保持力を高めながらも、毛髪にべたつきや重さを与えること
なく、しなやかでしっとりとした仕上がり感を与えることができ、かつ、低湿度下でのパサツキ防止とうるおい感に優れた毛髪化粧料を提供することにある。
The object of the present invention is to provide a supple and moist finish without giving the hair stickiness and weight while increasing the moisture retention of the hair, and to prevent rustiness under low humidity. An object of the present invention is to provide a hair cosmetic with an excellent moisture feeling.
本発明者は、このような状況に鑑み、鋭意研究した結果、ヒドロキシエーテル型カチオンと、アルキル型カチオンと、高級アルコールとを含有する毛髪化粧料が、上記の課題を解決することを見出し、本発明を完成するに至った。 As a result of diligent research in view of such circumstances, the present inventor has found that a hair cosmetic containing a hydroxy ether cation, an alkyl cation, and a higher alcohol solves the above-mentioned problems. The invention has been completed.
即ち、本発明の毛髪化粧料は、下記(A)〜(C)成分を含有することを特徴としている。
(A)下記一般式(I)で表されるヒドロキシエーテル型カチオン
R1−(OCH2CH(OH)CH2)m−N+(R2)3・X− … (I)(式中、R1は、直鎖又は分岐した炭素数12〜24の飽和もしくは不飽和アルキル基、R2は炭素数1〜3のアルキル基、mは1〜5の整数、Xはハロゲン原子又は炭素数1〜3のアルキル硫酸基を示す。)
(B)下記一般式(II)で表されるアルキル型カチオン
(C)炭素数14〜24の長鎖のアルキル基を有する高級アルコール。
That is, the hair cosmetic composition of the present invention is characterized by containing the following components (A) to (C).
(A) Hydroxy ether type cation represented by the following general formula (I) R 1 — (OCH 2 CH (OH) CH 2 ) m —N + (R 2 ) 3 · X − (I) (wherein R 1 is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R 2 is an alkyl group having 1 to 3 carbon atoms, m is an integer of 1 to 5, X is a halogen atom or carbon number 1 ˜3 alkyl sulfate groups.)
(B) Alkyl cation represented by the following general formula (II)
(C) A higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms.
また本発明の毛髪化粧料には、さらに、(D)シリコーン誘導体を含有することが望ましく、また(E)スフィンゴ脂質、セラミド、コレステロール誘導体、フィトステロール誘導体からなる群より選ばれる一種以上を含有することがより望ましい。 The hair cosmetic composition of the present invention preferably further contains (D) a silicone derivative, and (E) contains at least one selected from the group consisting of sphingolipids, ceramides, cholesterol derivatives, and phytosterol derivatives. Is more desirable.
本発明の毛髪化粧料は、毛髪の水分保持力を高め、その結果毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができ、かつ低湿度下でのパサツキ防止とうるおい感に優れた効果を付与することができる。 The hair cosmetic composition of the present invention increases the moisture retention of the hair, and as a result, it can give the hair a supple and moist finish without feeling sticky or heavy, and at low humidity. The effect which was excellent in the prevention of rustiness and a feeling of moisture can be provided.
以下、本発明を詳細に説明する。 Hereinafter, the present invention will be described in detail.
本発明における(A)成分のヒドロキシエーテル型カチオンは、例えば、下記一般式(I)
R1−(OCH2CH(OH)CH2)m−N+(R2)3・X− … (I)(式中、R1は、直鎖又は分岐した炭素数12〜24の飽和もしくは不飽和アルキル基、R2は炭素数1〜3のアルキル基、mは1〜5の整数、Xはハロゲン原子又は炭素数1〜3のアルキル硫酸基を示す。)で表され、具体例を示すと、ラウリルPGトリモニウムクロリド、ミリスチルPGトリモニウムクロリド、パルミチルPGトリモニウムクロリド、セチルPGトリモニウムクロリド、セトステアリルPGトリモニウムクロリド、ステアリルPGトリモニウムクロリド、アラキルPGトリモニウムクロリド、ベヘニルPGトリモニウムクロリド、カルナービルPGトリモニウムクロリド、オレイルPGトリモニウムク
ロリド、エライジルPGトリモニウムクロリド、リノレイルPGトリモニウムクロリド、リノレニルPGトリモニウムクロリド、ラウリルPGトリモニウムブロミド、ミリスチルPGトリモニウムブロミド、パルミチルPGトリモニウムブロミド、セチルPGトリモニウムブロミド、セトステアリルPGトリモニウムブロミド、ステアリルPGトリモニウムブロミド、アラキルPGトリモニウムブロミド、ベヘニルPGトリモニウムブロミド、カルナービルPGトリモニウムブロミド、オレイルPGトリモニウムブロミド、エライジルPGトリモニウムブロミド、リノレイルPGトリモニウムブロミド、リノレニルPGトリモニウムブロミド、ラウリルPGトリモニウムエトサルフェート、ミリスチルPGトリモニウムエトサルフェート、パルミチルPGトリモニウムエトサルフェート、セチルPGトリモニウムエトサルフェート、セトステアリルPGトリモニウムエトサルフェート、ステアリルPGトリモニウムエトサルフェート、アラキルPGトリモニウムエトサルフェート、ベヘニルPGトリモニウムエトサルフェート、カルナービルPGトリモニウムエトサルフェート、オレイルPGトリモニウムエトサルフェート、エライジルPGトリモニウムエトサルフェート、リノレイルPGトリモニウムエトサルフェート、リノレニルPGトリモニウムエトサルフェート、ラウリルPGトリモニウムメトサルフェート、ミリスチルPGトリモニウムメトサルフェート、パルミチルPGトリモニウムメトサルフェート、セチルPGトリモニウムメトサルフェート、セトステアリルPGトリモニウムメトサルフェート、ステアリルPGトリモニウムメトサルフェート、アラキルPGトリモニウムメトサルフェート、ベヘニルPGトリモニウムメトサルフェート、カルナービルPGトリモニウムメトサルフェート、オレイルPGトリモニウムメトサルフェート、エライジルPGトリモニウムメトサルフェート、リノレイルPGトリモニウムメトサルフェート、リノレニルPGトリモニウムメトサルフェート等のヒドロキシエーテル型カチオンが挙げられる。これらの中でもR1が炭素数22のベヘニル基、R2がメチル基、Xが塩素であるべヘニルPGトリモニウムクロリドが特に好ましい。本発明では、これらのヒドロキシエーテル型カチオンの中から1種又は2種以上を任意に用いることができ、その配合量は、好ましくは0.1〜10質量%(以下、特に記載のあるもの以外は、質量%を単に「%」で示す)、更に好ましくは、0.5〜5%の範囲である。この配合量の範囲であれば、毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができるため好ましい。
The hydroxy ether type cation of the component (A) in the present invention is, for example, the following general formula (I):
R 1 — (OCH 2 CH (OH) CH 2 ) m —N + (R 2 ) 3 · X − (I) (wherein R 1 is a straight-chain or branched C 12-24 saturated or An unsaturated alkyl group, R 2 is an alkyl group having 1 to 3 carbon atoms, m is an integer of 1 to 5 and X is a halogen atom or an alkyl sulfate group having 1 to 3 carbon atoms. As shown, lauryl PG trimonium chloride, myristyl PG trimonium chloride, palmityl PG trimonium chloride, cetyl PG trimonium chloride, cetostearyl PG trimonium chloride, stearyl PG trimonium chloride, aralkyl PG trimonium chloride, behenyl PG trimonium Chloride, Carnerville PG Trimonium Chloride, Oleyl PG Trimonium Chloride, Elidyl PG Tri Nium chloride, linoleyl PG trimonium chloride, linoleyl PG trimonium chloride, lauryl PG trimonium bromide, myristyl PG trimonium bromide, palmityl PG trimonium bromide, cetyl PG trimonium bromide, cetostearyl PG trimonium bromide, stearyl PG trimonium Bromide, aralkyl PG trimonium bromide, behenyl PG trimonium bromide, carnervir PG trimonium bromide, oleyl PG trimonium bromide, elaidyl PG trimonium bromide, linoleyl PG trimonium bromide, linoleyl PG trimonium bromide, lauryl PG trimonium ethosulphate , Myristyl PG trimonium sulfate, palmityl PG trimonium Sulfate, cetyl PG trimonium ethosulphate, cetostearyl PG trimonium ethosulphate, stearyl PG trimonium ethosulphate, aralkyl PG trimonium ethosulphate, behenyl PG trimonium ethosulphate, carnervir PG trimonium ethosulphate, oleyl PG trimonium eth Sulfate, Elidyl PG Trimonium Ethosulfate, Linoleyl PG Trimonium Ethosulfate, Linolenyl PG Trimonium Ethosulfate, Lauryl PG Trimonium Metosulfate, Myristyl PG Trimonium Metosulfate, Palmityl PG Trimonium Metosulfate, Cetyl PG Trimonium Metosulfate , Cetostearyl PG trimonium methosulphate Stearyl PG trimonium methosulphate, aralkyl PG trimonium methosulphate, behenyl PG trimonium methosulphate, carnervir PG trimonium methosulphate, oleyl PG trimonium methosulphate, elaidyl PG trimonium methosulphate, linoleyl PG trimonium methosulphate, Examples include hydroxy ether type cations such as linolenyl PG trimonium methosulphate. Among these, behenyl PG trimonium chloride in which R 1 is a behenyl group having 22 carbon atoms, R 2 is a methyl group, and X is chlorine is particularly preferable. In this invention, 1 type (s) or 2 or more types can be arbitrarily used from these hydroxy ether type | mold cations, The compounding quantity becomes like this. Preferably it is 0.1-10 mass% (hereinafter, especially except what is described) Represents mass% simply by “%”), more preferably in the range of 0.5 to 5%. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.
本発明における(B)成分のアルキル型カチオンは、下記一般式(II) The alkyl type cation of the component (B) in the present invention is represented by the following general formula (II)
(式中、R3〜R6のうちいずれか1個又は2個は炭素数8〜24のアルキル基、アルケニル基、ヒドロキシアルキル基又はヒドロキシアルケニル基であり、残りは、炭素数1〜3のアルキル基もしくはヒドロキシアルキル基又はベンジル基を表し、Yはハロゲン原子又は炭素数1〜3のアルキル硫酸基を示す。)で示され、上記式(II)のR3〜R6のうちいずれか1個又は2個 の炭素数8〜24のアルキル基は、例えばセチル基、ステアリル基、ベヘニル基、12−ヒドロキシステアリル基等であり、炭素数16〜22のアルキル基が好ましく、特に好ましいものとしてはベヘニル基が挙げられる。残りの炭素数1〜3のアルキル基もしくはヒドロキシアルキル基又はベンジル基は、好ましいものとしては、メチル基、エチル基、プロピル基、ヒドロキシメチル基及びヒドロキシエチル基が挙げられる。Yのハロゲン原子は、好ましくは塩素原子又は臭素原子である。 (In the formula, any one or two of R 3 to R 6 are an alkyl group having 8 to 24 carbon atoms, an alkenyl group, a hydroxyalkyl group, or a hydroxyalkenyl group, and the rest are those having 1 to 3 carbon atoms. Represents an alkyl group, a hydroxyalkyl group or a benzyl group, Y represents a halogen atom or an alkyl sulfate group having 1 to 3 carbon atoms), and any one of R 3 to R 6 in the above formula (II) One or two alkyl groups having 8 to 24 carbon atoms are, for example, a cetyl group, a stearyl group, a behenyl group, a 12-hydroxystearyl group, etc., and an alkyl group having 16 to 22 carbon atoms is preferable, A behenyl group may be mentioned. Preferred examples of the remaining alkyl group having 1 to 3 carbon atoms or hydroxyalkyl group or benzyl group include a methyl group, an ethyl group, a propyl group, a hydroxymethyl group, and a hydroxyethyl group. The halogen atom of Y is preferably a chlorine atom or a bromine atom.
前記一般式(II)で示されるアルキル型カチオンの具体例を示すと、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウム、塩化ベヘニルジメチルヒドロキシエチルアンモニウム、塩化ステアリルジメチルベンジルアンモニウム、塩化ジステアリルジメチルアンモニウム、塩化ジセチルジメチルアンモニウム、及びセチルトリエチルアンモニウムメチルサルフェート等が挙げられる。これらの中でも、塩化セチルトリメチルアンモニウム、塩化ステアリルトリメチルアンモニウム、塩化ベヘニルトリメチルアンモニウムが好ましく、更に、塩化ベヘニルトリメチルアンモニウムが特に好ましい。本発明では、これらのアルキル型カチオンの中から1種又は2種以上を任意に用いることができ、その配合量は、好ましくは0.1〜10%、更に好ましくは、0.5〜5%の範囲である。この配合量の範囲であれば、毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができるため好ましい。 Specific examples of the alkyl cation represented by the general formula (II) include cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, behenyltrimethylammonium chloride, behenyldimethylhydroxyethylammonium chloride, stearyldimethylbenzylammonium chloride, distearyl chloride. Examples thereof include dimethylammonium, dicetyldimethylammonium chloride, and cetyltriethylammonium methyl sulfate. Among these, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, and behenyltrimethylammonium chloride are preferable, and behenyltrimethylammonium chloride is particularly preferable. In this invention, 1 type (s) or 2 or more types can be arbitrarily used from these alkyl type cations, The compounding quantity becomes like this. Preferably it is 0.1-10%, More preferably, it is 0.5-5% Range. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.
本発明における(C)成分の炭素数14〜22の長鎖のアルキル基を有する高級アルコールは、好ましいものとしては、炭素数16〜22の長鎖高級アルコール、例えばセチルアルコール、ステアリルアルコール、ベヘニルアルコールである。これらの高級アルコールは、1種又は2種以上を組み合わせて用いることができ、その配合量は、好ましくは1〜20%、更に好ましくは、3〜10%の範囲である。この配合量の範囲であれば、毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができるため好ましい。 The higher alcohol having a long chain alkyl group having 14 to 22 carbon atoms as the component (C) in the present invention is preferably a long chain higher alcohol having 16 to 22 carbon atoms, such as cetyl alcohol, stearyl alcohol, or behenyl alcohol. is there. These higher alcohols can be used singly or in combination of two or more, and the blending amount is preferably 1 to 20%, more preferably 3 to 10%. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.
さらに本発明においては使用時の感触を高める目的で、(D)成分のシリコーン誘導体を配合することができる。シリコーン誘導体の具体例としては、ジメチルポリシロキサン、メチルフェニルポリシロキサン、アルコール変性シリコーン、アルキル変性シリコーン、アミノ変性シリコーン、ポリエーテルシリコーンなどを含み、例えば以下の(a)〜(g)等が挙げられる。 Furthermore, in the present invention, a silicone derivative as the component (D) can be blended for the purpose of enhancing the feel during use. Specific examples of the silicone derivative include dimethylpolysiloxane, methylphenylpolysiloxane, alcohol-modified silicone, alkyl-modified silicone, amino-modified silicone, polyether silicone and the like, for example, the following (a) to (g). .
(a)ジメチルポリシロキサン:メチルシロキサン構造を持ち、25℃における粘度が6〜100,000mPa・sである重合度ものが挙げられる。
(b)環状シリコーン:環状のメチルポリシロキサン構造を持つシリコーン油であり、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、環状シリコン樹脂等が挙げられる。
(c)高重合ジメチルポリシロキサン:メチルシロキサン構造を持ち、25℃における粘度が50,000〜20,000,000mPa・sであるものが挙げられ、高重合ジメチルポリシロキサンを本発明の毛髪化粧料中に配合する場合、液状油に溶解して配合するか、更にカチオン性界面活性剤やポリオキシエチレンアルキルエーテルなどの非イオン性界面活性剤水溶液中で調製した水性乳濁液を配合することが好ましい。液状油としてはジメチルポリシロキサンや、環状シリコーン又はイソパラフィン系炭化水素等を挙げることができる。
(d)アミノ変性シリコーン:N−(2−アミノエチル)アミノプロピル基又はN−(2−アミノエチル)アミノイソブチル基を持つシリコーン油であり、アミノ変性シリコーンを本発明の毛髪化粧料中に配合する場合、液状油に溶解して配合するか、更にカチオン性界面活性剤やポリオキシエチレンアルキルエーテルなどの非イオン性界面活性剤水溶液中で調製した水性乳濁液を配合することが好ましい。また水性乳濁液として用いる場合、該水性乳濁液中に含まれるアミノ変性シリコーンの量は20〜60質量%が好ましく、30〜50質量%が更に好ましい。また液状油としてはジメチルポリシロキサンや、環状シリコーン又はイソパラフィン系炭化水素等を挙げることができる。
(e)ポリエーテル変性シリコーン:ジメチルシロキサン・メチル(ポリオキシエチレン)シロキサン・メチル(ポリオキプロピレン)シロキサン共重合体、ジメチルシロキサン・メチル(ポリオキシエチレン)シロキサン共重合体、ジメチルシロキサン・メチル(ポ
リオキプロピレン)シロキサン共重合体等が挙げられる。
(f)アルコール変性シリコーン:ジメチルポリシロキサンのメチル基の一部をアルコキシ基に置き換えた構造を有し、ステアロキシメチルポリシロキサン、セトキシメチルポリシロキサン等が挙げられる。
(g)アルキル変性シリコーン:ジメチルポリシロキサンのメチル基の一部を長鎖アルキル基に置き換えた構造を有し、アルキル基の置換率及び大きさにより、液体からワックス状の性状を有するものが挙げられる。
(h)アミノフェニル変性シリコーン:N−(2−アミノエチル)アミノプロピル基又はN−(2−アミノエチル)アミノイソブチル基とフェニル基を持つシリコーン油であり、アミノフェニル変性シリコーンを本発明の毛髪化粧料中に配合する場合、液状油に溶解して配合するか、更にカチオン性界面活性剤やポリオキシエチレンアルキルエーテルなどの非イオン性界面活性剤水溶液中で調製した水性乳濁液を配合することが好ましい。また液状油としてはジメチルポリシロキサンや、環状シリコーン又はイソパラフィン系炭化水素等を挙げることができる。
(A) Dimethylpolysiloxane: A polymer having a methylsiloxane structure and a viscosity of 6 to 100,000 mPa · s at 25 ° C.
(B) Cyclic silicone: A silicone oil having a cyclic methylpolysiloxane structure, such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, and cyclic silicone resin.
(C) Highly polymerized dimethylpolysiloxane: one having a methylsiloxane structure and a viscosity at 25 ° C. of 50,000 to 20,000,000 mPa · s. When blended in, it may be blended by dissolving in liquid oil, or an aqueous emulsion prepared in an aqueous solution of a nonionic surfactant such as a cationic surfactant or polyoxyethylene alkyl ether may be blended. preferable. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, and isoparaffinic hydrocarbon.
(D) Amino-modified silicone: A silicone oil having an N- (2-aminoethyl) aminopropyl group or N- (2-aminoethyl) aminoisobutyl group, and the amino-modified silicone is blended in the hair cosmetic composition of the present invention. In this case, it is preferable to mix in a liquid oil or mix an aqueous emulsion prepared in an aqueous solution of a nonionic surfactant such as a cationic surfactant or polyoxyethylene alkyl ether. When used as an aqueous emulsion, the amount of amino-modified silicone contained in the aqueous emulsion is preferably 20 to 60% by mass, and more preferably 30 to 50% by mass. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, and isoparaffinic hydrocarbon.
(E) Polyether-modified silicone: dimethylsiloxane / methyl (polyoxyethylene) siloxane / methyl (polyoxypropylene) siloxane copolymer, dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, dimethylsiloxane / methyl (polyol) Xypropylene) siloxane copolymer and the like.
(F) Alcohol-modified silicone: has a structure in which part of the methyl group of dimethylpolysiloxane is replaced with an alkoxy group, and examples thereof include stearoxymethyl polysiloxane and cetoxymethyl polysiloxane.
(G) Alkyl-modified silicone: having a structure in which a part of methyl group of dimethylpolysiloxane is replaced with a long-chain alkyl group, and having liquid to wax-like properties depending on the substitution rate and size of the alkyl group. It is done.
(H) Aminophenyl-modified silicone: A silicone oil having an N- (2-aminoethyl) aminopropyl group or N- (2-aminoethyl) aminoisobutyl group and a phenyl group. When blended in cosmetics, dissolve in liquid oil or blend an aqueous emulsion prepared in a nonionic surfactant solution such as a cationic surfactant or polyoxyethylene alkyl ether. It is preferable. Examples of the liquid oil include dimethylpolysiloxane, cyclic silicone, and isoparaffinic hydrocarbon.
これらシリコーン誘導体の中では、(a)ジメチルポリシロキサン、(c)高重合ジメチルポリシロキサン、(d)アミノ変性シリコーン及び(h)アミノフェニル変性シリコーンが特に好ましい。これらのシリコーン誘導体は1種又は2種以上を組み合わせて用いることができ、その配合量は組成物全体に対して0.1〜20質量%、更に好ましくは0.5〜5.0質量%である。この配合量の範囲であれば、毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができるため好ましい。 Among these silicone derivatives, (a) dimethylpolysiloxane, (c) highly polymerized dimethylpolysiloxane, (d) amino-modified silicone and (h) aminophenyl-modified silicone are particularly preferable. These silicone derivatives can be used alone or in combination of two or more, and the blending amount thereof is 0.1 to 20% by mass, more preferably 0.5 to 5.0% by mass with respect to the whole composition. is there. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.
さらに本発明においては、(E)成分の、スフィンゴ脂質、セラミド、コレステロール誘導体、フィトステロール誘導体からなる群より選ばれる一種以上を配合することができる。スフィンゴ脂質としては、スフィンゴミエリン等のスフィンゴリン脂質、セレブロシド、ガングリオシド等のスフィンゴ糖脂質が挙げられ、また、トウモロコシ、コムギ胚芽、米フスマ、ほうれん草、スエヒロタケ、マツヨイグサなどの植物中から抽出される各種植物性スフィンゴ脂質が挙げられる。セラミドは、スフィンゴシンに脂肪酸がアミド結合したものであり、セラミド1、セラミド2、セラミド3、セラミド4、セラミド5、セラミド6が天然セラミドとして挙げられ、また、化学合成により製造される擬似セラミド等が挙げられる。コレステロール誘導体としては、水素添加したジヒドロコレステロール、低級又は高級脂肪酸とのエステル体が挙げられ、例えば、ヒドロキシステアリン酸コレステリル、オレイン酸コレステリル、イソステアリン酸コレステリル、ラノリン脂肪酸コレステリル、マカデミアナッツ油脂肪酸コレステリル、ノナン酸コレステリル、ステアリン酸コレステリル、酪酸コレステリルなどが市販されている。フィトステロール誘導体としては、β−シトステロール、スチグマステロール、カンペステロール、及びこれらの水素添加した化合物と低級又は高級脂肪酸とのエステル体が挙げられ、例えば、コメヌカ油脂肪酸フィトステリル、オレイン酸フィトステロール、ノナン酸フィトステロール、ステアリン酸フィトステロール、酪酸フィトステロールなどが市販されている。 Furthermore, in this invention, 1 or more types chosen from the group which consists of a sphingolipid, a ceramide, a cholesterol derivative, and a phytosterol derivative of (E) component can be mix | blended. Examples of sphingolipids include sphingophospholipids such as sphingomyelin, glycosphingolipids such as cerebroside and ganglioside, and various plants extracted from plants such as corn, wheat germ, rice bran, spinach, Shirohirotake and evening primrose. Sex sphingolipids. Ceramide is a sphingosine in which a fatty acid is amide-bonded. Ceramide 1, ceramide 2, ceramide 3, ceramide 4, ceramide 5, ceramide 6 are listed as natural ceramides, and pseudo-ceramides produced by chemical synthesis, etc. Can be mentioned. Examples of cholesterol derivatives include hydrogenated dihydrocholesterol, esters with lower or higher fatty acids, such as cholesteryl hydroxystearate, cholesteryl oleate, cholesteryl isostearate, lanolin fatty acid cholesteryl, macadamia nut oil fatty acid cholesteryl, nonoleate cholesteryl. In addition, cholesteryl stearate, cholesteryl butyrate, and the like are commercially available. Examples of phytosterol derivatives include β-sitosterol, stigmasterol, campesterol, and esters of these hydrogenated compounds and lower or higher fatty acids, such as rice bran oil fatty acid phytosteryl, oleic acid phytosterol, nonanoic acid phytosterol. In addition, phytosterol stearate, phytosterol butyrate and the like are commercially available.
また、本発明の毛髪化粧料には、上記スフィンゴ脂質、セラミド、コレステロール類及びフィトステロール類を溶解するために、液状油分を配合することもできる。液状油分として具体的には、流動パラフィン、スクワラン等の液状炭化水素、オリーブ油、マカデミアナッツ油、ホホバ油、液状ラノリン等の液状動植物抽出油、シリコーン油、パーフルオロ化油、脂肪酸及び高級アルコールを反応させて得られる液状エステル油等が挙げられる。 Moreover, in order to dissolve the sphingolipids, ceramides, cholesterols and phytosterols, a liquid oil can be blended in the hair cosmetic composition of the present invention. Specific examples of liquid oils include liquid hydrocarbons such as liquid paraffin and squalane, olive oil, macadamia nut oil, jojoba oil, liquid lanolin and other liquid animal and plant extract oils, silicone oil, perfluorinated oils, fatty acids and higher alcohols. And liquid ester oils obtained.
これらの(E)成分の中でも、セラミド及びフィトステロール誘導体が、経済性と効果の面で特に好ましい。また、これら(E)成分は1種又は2種以上を組み合わせて用いる事ができ、その配合量は、好ましくは0.01〜10%、更に好ましくは0.1〜5%であ
る。この配合量の範囲であれば、毛髪に対して、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができるため好ましい。
Among these (E) components, ceramide and phytosterol derivatives are particularly preferable in terms of economy and effect. Moreover, these (E) components can be used 1 type or in combination of 2 or more types, The compounding quantity becomes like this. Preferably it is 0.01-10%, More preferably, it is 0.1-5%. This blending amount is preferable because it can give the hair a supple and moist finish without feeling sticky or heavy.
本発明の毛髪化粧料は、上記のヒドロキシエーテル型カチオン、アルキル型カチオン、高級アルコールを必須成分とし、これらを水又は水に適宜な溶剤などを加えた液に含有させることによって調製されるが、これらの必須成分以外にも、本発明の効果を損なわない範囲で通常毛髪化粧料に一般的に配合される他の成分を目的に応じて配合することができる。 The hair cosmetic composition of the present invention is prepared by containing the above-mentioned hydroxy ether cation, alkyl cation, and higher alcohol as essential components, and adding them to water or a solution obtained by adding an appropriate solvent to water. In addition to these essential components, other components generally blended in hair cosmetics can be blended depending on the purpose within a range not impairing the effects of the present invention.
そのような成分としては、例えば、ラウリル硫酸塩、ポリオキシエチレンラウリルーテル硫酸塩、ラウリルベンゼンスルホン酸塩、ラウロイルメチ−β−アラニンナトリウム等のアニオン性界面活性剤;2−アルキル−N−カルボキシメチル−N−ヒドロキシエチルイミダゾニウムベタイン、ヤシ油脂肪酸アミドプロピルベタイン、ヤシ油アルキルN−カルボキシエチル−N−ヒドロキシエチルイミダゾリニウムベタインナトリウム等の両性界面活性剤:ポリオキシエチレンアルキルエーテル、ポリオキシエチレンソルビタン脂肪酸エステル、グリセリン脂肪酸エステル等の非イオン界面活性剤;カチオン化セルロース、ヒドロキシエチルセルロース、ポリ(塩化ジアリルジメチルアンモニウム)、高重合ポリエチレングリコール等の高分子化合物;グリセリン、プロピレングリコール、ブチレングリコール、ジプロピレングリコール等の湿潤剤;ステアリン酸、ベヘニン酸、オレイン酸等の高級脂肪酸;ミリスチン酸イソプロピル等のエステル油;流動イソパラフィン、ワセリン、スクワラン等の炭化水素;ジメチルポリシロキサン、高重合シリコーン、ポリエーテル変性シリコーン等のシリコン類;ジンクピリチオン、塩化ベンザルコニウム等の抗フケ成分;エタノール、メタノール、プロピルアルコール、イソプロピルアルコール等の低級アルコール;L−アスパラギン酸、L−アスパラギン酸ナトリウム、DL−アラニン、L−アルギニン、グリシン、L−グルタミン酸、L−システイン、Lスレオニン等のアミノ酸;その他紫外線吸収剤、防腐剤、糖類、香料、色剤、金属イオン封鎖剤、酸化防止剤、各種薬剤等が挙げられる。 Examples of such components include anionic surfactants such as lauryl sulfate, polyoxyethylene lauryl sulfate, lauryl benzene sulfonate, sodium lauroylmethy-β-alanine; 2-alkyl-N-carboxymethyl -Amphoteric surfactants such as N-hydroxyethyl imidazolium betaine, coconut oil fatty acid amidopropyl betaine, coconut oil alkyl N-carboxyethyl-N-hydroxyethyl imidazolinium betaine sodium: polyoxyethylene alkyl ether, polyoxyethylene sorbitan Nonionic surfactants such as fatty acid esters and glycerin fatty acid esters; polymers such as cationized cellulose, hydroxyethyl cellulose, poly (diallyldimethylammonium chloride), and highly polymerized polyethylene glycol Compound: Wetting agent such as glycerin, propylene glycol, butylene glycol, dipropylene glycol; higher fatty acid such as stearic acid, behenic acid, oleic acid; ester oil such as isopropyl myristate; hydrocarbon such as liquid isoparaffin, petrolatum, squalane Silicones such as dimethylpolysiloxane, highly polymerized silicone and polyether-modified silicone; antidandruff components such as zinc pyrithione and benzalkonium chloride; lower alcohols such as ethanol, methanol, propyl alcohol and isopropyl alcohol; L-aspartic acid, L -Amino acids such as sodium aspartate, DL-alanine, L-arginine, glycine, L-glutamic acid, L-cysteine, L-threonine; other UV absorbers, preservatives, sugars, fragrances, colorants, metals Examples include ion sequestering agents, antioxidants, and various drugs.
本発明の毛髪化粧料は、ヘアリンス、ヘアコンディショナー、ヘアトリートメント、ヘアパック、ヘアローション、ヘアリキッド、ヘアクリーム、ヘアフォーム、リーブオントリートメント、パーマ剤、ヘアカラー等に用いることができる。また本発明の毛髪化粧料は、常法により製造することができる。 The hair cosmetic composition of the present invention can be used for hair rinses, hair conditioners, hair treatments, hair packs, hair lotions, hair liquids, hair creams, hair foams, leave-on treatments, permanent agents, hair colors, and the like. The hair cosmetic composition of the present invention can be produced by a conventional method.
次に本発明を実施例を用いて詳細に説明するが、本発明はこれにより限定されるものではない。実施例に先立ち、各実施例で採用した試験法、評価法を説明する。 EXAMPLES Next, although this invention is demonstrated in detail using an Example, this invention is not limited by this. Prior to the examples, test methods and evaluation methods employed in each example will be described.
(1)毛髪の水分保持力試験法
各試料で処理した毛束を、温度25℃、湿度90%の条件下で24時間放置後、その質量を測定する。その後、温度25℃、湿度30%の条件下で24時間放置後、質量を測定し、湿度90%の条件下での質量を1としたときの相対値を求め、水分保持力とする。値が大きいほど水分保持力が高いことを示す。
(1) Hair moisture retention test method The hair bundle treated with each sample is allowed to stand for 24 hours under conditions of a temperature of 25 ° C. and a humidity of 90%, and then its mass is measured. Thereafter, after being left for 24 hours under conditions of a temperature of 25 ° C. and a humidity of 30%, the mass is measured, and the relative value when the mass under the condition of a humidity of 90% is set to 1 is obtained as moisture retention. A larger value indicates higher moisture retention.
(2)使用時の感触試験法
20名のパネルが試料を使用し、使用時の髪なじみ、指通りについて「良い」、「普通」、「悪い」の3段階で判定し、判定結果を「良い」と回答した人数により判断した。
判断基準は以下の通りである。
(2) Feeling test method during use 20 panels use samples, and the hair familiarity and fingering during use are judged in three stages: “good”, “normal”, and “bad”. Judgment was based on the number of respondents who answered “good”.
Judgment criteria are as follows.
◎:大変優れている・・・「良い」と答えた試験対象者の数が16名以上
○:優れている ・・・「良い」と答えた試験対象者の数が11〜15名
△:劣っている ・・・「良い」と答えた試験対象者の数が6〜10名
×:大変劣っている・・・「良い」と答えた試験対象者の数が5名以下
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less
(3)使用後の毛髪の仕上がり感試験法
20名のパネルが試料を使用し、使用後の毛髪のしっとり感、しなやかさについて「良い」、「普通」、「悪い」の3段階で判定し、判定結果を「良い」と回答した人数により判断した。
判断基準は以下の通りである。
◎:大変優れている・・・「良い」と答えた試験対象者の数が16名以上
○:優れている ・・・「良い」と答えた試験対象者の数が11〜15名
△:劣っている ・・・「良い」と答えた試験対象者の数が6〜10名
×:大変劣っている・・・「良い」と答えた試験対象者の数が5名以下
(3) Hair finish feeling test method after use 20 panels use samples to judge the moist feeling and suppleness of the hair after use in three stages: “good”, “normal”, and “bad”. The judgment result was judged by the number of people who answered “good”.
Judgment criteria are as follows.
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less
(4)低湿度環境でのパサツキのなさ、うるおい感
市販の黒色毛髪(10g,15cm、ビューラックス社製)を10%濃度のポリオキシエチレン(2E.O.)ラウリルエーテル硫酸ナトリウム2gでシャンプー洗浄し、お湯で充分に洗い流した後、本発明のヘアリンス組成物2gを塗布し、お湯で充分に洗い流し、タオルドライを行い、25℃湿度60%の環境下において6時間乾燥させた。次に、低湿度環境下(25℃湿度30%)に12時間放置し、パサツキのなさ、及びうるおい感の項目について、20名のパネルにより「良い」、「普通」、「悪い」の3段階で判定し、判定結果を「良い」と回答した人数により判断した。
判断基準は以下の通りである。
◎:大変優れている・・・「良い」と答えた試験対象者の数が16名以上
○:優れている ・・・「良い」と答えた試験対象者の数が11〜15名
△:劣っている ・・・「良い」と答えた試験対象者の数が6〜10名
×:大変劣っている・・・「良い」と答えた試験対象者の数が5名以下
(4) No rustling in low humidity environment, moist feeling Commercially available black hair (10 g, 15 cm, manufactured by Beaulux) was shampooed with 2 g of 10% polyoxyethylene (2E.O.) sodium lauryl ether sulfate. After thoroughly rinsing with hot water, 2 g of the hair rinse composition of the present invention was applied, rinsed thoroughly with hot water, towel-dried, and dried in an environment of 25 ° C. and 60% humidity for 6 hours. Next, let it stand in a low humidity environment (25 ° C, 30% humidity) for 12 hours, and there are three stages of "good", "normal", and "bad" with 20 panelists on the items of non-pumpiness and moisture feeling. Judgment was made based on the number of people who answered “good”.
Judgment criteria are as follows.
◎: Very excellent ... The number of test subjects who answered "good" is 16 or more. ○: Excellent ... The number of test subjects who answered "good" is 11-15. Inferior ... The number of test subjects who answered "good" is 6 to 10 x: Very inferior ... The number of test subjects who answered "good" is 5 or less
実施例1〜13及び比較例1〜3(ヘアリンス)
表1〜3に記載の配合組成によるヘアリンスを調製し、毛髪の水分保持力、使用時の髪なじみ、指通り等の使用感、使用後の仕上がり感、低湿度下でのパサツキのなさ、うるおい感について調べ、その結果を表1〜3に示した。
Examples 1 to 13 and Comparative Examples 1 to 3 (hair rinse)
Prepare hair rinses with the composition shown in Tables 1 to 3, moisture retention of hair, familiarity with hair during use, feeling of use such as fingering, finished feeling after use, lack of roughness under low humidity, moisture The feeling was examined, and the results are shown in Tables 1-3.
表1〜3より明らかなように、本発明による毛髪化粧料は比較例の組成物に比べて、優れた性能を示していた。 As is apparent from Tables 1 to 3, the hair cosmetic composition according to the present invention exhibited superior performance as compared with the composition of the comparative example.
以下、本発明毛髪化粧料のその他の処方例を実施例として挙げる。なお、これらの実施例の毛髪化粧料についても、上記の毛髪の水分保持力、使用時の髪なじみ、指通り等の使用感、使用後の仕上がり感、低湿度下でのパサツキのなさ、うるおい感の各項目を検討したところ、いずれの実施例においても、優れた特性を有しており良好であった。 Hereinafter, other formulation examples of the hair cosmetic composition of the present invention will be given as examples. In addition, for the hair cosmetics of these examples, the moisture retention of the hair, the familiarity with the hair during use, the feeling of use as a finger, the feeling of finish after use, the lack of roughness under low humidity, moisture When each item of feeling was examined, all the examples had excellent characteristics and were good.
実施例14(ヘアコンディショナー)
配合量(%)
(1)べヘニルPGトリモニウムクロリド 1.0
(2)ステアリルPGトリモニウムクロリド 1.0
(3)塩化ベヘニルトリメチルアンモニウム 0.5
(4)セトステアリルアルコール 6.5
(5)ベヘニルアルコール 0.5
(6)メチルポリシロキサン(300cs) 0.5
(7)高重合メチルポリシロキサン(10万cs) 1.0
(8)コメヌカ油脂肪酸フィトステリル 2.0
(9)流動パラフィン 0.5
(10)パラフィン 0.5
(11)プロピレングリコール 0.5
(12)ソルビトール 3.0
(13)グリセリン 0.5
(14)セラミド2 0.1
(15)トウモロコシ由来スフィンゴ脂質 0.1
(16)ヒドロキシエチルセルロース 0.4
(17)フェノキシエタノール 0.2
(18)香料 0.5
(19)精製水 全量を100とする
Example 14 (hair conditioner)
Compounding amount (%)
(1) Behenyl PG trimonium chloride 1.0
(2) Stearyl PG trimonium chloride 1.0
(3) Behenyltrimethylammonium chloride 0.5
(4) Cetostearyl alcohol 6.5
(5) Behenyl alcohol 0.5
(6) Methyl polysiloxane (300 cs) 0.5
(7) Highly polymerized methylpolysiloxane (100,000 cs) 1.0
(8) Rice bran oil fatty acid phytosteryl 2.0
(9) Liquid paraffin 0.5
(10) Paraffin 0.5
(11) Propylene glycol 0.5
(12) Sorbitol 3.0
(13) Glycerin 0.5
(14) Ceramide 2 0.1
(15) Corn-derived sphingolipid 0.1
(16) Hydroxyethyl cellulose 0.4
(17) Phenoxyethanol 0.2
(18) Fragrance 0.5
(19) Make the total amount of purified water 100
(製法)(1)〜(14)を80℃にて均一に混合溶解し、80℃に加温した(19)に(15)〜(17)を分散したものをプロペラで攪拌しながらを加え、乳化を行う。徐々に冷却を行い、60℃にて(18)を添加し、室温まで冷却して、ヘアコンディショナーを調製した。 (Production method) (1) to (14) were uniformly mixed and dissolved at 80 ° C., and (15) to (17) dispersed in (19) heated to 80 ° C. was added with stirring with a propeller. , Emulsification. The hair conditioner was prepared by gradually cooling, adding (18) at 60 ° C., and cooling to room temperature.
実施例15 ヘアトリートメント
配合量(%)
(1)べヘニルPGトリモニウムクロリド 2.0
(2)塩化ベヘニルトリメチルアンモニウム 1.0
(3)塩化ステアリルトリメチルアンモニウム 0.5
(4)セトステアリルアルコール 6.0
(5)ベヘニルアルコール 3.0
(6)メチルポリシロキサン(100cs) 2.0
(7)高重合メチルポリシロキサン(10万cs) 5.0
(8)コメヌカ油脂肪酸フィトステリル 3.0
(9)セリシン 0.5
(10)流動パラフィン 0.4
(11)パラフィン 2.0
(12)白色ワセリン 1.0
(13)1,3−ブチレングリコール 3.0
(14)ヒドロキシステアリン酸コレステリル 0.5
(15)セレブロシド 0.1
(16)ヒオウギエキス 0.5
(17)加水分解コムギ末 1.0
(18)LIPIDURE−C(日本油脂社製) 1.0
(19)防腐剤(ケーソンCG) 0.1
(20)香料 0.5
(21)精製水 全量を100とする
Example 15 Hair Treatment
Compounding amount (%)
(1) Behenyl PG trimonium chloride 2.0
(2) Behenyltrimethylammonium chloride 1.0
(3) Stearyltrimethylammonium chloride 0.5
(4) Cetostearyl alcohol 6.0
(5) Behenyl alcohol 3.0
(6) Methyl polysiloxane (100 cs) 2.0
(7) Highly polymerized methylpolysiloxane (100,000 cs) 5.0
(8) Rice bran oil fatty acid phytosteryl 3.0
(9) Sericin 0.5
(10) Liquid paraffin 0.4
(11) Paraffin 2.0
(12) White petrolatum 1.0
(13) 1,3-butylene glycol 3.0
(14) Cholesteryl hydroxystearate 0.5
(15) Cerebroside 0.1
(16) Cypress extract 0.5
(17) Hydrolyzed wheat powder 1.0
(18) LIPIDURE-C (manufactured by NOF Corporation) 1.0
(19) Preservative (Caisson CG) 0.1
(20) Fragrance 0.5
(21) 100% purified water
(製法)(1)〜(4)、(6)及び(8)〜(13)を80℃にて均一に混合溶解し油相とする。(7)及び(21)を60℃にて均一に混合攪拌し水相とする。水相に油相を加えて乳化したのち、(5)及び(14)〜(19)加えて、ホモミキサーを用いて均一に混合する。混合しながら徐々に冷却を行い、40℃にて(20)を添加し、室温まで冷却して、ヘアトリートメントを調製した。 (Production Method) (1) to (4), (6) and (8) to (13) are uniformly mixed and dissolved at 80 ° C. to obtain an oil phase. (7) and (21) are uniformly mixed and stirred at 60 ° C. to obtain an aqueous phase. After the oil phase is added to the aqueous phase and emulsified, (5) and (14) to (19) are added and mixed uniformly using a homomixer. While mixing, the mixture was gradually cooled, (20) was added at 40 ° C., and the mixture was cooled to room temperature to prepare a hair treatment.
実施例16 アウトバストリートメント
配合量(%)
(1)べヘニルPGトリモニウムクロリド 1.0
(2)塩化ベヘニルトリメチルアンモニウム 0.5
(3)塩化ステアリルトリメチルアンモニウム 0.2
(4)セチルアルコール 4.0
(5)シリコーン水性エマルジョン 2.0
(XS65−B7116、GE東芝シリコン社製)
(6)コメヌカ油脂肪酸フィトステリル 3.0
(7)オレイン酸コレステリル 1.0
(8)1,3−ブチレングリコール 2.0
(9)セバシン酸ジエチル 3.0
(10)海苔タンパク質加水分解物 2.0
(ピュアポルフィラPE、株式会社白子社製)
(11)ローヤルゼリーエキス 0.2
(12)フェノキシエタノール 0.2
(13)香料 微 量
(14)精製水 全量を100とする
Example 16 Out bath treatment
Compounding amount (%)
(1) Behenyl PG trimonium chloride 1.0
(2) Behenyltrimethylammonium chloride 0.5
(3) Stearyltrimethylammonium chloride 0.2
(4) Cetyl alcohol 4.0
(5) Silicone aqueous emulsion 2.0
(XS65-B7116, manufactured by GE Toshiba Silicon Corporation)
(6) Rice bran oil fatty acid phytosteryl 3.0
(7) Cholesteryl oleate 1.0
(8) 1,3-butylene glycol 2.0
(9) Diethyl sebacate 3.0
(10) Nori protein hydrolyzate 2.0
(Pure Porphyra PE, manufactured by Shiroko Co., Ltd.)
(11) Royal jelly extract 0.2
(12) Phenoxyethanol 0.2
(13) Fragrance fine amount (14) Purified water Total amount is 100
(製法)(1)〜(4)及び(6)〜(8)を80℃にて均一に混合溶解させ、(9)〜(12)及び(14)を70℃にて混合したものを加えて乳化し、モミキサーで混合分散を行いながら、60℃にて(5)及び(13)を加え、室温まで冷却して、アウトバストリートメントを調製した。 (Production method) (1) to (4) and (6) to (8) are uniformly mixed and dissolved at 80 ° C, and (9) to (12) and (14) are mixed at 70 ° C. (5) and (13) were added at 60 ° C. while mixing and dispersing with a momixer, and the mixture was cooled to room temperature to prepare an out bath treatment.
実施例17 ヘアパック
配合量(%)
(1)べヘニルPGトリモニウムクロリド 0.5
(2)塩化ベヘニルトリメチルアンモニウム 2.0
(3)ベヘニルアルコール 5.0
(4)セトステアリルアルコール 5.0
(5)コメヌカ油脂肪酸フィトステリル 1.0
(6)シリコーン水性エマルジョン
(XS65−B7116、GE東芝シリコン社製) 6.0
(7)ヒドロキシウレア 1.0
(8)PG 3.0
(9)セバシン酸ジエチル 1.0
(10)エデト酸二ナトリウム 0.1
(11)フェノキシエタノール 0.2
(12)香料 0.6
(13)精製水 全量を100とする
Example 17 Hair Pack
Compounding amount (%)
(1) Behenyl PG trimonium chloride 0.5
(2) Behenyltrimethylammonium chloride 2.0
(3) Behenyl alcohol 5.0
(4) Cetostearyl alcohol 5.0
(5) Rice bran oil fatty acid phytosteryl 1.0
(6) Silicone aqueous emulsion (XS65-B7116, manufactured by GE Toshiba Silicon Corp.) 6.0
(7) Hydroxyurea 1.0
(8) PG 3.0
(9) Diethyl sebacate 1.0
(10) Edetate disodium 0.1
(11) Phenoxyethanol 0.2
(12) Fragrance 0.6
(13) Total amount of purified water is 100
(製法)(1)〜(5)を80℃にて均一に混合溶解させ、(8)〜(13)を50℃にて混合したものを加えて乳化し、モミキサーで混合分散を行いながら、50℃で(6)〜(7)を加えて、室温まで冷却して、ヘアパックを調製した。 (Production method) (1) to (5) are uniformly mixed and dissolved at 80 ° C., and (8) to (13) mixed at 50 ° C. are added and emulsified. (6)-(7) was added at 50 degreeC, and it cooled to room temperature, and prepared the hair pack.
実施例18 トリートメントフォーム
配合量(%)
(1)べヘニルPGトリモニウムクロリド 0.5
(2)塩化ベヘニルトリメチルアンモニウム 0.2
(3)セトステアリルアルコール 1.0
(4)メチルポリシロキサン(300cs) 0.5
(5)ポリエーテル変性シリコーン
(シリコンFZ−4173、東レダウコーニング社) 0.5
(6)コメヌカ油脂肪酸フィトステリル 1.0
(7)マカデミアナッツ油脂肪酸コレステリル 0.2
(8)セラミド1・セラミド5混合物(1:1) 0.1
(9)ポリオキシエチレン(15)セチエルエーテル 0.5
(10)ポリオキシエチレン(20)セチルエーテル 0.5
(11)ポリオキシエチレン(60)硬化ヒマシ油 0.5
(12)1,3−ブチレングリコール 0.5
(13)フェノキシエタノール 0.5
(14)精製水 全量を100とする
Example 18 Treatment Form
Compounding amount (%)
(1) Behenyl PG trimonium chloride 0.5
(2) Behenyltrimethylammonium chloride 0.2
(3) cetostearyl alcohol 1.0
(4) Methyl polysiloxane (300 cs) 0.5
(5) Polyether-modified silicone (silicon FZ-4173, Toray Dow Corning) 0.5
(6) Rice bran oil fatty acid phytosteryl 1.0
(7) Macadamia nut oil fatty acid cholesteryl 0.2
(8) Ceramide 1 / ceramide 5 mixture (1: 1) 0.1
(9) Polyoxyethylene (15) cetiel ether 0.5
(10) Polyoxyethylene (20) cetyl ether 0.5
(11) Polyoxyethylene (60) hydrogenated castor oil 0.5
(12) 1,3-butylene glycol 0.5
(13) Phenoxyethanol 0.5
(14) Total amount of purified water is 100
(製法)(1)〜(11)を80℃にて均一に混合溶解し、80℃に加温した(14)にプロペラで攪拌しながら加えて乳化する。徐々に冷却を行い、60℃にて(12)及び(13)を添加し、室温まで冷却して、原液とした。次にエアゾール耐圧容器に原液:LPGガスを92:8の比率で充填し、トリートメントフォームを調製した。 (Manufacturing method) (1) to (11) are uniformly mixed and dissolved at 80 ° C and added to (14) heated to 80 ° C while stirring with a propeller to emulsify. The mixture was gradually cooled, (12) and (13) were added at 60 ° C., and cooled to room temperature to obtain a stock solution. Next, the aerosol pressure vessel was filled with stock solution: LPG gas at a ratio of 92: 8 to prepare a treatment foam.
以上記載のごとく、本発明は、べたつきや重さを感じることなく、しなやかでしっとりとした仕上がり感を与えることができ、かつ低湿度下でのパサツキ防止とうるおい感に優れた毛髪化粧料を提供することができる。 As described above, the present invention provides a hair cosmetic that can give a supple and moist finish without feeling sticky or heavy, and that is excellent in prevention of moisture and moisture in low humidity. can do.
Claims (4)
(A)下記一般式(I)で表されるヒドロキシエーテル型カチオン
R1−(OCH2CH(OH)CH2)m−N+(R2)3・X− … (I)(式中、R1は、直鎖又は分岐した炭素数12〜24の飽和もしくは不飽和アルキル基、R2は炭素数1〜3のアルキル基、mは1〜3の整数、Xはハロゲン原子又は炭素数1〜3のアルキル硫酸基を示す。)
(B)下記一般式(II)で表されるアルキル型カチオン
(C)炭素数14〜24の長鎖のアルキル基を有する高級アルコール A hair cosmetic containing the following components (A) to (C).
(A) Hydroxy ether type cation represented by the following general formula (I) R 1 — (OCH 2 CH (OH) CH 2 ) m —N + (R 2 ) 3 · X − (I) (wherein R 1 is a linear or branched saturated or unsaturated alkyl group having 12 to 24 carbon atoms, R 2 is an alkyl group having 1 to 3 carbon atoms, m is an integer of 1 to 3, X is a halogen atom or 1 carbon atom ˜3 alkyl sulfate groups.)
(B) Alkyl cation represented by the following general formula (II)
(C) A higher alcohol having a long-chain alkyl group having 14 to 24 carbon atoms
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Cited By (7)
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JP2011012058A (en) * | 2009-06-03 | 2011-01-20 | Toho Chem Ind Co Ltd | Composition for hair |
JP2012171890A (en) * | 2011-02-18 | 2012-09-10 | Kracie Home Products Ltd | Hair rinse composition |
JP2013023471A (en) * | 2011-07-21 | 2013-02-04 | Kracie Home Products Ltd | Hair rinsing composition |
JP2013043848A (en) * | 2011-08-23 | 2013-03-04 | Kracie Home Products Ltd | Hair cosmetic |
JP2014043419A (en) * | 2012-08-27 | 2014-03-13 | Kracie Home Products Ltd | Hair cosmetic |
JP2014043426A (en) * | 2012-08-28 | 2014-03-13 | Kracie Home Products Ltd | Hair cosmetics |
JP2014156424A (en) * | 2013-02-15 | 2014-08-28 | Kracie Home Products Ltd | Hair cosmetic |
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JP2011012058A (en) * | 2009-06-03 | 2011-01-20 | Toho Chem Ind Co Ltd | Composition for hair |
JP2012171890A (en) * | 2011-02-18 | 2012-09-10 | Kracie Home Products Ltd | Hair rinse composition |
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JP2013043848A (en) * | 2011-08-23 | 2013-03-04 | Kracie Home Products Ltd | Hair cosmetic |
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JP2014156424A (en) * | 2013-02-15 | 2014-08-28 | Kracie Home Products Ltd | Hair cosmetic |
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