JP2009520113A - マトリックスを含まないポリピリダゾール短繊維の不織層 - Google Patents
マトリックスを含まないポリピリダゾール短繊維の不織層 Download PDFInfo
- Publication number
- JP2009520113A JP2009520113A JP2008544652A JP2008544652A JP2009520113A JP 2009520113 A JP2009520113 A JP 2009520113A JP 2008544652 A JP2008544652 A JP 2008544652A JP 2008544652 A JP2008544652 A JP 2008544652A JP 2009520113 A JP2009520113 A JP 2009520113A
- Authority
- JP
- Japan
- Prior art keywords
- polypyridazole
- filament
- average
- fibers
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 95
- 239000011159 matrix material Substances 0.000 title claims abstract description 10
- 239000004744 fabric Substances 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims description 19
- 229920006231 aramid fiber Polymers 0.000 claims description 7
- -1 (2,5-dihydroxy) phenylene Chemical group 0.000 claims description 6
- 239000004760 aramid Substances 0.000 claims description 6
- 230000035515 penetration Effects 0.000 claims description 6
- 229920003366 poly(p-phenylene terephthalamide) Polymers 0.000 claims description 4
- 238000004080 punching Methods 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 7
- 239000002131 composite material Substances 0.000 description 7
- 239000002759 woven fabric Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 6
- 239000012634 fragment Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 229920012306 M5 Rigid-Rod Polymer Fiber Polymers 0.000 description 3
- 229920002480 polybenzimidazole Polymers 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- 229920003235 aromatic polyamide Polymers 0.000 description 2
- 238000007378 ring spinning Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920000456 Kevlar® KM2 Polymers 0.000 description 1
- ZCQWOFVYLHDMMC-UHFFFAOYSA-N Oxazole Chemical compound C1=COC=N1 ZCQWOFVYLHDMMC-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- BBAWTPDTGRXPDG-UHFFFAOYSA-N [1,3]thiazolo[4,5-b]pyridine Chemical compound C1=CC=C2SC=NC2=N1 BBAWTPDTGRXPDG-UHFFFAOYSA-N 0.000 description 1
- 238000010042 air jet spinning Methods 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000007383 open-end spinning Methods 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F41—WEAPONS
- F41H—ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- F41H5/00—Armour; Armour plates
- F41H5/02—Plate construction
- F41H5/04—Plate construction composed of more than one layer
- F41H5/0471—Layered armour containing fibre- or fabric-reinforced layers
- F41H5/0485—Layered armour containing fibre- or fabric-reinforced layers all the layers being only fibre- or fabric-reinforced layers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/02—Layered products comprising a layer of synthetic resin in the form of fibres or filaments
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4334—Polyamides
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4334—Polyamides
- D04H1/4342—Aromatic polyamides
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/498—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
- D04H3/009—Condensation or reaction polymers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Nonwoven Fabrics (AREA)
- Laminated Bodies (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Multicomponent Fibers (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Artificial Filaments (AREA)
- Woven Fabrics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US74887705P | 2005-12-08 | 2005-12-08 | |
| PCT/US2006/061738 WO2007145673A2 (en) | 2005-12-08 | 2006-12-07 | Matrix free non-woven layer of polypyridazle short fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2009520113A true JP2009520113A (ja) | 2009-05-21 |
| JP2009520113A5 JP2009520113A5 (enExample) | 2010-01-28 |
Family
ID=38721757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2008544652A Pending JP2009520113A (ja) | 2005-12-08 | 2006-12-07 | マトリックスを含まないポリピリダゾール短繊維の不織層 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8051494B2 (enExample) |
| EP (1) | EP1957700B1 (enExample) |
| JP (1) | JP2009520113A (enExample) |
| KR (1) | KR20080075219A (enExample) |
| CN (1) | CN101374986B (enExample) |
| WO (1) | WO2007145673A2 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2047019B1 (en) * | 2006-07-31 | 2010-11-03 | E.I. Du Pont De Nemours And Company | Nonwoven web comprising polyarenazole microfibers and process for making same |
| US7665149B2 (en) * | 2008-05-14 | 2010-02-23 | E.I. Du Pont De Nemours And Company | Ballistic resistant body armor articles |
| US8015617B1 (en) * | 2008-05-14 | 2011-09-13 | E. I. Du Pont De Nemours And Company | Ballistic resistant body armor articles |
| SG172188A1 (en) * | 2008-12-18 | 2011-07-28 | Novartis Ag | Reusable lens molds, methods of use thereof and ophthalmic lenses |
| GB2459945B (en) * | 2009-04-06 | 2014-10-08 | Vestas Wind Sys As | PIPD fibres in wind turbine blades |
| CA2722136C (en) | 2009-04-20 | 2015-06-16 | Barrday Inc. | Improved ballistic composites having large denier per filament high performance yarns |
| US20110312238A1 (en) * | 2009-12-29 | 2011-12-22 | E.I. Du Pont De Nemours And Company | Enhanced lightweight ballistic materials |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07505453A (ja) * | 1992-04-03 | 1995-06-15 | デーエスエム・ナムローゼ・フェンノートシャップ | 実質的に短ポリオレフィン繊維からなる不織層 |
| JPH08509516A (ja) * | 1993-04-28 | 1996-10-08 | アクゾ ノーベル ナムローゼ フェンノートシャップ | ピリドビスイミダゾールに基く剛直なロッドポリマー |
| US5736474A (en) * | 1993-03-25 | 1998-04-07 | Thomas; Howard L. | Multi-structure ballistic material |
| WO1999027169A1 (en) * | 1997-11-21 | 1999-06-03 | Akzo Nobel N.V. | Flame-retardant materials |
| JP2007500798A (ja) * | 2003-07-25 | 2007-01-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 抗菌性の弾道布および保護物品 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT318252B (de) * | 1972-03-06 | 1974-10-10 | Fehrer Ernst Gmbh | Vorrichtung zum Einführen von Vliesen in Nadelmaschinen |
| WO1994021450A1 (en) | 1993-03-25 | 1994-09-29 | Thomas Howard L | Ballistic resistant fabric |
| BR0012310A (pt) | 1999-06-14 | 2002-03-19 | Du Pont | Processo de ruptura por tração, fio, método de operação de uma máquina de fiação de fibra básica e processo para a conversão da fibra de filamento contìnuo em fio de filamento descontìnuo |
| DE60336140D1 (de) * | 2002-06-27 | 2011-04-07 | Teijin Aramid Bv | Verfahren zur herstellung von synthetisch-organischen fasern mit hoher festigkeit und/oder hohem modul aus aromatischen heterozyklischen steifen polymeren |
| WO2005001373A1 (en) | 2003-06-27 | 2005-01-06 | Auburn University | Layered ballistic-resistant material |
| US8008217B2 (en) * | 2005-06-21 | 2011-08-30 | E.I. Du Pont De Nemours And Company | Fabrics with strain-responsive viscous liquid polymers |
| EP2047019B1 (en) * | 2006-07-31 | 2010-11-03 | E.I. Du Pont De Nemours And Company | Nonwoven web comprising polyarenazole microfibers and process for making same |
| US7771810B2 (en) * | 2006-12-15 | 2010-08-10 | E.I. Du Pont De Nemours And Company | Honeycomb from paper having a high melt point thermoplastic fiber |
| US7665149B2 (en) * | 2008-05-14 | 2010-02-23 | E.I. Du Pont De Nemours And Company | Ballistic resistant body armor articles |
-
2006
- 2006-12-07 CN CN2006800463755A patent/CN101374986B/zh not_active Expired - Fee Related
- 2006-12-07 KR KR1020087016439A patent/KR20080075219A/ko not_active Ceased
- 2006-12-07 US US12/086,221 patent/US8051494B2/en not_active Expired - Fee Related
- 2006-12-07 JP JP2008544652A patent/JP2009520113A/ja active Pending
- 2006-12-07 EP EP06851361A patent/EP1957700B1/en not_active Not-in-force
- 2006-12-07 WO PCT/US2006/061738 patent/WO2007145673A2/en not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07505453A (ja) * | 1992-04-03 | 1995-06-15 | デーエスエム・ナムローゼ・フェンノートシャップ | 実質的に短ポリオレフィン繊維からなる不織層 |
| US5736474A (en) * | 1993-03-25 | 1998-04-07 | Thomas; Howard L. | Multi-structure ballistic material |
| JPH08509516A (ja) * | 1993-04-28 | 1996-10-08 | アクゾ ノーベル ナムローゼ フェンノートシャップ | ピリドビスイミダゾールに基く剛直なロッドポリマー |
| WO1999027169A1 (en) * | 1997-11-21 | 1999-06-03 | Akzo Nobel N.V. | Flame-retardant materials |
| JP2007500798A (ja) * | 2003-07-25 | 2007-01-18 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 抗菌性の弾道布および保護物品 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007145673A3 (en) | 2008-06-12 |
| CN101374986B (zh) | 2012-07-04 |
| EP1957700B1 (en) | 2012-07-18 |
| KR20080075219A (ko) | 2008-08-14 |
| WO2007145673A2 (en) | 2007-12-21 |
| CN101374986A (zh) | 2009-02-25 |
| US8051494B2 (en) | 2011-11-08 |
| US20090188014A1 (en) | 2009-07-30 |
| EP1957700A2 (en) | 2008-08-20 |
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