JP2009256267A - Scalp and hair cosmetic - Google Patents
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本発明は頭皮頭髪用化粧料、ヘアトニックなどの頭皮用化粧料とヘアリキッドなどの整髪用化粧料との双方の機能を兼ね備えた新たなタイプの頭皮頭髪用の化粧料に関する。 The present invention relates to a new type of scalp and hair cosmetics which has both functions of a scalp and hair cosmetics, a scalp cosmetic such as a hair tonic, and a hairdressing cosmetic such as a hair liquid.
これまで、頭に使用する化粧料として、ヘアトニックなど、ふけやかゆみを抑えるなど頭皮への作用目的を有する頭皮用化粧料と、整髪を主たる目的とするヘアリキッドに代表される整髪用化粧料とに大別される。 So far, cosmetics used on the head, such as hair tonics, scalp cosmetics that have a purpose of acting on the scalp, such as suppressing dandruff and itching, and hair styling cosmetics represented by hair liquids that are primarily intended for hair styling. It is roughly divided into
頭皮用化粧料であるヘアトニックは、アルコールを含む水溶液であって、必要に応じて、メントールやトウガラシチンキなどの清涼剤や鎮痒剤、センブリエキス、エストラジオールなどの育毛成分を含む。また、場合によってはグリセリンなどの保湿剤を含む場合がある。ヘアトニックは頭皮に適用され、頭皮に清涼感を付与したり、頭皮への刺激により育毛を促進する化粧料であるので、油分や増粘剤は基本的には含まれず、配合された場合も、それらの配合量はそれぞれ１％以下、多くとも５％以下である。 A hair tonic, which is a cosmetic for scalp, is an aqueous solution containing alcohol, and if necessary, contains a hair-growth component such as a refreshing agent or an antipruritic agent such as menthol or chili tincture, an assembly extract, or estradiol. In some cases, a humectant such as glycerin may be included. Hair tonic is a cosmetic that is applied to the scalp and gives a refreshing feeling to the scalp and promotes hair growth by stimulating the scalp, so oils and thickeners are basically not included. Their blending amounts are each 1% or less, and at most 5% or less.
例えば、特開平５−５８８５０号公報（特許文献１）には、ヘアトニックに分類されうる化粧料として、奇数炭素数を有する脂肪酸類もしくは奇数炭素数を有するアルコール類と、ヒドロキシプロピルアルコールと、低級アルコールとを含有する頭皮用化粧料が記載されている。また、特開２００７−２３８５６９号公報（特許文献２）には、エタノールを２０％、１，３−ブチレングリコールを３％、ポリオキシエチレングリコールを０．５％、その他の育毛成分を０．５％含むヘアトニックが開示されている。 For example, Japanese Patent Application Laid-Open No. 5-58850 (Patent Document 1) describes cosmetics that can be classified as hair tonics as fatty acids having an odd number of carbons or alcohols having an odd number of carbons, hydroxypropyl alcohol, A scalp cosmetic containing alcohol is described. Japanese Patent Application Laid-Open No. 2007-238569 (Patent Document 2) discloses that ethanol is 20%, 1,3-butylene glycol is 3%, polyoxyethylene glycol is 0.5%, and other hair growth ingredients are 0.5. % Hair tonic is disclosed.
整髪用化粧料は、水を主体としたヘアリキッド、エマルジョン系であるヘアクリームやヘアフォーム、ゲル状のヘアジェル、ワックス状のヘアワックスに分類される。整髪用化粧料は、整髪のために、油分や樹脂成分、毛髪への被膜を形成するために必要な量の水溶性高分子、さらには固形状のワックスが配合された化粧料である。 Hairdressing cosmetics are classified into water-based hair liquids, emulsion-type hair creams and hair foams, gel-like hair gels, and wax-like hair waxes. Hairdressing cosmetics are cosmetics in which an oil, a resin component, a water-soluble polymer in an amount necessary to form a film on hair, and a solid wax are blended for hairdressing.
例えば、前述の特許文献２には、エタノールを４０％、グリセリンを５％、Ｎ−メタクリロイルオキシエチル−Ｎ，Ｎ−ジメチルアンモニウム−α，Ｎ−カルボキシベタイン・メタクリル酸ブチル重合体を３％、スクワランを１０％、ポリオキシエチレンセチルエーテルを２．５％、その他の育毛成分を０．２％含むヘアリキッドが開示されている。 For example, in Patent Document 2 mentioned above, ethanol 40%, glycerin 5%, N-methacryloyloxyethyl-N, N-dimethylammonium-α, N-carboxybetaine / butyl methacrylate polymer 3%, squalane 10%, 2.5% polyoxyethylene cetyl ether, and 0.2% other hair growth ingredients are disclosed.
特開２００６−２８１１３号公報（特許文献３）には、ヘアリキッドとしても使用されうる頭髪用化粧料として、カチオン界面活性剤と多価アルコール、シリコーン化ペプチド−ポリシロキサン化合物共重合体並びに特定構造の高重合シリコーンを含む組成物が記載されている。また、特開２００７−３０８４２４号公報（特許文献４）には、ツバキ油を２０％、濃グリセリン５％、カルボキシビニルポリマーを０．１５％、非イオン界面活性剤であるポリオキシエチレン硬化ヒマシ油を４％、ツバキセラミドを０．１％含む保湿性に優れた整髪用化粧料が開示されている。 JP 2006-28113 A (Patent Document 3) discloses a cosmetic for hair that can also be used as a hair liquid, a cationic surfactant, a polyhydric alcohol, a silicone-modified peptide-polysiloxane compound copolymer, and a specific structure. A composition comprising a highly polymerized silicone is described. JP 2007-308424 (Patent Document 4) discloses 20% camellia oil, 5% concentrated glycerin, 0.15% carboxyvinyl polymer, polyoxyethylene hydrogenated castor oil which is a nonionic surfactant. Hair styling cosmetics excellent in moisturizing properties containing 4% and 0.1% Tsubakiceramide are disclosed.
特開２００７−１５９３６号公報（特許文献５）には、塩化ベヘニルトリエチルアンモニウムなどの界面活性剤を５％、プロピレングリコールや高級アルコールを５．５％、流動パラフィンやシリコーン、ステアリルアルコールなどの油分を２５％を含むヘアクリームが開示されている。また、前記特許文献４には、ツバキ油を２５％、濃グリセリンを５％、ステアリン酸を２．５％、ベヘニルアルコールを１．０％、水添大豆リン脂質を１％、ツバキセラミドを０．１％を含んだヘアクリームが開示されている。 JP 2007-15936 A (Patent Document 5) contains 5% surfactant such as behenyltriethylammonium chloride, 5.5% propylene glycol and higher alcohol, oil such as liquid paraffin, silicone and stearyl alcohol. A hair cream containing 25% is disclosed. In Patent Document 4, camellia oil is 25%, concentrated glycerin is 5%, stearic acid is 2.5%, behenyl alcohol is 1.0%, hydrogenated soybean phospholipid is 1%, and camelloceramide is 0. A hair cream containing 1% is disclosed.
特開２００７−３２６７９７号公報（特許文献６）には、カルボキシビニルポリマーを０．５％、ポリオキシエチレン硬化ヒマシ油を３％、ポリオキシエチレンステアリルエーテルを３％、Ｎ−メタクリロイルオキシエチル−Ｎ，Ｎ−ジメチルアンモニウム−α，Ｎ−カルボキシベタイン・アルキルメタクリル酸エステル共重合体系を７％、エタノールを５％、グリセリンを５％、ジグリセリンを６％、トリエタノールアミン０．６％を含むヘアジェルが開示されている。特開２００７−２９７２９９号公報（特許文献７）には、エタノールを１０％、ポリビニルピロリドンを６％、ポリオキシエチレンホホバ油を３．０％、イソプレングリコールを５％、カルボキシビニルポリマーを０．３％、中和剤を０．２％を含むヘアジェルが開示されている。 In JP 2007-326797 A (Patent Document 6), 0.5% of carboxyvinyl polymer, 3% of polyoxyethylene hydrogenated castor oil, 3% of polyoxyethylene stearyl ether, N-methacryloyloxyethyl-N , N-dimethylammonium-α, N-carboxybetaine alkylmethacrylate copolymer system containing 7%, ethanol 5%, glycerin 5%, diglycerin 6%, triethanolamine 0.6% Is disclosed. In JP 2007-297299 A (Patent Document 7), ethanol is 10%, polyvinylpyrrolidone is 6%, polyoxyethylene jojoba oil is 3.0%, isoprene glycol is 5%, carboxyvinyl polymer is 0.3%. %, And a gel containing 0.2% neutralizing agent is disclosed.
さらに、特開２００７−３２０８７２号公報（特許文献８）には、室温で固形のロウ類および／又は室温で固形の炭化水素類、ポリオキシプロピレンソルビット、ポリオキシアルキレンアルキルエーテル、およびソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、グリセリン脂肪酸エステルおよびポリオキシエチレングリセリン脂肪酸エステルからなる群から選ばれる１種以上を含有してなるワックス状の整髪用化粧料が開示されている。 Furthermore, Japanese Patent Application Laid-Open No. 2007-320872 (Patent Document 8) discloses waxes that are solid at room temperature and / or hydrocarbons that are solid at room temperature, polyoxypropylene sorbite, polyoxyalkylene alkyl ether, and sorbitan fatty acid ester, A waxy hairdressing cosmetic composition containing at least one selected from the group consisting of polyoxyethylene sorbitan fatty acid ester, glycerin fatty acid ester and polyoxyethylene glycerin fatty acid ester is disclosed.
特開２００６−２６５２１７号公報（特許文献９）には、カルボキシビニルポリマーを０．０５〜２％、ポリビニルピロリドンを０．５〜５％、ヒドロキシエチルセルロースを０．０５〜２％、親水性のノニオン界面活性剤を１０〜４０％を含み、水性の整髪用化粧料でありながら油性ワックス様の質感と整髪力を備えた新たなタイプの整髪用化粧料が開示されている。 Japanese Patent Application Laid-Open No. 2006-265217 (Patent Document 9) discloses a carboxyvinyl polymer of 0.05 to 2%, polyvinylpyrrolidone of 0.5 to 5%, hydroxyethyl cellulose of 0.05 to 2%, and a hydrophilic nonion. A new type of hairdressing cosmetics containing 10 to 40% of a surfactant and having an oily wax-like texture and hairstyling power while being an aqueous hairdressing cosmetic is disclosed.
しかしながら、上記した整髪用化粧料は、油分以外にアクリル系やビニルピロリドン系、ビニルメチルエーテル系等の樹脂成分、頭髪に被膜を形成する水溶性高分子や常温で固形状のワックスを含んでいるので、直接地肌に化粧料が届きにくい。そこで、整髪だけでなく清涼感も得ようとするならば、頭皮への直接適用を目的とする頭皮用化粧料と、整髪を目的とする整髪用化粧料を併用しなければならなかった。 However, the above-described cosmetic for hairdressing contains not only oil but also resin components such as acrylic, vinyl pyrrolidone, and vinyl methyl ether, a water-soluble polymer that forms a film on the hair, and a solid wax at room temperature. Therefore, it is difficult for cosmetics to reach the skin directly. Therefore, in order to obtain not only hair styling but also a refreshing feeling, it was necessary to use a scalp cosmetic intended for direct application to the scalp and a hair styling cosmetic intended for hair styling.
このとき、化粧料を頭皮にまで届かせ、頭皮に清涼感を付与するために、上記の整髪用化粧料、例えばヘアクリームやヘアフォームなどの乳化系化粧料に多量のアルコールを添加すると、エマルジョンが壊れてしまい、油のべたつき感だけを生じてしまう。また、ヘアジェルにアルコールを加えると増粘剤の機能が失われてしまい、良好な整髪性を確保できない。さらに、ヘアワックスにアルコールを加えるとワックスがアルコールに溶解して粘性のある液状になるが、ワックスのためにアルコールが頭皮に到達せず、頭皮用化粧料の機能を果たさない。そして、ヘアリキッドにアルコールを加えるのでは、リキッドに含まれる水溶性高分子や樹脂成分の配合を増やさざるを得ず、十分な整髪効果が得られない。一方、ヘアトニックに油分を加えたのでは安定な製剤とならず、良好な整髪性も得ることができない。このように、これまでの頭皮用化粧料や頭髪用化粧料では解決すべく多くの問題があった。 At this time, in order to reach the scalp and impart a refreshing feeling to the scalp, when a large amount of alcohol is added to the above-mentioned hairdressing cosmetic, for example, an emulsified cosmetic such as a hair cream or a hair foam, an emulsion Will be broken and only the oil will be sticky. Moreover, when alcohol is added to a hair gel, the function of a thickener will be lost and favorable hair-styling property cannot be ensured. Furthermore, when alcohol is added to the hair wax, the wax dissolves in the alcohol and becomes a viscous liquid, but because of the wax, the alcohol does not reach the scalp and does not function as a scalp cosmetic. If alcohol is added to the hair liquid, the amount of the water-soluble polymer and the resin component contained in the liquid must be increased, and a sufficient hair styling effect cannot be obtained. On the other hand, when oil is added to the hair tonic, the preparation is not stable, and good hair styling properties cannot be obtained. As described above, the conventional scalp cosmetics and hair cosmetics have many problems to be solved.
本発明は上記の背景技術に鑑みてなされたものであって、頭皮用化粧料のように頭皮への適用が可能な化粧料であって、しかも適切な整髪性が得られる新たなタイプの頭皮頭髪用の化粧料を提供することを目的としている。 The present invention has been made in view of the above-described background art, and is a cosmetic that can be applied to the scalp, such as a scalp cosmetic, and is a new type of scalp that provides appropriate hair-styling properties. It aims to provide cosmetics for hair.
本発明の頭皮頭髪用化粧料は、３０〜５０質量％のエタノールと、１０〜３０質量％の室温で液体であるシリコーン及び室温で液体である炭化水素からなる群から選ばれる１種又は２種以上の化合物、０．１〜０．５質量％の非イオン界面活性剤、０．０１〜０．５質量％のカルボキシビニルポリマー及び２０〜５０質量％の水を含む油滴分散型の頭皮頭髪用化粧料である。 The scalp and hair cosmetic of the present invention is one or two selected from the group consisting of 30 to 50% by mass of ethanol, 10 to 30% by mass of silicone that is liquid at room temperature and hydrocarbon that is liquid at room temperature. An oil droplet-dispersed scalp scalp hair comprising the above compound, 0.1 to 0.5% by mass of a nonionic surfactant, 0.01 to 0.5% by mass of carboxyvinyl polymer and 20 to 50% by mass of water. For cosmetics.
本発明によると、へアリキッドのような良好な整髪性とヘアトニックのような清涼感を同時に付与できる新しいタイプの頭皮頭髪用化粧料が提供される。 ADVANTAGE OF THE INVENTION According to this invention, the new type scalp hair cosmetics which can provide the good hair-styling property like hair liquid and the refreshing feeling like hair tonic simultaneously are provided.
本発明の頭皮頭髪用化粧料は、３０〜５０質量％のエタノールと、１０〜３０質量％のシリコーン及び室温で液状である炭化水素からなる群から選ばれる１種又は２種以上の化合物、０．１〜０．５質量％の非イオン界面活性剤、０．０１〜０．５質量％のカルボキシビニルポリマー及び２０〜５０質量％の水を含む。 The cosmetic for scalp and hair of the present invention is one or two or more compounds selected from the group consisting of 30 to 50% by mass of ethanol, 10 to 30% by mass of silicone, and hydrocarbons that are liquid at room temperature, 0 0.1-0.5% by weight nonionic surfactant, 0.01-0.5% by weight carboxyvinyl polymer and 20-50% by weight water.
本発明の頭皮頭髪用化粧品は、エタノールと油分を主体とした油滴分散系の化粧料である。本発明においては、エタノールを３０〜５０質量％を含む。この範囲内において適度な清涼感を付与できる。 The cosmetic for scalp and hair of the present invention is an oil droplet dispersion cosmetic mainly composed of ethanol and oil. In this invention, 30-50 mass% of ethanol is included. An appropriate refreshing feeling can be imparted within this range.
本発明において油分として常温で液状であるシリコーン又は常温で液状である炭化水素類が用いられ、その中でも特に、水、アルコール、グリコール類に溶解しない化合物が用いられる。ここで、水等に溶解しないとは、常温において任意の割合で溶解しないという意味であって、両者を混合した場合に２相となればよく、わずかに溶解されても差し支えない。シリコーンは、オルガノポリシロキサン類の総称であって、いわゆるシリコーンオイルと称されるものが好適に用いられる。また、油分として化粧料中に分散されるのであれば、シリコーンオイルに他の成分例えば酸化シリカなどが配合されたシリコーン樹脂などが配合されていても差し支えない。また、シリコーンは化粧品として使用可能なもので、水、アルコール、グリコール類に溶解しない物であれば特に限定されず、例えば、メチルポリシロキサンや高重合メチルポリシロキサン（平均重合度が６５０以上のもの）、デカメチルテトラシロキサン、オクタメチルトリシロキサン、さらにジメチコノールと称されるように、オリガノポリシロキサン類に水酸基などを導入した各種の変性ポリシロキサンを用いても差し支えない。 In the present invention, silicone that is liquid at normal temperature or hydrocarbons that are liquid at normal temperature are used as the oil, and among them, compounds that are not soluble in water, alcohol, or glycols are used. Here, not dissolving in water or the like means that it does not dissolve at an arbitrary ratio at room temperature, and when both are mixed, it may be two phases and may be slightly dissolved. Silicone is a general term for organopolysiloxanes, and what is called silicone oil is preferably used. Moreover, as long as it is disperse | distributed in cosmetics as an oil component, the silicone resin etc. which mix | blended other components, for example, silica oxide etc., may be mix | blended with silicone oil. Silicone can be used as a cosmetic and is not particularly limited as long as it is insoluble in water, alcohol and glycols. For example, methylpolysiloxane or highly polymerized methylpolysiloxane (having an average polymerization degree of 650 or more) ), Decamethyltetrasiloxane, octamethyltrisiloxane, and various modified polysiloxanes in which hydroxyl groups are introduced into origanopolysiloxanes, such as dimethiconol, may be used.
本発明において用いられる炭化水素は、室温で液状のものが用いられる。例えば、スクワラン、流動パラフィン、イソパラフィン、プリスタン、ポリイソブチレン、ポリブテン等が挙げられる。 The hydrocarbon used in the present invention is liquid at room temperature. For example, squalane, liquid paraffin, isoparaffin, pristane, polyisobutylene, polybutene and the like can be mentioned.
上記油分は化粧料中に１０〜３０質量％配合される。１０質量％未満であれば適度な整髪性が得られず、３０質量％を超えて配合すると、べたつく傾向が出てヘアトニックとしての機能が失われる虞が高くなる。また、油分としてシリコーンを単独で用いても良いが、粘度の異なる２種以上のシリコーン、例えば、粘度の低いメチルポリシロキサン、例えば２５℃における粘度２０ｍｍ２／Ｓのメチルポリシロキサンと、高粘度のメチルポリシロキサン、例えば２５℃における粘度５０００ｍｍ２／Ｓのメチルポリシロキサンを混合して用いるのが好ましい。さらに、より適度な整髪力を得るためには、シリコーンと炭化水素の両者を併用するのがよい。 10-30 mass% of said oil is mix | blended in cosmetics. If it is less than 10% by mass, an appropriate hair styling property cannot be obtained, and if it exceeds 30% by mass, there is a tendency to become sticky and the function as a hair tonic is lost. Silicone may be used alone as an oil component, but two or more types of silicones having different viscosities, for example, methylpolysiloxane having a low viscosity, for example, a methylpolysiloxane having a viscosity of 20 mm 2 / S at 25 ° C., and a high viscosity It is preferable to use a mixture of methylpolysiloxane, for example, methylpolysiloxane having a viscosity of 5000 mm 2 / S at 25 ° C. Furthermore, in order to obtain more appropriate hair styling power, it is preferable to use both silicone and hydrocarbon in combination.
本発明においては界面活性剤として非イオン界面活性剤が用いられる。非イオン界面活性剤も特に限定されるものではなく、例えば、ポリグリセリン脂肪酸エステル、或いはポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンラウリルエーテル、ポリオキシエチレンセチルエーテル、ポリオキシエチレンステアリルエーテルなどのポリオキシエチレンのアルキルエーテル類が例示される。この中でも使用感からポリグリセリン脂肪酸エステル又はポリオキシエチレン硬化ヒマシ油が好ましい。 In the present invention, a nonionic surfactant is used as the surfactant. The nonionic surfactant is not particularly limited, and examples thereof include polyoxyglycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, and other polyoxyethylene fatty acid esters. Examples include ethylene alkyl ethers. Among these, polyglycerin fatty acid ester or polyoxyethylene hydrogenated castor oil is preferable from the viewpoint of use.
界面活性剤の配合量は化粧料中に０．１〜０．５質量％である。本発明においては油分を比較的大きい粒子径の液滴状態で安定に分散できればよく、０．５質量％を超えて配合した場合には乳化状態となり、べたつきが生じる。０．１質量％より少ない場合は油滴粒子が合一し、安定性が保たれず油分が分離される。 The compounding quantity of surfactant is 0.1-0.5 mass% in cosmetics. In the present invention, it suffices if the oil can be stably dispersed in the form of droplets having a relatively large particle diameter. When the oil content exceeds 0.5% by mass, it becomes emulsified and stickiness occurs. When the amount is less than 0.1% by mass, the oil droplet particles coalesce and stability is not maintained and the oil component is separated.
本発明においては界面活性剤と同様に、カルボキシビニルポリマーが油分を化粧料中に安定に分散させる。カルボキシビニルポリマーは０．５％以下では被膜形性能を有さず、油滴の分散性を維持するのに貢献する。その配合量は０．０１〜０．５質量％、好ましくは０．１〜０．３質量％である。０．５質量％を超えて配合すると油滴の分散性、言い換えると分散した油滴の安定性がよくなるが、べたつき感が大きくなり、また、頭皮へ化粧料が充分に届かない虞が強くなる。そして化粧料の使用性や使用感が低下する懸念がある。一方、０．０１質量％よりも少ないと、油滴の安定性が得られないことがある。 In the present invention, like the surfactant, the carboxyvinyl polymer stably disperses the oil in the cosmetic. Carboxyvinyl polymer has no film-form performance at 0.5% or less, and contributes to maintaining the dispersibility of oil droplets. The blending amount is 0.01 to 0.5% by mass, preferably 0.1 to 0.3% by mass. When the amount exceeds 0.5% by mass, the dispersibility of the oil droplets, in other words, the stability of the dispersed oil droplets is improved, but the feeling of stickiness is increased, and there is a strong possibility that the cosmetic does not reach the scalp sufficiently. . And there is a concern that the usability and the feeling of use of the cosmetics are lowered. On the other hand, if it is less than 0.01% by mass, the stability of the oil droplets may not be obtained.
本発明においては、必要に応じてキサンタンガム及び／又はシロキクラゲ抽出物を更に含む場合がある。これらの成分も皮膜形成性がなく、油滴の分散性を維持するのに貢献するが、カルボキシビニルポリマーが存在しないと油滴の安定性に貢献しない。一方、カルボキシビニルポリマーとキサンタンガムやシロキクラゲ抽出物の配合量が多いとベタツキ感が高まり、頭皮へ化粧料が十分に届かなくなる虞が強くなる。すなわち、本発明においては、カルボキシビニルポリマーの一部をキサンタンガムやシロキクラゲ抽出物に置き換えることができる。従って、キサンタンガムやシロキクラゲ抽出物は、それらの配合量とカルボキシビニルポリマーの配合量の合計が化粧料中に０．５質量％を超えないように配合される。 In this invention, a xanthan gum and / or a white jellyfish extract may be further included as needed. These components also have no film-forming property and contribute to maintaining the dispersibility of the oil droplets, but do not contribute to the stability of the oil droplets if no carboxyvinyl polymer is present. On the other hand, if the amount of the carboxyvinyl polymer, xanthan gum or white jellyfish extract is large, the sticky feeling is increased, and there is a strong possibility that the cosmetic will not reach the scalp sufficiently. That is, in the present invention, a part of the carboxyvinyl polymer can be replaced with xanthan gum or a white jellyfish extract. Therefore, xanthan gum and white jellyfish extract are blended so that the total of their blending amount and the carboxyvinyl polymer blending amount does not exceed 0.5 mass% in the cosmetic.
シロキクラゲの抽出物は例えば特開２００８−１３４７０号公報にも開示されているように多糖類を多く含む。本発明において用いられるシロキクラゲは、シロキクラゲ科に属するキノコの総称をいい、本発明ではシロキクラゲ科シロキクラゲ（学名：Ｔｒｅｍｅｌｌａ ｆｕｃｉｆｏｒｍｉｓ Ｂ．）に限らず、ハナビラニカワタケ（Ｔｒｅｍｅｌｌａ ｆｏｌｉａｃｅａ Ｆｒ．）、及びコガネニカワタケ（Ｔｒｅｍｅｌｌａ ｍｅｓｅｎｔｅｒｉｃａ Ｒｅｔｚ．Ｆｒ．）などが用いられる。シロキクラゲは、その菌体だけでなく子実体も利用できる。 The extract of white jellyfish contains a lot of polysaccharides as disclosed in, for example, Japanese Patent Application Laid-Open No. 2008-13470. The white jellyfish used in the present invention is a generic name for mushrooms belonging to the family Asteraceae, and in the present invention, it is not limited to the white jellyfish (Sterrel jellyfish) (scientific name: Tremella fuciformis B.), and (Tremella mesenterica Retz. Fr.) and the like are used. As for the white jellyfish, not only the fungus body but also the fruiting body can be used.
抽出溶媒としては、水、メタノールやエタノールなど炭素数１〜４の低級アルコール、１，３−ブチレングリコールやプロピレングリコール等の多価アルコール、ヘキサンやペンタン等の炭化水素、アセトンやメチルエチルケトン等のケトン類、エチルエーテルやプロピルエーテル、テトラヒドロフラン等のケトン類、アセトニトリル等が例示される。これらの溶媒は単独で用いても２種以上を混合して用いてもよい。これらの中でも、多糖類を抽出できる溶媒が好適であり、好ましくは、水又は水と任意の割合で混合可能な溶媒、例えば、エタノールや１，３−ブチレングリコールとの混液を用いるのがよい。 Extraction solvents include water, lower alcohols having 1 to 4 carbon atoms such as methanol and ethanol, polyhydric alcohols such as 1,3-butylene glycol and propylene glycol, hydrocarbons such as hexane and pentane, and ketones such as acetone and methyl ethyl ketone. And ketones such as ethyl ether, propyl ether and tetrahydrofuran, acetonitrile and the like. These solvents may be used alone or in combination of two or more. Among these, a solvent capable of extracting a polysaccharide is preferable, and water or a solvent that can be mixed with water at an arbitrary ratio, for example, ethanol or 1,3-butylene glycol is preferably used.
抽出法は特に限定されるものではなく、例えば抽出溶媒と菌体を混合して加温抽出した後、菌体を除去する方法が例示される。得られた抽出物はそのまま用いられるか、適宜濃縮したものや噴霧乾燥や凍結乾燥などによって粉末状に乾燥したものを用いることもできる。また、必要に応じて、活性炭による脱色や液液抽出などによる夾雑物の除去などを行っても差し支えない。また、多糖体として精製された市販のシロキクラゲ多糖体（例えば商品名「Blancveil-TP」日本精化株式会社製）を用いてもよい。 The extraction method is not particularly limited, and for example, a method of removing the bacterial cells after mixing the extraction solvent and the bacterial cells and performing warm extraction is exemplified. The obtained extract can be used as it is, or can be appropriately concentrated, or dried in a powder form by spray drying or freeze drying. If necessary, it is possible to remove impurities by decolorization with activated carbon or liquid-liquid extraction. Alternatively, a commercially available white jellyfish polysaccharide purified as a polysaccharide (for example, “Blancveil-TP” manufactured by Nippon Seika Co., Ltd.) may be used.
本発明の頭皮頭髪用化粧料は油分を水−アルコール系の溶液中に分散させたものであり、配合成分のうち水溶性の成分を水に溶解した水溶液と、配合成分のうち油溶性の成分を油に溶解した油相とを混合・攪拌することにより得られる。本発明の化粧料は、乳化物とは異なり油滴を分散させた製剤である。この製剤を得るには、ホモジェネータを用いて油滴を分散させてもよいし、より撹拌力の弱い方法、例えば、５０〜１０００ｒｐｍ、好ましくは５０〜５００ｒｐｍ程度の回転速度で、数分から１０分間程度、油滴が均一に分散するように攪拌して分散させても良い。ホモジェネーターを用いる場合には、乳化物を得る場合と同様な攪拌条件、例えば、１５００ｒｐｍ〜４５００ｒｐｍ程度の回転速度で攪拌するのがよく、この場合にはより粒子径が揃った均一で好ましい分散状態となる。 The scalp scalp hair cosmetic of the present invention is obtained by dispersing an oil in a water-alcohol solution, an aqueous solution in which a water-soluble component is dissolved in water, and an oil-soluble component in the formulation components. It is obtained by mixing and stirring an oil phase dissolved in oil. Unlike the emulsion, the cosmetic of the present invention is a preparation in which oil droplets are dispersed. In order to obtain this preparation, oil droplets may be dispersed using a homogenator, or a method with a weaker stirring force, for example, about 50 to 1000 rpm, preferably about 50 to 500 rpm, and about several minutes to 10 minutes. The oil droplets may be dispersed by stirring so that the oil droplets are uniformly dispersed. When using a homogenator, it is better to stir under the same stirring conditions as in the case of obtaining an emulsion, for example, at a rotational speed of about 1500 rpm to 4500 rpm. In this case, a uniform and preferable dispersion with more uniform particle diameters. It becomes a state.
本発明の化粧料における油分の粒子径は３０〜１５００μｍである。なお、この粒子径は実施例に記載の方法により測定される粒子径である。本発明の化粧料は界面活性剤の配合量が油分の配合量に対して相対的に少ないので、ミセルを形成できず、粒子径が数μｍ〜１０μｍ程度となる安定な化粧料は得られない。また、１５００μｍを超える場合には油滴が合一して均一な油滴とならず、油分として分離する傾向にある。 The particle size of the oil in the cosmetic of the present invention is 30 to 1500 μm. In addition, this particle diameter is a particle diameter measured by the method as described in an Example. Since the cosmetic of the present invention has a relatively small amount of surfactant relative to the amount of oil, micelles cannot be formed, and a stable cosmetic with a particle size of about several μm to 10 μm cannot be obtained. . On the other hand, when it exceeds 1500 μm, the oil droplets are united to form a uniform oil droplet, but tend to be separated as an oil component.
本発明においては、上記の必須成分以外に清涼剤や鎮痒剤、抗炎症剤、育毛促進成分等、ヘアトニックや育毛剤として頭皮に直接適用されることを目的とする化粧料に配合されうる有効成分を配合できる。用いられうる清涼剤や鎮痒剤として、ｌ−メントールやｄｌ−メントール、トウガラシチンキが例示される。また抗炎症剤として、グアイアズレン、グリチルリチン酸、グリチルレチン酸などが例示される。育毛促進成分として、センブリエキスやビタミンＥ群、エストラジオールなどの抗男性ホルモンが例示され、毛包刺激作用を有するヒノキチオールやプラセンタエキスなども配合されうる。なお、例えばトウガラシチンキなどのようにその組成中にエタノールを含む場合には、当該成分中のアルコールを含めて化粧料中のアルコールの配合量として３０〜５０質量％に調整される。また、油滴分散型の剤型が担保される限りにおいて、防腐剤や着色剤など補助的に用いられる成分も配合されうる。 In the present invention, in addition to the essential components described above, a refreshing agent, an antipruritic agent, an anti-inflammatory agent, a hair growth-promoting component, etc., which can be incorporated into cosmetics intended to be applied directly to the scalp as a hair tonic or hair growth agent Ingredients can be blended. Examples of the refreshing agent or antipruritic agent that can be used include l-menthol, dl-menthol, and chili tincture. Examples of anti-inflammatory agents include guaiazulene, glycyrrhizic acid, glycyrrhetinic acid and the like. Examples of hair-growth-promoting components include assembly extract, vitamin E group, and anti-androgen such as estradiol, and hinokitiol, placenta extract, and the like having hair follicle stimulating action can also be blended. In addition, when ethanol is included in the composition, such as chili pepper tincture, for example, the amount of alcohol in the cosmetic is adjusted to 30 to 50% by mass including the alcohol in the component. In addition, auxiliary components such as preservatives and coloring agents may be blended as long as the oil droplet dispersion type dosage form is secured.
さらに、必要に応じて、水酸化カリウムや水酸化ナトリウム、エタノールアミン、イプシロンアミノカプロン酸、塩酸やリン酸など、中和するに必要な量の酸やアルカリを中和剤として配合できる。これらの酸は有機酸、無機酸いずれであっても差し支えない。また、好ましくは化粧料のｐＨは６．０〜８．０の範囲に調整される。 Furthermore, if necessary, an amount of acid or alkali necessary for neutralization such as potassium hydroxide, sodium hydroxide, ethanolamine, epsilon aminocaproic acid, hydrochloric acid or phosphoric acid can be blended as a neutralizing agent. These acids can be either organic acids or inorganic acids. Further, the pH of the cosmetic is preferably adjusted to a range of 6.0 to 8.0.
こうして得られた頭皮頭髪用化粧料は、比較的多量のエタノールや油分を含み、整髪成分となる樹脂成分やワックス、皮膜形成を行うだけの十分な量の被膜形成性の水溶性高分子を含んでいない。そのために、頭皮まで充分にエタノールや水が行き渡るとともに油分が頭髪表面に保持される。その結果、頭皮においてさっぱりとした清涼感が得られる一方で、頭髪に対してべたつかずすっきりとした整髪力が得られる。すなわち、本発明の頭皮頭髪化粧料は１剤でありながら、ヘアトニック様の頭皮用化粧料の効果とヘアリキッド様の頭髪用化粧料の効果という２剤の効果を同時に発揮する。 The scalp and hair cosmetic composition thus obtained contains a relatively large amount of ethanol and oil, and contains a resin component and a wax as a hair-styling component, and a film-forming water-soluble polymer in an amount sufficient to form a film. Not. For this reason, ethanol and water are sufficiently distributed to the scalp and oil is retained on the hair surface. As a result, a refreshing refreshing feeling can be obtained in the scalp, while a clean hair-styling power can be obtained without being sticky to the hair. That is, while the scalp hair cosmetic of the present invention is a single agent, it simultaneously exhibits the effects of two agents, the effect of a hair tonic-like scalp cosmetic and the effect of a hair liquid-like hair cosmetic.
次に下記の実施例に基づき、本発明についてさらに説明する。なお、本発明は下記の実施例に限られないのは言うまでもない。 Next, the present invention will be further described based on the following examples. Needless to say, the present invention is not limited to the following embodiments.
表１及び表２に示す成分表に従い、各種の化粧料を製造した。製造方法は次のとおりである。成分１２の一部に成分１〜５を溶解した水相に、予め成分６〜９を溶解したものを加えて溶解する。これに成分１０〜１２を溶解した水相を加え、更に成分１３〜１８の油分を加え、均一になるまで攪拌分散させる。この操作は室温で行った。また、表に示す成分中、ジメチコン・ジメチコノール混合物は、ジメチルポリシロキサンとジメチルポリシロキサンに水酸基を導入した化合物との混合物であって、商品名ＡＢＩＬ ＯＳＷ５（エボニックデグサジャパン社製）である。また、カルボキシビニルポリマーは分子量１００万〜３００万の商品名ハイビスワコー１０４（和光純薬工業株式会社製）である。 Various cosmetics were produced according to the ingredient tables shown in Tables 1 and 2. The manufacturing method is as follows. To a water phase in which components 1 to 5 are dissolved in a part of component 12, a solution in which components 6 to 9 are dissolved in advance is added and dissolved. To this, an aqueous phase in which components 10 to 12 are dissolved is added, and oil components 13 to 18 are further added and stirred and dispersed until uniform. This operation was performed at room temperature. Among the components shown in the table, the dimethicone / dimethiconol mixture is a mixture of dimethylpolysiloxane and a compound obtained by introducing a hydroxyl group into dimethylpolysiloxane, and is trade name ABIL OSW5 (Evonik Degussa Japan). The carboxyvinyl polymer is trade name Hibiswako 104 (manufactured by Wako Pure Chemical Industries, Ltd.) having a molecular weight of 1,000,000 to 3,000,000.
次に得られた化粧料について、目視による外観状態、頭部に使用した際のべたつき感（使用感）、安定性として室温で６０日放置した後の目視による外観状態、頭髪のセット効果（整髪効果）、頭皮におけるかゆみ止め効果について、下記の評価基準に従って評価した。また、粒子径は実体顕微鏡（キーエンス社製 デジタルマイクロスコープ ＶＨＸ−５００）観察により測定した。少量の化粧料をスライドグラス上に取り、２００倍の拡大率で観察した。視野内の油滴を、測定ソフトにより最大から最小粒子径までを測定した。その操作を３回繰り返し、その粒子径の最大範囲を、当該化粧料における油滴の粒子径範囲（μｍ）とした。それらの結果を表１、表２に示す。 Next, with regard to the obtained cosmetics, visual appearance, stickiness when used on the head (feeling of use), visual appearance after standing at room temperature for 60 days as a stability, hair setting effect (hairdressing) Effect), the anti-itch effect on the scalp was evaluated according to the following evaluation criteria. The particle diameter was measured by observation with a stereomicroscope (Digital Microscope VHX-500 manufactured by Keyence Corporation). A small amount of cosmetic was taken on a slide glass and observed at 200 times magnification. The oil droplets in the field of view were measured from the maximum to the minimum particle size using measurement software. The operation was repeated three times, and the maximum range of the particle size was defined as the particle size range (μm) of the oil droplets in the cosmetic. The results are shown in Tables 1 and 2.
〈評価基準〉
（外観）
○：油滴が均一に分散されていた
×：分散が不要又は油滴分散状態にならない、あるいは乳化状態であった
（使用感）
◎：べたつかない
○：ややべたつかない
△：ややべたつく
×：べたつく
（安定性）
○：分離せずに分散状態が保たれていた
×：分離して油層が見られた
（セット効果）
◎：非常に良い
○：良い
△：やや悪い
×：悪い
（かゆみ止め効果）
◎：非常に良い
○：良い
△：やや悪い
×：悪い
<Evaluation criteria>
(appearance)
○: Oil droplets were uniformly dispersed ×: Dispersion was unnecessary or oil droplets were not dispersed or emulsified (usability)
◎: Not sticky ○: Slightly non-sticky △: Slightly sticky ×: Sticky (stability)
○: Dispersed state was maintained without separation ×: Oil layer was seen after separation (set effect)
◎: Very good ○: Good △: Somewhat bad ×: Bad (Itching prevention effect)
◎: Very good ○: Good △: Somewhat bad ×: Bad
表１から分かるように本発明の化粧料によれば、べたつきもなく良好な整髪性と、頭皮に直接作用して良好なかゆみ止め効果が同時に得られた。また、製剤的にも安定な油滴分散系のものが得られた。 As can be seen from Table 1, according to the cosmetics of the present invention, good hair styling without stickiness and a good itching prevention effect by directly acting on the scalp were obtained at the same time. In addition, an oil droplet dispersion system that was stable in terms of formulation was also obtained.
一方、比較例の化粧料においては、エタノールが３０％未満の化粧料（比較例１）では必要とする３０％近くの油分になると乳化状態となり、べたついて使用感が悪いものとなった。エタノールが５０％を越えた化粧料（比較例２）では安定性に欠けるものとなった。油分やエタノールが少なくなると、良好な分散状態にならず使用感も欠けるものとなる（比較例８、９）。そして、油分が３０％を越えると、整髪効果が高まるが使用感等に欠ける結果となる（比較例７）。エタノールと油分が好ましい範囲であっても、界面活性剤が多いと乳化状態となり、べたついてしまい使用感に欠けたりすることがある（比較例３）。一方、界面活性剤が０．１質量％より少ない場合には均一性に欠け、安定性も悪いものとなった（比較例４）。また、増粘剤の配合量が適当でなければ、この場合にも良好な分散性が得られない（比較例５、６）という結果になった。 On the other hand, in the cosmetics of the comparative examples, the cosmetics with less than 30% ethanol (Comparative Example 1) became emulsified when the required oil content was close to 30%, resulting in stickiness and poor usability. The cosmetic (Comparative Example 2) in which ethanol exceeded 50% lacked stability. When the amount of oil or ethanol is reduced, the dispersion state is not good and the feeling of use is lacking (Comparative Examples 8 and 9). When the oil content exceeds 30%, the hair styling effect is enhanced, but the feeling of use is lacking (Comparative Example 7). Even if ethanol and oil content are in the preferred range, if there is a large amount of surfactant, the emulsion becomes emulsified and may become sticky and lack a feeling of use (Comparative Example 3). On the other hand, when the surfactant was less than 0.1% by mass, the uniformity was poor and the stability was poor (Comparative Example 4). In addition, if the blending amount of the thickener was not appropriate, good dispersibility could not be obtained in this case (Comparative Examples 5 and 6).
以上のように、本発明の化粧料は油滴分散性もよく、ヘアトニックの効果であるかゆみ止め効果とヘアリキッドなどの効果である整髪効果の双方の効果を良好に発揮することが確認された。 As described above, the cosmetics of the present invention have good oil droplet dispersibility, and it has been confirmed that both the anti-itch effect that is a hair tonic effect and the hair styling effect that is an effect such as a hair liquid are exhibited well. It was.
Claims (5)
１０〜３０質量％の室温で液状であるシリコーン及び室温で液状である炭化水素からなる群から選ばれる１種又は２種以上の化合物、
０．１〜０．５質量％の非イオン界面活性剤、
０．０１〜０．５質量％のカルボキシビニルポリマー、
２０〜５０質量％の水を含む油滴分散型の頭皮頭髪用化粧料。 30-50 mass% ethanol,
1 or 2 or more compounds selected from the group consisting of 10 to 30% by mass of a silicone that is liquid at room temperature and a hydrocarbon that is liquid at room temperature,
0.1 to 0.5% by weight of a nonionic surfactant,
0.01 to 0.5% by weight of carboxyvinyl polymer,
An oil droplet-dispersed cosmetic for scalp and hair containing 20 to 50% by mass of water.
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| JP5464818B2 JP5464818B2 (en) | 2014-04-09 |
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Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62263111A (en) * | 1986-05-09 | 1987-11-16 | Shiseido Co Ltd | Viscous composition |
| JPH01250305A (en) * | 1987-12-22 | 1989-10-05 | Kobayashi Kose Co Ltd | Composition for cosmetic |
| JPH10218739A (en) * | 1997-01-31 | 1998-08-18 | Shiseido Co Ltd | Hair cosmetic |
| JP2000191450A (en) * | 1998-12-25 | 2000-07-11 | Lion Corp | Hair cosmetic |
| JP2002327019A (en) * | 2001-03-02 | 2002-11-15 | Shiseido Co Ltd | Aqueous polymer emulsion and cosmetic using the same |
| JP2004091354A (en) * | 2002-08-30 | 2004-03-25 | Kanebo Ltd | Hair tonic |
| JP2005089366A (en) * | 2003-09-17 | 2005-04-07 | Shiseido Co Ltd | Emulsified composition for hair |
| JP2005132782A (en) * | 2003-10-31 | 2005-05-26 | Shiseido Co Ltd | Composition for scalp and hair |
| JP2005247783A (en) * | 2004-03-05 | 2005-09-15 | Isp Japan Kk | Hair-styling wax or hair-setting gel composition containing polyasparatic acid derivative |
| JP2005330257A (en) * | 2004-04-19 | 2005-12-02 | Nippon Fine Chem Co Ltd | Cosmetic |
| JP2007015951A (en) * | 2005-07-06 | 2007-01-25 | Kanebo Home Products Kk | Hair cosmetic |
| JP2007238569A (en) * | 2006-03-10 | 2007-09-20 | Kanebo Cosmetics Inc | Hair cosmetic |
| JP2008001628A (en) * | 2006-06-22 | 2008-01-10 | Ichimaru Pharcos Co Ltd | Hair cosmetic |
-
2008
- 2008-04-18 JP JP2008109116A patent/JP5464818B2/en not_active Expired - Fee Related
Patent Citations (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62263111A (en) * | 1986-05-09 | 1987-11-16 | Shiseido Co Ltd | Viscous composition |
| JPH01250305A (en) * | 1987-12-22 | 1989-10-05 | Kobayashi Kose Co Ltd | Composition for cosmetic |
| JPH10218739A (en) * | 1997-01-31 | 1998-08-18 | Shiseido Co Ltd | Hair cosmetic |
| JP2000191450A (en) * | 1998-12-25 | 2000-07-11 | Lion Corp | Hair cosmetic |
| JP2002327019A (en) * | 2001-03-02 | 2002-11-15 | Shiseido Co Ltd | Aqueous polymer emulsion and cosmetic using the same |
| JP2004091354A (en) * | 2002-08-30 | 2004-03-25 | Kanebo Ltd | Hair tonic |
| JP2005089366A (en) * | 2003-09-17 | 2005-04-07 | Shiseido Co Ltd | Emulsified composition for hair |
| JP2005132782A (en) * | 2003-10-31 | 2005-05-26 | Shiseido Co Ltd | Composition for scalp and hair |
| JP2005247783A (en) * | 2004-03-05 | 2005-09-15 | Isp Japan Kk | Hair-styling wax or hair-setting gel composition containing polyasparatic acid derivative |
| JP2005330257A (en) * | 2004-04-19 | 2005-12-02 | Nippon Fine Chem Co Ltd | Cosmetic |
| JP2007015951A (en) * | 2005-07-06 | 2007-01-25 | Kanebo Home Products Kk | Hair cosmetic |
| JP2007238569A (en) * | 2006-03-10 | 2007-09-20 | Kanebo Cosmetics Inc | Hair cosmetic |
| JP2008001628A (en) * | 2006-06-22 | 2008-01-10 | Ichimaru Pharcos Co Ltd | Hair cosmetic |
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