JP2009195991A - Member for producing casting - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a member for producing castings which is less liable to thermal shrinkage due to thermal decomposition, and easy to handle. <P>SOLUTION: Disclosed is a member for producing castings which is prepared by forming a base paper for a paper-jointing tube into a tubular shape and includes an organic fiber, an inorganic fiber, and a binder. The base paper for a paper-jointing tube is preferably formed into a tubular shape through winding. The contents of the organic fiber, the inorganic fiber and the binder are preferably 10 to 70 parts by weight, 1 to 80 parts by weight and 10 to 85 parts by weight, respectively. The organic fiber is preferably a pulp fiber. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to a casting manufacturing part in which a paper tube base paper is formed into a tubular shape, a manufacturing method thereof, and a casting manufacturing method using the same.

  In the manufacture of castings, in general, a casting mold having a cavity (core if necessary) is formed from casting sand, and a receiving port, a gate, a runner and a weir (hereinafter referred to as a pouring system) for supplying molten metal to the cavity. Also called degassing, hot water, and frying. Such pouring systems, degassing, hot water, and frying are usually formed integrally with casting molds with casting sand, or the pouring system is made of pouring components made of refractory materials such as ceramics and bricks. Or formed.

  When the above-described pouring system or the like is formed integrally with a mold, it is difficult to make the pouring system arrangement complicated, and casting sand is likely to be mixed into the molten metal. On the other hand, when a pouring system or the like made of the refractory material is used, the temperature of the molten metal tends to decrease when the molten metal comes into contact with the pouring system or the like. In addition, when forming a pouring system or the like, the refractory material must be cut with a high speed cutter such as a diamond cutter, and the cut refractory material must be wound with tape to connect them, which is troublesome. It was. Moreover, after pouring, there is a problem that a pouring system or the like is damaged by a thermal shock or the like, and a large amount of industrial waste is generated, which takes time and labor. Thus, the pouring system made of a refractory material was generally inconvenient to handle.

  As a technique for solving such a problem, for example, a technique described in Patent Document 1 is known. This technique uses a heat insulating material formed from a slurry in which organic or inorganic fibers and an organic or inorganic binder are mixed, instead of using a refractory material for the pouring component.

  However, there has been a problem that a pouring system or the like in which organic fibers and an organic binder are combined contracts greatly due to thermal decomposition when the molten metal is supplied, and the molten metal leaks from the pouring system or the like. In addition, since the heat insulating material combining inorganic fibers and an inorganic binder is difficult to be molded into a three-dimensional form such as a hollow shape, a pouring system corresponding to various cavity shapes using this heat insulating material is used. Could not be formed.

  On the other hand, cast paper cores are known in which inorganic powder and / or inorganic fibers are mixed with cellulose fibers to reduce the amount of cellulose fibers used. The casting paper core has reduced shrinkage during drying, suppresses the generation of gas and tar-like polymer compounds derived from cellulose fibers during casting, and as a result, casting defects are prevented and casting workability is improved. (For example, see Patent Document 2 below).

  However, since the casting paper core described in Patent Document 2 does not contain a binder, it is not suitable for a pouring system corresponding to various cavity shapes.

Japanese Utility Model Publication No. 1-60742 Japanese Patent Laid-Open No. 9-253792

  The present invention has been made in view of the above-described problems, and an object of the present invention is to provide a pouring system that can suppress thermal shrinkage due to thermal decomposition, has excellent handling properties, and is compatible with various cavity shapes. It is another object of the present invention to provide a casting manufacturing part capable of forming a casting, a manufacturing method thereof, and a casting manufacturing method using the same.

  The present invention achieves the above-mentioned object by providing a casting manufacturing part in which a paper tube base paper is formed into a tubular shape, and including a casting manufacturing part containing organic fibers, inorganic fibers, and a binder.

  The present invention also provides a casting production method using a casting production part containing organic fibers, inorganic fibers and a binder, wherein the casting production part is arranged in foundry sand. Is.

  Further, the present invention is a method for producing a casting production part according to the present invention, wherein the paper tube base paper is made from a raw slurry containing at least the organic fiber and the inorganic fiber, and the paper tube is made. The present invention provides a method for producing a casting production part, comprising a step of forming a paper tube from a base paper and a step of including the binder in the formed paper tube.

  ADVANTAGE OF THE INVENTION According to this invention, the part for casting manufacture which can suppress the thermal contraction accompanying thermal decomposition and is excellent in the handleability, its manufacturing method, and the manufacturing method of a casting using this casting manufacture part are provided.

It is a figure which shows typically one Embodiment which applied the component for casting manufacture of this invention to the runner for gates. It is a perspective view which shows typically the state which has arrange | positioned the runner of the embodiment with other casting manufacture components, such as a casting_mold | template.

  Hereinafter, the present invention will be described based on preferred embodiments thereof.

  The casting production part of the present invention is a casting production part obtained by forming a paper tube base paper into a tubular shape, and contains organic fibers, inorganic fibers, and a binder. The casting production part of the present invention is preferably formed by winding a paper tube base paper. When winding, a part of the paper tube base paper may or may not overlap. Further, a plurality of the paper tube base papers may be rolled up. When producing a long cylindrical casting manufacturing part, it is preferable to spirally roll a strip-shaped paper tube base paper. The casting manufacturing part of the present invention may be formed by rolling, for example, a rectangular paper tube base paper and joining two opposing sides without winding the paper tube base. The thickness of the paper tube base paper is preferably 0.4 to 2 mm, particularly preferably 0.7 to 1.5 mm, considering the strength as a casting production part.

The organic fiber mainly forms the framework of a casting production part, but at the time of casting, part or all of the organic fiber is thermally decomposed by the molten metal, and after the casting is produced, the thermally decomposed part becomes a void.
Examples of the organic fibers include paper fibers, fibrillated synthetic fibers, and regenerated fibers (for example, rayon fibers). These fibers can be used alone or in admixture of two or more. Among these, it is particularly preferable to use paper fiber because it can be obtained easily and stably, the manufacturing cost can be reduced, and sufficient strength can be obtained after dehydration and drying.

  In addition to wood pulp, cotton pulp, linter pulp, bamboo straw and other non-wood pulp can be used for the paper fiber, and virgin pulp or waste paper pulp (collected product) is used alone or in combination of two or more. Can be used. And waste paper pulp is particularly preferable from the viewpoints of availability, stability, environmental protection, and reduction of manufacturing costs.

  Considering the surface smoothness, impact strength, thickness uniformity, etc. of the molded casting production part, the average fiber length of the organic fiber is preferably 0.8 to 2.0 mm, 0.9 to 1.8 mm. Is more preferable.

  From the viewpoint of ease of molding as a casting production part, ensuring strength, reducing gas generation, etc., the content of the organic fiber in the casting production part of the present invention is preferably 10 to 70 parts by weight, and 20 to 60 parts. Part by weight is more preferred. In the present specification, the term “part by weight” means a value relative to a total of 100 parts by weight of organic fiber, inorganic fiber and binder.

  The inorganic fiber, like the organic fiber, mainly forms the framework of the casting production part, but does not decompose or burn even with the heat of the molten metal during casting, and serves to maintain the original shape of the casting production part. .

  Examples of the inorganic fibers include carbon fibers, artificial mineral fibers such as rock wool, ceramic fibers, natural mineral fibers, and the like, and these fibers can be used alone or in admixture of two or more. Of these, carbon fibers that can maintain high strength even at high temperatures are preferably used from the viewpoint of reducing shrinkage associated with carbonization of the organic binder, particularly when an organic binder is used as the binder, thereby reducing manufacturing costs. From this point, it is preferable to use rock wool.

  In consideration of ensuring drainage during papermaking of the paper tube base paper and ease of processing of the paper tube base paper, the average fiber length of the inorganic fiber is preferably 0.2 to 10 mm, and more preferably 0.5 to 8 mm.

  From the viewpoint of securing strength as a casting production part and ease of processing of the paper tube base paper produced, the content of the inorganic fiber is preferably 1 to 80 parts by weight, and more preferably 7 to 40 parts by weight. .

  From the viewpoint of ease of molding as a casting production part, ensuring strength, etc., the ratio of the inorganic fiber to the organic fiber (inorganic fiber content / organic fiber content) is a weight ratio, for example, in the case of carbon fiber. 1-60 are preferable and 2-30 are more preferable. When rock wool is used as the inorganic fiber, the ratio is preferably 10 to 90, and more preferably 20 to 80.

  Examples of the binder include organic binders and inorganic binders as described later. They can be used alone or in combination.

The organic binder serves to bind the organic fiber and the inorganic fiber in the casting production part of the present invention, increases the strength of the casting production part of the present invention, and is carbonized by the heat of the molten metal during casting. Thus, there are those that play the role of maintaining the strength of the casting manufacturing component.
As said organic binder, thermosetting resins, such as a phenol resin, an epoxy resin, and a furan resin, are mentioned. Of these, phenol resins are particularly preferable from the viewpoints that the amount of generated combustible gas is small, combustion is difficult, and the residual carbon ratio after pyrolysis (carbonization) is high. Further, among the phenol resins, a resol type resin that does not require a curing agent and can be impregnated into the casting production component of the present invention is preferable.

The inorganic binder plays a role of binding the organic fiber and the inorganic fiber in the casting production part of the present invention, and has the effect of suppressing combustion gas and flame generation without thermal decomposition even during casting production. There are those that exhibit the effect of preventing carburization during casting production.
Examples of the inorganic binder include compounds containing SiO ₂ as a main component such as colloidal silica, obsidian, mullite, nacre, ethyl silicate, and water glass. Among these, it is particularly preferable to use colloidal silica from the standpoints that it can be used alone and is easy to apply. Further, it is particularly preferable to use obsidian from the viewpoint of preventing carburization. The inorganic binder can be used alone or in admixture of two or more.

  In consideration of securing strength as a part for casting production, ease of molding, and the like, the content of the binder (solid content) is preferably 10 to 85 parts by weight, and more preferably 20 to 80 parts by weight.

When a binder other than obsidian is used as the binder, the content of the binder in the casting production component of the present invention is preferably 10 to 70 parts by weight, and more preferably 20 to 50 parts by weight.
Further, when obsidian is used as the binder, it is preferable to include at least 20 parts by weight in all binders. Only obsidian can be used as the binder.

Two or more binders having different melting points can be used in combination. In particular, a low melting point binder and a high melting point binder are used in combination from the viewpoints of ensuring the shape retention of parts for casting production from room temperature (before casting) to high temperature (during casting) and preventing carburization during casting. Is preferred. In this case, examples of the low melting point binder include clay, water glass, obsidian, and the like, and examples of the high melting point binder include the above-mentioned compounds containing SiO ₂ as a main component, mullite, wollastonite, Al ₂ O _{3 and the} like. Is mentioned.

A paper strength reinforcing material can be added to the casting production part of the present invention. By adding the paper strength reinforcing material, swelling of the paper tube when the paper tube is impregnated with the binder can be reduced.
The addition amount of the paper strength reinforcing material is preferably 1 to 20%, particularly 2 to 10% of the weight of the organic fiber.
Examples of the paper strength reinforcing material include polyvinyl alcohol, carboxymethyl cellulose (CMC), sponge (polyamideamine epichlorohydrin resin), and the like.

  Other components such as a flocculant and a colorant can be further added to the casting production part of the present invention.

  The thickness of the casting production part can be appropriately set according to the place where it is used, but considering the securing of strength as a casting production part, ensuring air permeability, suppressing production costs, etc. The thickness of the portion in contact with the molten metal is preferably 0.2 to 2 mm, and more preferably 0.4 to 1.5 mm.

  In the casting production part, the compressive strength in a state before being used for casting is preferably 10 N or more, and more preferably 30 N or more in terms of securing strength.

  From the viewpoint of suppressing the generation of gas accompanying the thermal decomposition of the organic binder as much as possible, the water content (weight water content) in the state before being used for casting is preferably 10% or less, and more preferably 8% or less. preferable.

Density of the part for casting is secured in strength, light weight, because in terms of such easy processing, 0.5 g / cm ³ or more preferably, 0.6 to 1.2 g / cm ³ is more preferable.

Next, a method for manufacturing the casting manufacturing part will be described.
First, a raw material slurry is prepared by dispersing the organic fiber, the inorganic fiber, and the binder in a predetermined dispersion medium. The binder can be incorporated into the paper tube by impregnation after the paper tube base paper is made and dehydrated and dried, or after the paper tube base paper is further formed into a paper tube. The addition of the binder to the slurry can be omitted.

  Examples of the dispersion medium include water, white water, and solvents such as ethanol and methanol. Among these, water is preferable from the viewpoints of papermaking, dewatering molding stability, quality stability, cost reduction, and ease of handling.

  The amount of the organic fiber used with respect to the dispersion medium in the raw slurry is preferably 0.1 to 3% by weight, considering the surface smoothness and thickness uniformity of the paper tube base paper to be produced, 2% by weight is more preferred.

  Additives such as flocculants and preservatives can be added to the raw material slurry.

Next, a paper tube base paper is made using the raw slurry.
Examples of the papermaking method of the paper for the tube core include, for example, a paper making method using a continuous paper making type circular paper machine, a long paper machine, a short paper machine, a twin wire paper machine, and a batch paper making method. A papermaking method such as a koji method can be employed.

  In order to maintain the shape retention and mechanical strength of the paper tube base paper after papermaking, preferably the moisture content (weight moisture content, the same shall apply hereinafter) is 70% or less, more preferably 60% or less. The paper tube base paper is dehydrated until it becomes. The paper tube base paper after papermaking is dehydrated by, for example, dehydration by suction, dehydration by blowing pressurized air, dehydration by pressing with a pressure roll or pressure plate, etc. be able to.

  The dehydrated base paper body for paper tube is then transferred to a drying step, and a method conventionally used for paper drying can be used for drying.

  Next, the obtained base paper for paper tube is cut to produce a plurality of strips having a predetermined width, and they are spirally wound to obtain a paper tube having a multilayer structure.

The obtained paper tube can be impregnated with a binder partially or entirely as required. Examples of the binder impregnated in the paper tube include resol phenol resin, colloidal silica, ethyl silicate, water glass and the like.
In this way, it is possible to omit the addition of the binder to the raw slurry by impregnating the binder after forming the paper tube.

  Next, the paper tube is heated and dried at a predetermined temperature to complete the manufacture of the paper tube. After the dried paper tube base paper is impregnated with the binder, the paper tube base paper may be processed into a paper tube.

  The casting production component of the present invention can be used, for example, in a runner for a gate such as the embodiment shown in FIG. In FIG. 1, the code | symbol 1 shows the runner for gates.

  Next, the casting manufacturing method of the present invention will be described based on the casting manufacturing method using the gate runner.

  First, as shown in FIG. 2, in addition to the runner 1 for the pouring gate, a runner for a pouring system such as a receiving port 2, a runner (including an elbow pipe (L-shaped pipe)) 3, a weir 4, and a degassing runner 5. Casting production parts comprising a runner 6, 7 for hot water (top and side), a runner 8 for lifting, and a mold 9 having a cavity (not shown) corresponding to the shape of the casting product inside are placed at predetermined positions. Deploy.

  Then, these casting production parts are embedded in foundry sand (not shown), and a molten metal having a predetermined composition is guided into the cavity of the mold 9 through the pouring system. At this time, when the organic binder is contained in the casting production part, the binder is thermally decomposed and carbonized together with the organic fiber by the heat of the molten metal, but the strength as the casting production part is lost. Absent. In addition, since the inorganic fiber suppresses the thermal contraction of the casting production part due to the thermal decomposition, the runners 1 are not cracked and are not flowed by the molten metal. There is no mixing of casting sand with metal. Further, since the organic fibers are thermally decomposed, the runners after the mold is disassembled and the cast product is taken out are easily removed from the mold.

  As the foundry sand, those conventionally used in the production of castings can be used without particular limitation.

  After the casting is finished, the casting is cooled to a predetermined temperature to remove the foundry sand, and the cast product is further blasted. Also, remove unnecessary parts such as the pouring system. Then, post-processing such as trimming is performed as necessary to complete the casting production.

  As described above, according to the casting production part of the present embodiment and the casting production method using the same, the organic fibers are decomposed by the heat of the molten metal to form voids in the casting production part. On the other hand, the strength as a casting production part can be maintained by the inorganic fibers and the binder, and the part can be easily separated and removed after the mold is disassembled. In other words, by using organic fibers, inorganic fibers, and a binder, the casting manufacturing component of the present invention maintains strength as a casting manufacturing component during mold molding and casting, and the strength decreases when the mold is disassembled. Therefore, compared with the conventional casting method using a refractory material as a casting production part, the disposal of the casting production part is easy, and the amount of waste generated can be greatly reduced.

  In addition, since the casting production part of the present invention contains organic fibers, inorganic fibers, and a binder, the amount of flame at the time of casting is reduced as compared with a casting production part made only of organic fibers. Reduced strength of casting parts due to combustion, cracking of casting parts due to thermal shrinkage due to thermal decomposition (carbonization) of organic binder, and prevention of product defects due to mixing of casting sand into molten metal The

  In addition, since the casting production component of the present invention has air permeability, the gas generated during casting can be released to the casting sand side, so that the casting does not form a so-called nest and is defective. Can be prevented.

  In addition, the casting manufacturing component of the present invention is lightweight, and can be easily cut with a simple device, so that it is excellent in handleability.

  The present invention is not limited to the above-described embodiment, and can be changed as appropriate without departing from the spirit of the present invention.

  In addition to the runner 1 for the sprue of the above-described embodiment, the casting manufacturing component of the present invention also includes the runners 2 to 8 for the catch, the runner, the weir, the vent, the hot water, and the lift as shown in FIG. Can be used.

  The casting production method of the present invention can be applied to casting of non-ferrous metals such as aluminum and its alloys, copper and its alloys, nickel, lead and the like in addition to cast iron.

  Hereinafter, the present invention will be described more specifically with reference to examples.

[Example 1]
Using the following raw material slurry, papermaking, dehydration, and drying were performed to obtain a paper tube base paper having a thickness of 1 mm and a basis weight of 440 g / m ² . The following paper tube was produced from the obtained paper tube base paper. The paper tube was impregnated with a binder as described below, dried and heat-cured to obtain a runner for a gate (parts for casting production, weight of about 30 g) having the following physical properties.

<Preparation of raw material slurry>
An organic fiber and an inorganic fiber having the following composition are dispersed in water to prepare a slurry of about 1% (the total weight of the organic fiber and the inorganic fiber is 1% by weight with respect to water). The raw material slurry having a mixing ratio (weight ratio) of organic fiber, inorganic fiber, and binder of the following values was obtained.

[Combination of raw slurry]
Organic fiber: used newspaper, average fiber length is 1 mm, freeness (CSF, the same applies hereinafter) is 150 cc
Inorganic fiber: Carbon fiber (made by Toray Industries, Inc., trade name: “Treka chop”), a fiber with a length of 3 mm is applied to a beater, and a 26: 8 slurry of organic fiber and inorganic fiber in a weight mixing ratio of 300 cc freeness It was adjusted.
Inorganic binder: Obsidian (Kinsei Matec's “Nice catch”)
Organic binder: Epoxy phenol resin (manufactured by Sumitomo Bakelite Co., Ltd.)
Flocculant: Polyacrylamide flocculant (Mitsui Cytec Co., Ltd., A110)
Dispersion medium: water Weight mixing ratio of organic fiber, inorganic fiber, inorganic binder, organic binder = 26: 8: 48: 18

<Conditions for paper tube base paper>
Using the above raw material composition, paper was made at a line speed of 1.5 m / min using an inclined short paper machine to prepare a wet paper sheet.

<Dehydration and drying conditions for base paper for paper tubes>
The obtained paper sheet was sandwiched with felt and dehydrated while sucking the paper sheet. The paper sheet was passed between heating rolls at 120 ° C. at a line speed of 1.5 m / min, and the water content of the paper sheet was 5% by weight. It was as follows.

<Paper tube forming process>
The obtained paper core for paper tube is cut to obtain five strips having widths of 54.4 mm, 54.8 mm, 55.2 mm, 55.6 mm and 56.0 mm, respectively. First, the strip having the smallest width is spirally formed. A paper tube having an inner diameter of about 30 mm and a density of 1.0 g / cm ³ was prepared by winding the other four strips in a spiral manner in order of increasing width. In this case, the strips were joined with an adhesive.

<Dry curing process>
The paper tube was placed in a drying oven at 200 ° C. for about 60 minutes and dried to obtain a runner.

<Physical properties of the runner>
Thickness: 1.0mm

<Manufacture of castings>
The runner obtained in Example 1 was used to construct a pouring system as shown in FIG. 2, and a mold was formed using the pouring system, and the molten metal (1400 ° C.) was injected from the inlet.

<Evaluation of runners after casting production>
No violent flames from blowing back or lifting to the receiving port were observed. Further, when the mold was disassembled after casting, the runner covered the solidified metal cleanly, and the runner could be easily removed by subsequent blasting.

  As described above, it was confirmed that the runner (casting part) obtained in Example 1 can suppress heat shrinkage due to thermal decomposition and is excellent in handleability.

1 Runner for runner 2 Runner for runner 3 Runner for runner 4 Runner for weir 5 Runner for degassing 6, 7 Runner for hot water 8 Runner for lifting 9 Mold

Claims (11)

  A casting production part obtained by forming a paper tube base paper into a tubular shape, which contains organic fibers, inorganic fibers, and a binder.   The casting manufacturing component according to claim 1, wherein the base paper for paper tube is wound and formed into a tubular shape.   The organic fiber content is 10 to 70 parts by weight, the inorganic fiber content is 1 to 80 parts by weight, the binder content is 10 to 85 parts by weight, and the organic fiber, The casting manufacturing component according to claim 1 or 2, wherein the total content of the inorganic fibers and the binder is 100 parts by weight.   The casting manufacturing component according to claim 1, wherein the binder contains two or more binders having different melting points.   The part for casting production according to claim 1, wherein the binder is an organic binder and / or an inorganic binder. The casting manufacturing part according to claim 5, wherein the inorganic binder is a compound containing SiO ₂ as a main component.   The said organic fiber is a paper fiber, The casting manufacturing component in any one of Claims 1-6.   A casting production method using the casting production part according to any one of claims 1 to 7, wherein the casting production part is arranged in casting sand.   A method for producing a casting production part according to any one of claims 1 to 7, wherein the paper tube base paper is made from a raw slurry containing at least the organic fiber and the inorganic fiber, and the paper is made. A method for producing a casting production part, comprising: forming a paper tube from a raw paper for a tube; and incorporating the binder into the formed paper tube.   The method for producing a casting manufacturing part according to claim 9, wherein the binder is an organic binder, and the organic binder is included by impregnation.   The method for producing a casting production part according to claim 10, wherein an inorganic binder is included in the raw slurry.

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