JP2009154350A - Skin material for skin-integrated foam molding - Google Patents

Skin material for skin-integrated foam molding Download PDF

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JP2009154350A
JP2009154350A JP2007333690A JP2007333690A JP2009154350A JP 2009154350 A JP2009154350 A JP 2009154350A JP 2007333690 A JP2007333690 A JP 2007333690A JP 2007333690 A JP2007333690 A JP 2007333690A JP 2009154350 A JP2009154350 A JP 2009154350A
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Prior art keywords
nonwoven fabric
skin
skin material
foam
resin
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JP2007333690A
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JP4955530B2 (en
Inventor
Hidetaka Sato
秀高 佐藤
Katsuhiko Akata
勝彦 赤田
Ikuhisa Shiraishi
育久 白石
Koshin Matsushima
康臣 松島
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Achilles Corp
Kuraray Kuraflex Co Ltd
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Achilles Corp
Kuraray Kuraflex Co Ltd
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Priority to JP2007333690A priority Critical patent/JP4955530B2/en
Priority to CN200880127671.7A priority patent/CN101970227B/en
Priority to PCT/JP2008/073397 priority patent/WO2009081927A1/en
Publication of JP2009154350A publication Critical patent/JP2009154350A/en
Priority to HK11104433.4A priority patent/HK1150439A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B68SADDLERY; UPHOLSTERY
    • B68GMETHODS, EQUIPMENT, OR MACHINES FOR USE IN UPHOLSTERING; UPHOLSTERY NOT OTHERWISE PROVIDED FOR
    • B68G5/00Resilient upholstery pads
    • B68G5/02Resilient upholstery pads of cellular material, e.g. sponge rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/245Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it being a foam layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00Composition of foam
    • B32B2266/02Organic
    • B32B2266/0214Materials belonging to B32B27/00
    • B32B2266/0278Polyurethane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2601/00Upholstery

Abstract

<P>PROBLEM TO BE SOLVED: To provide a skin material that can eject internal gas smoothly from an outer skin while preventing exudation of resin in putting foam resin in a bag-shaped skin material to carry out foam-molding. <P>SOLUTION: The skin material includes a surface material 11, a polyurethane foam bonded to the inside of the surface material 11, and a nonwoven fabric 13 bonded to the inside of the polyurethane foam 12 and having waterproof pressure of 450 mmH<SB>2</SB>O or higher, preferably 500 mmH<SB>2</SB>O or higher, further preferably 550 mmH<SB>2</SB>O or higher, air permeability of 0.1-20 cc/cm<SP>2</SP>/s, preferably 5-15 cc/cm<SP>2</SP>/s, and an average pore size of 0.1-20 μm, preferably 5-15 μm. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

この発明は表皮一体発泡成形用の表皮材に関し、表皮材を立体的に縫製してその内部に液状の発泡樹脂を注入して発泡させ、表皮材と一体とした成形体を得る場合に、液状の発泡樹脂の浸透による染み出しを防止し、しかも気泡を排出して巣穴の発生を防止できる染み出し防止性と通気性を備えたもので、特に車両用のヘッドレストやアームレスト、コンソールボックスなどの成形に使用して好適なものである。   The present invention relates to a skin material for skin-integrated foam molding, in which a skin material is sewed three-dimensionally, and a liquid foamed resin is injected into the interior to foam, thereby obtaining a molded body integrated with the skin material. It prevents bleeding due to the infiltration of foamed resin, and also has anti-bleeding and air permeability that can discharge bubbles and prevent the formation of burrows, especially for vehicle headrests, armrests, console boxes, etc. It is suitable for use in molding.

表皮材を立体的に縫製してその内部に液状の発泡樹脂を注入して発泡させ、表皮材と一体とした成形体を得る表皮一体発泡成形法で作られる製品のひとつに車両用のヘッドレストやアームレストなどがある(特許文献1参照)。
このような表皮一体発泡成形法で車両用のヘッドレストやアームレスト、コンソールボックスを成形する場合に用いる表皮材としては、風合い、伸縮性などの観点から織布、不織布、編布、合成皮革などの表生地の裏面に通常、軟質ポリウレタンフォームを接着することが行なわれるが、立体的に縫製後、液状の発泡樹脂を注入すると、軟質ポリウレタンフォームに浸透し、軟質ポリウレタンフォームが硬化したり、表生地まで浸出して硬化し風合いや外観を悪化させる。
One of the products made by the integral skin foaming method is to sew the skin material three-dimensionally and inject a liquid foamed resin into the interior to foam and obtain a molded body integrated with the skin material. There is an armrest or the like (see Patent Document 1).
As the skin material used when molding vehicle headrests, armrests, and console boxes by such a skin-integrated foam molding method, the surface material such as woven fabric, non-woven fabric, knitted fabric, and synthetic leather is used from the viewpoint of texture and stretchability. Usually, a flexible polyurethane foam is adhered to the back of the fabric, but if a liquid foamed resin is injected after three-dimensional sewing, it penetrates into the flexible polyurethane foam and the flexible polyurethane foam hardens, or even to the surface fabric. It exudes and hardens and deteriorates the texture and appearance.

このため軟質ポリウレタンフォームの裏面にポリウレタンフィルムを接着することで、液状の発泡樹脂の浸透を防止することが行なわれている。
一方、このようなポリウレタンフィルムが接着された表皮材を縫製し、その内部に液状の発泡樹脂を注入すると、発泡の際に生じる気体(ガス)が抜けずに残り、冷えると収縮し巣穴と呼ばれる空洞が発生し、これにより表皮材にしわが生じてしまう。
For this reason, the penetration of liquid foamed resin is prevented by adhering a polyurethane film to the back surface of the flexible polyurethane foam.
On the other hand, when a skin material to which such a polyurethane film is bonded is sewed and a liquid foam resin is injected into the inside, the gas (gas) generated during foaming remains without escaping, and when cooled, it shrinks and shrinks A so-called cavity is generated, which causes wrinkles in the skin material.

そこで、液状の発泡樹脂の浸透を防止すると同時に、気体(ガス)を通過させることができる表皮材が必要とされ、例えば表布とスラブフォームと微小通気孔が形成された遮蔽フィルムとの三層ラミネート表皮材を用いることで、浸透を防止する染み出し防止性と通気性を兼ね備えるようにしている手法がある。(特許文献2参照)。
特開平4−314507号公報 特開平1−228811号公報
Therefore, there is a need for a skin material that can allow gas (gas) to pass through while preventing penetration of the liquid foamed resin. For example, a three-layer structure comprising a top cloth, a slab foam, and a shielding film in which minute ventilation holes are formed. There is a technique in which a laminate skin material is used so as to have both bleeding prevention and air permeability to prevent permeation. (See Patent Document 2).
JP-A-4-314507 Japanese Patent Laid-Open No. 1-228811

ところが、特許文献2に記載の三層ラミネート表皮材では、遮蔽フィルムとしてポリウレタンフィルムや塩化ビニルフィルムが使用されており、これらの合成樹脂フィルムに微小通気孔が形成してあるため注入する発泡樹脂との接触により、耐熱性の問題から孔の大きさが変化しやすく、変化して通気孔が大きくなると発泡樹脂の浸透による染み出しが生じ易く、変化しなくても通気孔が小さすぎると、通気性が不十分で気体(ガス)が抜けないという問題があり、微小通気孔の大きさなどを設定することが難しく、発泡樹脂の注入条件の管理も難しいという問題がある。
また、この表皮材は、合成樹脂製の遮蔽フィルムを備えるため裏面が滑りにくく、ミシンによる縫製がしにくく、ミシンの針が通り難いという問題がある。
However, in the three-layer laminate skin material described in Patent Document 2, a polyurethane film or a vinyl chloride film is used as a shielding film, and since a fine ventilation hole is formed in these synthetic resin films, Due to the heat resistance problem, the size of the hole is likely to change due to heat resistance problems, and if the ventilation hole changes and the ventilation hole becomes large, bleeding due to the infiltration of the foamed resin tends to occur. There is a problem that gas (gas) does not escape due to insufficient properties, there is a problem that it is difficult to set the size of the minute ventilation holes, etc., and it is also difficult to manage the injection conditions of the foamed resin.
In addition, since this skin material is provided with a synthetic resin shielding film, the back surface is difficult to slip, it is difficult to sew with a sewing machine, and the needle of the sewing machine is difficult to pass.

この発明は、かかる従来技術の課題に鑑みてなされたもので、液状の発泡樹脂の浸透による染み出しを防止できる染み出し防止性を有するとともに、発泡の際に発生する気体(ガス)が適度に抜ける通気性を有する表皮一体発泡成形用の表皮材を提供しようとするものである。   The present invention has been made in view of the problems of the prior art, and has an exudation preventing property capable of preventing exudation due to permeation of a liquid foamed resin, and an appropriate amount of gas (gas) generated during foaming. An object of the present invention is to provide a skin material for integral foam molding of the skin having breathability.

上記従来技術の課題を解決するためこの発明の請求項1記載の表皮一体発泡成型用の表皮材は、成形体の外形状に縫製され内部に液状の発泡樹脂を注入して発泡させ一体とする表皮一体発泡成形用の表皮材であって、成形体の外側に配置される表生地と、この表生地の内側に接着されるポリウレタンフォームと、このポリウレタンフォームの内側に接着され染み出し防止性および通気性を有する不織布とからなり、この不織布の前記染み出し防止性が、耐水圧450mmHO以上であるとともに、前記通気性が、通気度0.1〜20cc/cm/sであり、平均ポアサイズが0.1〜20μmであることを特徴とするものである。
この表皮一体発泡成形用の表皮材によれば、表生地とポリウレタンフォームと染み出し防止性および通気性を有する不織布とで表皮材を構成し、不織布の染み出し防止性を、耐水圧で450mmHO以上とし、通気性を、通気度で0.1〜20cc/cm/sとするとともに、平均ポアサイズを0.1〜20μmとすることで、液状の発泡樹脂の浸透による染み出しを防止し、しかも熱による通気性の変化を防止して発泡の際の気体(ガス)の通気性を確保するようにしている。
これにより、通気孔の設定や微小孔の形成工程の必要がなく、発泡樹脂の注入条件も緩和してしわのない製品を成形することができるようになる。
In order to solve the above-mentioned problems of the prior art, the skin material for integral foam molding according to claim 1 of the present invention is sewn into the outer shape of the molded body, and injects a liquid foamed resin into the interior to foam and integrate. A skin material for integral foam molding, comprising a surface fabric disposed on the outside of the molded body, a polyurethane foam adhered to the inside of the surface fabric, and an anti-bleeding property adhered to the inside of the polyurethane foam and It consists of a non-woven fabric having air permeability, and the anti-bleeding property of this non-woven fabric is a water pressure resistance of 450 mmH 2 O or more, and the air permeability is an air permeability of 0.1 to 20 cc / cm 2 / s. The pore size is 0.1 to 20 μm.
According to this skin material for integral foam molding, a skin material is composed of a surface fabric, a polyurethane foam, and a non-woven fabric having bleeding resistance and breathability, and the nonwoven fabric has a bleeding resistance of 450 mmH 2 in water pressure resistance. O and above, and the air permeability is 0.1-20 cc / cm 2 / s in terms of air permeability, and the average pore size is 0.1-20 μm to prevent exudation due to penetration of the liquid foamed resin. In addition, the change in air permeability due to heat is prevented to ensure the air permeability of the gas at the time of foaming.
Accordingly, there is no need for a vent hole setting process or a micro-hole forming process, and the foaming resin injection conditions can be relaxed and a wrinkle-free product can be molded.

また、この発明の請求項2記載の表皮一体発泡成型用の表皮材は、請求項1記載の構成に加え、前記不織布の平均繊維径が、0.1〜10μmであることを特徴とするものである。
この表皮一体発泡成形用の表皮材によれば、不織布の平均繊維径を、0.1〜10μmとすることで、必要なポアサイズなどを容易に確保できるようになる。
Moreover, the skin material for integral foam molding according to claim 2 of the present invention is characterized in that, in addition to the structure of claim 1, the nonwoven fabric has an average fiber diameter of 0.1 to 10 μm. It is.
According to the skin material for integral skin foaming, the required pore size and the like can be easily ensured by setting the average fiber diameter of the nonwoven fabric to 0.1 to 10 μm.

さらに、この発明の請求項3記載の表皮一体発泡成型用の表皮材は、請求項1または2記載の構成に加え、前記不織布の目付が、30〜70g/mであることを特徴とするものである。
この表皮一体発泡成形用の表皮材によれば、不織布の目付を、30〜70g/mとすることで、硬くなったり、成形不良が生じたりしないようにしている。
Furthermore, the skin material for integral foam molding according to claim 3 of the present invention is characterized in that, in addition to the configuration of claim 1 or 2, the basis weight of the nonwoven fabric is 30 to 70 g / m 2. Is.
According to the skin material for integral foam molding of the skin, the basis weight of the nonwoven fabric is set to 30 to 70 g / m 2 so that it does not become hard or does not cause molding defects.

さらに、この発明の請求項4記載の表皮一体発泡成形用の表皮材は、請求項1〜3のいずれかに記載の構成に加え、前記不織布が、メルトブロー製法により得られた不織布であることを特徴とするものである。
この表皮一体発泡成形用の表皮材によれば、メルトブロー製法で不織布を成形することで、柔軟でかつ極細の繊維径の不織布を得ることが容易であり、その結果、表生地の風合いに与える影響を少なく出来る。
Furthermore, in addition to the structure according to any one of claims 1 to 3, the skin material for skin integrated foam molding according to claim 4 of the present invention is that the nonwoven fabric is a nonwoven fabric obtained by a melt blow manufacturing method. It is a feature.
According to this skin material for integral foam molding, it is easy to obtain a nonwoven fabric with a flexible and ultrafine fiber diameter by molding the nonwoven fabric by the melt blow manufacturing method, and as a result, the effect on the texture of the surface fabric Can be reduced.

また、この発明の請求項5記載の表皮一体発泡成形用の表皮材は、請求項1〜4のいずれかに記載の構成に加え、前記不織布が、熱可塑性エラストマー樹脂からなる不織布の単層またはこれに他の樹脂からなる不織布を積層した複数層で構成されることを特徴とするものである。この熱可塑性エラストマーの種類としては特に限定は無いが、スチレン系,オレフィン系,PVC系,ウレタン系,エステル系,アミド系などが上げられる。この内、比較的安価でメルトブロー製法により細繊維径が得られるスチレン系熱可塑性エラストマーが好ましい。
この表皮一体発泡成形用の表皮材によれば、不織布を、熱可塑性エラストマー樹脂からなる不織布の単層またはこれに他の樹脂からなる不織布を積層した複数層で構成することで、必要な耐水性、通気度、ポアサイズを確保して、液状の発泡樹脂の浸透による染み出しを防止し、しかも熱による通気性の変化を抑制して発泡の際の気体(ガス)の通気性に優れる。
In addition to the structure according to any one of claims 1 to 4, the skin material for skin-integrated foam molding according to claim 5 of the present invention is a single layer of a nonwoven fabric comprising a thermoplastic elastomer resin. It is comprised by the multiple layer which laminated | stacked the nonwoven fabric which consists of another resin on this. The type of the thermoplastic elastomer is not particularly limited, and examples thereof include styrene, olefin, PVC, urethane, ester, and amide. Of these, styrene-based thermoplastic elastomers that can be obtained at a relatively low cost and have a fine fiber diameter by a melt blow production method are preferred.
According to the skin material for integral foam molding of the skin, the nonwoven fabric is composed of a single layer of a nonwoven fabric made of a thermoplastic elastomer resin or a plurality of layers obtained by laminating a nonwoven fabric made of another resin on the nonwoven fabric. In addition, air permeability and pore size are ensured to prevent seepage due to penetration of the liquid foamed resin, and the change in air permeability due to heat is suppressed, and the gas (gas) permeability during foaming is excellent.

さらに、この発明の請求項6記載の表皮一体発泡成形用の表皮材は、請求項1〜5のいずれかに記載の構成に加え、前記不織布が熱可塑性エラストマー樹脂からなる不織布の少なくとも一方面または両方面に、ポリブチレンテレフタレート樹脂からなる不織布を設けた2層または3層の積層体で構成されることを特徴とするものである。
この表皮一体発泡成形用の表皮材によれば、液状の発泡樹脂の浸透による染み出しを一層確実に防止するとともに、表面摩擦の小さいポリブチレンテレフタレート樹脂からなる不織布を設けているため縫製の際のミシン送り性にも優れる。
Furthermore, in addition to the structure in any one of Claims 1-5, the skin material for skin integral foam molding of Claim 6 of this invention is at least one surface of the nonwoven fabric in which the said nonwoven fabric consists of thermoplastic elastomer resin, or It is characterized by being constituted by a two-layer or three-layer laminate provided with a nonwoven fabric made of polybutylene terephthalate resin on both sides.
According to the skin material for the integral foam molding of the skin, it is possible to prevent the liquid foam resin from seeping out due to the penetration of the foamed resin, and to provide a non-woven fabric made of polybutylene terephthalate resin with low surface friction. Excellent machine feedability.

この発明の請求項1記載の表皮一体発泡成形用の表皮材によれば、表生地とポリウレタンフォームと染み出し防止性および通気性を有する不織布とで表皮材を構成し、不織布の染み出し防止性を、耐水圧で450mmHO以上とし、通気性を、通気度で0.1〜20cc/cm/sとするとともに、平均ポアサイズを0.1〜20μmとしたので、液状の発泡樹脂の浸透による染み出しを防止し、しかも熱による通気性の変化を防止して発泡の際の気体(ガス)の通気性を確保することができる。
これにより、通気孔の設定や微小孔の形成工程も必要なく、ミシンによる縫製も容易にでき、発泡樹脂の注入条件も緩和してしわのない製品を成形することができる。
According to the skin material for skin-integrated foam molding according to claim 1 of the present invention, the skin material is constituted by the skin material, the polyurethane foam, and the nonwoven fabric having a bleeding prevention property and breathability, and the nonwoven fabric is prevented from bleeding. Is set to 450 mmH 2 O or more with a water pressure resistance, the air permeability is set to 0.1 to 20 cc / cm 2 / s, and the average pore size is set to 0.1 to 20 μm. It is possible to prevent bleeding due to heat and prevent change in air permeability due to heat to ensure gas (gas) air permeability during foaming.
This eliminates the need for setting the air holes and forming the minute holes, making it easy to sew with a sewing machine, and relaxing the conditions for injecting the foamed resin, thereby forming a wrinkle-free product.

また、この発明の請求項2記載の表皮一体発泡成形用の表皮材によれば、不織布の平均繊維径を、0.1〜10μmとしたので、必要なポアサイズを容易に確保することができ、液状の発泡樹脂の浸透による染み出しを防止し、しかも発泡の際の気体(ガス)が適度に抜ける通気性を確保することができる。   Moreover, according to the skin material for skin integral foam molding according to claim 2 of the present invention, since the average fiber diameter of the nonwoven fabric is 0.1 to 10 μm, the necessary pore size can be easily secured, It is possible to prevent seepage due to penetration of the liquid foamed resin, and to ensure air permeability through which gas (gas) during foaming is appropriately discharged.

さらに、この発明の請求項3記載の表皮一体発泡成形用の表皮材によれば、不織布の目付を、30〜70g/mとしたので、硬くなったり、成形不良が生じたりすることを防止でき、液状の発泡樹脂の浸透による染み出しを防止し、しかも発泡の際の気体(ガス)が適度に抜ける通気性を確保することができる。 Furthermore, according to the skin material for integral foam molding according to claim 3 of the present invention, since the basis weight of the nonwoven fabric is 30 to 70 g / m 2 , it is prevented that the nonwoven fabric becomes hard or a molding defect is caused. It is possible to prevent the liquid foamed resin from seeping out due to the permeation, and to ensure the air permeability through which the gas (gas) at the time of foaming escapes appropriately.

さらに、この発明の請求項4記載の表皮一体発泡成形用の表皮材によれば、メルトブロー製法により得られる不織布を使用したので、柔軟でかつ必要な耐水性、通気度、ポアサイズを容易にコントロールすることができ、液状の発泡樹脂の浸透による染み出しを防止し、発泡の際の気体(ガス)が適度に抜ける通気性を確保することができる。   Furthermore, according to the skin material for integral foam molding according to claim 4 of the present invention, since the nonwoven fabric obtained by the melt blow manufacturing method is used, it is flexible and easily controls required water resistance, air permeability, and pore size. It is possible to prevent permeation due to penetration of the liquid foamed resin, and to ensure air permeability through which gas (gas) during foaming can be appropriately discharged.

また、この発明の請求項5記載の表皮一体発泡成形用の表皮材によれば、不織布を、熱可塑性エラストマー樹脂からなる不織布の単層またはこれに他の樹脂からなる不織布を積層した複数層で構成するようにしたので、必要な耐水性、通気度、ポアサイズを確保することができ、液状の発泡樹脂の浸透による染み出しを防止し、発泡の際の気体(ガス)が適度に抜ける通気性を確保することができる。
また、熱可塑性エラストマー樹脂からなる不織布を使用することで、より高い柔軟性を持たせることができる。表皮一体発泡成形用の表皮材は、硬いと表面に折れ皺(角)が出やすくなる為、出来るだけ柔軟な方が良い。この時の熱可塑性エラストマーの目付は不織布全体の目付の50%以上あれば効果がある。
Moreover, according to the skin material for skin integral foam molding according to claim 5 of the present invention, the nonwoven fabric is a single layer of a nonwoven fabric made of a thermoplastic elastomer resin or a plurality of layers in which a nonwoven fabric made of another resin is laminated. Because it is configured, it can ensure the required water resistance, air permeability, and pore size, prevent exudation due to the penetration of liquid foam resin, and breathability that allows gas to escape properly during foaming Can be secured.
Further, by using a nonwoven fabric made of a thermoplastic elastomer resin, higher flexibility can be provided. The skin material for foam integrated molding is preferably as flexible as possible because it will easily crease (corner) on the surface if it is hard. If the basis weight of the thermoplastic elastomer at this time is 50% or more of the basis weight of the whole nonwoven fabric, it is effective.

さらに、この発明の請求項6記載の表皮一体発泡成形用の表皮材によれば、不織布が、熱可塑性エラストマー樹脂からなる不織布の少なくとも一方面または両方面に、ポリブチレンテレフタレート樹脂からなる不織布を熱接着してなる2層または3層の積層体で構成してあるので、液状の発泡樹脂の浸透による染み出しを確実に防止し、しかも耐熱性に優れることで、熱による通気性の変化を防止して発泡の際に発生する気体(ガス)が適度に抜ける通気性を十分確保することができ、さらに縫製の際のミシン送り性にも優れる。
また熱可塑性エラストマー樹脂からなる不織布のポリウレタンフォーム側の一方面にポリブチレンテレフタレート樹脂からなる不織布を積層させる事により、ポリウレタンフォームとの接着強力を向上させる事が出来る。また、ポリウレタンフォームとの反対側の一方面にポリブチレンテレフタレート樹脂からなる不織布を積層させる事により、表皮一体発泡成形用の表皮材裏面の滑り性が向上し、縫製作業効率の向上を図ることが出来る。
Furthermore, according to the skin material for integral skin foaming according to claim 6 of the present invention, the nonwoven fabric is heated on at least one side or both sides of the nonwoven fabric made of thermoplastic elastomer resin by heating the nonwoven fabric made of polybutylene terephthalate resin. Because it is composed of a two-layer or three-layer laminate that is bonded together, it can reliably prevent seepage due to the penetration of liquid foamed resin, and it also has excellent heat resistance, preventing changes in breathability due to heat. Thus, it is possible to sufficiently ensure the air permeability through which the gas (gas) generated during foaming is adequately released, and further excellent in the machine feedability during sewing.
Further, by laminating a non-woven fabric made of polybutylene terephthalate resin on one surface of the non-woven fabric made of thermoplastic elastomer resin on the polyurethane foam side, the adhesive strength with the polyurethane foam can be improved. In addition, by laminating a non-woven fabric made of polybutylene terephthalate resin on one side opposite to the polyurethane foam, the slipperiness of the back of the skin material for skin integral foam molding can be improved, and the sewing work efficiency can be improved. I can do it.

以下、この発明の表皮一体発泡成形用の表皮材の一実施の形態について、詳細に説明する。
図1〜図3は、この発明の表皮一体発泡成形用の表皮材の一実施の形態にかかり、図1は断面図、図2は成形体の一例の車両用のヘッドレストの概略斜視図、図3は成形工程の概略断面図である。
Hereinafter, an embodiment of a skin material for foam integrated foam molding according to the present invention will be described in detail.
1 to 3 relate to an embodiment of a skin material for foam integrated foam molding of the present invention, FIG. 1 is a cross-sectional view, FIG. 2 is a schematic perspective view of a vehicle headrest as an example of a molded body, FIG. 3 is a schematic cross-sectional view of the molding process.

この発明の表皮一体発泡成形用の表皮材10は、例えば図2および図3に示す、車両用のヘッドレスト20の表皮材10として用いられ、ヘッドレスト20の外形に対応する形状に立体的に縫製され、その内部に補強材や支柱などのインサート部品21が装着され、これら装着されたインサート部品21と表皮材10との内部空間に液状の発泡樹脂が注入され、表皮材10と発泡した発泡樹脂とが一体となった表皮一体発泡成形体の製品であるヘッドレストとなる。この発明の表皮一体発泡成形用の表皮材10は、表皮一体発泡成形体の表皮の一部において使用されても構わない。例えば、液状の発泡樹脂の注入圧が大きくかかる部分のみ使用することも可能である。   A skin material 10 for skin foam integrated molding according to the present invention is used, for example, as a skin material 10 of a vehicle headrest 20 shown in FIGS. 2 and 3, and is three-dimensionally sewn into a shape corresponding to the outer shape of the headrest 20. Insert parts 21 such as reinforcing materials and support pillars are mounted therein, and a liquid foamed resin is injected into the internal space between the mounted insert parts 21 and the skin material 10, and the skin material 10 and the foamed resin foamed It becomes a headrest which is a product of a skin-integrated foam-molded product. The skin material 10 for skin integral foam molding of this invention may be used in a part of the skin of the skin integral foam molded article. For example, it is possible to use only the portion where the injection pressure of the liquid foamed resin is large.

このような表皮一体発泡成形用の表皮材10は、図1に示すように、表生地11と、軟質ポリウレタンフォーム12と、染み出し防止性および通気性を備える不織布13とを接着して構成することができる。   As shown in FIG. 1, such a skin material 10 for skin integral foam molding is constituted by adhering a surface fabric 11, a flexible polyurethane foam 12, and a non-woven fabric 13 having a bleeding prevention property and a breathability. be able to.

表生地11としては、ヘッドレスト20としての風合いや感触および通気性を考慮して繊維を編織した布地や不織布などが用いられるほか、天然皮革や合成皮革など従来から一般的に使用されている素材が用いられる。   As the front fabric 11, fabrics and non-woven fabrics woven with fibers in consideration of the texture, feel and breathability as the headrest 20 are used, and materials conventionally used in general such as natural leather and synthetic leather are used. Used.

軟質ポリウレタンフォーム12は、この表生地11の裏面側に接着され、表生地11の風合いや伸縮性などが内部に注入発泡されて一体とされる発泡樹脂によって損なわれないようにするものである。軟質ポリウレタンフォーム12は、一般に表皮一体発泡成形用に用いられているものが使用できるが、好ましくは密度が18〜60Kg/m3(さらに好ましくは35〜55Kg/m)、硬度が90〜500N(さらに好ましくは350〜450N)である。またその厚さは、成形品の種類や材質によっても異なるが、例えば1mm〜15mm程度とされる。 The flexible polyurethane foam 12 is bonded to the back side of the front fabric 11 so that the texture and stretchability of the front fabric 11 are not damaged by the foamed resin that is injected and foamed inside. As the flexible polyurethane foam 12, those generally used for skin integral foam molding can be used. Preferably, the density is 18 to 60 kg / m 3 (more preferably 35 to 55 kg / m 3 ), and the hardness is 90 to 500 N ( More preferably, it is 350-450N). The thickness varies depending on the type and material of the molded product, but is about 1 mm to 15 mm, for example.

この軟質ポリウレタンフォーム12の裏面側には、軟質ポリウレタンフォーム12や表生地11への液状の発泡樹脂の浸透を防止するため、染み出し防止性を有するとともに、発泡樹脂の注入発泡にともなって発生する気体(ガス)による気泡が残ることを防止するため、通気性を有する必要があり、しかも発泡樹脂との接触により熱変形しない耐熱性を有するものが必要であり、ここでは、不織布13を用いることで、染み出し防止性と通気性を確保するようにしている。
このような染み出し防止性および通気性を備える不織布13としては、染み出し防止性を表す物性として、耐水圧を用い、耐水圧(JIS−L1092)が450mmHO(mmAq)以上であること、および通気性を表す物性として通気度を用い、通気度(JIS−L1096)が0.1〜20cc/cm/sであること、さらに、これら耐水圧よび通気度を決定する物性としてポアサイズを用い、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく測定)の平均が0.1〜20μmであることが必要である。また、上記不織布の耐水圧は、好ましくは500mmHO以上、更に好ましくは550mmHO以上である。また、上記不織布の通気度は好ましくは5〜15cm/sである。また、上記不織布のポアサイズは好ましくは、5〜15μmである。
In order to prevent the liquid foamed resin from penetrating into the flexible polyurethane foam 12 and the front fabric 11 on the back side of the flexible polyurethane foam 12, the flexible polyurethane foam 12 has an anti-bleeding property and is generated with the foaming of the foamed resin. In order to prevent gas bubbles from remaining, it is necessary to have air permeability and heat resistance that does not cause thermal deformation due to contact with the foamed resin. Here, the nonwoven fabric 13 is used. In order to ensure the prevention of bleeding and air permeability.
As the nonwoven fabric 13 having such a bleeding prevention property and air permeability, as a physical property representing the bleeding prevention property, a water pressure is used, and a water pressure resistance (JIS-L1092) is 450 mmH 2 O (mmAq) or more, Further, air permeability is used as a physical property representing air permeability, air permeability (JIS-L1096) is 0.1 to 20 cc / cm 2 / s, and pore size is used as a physical property for determining the water pressure resistance and air permeability. The average pore size (measured based on the valve point method of ASTM F-361-80) needs to be 0.1 to 20 μm. The water pressure resistance of the nonwoven fabric is preferably 500 mmH 2 O or more, more preferably 550 mmH 2 O or more. Moreover, the air permeability of the nonwoven fabric is preferably 5 to 15 cm 2 / s. The pore size of the nonwoven fabric is preferably 5 to 15 μm.

不織布13の耐水圧が450mmHO(mmAq)未満であると、その内側の軟質ウレタンフォーム12に液状の発泡樹脂が浸透して染み出してしまう。
また、不織布13の通気度が0.1cc/cm/s未満であると、発泡樹脂から発生する気体(ガス)が抜けずに巣穴が発生するおそれがあり、通気度が20cc/cm/sを超えて大きいと、空気などの気体(ガス)が抜け過ぎて成形体が膨らまなくなるおそれがある。
さらに、不織布13のポアサイズによって通気度および耐水圧がある程度定まるが、平均ポアサイズが20μmを超えて大きいと、通気度および耐水圧を上記の範囲に保つことができなくなる。なお、このポアサイズは、表皮材10として用いる場合にこれらの値であれば良く、不織布をエンボスやカレンダーなどの後工程で加工を施す場合には、これらの加工によってポアサイズを調整することができ、調整後、液状の発泡樹脂を充填する前の状態で上記の値を確保できれば良い。
If the water pressure resistance of the nonwoven fabric 13 is less than 450 mmH 2 O (mmAq), the liquid foamed resin will permeate and ooze out into the flexible urethane foam 12 inside.
Further, if the air permeability of the nonwoven fabric 13 is less than 0.1 cc / cm 2 / s, there is a possibility that a gas (gas) generated from the foamed resin will not escape and a burrow may be generated, and the air permeability is 20 cc / cm 2. If it exceeds / s, gas (gas) such as air may escape too much and the molded body may not expand.
Furthermore, although the air permeability and the water pressure resistance are determined to some extent depending on the pore size of the nonwoven fabric 13, if the average pore size exceeds 20 μm, the air permeability and the water pressure resistance cannot be maintained in the above ranges. The pore size may be any of these values when used as the skin material 10, and when the nonwoven fabric is processed in a subsequent process such as embossing or calendar, the pore size can be adjusted by these processing, After the adjustment, it is only necessary to ensure the above value in a state before filling with the liquid foamed resin.

このような耐水圧、通気度、ポアサイズの不織布13を用いることで、表生地11、軟質ポリウレタンフォーム12、不織布13により表皮材10を構成し、立体成形した内部空間に液状の発泡樹脂を注入して発泡樹脂と一体となった表皮一体発泡成形体を成形することで、液状の発泡樹脂が軟質ポリウレタンフォーム12に浸透して染み出し、硬くなることもなく、発泡樹脂からの気体(ガス)が抜けずに巣穴が発生し、表生地11にしわが発生することもなく、所望の製品を得ることができるとともに、発泡樹脂の注入で表皮材10が膨らまずに成形不能となることもない。   By using the nonwoven fabric 13 having such a water pressure resistance, air permeability, and pore size, the skin material 10 is constituted by the outer fabric 11, the flexible polyurethane foam 12, and the nonwoven fabric 13, and a liquid foamed resin is injected into the three-dimensionally formed internal space. By molding the skin-integrated foamed molded body integrated with the foamed resin, the liquid foamed resin penetrates into the flexible polyurethane foam 12 and oozes out, and the gas (gas) from the foamed resin does not become hard. Nest holes are not generated without wrinkles, and no wrinkles are generated on the surface dough 11, so that a desired product can be obtained and the skin material 10 does not swell due to the injection of the foamed resin and cannot be molded.

また、不織布13の平均繊維径が、0.1〜10μmであることが好ましく、より好ましくは2〜5μmである。繊維径は、不織布13のポアサイズを決定する要素の1つであり、平均繊維径を10μmを超えて大きくすると、ポアサイズが大きくなって上記のポアサイズの範囲にすることができなくなる。また、平均繊維径が0.1μm未満の不織布は、その生産性が極端に落ちる。
なお、不織布13の繊維径が大きくてもエンボスやカレンダーなどの後加工によりポアサイズを上記の範囲内にすることもできる。
Moreover, it is preferable that the average fiber diameter of the nonwoven fabric 13 is 0.1-10 micrometers, More preferably, it is 2-5 micrometers. The fiber diameter is one of the factors that determine the pore size of the nonwoven fabric 13, and when the average fiber diameter is increased beyond 10 μm, the pore size increases and cannot be in the above pore size range. Further, the productivity of the nonwoven fabric having an average fiber diameter of less than 0.1 μm is extremely lowered.
Even if the fiber diameter of the nonwoven fabric 13 is large, the pore size can be set within the above range by post-processing such as embossing and calendering.

さらに、不織布13の目付が、30〜70g/mであることが好ましい。
不織布13の目付が30g/m未満であると、不織布として必要な物性を得ることができず、70g/mを超えて大きくなると、硬くなり成形不良となる。
この不織布13の目付は、表皮一体発泡成形体としての製品によっても好ましい範囲が異なるが、例えばヘッドレストの場合には、30〜50g/mの範囲が好ましく、アームレストの場合には、40〜70g/mの範囲が好ましい。
なお、不織布13の目付が同じでも繊維径などにより物性は異なるが、その場合でも上記ポアサイズを満たす必要がある。
Furthermore, it is preferable that the fabric weight of the nonwoven fabric 13 is 30-70 g / m < 2 >.
If the basis weight of the nonwoven fabric 13 is less than 30 g / m 2 , the physical properties required for the nonwoven fabric cannot be obtained, and if it exceeds 70 g / m 2 , the fabric becomes hard and defective molding occurs.
The basis weight of the nonwoven fabric 13 varies depending on the product as the skin-integrated foamed molded article, but for example, in the case of a headrest, a range of 30 to 50 g / m 2 is preferable, and in the case of an armrest, 40 to 70 g. A range of / m 2 is preferred.
In addition, even if the fabric weight of the nonwoven fabric 13 is the same, the physical properties differ depending on the fiber diameter and the like, but even in that case, it is necessary to satisfy the pore size.

なお、不織布の製造方法は、特に限定するものでないが、メルトブロー製法が好ましい。例えば不織布の製法として一般なスパンボンド法、スパンレース法等であると、製法上細い繊維径のものを採取するのが困難である。その為、適宜な耐水圧・通気度・ポアサイズのものを得ようとすると、高目付になり剛性が高く硬くなる傾向にある。これに対しメルトブロー製法によれば、溶融状態の樹脂を紡糸する際に高速高温空気で噴射、開繊して、ベルト又は金網上に集積して不織布の形態とするので、極細の繊維径にすることが容易である。この為、低目付で柔軟な状態で適宜な耐水圧・通気度・ポアサイズのものを得ることが出来る。   In addition, the manufacturing method of a nonwoven fabric is although it does not specifically limit, The melt blow manufacturing method is preferable. For example, when a general spunbond method, a spunlace method, or the like is used as a method for producing a nonwoven fabric, it is difficult to collect a thin fiber diameter in terms of the production method. For this reason, when trying to obtain an appropriate water pressure resistance, air permeability, and pore size, the weight per unit area tends to be high, and the rigidity tends to be high. On the other hand, according to the melt blow manufacturing method, when spinning a molten resin, it is sprayed and opened with high-speed and high-temperature air and accumulated on a belt or a wire mesh to form a non-woven fabric. Is easy. For this reason, it is possible to obtain an appropriate water pressure resistance, air permeability, and pore size in a low weight and flexible state.

このような不織布13を構成する合成樹脂としては、特に問わないが、不織布が柔軟なことで表皮材の表面に折れ皺(角)が出にくくなり、外観上好ましいことから、例えば熱可塑性エラストマーが好ましく、その中でもスチレン系熱可塑性エラストマーが更に好ましく、例えばSEPS(スチレンエチレンプロピレンスチレンブロック共重合体)、SIS(スチレンイソプレンスチレンブロック共重合体)、SBPS(スチレンブチレンプロピレンスチレンブロック共重合体)、SEBS(スチレンエチレンブチレンスチレンブロック共重合体)などを挙げることができるほか、耐水性および通気性を兼ね備え、ポアサイズが上記範囲となる合成樹脂を用いることができる。   The synthetic resin constituting such a nonwoven fabric 13 is not particularly limited. However, since the nonwoven fabric is flexible, folds (corners) are less likely to appear on the surface of the skin material, which is preferable in appearance. For example, a thermoplastic elastomer is used. Of these, styrene-based thermoplastic elastomers are more preferable. For example, SEPS (styrene ethylene propylene styrene block copolymer), SIS (styrene isoprene styrene block copolymer), SBPS (styrene butylene propylene styrene block copolymer), SEBS. (Styrene ethylene butylene styrene block copolymer) and the like, and a synthetic resin having both water resistance and air permeability and having a pore size in the above range can be used.

また、表皮材の裏面は摩擦抵抗が少ないことが好ましい。表皮材の裏面を構成する不織布が摩擦抵抗の少ない樹脂からなることにより、ミシン縫製の際の滑り性が向上し、作業効率を向上することが出来る。この時の摩擦抵抗の低い樹脂の種類としては特に制限は無いが、ポリエチレンテレフタレート・ポリブチレンテレフタレートなどのポリエステル系樹脂、ポリプロピレンなどのポリオレフィン系樹脂、ポリアミド系樹脂などが挙げられる。その中でも、メルトブロー製法により不織布化が容易なのは、ポリブチレンテレフタレート・ポリプロピレンであり、更に他の層との接着性が高いのはポリプロピレンである。熱溶融しやすい樹脂はメルトブロー製法、他の層との熱接着性などで有利である一方、溶融による通気度の低下や硬化を抑制、制御する観点からは熱溶融しにくい樹脂、例えば変性ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリプロピレン、ポリアミド系樹脂などが有利である。不織布全体が硬くなると、表面に折れ皺(角)が発生する原因になる。メルトブロー性、接着性、溶融性の制御などのバランスからポリブチレンテレフタレートを選択するのが最も好ましい。また少なくともポリウレタンフォームと接する部分において不織布はポリウレタンフォームと良好に接着することが好ましく、例えば、ポリエチレンテレフタレート・ポリブチレンテレフタレートなどのポリエステル系樹脂、ポリプロピレンなどのポリオレフィン系樹脂、ポリアミド系樹脂などが挙げられる。ポリウレタンフォームと不織布との接着性を改善するために接着剤などを用いることもできるが、通気性を保持する観点から不織布の熱接着が好ましい。   Moreover, it is preferable that the back surface of the skin material has a low frictional resistance. When the non-woven fabric constituting the back surface of the skin material is made of a resin having a low frictional resistance, the slipperiness at the time of sewing the sewing machine can be improved, and the working efficiency can be improved. The type of resin having low frictional resistance at this time is not particularly limited, and examples thereof include polyester resins such as polyethylene terephthalate and polybutylene terephthalate, polyolefin resins such as polypropylene, and polyamide resins. Among them, polybutylene terephthalate / polypropylene is easily made into a non-woven fabric by a melt blow production method, and polypropylene is more adhesive to other layers. Resins that are easily melted by heat are advantageous in terms of the melt blow process, thermal adhesion to other layers, etc., but from the viewpoint of suppressing and controlling the decrease in air permeability and curing due to melting, resins that are difficult to heat melt, such as modified polyethylene terephthalate Polybutylene terephthalate, polypropylene, polyamide resin and the like are advantageous. When the whole nonwoven fabric becomes hard, it causes a crease (corner) on the surface. It is most preferable to select polybutylene terephthalate from the balance of melt blowability, adhesion, and meltability control. Further, it is preferable that the nonwoven fabric adheres well to the polyurethane foam at least at a portion in contact with the polyurethane foam. Examples thereof include polyester resins such as polyethylene terephthalate and polybutylene terephthalate, polyolefin resins such as polypropylene, and polyamide resins. An adhesive or the like can be used to improve the adhesion between the polyurethane foam and the nonwoven fabric, but thermal bonding of the nonwoven fabric is preferable from the viewpoint of maintaining air permeability.

また、不織布13としては、上記樹脂によるものを単層で用いるほか、他の合成樹脂を積層して不織布を構成するようにしても良い。この場合、ポリウレタンフォームに接する第1の不織布層は、ポリウレタンフォームと親和性が高い樹脂からなることが好ましく、同様に該第1の不織布層と積層する第2の不織布層との親和性が高い樹脂からなることが好ましい。熱接着する場合は溶融による通気性の阻害を生じないように例えば目付を30〜70g/mとすることが望ましい。接着性と通気性を調節するために空隙率を調節する方法を取ることもできる。不織布の柔軟性を得るために柔軟性の高い不織布からなる柔軟層を設けることが好ましく、これは例えば熱可塑性エラストマーなどからなること不織布が用いられ、柔軟性の効果を充分得るには不織布全体の目付けの50%以上を該柔軟層とすることが望ましい。柔軟層を前記第1の不織布層としても良いが、ポリウレタンフォームと親和性の高い第1の不織布層の上に該柔軟層を設けることで熱接着の際の通気度制御などの観点から好ましい。また該第1の不織布層と柔軟層の間に接着性を高めるために更に間に別の不織布を積層しても良い。柔軟層を形成する柔軟な不織布は膠着感が高い場合があるが、更に滑り性が高く、該柔軟層との親和性の高い不織布を積層し、表皮材の裏面とすることでミシン縫製の作業性を向上できる。表皮材の裏面を形成する層として用いられる不織布は、例えば目付を30〜70g/mにすることが好ましく、材料としては前記裏面を構成するのに有利な樹脂が用いられる。該裏面層と柔軟層の接着性を高めるために更に間に別の不織布を積層しても良い。以上のことから、複層で不織布を構成する場合、例えば、ポリウレタンフォームと親和性の高い第1層、柔軟層からなる第2層、裏面を構成する滑り性の良い層からなる第3層をこの順に積層した構造とすることが好ましい。 Moreover, as the nonwoven fabric 13, what uses the said resin by a single layer may be laminated | stacked, and you may make it laminate | stack another synthetic resin and comprise a nonwoven fabric. In this case, the first nonwoven fabric layer in contact with the polyurethane foam is preferably made of a resin having a high affinity with the polyurethane foam, and similarly has a high affinity with the second nonwoven fabric layer laminated with the first nonwoven fabric layer. It is preferable to consist of resin. In the case of heat bonding, for example, the basis weight is preferably set to 30 to 70 g / m 2 so as not to inhibit air permeability due to melting. In order to adjust the adhesion and air permeability, a method of adjusting the porosity can be taken. In order to obtain the flexibility of the nonwoven fabric, it is preferable to provide a flexible layer made of a highly flexible nonwoven fabric. For example, a nonwoven fabric made of a thermoplastic elastomer is used. It is desirable that 50% or more of the basis weight be the flexible layer. Although the flexible layer may be the first nonwoven fabric layer, it is preferable from the viewpoint of air permeability control at the time of thermal bonding by providing the flexible layer on the first nonwoven fabric layer having high affinity with polyurethane foam. Further, another non-woven fabric may be laminated between the first non-woven fabric layer and the flexible layer in order to enhance the adhesion. The flexible nonwoven fabric that forms the flexible layer may have a high feeling of sticking, but it is even more slippery and the sewing work is performed by laminating the nonwoven fabric with high affinity with the flexible layer and using it as the back surface of the skin material. Can be improved. The nonwoven fabric used as the layer forming the back surface of the skin material preferably has a basis weight of 30 to 70 g / m 2 , for example, and a resin that is advantageous for constituting the back surface is used as the material. In order to enhance the adhesion between the back layer and the flexible layer, another non-woven fabric may be further laminated. From the above, when forming a nonwoven fabric with multiple layers, for example, a first layer having a high affinity with polyurethane foam, a second layer consisting of a flexible layer, and a third layer consisting of a layer with good slipperiness constituting the back surface A stacked structure in this order is preferable.

このように、不織布を複層構造とする場合、全体として耐水圧450mmHO以上であって通気度0.1〜20cc/cm/sであり、平均ポアサイズが0.1〜20μmの範囲であれば、その層構成はいかなるものであってもよい。積層方法としては、接着剤を活用する方法と熱エンボス法が上げられるが、熱エンボス法がより好ましい。熱エンボス法で積層する事により、不織布の摩擦抵抗値を下げる事が出来、滑り性の向上が図れる。これによりミシン縫製の作業性を向上させる事が出来る。この時の熱エンボスの圧着面積は2〜50%が好ましく、50%を超えると、風合いが硬くなり表皮に折れ皺(角)が出る原因になる。2%以下であると摩擦抵抗値を下げる効果がない。 Thus, when the nonwoven fabric and multilayer structure are a in overall water pressure resistance 450mmH 2 O or permeability 0.1~20cc / cm 2 / s, the average pore size in the range of 0.1~20μm Any layer structure may be used as long as it is present. As a laminating method, a method using an adhesive and a hot embossing method can be raised, and the hot embossing method is more preferable. By laminating by the hot embossing method, the frictional resistance value of the nonwoven fabric can be lowered and the slipperiness can be improved. As a result, the workability of the sewing machine can be improved. At this time, the pressure-bonding area of the heat embossing is preferably 2 to 50%, and if it exceeds 50%, the texture becomes hard and the skin is broken and wrinkles (corners) are caused. If it is 2% or less, there is no effect of lowering the frictional resistance value.

実施例では、具体的な不織布13として、例えば図1中に拡大して示すように、スチレンエチレンプロピレンスチレンブロック共重合体(SEPS)の表裏面(両方面)に、ポリブチレンテレフタレート(PBT)を設けた3層13a,13b,13bの不織布が用いられ、その厚さ(JIS−L1096)は0.2〜0.4mm程度、好ましくは0.3mm程度のものが使用され、通気度(JIS−L1096)は18cc/cm/秒程度、耐水圧を500mmHO程度、ポアサイズが平均15.8μmのものを使用した。 In the examples, as specific nonwoven fabric 13, for example, as shown in an enlarged manner in FIG. 1, polybutylene terephthalate (PBT) is formed on the front and back surfaces (both surfaces) of styrene ethylene propylene styrene block copolymer (SEPS). The provided non-woven fabric of three layers 13a, 13b, and 13b is used, and the thickness (JIS-L1096) is about 0.2 to 0.4 mm, preferably about 0.3 mm, and the air permeability (JIS- L1096) used was about 18 cc / cm 2 / sec, with a water pressure resistance of about 500 mmH 2 O, and an average pore size of 15.8 μm.

表生地11と軟質ポリウレタンフォーム12と不織布13を積層して表皮材10を成形する方法としては、接着剤を使用する方法、ホットメルトフィルムを使用する方法、高周波ウェルダによる方法、フレームラミネートによる方法等があるが、表生地11や軟質ポリウレタンフォーム12の風合いを損ねることがなく、乾燥工程が不要であり、接着速度も速く生産性に優れるためフレームラミネートによる方法が好適である。   As a method of forming the skin material 10 by laminating the surface fabric 11, the flexible polyurethane foam 12 and the nonwoven fabric 13, a method using an adhesive, a method using a hot melt film, a method using a high frequency welder, a method using a frame laminate, etc. However, since the texture of the surface fabric 11 and the flexible polyurethane foam 12 is not impaired, a drying step is unnecessary, the bonding speed is fast, and the productivity is excellent, the method by frame lamination is preferable.

このような耐熱性および通気性を有し、染み出し防止性を有する不織布13を裏面に接着した表皮材10は、成形体として例えば、図3に示すように、車両用のヘッドレスト20の外形に対応する形状に立体的に縫製され、その内部に補強材や支柱などのインサート部品21が装着されて成形装置30の発泡型31に取り付けられ、これら装着されたインサート部品21と表皮材10の裏面の不織布13との内部空間に液状の発泡樹脂が注入ノズル32から注入され、表皮材10と発泡した発泡樹脂とが一体となった表皮一体発泡成形体の製品であるヘッドレスト20となる(図2参照)。なお、この発明の表皮一体発泡成形用の表皮材10は、表皮一体発泡成形体の表皮の一部分において使用されても構わない。例えば、液状の発泡樹脂が直接あたる部分にのみこの発明の表皮一体発泡成形用の表皮材10使用することも可能である。   The skin material 10 obtained by adhering the nonwoven fabric 13 having heat resistance and air permeability and preventing bleeding to the back surface is formed as a molded body, for example, on the outer shape of a headrest 20 for a vehicle as shown in FIG. Three-dimensional sewing is performed in a corresponding shape, and an insert part 21 such as a reinforcing material or a support is mounted inside and attached to the foaming die 31 of the molding apparatus 30, and the inserted insert part 21 and the back surface of the skin material 10 are mounted. Liquid foam resin is injected from the injection nozzle 32 into the inner space of the non-woven fabric 13 to form a headrest 20 that is a product of a skin-integrated foam-molded product in which the skin material 10 and the foamed foam resin are integrated (FIG. 2). reference). In addition, the skin material 10 for skin integral foam molding of this invention may be used in a part of the skin of the skin integral foam molded article. For example, it is also possible to use the skin material 10 for skin-integrated foam molding of the present invention only in a portion directly exposed to a liquid foamed resin.

こうして表皮一体発泡成形法で成形した成形体であるヘッドレスト20では、不織布13によって注入された液状やクリーム状の発泡樹脂が軟質ポリウレタンフォーム12や表生地11に浸透して染み出すことが防止されて硬くなることもなく、注入した液状などの発泡樹脂が不織布13に衝突する場合でも圧力や熱などで不織布13の通気性が変化することもなく、例えガスなどの気体が生じても不織布13を通過させて排出することができ、巣穴の発生を防止することができる。   Thus, in the headrest 20 which is a molded body molded by the skin-integrated foam molding method, the liquid or cream-like foamed resin injected by the nonwoven fabric 13 is prevented from penetrating into the flexible polyurethane foam 12 and the outer fabric 11 and oozing out. Even when foamed resin such as injected liquid collides with the nonwoven fabric 13 without being hardened, the air permeability of the nonwoven fabric 13 does not change due to pressure, heat, or the like. It can be discharged through, and the formation of burrows can be prevented.

さらに、この表皮材10では、従来の合成樹脂フィルムに微小通気孔を設ける場合のような通気孔の加工工程の必要がなく、成形が容易であり、工程を短縮することができる。   Further, in the skin material 10, there is no need for a process step for forming a vent hole as in the case of providing a micro vent hole in a conventional synthetic resin film, the molding is easy, and the process can be shortened.

また、ウレタンフィルムなどに比べて滑り易くミシンによる縫製が容易にできるとともに、表皮材10とするため表生地11、軟質ポリウレタンフォーム12とラミネートする場合にも不織布13を送り出しやすく、しかも耐熱性に優れるため、例えばフレームラミネート法でラミネートする場合にも変形することもなく表皮材10の成形も容易となる。   Further, it is easier to sew with a sewing machine than a urethane film or the like, and it is easy to send out the nonwoven fabric 13 when it is laminated with the outer fabric 11 and the flexible polyurethane foam 12 to make the outer skin material 10, and it has excellent heat resistance. Therefore, for example, even when laminating by a frame laminating method, the skin material 10 can be easily molded without deformation.

以下、この発明の実施例について、比較例とともに説明するが、本発明は、この実施例に限定するものでない。   Examples of the present invention will be described below together with comparative examples. However, the present invention is not limited to these examples.

<評価サンプルの形成>
各実施例、比較例において評価サンプルは次のようにして作成した。厚さ5mm、硬度35N(JIS K6400−2)の軟質ポリウレタンフォームと不織布をフレームラミネート法により積層した。これを縦300mm横200mmの長方形に2枚切り出し、3方を工業用ミシンにて、ポリエステル糸を使用して、不織布が内側になるように縫製した袋状の評価サンプルを作成した。すなわち評価サンプルは表生地のない表皮材のごとき構造である。なお不織布が2層であるものは第1層、第2層、の順に積層した構造であり、3層であるものは第1層、第2層、第3層の順に積層した構造であり、それぞれ該第1層を軟質ポリウレタンフォームと接するように積層した。また熱エンボス処理を施したものはいずれも、丸ドット形状で、熱圧着部分の圧着面積は面全体面積(600cm)の3%とした。
なお、この評価サンプルの内部に発泡樹脂(ポリエーテルポリオール100重量部、ポリイソシアネートとしてTDI−80とポリメリックMDIの混合物70重量部、反応性の触媒としてジメチルエタノールアミン(2−ジメチルアミノエタノール、DMEA)2.5重量部、非反応性の触媒としてトリエチレンジアミン(TEDA)1.0重量部、発泡剤として水3.5質量部及び整泡剤としてシリコーンオイル1重量部の混合物)を注入ノズルから注入し発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
<Formation of evaluation sample>
In each example and comparative example, an evaluation sample was prepared as follows. A flexible polyurethane foam having a thickness of 5 mm and a hardness of 35 N (JIS K6400-2) and a nonwoven fabric were laminated by a frame laminating method. Two pieces of this were cut out into a rectangle of 300 mm in length and 200 mm in width, and a bag-like evaluation sample was prepared by sewing the three sides with an industrial sewing machine using polyester yarn so that the nonwoven fabric was inside. That is, the evaluation sample has a structure such as a skin material without a surface fabric. In addition, what is a nonwoven fabric is a structure which laminated | stacked in order of the 1st layer and the 2nd layer, and what is 3 layers is a structure laminated | stacked in order of the 1st layer, the 2nd layer, and the 3rd layer, Each of the first layers was laminated so as to be in contact with the flexible polyurethane foam. In addition, all those subjected to the heat embossing treatment were round dot shapes, and the crimping area of the thermocompression bonding portion was 3% of the entire surface area (600 cm 2 ).
In this evaluation sample, a foamed resin (100 parts by weight of polyether polyol, 70 parts by weight of a mixture of TDI-80 and polymeric MDI as polyisocyanate, dimethylethanolamine (2-dimethylaminoethanol, DMEA) as a reactive catalyst) 2.5 parts by weight, 1.0 part by weight of triethylenediamine (TEDA) as a non-reactive catalyst, 3.5 parts by weight of water as a foaming agent and 1 part by weight of silicone oil as a foam stabilizer) are injected from an injection nozzle. The foamed molded body integrated with the evaluation sample was obtained by foaming and curing.

<評価方法>
この実施例では、不織布による発泡樹脂の染み出し防止性および発泡樹脂からのガスの発生による巣穴の発生、ミシン性、耐剥離性を評価した。その評価方法は以下のとおりである。
<染み出し防止性>
表皮材の上部開口からポリウレタンの原液を注入し、硬化後に、底部縫製部からの高さ2cmから5cmの範囲における注入ウレタンフォームの染み出し状態を目視で評価するとともに、この部分の軟質ポリウレタンフォームを剥がして、ゴム硬度計で6箇所の硬度を測定して硬度の平均を求め、元の軟質ポリウレタンフォームの硬度との変化から染み出し防止性を評価した。評価基準は以下のとおりである。
〇:注入ウレタンフォームが表皮材の表面まで浸透しておらず、表面硬度の変化が10N未満
×:注入ウレタンフォームが表皮材の表面まで浸透しており、表面硬度の変化が10N以上
<巣穴の発生>
上記評価サンプルの断面を観察し、表皮材と注入ウレタンフォームの界面における巣穴(空隙)の発生の有無を目視で判断した。
〇:巣穴(空隙)の発生がない
×:巣穴(空隙)が観察される
<ミシン送り性>
上記評価サンプルを縫製する際のミシン送り性について評価した。
〇:不織布がスムーズに送れ、縫い目が直線である
△:不織布が若干引っかかるが、縫い目は直線である
×:不織布がスムーズに送れず、縫い目が揃わない
<耐剥離性>
上記表皮材のポリウレタンフォームと不織布の剥離強力について評価した。
○:不織布を強く引っ張っても界面がポリウレタンフォームに接着している。
△:不織布を軽く引っ張ってもポリウレタンフォームに接着しているが、
強く引っ張ると界面が剥がれる。
×:不織布を軽く引っ張るとポリウレタンフォームから剥がれる。
なお、不織布を引っ張った際に界面よりも先にポリウレタンフォームまたは不織布が材料破壊したものは〇とした。
<Evaluation method>
In this example, the prevention of seepage of the foamed resin by the nonwoven fabric and the generation of burrows due to the generation of gas from the foamed resin, the sewing performance, and the peel resistance were evaluated. The evaluation method is as follows.
<Prevention of bleeding>
The polyurethane stock solution is injected from the top opening of the skin material, and after curing, the exuding state of the injected urethane foam in the range of 2 cm to 5 cm in height from the bottom sewn part is visually evaluated, and the flexible polyurethane foam of this part is After peeling off, the hardness of six locations was measured with a rubber hardness meter to determine the average hardness, and the bleeding prevention property was evaluated from the change from the hardness of the original flexible polyurethane foam. The evaluation criteria are as follows.
○: The injected urethane foam does not penetrate to the surface of the skin material, and the change in surface hardness is less than 10N. ×: The injected urethane foam penetrates to the surface of the skin material, and the change in surface hardness is 10N or more Occurrence>
The cross section of the evaluation sample was observed, and the presence or absence of burrows (voids) at the interface between the skin material and the injected urethane foam was judged visually.
◯: No burrow (void) is generated ×: Nest hole (void) is observed <sewing machine feedability>
The sewing machine feedability when sewing the evaluation sample was evaluated.
○: The nonwoven fabric can be smoothly fed and the seam is straight △: The nonwoven fabric is slightly caught but the seam is straight ×: The nonwoven fabric cannot be smoothly fed and the seam is not aligned <Release Resistance>
The peel strength of the polyurethane foam and nonwoven fabric of the skin material was evaluated.
○: Even if the nonwoven fabric is pulled strongly, the interface is adhered to the polyurethane foam.
Δ: Even if the nonwoven fabric is pulled lightly, it adheres to the polyurethane foam.
Pulling strongly will peel the interface.
X: When the nonwoven fabric is pulled lightly, it peels off from the polyurethane foam.
When the nonwoven fabric was pulled, the polyurethane foam or the nonwoven fabric was destroyed before the interface.

(実施例1)
評価サンプル:目付が25g/mのスチレン系エラストマー樹脂メルトブローン不織布(第2層)(SEPS、平均繊維径4.5μm)の片面に目付が20g/mのポリブチレンテレフタレート(PBT、平均繊維径3.5μm)からなるメルトブローン不織布(第1層)を熱エンボスにて熱圧着した2層積層体の不織布を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が12.5cc/cm/s、耐水圧(JIS−L1092)が529mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は12.1μmであった。
この不織布から得られた評価サンプルの内部に発泡樹脂を注入ノズルから注入し発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は37Nで、表面硬度の変化が10N未満であり、表面への発泡樹脂の浸透はなく、軟質ポリウレタンフォームの感触がそのまま残り、気泡による巣穴の発生もなかった。また、ミシン送り性は、若干引っかかるが、縫い目は直線であった。更に耐剥離性は、高かった(表1参照)。
Example 1
Evaluation sample: Polybutylene terephthalate (PBT, average fiber diameter) having a basis weight of 20 g / m 2 on one side of a styrene elastomer resin meltblown nonwoven fabric (second layer) (SEPS, average fiber diameter 4.5 μm) having a basis weight of 25 g / m 2 A two-layer laminated nonwoven fabric obtained by thermocompression bonding of a melt blown nonwoven fabric (first layer) made of 3.5 μm with hot embossing was used.
As shown in Table 1, the measured values of this nonwoven fabric are as follows: air permeability (JIS-L1096) is 12.5 cc / cm 2 / s, water pressure resistance (JIS-L1092) is 529 mmH 2 O, and pore size (ASTMF) The average value of a porous material automatic pore measuring apparatus based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 12.1 μm.
A foamed resin was injected into the evaluation sample obtained from the nonwoven fabric through an injection nozzle, foamed, and cured to obtain a foamed molded body integrated with the evaluation sample.
The average surface hardness (JIS K6400-2) of the obtained foamed molded article was 37N, the change in surface hardness was less than 10N, there was no penetration of the foamed resin into the surface, and the feel of the flexible polyurethane foam remained as it was, There was no burrow caused by bubbles. Further, the machine feedability was slightly caught, but the seam was a straight line. Furthermore, the peel resistance was high (see Table 1).

(実施例2)
評価サンプル:目付が35g/mのスチレン系エラストマー樹脂メルトブローン不織布(SEPS、平均繊維径4.5μm)の片面に目付が30g/mのポリブチレンテレフタレート(PBT、平均繊維径3.5μm)からなるメルトブローン不織布を熱エンボスにて熱圧着した2層積層体の不織布を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が6.6cc/cm/s、耐水圧(JIS−L1092)が620mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は8.6μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は36Nで、表面硬度の変化が10N未満であり、表面への発泡樹脂の浸透はなく、軟質ポリウレタンフォームの感触がそのまま残り、気泡による巣穴の発生もなかった。また、ミシン送り性は、若干引っかかるが、縫い目は直線であった。更に耐剥離性は、高かった(表1参照)。
(Example 2)
Evaluation sample: From a polybutylene terephthalate (PBT, average fiber diameter of 3.5 μm) having a basis weight of 30 g / m 2 on one side of a styrene elastomer resin meltblown nonwoven fabric (SEPS, average fiber diameter of 4.5 μm) having a basis weight of 35 g / m 2 A two-layer laminate nonwoven fabric obtained by thermocompression bonding of the resulting meltblown nonwoven fabric with hot embossing was used.
As shown in Table 1, each measured value of this nonwoven fabric has an air permeability (JIS-L1096) of 6.6 cc / cm 2 / s, a water pressure resistance (JIS-L1092) of 620 mmH 2 O, and a pore size (ASTMF). The average value of a porous material automatic pore measuring apparatus based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 8.6 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded product was 36N, the change in surface hardness was less than 10N, there was no penetration of the foamed resin into the surface, and the feel of the flexible polyurethane foam remained as it was, There was no burrow caused by bubbles. Further, the machine feedability was slightly caught, but the seam was a straight line. Furthermore, the peel resistance was high (see Table 1).

(実施例3)
評価サンプル:目付が70g/mのポリプロピレンレン樹脂メルトブローン不織布(PP、平均繊維径3.0μm)の単層を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が11.7cc/cm/s、耐水圧(JIS−L1092)が918mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は10.4μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は43Nで、表面硬度の変化が10N未満であり、表面への発泡樹脂の浸透はほとんどなく、軟質ポリウレタンフォームの感触がそのまま残り、気泡による巣穴の発生もなかった。また、ミシン送り性も良く、スムーズに送れ、縫い目が直線であった。更に耐剥離性は、高かった(表1参照)。
(Example 3)
Evaluation sample: A single layer of polypropylenelene resin meltblown nonwoven fabric (PP, average fiber diameter: 3.0 μm) having a basis weight of 70 g / m 2 was used.
As shown in Table 1, the measured values of this nonwoven fabric are as follows: air permeability (JIS-L1096) is 11.7 cc / cm 2 / s, water pressure resistance (JIS-L1092) is 918 mmH 2 O, and pore size (ASTMF) The average value of a porous material automatic pore measuring device based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 10.4 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded product was 43N, the change in surface hardness was less than 10N, and there was almost no penetration of the foamed resin into the surface, and the feel of the flexible polyurethane foam remained as it was. There was also no generation of burrows due to bubbles. Also, the machine feedability was good, it could be fed smoothly, and the seam was straight. Furthermore, the peel resistance was high (see Table 1).

(実施例4)
評価サンプル:目付が15g/mのスチレン系エラストマー樹脂メルトブローン不織布(SEPS、平均繊維径4.5μm)の片面に、目付が25g/mで同一樹脂のスチレン系エラストマー樹脂メルトブローン不織布(SEPS、平均繊維径4.5μm)を熱エンボスにて熱圧着した2層積層体の不織布を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が18.4cc/cm/s、耐水圧(JIS−L1092)が560mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は14.8μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は44Nで、表面硬度の変化が10N未満であり、表面への発泡樹脂の浸透はほとんどなく、軟質ポリウレタンフォームの感触が残り、気泡による巣穴の発生もなかった。また、ミシン送り性は、若干引っかかるが、縫い目は直線であった。耐剥離性は、中程度であった(表1参照)。
Example 4
Evaluation sample: Styrene elastomer resin melt blown nonwoven fabric (SEPS, average weight of 25 g / m 2) of the same resin on one side of a styrene elastomer resin melt blown nonwoven fabric (SEPS, average fiber diameter 4.5 μm) having a basis weight of 15 g / m 2 A two-layer laminate nonwoven fabric obtained by thermocompression bonding with a fiber diameter of 4.5 μm) by hot embossing was used.
As shown in Table 1, the measured values of this nonwoven fabric were as follows: air permeability (JIS-L1096) was 18.4 cc / cm 2 / s, water pressure resistance (JIS-L1092) was 560 mmH 2 O, and pore size (ASTMF) The average value of a porous material automatic pore measuring apparatus based on a valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 14.8 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded article was 44N, the change in surface hardness was less than 10N, the penetration of the foamed resin into the surface was scarce, and the feel of the flexible polyurethane foam remained, There was no burrow caused by bubbles. Further, the machine feedability was slightly caught, but the seam was a straight line. The peel resistance was moderate (see Table 1).

(実施例5)
評価サンプル:目付が65g/mのスチレン系エラストマー樹脂メルトブローン不織布(SEPS、平均繊維径4.5μm)の単層品を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が15.4cc/cm/s、耐水圧(JIS−L1092)が600mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は13.3μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は39Nで、表面硬度の変化が10N未満であり、表面への発泡樹脂の浸透はほとんどなく、軟質ポリウレタンフォームの感触がそのまま残り、気泡による巣穴の発生もなかった。また、ミシン送り性は、若干引っかかるが、縫い目は直線であった。耐剥離性は、中程度であった(表1参照)。
(Example 5)
Evaluation sample: A single-layer product of a styrene-based elastomer resin meltblown nonwoven fabric (SEPS, average fiber diameter: 4.5 μm) having a basis weight of 65 g / m 2 was used.
As shown in Table 1, the measured values of this nonwoven fabric are as follows: air permeability (JIS-L1096) is 15.4 cc / cm 2 / s, water pressure resistance (JIS-L1092) is 600 mmH 2 O, and pore size (ASTMF) The average value of a porous material automatic pore measuring apparatus based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 13.3 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded article was 39N, the change in surface hardness was less than 10N, the penetration of the foamed resin into the surface was almost none, and the feel of the flexible polyurethane foam remained as it was. There was also no generation of burrows due to bubbles. Further, the machine feedability was slightly caught, but the seam was a straight line. The peel resistance was moderate (see Table 1).

(実施例6)
評価サンプル:目付が20g/mのポリブチレンテレフタレートからなるメルトブローン不織布(PBT、平均繊維径3.5μm)の片面に目付が25g/mのスチレン系エラストマー樹脂(SEPS、平均繊維径4.5μm)からなるメルトブローン不織布を熱エンボスにて熱圧着した2層積層体の不織布を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が12.5cc/cm/s、耐水圧(JIS−L1092)が529mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は12.1μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は35Nで、表面硬度の変化が10N未満であり、表面への発泡樹脂の浸透はなく、軟質ポリウレタンフォームの感触がそのまま残り、気泡による巣穴の発生もなかった。また、ミシン送り性も良く、スムーズに送れ、縫い目が直線であった。耐剥離性は、中程度であった(表1参照)。
(Example 6)
Evaluation sample: Styrene elastomer resin (SEPS, average fiber diameter of 4.5 μm) having a basis weight of 25 g / m 2 on one side of a melt blown nonwoven fabric (PBT, average fiber diameter of 3.5 μm) made of polybutylene terephthalate having a basis weight of 20 g / m 2 A two-layer nonwoven fabric obtained by thermocompression bonding of a melt blown nonwoven fabric made of
As shown in Table 1, the measured values of this nonwoven fabric are as follows: air permeability (JIS-L1096) is 12.5 cc / cm 2 / s, water pressure resistance (JIS-L1092) is 529 mmH 2 O, and pore size (ASTMF) The average value of a porous material automatic pore measuring apparatus based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 12.1 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded product was 35N, the change in surface hardness was less than 10N, there was no penetration of the foamed resin into the surface, and the feel of the flexible polyurethane foam remained as it was, There was no burrow caused by bubbles. Also, the machine feedability was good, it could be fed smoothly, and the seam was straight. The peel resistance was moderate (see Table 1).

(実施例7)
評価サンプル:目付が20g/mのスチレン系エラストマー樹脂メルトブローン不織布(SEPS、平均繊維径4.5μm)の両面に目付が10g/mのポリブチレンテレフタレート(PBT、平均繊維径3.5μm)からなるメルトブローン不織布を熱エンボスにて熱圧着した3層積層体の不織布を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が16.2cc/cm/s、耐水圧(JIS−L1092)が495mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は12.6μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は36Nで、表面硬度の変化が10N未満であり、表面への発泡樹脂の浸透はなく、軟質ポリウレタンフォームの感触がそのまま残り、気泡による巣穴の発生もなかった。また、ミシン送り性も良く、スムーズに送れ、縫い目が直線であった。更に耐剥離性は、高かった(表1参照)。
(Example 7)
Evaluation sample: a basis weight of 20 g / m 2 of a styrene elastomer resin melt blown nonwoven fabric (SEPS, average fiber diameter 4.5 [mu] m) from both sides in the basis weight of 10 g / m 2 of polybutylene terephthalate (PBT, average fiber diameter 3.5 [mu] m) A three-layer laminated nonwoven fabric obtained by thermocompression bonding of the resulting meltblown nonwoven fabric with hot embossing was used.
As shown in Table 1, the measured values of this nonwoven fabric were an air permeability (JIS-L1096) of 16.2 cc / cm 2 / s, a water pressure resistance (JIS-L1092) of 495 mmH 2 O, and a pore size (ASTMF). The average value of a porous material automatic pore measuring apparatus based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 12.6 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded product was 36N, the change in surface hardness was less than 10N, there was no penetration of the foamed resin into the surface, and the feel of the flexible polyurethane foam remained as it was, There was no burrow caused by bubbles. Also, the machine feedability was good, it could be fed smoothly, and the seam was straight. Furthermore, the peel resistance was high (see Table 1).

(比較例1)
評価サンプル:目付が10g/mのスチレン系エラストマー樹脂メルトブローン不織布(SEPS、平均繊維径4.5μm)の片面に、目付が10g/mのポリブチレンテレフタレート(PBT、平均繊維径3.5μm)からなるメルトブローン不織布を熱エンボスにて熱圧着した2層積層体の不織布を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が50.0cc/cm/s、耐水圧(JIS−L1092)が370mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は19.6μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は46Nで、表面硬度の変化が10N以上であり、表面に発泡樹脂が浸透し、軟質ポリウレタンフォームの感触が失われて硬くなった。また、通気度が高く評価サンプルが膨らみにくかった。なお、ミシン送り性は良く、スムーズに送れ、縫い目が直線であった。耐剥離性は、高かった(表1参照)。
(Comparative Example 1)
Evaluation sample: basis weight of 10 g / m 2 styrene elastomer resin melt blown nonwoven fabric (SEPS, average fiber diameter 4.5 [mu] m) on one side of the basis weight is 10 g / m 2 of polybutylene terephthalate (PBT, average fiber diameter 3.5 [mu] m) A two-layer nonwoven fabric obtained by thermocompression bonding of a meltblown nonwoven fabric made of the above with hot embossing was used.
As shown in Table 1, the measured values of this nonwoven fabric were 50.0 cc / cm 2 / s in air permeability (JIS-L1096), 370 mmH 2 O in water pressure resistance (JIS-L1092), and pore size (ASTMF). The average value of a porous material automatic pore measuring device based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 19.6 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded body is 46N, the change in surface hardness is 10N or more, the foamed resin penetrates the surface, the feel of the flexible polyurethane foam is lost, and it becomes hard It was. Moreover, the air permeability was high and the evaluation sample was difficult to swell. The machine feedability was good, the machine could be fed smoothly, and the seam was straight. The peel resistance was high (see Table 1).

(比較例2)
評価サンプル:目付が15g/mのスチレン系エラストマー樹脂メルトブローン不織布(SEPS、平均繊維径4.5μm)の片面に、目付が10g/mのポリブチレンテレフタレート(PBT、平均繊維径3.5μm)からなるメルトブローン不織布を熱エンボスにて熱圧着した2層積層体の不織布を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が33.0cc/cm/s、耐水圧(JIS−L1092)が426mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は17.1μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は46Nで、表面硬度の変化が10N以上であり、表面への発泡樹脂の浸透があり、軟質ポリウレタンフォームの感触が相当失われた。なお、気泡による巣穴の発生もなく、ミシン送り性は良く、スムーズに送れ、縫い目が直線であった。耐剥離性は、高かった(表1参照)。
(Comparative Example 2)
Evaluation sample: Polybutylene terephthalate (PBT, average fiber diameter of 3.5 μm) having a basis weight of 10 g / m 2 on one surface of a styrene elastomer resin melt blown nonwoven fabric (SEPS, average fiber diameter of 4.5 μm) having a basis weight of 15 g / m 2 A two-layer nonwoven fabric obtained by thermocompression bonding of a meltblown nonwoven fabric made of the above with hot embossing was used.
As shown in Table 1, each measured value of this nonwoven fabric has an air permeability (JIS-L1096) of 33.0 cc / cm 2 / s, a water pressure resistance (JIS-L1092) of 426 mmH 2 O, and a pore size (ASTMF). The average value of a porous material automatic pore measuring apparatus based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 17.1 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded body is 46N, the change in surface hardness is 10N or more, the foamed resin penetrates the surface, and the feel of the flexible polyurethane foam is considerably lost. It was. In addition, there was no generation of burrows due to bubbles, the machine feedability was good, the machine was fed smoothly, and the seam was straight. The peel resistance was high (see Table 1).

(比較例3)
評価サンプル:目付が10g/mのポリブチレンテレフタレート(PBT、平均繊維径3.5μm)100%からなるメルトブローン不織布の片面に、目付が30g/mで同一樹脂ポリブチレンテレフタレート(PBT、平均繊維径3.5μm)からなるメルトブローン不織布を熱エンボスにて熱圧着した2層積層体の不織布を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が15.3cc/cm/s、耐水圧(JIS−L1092)が325mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は13.5μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は48Nで、表面硬度の変化が10N以上であり、表面に発泡樹脂が浸透し、軟質ポリウレタンフォームの感触が失われて硬くなった。なお、気泡による巣穴の発生もなく、ミシン送り性は良く、スムーズに送れ、縫い目が直線であった。耐剥離性は、高かった(表1参照)。
(Comparative Example 3)
Evaluation sample: a basis weight of 10 g / m 2 of polybutylene terephthalate on one side of (PBT, average fiber diameter 3.5 [mu] m) meltblown nonwoven fabric made of 100 percent, basis weight same resin polybutylene terephthalate at 30g / m 2 (PBT, average fiber A two-layer nonwoven fabric obtained by thermocompression bonding of a meltblown nonwoven fabric having a diameter of 3.5 μm) by hot embossing was used.
As shown in Table 1, the measured values of this nonwoven fabric are as follows: air permeability (JIS-L1096) is 15.3 cc / cm 2 / s, water pressure resistance (JIS-L1092) is 325 mmH 2 O, and pore size (ASTMF) The average value of a porous material automatic pore measuring device based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 13.5 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded product was 48N, the change in surface hardness was 10N or more, the foamed resin penetrated the surface, and the soft polyurethane foam lost its feel and became hard. It was. In addition, there was no generation of burrows due to bubbles, the machine feedability was good, the machine was fed smoothly, and the seam was straight. The peel resistance was high (see Table 1).

(比較例4)
評価サンプル:目付が40g/mのポリブチレンテレフタレート(PBT、平均繊維径3.5μm)からなるメルトブローン不織布の単層品を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が20.8cc/cm/s、耐水圧(JIS−L1092)が254mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は14.5μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は47Nで、表面硬度の変化が10N以上であり、表面への発泡樹脂の浸透があり、軟質ポリウレタンフォームの感触が相当失われた。なお、気泡による巣穴の発生もなく、ミシン送り性は良く、スムーズに送れ、縫い目が直線であった。耐剥離性は、高かった(表1参照)。
(Comparative Example 4)
Evaluation sample: A single-layer product of a melt blown nonwoven fabric made of polybutylene terephthalate (PBT, average fiber diameter 3.5 μm) having a basis weight of 40 g / m 2 was used.
As shown in Table 1, the measured values of this nonwoven fabric are as follows: air permeability (JIS-L1096) is 20.8 cc / cm 2 / s, water pressure resistance (JIS-L1092) is 254 mmH 2 O, and pore size (ASTMF) The average value of a porous material automatic pore measuring apparatus based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 14.5 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded body is 47N, the change in surface hardness is 10N or more, the foamed resin penetrates the surface, and the feel of the flexible polyurethane foam is considerably lost. It was. In addition, there was no generation of burrows due to bubbles, the machine feedability was good, the machine was fed smoothly, and the seam was straight. The peel resistance was high (see Table 1).

(比較例5)
評価サンプル:目付が40g/mのポリプロピレンレン樹脂メルトブローン不織布(PP、平均繊維径3.0μm)の単層品を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が32.6cc/cm/s、耐水圧(JIS−L1092)が568mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は19.0μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。この際、通気度が高く評価サンプルが膨らみにくかった。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は46Nで、表面硬度の変化が10N以上であった。ミシン送り性は良く、スムーズに送れ、縫い目が直線であった。なお、気泡による巣穴の発生はなかった。耐剥離性は、高かった(表1参照)。
(Comparative Example 5)
Evaluation sample: A single-layer product of a polypropylene-lens resin meltblown nonwoven fabric (PP, average fiber diameter: 3.0 μm) having a basis weight of 40 g / m 2 was used.
As shown in Table 1, each measured value of this nonwoven fabric is 32.6 cc / cm 2 / s in air permeability (JIS-L1096), 568 mmH 2 O in water pressure resistance (JIS-L1092), and has a pore size (ASTMF). The average value of a porous material automatic pore measuring device based on a valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 19.0 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing. At this time, the air permeability was high and the evaluation sample was difficult to swell.
The average surface hardness (JIS K6400-2) of the obtained foamed molded product was 46N, and the change in surface hardness was 10N or more. The machine feedability was good, it could be fed smoothly and the seam was straight. Nest holes were not generated by bubbles. The peel resistance was high (see Table 1).

(比較例6)
評価サンプル:目付が45g/mのスチレン系エラストマー樹脂メルトブローン不織布(SEPS、平均繊維径3.0μm)の単層品を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が45.3cc/cm/s、耐水圧(JIS−L1092)が395mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は22.8μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は47Nで、表面硬度の変化が10N以上であり、表面に発泡樹脂が浸透し、軟質ポリウレタンフォームの感触が失われて硬くなった。また、通気度が高く評価サンプルが膨らみにくかった。ミシン送り性は、若干引っかかるが、縫い目は直線であった。耐剥離性は、中程度であった(表1参照)。
(Comparative Example 6)
Evaluation sample: A single-layer product of a styrene-based elastomer resin meltblown nonwoven fabric (SEPS, average fiber diameter: 3.0 μm) having a basis weight of 45 g / m 2 was used.
As shown in Table 1, each measured value of this nonwoven fabric is 45.3 cc / cm 2 / s in air permeability (JIS-L1096), 395 mmH 2 O in water pressure resistance (JIS-L1092), and has a pore size (ASTMF). The average value of a porous material automatic pore measuring apparatus based on the valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 22.8 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained foamed molded body is 47N, the change in surface hardness is 10N or more, the foamed resin penetrates the surface, the feel of the flexible polyurethane foam is lost, and it becomes hard It was. Moreover, the air permeability was high and the evaluation sample was difficult to swell. The machine feedability was slightly caught, but the seam was a straight line. The peel resistance was moderate (see Table 1).

(比較例7)
評価サンプル:目付が50g/mのポリウレタン樹脂メルトブローン不織布(PU、平均繊維径5.0μm)の単層品を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が51.5cc/cm/s、耐水圧(JIS−L1092)が383mmHOであり、ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)の平均値は26.4μmであった。
この不織布から得た評価サンプルの内部に発泡樹脂を注入ノズルから注入して発泡させ、硬化させることで評価サンプルと一体の発泡成形体を得た。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は50Nで、表面硬度の変化が10N以上であり、表面に発泡樹脂が浸透し、軟質ポリウレタンフォームの感触が失われて硬くなった。また、巣穴が発生し通気度が高く評価サンプルが膨らみにくく、ミシン送り性も悪く、成形性が劣った。また耐剥離性は低かった(表1参照)。
(Comparative Example 7)
Evaluation sample: A single layer product of polyurethane resin melt blown nonwoven fabric (PU, average fiber diameter 5.0 μm) having a basis weight of 50 g / m 2 was used.
As shown in Table 1, the measured values of this nonwoven fabric were 51.5 cc / cm 2 / s in air permeability (JIS-L1096), 383 mmH 2 O in water pressure resistance (JIS-L1092), and pore size (ASTMF) The average value of a porous material automatic pore measuring apparatus based on a valve point method of -361-80 (manufactured by Palm Porometer POROUS MATERIALS, INC.) Was 26.4 μm.
A foamed resin integrated with the evaluation sample was obtained by injecting a foamed resin into the evaluation sample obtained from the nonwoven fabric through an injection nozzle to cause foaming and curing.
The average surface hardness (JIS K6400-2) of the obtained molded foam is 50N, the change in surface hardness is 10N or more, the foamed resin penetrates the surface, and the soft polyurethane foam loses its feel and becomes hard. It was. Further, a burrow was generated, the air permeability was high, and the evaluation sample was difficult to swell, the sewing machine feedability was poor, and the moldability was poor. Moreover, the peel resistance was low (see Table 1).

(比較例8)
評価サンプル:不織布の代わりに目付が50g/mのポリウレタン樹脂フィルム(PU)を用いた。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は36Nで、表面硬度の変化が10N未満であり、表面への発泡樹脂の浸透はなかったが、巣穴が発生した。また、ミシン送り性も悪く、成形性が劣った。また耐剥離性は、低かった(表1参照)。
(Comparative Example 8)
Evaluation sample: A polyurethane resin film (PU) having a basis weight of 50 g / m 2 was used instead of the nonwoven fabric.
The average surface hardness (JIS K6400-2) of the obtained molded foam was 36N, the change in surface hardness was less than 10N, and there was no penetration of the foamed resin into the surface, but burrows were generated. Also, the machine feedability was poor and the moldability was poor. Moreover, the peel resistance was low (see Table 1).

(比較例9)
評価サンプル:目付が80g/mのポリエチレンテレフタレート樹脂スパンレース不織布(PET、平均繊維径15.0μm)の単層品を用いた。
この不織布の各測定値は、表1に示したように、通気度(JIS−L1096)が240.0cc/cm/sであった。なお、耐水圧(JIS−L1092)および平均ポアサイズ(ASTMF‐361‐80のバルブポイント法に基づく 多孔質材料自動細孔測定装置 パームポロメーター POROUS MATERIALS,INC.製 による)については測定不能であった。
得られた発泡成形体の表面硬度(JIS K6400−2)の平均は70Nで、表面硬度の変化が10N以上であり、表面に発泡樹脂が浸透し、軟質ポリウレタンフォームの感触が失われて非常に硬くなった。また、通気度が高く評価サンプルが膨らみにくかった。なお、気泡による巣穴の発生はなく、ミシン送り性は良く、スムーズに送れ、縫い目が直線であった。耐剥離性は、高かった(表1参照)。
(Comparative Example 9)
Evaluation sample: A single layer product of polyethylene terephthalate resin spunlace nonwoven fabric (PET, average fiber diameter 15.0 μm) having a basis weight of 80 g / m 2 was used.
As shown in Table 1, each measured value of this nonwoven fabric had an air permeability (JIS-L1096) of 240.0 cc / cm 2 / s. In addition, the water pressure resistance (JIS-L1092) and the average pore size (based on ASTMF-361-80 valve point method, porous material automatic pore measuring device Palm Porometer manufactured by POROUS MATERIALS, INC.) Could not be measured. .
The average surface hardness (JIS K6400-2) of the obtained foamed molded product is 70N, the change in surface hardness is 10N or more, the foamed resin penetrates the surface, and the feel of the flexible polyurethane foam is lost. It became hard. Moreover, the air permeability was high and the evaluation sample was difficult to swell. In addition, there was no generation | occurrence | production of the nest hole by the bubble, the sewing machine feedability was good, it was able to feed smoothly, and the seam was a straight line. The peel resistance was high (see Table 1).

Figure 2009154350
Figure 2009154350

この発明の表皮一体発泡成形用の表皮材の一実施の形態にかかる断面図である。It is sectional drawing concerning one Embodiment of the skin material for skin integral foam molding of this invention. この発明の表皮一体発泡成形用の表皮材の一実施の形態にかかる成形体の一例の車両用のヘッドレストの概略斜視図である。BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic perspective view of a vehicle headrest as an example of a molded body according to an embodiment of a skin material for integral foam molding of the present invention. この発明の表皮一体発泡成形用の表皮材の一実施の形態にかかる成形体の一例の車両用のヘッドレストの成形工程の概略断面図である。It is a schematic sectional drawing of the formation process of the headrest for vehicles of an example of the molded object concerning one Embodiment of the skin material for skin integrated foam molding of this invention.

符号の説明Explanation of symbols

10 表皮材
11 表生地
12 軟質ポリウレタンフォーム
13 不織布
20 ヘッドレスト(成形体)
21 インサート部品
30 成形装置
31 発泡型
32 注入ノズル
10 Skin material 11 Surface fabric 12 Flexible polyurethane foam 13 Non-woven fabric 20 Headrest (molded body)
21 Insert component 30 Molding device 31 Foaming mold 32 Injection nozzle

Claims (6)

成形体の外形状に縫製され内部に液状の発泡樹脂を注入して発泡させ一体とする表皮一体発泡成形用の表皮材であって、
成形体の外側に配置される表生地と、この表生地の内側に接着されるポリウレタンフォームと、このポリウレタンフォームの内側に接着され染み出し防止性および通気性を有する不織布とからなり、
この不織布の前記染み出し防止性が、耐水圧450mmHO以上であるとともに、前記通気性が、通気度0.1〜20cc/cm/sであり、平均ポアサイズが0.1〜20μmであることを特徴とする表皮一体発泡成形用の表皮材。
A skin material for integral skin foam molding that is sewn into the outer shape of a molded body and injects a liquid foam resin into the inside to foam and integrate.
It consists of a surface fabric disposed outside the molded body, a polyurethane foam adhered to the inside of the surface fabric, and a nonwoven fabric that adheres to the inside of the polyurethane foam and has anti-bleeding properties and breathability.
The non-permeability of the nonwoven fabric is a water pressure resistance of 450 mmH 2 O or more, the air permeability is an air permeability of 0.1 to 20 cc / cm 2 / s, and an average pore size is 0.1 to 20 μm. A skin material for integral foam molding of the skin.
前記不織布の平均繊維径が、0.1〜10μmであることを特徴とする請求項1記載の表皮一体発泡成形用の表皮材。   The skin material for skin-integrated foam molding according to claim 1, wherein the nonwoven fabric has an average fiber diameter of 0.1 to 10 µm. 前記不織布の目付が、30〜70g/mであることを特徴とする請求項1または2記載の表皮一体発泡成形用の表皮材。 The basis weight of the nonwoven fabric, according to claim 1 or 2 skin material for an integral skin foam molded according characterized in that it is a 30~70g / m 2. 前記不織布がメルトブロー製法により得られた不織布であることを特徴とする請求項1〜3いずれかに記載の表皮一体発泡成形用の表皮材。   The skin material for skin-integrated foam molding according to any one of claims 1 to 3, wherein the nonwoven fabric is a nonwoven fabric obtained by a melt blow manufacturing method. 前記不織布が、熱可塑性エラストマー樹脂からなる不織布の単層またはこれに他の樹脂からなる不織布を積層した複数層で構成されることを特徴とする請求項1〜4のいずれかに記載の表皮一体発泡成形用の表皮材。   The said nonwoven fabric is comprised by the multilayer which laminated | stacked the nonwoven fabric which consists of a single layer of the nonwoven fabric which consists of a thermoplastic elastomer resin, or another resin on this, The skin integrated body in any one of Claims 1-4 characterized by the above-mentioned. Skin material for foam molding. 前記不織布が、熱可塑性エラストマー樹脂からなる不織布の少なくとも一方面または両方面に、ポリブチレンテレフタレート樹脂からなる不織布を熱接着してなる2層または3層の積層体で構成されることを特徴とする請求項1〜5のいずれかに記載の表皮一体発泡成形用の表皮材。   The nonwoven fabric is composed of a two-layer or three-layer laminate formed by thermally bonding a nonwoven fabric made of polybutylene terephthalate resin to at least one surface or both surfaces of a nonwoven fabric made of a thermoplastic elastomer resin. The skin material for skin integral foam molding in any one of Claims 1-5.
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PCT/JP2008/073397 WO2009081927A1 (en) 2007-12-26 2008-12-24 Upholstery material for forming integrated-foam upholstery
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