JP2009096743A - Hair-dyeing agent composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a hair-dyeing agent composition that exhibits an excellent hair-dyeing property, particularly an excellent effect of suppressing dyeing of scalp, and to provide a hair-dyeing agent composition that is excellent in the prevention of hair damage, conditioning effects and stability. <P>SOLUTION: The hair-dyeing agent composition comprises a first agent comprising at least an oxidative dye and an alkali agent and a second agent comprising an oxidizing agent, wherein the first agent and/or the second agent contains one or two or more selected from among polyethylene glycol, isoprene glycol and triethylene glycol and the content thereof is 7-15 mass% at the time when the composition is used (when the two agents are mixed). <P>COPYRIGHT: (C)2009,JPO&amp;INPIT

Description

  The present invention relates to a hair dye composition that is excellent in hair dyeing properties and particularly excellent in the effect of suppressing dyeing of the scalp. Furthermore, it is related with the hair dye composition excellent also in hair damage, a conditioning effect, and stability.

  At the time of hair dyeing, the mixed drug solution may adhere to the scalp and dye not only the hair but also the scalp.

  In order to prevent staining of the scalp, for example, by combining a specific silicone compound, a method for preventing dripping of the chemical solution (see Patent Document 1), a method for performing a pretreatment step with metal ions (see Patent Document 2), Skin dyeing by blending a method using reaction heat at the time of mixing (see Patent Document 3), chlorxylenol or chlorobutanol (see Patent Document 4), a specific amount of ascorbic acid (see Patent Documents 5 to 8), etc. A method for preventing wear is disclosed.

  In addition, it has been found that the combination of ascorbic acid and polyethylene glycol (see Patent Document 8) and the combination of α-olefin oligomer and polyethylene glycol (see Patent Document 9) suppress the dyeing property of the scalp. However, it has not been recognized that the effect of suppressing scalp dyeing is manifested only with a specific amount of polyethylene glycol.

In acidic hair dyes, it has been found that the removal of skin dyeing is improved when polyethylene glycol is contained (see Patent Document 10), but the recognition that the oxidation hair dye suppresses scalp dyeing is recognized. It has not been.
JP-A-3-127721 JP-A-6-48926 JP 2000-86471 A Japanese Patent Laid-Open No. 10-167937 JP 2002-29946 A JP 2003-40747 JP 2005-53876 A JP-A-2005-53877 JP 2003-95900 A JP 2001-172140 A

  Although all of the above prior arts have been improved as hair dye compositions, they have excellent hair dyeing properties, and have not been sufficiently exerted particularly in the effect of suppressing scalp dyeing.

  As a result of intensive studies to achieve the above object, the hair dye composition can be used in a hair dyeing composition by using a specific amount of one or more selected from polyethylene glycol, isoprene glycol, and triethylene glycol. It has been found that it is excellent and in particular can suppress the scalp dyeing.

That is, claim 1 of the present invention comprises a first agent containing at least an oxidation dye and an alkali agent and a second agent containing an oxidizing agent, and polyethylene glycol and isoprene glycol are contained in the first agent and / or the second agent. A hair dye composition comprising one or more selected from triethylene glycol and having a content of 7 to 15% by mass when used (during mixing).

  Moreover, Claim 2 of this invention is a hair dye composition characterized by mix | blending 1 type, or 2 or more types chosen from polyethyleneglycol, isopreneglycol, and triethyleneglycol in a 1st agent.

  The hair dye composition of the present invention is excellent in hair dyeing properties, and can particularly suppress dyeing of the scalp. Furthermore, it is excellent in hair damage, conditioning effect and stability.

Hereinafter, the configuration of the present invention will be described in detail.
The polyethylene glycol used in the present invention preferably has an average molecular weight of 190 to 1050 in view of the scalp dyeing inhibitory effect, the stability of the composition, and the feel during use. Specifically, polyethylene glycol 200 (average molecular weight 190-210), polyethylene glycol 300 (average molecular weight 280-320), polyethylene glycol 400 (average molecular weight 380-420), polyethylene glycol 600 (average molecular weight 570-630) and polyethylene Glycol 1000 (average molecular weight 950-1050) is applicable.

  The isoprene glycol used in the present invention is also called 3-methyl-1,3-butanediol, and is represented by the following general formula (1).

(Chemical formula 1)
(CH ₃ ) ₂ C (OH) C ₂ H ₄ OH (1)

  The triethylene glycol used in the present invention is represented by the following general formula (2).

(Chemical formula 2)
H (OC ₂ H ₄ ) ₃ OH (2)

  The polyethylene glycol, isoprene glycol, and triethylene glycol can be contained singly or in combination, and the content thereof is 7 to 15% by mass at the time of use (mixing), more preferably 10 to 13% by mass. %. If the content is less than 7% by mass, the effect of suppressing dyeing of the scalp is not exerted. Therefore, the content is preferably 7% by mass or more, and if it exceeds 15% by mass, stickiness and the like occur when applied to the hair. The following is preferred.

In the hair dye composition of the present invention, 5-aminoorthocresol, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, 1-amino-4-methylaminoanthraquinone, 3, 3'-iminodiphenol, 2,4-diaminophenoxyethanol hydrochloride, 2,4-diaminophenol hydrochloride, toluene-2,5-diamine hydrochloride, nitroparaphenylenediamine hydrochloride, paraphenylenediamine hydrochloride, N-phenylparaphenylenediamine hydrochloride , Metaphenylenediamine hydrochloride, orthoaminophenol, N-phenylparaphenylenediamine acetate, 1,4-diaminoanthraquinone, 2,6-diaminopyridine, 1,5-dihydroxynaphthalene, toluene-2,5-diamine, toluene-3 , 4-diamine, nitroparaf Enylenediamine, paraaminophenol, paranitroorthophenylenediamine, paraphenylenediamine, paramethylaminophenol, picramic acid, sodium picrate, N, N-bis (4-aminophenyl) -2,5-diamino-1,4-quinonediimine 5- (2-hydroxyethylamino) -2-methylphenol, N-phenylparaphenylenediamine, metaaminophenol, metaphenylenediamine, 5-aminoorthocresol sulfate, 2-amino-5-nitrophenol sulfate, orthosulfate Aminophenol, orthochloroparaphenylenediamine sulfate, 4,4'-diaminodiphenylamine sulfate, 2,4-diaminophenol sulfate, toluene-2,5-diamine sulfate, nitroparaphenylenediamine sulfate, parasulfate sulfate Aminophenol, paranitroorthophenylenediamine sulfate, paranitrometaphenylenediamine sulfate, paraphenylenediamine sulfate, paramethylaminophenol sulfate, N, N-bis (2-hydroxyethyl) paraphenylenediamine sulfate, metaaminophenol sulfate, sulfuric acid Metaphenylenediamine, catechol, diphenylamine, α-naphthol, hydroquinone, pyrogallol, phloroglucin, gallic acid, resorcin, and the like can be blended.

  These oxidation dyes may be used alone or in combination of two or more, and the blending amount thereof is preferably 0.001 to 10% by mass, and 0.01 to 5% by mass in use. More preferably it is.

  Further, the hair dye composition of the present invention may contain a direct dye, and examples thereof include an acid dye, a nitro dye, a disperse dye, and a basic dye.

  Examples of the acid dye include Blue No. 1, Purple No. 401, Black No. 401, Orange No. 205, Red No. 227, Red No. 106, Yellow No. 203, and Acid Orange 3. Nitro dyes include 2-nitro-paraphenylenediamine, 2-amino-6-chloro-4-nitrophenol, 3-nitro-parahydroxyethylaminophenol, 4-nitro-orthophenylenediamine, 4-amino-3- Nitrophenol, 4-hydroxypropylamino-3-nitrophenol, HC Blue No. 2, HC Orange No. 1, HC Red No. 1, HC Yellow No. 2, HC Yellow No. 1 4. HC Yellow No. 4 5, HC Red No. 3, N, N-bis (2-hydroxyethyl) -2-nitroparaphenylenediamine, 4-nitrometaphenylenediamine and the like, or salts thereof such as sulfates and hydrochlorides. Examples of the disperse dye include disperse purple 1, disperse blue 1, and disperse black 9. Examples of basic dyes include basic blue 99, basic brown 16, basic brown 17, basic red 76, basic red 51, basic yellow 57, basic yellow 87, basic orange 31 and the like.

  Two or more direct dyes may be used in combination, and the blending amount thereof is preferably 0.001 to 5% by mass, particularly preferably 0.01 to 3% by mass when used.

  In the hair dye composition of the present invention, ammonia and a salt thereof (ammonium chloride, ammonium carbonate, ammonium hydrogen carbonate, etc.), monoethanolamine, diethanolamine, triethanolamine, isopropanolamine, 2-amino-2- Examples thereof include alkanolamines such as methylpropanol and 2-aminobutanol or salts thereof, carbonates such as guanidine carbonate, sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate, and the like.

  Two or more alkali agents may be used in combination, and the content thereof is preferably 0.05 to 15% by mass, more preferably 0.1 to 10% by mass.

  The second agent of the hair dye composition of the present invention contains an oxidizing agent, such as hydrogen peroxide, sodium perborate, ammonium perborate, potassium perborate, sodium percarbonate, percarbonate. Examples thereof include potassium, sodium bromate, urea peroxide, melamine peroxide and the like, and hydrogen peroxide is particularly preferable. You may use the said oxidizing agent 1 type or in mixture of 2 or more types.

  The pH of the hair dye composition of the present invention is preferably 8 to 12 for the first agent and 2 to 5 for the second agent. The pH at the time of use (during mixing) is from the point of hair dyeing effect and skin irritation, 8-11 are preferable.

  As the pH adjuster, in addition to the above-mentioned alkaline agents, inorganic acids such as hydrochloric acid and phosphoric acid, organic acids such as citric acid, glycolic acid and lactic acid, hydrochlorides such as ammonium chloride and monoethanolamine hydrochloride, diphosphate phosphate Examples thereof include phosphates such as monopotassium hydrogen and disodium monohydrogen phosphate.

  The hair dye composition of the present invention preferably contains one or more higher alcohols in the first agent and the second agent from the viewpoint of improving touch and stability. These have the effect of forming a structure with a surfactant to prevent separation and improving the feel during rinsing. As the higher alcohol, those having 8 to 22 carbon atoms, particularly 16 to 22 carbon atoms are preferable, and specific examples include cetyl alcohol, stearyl alcohol, behenyl alcohol, oleyl alcohol, and the like, and mixtures thereof. In particular, cetyl alcohol is preferable in terms of touch.

  Two or more types of higher alcohols may be used in combination, and the content thereof is preferably 0.01 to 25% by mass, particularly 0.1 to 20% by mass, for each of the first agent and the second agent.

  The hair dye composition of the present invention preferably further contains basic amino acids for the purpose of preventing hair damage. Examples of basic amino acids include arginine, histidine, lysine and the like. Examples of amino acid salts include hydrochlorides and acidic amino acid salts. Arginine or a salt thereof is particularly preferable. These basic amino acids or salts thereof can be used alone or in combination of two or more. The content of these amino acids is preferably 0.001 to 0.5% by mass, particularly 0.05 to 0.3% by mass when used (mixed).

  The hair dye composition of the present invention preferably further contains amphoteric polymers in order to impart an excellent usability. Examples of amphoteric polymers include monochloroacetic acid amphoteric products of dialkylaminoethyl methacrylate / methacrylic acid alkyl ester copolymers (trade names: Yucaformer 301, AM-75, SM [manufactured by Mitsubishi Chemical Corporation], etc.), hydroxy acrylate Propyl / butylaminoethyl methacrylate / acrylic acid octylamide copolymer (trade name: Amphomer 28-4910, LV-71 [manufactured by National Starch Co., Ltd.]), dimethyldiallylammonium chloride / acrylic acid copolymer, dimethyl chloride Diallylammonium / acrylic acid / acrylamide copolymer, methacrylamidopropyltrimethylammonium chloride / acrylic acid / methyl acrylate copolymer (trade names: Marquat 280, 295, 3330, 3331, 2001 [Ondeo Naru Etc.], and the like, dimethyldiallylammonium chloride / acrylic acid copolymer, dimethyldiallylammonium chloride / acrylic acid / acrylamide copolymer, methacrylamidopropyltrimethylammonium chloride / acrylic acid / methyl acrylate copolymer In particular, dimethyldiallylammonium chloride / acrylic acid copolymer is preferred, and among them, dimethyldiallylammonium chloride and acrylic acid in a mass ratio of 95: 5 to 80:20 are preferred.

  The hair dye composition of the present invention preferably further contains silicones in order to impart an excellent usability. Examples of silicones include polysiloxanes (dimethylpolysiloxane, methylphenylpolysiloxane, etc.), modified silicones (amino-modified silicone, fluorine-modified silicone, alcohol-modified silicone, polyoxyalkylene-modified silicone, epoxy-modified silicone, alkyl-modified silicone, Fatty acid-modified silicone, alkyl-modified silicone, acrylic-modified silicone, perfluoroalkyl polyoxyalkylene-modified silicone, etc.) and cyclic polysiloxane.

In the composition of the present invention, water and, if necessary, an organic solvent are used as a medium.
Examples of organic solvents include lower alkanols such as ethanol and 2-propanol, aromatic alcohols such as benzyl alcohol and benzyloxyethanol, polyols such as propylene glycol, 1,3-butanediol, diethylene glycol, and glycerin, ethyl cellosolve, Examples thereof include cellosolves such as butyl cellosolve, and carbitols such as ethyl carbitol and butyl carbitol.

  In the hair dye composition of the present invention, in addition to the essential components described above, optional components that are usually used can be used as long as they do not impair the effects of the present invention. These components include anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, higher alcohols, higher fatty acids, hydrocarbons, waxes, ester oils, vegetable oils, UV absorbers , Preservatives, moisturizers, polyhydric alcohols, anionic polymers, cationic polymers, nonionic polymers, polymers, amino acid derivatives, sugar derivatives, animal and plant derivatives, animal and plant extracts, flavors, thickeners, vitamins UV absorbers, colorants, sequestering agents, antioxidants, and the like.

  The hair dye composition of this invention is not specifically limited, The thing of various dosage forms becomes object. For example, a two-component type in which a first agent containing an oxidizing dye and an alkaline agent and a second agent containing an oxidizing agent are used in combination, or the aforementioned first agent, second agent and persulfates as active ingredients. Examples include a three-agent type using a third agent or a third agent not containing persulfates as an active ingredient. Further, the mixing ratio when two or more types are used is not particularly limited as long as there is no inconvenience in the effects of the present invention.

  EXAMPLES Next, although this invention is demonstrated in detail based on an Example, it is not limited to this. A compounding amount is a mass percentage (%) unless otherwise specified.

  The hair dye composition shown in “Table 1” was prepared by a conventional method, and the following evaluation was performed.

(1) Skin Dyeability Test The first agent prepared based on the Examples and Comparative Examples and the second agent containing the following oxidizing agent were mixed at a ratio of 1: 1, and the arms of 20 subjects were mixed. Apply to the inner part in a circle with a diameter of about 1 cm. After leaving for 20 minutes, it was rinsed off with warm water. Next, it was lightly rubbed with a finger for 1 minute using soap and rinsed with warm water. The degree of dyeing of each panel on the skin was visually observed and judged according to the following evaluation criteria.

Second agent mass%
Hydrogen peroxide solution (35%) 16.0
Cetyl alcohol 3.0
Stearyl alcohol 3.0
Liquid paraffin 5.0
Sodium lauryl sulfate 1.0
Polyoxyethylene (5.5) cetyl ether 5.0
Sodium stannate 0.1
Hydroxyethane diphosphonic acid 0.1
Sodium pyrophosphate pH 3 amount 100% with purified water.

Criteria for evaluating skin staining ○: Good 15 or more subjects with almost no skin staining Δ: Normal 5 to 15 subjects with little skin staining ×: Poor 5 subjects with little skin staining Less than one person

(2) Dyeing test 40 g of the first agent prepared based on Examples and Comparative Examples is added to 40 mL of the second agent containing the following oxidizing agent and shaken and mixed, and the mixture is applied to a hair bundle of 30 g of white hair. The plate was allowed to stand at room temperature for 20 minutes, washed, and air-dried. About each hair | bristle bundle, the dyeing | staining state was observed visually by 20 test subjects. The evaluation criteria are as follows.

Dyeability evaluation criteria ○: Good 15 or more subjects who answered that dyeability was good Δ: Normal 5 or more subjects who answered that dyeability was good Less than 15 people ×: Poor 5 subjects who answered that dyeability was good Less than one person

(3) Sensory test (hair damage / smoothness)
Using the hair bundles subjected to the dyeing test, 20 subjects evaluated the feel of hair damage, smoothness, etc. by palpation. The criteria for evaluation are as follows.

Hair damage evaluation criteria ○: Good 15 or more subjects who answered that the hair was not damaged △: Normal 7 or more subjects who said that the hair was not damaged ×: Bad The hair was not damaged Less than 7 subjects

Evaluation criteria for smoothness ○: 15 or more subjects who answered that it was smooth △: Normal 7 or more subjects who answered that it was smooth ×: Less than 7 subjects who answered that it was smooth

(4) Stability test The 1st agent prepared based on the Example and the comparative example was preserve | saved for one month in a 50 degreeC thermostat. It observed visually and judged by the following evaluation criteria.

Stability evaluation criteria ○: Good Component separation / aggregation not observed Δ: Normal Component aggregation slightly observed but not separated ×: Poor separation observed

Examples 1-16, Comparative Examples 1-7

  From the above results, it can be seen that the hair dye compositions shown in the examples constituting the present invention are excellent in hair dyeing properties, and particularly excellent in the effect of suppressing scalp dyeing. It can also be seen that the hair damage, conditioning effect and stability are also excellent. On the other hand, the hair dye composition shown in the comparative example lacking the constitution of the present invention was inferior to the examples in any evaluation and could not achieve the object of the present invention.

  The hair dye composition 2nd agent shown in "Table 2" was adjusted by the conventional method, and the above-mentioned evaluation was performed. In addition, the comparative example 7 was used for the hair dye composition 1st agent used for evaluation.

Examples 17-19, Comparative Examples 8-13

  From the above results, it can be seen that the hair dye compositions shown in the examples constituting the present invention are excellent in hair dyeing properties, and particularly excellent in the effect of suppressing scalp dyeing. It can also be seen that the hair damage, conditioning effect and stability are also excellent. On the other hand, the hair dye composition shown in the comparative example lacking the constitution of the present invention was inferior to the examples in any evaluation and could not achieve the object of the present invention.

  Hereinafter, other formulation examples of the hair dye composition of the present invention will be given as examples.

Example 20
First agent mass%
Polyethylene glycol 600 20.0
Paraphenylenediamine 0.7
Metaaminophenol 0.1
Resorcin 0.7
HC Red No. 3 0.1
Monoethanolamine 4.0
Ammonium bicarbonate 1.5
Ammonium chloride 1.0
Cetyl alcohol 2.5
Stearyl alcohol 2.5
Behenyl alcohol 1.5
L-Arginine 0.5
Dimethyldiallylammonium chloride / acrylic acid copolymer liquid (trade name: Marcote 280 [manufactured by Ondeo Narco)] 3.0
Highly polymerized silicone emulsion (trade name: KM-902
[Shin-Etsu Chemical Co., Ltd.] 1.0
Aminopolyether-modified silicone emulsion (trade name:
SILSTYLE 401 [Toray Dow Corning]] 0.5
Liquid paraffin 0.5
Vaseline 1.0
Polyoxyethylene (10) cetyl ether 1.0
Polyoxyethylene (25) lauryl ether 1.0
Sodium cetyl sulfate 0.5
Beeslow 0.5
Octyldodecanol 1.0
Sodium sulfite 0.4
L-ascorbic acid sulfate disodium salt 0.01
Sodium ascorbate 0.2
Edetate disodium 0.2
Glycine 0.01
L-alanine 0.01
L-proline 0.01
Olive oil 0.1
Wheat hydrolyzate (trade name: GLUADIN W20
[Cognis Co., Ltd.]) 1.0
Vegetable squalane 0.1
Cationized honey derivative (trade name: Honeycoat 50 [manufactured by ARCH)] 0.1
Fennel extract (trade name: NAB Fennel
Seed Extract [manufactured by ARCH]] 0.1
Gallica rose extract (trade name: Phytofullur
French Rose [manufactured by CRODAROM] 0.1
Tokinsengka extract (trade name: Organic Tokinsengka extract BG-50 [manufactured by Koei Kogyo Co., Ltd.]) 0.1
Jojoba extract (trade name: jojoba leaf extract [manufactured by Koei Kogyo Co., Ltd.]) 0.1
Kagii Baranori Extract (Brand name: BIOSTRUCTURER [manufactured by SECMA]) 0.1
Fragrance 0.8
Purified water residue

  A first agent was prepared with the formulation described in Example 20. As a result, the pH was 9.5. When the 2nd agent containing the oxidizing agent used for evaluation of the said Examples 1-16 and Comparative Examples 1-7 was mixed in the ratio of 1: 1, the liquid mixture of pH 8.5 was obtained. When this liquid mixture was used, it was excellent in dyeing | staining property of hair, and it had the characteristic excellent in the effect which suppresses dyeing | staining of a scalp especially. Furthermore, it was excellent in hair damage, conditioning effect, and stability.

Example 21
First agent mass%
Isoprene glycol 20.0
Paraphenylenediamine 0.7
Metaaminophenol 0.1
Resorcin 0.7
Strong ammonia water 6.0
Ammonium chloride 1.0
Cetyl alcohol 4.0
Stearyl alcohol 4.0
L-lysine hydrochloride 0.5
Dimethyldiallylammonium chloride / acrylic acid copolymer liquid (trade name: Marcote 295 [manufactured by Ondeo Narco)] 1.5
Highly polymerized methylpolysiloxane (100,000 mm ² / s) 2.0
Methyl polysiloxane (5,000 mm ² / s) 0.5
Methyl polysiloxane (10 mm ² / s) 3.0
Methylphenylpolysiloxane (trade name: SH-556
[Toray Dow Corning]] 0.5
Isopropyl isostearate 0.8
White beeswax 0.5
Sodium cetyl sulfate 0.9
Polyoxyethylene (5.5) cetyl ether 0.5
Polyoxyethylene (30) cetyl ether 1.0
Ammonium thioglycolate solution (50% solution) 0.6
Hydroxyethanediphosphonic acid tetrasodium 0.1
Soy protein hydrolyzate (trade name: Promois WS
[Made by Seiwa Kasei Co., Ltd.]) 0.5
Hydrolyzed silk liquid (trade name: Promois silk-1000
[Made by Seiwa Kasei Co., Ltd.]) 0.5
Water-soluble collagen solution (3) (trade name: Neptigen N
[Ichimaru Falcos] 0.1)
D-pantothenyl alcohol 0.1
Monoammonium glycyrrhizinate 0.01
Horsetail extract (trade name: Horsetail extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.1
Usvenia oyster extract (Brand name: Usvenia oyster extract BG
[Maruzen Pharmaceutical Co., Ltd.] 0.1
Kawara mugwort extract (Brand name: Inchinkou extract BG
[Maruzen Pharmaceutical Co., Ltd.] 0.1
Shobu Root Extract (trade name: Shobu Extract [Maruzen Pharmaceutical Co., Ltd.]) 0.1
Yukinoshita Extract (trade name: Yukinoshita Extract BG
[Maruzen Pharmaceutical Co., Ltd.] 0.1
Soybean extract (trade name: Soybean extract BG
[Maruzen Pharmaceutical Co., Ltd.] 0.1
Carrot extract (trade name: carrot extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.1
Murasaki assembly extract (trade name: Murasaki assembly extract [Maruzen Pharmaceutical Co., Ltd.]) 0.1
Alkyl glucoside (trade name: APG600 [manufactured by Cognis)] 1.0
Fragrance 0.5
Purified water residue

  A first agent was prepared with the formulation described in Example 21. As a result, the pH was 10.8. When the second agent containing the oxidizing agent used in the evaluation of Examples 1 to 16 and Comparative Examples 1 to 7 was mixed at a ratio of 1: 1, a mixed solution having a pH of 9.7 was obtained. When this liquid mixture was used, it was excellent in dyeing | staining property of hair, and it had the characteristic excellent in the effect which suppresses dyeing | staining of a scalp especially. Furthermore, it was excellent in hair damage, conditioning effect, and stability.

Example 22
First agent mass%
Triethylene glycol 20.0
Paraphenylenediamine 0.7
Metaaminophenol 0.1
Resorcin 0.7
Monoethanolamine 7.0
Guanidine carbonate 2.0
Cetanol 6.0
L-Arginine 1.0
Dimethyldiallylammonium chloride / acrylic acid copolymer liquid (trade name: Marcote 3330 [manufactured by Ondeo Narco)] 3.0
Linear high-polymerization polyether-modified silicone (trade name:
FZ-2250 [Toray Dow Corning Co., Ltd.]) 1.0
Methylcyclopolysiloxane (trade name: DC246 Fluid)
[Toray Dow Corning]] 1.0
Liquid paraffin 0.5
Vaseline 1.0
Polyoxyethylene (5.5) cetyl ether 1.0
Polyoxyethylene (25) lauryl ether 1.0
Sodium cetyl sulfate 0.5
Ammonium thioglycolate solution (50% solution) 0.6
Edetate tetrasodium 0.1
Dimer acid dilinoleic acid (phytosteryl / isostearyl /
Cetyl / stearyl / behenyl) (trade name: Plandool
-H [Nippon Seika Co., Ltd.]) 0.2
Hydrolyzed collagen solution (trade name: Promois W-32MR
[Made by Seiwa Kasei Co., Ltd.]) 0.5
Royal Jelly Extract (trade name: Royal Jelly Extract BG
[Maruzen Pharmaceutical Co., Ltd.] 0.1
N-lauroyl-L-glutamate di (phytosteryl
2-octyldodecyl) (Brand name: El Dew PS-203)
[Ajinomoto Co.] 0.1
Hydrolyzed conchiolin solution (trade name: pearl protein extract [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.5
Honey 0.1
Trimethylglycine 0.3
Sericin 0.1
Linden extract (trade name: Linden extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.1
Phenoxyethanol 0.2
Fragrance 0.3
Purified water residue

Third agent mass%
Burdock extract (Brand name: Burdock extract BG [Maruzen Pharmaceutical Co., Ltd.]) 1.0
Hydrolyzed wheat liquid (trade name: Promois WG [manufactured by Seiwa Kasei Co., Ltd.]) 5.0
Chanoki extract (trade name: Oolong tea extract BG
[Maruzen Pharmaceutical Co., Ltd.] 1.0
Horsetail extract (trade name: Horsetail extract (Maruzen Pharmaceutical Co., Ltd.)) 1.0
Glycerin residue

  A first agent and a third agent were prepared with the composition described in Example 22. As a result, the pH of the first agent was 11.0. When the 1st agent: 2nd agent: 3rd agent was mixed in the ratio of 10: 10: 1 using the 2nd agent containing the oxidizing agent used for evaluation of the said Examples 1-16 and Comparative Examples 1-7 , PH 9.8 mixture was obtained. When this liquid mixture was used, it was excellent in dyeing | staining property of hair, and it had the characteristic excellent in the effect which suppresses dyeing | staining of a scalp especially. Furthermore, it was excellent in hair damage, conditioning effect, and stability.

  In addition, the composition of the fragrance | flavor used in the said Examples 20-22 is shown in Table 3.

The hair dye composition of the present invention is excellent in hair dyeability, and in particular, can supply a hair dye composition excellent in the effect of suppressing scalp dyeing. Furthermore, hair damage, conditioning effect,
It is possible to supply a hair dye composition having excellent stability.

Claims (2)

It consists of a first agent containing at least an oxidative dye and an alkali agent and a second agent containing an oxidant, and one or more selected from polyethylene glycol, isoprene glycol and triethylene glycol in the first agent and / or the second agent A hair dye composition comprising two or more kinds, and a content of 7 to 15% by mass when used (mixed). A hair dye composition comprising one or more selected from polyethylene glycol, isoprene glycol and triethylene glycol in the first agent.