JP2005239627A - Hairdye composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a hairdye composition having good dye affinity, and imparting very superior gloss-imparting effects, and moist and excellent conditioning effects to the hair after being dyed. <P>SOLUTION: The hairdye composition is composed of a first agent containing an alkali agent and a second agent containing an oxidant, and the first agent and/or the second agent contain heavy liquid isoparaffin. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to a hair dye composition, and in particular, a hair dye composition having good dyeability and a very excellent gloss-imparting effect and moist excellent conditioning effect on hair after dyeing. About. In the present invention, the hair dye composition includes a decoloring agent when it does not contain an oxidation dye.

  Conventionally, combinations of specific oxidation dyes with silicone, protein hydrolyzate, etc. have been proposed to obtain a glossy finish after hair dyeing (for example, see Patent Documents 1 and 2). Therefore, the color width that gives gloss is limited, and it is difficult to exhibit the characteristics with a wide color width.

  In addition, light isoparaffins in hair dyes are proposed as components that can reduce the blending amount of alkaline agents blended in one agent and reduce irritating odors (see, for example, Patent Documents 3, 4, and 5). However, when blended with heavy liquid isoparaffin in the hair dye, it is not known to improve the dyeability and to have a very excellent gloss and moisturizing conditioning effect on the hair. It was.

JP 2002-226338 A JP 2002-226339 A JP 2001-2538 A JP 2003-95901 A JP 2003-221319 A

  In the above circumstances, the object of the present invention is to provide a hair dye composition that has good dyeability and gives a very excellent glossing effect and moist excellent conditioning effect to hair after dyeing. It is to provide.

  As a result of earnest research to achieve the object of the present invention, the present inventors have found that the hair dye composition described below has good dyeability and has a very excellent gloss imparting effect on the hair after hair dyeing. The present invention was completed by finding that it provides a moist and excellent conditioning effect.

  Namely, a hair dye composition comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent, wherein the first agent and / or the second agent contains heavy fluid isoparaffin. It is.

According to the present invention, it is possible to provide a hair dye composition which has good dyeability and gives a very excellent gloss imparting effect and moist excellent conditioning effect to hair after dyeing.

  Hereinafter, the configuration of the present invention will be described in detail.

  The heavy liquid isoparaffin used in the present invention is also called hydrogenated polyisobutene, and is a mixture of hydrocarbons having side chains obtained by copolymerizing isobutene and n-butene and then hydrogenating. The average molecular weight is preferably about 700 to 3000, and if the average molecular weight is less than 700, the intended gloss imparting effect or conditioning effect is not exhibited, and if it exceeds 3000, the finish may be sticky. Specific examples include Pearl Ream 18, 24, 46, Polybis 10SH (manufactured by NOF Corporation) and the like.

  The concentration of the heavy liquid isoparaffin is 0.05 to 5% by mass, preferably 0.1 to 2.5% by mass when used. If it is less than 0.05% by mass, the desired gloss imparting effect and conditioning effect may not be obtained, and if it exceeds 5% by mass, the finish may be sticky.

  In the hair dye composition of the present invention, 5-aminoorthocresol, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, 1-amino-4-methylaminoanthraquinone, 3, 3'-iminodiphenol, 2,4-diaminophenoxyethanol hydrochloride, 2,4-diaminophenol hydrochloride, toluene-2,5-diamine hydrochloride, nitroparaphenylenediamine hydrochloride, paraphenylenediamine hydrochloride, N-phenylparaphenylenediamine hydrochloride , Metaphenylenediamine hydrochloride, orthoaminophenol, N-phenylparaphenylenediamine acetate, 1,4-diaminoanthraquinone, 2,6-diaminopyridine, 1,5-dihydroxynaphthalene, toluene-2,5-diamine, toluene-3 , 4-diamine, nitropara Enylenediamine, paraaminophenol, paranitroorthophenylenediamine, paraphenylenediamine, paramethylaminophenol, picramic acid, sodium picrate, N, N-bis (4-aminophenyl) -2,5-diamino-1,4-quinonediimine 5- (2-hydroxyethylamino) -2-methylphenol, N-phenylparaphenylenediamine, metaaminophenol, metaphenylenediamine, 5-aminoorthocresol sulfate, 2-amino-5-nitrophenol sulfate, orthosulfate Aminophenol, orthochloroparaphenylenediamine sulfate, 4,4′-diaminodiphenylamine sulfate, 2,4-diaminophenol sulfate, toluene-2,5-diamine sulfate, nitroparaphenylenediamine sulfate, sulfuric acid Laaminophenol, paranitroorthophenylenediamine sulfate, paranitrometaphenylenediamine sulfate, paraphenylenediamine sulfate, paramethylaminophenol sulfate, N, N-bis (2-hydroxyethyl) paraphenylenediamine sulfate, metaaminophenol sulfate, Metaphenylenediamine sulfate, catechol, diphenylamine, α-naphthol, hydroquinone, pyrogallol, phloroglucin, gallic acid, resorcin, and the like can be blended. These oxidation dyes may be used singly or in combination of two or more, and the blending amount may not provide a sufficient hair dyeing effect when the concentration at the time of use is less than 0.001% by mass. In addition, since the dyeability cannot be improved even when the content exceeds 10% by mass, the concentration during use is preferably 0.001 to 10% by mass, and more preferably 0.01 to 5% by mass. preferable.

  A well-known thing can be widely used for the hair dye composition of this invention, without specifically limiting as an oxidizing agent. For example, hydrogen peroxide, persulfate, perborate, bromate, periodate, urea peroxide, etc., for example, sodium hydrogen peroxide, ammonium peroxide, potassium peroxide, perborate Examples thereof include sodium acid, ammonium perborate, potassium perborate, sodium percarbonate, sodium bromate and the like. You may use the said oxidizing agent 1 type or in mixture of 2 or more types.

  The hair dye composition of the present invention includes other alkaline agents, hydrocarbons, waxes, animal and vegetable oils and fats, cationic polymers, anionic polymers, amphoteric polymers, and nonionic substances as long as the effects of the present invention are not impaired. Polymers, higher alcohols, higher fatty acids, lower alcohols, organic solvents or penetration enhancers, polyhydric alcohols, esters, ethers, silicones, anionic surfactants, cationic surfactants, amphoteric surfactants Agents, nonionic surfactants, preservatives, chelating agents, stabilizers, antioxidants, pH adjusters, animal and plant-derived protein hydrolysates, amino acids, various plant extracts, herbal extracts, vitamins, It is possible to mix | blend a pigment | dye, a fragrance | flavor, a pigment, a ultraviolet absorber, etc. suitably.

  The hair dye composition of this invention is not specifically limited, The thing of various dosage forms becomes object. For example, a two-agent type using a combination of a first agent containing an alkaline agent and a second agent containing an oxidizing agent, or a third agent comprising the above-mentioned first agent, second agent and persulfate as active ingredients Or the 3 agent type | mold etc. which use in combination with the 3rd agent which does not contain a persulfate as an active ingredient are mentioned. In addition, the mixing ratio in the case of using two or more types is not particularly limited as long as there is no inconvenience in the feeling of use, dyeability, sagging or usability which are the effects of the present invention.

  Hereinafter, the present invention will be specifically described with reference to examples, but the present invention is not limited thereto. Prior to the examples, the evaluation methods used in the examples will be described.

(1) Dyeing test 40 g of the first agent prepared based on Examples and Comparative Examples is added to 40 mL of the second agent containing the following oxidizing agent, and mixed by shaking, and the mixture is applied to a hair bundle of 30 g of white hair. Then, it was allowed to stand at room temperature for 30 minutes, washed, and air-dried. About each hair | bristle bundle, the dyeing | staining state was observed visually by 20 test subjects. The evaluation criteria are as follows.

Emulsion second agent mass%
Hydrogen peroxide solution (35%) 16.0
Cetanol 1.2
Sodium cetyl sulfate 0.15
Isopropyl isostearate 0.15
Polyoxyethylene (5.5) cetyl ether 0.1
Polyoxyethylene (30) cetyl ether 0.2
Beeswax 0.1
Phenacetin 0.05
Hydroxyethane diphosphonic acid 0.1
Edetate disodium 0.05
Sodium pyrophosphate pH 3 amount 100% with purified water.

Dyeability evaluation criteria ○: Good 15 or more subjects who answered that dyeability was good △: Normal 5 or more subjects who answered that dyeability was good X: Poor 5 subjects who answered that dyeability was good Less than one person

(2) Sensory test (glossy, moist feeling)
Using the hair bundles subjected to the dyeing test, the gloss was visually evaluated by 20 subjects, and the moist feeling was evaluated by palpation. The criteria for evaluation are as follows.

Evaluation criteria for gloss: ○: 15 or more subjects who answered that there is gloss △: Normal 7 or more subjects who said that there was gloss ×: Less than 7 subjects who said that there was bad gloss

Moisture Evaluation Criteria ○: 15 or more subjects who responded that they were moist △: Normal 7 or more subjects who responded that they were moist ×: Poor 7 subjects who answered that they were moist Less than one person

  The hair dye compositions of Examples 1 to 4 and Comparative Examples 1 to 3 were prepared and the test was performed. Table 1 shows the respective compositions and test results. The unit of prescription in the table is all mass%.

  As is apparent from Table 1, the hair dye composition of the present invention has good dyeability, and has an excellent effect of imparting gloss to the hair after dyeing and an excellent conditioning effect that is moist. It was recognized that On the other hand, Comparative Examples 1 to 3 were inferior in any of the characteristics of dyeability, gloss imparting effect and moist and excellent conditioning effect, and the object of the present invention could not be achieved.

Example 5 (bleaching agent)
・ First agent mass%
Heavy liquid isoparaffin (trade name: Pearl Ream 18 [Nippon Yushi Co., Ltd.]) 2.0
Monoethanolamine 4.0
Ammonium bicarbonate 1.5
Strong ammonia water 5.0
Ammonium chloride 1.0
Cetanol 4.5
Paraffin 0.5
Vaseline 1.0
Polyoxyethylene (12) cetyl ether 1.0
Polyoxyethylene (25) lauryl ether 1.0
Sodium cetyl sulfate 0.1
Beeslow 0.5
Oleyl alcohol 1.0
Octyldodecanol 1.0
Propylene glycol 10.0
Oleic acid 0.3
Edetate disodium 0.2
Glycine 0.01
L-alanine 0.01
L-proline 0.01
Dimethyldiallylammonium chloride / acrylic acid copolymer liquid
(Product name: Marcote 280 [Naruco Co., Ltd.]) 1.0
Camellia oil 0.1
Wheat hydrolyzate (trade name: GLUADIN WLM [manufactured by Cognis)] 1.0
Vegetable squalane 0.1
Cationized honey derivatives
(Product name: Honeycoat 50 [manufactured by ARCH)] 0.1
Fennel extract (trade name: NAB Fennel
Seed Extract [manufactured by ARCH]] 0.1
Gallica rose extract (trade name: Phytofullur
French Rose [manufactured by CRODAROM] 0.1
Tokakinka extract (trade name: Organic
Tokinkinka extract BG-50 [manufactured by Koei Kogyo Co., Ltd.]) 0.1
Jojoba extract (trade name: jojoba leaf extract [manufactured by Koei Kogyo Co., Ltd.]) 0.1
Yukinoshita extract
(Product name: Yukinoshita Extract BG [Maruzen Pharmaceutical Co., Ltd.]) 0.1
Kagii Baranori Extract
(Product name: BIOSTRUCTURER [manufactured by SECMA]) 0.1
Fragrance 0.8
Purified water residue

・ 3rd agent mass%
Ammonium persulfate 25.0
Potassium persulfate 7.5
Sodium persulfate 20.0
Anhydrous sodium metasilicate 20.0
Silica anhydride 10.0
Sodium silicate 11.0
Sodium stearate 2.0
Sodium lauryl sulfate 2.0
Guar gum 1.0
Carboxymethylcellulose 1.0
Liquid paraffin 0.5

  A first bleaching agent and a third bleaching agent were prepared with the composition described in Example 5. As a result, the first bleaching agent had a viscosity of 15000 mPa · s and a pH of 12.0. When the first agent, the second agent and the third agent were mixed at a ratio of 3: 6: 2 using the emulsion second agent (viscosity 1500 mPa · s), the viscosity at the time of mixing was 6000 mPa · s and pH 10.8. A mixture was obtained. When this mixed solution was used, it was confirmed that the dyeing property was good and that the hair was excellent in terms of moisturizing effect and moisturizing effect.

Example 6 (hair dye)
・ First agent mass%
Heavy liquid isoparaffin (trade name: Polybis 10SH [manufactured by NOF Corporation)] 1.0
Monoethanolamine 2.0
Strong ammonia water 3.5
Cetanol 7.0
Paraffin 0.5
Vaseline 1.0
Beeslow 0.5
Vegetable squalane 0.1
Sodium cetyl sulfate 0.2
Polyoxyethylene (12) cetyl ether 1.0
Polyoxyethylene (25) lauryl ether 1.5
Propylene glycol 9.0
Paraphenylenediamine 0.6
Paraaminophenol 0.5
Metaaminophenol 0.1
Ammonium thioglycolate solution (50% solution) 0.4
Sodium sulfite 0.1
L-ascorbic acid sulfate disodium salt 0.01
Sodium ascorbate 0.2
Hydroxyethanediphosphonic acid tetrasodium 0.2
Glycine 0.01
L-proline 0.01
L-alanine 0.01
Dimethyldiallylammonium chloride / acrylic acid copolymer liquid
(Product name: Marcote 280 [manufactured by Nalco]) 1.5
Olive oil 0.1
Highly polymerized methylpolysiloxane 0.5
Soy protein hydrolyzate (trade name: Promois WS [manufactured by Seiwa Kasei Co., Ltd.]) 0.1
Hydrolyzed silk liquid (trade name: Promois silk-1000 [manufactured by Seiwa Kasei Co., Ltd.]) 0.1
Water-soluble collagen solution (3) (trade name: Neptigen N [manufactured by Ichimaru Falcos]) 0.01
D-pantothenyl alcohol 0.1
Monoammonium glycyrrhizinate 0.01
Horsetail extract (trade name: Horsetail extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.1
Usvenia oyster extract (Brand name: Usvenia oyster extract BG
[Maruzen Pharmaceutical Co., Ltd.] 0.1
Kawara mugwort extract (Brand name: Inchinkou extract BG
[Maruzen Pharmaceutical Co., Ltd.] 0.1
Shobu root extract (trade name: Shobu extract [Maruzen Pharmaceutical Co., Ltd.]) 0.1
Yukinoshita extract (trade name: Yukinoshita extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.1
Soybean extract (trade name: Soybean extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.1
Carrot extract (trade name: carrot extract BG [manufactured by Maruzen Pharmaceutical Co., Ltd.]) 0.1
Purple extract (Product name: Purple extract)
[Maruzen Pharmaceutical Co., Ltd.] 0.1
Alkyl glucoside (trade name: APG600 [manufactured by Cognis Co., Ltd.]) 1.0
Royal jelly extract (trade name: Royal jelly extract [Maruzen Pharmaceutical Co., Ltd.]) 0.1
Fragrance 0.5
Purified water residue

・ Second agent mass%
Hydrogen peroxide solution (35%) 16.0
Cetanol 6.0
Liquid paraffin 4.0
Polyoxyethylene (5.5) cetyl ether 5.0
Sodium lauryl sulfate 1.0
Edetate disodium 0.1
Phenacetin 0.1
Tartaric acid 0.1
Sodium pyrophosphate pH 3 amount of purified water

  When a hair dye was prepared with the composition described in Example 6, a first agent having a viscosity of 20000 mPa · s and a pH of 9.8 and a second agent having a viscosity of 10,000 mPa · s were obtained. When the first agent and the second agent were mixed at a ratio of 1: 1, a mixed solution having a viscosity of 15000 mPa · s and a pH of 9.3 was obtained. When this mixture is used, it has a good odor at the time of use, good dyeability, and an excellent conditioning effect that is very moisturizing and moisturizing after hair dyeing. Was recognized.

In addition, the fragrance | flavor used by said prescription is the following.

  According to the present invention, it is possible to provide a hair dye composition which has good dyeability and gives a very excellent gloss imparting effect and moist excellent conditioning effect to hair after dyeing.

Claims (1)

A hair dye composition comprising a first agent containing an alkaline agent and a second agent containing an oxidizing agent, wherein the first agent and / or the second agent contains heavy fluid isoparaffin.