JPH08268848A - Hair oxidizing and dyeing agent composition - Google Patents

Abstract

PURPOSE: To obtain a composition having excellent extensibility, coating property, level dyeing property and dyeing property without drop-falling from head hair in hair dyeing treatment and having a hair damage inhibiting effect in hair dyeing. CONSTITUTION: This composition contains a sugar derivative expressed by the general formula (A is a residue removed n-pieces of hydroxyl group from the sugar; R is an 18-32C fatty acid; (n)>=1), a humectant component selected from a group of a polyhydric alcohol, sugars, mucopolysaccharides, an NMF component, charonic acid, choresteryl-12-hydroxystearate and a bile acid salt and an oxidizing dye. The sugar derivative is a branched aliphatic ether sugar and/or a branched aliphatic glycoside or a maltose isostearylether and/or isostearyl glycoside. The humectant component is an oxidant-containing polyhydric alcohol. The objective composition is a multiagents type and contains a sugar derivative, a humectant component, an oxidizing dye and an oxidant in blending.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to improvements in hair dye compositions, especially oxidative hair dye compositions.

[0002]

2. Description of the Related Art Oxidative hair dyes are the most widely used permanent hair dyes. The oxidation dye in the hair dye penetrates into the hair, undergoes oxidative polymerization, and develops color to cause hair to grow. The feature is that the hair dyeing effect lasts because it is chemically dyed.
As the formulation of the oxidative hair dye, the first agent containing the oxidative dye,
Most of the two-component type is used by mixing with a second agent containing an oxidant at the time of use, but there is also a one-component type used as a powder formulation by mixing with water at the time of use, or a multi-component type of three or more agents.

In any case, the oxidative hair dye chemically dyes hair by an oxidative polymerization reaction. This oxidative polymerization is a fairly vigorous reaction, and uneven application of the oxidative hair dye to the hair may cause uneven dyeing. In order to eliminate this uneven coloring, when the hair dye composition is applied to the hair, various solvents, dispersion media, etc. are added to the oxidative hair dye composition so that it has high fluidity. It was provided in liquid form.

[0004]

However, in such a liquid having high fluidity, the hair dye drips from the hair during or after the hair dyeing treatment, and adheres to the skin or clothes or flows down the face. There was such a problem as On the other hand, if an attempt is made to increase the viscosity of the hair dye by using a thickener or the like so that the hair dye does not sag, the conventional thickener is poor in the spreadability, coatability, and levelness of the oxidative hair dye on the hair. Further, there is a problem that the dyeing property is deteriorated because the thickener inhibits the permeability of the oxidation dye into the hair.

Further, the hair dyeing with an oxidative hair dye has a problem that the hair is easily damaged, the hair after dyeing is liable to be cut or split ends, and dryness occurs. .

The present invention has been made in view of the above problems of the prior art, and its object is extensibility, coatability, etc. even though the hair dye does not drip during the hair dyeing treatment. Is excellent in usability, has no uneven dyeing and is excellent in levelness, and the dyeing property of the oxidative dye is not impaired, and further, there is little hair damage at the time of dyeing, and it has an effect of preventing dryness. An object is to provide an oxidative hair dye composition.

[0007]

Means for Solving the Problems As a result of intensive studies for achieving the above-mentioned object, the present inventors have found that the above-mentioned problems can be solved by adding a certain sugar derivative and a moisturizing component to an oxidative hair dye. Found to be resolved. That is, the oxidative hair dye composition according to claim 1 of the present invention comprises a sugar derivative represented by the general formula 4, a polyhydric alcohol, a saccharide, and a mucopolysaccharide,
It is characterized by containing an oxidative dye and a moisturizing component selected from the group consisting of NMF component, caronic acid, cholesteryl-12-hydroxystearate and bile salt.

[Chemical 4] (In the formula, A is a residue obtained by removing n hydroxyl groups from sugar, R is
Represents a fatty chain having a total carbon number of 18 to 32 and having a branched chain, and n represents 1 or more. )

The oxidative hair dye composition according to claim 2 is characterized in that, in the oxidative hair dye composition according to claim 1, the sugar derivative is a branched aliphatic glycoside represented by the general formula 5. To do.

Embedded image (However, in the formula, A is a residue obtained by removing a hemiacetal hydroxyl group from a sugar, and R is the same as the above Chemical formula 4.)

The oxidative hair dye composition according to claim 3 is characterized in that, in the oxidative hair dye composition according to claim 1, the sugar derivative is a sugar-branched aliphatic ether represented by the general formula (6). And

[Chemical 6] (However, in the formula, A is a residue obtained by removing n non-hemiacetal hydroxyl groups from a sugar, and R and n are the same as those in the above chemical formula 4.)

The oxidative hair dye composition according to claim 4 is characterized in that, in the oxidative hair dye composition according to claim 1 or 2, the sugar derivative is isostearyl maltoside.
The oxidative hair dye composition according to claim 5 is the oxidative hair dye composition according to claim 1 or 3, wherein the sugar derivative is maltitol isostearyl ether. The oxidative hair dye composition according to claim 6 is the oxidative hair dye composition according to claims 1 to 5, wherein the moisturizing component has a molecular weight of 10
It is characterized by being a polyhydric alcohol selected from polyethylene glycol of 0 to 1000, propylene glycol, dipropylene glycol, glycerin, diglycerin and 1,3-butylene glycol. The oxidative hair dye composition according to claim 7 is characterized in that, in the oxidative hair dye composition according to claims 1 to 6, an oxidant is contained. The oxidative hair dye composition according to claim 8 is a composition according to claims 1 to 7.
The oxidative hair dye composition described is of a multi-dose type, and when mixed,
It is characterized by containing a sugar derivative, a moisturizing component, an oxidizing dye, and an oxidizing agent.

The structure of the present invention will be described in detail below. First, in the present invention, the sugar derivative is a compound in which the hydroxyl group of the sugar is alkylated with a branched aliphatic hydrocarbon group, and in particular, the hemiacetal hydroxyl group of the sugar and the branched aliphatic hydrocarbon group form a glycosidic bond. Branched aliphatic glycosides and other hydroxyl groups (called non-hemiacetal hydroxyl groups)
An ether-bonded product of a branched aliphatic hydrocarbon group and a branched aliphatic hydrocarbon group is called a sugar branched aliphatic ether. The hemiacetal hydroxyl group refers to one hydroxyl group of hemiacetal produced when a sugar forms a cyclic structure.

The branched aliphatic glycoside used in the present invention is represented by the above general formula 5, wherein A is a residue obtained by removing a hemiacetal hydroxyl group from a sugar, and such a sugar is glucose. , Galactose, xylose, fructose, altrose, talose, mannose, arabinose, idose, lyxose, ribose, monosaccharides and mixtures thereof such as allose, maltose, isomaltose, lactose, xylobiose, kentiobiose,
Cordiobiose, cellobiose, sophorose, nigerose, sucrose, melibiose, laminaribiose,
Examples thereof include disaccharides such as rutinose and mixtures thereof, trisaccharides such as maltotriose and mixtures thereof, or higher polysaccharides, polymers of monosaccharides, and mixtures of these saccharides.

The sugar-branched aliphatic ether used in the present invention is represented by the above-mentioned general formula 6, wherein A is a residue obtained by removing n non-hemiacetal hydroxyl groups from sugar,
Examples of such sugars include sugar alcohols such as maltitol, sorbitol, erythritol, mannitol, galactitol, glucitol, inositol, maltotriitol, maltotetriitol, and mixtures thereof. In addition, n represents the average number of branched fatty chains bonded to one sugar molecule.

In any of the general formulas, R is an aliphatic chain having a branched chain and has a total carbon number of 18 to 32. Specific examples of the branched chain include, for example, methyl group, ethyl group, propyl group,
Isopropyl group, butyl group, pentyl group, hexyl group,
Heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group,
Examples thereof include a heptadecyl group, a hexadecyl group, a heptadecyl group and further higher fatty chains. The position and number of such branched chains are not particularly limited. Specific examples of R include 2-decyltetradecyl group, 2-tetradecyloctadecyl group, isostearyl group, isomyristyl group, 2,7-dimethylhexadecyl group, tetrahydrageranyl group, 2,7-dimethyloctadecyl group. Etc., but it is not particularly limited as long as it has a branched chain and has a total carbon number of 18 to 32. When R is a linear fatty chain or the total number of carbon atoms of R is less than 18, the thickening effect is not sufficiently exhibited, and when the total number of carbon atoms is greater than 32, the hydrophobicity becomes high and water Solubility is poor and it becomes difficult to use in water.

The sugar derivatives according to the present invention are all known substances, and the branched aliphatic glycoside represented by the general formula 5 is, for example, the acid catalyst for sugar modification described in JP-A-63-84637. In addition to the synthesizing method using the same, it is possible to synthesize by using the reaction generally used for glycosylation (König-Knol reaction, Helferreich method, or other ether exchange method).

On the other hand, the sugar-branched aliphatic ether represented by the general formula 6 can be obtained by, for example, the method of Robert et al. (Tetrahedro).
n, 35 , 2169-2172 (1979)). That is, the sugar is dissolved in a non-aqueous solvent such as dimethylformamide or dimethylsulfoxide, and the compound represented by the following general formula 7 is added to the solution to give a solution in the presence of a catalyst.
It is obtained by reacting at 0 to 130 ° C.

Embedded image (wherein, X is a halogen salt of a hydroxyl group or a halogen group or a trialkylammonium group such as trimethylammonium bromide, and R is the same as in the above Chemical Formula 6).

Two or more sugar derivatives can be used in the oxidative hair dye composition of the present invention. For example, a mixture of sugar-branched aliphatic ether or a branched fatty chain of a branched aliphatic glycoside or a kind of sugar, and in the sugar-branched aliphatic ether, a mixture of sugar derivatives different in the number of bonded branched fatty chains or the bonding position may be used. Of course, a mixture of a sugar-branched aliphatic ether and a branched aliphatic glycoside may be used.

Examples of the moisturizing component used in combination with the sugar derivative in the present invention include the following. (1) Polyhydric alcohol, for example, a molecular weight of 100 to 1000
Polyethylene glycol, propylene glycol, dipropylene glycol, glycerin, diglycerin,
1,3-butylene glycol, etc. (2) Sugars, for example, sorbitol, mannitol, maltitol, xylitol, etc. (3) Mucopolysaccharides, for example, hyaluronic acid, chondroitin sulfate, mucoitin sulfate, etc. (4) NMF components, for example dl- Na pyrrolidonecarboxylate, Na lactate, etc. (5) Others, for example, cholesteryl-12-hydroxystearate, caronic acid, bile salts, etc. In the present invention, one kind or two or more kinds thereof can be arbitrarily used. . Among these moisturizing components, (1) polyhydric alcohol is preferable in the present invention.

Examples of the oxidative dyes used in the oxidative hair dye composition of the present invention include phenylenediamines, aminophenols, toluylenediamines, aminonitrophenols, diphenylamines, diaminophenylamines and N-. Examples thereof include phenylphenylenediamines, diaminopyridines, resorcin, pyrogallol, catechol, aminocresols and salts thereof. The blending amount of the oxidative dye is not particularly limited as long as it is within the range generally used for oxidative hair dyes. In the present invention,
In general, a color tone adjusting agent that changes a color tone in combination with an oxidative dye as a main agent is also included in the oxidative dye of the present invention.

Since the oxidative hair dye composition according to the present invention contains the above-mentioned sugar derivative, it has an appropriate viscosity so that it does not drip or flow, and it can be applied to hair quickly and evenly. Also has the effect of being uniform.
In addition, the sugar derivative according to the present invention does not inhibit the oxidation dye from penetrating into the hair and being dyed, so that good dyeability can be obtained. Further, the sugar derivative of the present invention is characterized in that it is stable without being decomposed even in an acid or an alkali, has no sensitizing property or irritating property even when incorporated into a hair dye composition, and is excellent in safety.

The hair dye composition may contain lower alcohols such as ethanol and isopropanol. When a surfactant is used as a thickener in such a system, the thickening effect is remarkably reduced. Therefore, it is necessary to add a large amount of a surfactant, and problems such as irritation and inhibition of dyeing property tend to occur. If the sugar derivative according to the present invention is used, a thickening effect can be obtained with a small amount even in such a system. In the oxidative hair dye composition of the present invention, the blending amount of the sugar derivative is not particularly limited as long as the effects of the present invention can be obtained, and the blending amount can be appropriately adjusted and used. It is 0.5 to 60% by weight, preferably 1 to 15% by weight.

Further, in the oxidative hair dye composition of the present invention, by using a moisturizing component together with the above-mentioned sugar derivative, damage to the hair during hair dyeing treatment is extremely small, and split ends, cut hairs and the like are produced. The effect of being difficult can be obtained at the same time. If the moisturizing component is not used in combination, such a hair damage preventing effect cannot be obtained. The amount of the moisturizing component blended in the oxidative hair dye composition of the present invention is 0.01 to 20.0% by weight of the entire composition. If it is less than 0.01% by weight, the desired effect cannot be obtained, and if it is used in excess of 20.0% by weight, the effect cannot be expected to increase.

The oxidative hair dye composition according to the present invention may take any one-form or multi-form of two or more parts. For example, 2
In the dosage form, a two-part composition containing a first derivative containing a sugar derivative, a moisturizing component and an oxidative dye and a second agent containing an oxidizer, which is used by mixing at the time of use, and a saccharide derivative and an oxidative dye A two-part composition in which the first agent to be used and the second agent containing a moisturizing component and an oxidizing agent are mixed and used at the time of use is preferable. The mixing ratio of the first agent and the second agent is usually a weight ratio of the first agent: the second agent =
The ratio is often 1: 1 but is not particularly limited as long as there is no inconvenience in dripping, usability and leveling property. Examples of the oxidizing agent used in the present invention include hydrogen peroxide, persulfate, perborate, bromate, periodate, and urea peroxide.

The oxidative hair dye composition of the present invention may contain other components usually used in hair dyes as long as the effects of the present invention are not impaired. For example, the components usually added to the first agent include lanolin, squalane, liquid paraffin, petrolatum, higher fatty acids, triglycerides,
Examples thereof include oily components such as ester oils, silicones such as methylphenyl polysiloxane, dimethyl siloxane / methyl (polyoxyethylene) siloxane copolymer, rubbery dimethyl polysiloxane, and amino-modified polysiloxane.

In addition, antioxidants and stabilizers such as thioglycolate, L-ascorbate, bisulfite, hydrosulfite, bisulfate, collagen hydrolyzate, keratin hydrolyzate and silk protein. Protein hydrolyzate such as hydrolyzate, elastin hydrolyzate, soybean protein hydrolyzate and the like, and quaternary products thereof, ammonia water, alkanolamine, ammonium carbonate, sodium hydrogen carbonate, and an alkali agent such as potassium hydroxide are added. It is also possible.

It is also possible to use other amphipathic substances and surfactants as the emulsifier. Examples of nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene polyhydric alcohol fatty acid partial esters, polyoxyethylene hydrogenated castor oil derivatives, and other polyoxyethylene-based surfactants, octylpolyether. Alkyl polyglycosides such as glycosides, polyglycerin fatty acid esters, polyglycerin-based surfactants such as polyglycerin alkyl ethers, maltitol hydroxyalkyl ethers, sugar alcohol ethers such as sorbitol alkyl ethers, fatty acid diethanolamides, and the like, Anions such as higher fatty acid salts, alkylbenzene sulfonates, phosphoric acid esters, alkyl sulfates, alkyl sulfate ester salts, and polyoxyethylene alkyl sulfate ester salts Surfactants, amino acids, alkyl trimethyl ammonium salt, dialkyl dimethyl ammonium salts, alkyl cationic surfactants dimethylamine oxide, and the like, other surfactants can be appropriately used in combination.

Further, for example, ethanol, butanol,
Lower alcohols such as propanol and isopropanol, 2-ethylhexyl alcohol, 2-hexyldecyl alcohol, 2-decyltetradecyl alcohol, isostearyl alcohol, cetostearyl alcohol,
Higher alcohols such as lauryl alcohol, stearyl alcohol and cetyl alcohol, benzyl alcohol and the like can be added.

Examples of the sequestering agents and preservatives include hydroxyethanediphosphonates, phenacetin, EDTA and its salts, parabens, stannates, and the like. Polymer compounds include poly (dimethylallylammonium ammonium). (Halide) type cationic polymer, polyethylene glycol, epichlorohydrin, propyleneamine and cocoylamine obtained from a condensation product type of tallowylamine obtained from tallow fatty acid, a cationic polymer, polyethylene glycol, epichlorohydrin, propyleneamine and coconut oil fatty acid The condensation polymer type cationic polymer, vinylpyrrolidone, dimethylaminomethacrylate copolymer type cationic polymer, quaternary nitrogen-containing cellulose ether type cationic polymer and the like can be mentioned.

Also, lauric acid diethanolamide, carboxymethyl cellulose, carboxy vinyl polymer, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, xanthan gum, carrageenan, alginate, pectin, phaseran, gum arabic, gut gum, karaya gum, tragacanth gum, agar powder, bentonite. Further, a thickener such as a crosslinkable polyacrylic acid salt can also be used in combination as long as the effect of the present invention is not impaired. Others, pH adjusters, fragrances, drugs,
A colorant, water, etc. can be appropriately added.

Examples of components to be added to the second agent include phenacetin, EDTA and salts thereof, parabens,
Sequestrants such as stannates and preservatives, higher grades such as 2-ethylhexyl alcohol, 2-hexyldecyl alcohol, 2-decyltetradecyl alcohol, isostearyl alcohol, cetostearyl alcohol, lauryl alcohol, stearyl alcohol, cetyl alcohol Alcohols, polyoxyethylene alkyl ethers, alkyl sulfate salts, surfactants such as acylmethyl taurines, organic acids such as citric acid, malic acid, acetic acid, lactic acid, oxalic acid, tartaric acid, formic acid, levulinic acid, Examples thereof include acids such as inorganic acids such as phosphoric acid and hydrochloric acid, pH adjusting agents, fragrances, drugs, coloring agents, water and the like.

[0031]

EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited thereto. In addition, the compounding amounts are all represented by weight%. Prior to the examples, the test method used in each example will be described.

[Hair Dyeing Test] Hair of 10 panelists was dyed with each test hair dye composition, and the hair fell down during hair dyeing, spreadability / applicability to hair, and even dyeability. Was relatively evaluated. The evaluation criteria are as follows. <Evaluation of dripping> ◎: No dripping, no dripping ○: Almost no dripping, dripping △: Dripping, dripping ×: Dripping, dripping is severe

<Evaluation of extensibility and coatability> ◎: Very good elongation and easy application ○: Fairly good elongation and easy application Δ: Not very good elongation and difficult application ×: Poor extension , Uneven coating <Evaluation of level dyeing ability> ◎: Evenly dyed well ○: Almost uniformly dyed △: Some dyeing unevenness was found ×: Dyeing unevenness was created

[Hair Damage Test] A set of 12 human hair bundles each having a length of 6 cm and having a length of 6 cm was taken from human hair mixed with white hair, and the test hair dye composition was sufficiently applied to the human hair bundle for 15 minutes at 30 ° C. The hair was dyed, washed with water, and dried. The stress I when the human hair bundle was extended by 20% was measured before dyeing (I ₁ ) and after dyeing (I ₀ ) respectively, and from the obtained hair intensity ratio (I ₁ / I ₀ ),
The hair damage prevention effect, the moist feeling after dyeing, and the smoothness were evaluated as follows. A hair strength ratio closer to 1 indicates less hair damage.

<Evaluation of hair damage prevention effect> ⊚: Hair strength ratio is 0.9 or more ○: Hair strength ratio is 0.8 or more and less than 0.9 Δ: Hair strength ratio is 0.6 or more and less than 0.7 × : Hair strength ratio is less than 0.6 <Evaluation of moisturizing> ◎: Very moist feeling ○: Moisturizing feeling △: Slightly moisturizing ×: Moisturizing <Evaluation of smoothness> ◎: Very moisturizing Yes ○: Smooth △: Slightly stiff ×: Stiff

Formulation Examples 1 and 2, Comparative Examples 1 and 2 First, Emalex O which is a conventionally used thickener.
A hair dyeing test was conducted using P-5 as a comparative example. [Preparation of Hair Dye Composition] 1) Preparation of First Agent Using the samples shown in Table 1, a first agent was prepared according to a conventional method according to the following formulation. <Formulation> First agent Isopropanol 5.0 wt% Sample (see Table 1) 1.0 to 26.0 Ammonium thioglycolate 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Ammonia water 6.0 Paraphenylenediamine 1.0 Resorcin 1.0 Fragrance Suitable amount Ion-exchanged water Residual

[0037]

[Table 1] ──────────────────────────────────── Test materials (blending amount) ──── ──────────────────────────────── Formulation 1 Maltitol monoisostearyl ether (5.0 wt%) + 1, 3-Butylene glycol (1.0 wt%) Formulation example 2 Isostearyl maltoside (5.0 wt%) + 1,3-butylene glycol (1.0 wt%) Comparative example 1 Emarex OP-5 * (25.0 wt%) ) Comparative Example 2 Emarex OP-5 * (25.0 wt%) + 1,3-butylene glycol (1.0 wt%) ────────────────────── ─────────────── * POE (5) Octyl phenyl ether, manufactured by Nippon Emulsion Co., Ltd.

2) Preparation of Second Agent Next, a transparent liquid second agent a is prepared by a conventional method according to the formulation shown in Table 2 below.
And a cream liquid second agent b were prepared.

[Table 2] ──────────────────────────────────── 2nd agent component a (transparent liquid) b (cream liquid) ──────────────────────────────────── Hydrogen peroxide 30% 15.0 15 0.0 Phosphate buffer solution Adjusted to pH 3 Adjusted to pH 3 Methylparaben 0.1 0.1 Sodium stannate 0.1 0.1 Liquid paraffin-5.0 Stearyl alcohol-3.0 Sodium lauryl sulfate-0.5 POE (20 ) Cetyl ether − 0.5 Ion-exchanged water Residual residue ─────────────────────────────────────

[Hair Dyeing Test] An oxidative hair dye composition obtained by mixing the respective first agents of the above-mentioned formulation examples 1 and 2 and comparative examples 1 and 2 with each second agent in a weight ratio of 1: 1. Was used to carry out a hair dyeing test. Table 3 shows the properties before and after mixing and the results of the hair dyeing test.

[Table 3] ──────────────────────────────────── 1st agent 2nd agent Properties Dripping extension Uniformity Before mixing After mixing ・ Applicability ──────────────────────────────────── Formulation example 1 a Gel-like gel-like ◎ ◎ ◎ ◎ Blending example 2 a Gel-like gel-like ◎ ◎ ◎ ◎ Comparative example 1 a Liquid liquid × ○ × Comparative example 2 a Liquid liquid × ○ × ───────────── ─────────────────────── Blending example 1 b Gel-like gel-like ◎ ◎ ◎ ◎ Blending example 2 b Gel-like gel-like ◎ ◎ ◎ ◎ Comparative example 1 b Liquid Liquid × ○ × Comparative Example 2b Liquid Liquid × ○ × ─────────────────────────────────────

As can be seen from Table 3, the first agent (formulation examples 1 and 2) in which the sugar derivative and the moisturizing component (1,3-butylene glycol) are used in combination is a gel and is mixed with any second agent. While it was still in the form of a gel after that, the first agent (Comparative Example 1) using the conventional thickener (Emarex OP-5) or the first agent (Comparative Example) in which a moisturizing component was used in combination therewith The liquid 2) was liquid and remained liquid after mixing with the second agent, which was difficult to mix and was likely to be non-uniform. In the hair dyeing test, the oxidative hair dye compositions using the first agent of Formulation Examples 1 and 2 did not drip or run off, and the extensibility / applicability to hair was good, and It had excellent dyeability. In contrast,
Since the mixtures of Comparative Examples 1 and 2 using the conventional thickeners are liquid, there are problems such as dripping and runoff, and poor levelness.

Comparative Examples 3 to 5 The first agent (Comparative Example 3) in which only the sugar derivative or the moisturizing component was blended in the same formulation as in the Formulation Examples 1 and 2 using the samples of Table 4
To 5) were prepared, and the second agents were mixed in a weight ratio of 1: 1 to prepare an oxidative hair dye composition.

[Table 4] ──────────────────────────────────── 1st agent Reagent (blending amount) ─ ─────────────────────────────────── Comparative Example 3 Maltitol monoisostearyl ether (5.0 wt%) Comparative Example 4 Isostearyl maltoside (5.0 wt%) Comparative Example 5 1,3-butylene glycol (1.0 wt%) ─────────────────────── ──────────────

Properties of the hair dye compositions using the first agent of Comparative Examples 3 to 5 and the hair dye compositions using the above Formulation Examples 1 and 2,
Table 5 shows a comparison of the results of the hair dyeing test and the hair damage test.

[Table 5] ──────────────────────────────────── 1st agent 2nd agent Properties Drip extension Properties Level dyeing Hair damage (after mixing) ・ Prevention of application ───────────────────────────────────── Formulation Example 1 a Gel-like ◎ ◎ ◎ ◎ ◎ Formulation Example 2 a Gel-like ◎ ◎ ◎ ◎ ◎ Comparative Example 3 a Gel-like ◎ ◎ ◎ ○ △ Comparative Example 4 a Gel-like ◎ ◎ ○ △ Comparative Example 5 a Liquid × △ × ○ ─ ─────────────────────────────────── Mixing example 1 b Gel ◎ ◎ ◎ ◎ ◎ Mixing example 2 b Gel Condition ◎ ◎ ◎ ◎ ◎ Comparative Example 3 b Gel ◎ ◎ ◎ △ Comparative Example 4 b Gel ◎ ◎ ◎ ○ △ Comparative Example 5 b Liquid x △ × ○ ───────────────── ────────────────────

As can be seen from Table 5, when the sugar derivative and the moisturizing component (1,3-butylene glycol) were used in combination (Formulation Examples 1 and 2), gel hair dye compositions were obtained,
It does not drip, and has good spreadability / applicability to hair and level dyeability. Also, there is very little hair damage. On the other hand, when the sugar derivative alone is blended (Comparative Examples 3 to 4), the hair damage preventing effect is poor, and when only the moisturizing component (1,3-butylene glycol) is blended (Comparative Example 5). Although there was little hair damage, the obtained hair dye composition was in a liquid state, and all of the evaluations of sagging in the hair dyeing test, spreadability / applicability, and levelness were extremely poor. From the above, it is understood that the effects of the present invention are obtained when the sugar derivative and the moisturizing component are used in combination.

Formulation Examples 3 to 5 and Comparative Examples 6 to 8 Using the samples of Table 6, a first agent was prepared in the same formulation as in the formulation examples 1 and 2, and the weight ratio of each of the second agents was 1: 1. To obtain an oxidative hair dye composition.

[Table 6] ──────────────────────────────────── Mixing example Mixing example Mixing example Comparative example Comparative example Comparative Example Sample 3 4 5 6 7 8 ──────────────────────────────────── Isostearyl maltoside 8.0 − − − − − Maltitol Isostearyl Ether − 8.0 − − − − 2-Tetradecyl Octadecyl Maltosit − − 8.0 − − − Stearyl Maltosit − − − 8.0 − − 2-Hexyl Tesyl Maltosit − − − − 8.0 − 2-Hexadecyl Octadecyl Maltoside 8.0 1,3-Vetylene glycol 2.0 2.0 2.0 2.0 2.0 2.0 ────────────────────────── ─────────── Properties Pre-mixed gel-like gel-like gel-like liquid liquid Separation After mixing (+ 2nd agent a) Gel-like gel-like gel-like liquid liquid After separation-mixing (+ 2nd agent) Gel-like gel-like gel-like liquid liquid Separation Hair test Dripping ◎ ◎ ◎ × ×-* Spreading Properties / Applicability ◎ ◎ ◎ ○ ○ − * Level dyeing ◎ ◎ ◎ × × − * ───────────────────────────── ─────── *-: Indicates that the hair dyeing test was not performed.

As can be seen from Table 6, in Formulation Examples 3 to 5 in which the sugar derivative of the present invention is blended, gel-like oxidative hair dye compositions can be obtained, but when the fatty chain is linear (comparative) In Example 6) or when the total number of carbon atoms in the branched fatty chain was less than 18 (Comparative Example 7), the hair dye composition was liquid and did not form a gel. In addition, when the total number of carbon atoms in the branched fatty chain was larger than 32 (Comparative Example 8), separation occurred and a uniform hair dye composition could not be obtained. Further, the hair dye compositions using Formulation Examples 3 to 5 were excellent in the hair dyeing test and the hair damage preventing effect, but the hair dye compositions using the first agent of Comparative Examples 6 to 7 were liquid. For this reason, there was dripping and the like, and the extensibility, coating property, and leveling property were inferior to those of the formulation examples 3 to 5 of the present invention.

Formulation Examples 6 to 12 Using the samples shown in Tables 7 and 8, each first agent was prepared in the same formulation as in Formulation Examples 1 and 2, and then each second agent and the weight ratio 1:
The mixture was mixed in No. 1, and a hair dyeing test and a hair damage test were performed on each mixture.

[Table 7] ──────────────────────────────────── Composition example Sample 6 7 8 9 10 11 12 ──────────────────────────────────── Isostearyl maltoside 8.0 8.0 8.0 8.0 8.0 4.0 − Maltitol Isostearyl ether − − − − − 4.0 8.0 1,3-butylene glycol − − − − − − − Glycerin 2.0 − − − 1.0 1.0 − difluoro propylene glycol − 2.0 − − 1.0 − 1.0 sorbitol − − 2.0 − − − hyalurone Acid − − − 2.0 − − 2.0 Ethylene glycol − − − − − − − − ────────────────────────────────── ─── Dripping ◎ ◎ ◎ ◎ ◎ ◎ ◎ Extendability / applicability ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ Level dyeing ◎ ◎ ◎ ◎ ◎ ◎ ◎ Hair damage prevention effect ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ Moisture ◎ ◎ ○ ○ ◎ ◎ ◎ Smoothness ◎ ◎ ○ ○ ◎ ◎ ◎ ──────────────────── ─────────────────

[Table 8] ──────────────────────────────── Composition example Sample 13 14 15 16 16 17 ───── ─────────────────────────── Isostearyl maltoside 8.0 8.0 8.0 8.0 8.0 Maltitol isostearyl ether − − − − − 1,3- Butylene glycol 0.005 0.01 20.0 30.0-Glycerin --- --- Difluoro-ethylene glycol --- --- Sorbitol --- --- Hyaluronic acid ----- Ethylene glycol --- --2.0 ───────── ─────────────────────── Dripping ◎ ◎ ◎ ◎ ◎ ◎ Spreadability / applicability ◎ ◎ ◎ ◎ ◎ Level dyeing ◎ ◎ ◎ ◎ ◎ Hair damage Prevention effect △ ◎ ◎ ◎ ◎ △ Moisture △ ◎ ◎ ◎ ◎ △ Smoothness △ ○ ◎ △ ────────────────────────────────

From the above, it is understood that by using the sugar derivative of the present invention in combination with a moisturizing component, an oxidative hair dye composition having a gel form and excellent in hair dyeing effect and hair damage preventing effect can be obtained. To be done. Further, each of the oxidative hair dye compositions of the present invention had a good dyeing property with an oxidative dye, and a deep finished state was obtained.

Formulation Example 18 The first agent and the second agent c prepared by the following formulation were mixed in a weight ratio of 1:
When mixed in No. 1, it was a gel composition having a uniform and appropriate viscosity, and did not drip from the hair during hair dyeing treatment.
An oxidative hair dye composition having excellent extensibility, coating property, level dyeing property, and dyeing property, and having an excellent effect of preventing hair damage was obtained. <First agent> Isopropanol 5.0% by weight Isostearyl maltoside 5.0 Natrim hydrosulfite 0.1 L-ascorbic acid 0.5 EDTA 0.1 Monoethanolamine 1.0 Ammonia water 6.0 Paraphenylenediamine 1.0 Resorcin 0.5 Meta aminophenol 0.1 Fragrance Suitable amount Ion-exchanged water Residual <Second agent c> Hydrogen peroxide water 15.0 Phosphate buffer solution Suitable amount Sodium stannate 0.1 Methylparaben 0.1 Diglycerin 1.0

Formulation Example 19 Three-part hair dye <First part> Isopropanol 5.0% by weight Isostearyl maltoside 5.0 Sodium pyrrolidonecarboxylate 1.0 Thioglycol ammonium 1.0 L-Ascorbic acid 0.5 EDTA 0.5 Paraphenylenediamine 1.0 Ammonia water 7.0 Fragrance Suitable amount Ion-exchanged water Residual <Second agent d> Hydrogen peroxide water 30% 15.0 Phosphate buffer 0.1 Methylparaben 0.1 Tin Sodium acid 0.1 Propylene glycol 1.0 Ion-exchanged water Residual <Third agent> Ammonium sulfate 2.0 Sodium metasilicate 20.0 Ammonium persulfate 75.0 EDTA 1.0 Carboxymethylcellulose 2.0

(Production Method) The formulation of the above-mentioned first agent was sequentially dissolved in ion-exchanged water to obtain a first agent. Also, the second agent d was prepared in the same manner. Each component of the third agent was well pulverized and mixed to obtain a third agent. Dissolve the third agent in the second agent d,
The agents were mixed to obtain a three-component hair dye. Usually, they are mixed in the above order, but the order is not limited to this. The weight ratio of the first agent, the second agent d and the third agent prepared by the above formulation is 1: 1: 1.
When mixed with, it is a gel composition having a uniform and appropriate viscosity, does not drip from the hair during hair dyeing, and has good spreadability, applicability, leveling property, and dyeing property. Thus, an oxidative hair dye composition having an excellent effect of preventing hair damage was obtained.

The first agent prepared according to the formulations of the following formulation examples 20 to 38 was mixed with the second agent a or the second agent b in Table 3 in a weight ratio of 1:
When mixed in 1, a gel-like oxidative hair dye composition having a uniform and appropriate viscosity was obtained. All of these do not drip from the hair during hair dyeing treatment, and have extensibility, applicability,
An oxidative hair dye composition having good leveling and dyeing properties and an excellent hair damage preventing effect was obtained. Further, all the hair dye compositions were safe hair dye compositions with no irritation to the scalp.

Formulation Example 20 Isopropanol 5.0 wt% Isostearyl maltoside 5.0 Polyethylene glycol (molecular weight 500) 2.0 Sodium hydrosulfite 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Monoethanolamine 0 .5 paratoluene diaminosulfate 1.0 resorcin 1.0 orthoaminophenol 0.1 paraaminophenol 0.01 paraaminoorthocresol 0.05 perfume proper amount ion-exchanged water residual

Formulation Example 21 Glycerin 14.0% by weight Chondroitin sulfate 0.2 Isopropanol 5.0 Isostearyl maltoside 4.0 Represented by the general formula 3 above, A is 1.0 polymerization of three glucose monosaccharides. Compound in which R is an isostearyl group sodium pyrosulfite 0.1 L-ascorbic acid 0.5 EDTA 0.5 monoethanolamine 0.5 paratoluene diaminosulfate 1.0 resorcin 1.0 orthoaminophenol 0.1 Metaphenylenediamine 0.01 Paraaminoorthocresol 0.05 Perfume Appropriate amount Ion-exchanged water Residual

Formulation Example 22 Propylene glycol 5.0% by weight Polyethylene glycol 400 15.0 Isopropanol 5.0 Isostearyl maltoside 5.0 Amino-modified polysiloxane 0.5 (Silicone SM-8702C: Toray Silicone Co.) Chloride Stearyl trimethyl ammonium 0.1 Sodium hydrosulfite 0.1 L-ascorbic acid 0.5 Hydroxyethanediphosphonic acid 0.5 Ammonia water 6.0 Monoethanolamine 1.0 Paraphenylenediaminosulfate 1.0 Resorcinol 1.0 Para-aminophenol 0.1 Para-nitro-ortho-phenylenediamine 0.01 Para-amino-ortho-cresol 0.01 Perfume Appropriate amount Ion-exchanged water Residual

Formulation Example 23 Isopropanol 5.0% by weight Vaseline 0.5 Isostearyl maltoside 5.0 Isostearyl maltototrioside 5.0 Sodium chondroitin sulfate 1.0 Cholesteryl-12-hydroxystearate 1.0 Thioglycol Ammonium acid 0.5 L-ascorbic acid 0.5 EDTA 0.5 Methylparaben 1.0 Monoethanolamine 0.5 Sodium hydroxide 0.2 Paraphenylenediamine 1.0 Paraaminoorthocresol 1.0 Orthoaminophenol 0.1 Fragrance Suitable amount Ion exchange water Residual

Formulation Example 24 1,3-butylene glycol 14.0% by weight sodium chondroitin sulfate 0.1 isopropanol 5.0 methylphenylpolysiloxane 1.0 (Silicone KF56: manufactured by Shin-Etsu Chemical Co., Ltd.) quaternized collagen Hydrolyzate 0.5 Isostearyl maltoside 5.0 Ammonium thioglycolate 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Monoethanolamine 0.5 Sodium hydrogen carbonate 1.0 Paraphenylenediamine 1.0 Meta Aminophenol 1.0 Orthoaminophenol 0.1 Metaphenylenediamine 0.01 Paraaminoorthocresol 0.01 Perfume Suitable amount Ion-exchanged water Residual

Formulation Example 25 Maltitol Aqueous Solution 14.0% by Weight Sodium Chondroitin Sulfate 0.2 Isopropanol 5.0 Squalane 3.0 Isostearyl Maltoside 7.0 Carboxymethyl Cellulose 0.2 Sodium Hydrosulfite 0.1 L-Ascorbine Acid 0.5 EDTA 0.5 Ammonia water 6.0 Ammonium carbonate 2.0 Paratoluene diaminosulfate 1.0 Metaaminophenol 2.0 Orthoaminophenol 0.3 Perfume Suitable amount Ion exchange water Residual

Formulation Example 26 Solbit 15.0% by weight Sodium hyaluronate 0.1 Benzyl alcohol 2.0 Isostearyl maltoside 8.0 Sodium pyrosulfite 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Silk protein hydrate Decomposition product 0.1 Monoethanolamine 0.5 Paraphenylenediamine 1.0 Resorcinol 1.0 Orthoaminophenol 0.2 Metaaminophenol 0.1 Paraaminoorthocresol 0.05 Perfume Suitable amount Ion exchange water Residual

Formulation Example 27 Isopropanol 5.0% by weight Isostearyl maltoside 5.0 Propylene glycol 2.0 Potassium isostearate 4.5 Emarex OP-5 2.0 (POE (5) octyl phenyl ether, Japanese emulsion ( EMALEX OP-10 1.0 (POE (10) octyl phenyl ether, manufactured by Nippon Emulsion Co., Ltd.) sodium hydrosulfite 0.5 L-ascorbic acid 0.5 EDTA 0.5 monoethanolamine 2 0.0 paratoluene diaminosulfate 1.0 resorcin 1.0 paraaminophenol 0.1 perfume proper amount ion-exchanged water residual

Formulation Example 28 Diglycerin 13.0 wt% Mabit 2.0 Isopropanol 5.0 Isostearyl Maltoside 5.0 Sodium lauryl sulfate 0.5 Cetanol 4.0 Emarex OP-5 3.0 (POE (5 ) Octyl phenyl ether, manufactured by Nippon Emulsion Co., Ltd.) Keratin hydrolyzate 0.3 Sodium hydrosulfite 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Ammonia water 6.0 Paraphenylenediamine 1.0 Paraaminophenol 1.0 Para-amino orthocresol 0.02 Fragrance Suitable amount Ion-exchanged water Residual

Formulation Example 29 Propylene glycol 13.0% by weight Liquid paraffin 2.0 Isopropanol 5.0 Isostearyl maltoside 5.0 Mucoitin sulfate 1.0 Sodium bile acid 1.0 Dimethylsiloxane methyl (polyoxyethylene) 0 .3 Siloxane copolymer (EO = 24) (Silicone SC-9450: manufactured by Shin-Etsu Chemical Co., Ltd.) Stearyl trimethyl ammonium chloride 0.2 Collagen hydrolyzate 0.3 Sodium hydrosulfite 0.1 L-Ascorbic acid 0 .5 EDTA 0.5 ammonia water 6.0 para-phenylenediamine 1.0 meta-aminophenol 1.0 para-nitro-ortho-phenylenediamine 0.02 perfume proper amount ion-exchanged water residual

Formulation Example 30 Polyethylene glycol 2.0% by weight Lanolin 2.0 Ethanol 5.0 Isostearyl maltoside 10.0 1,3-Butylene glycol 3.0 Xanthan gum 0.5 POE (60) hydrogenated castor oil 2. 0 (HCO-60: Nikko Chemicals Co., Ltd.) Elastin hydrolyzate 0.2 Sodium pyrosulfite 0.1 Sodium hydroxide 0.3 L-Ascorbic acid 0.5 EDTA 0.5 Methylparaben 1.0 Ammonia water 6 0.0 paratoluene diaminosulfate 1.0 resorcin 1.0 paraaminoorthocresol 0.5 perfume proper amount ion-exchanged water residual

Formulation Example 31 Polyethylene glycol (molecular weight 1000) 10.0% by weight Dipropylene glycol 2.0 Isopropanol 5.0 Isostearyl maltoside 5.0 Chondroitin sulfate 1.0 Self-emulsifying glycerin monostearate 2.0 ( Tegin T: Nikko Chemicals Co., Ltd.) Hydroxyethyl cellulose hydroxypropyl trimethyl 0.2 Ammonium chloride ether Dimethyl siloxane methyl (polyoxyethylene) 0.2 Siloxane copolymer (EO = 24) (Silicone SC-9450: Shin-Etsu Chemical) Amino-modified polysiloxane 0.5 (Silicone SM-8702C: manufactured by Toray Silicone) Sodium hydrosulfite 0.1 L-ascorbic acid 0.5 EDTA 0.5 Methylparaben 1. 0 Ammonia water 6.0 Para-phenylenediamine 1.5 Resorcin 1.0 Para-aminophenol 0.2 Meta-aminophenol 0.1 Perfume Suitable amount Ion-exchanged water Residual

Formulation Example 32 Glycerin 14.0% by weight Vaseline 2.0 Ethanol 5.0 Isostearyl maltoside 5.0 Polyethylene glycol (molecular weight 300) 1.0 Diglycerin 2.0 Self-emulsifying glyceryl monostearate 2. 0 (Teguin T: Nikko Chemicals Co., Ltd.) Carboxy vinyl polymer 0.1 Dimethyl siloxane / methyl (polyoxyethylene) 0.2 Siloxane copolymer (EO = 24) (Silicone SC-9450: Shin-Etsu Chemical Co., Ltd.) Sodium thiosulfate 0.1 N-methylpyrrolidone 0.5 L-ascorbic acid 0.5 EDTA 0.5 methylparaben 0.1 monoethanolamine 3.0 potassium hydroxide 0.3 paraphenylenediamine 1.0 resorcinol 1 0.0 Meta aminophenol 0.1 Para amino Sokurezoru 0.05 Perfume Appropriate amount Ion exchanged water Balance

Formulation Example 33 Diglycerin 14.0% by weight Lanolin 2.0 Isopropanol 5.0 Isostearyl maltoside 5.0 Maltitol hydroxyaliphatic ether 2.0 (where the aliphatic hydrocarbon group is a dodecyl group or a tetradecyl group) Mixture) Sodium chondroitin sulfate 0.1 Methylphenylpolysiloxane 0.2 (Silicone KF56: manufactured by Shin-Etsu Chemical Co., Ltd.) Sodium hydrosulfite 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Methylparaben 0.1 Monoethanol Amine 0.5 Paraphenylenediamine 1.0 Paraaminophenol 1.0 Resorcinol 0.05 Paranitroorthophenylenediamine 0.02 Fragrance Suitable amount Ion-exchanged water Residual

Formulation Example 34 Oleic acid 20.0% by weight Isostearyl maltoside 7.0 Caronic acid 2.0 Dipropylene glycol 2.0 Isopropanol 10.0 Ammonia water (28%) 8.0 Sodium hydrosulfite 0.0. 1 EDTA 0.4 Paraphenylenediamine 0.3 Resorcin 0.05 Ion-exchanged water Residual

Formulation 35 Isopropanol 6.0 Isostearyl Maltoside 7.0 Compound represented by the above general formula 3, wherein A is a 1.0 polymer having 3 glucose units, and R is an isostearyl group. A compound represented by Formula 3, in which A is a 1.0 polymer having four glucose units, and R is an isostearyl group Mannitol 1.0 Hyaluronic acid 2.0 Ammonium thioglycolate 0.5 L-ascorbic acid 0 .5 EDTA 0.5 monoethanolamine 0.5 paratoluene diaminosulfate 1.0 resorcin 1.0 orthoaminophenol 0.1 metaphenylenediamine 0.01 paraaminoorthocresol 0.05 perfume proper amount ion-exchanged water residual

Formulation Example 36 Isopropanol 8.0% by weight Isostearyl maltoside 5.0 Polyethylene glycol (molecular weight 100) 0.5 Sodium lactate 2.0 L-Ascorbic acid 0.5 EDTA 0.5 Methylparaben 1.0 Monoethanol Amine 0.5 Sodium hydroxide 0.2 Paraphenylenediamine 1.0 Paraaminoorthocresol 1.0 Orthoaminophenol 0.1 Perfume Suitable amount Ion exchange water Residual

Formulation Example 37 Benzyl alcohol 2.0 Isostearyl maltoside 8.0 Mannitol 1.5 Cholesteryl-12-hydroxystearate 2.0 Sodium pyrosulfite 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Mono Ethanolamine 0.5 Paraphenylenediamine 1.0 Resorcinol 1.0 Orthoaminophenol 0.2 Metaaminophenol 0.1 Paraaminoorthocresol 0.05 Perfume Appropriate amount Ion exchange water Residual

Formulation 38 Cetyl alcohol 2.0% by weight Isostearyl maltoside 1.0 1,3-butylene glycol 0.5 Glycerin 0.5 Ammonium thioglycolate 2.0 Edetate 0.2 Paraphenylenediamine 2 0.0 Ortho aminophenol 2.0 Resorcin 0.2 Ion-exchanged water Residual

[0071]

EFFECTS OF THE INVENTION The oxidative hair dye composition according to the present invention has an appropriate viscosity by blending a sugar derivative and a moisturizing component, and does not drip from the hair during hair dyeing treatment. It is characterized in that it has good extensibility, coatability, and level dyeing property, does not impair the dyeing property of the oxidative dye, and is excellent in the hair damage preventing effect and the dryness preventing effect.

 ─────────────────────────────────────────────────── ─── Continued Front Page (72) Inventor Keiichi Uehara 1050 Shinba-cho, Kohoku-ku, Yokohama-shi, Kanagawa Inside Shiseido Daiichi Research Center, Inc. (72) Inventor Masakazu Okumura 5-1-1 Umei, Takasago-shi, Hyogo No. 1 Inside the Nippon Seika Co., Ltd. (72) Inventor Takafumi Kusumoto 2-3-7 Shimbashi, Minato-ku, Tokyo Inside Nihon Seika Co., Ltd. Tokyo Branch

Claims (8)

[Claims] 1. A sugar derivative represented by the general formula 1 and a group selected from the group consisting of polyhydric alcohols, sugars, mucopolysaccharides, NMF components, caronic acid, cholesteryl-12-hydroxystearate and bile salts. An oxidative hair dye composition comprising a moisturizing component to be used and an oxidative dye. Embedded image (In the formula, A is a residue obtained by removing n hydroxyl groups from sugar, R is
Represents a fatty chain having a total carbon number of 18 to 32 and having a branched chain, and n represents 1 or more. ) 2. The oxidative hair dye composition according to claim 1, wherein the sugar derivative is a branched aliphatic glycoside represented by the general formula 2. Embedded image (However, in the formula, A is a residue obtained by removing a hemiacetal hydroxyl group from a sugar, and R is the same as the above chemical formula 1.) 3. The oxidative hair dye composition according to claim 1, wherein the sugar derivative is a sugar-branched aliphatic ether represented by the general formula 3. Embedded image (However, in the formula, A is a residue obtained by removing n non-hemiacetal hydroxyl groups from a sugar, and R and n are the same as those in the above chemical formula 1.) 4. The oxidative hair dye composition according to claim 1, wherein the sugar derivative is isostearyl maltoside. 5. The oxidative hair dye composition according to claim 1 or 3, wherein the sugar derivative is maltitol isostearyl ether. 6. The oxidative hair dye composition according to claim 1, wherein the moisturizing component is polyethylene glycol, propylene glycol, dipropylene glycol, glycerin, diglycerin, 1,3-having a molecular weight of 100 to 1,000.
An oxidative hair dye composition, which is a polyhydric alcohol selected from butylene glycol. 7. The oxidative hair dye composition according to any one of claims 1 to 6, further comprising an oxidant. 8. The oxidative hair dye composition according to any one of claims 1 to 7 is composed of a multi-dose type and contains a sugar derivative, a moisturizing component, an oxidative dye and an oxidant when mixed. An oxidative hair dye composition.