JPH0840853A - Oxidation hair dyeing agent composition - Google Patents

Abstract

PURPOSE:To obtain an oxidation hair dyeing agent composition containing a specific saccharide derivative, a cationic high polymer compound and oxidation dye, free from dropping from hair in hair-dyeing treatment, having good extensibility, coating property, uniformly dyeing property, dyeability and washing resistance and having tension and stiffness in hair after hair dyeing. CONSTITUTION:This composition contains a saccharide derivative of the formula [A is a residue after removing n hydroxyl groups; R is an 18-32C branched chain fatty chain; (n) is >=1[preferably a saccharide-branched aliphatic ether of the formula A-O-R (A is a residue after removing n non-hemiacetal-based hydroxyl groups), a cationic polymer compound [preferably a poly(dimethylallyl- ammonuum halide) type cationic polymer, a dimethyldiallyl-ammonium halide- acrylamide copolymer type cationic polymer, etc.] and an oxidation dye.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to improvements in hair dye compositions, especially oxidative hair dye compositions.

[0002]

2. Description of the Related Art Oxidative hair dyes are the most widely used permanent hair dyes. The oxidation dye in the hair dye penetrates into the hair, undergoes oxidative polymerization, and develops color to cause hair to grow. The feature is that the hair dyeing effect lasts because it is chemically dyed.
As the formulation of the oxidative hair dye, the first agent containing the oxidative dye,
Most of the two-component type is used by mixing with a second agent containing an oxidant at the time of use, but there is also a one-component type used as a powder formulation by mixing with water at the time of use, or a multi-component type of three or more agents.

In any case, the oxidative hair dye chemically dyes hair by an oxidative polymerization reaction. This oxidative polymerization is a fairly vigorous reaction, and uneven application of the oxidative hair dye to the hair may cause uneven dyeing. In order to eliminate this uneven coloring, when the hair dye composition is applied to the hair, various solvents, dispersion media, etc. are added to the oxidative hair dye composition so that it has high fluidity. It was provided in liquid form.

[0004]

However, in such a liquid having high fluidity, the hair dye drips from the hair during or after the hair dyeing treatment, and adheres to the skin or clothes or flows down the face. There was such a problem as On the other hand, if an attempt is made to increase the viscosity of the hair dye by using a thickener or the like so that the hair dye does not sag, the conventional thickener is poor in the spreadability, coatability, and levelness of the oxidative hair dye on the hair. Further, there is a problem that the dyeing property is deteriorated because the thickener inhibits the permeability of the oxidation dye into the hair.

Further, since hair after being dyed with an oxidative hair dye has a problem that it tends to be dull and lacks in firmness, elasticity and smoothness, it is desired to incorporate a cationic polymer. . However, in the prior art, since anionic substances such as anionic surfactants and higher fatty acids were used for gelation, it was impossible to blend a large amount of cationic polymer compounds. The present invention has been made in view of the problems of the prior art as described above, and an object thereof is usability such as extensibility and applicability in spite of no dripping of the hair dye during hair dyeing treatment. The object of the present invention is to provide an oxidative hair dye composition which is excellent in the feeling of use after dyeing, has no unevenness in dyeing, has good levelness of dyeing, and is excellent in dyeing property of an oxidative dye.

[0006]

Means for Solving the Problems As a result of intensive studies for achieving the above-mentioned object, the present inventors have found that the oxidative hair dye is prepared by blending a certain sugar derivative and a cationic polymer compound into the oxidative hair dye. We have found that the problems can be solved.

That is, the oxidative hair dye composition according to claim 1 of the present invention is characterized by containing a sugar derivative represented by the general formula 4, a cationic polymer compound and an oxidative dye. To do.

[Chemical 4] (In the formula, A is a residue obtained by removing n hydroxyl groups from sugar, R is
Represents a fatty chain having a total carbon number of 18 to 32 and having a branched chain, and n represents 1 or more. )

The oxidative hair dye composition according to claim 2 is characterized in that, in the oxidative hair dye composition according to claim 1, the sugar derivative is a branched aliphatic glycoside represented by the general formula 5. To do.

Embedded image (However, in the formula, A is a residue obtained by removing a hemiacetal hydroxyl group from a sugar, and R is the same as the above Chemical formula 4.)

The oxidative hair dye composition according to claim 3 is characterized in that, in the oxidative hair dye composition according to claim 1, the sugar derivative is a sugar-branched aliphatic ether represented by the general formula (6). And

[Chemical 6] (However, in the formula, A is a residue obtained by removing n non-hemiacetal hydroxyl groups from a sugar, and R and n are the same as those in the above chemical formula 4.)

The oxidative hair dye composition according to claim 4 is characterized in that, in the oxidative hair dye composition according to claim 1 or 2, the sugar derivative is isostearyl maltoside.
The oxidative hair dye composition according to claim 5 is the oxidative hair dye composition according to claim 1 or 3, wherein the sugar derivative is maltitol isostearyl ether.

The oxidative hair dye composition according to claim 6 is the oxidative hair dye composition according to any one of claims 1 to 5, wherein the cationic polymer compound is a poly (dimethylallylammonium halide) type cationic polymer. , A copolymer type cationic polymer of dimethyldiallylammonium halide and acrylamide, polyethylene glycol, epichlorohydrin, a cationic polymer which is a condensation product type of taroylamine obtained from propyleneamine and tallow fatty acid, polyethylene glycol, epichlorohydrin, propyleneamine and Cationic polymer which is a condensation product type of cocoylamine obtained from coconut oil fatty acid, vinylpyrrolidone, dimethylaminomethacrylate copolymer type cationic polymer, quaternary nitrogen-containing cellulose ether type cationic high content Characterized in that it contains the selected one or two or more from the group of.

The oxidative hair dye composition according to claim 7 is characterized in that, in the oxidative hair dye composition according to claims 1 to 6, an oxidant is contained. The oxidative hair dye composition according to claim 8 is a multi-agent type of the oxidative hair dye composition according to any one of claims 1 to 7, and when mixed, a sugar derivative, a cationic polymer compound, and an oxidative dye. It is characterized by containing.

The structure of the present invention will be described in detail below. First, in the present invention, the sugar derivative is a compound obtained by alkylating a hydroxyl group of a sugar with a branched aliphatic hydrocarbon group, and in particular, a hemiacetal hydroxyl group of the sugar and a branched aliphatic acid hydrocarbon group form a glycoside bond. Branched fatty glycosides,
An ether bond product of a hydroxyl group other than that (called a non-hemiacetal hydroxyl group) and a branched aliphatic hydrocarbon group is called a sugar branched aliphatic ether. The hemiacetal hydroxyl group refers to one hydroxyl group of hemiacetal generated when a sugar forms a cyclic structure.

The branched aliphatic glycoside used in the present invention is represented by the above general formula 5, wherein A is a residue obtained by removing a hemiacetal hydroxyl group from a sugar, and such a sugar is glucose. , Monosaccharides such as galactose, xylose, fructose, altrose, talose, mannose, arabinose, idose, lyxose, ribose, and allose, and mixtures thereof, maltose, isomaltose, lactose, xylobiose, kentiobiose,
Cordiobiose, cellobiose, sophorose, nigerose, sucrose, melibiose, laminaribiose,
Examples thereof include disaccharides such as rutinose and mixtures thereof, trisaccharides such as maltotriose and mixtures thereof, or higher polysaccharides, polymers of monosaccharides, and mixtures of these saccharides.

The sugar-branched aliphatic ether used in the present invention is represented by the above-mentioned general formula 6, wherein A is a residue obtained by removing n non-hemiacetal hydroxyl groups from sugar,
Examples of such sugars include sugar alcohols such as maltitol, sorbitol, erythritol, mannitol, galactitol, glucitol, inositol, maltotriitol, maltotetriitol, and mixtures thereof. In addition, n represents the average number of branched fatty chains bonded to one sugar molecule.

In any of the general formulas, R is an aliphatic chain having a branched chain and has a total carbon number of 18 to 32. Specific examples of the branched chain include, for example, methyl group, ethyl group, propyl group,
Isopropyl group, butyl group, pentyl group, hexyl group,
Heptyl group, octyl group, nonyl group, decyl group, undecyl group, dodecyl group, tridecyl group, tetradecyl group,
Examples thereof include a heptadecyl group, a hexadecyl group, a heptadecyl group and further higher fatty chains. The position and number of such branched chains are not particularly limited. Specific examples of R include 2-decyltetradecyl group, 2-tetradecyloctadecyl group, isostearyl group, isomyristyl group, 2,7-dimethylhexadecyl group, tetrahydrageranyl group, 2,7-dimethyloctadecyl group. Etc., but it is not particularly limited as long as it has a branched chain and has a total carbon number of 18 to 32. When R is a linear fatty chain or the total number of carbon atoms of R is less than 18, the thickening effect is not sufficiently exhibited, and when the total number of carbon atoms is greater than 32, the hydrophobicity becomes high and water Solubility is poor and it becomes difficult to use in water.

The sugar derivatives according to the present invention are all known substances, and the branched aliphatic glycoside represented by the general formula 5 is, for example, the acid catalyst for sugar modification described in JP-A-63-84637. In addition to the synthesizing method using the same, it is possible to synthesize by using the reaction generally used for glycosylation (König-Knol reaction, Helferreich method, or other ether exchange method).

On the other hand, the sugar-branched aliphatic ether represented by the general formula 6 is, for example, the method of Robert et al. (Tetrahedro).
n, 35 , 2169-2172 (1979)). That is, the sugar is dissolved in a non-aqueous solvent such as dimethylformamide or dimethylsulfoxide, and the compound represented by the following general formula 7 is added to the solution to give a solution in the presence of a catalyst.
It is obtained by reacting at 0 to 130 ° C.

Embedded image (wherein, X is a halogen salt of a hydroxyl group or a halogen group or a trialkylammonium group such as trimethylammonium bromide, and R is the same as in the above Chemical Formula 6).

Two or more sugar derivatives can be used in the oxidative hair dye composition of the present invention. For example, a mixture of sugar-branched aliphatic ether or a branched fatty chain of a branched aliphatic glycoside or a kind of sugar, and in the sugar-branched aliphatic ether, a mixture of sugar derivatives different in the number of bonded branched fatty chains or the bonding position may be used. Of course, a mixture of a sugar-branched aliphatic ether and a branched aliphatic glycoside may be used.

Examples of the cationic polymer compound used in combination with the sugar derivative in the present invention include poly (dimethylallylammonium halide) type cationic polymers and copolymer type cationic polymers of dimethyldiallylammonium halide and acrylamide. Polyethylene glycol, epichlorohydrin, propyleneamine, and tallowylamine, which is a condensation product type of tallowylamine, which is a condensation polymer type, is a condensation product type of cocoylamine obtained from polyethylene glycol, epichlorohydrin, propyleneamine, and coconut oil fatty acid. Examples thereof include cationic polymers, vinylpyrrolidone, dimethylaminomethacrylate copolymer type cationic polymers, and quaternary nitrogen-containing cellulose ether type cationic polymers.

Among these, the poly (dimethylallylammonium halide) type cationic polymer is represented by the following general formula (1). General formula (1):

Embedded image Or

[Chemical 9] (In Chemical Formula 8 or Chemical Formula 9, R ₁ or R ₂ represents a hydrogen atom or a methyl group, X represents a halogen atom, and p represents 150 to 6).
It is an integer of 200. )

The poly (dimethylallylammonium halide) type cationic polymer represented by the general formula (1) is, for example, Merquat 100 sold by Merck & Co., Inc. ) And the like. Marquat 100 is a pale yellow viscous liquid which is an aqueous solution having a pure content of about 40%, in which X is chloro.

The copolymer type cationic polymer of dimethyldiallylammonium halide and acrylamide is represented by the following general formula (2). General formula (2)

[Chemical 10] Or

[Chemical 11] (Formula 10 or formula 11 Oite, R ₃ is R ₄ is a hydrogen atom or a methyl group, X represents a halogen atom, the sum of q and r 1
It is an integer of 50 to 9000. )

Incidentally, the copolymer type cationic polymer of dimethyldiallylammonium halide and acrylamide represented by the general formula (2) is represented by the general formula (2) for the sake of convenience. It does not have to be a polymer, and the order of arranging the monomers may be arbitrary. Examples of the copolymer type cationic polymer of dimethyldiallylammonium halide and acrylamide include Merquat 550 sold by Merck & Co., Inc. By the way, the Marcoat 550 is a colorless viscous liquid which is an aqueous solution of about 8% in pure content in which X is chlorine.

Examples of the cationic polymer which is a condensation product type of polyethylene glycol, epichlorohydrin, propyleneamine, taroylamine or cocoylamine include, for example, Henkel International C
Polyquat H) sold by O.). Polycoat H is an aqueous solution having a pure content of about 50% and is a pale yellow viscous liquid.

Examples of the vinylpyrrolidone-dimethylaminomethacrylate copolymer type cationic polymer include Gafquart 755 and Gafcoat 734 sold by GAF Corp., USA.
(Gafquart 734) and the like. Gaff coat 7
55 is a pale yellow viscous liquid which is an aqueous solution having a pure content of about 20%, and the guff coat 734 is a pale yellow liquid which is an alcohol solution having a pure content of about 50%.

Examples of the quaternary nitrogen-containing cellulose ether type cationic polymer include, for example, Polymer JR-400 and Polymer JR-1 sold by Union Carbide Corp. of the United States.
25 (Polymer JR-125), Polymer JR-30M (Poly
mer JR-30M) and so on. The polymer JR series is a white or pale yellow powder. In the present invention, one kind or two or more kinds of the above cationic polymer compounds can be optionally used.

Examples of the oxidative dye used in the oxidative hair dye composition of the present invention include phenylenediamines, aminophenols, toluylenediamines, aminonitrophenols, diphenylamines, diaminophenylamines and N-. Examples thereof include phenylphenylenediamines, diaminopyridines, resorcin, pyrogallol, catechol, aminocresols and salts thereof. The blending amount of the oxidative dye is not particularly limited as long as it is within the range generally used for oxidative hair dyes. In the present invention,
In general, a color tone adjusting agent that changes a color tone in combination with an oxidative dye as a main agent is also included in the oxidative dye of the present invention.

Since the oxidative hair dye composition according to the present invention contains the above-mentioned sugar derivative, it has an appropriate viscosity so that it does not drip or run off, and moreover, it can be applied quickly and evenly to the hair and is dyed. Also has the effect of being uniform.
Further, the sugar derivative according to the present invention does not hinder the dye from penetrating into hair and dyeing, and good dyeing property can be obtained. Further, the sugar derivative of the present invention is characterized in that it is stable without being decomposed even in an acid or an alkali, has no sensitizing property or irritating property even when incorporated into a hair dye composition, and is excellent in safety.

Further, lower alcohols such as ethanol and isopropanol may be blended in the hair dye composition. When a surfactant is used as a thickener in such a system, the thickening effect is remarkably reduced. Therefore, it is necessary to add a large amount of a surfactant, and problems such as irritation and inhibition of dyeing property tend to occur. If the sugar derivative according to the present invention is used, a thickening effect can be obtained with a small amount even in such a system. In the oxidative hair dye composition of the present invention, the blending amount of the sugar derivative is not particularly limited as long as the effects of the present invention can be obtained, and the blending amount can be appropriately adjusted and used. It is 0.5 to 60% by weight, preferably 1 to 15% by weight.

In the oxidative hair dye composition of the present invention, a cationic polymer compound can be blended by using the above-mentioned sugar derivative, so that the hair after dyeing has firmness.
There is a synergistic effect that the feeling of elasticity and smoothness is greatly improved, and the dyeing property and cleaning resistance due to the oxidation dye are also significantly improved. The amount of the cationic polymer compound blended in the oxidative hair dye composition of the present invention is 0.01 to 15.
0 wt% is preferred. If it is less than 0.01% by weight, the desired effect cannot be obtained, and if it exceeds 15.0% by weight, stickiness appears, which is not preferable.

The oxidative hair dye composition according to the present invention may take any one-form or multi-form of two or more parts. For example, 2
In the dosage form, a two-part composition in which a first agent containing a sugar derivative, a cationic polymer compound and an oxidative dye and a second agent containing an oxidant are mixed at the time of use, a sugar derivative and an oxidative dye A two-part composition in which a first agent containing a and a second agent containing a cationic polymer compound and an oxidizing agent are mixed and used at the time of use is preferable. The mixing ratio of the first agent and the second agent is usually 1st agent: 2nd agent = 1: 1 in weight ratio, but unless there is a problem in dripping, usability, leveling property, etc. There is no particular limitation. The oxidizing agent used in the present invention includes:
Examples thereof include hydrogen peroxide, persulfate, perborate, bromate, periodate, and urea peroxide.

The oxidative hair dye composition of the present invention may contain other components usually used in hair dyes, as long as the effects of the present invention are not impaired. For example, as a component usually added to the first agent, glycerin, propylene glycol, dipropylene glycol, polyethylene glycol, chondroitin sulfate, hyaluronate, diglycerin, 1,3-butylene glycol, pyrrolidone carboxylate, sorbitol. Moisturizers such as maltitol, lactose, oligosaccharides, lanolin, squalane, liquid paraffin, petroleum jelly, higher fatty acids, triglycerides, oil components such as ester oils, methylphenylpolysiloxane,
Examples thereof include silicones such as dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymer, rubbery dimethylpolysiloxane, and amino-modified polysiloxane.

Further, antioxidants and stabilizers such as thioglycollate, L-ascorbate, bisulfite, hydrosulfite, bisulfate, collagen hydrolyzate, keratin hydrolyzate, silk protein. Protein hydrolyzate such as hydrolyzate, elastin hydrolyzate, soybean protein hydrolyzate and the like, and quaternary products thereof, ammonia water, alkanolamine, ammonium carbonate, sodium hydrogen carbonate, and an alkali agent such as potassium hydroxide are added. It is also possible.

It is also possible to use another amphipathic substance or a surfactant as the emulsifier. Examples of nonionic surfactants include polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene polyhydric alcohol fatty acid partial esters, polyoxyethylene hydrogenated castor oil derivatives, and other polyoxyethylene-based surfactants, octylpolyether. Alkyl polyglycosides such as glycosides, polyglycerin fatty acid esters, polyglycerin-based surfactants such as polyglycerin alkyl ethers, maltitol hydroxyalkyl ethers, sugar alcohol ethers such as sorbitol alkyl ethers, fatty acid diethanolamides, and the like, Anions such as higher fatty acid salts, alkylbenzene sulfonates, phosphoric acid esters, alkyl sulfates, alkyl sulfate ester salts, and polyoxyethylene alkyl sulfate ester salts Surfactants, amino acids, alkyl trimethyl ammonium salt, dialkyl dimethyl ammonium salts, alkyl cationic surfactants dimethylamine oxide, and the like, other surfactants can be appropriately used in combination.

Further, for example, ethanol, butanol,
Lower alcohols such as propanol and isopropanol, 2-ethylhexyl alcohol, 2-hexyldecyl alcohol, 2-decyltetradecyl alcohol, isostearyl alcohol, cetostearyl alcohol,
Higher alcohols such as lauryl alcohol, stearyl alcohol and cetyl alcohol, benzyl alcohol and the like can be added.

Examples of the sequestering agents and preservatives include hydroxyethanediphosphonates, phenacetin, EDTA and its salts, parabens and stannates. Also, lauric acid diethanolamide, carboxymethyl cellulose, carboxyvinyl polymer, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, xanthan gum, carrageenan, alginate, pectin, phaseran, gum arabic, gutchi gum, karaya gum, tragacanth gum, agar powder, bentonite, crosslinkable Thickeners such as polyacrylic acid salts can also be used in combination as long as the effects of the present invention are not impaired. Others, pH adjusters, fragrances, drugs,
A colorant, water, etc. can be appropriately added.

The components to be added to the second agent include, for example, phenacetin, EDTA and salts thereof, parabens,
Sequestrants such as stannates and preservatives, higher grades such as 2-ethylhexyl alcohol, 2-hexyldecyl alcohol, 2-decyltetradecyl alcohol, isostearyl alcohol, cetostearyl alcohol, lauryl alcohol, stearyl alcohol, cetyl alcohol Alcohols, polyoxyethylene alkyl ethers, alkyl sulfate salts, surfactants such as acylmethyl taurines, organic acids such as citric acid, malic acid, acetic acid, lactic acid, oxalic acid, tartaric acid, formic acid, levulinic acid, Examples thereof include acids such as inorganic acids such as phosphoric acid and hydrochloric acid, pH adjusting agents, fragrances, drugs, coloring agents, water and the like.

[0039]

EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited thereto. In addition, all the compounding amounts show weight%. Prior to the examples, the test method used in each example will be described.

[Hair Dyeing Test] Hair of 10 panelists was dyed with each test hair dye composition, and dripping during hair dyeing, spreadability / applicability to hair, level dyeing property and The relative smoothness of the hair after dyeing was evaluated. The evaluation criteria are as follows. <Evaluation of dripping> ◎: No dripping, no dripping ○: Almost no dripping, dripping △: Dripping, dripping ×: Dripping, dripping is severe

<Evaluation of extensibility and coatability> ◎: Very good elongation and easy application ○: Fairly good elongation and easy application Δ: Not very good elongation and difficult application ×: Poor extension , Uneven coating

<Evaluation of Level Dyeability> ⊚: Evenly dyed well ◯: Almost uniformly dyed Δ: Slightly uneven dyeing occurred ×: Dyeing unevenness occurred

<Evaluation of smoothness> ◎: Very smooth ○: Smooth Δ: Slightly smooth ×: Lack of smoothness <Evaluation of firmness / elasticity> ◎: Very firmness / rigidity felt ○: Firmness A firmness is felt. △: The firmness and stiffness are poor. ×: The firmness and stiffness are not felt.

[Dyeing test] 2 g of human hair bundle with white hair
Wash the area with commercially available shampoo, lightly wipe with a towel and place on an aluminum tray. Take 5g of hair dye composition in an aluminum tray and 2
Rub the back and front of the human hair bundle at 5 to 30 ° C with a toothbrush and leave for 15 minutes. Then, it was thoroughly washed with slightly warm water, wiped with a towel, then dried with a dryer, and the difference in color from that of human hair containing untreated white hair was visually judged.

<Evaluation of Dyeability> ◎: Very good ○: Good Δ: Slightly bad ×: Bad

[Washing resistance test] After the determination in the dyeing test, the dyed human hair bundle was divided into two equal parts, one of them was impregnated with a commercial shampoo solution, hand-washed 10 times, and then dried. . Repeat this 10 times, with the human hair bundle before shampoo,
The color of human hair bundles after shampoo was visually compared to examine the wash resistance (shampoo resistance).

<Evaluation of Washing Resistance> ◎: Very good (no fading at all) ○: Good (slightly fading) Δ: Slightly bad (fading) X: Bad (fading marked)

Formulation Examples 1-2, Comparative Examples 1-2 First, the conventionally used thickener, Emarex O.
A hair dyeing test was conducted using P-5 as a comparative example. [Preparation of Hair Dye Composition] 1) Preparation of First Agent Using the samples shown in Table 1, a first agent was prepared according to a conventional method according to the following formulation.

<Formulation> First agent Isopropanol 5.0 wt% Sample (see Table 1) 5.0 to 26.0 Ammonium thioglycolate 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Ammonia water 6.0 Paraphenylenediamine 1.0 Resorcin 1.0 Fragrance Suitable amount Ion-exchanged water Residual

[0050]

[Table 1] ──────────────────────────────────── Test materials (blending amount) ──── ──────────────────────────────── Formulation 1 Maltitol monoisostearyl ether (5.0 wt%) + Polycoat H (1.0 wt%) Formulation Example 2 Isostearyl maltoside (5.0 wt%) + Polycoat H (1.0 wt%) Comparative Example 1 Emarex OP-5 * (25.0 wt%) + Oleic acid (10.0 wt%) %) Comparative Example 2 Emarex OP-5 * (25.0 wt%) + Oleic acid (10.0 wt%) + Polycoat H (1.0 wt%) ──────────────── ───────────────────── * POE (5) Octyl phenyl ether, manufactured by Nippon Emulsion Co., Ltd.

2) Preparation of Second Agent Next, a second liquid a which is a transparent liquid is prepared by a conventional method according to the formulation shown in Table 2 below.
And a cream liquid second agent b were prepared.

[Table 2] ──────────────────────────────────── 2nd agent component a (transparent liquid) b (cream liquid) ──────────────────────────────────── Hydrogen peroxide 30% 15.0 15 0.0 Phosphate buffer solution Adjusted to pH 3 Adjusted to pH 3 Methylparaben 0.1 0.1 Sodium stannate 0.1 0.1 Liquid paraffin-5.0 Stearyl alcohol-3.0 Sodium lauryl sulfate-0.5 POE (20 ) Cetyl ether − 0.5 Ion-exchanged water Residual residue ─────────────────────────────────────

[Hair Dyeing Test] An oxidative hair dye composition obtained by mixing each of the first agents of the above-mentioned formulation examples 1 and 2 and comparative examples 1 and 2 with each of the second agents at a weight ratio of 1: 1. Was used to carry out a hair dyeing test. Table 3 shows the properties before and after mixing and the results of the hair dyeing test.

[Table 3] ──────────────────────────────────── 1st agent 2nd agent Properties Dripping extension Uniformity Smoothness Before mixing After mixing ・ Applicability ──────────────────────────────────── Example 1 a Gel-like gel-like ◎ ◎ ◎ ◎ ◎ Blending example 2 a Gel-like gel ◎ ◎ ◎ ◎ ◎ Comparative example 1 a Liquid liquid × ○ × × Comparative example 2 a Precipitation − − − − − ────── ────────────────────────────── Recipe 1b Gel-like gel ◎ ◎ ◎ ◎ ◎ Recipe 2b Gel-like gel ◎ ◎ ◎ ◎ ◎ Comparative Example 1b Liquid Liquid × ○ × × Comparative Example 2b Precipitation − − − − − − ────────────────────────── ───────────

As can be seen from Table 3, the first agents (formulation examples 1 and 2) in which the sugar derivative and the cationic polymer compound (polycoat H) were used in combination were in a gel form and were mixed with any of the second agents. The first agent (Comparative Example 1) using a conventional thickener (Emarex OP-5 + oleic acid) was liquid, while it was gel-like, and remained liquid after mixing with the second agent. It was difficult to mix, and it was easy to become non-uniform. Further, the first agent (Comparative Example 2) in which the conventional thickener and the cationic polymer compound were used in combination caused precipitation, and it was shown that the cationic polymer compound cannot be blended in the conventional thickening system. Further, in the hair dyeing test, the oxidative hair dye compositions using the first agent of Formulation Examples 1 and 2 did not sag or run off, and the extensibility / applicability to hair was good, It was excellent in levelness and smoothness after dyeing. On the other hand, since the mixture of Comparative Example 1 using the conventional thickener is liquid, it has dripping and runoff, and has problems such as poor levelness and smoothness.

Comparative Examples 3 to 5 Using the samples shown in Table 4, a sugar derivative or a cationic polymer compound alone was blended in the same formulation as in Formulation Examples 1 and 2 above.
Agents (Comparative Examples 3 to 5) were prepared, and the respective second agents were mixed at a weight ratio of 1: 1 to prepare an oxidative hair dye composition.

[Table 4] ──────────────────────────────────── 1st agent Reagent (blending amount) ─ ─────────────────────────────────── Comparative Example 3 Maltitol monoisostearyl ether (5.0 wt%) Comparative Example 4 Isostearyl Maltoside (5.0 wt%) Comparative Example 5 Polycoat H (1.0 wt%) ──────────────────────────── ──────────

Properties of hair dye compositions using the first agent of Comparative Examples 3 to 5 and hair dye compositions using the above-mentioned Formulation Examples 1 and 2,
Tables 5 and 6 show a comparison of the results of the hair dyeing test, the dyeing property test and the washing resistance test.

[Table 5] ──────────────────────────────────── 1st agent 2nd agent Properties Dripping extension Properties Uniformity Smoothness Harness Dyeability (after mixing) ・ Applicability ・ Stiffness ─────────────────────────────── ────── Formulation 1 a gel ◎ ◎ ◎ ◎ ◎ ◎ ◎ Formulation 2 a gel ◎ ◎ ◎ ◎ ◎ ◎ ◎ Comparative Example 3 a gel ◎ ◎ △ △ ○ Comparative Example 4 a gel ◎ ◎ ◎ ◎ △ △ ○ Comparative Example 5a Liquid × △ × △ × × ──────────────────────────────────── ─ Formulation 1 b gel ◎ ◎ ◎ ◎ ◎ ◎ ◎ Formulation 2 b gel ◎ ◎ ◎ ◎ ◎ ◎ Comparative example 3 b gel ◎ ◎ ◎ △ △ ○ Comparative example 4 b gel ◎ ◎ ◎ ◎ △ △ ○ Comparison Example 5b Liquid × △ × △ △ × ────────────────── ─────────────────

[Table 6]

As can be seen from Tables 5 and 6, when the sugar derivative and the cationic polymer compound (Polycoat H) were used in combination (Formulation Examples 1 and 2), gel hair dye compositions were obtained, It does not drip, and has good spreadability / applicability to hair and level dyeability. It was also excellent in dyeing property and wash resistance. Furthermore, the hair after dyeing was very smooth and had an excellent feeling of use. On the other hand, when only the sugar derivative was blended (Comparative Examples 3 and 4), the properties and dripping were as in Formulation Examples 1 and 2.
Although there is not much difference in extensibility, coating property, and level dyeing property, dyeing property,
It was inferior in washing resistance and smoothness after dyeing.

Further, when only the cationic polymer compound was blended (Comparative Example 5), the obtained hair dye composition was in a liquid form and was used in any of the hair dyeing test, the dyeing test and the wash resistance test. Was also significantly inferior. From the above, it is understood that the effects of the present invention are obtained when the sugar derivative and the cationic polymer compound are used in combination.

Formulation Examples 3 to 10 and Comparative Examples 6 to 8 Using the samples shown in Tables 7 and 8, a first agent was prepared in the same formulation as in Formulation Examples 1 and 2, and the weight ratio to each of the second agents was adjusted. The mixture was mixed at a ratio of 1: 1 to obtain an oxidative hair dye composition.

[Table 7] ──────────────────────────────────── Mixing example Mixing example Mixing example Comparative example Comparative example Comparative Example Sample 3 4 5 6 7 8 ──────────────────────────────────── Isostearyl maltoside 7.0 − − − − − Maltitol Isostearyl Ether − 7.0 − − − − 2-Tetradecyl Octadecyl Maltosit − − 7.0 − − − Stearyl Maltosit − − − 7.0 − − 2-Hexyl Tesyl Maltosit − − − − 7.0 − 2-Hexadecyl octadecyl maltoside − − − − − 7.0 Polycoat H 0.5 0.5 0.5 0.5 0.5 0.5 ────────────────────────────── ─────── Properties Before mixing Gel-like gel-like gel-like liquid or liquid After separating and mixing + Second agent a) Gel-like gel-like gel-like liquid liquid after separation and mixing (+ 2nd agent b) gel-like gel-like gel-like liquid liquid separation hair dyeing test Dripping ◎ ◎ ◎ × ×-* Spreadability / coatability ◎ ◎ ◎ ○ ○ − * Level dyeing ◎ ◎ ◎ ◎ × × − * Smoothness ◎ ◎ ◎ ◎ △ △ − * Toughness and elasticity ◎ ◎ ◎ △ △ − * ───────────── ─────────────────────── − *: Indicates that the hair dyeing test was not performed.

[Table 8] ──────────────────────────────────── Mixing example Mixing example Mixing example Mixing example Mixing example Sample 6 7 8 9 10 ──────────────────────────────────── Isostearyl maltoside 7.0 7.0 7.0 7.0 7.0 Policoat H 0.001 0.01 8.0 15.0 20.0 ──────────────────────────────────── Hair dyeing test Dripping ◎ ◎ ◎ ◎ ◎ Extendability / applicability ◎ ◎ ◎ ◎ ◎ ○ Level dyeing ◎ ◎ ◎ ◎ ◎ △ Smoothness △ ○ ◎ ◎ ◎ ◎ Elasticity △ △ ◎ ◎ ◎ ◎ ───────────── ────────────────────────

As can be seen from Tables 7 and 8, in Examples 3 to 5 containing the sugar derivative of the present invention, gel-like oxidative hair dye compositions can be obtained, but the fatty chain is linear. In the case (Comparative Example 6) and the case where the total number of carbon atoms in the branched fatty chain was less than 18 (Comparative Example 7), the hair dye composition was liquid and did not form a gel. In addition, when the total number of carbon atoms in the branched fatty chain was larger than 32 (Comparative Example 8), separation occurred and a uniform hair dye composition could not be obtained. In addition, the hair dye compositions using Formulation Examples 3 to 5 were excellent in all evaluations in the hair dye test, but the hair dye compositions using the first agent of Comparative Examples 6 to 7 were liquid. There is dripping, etc.
Formulation Example 1 of the present invention also in coating properties, level dyeability, and smoothness
It was inferior to ~ 3. In addition, formulation examples 6 to 10
Therefore, when 0.01 to 15.0% by weight of the cationic polymer compound is blended in the hair dye composition of the present invention, the extensibility / coating property, the leveling property, and the smoothness are improved. If the amount of the cationic polymer compound is less than 0.01% by weight, the effect on smoothness is not exerted, and if the amount of the cationic polymer compound exceeds 15% by weight, the extensibility, coating property and leveling property are deteriorated. There was a tendency.

Formulation Examples 11 to 17 Each first agent was prepared using the samples shown in Table 9 in the same formulation as in Formulation Examples 1 and 2, and then mixed with each of the second agents in a weight ratio of 1: 1. Various tests were performed on each mixture.

[Table 9] ──────────────────────────────────── Composition example Sample 11 12 13 14 15 16 17 ──────────────────────────────────── Isostearyl maltoside 8.0 8.0 8.0 8.0 8.0 4.0 − Maltitol Isostearyl ether − − − − − 4.0 8.0 Mercoat 100 1.0 − − − 0.5 1.0 − Mercoat 550 − 1.0 − − 0.5 − 1.0 Polymer JR − 400 − − 1.0 − − − − Guffcoat 755 − − − 1.0 − − 1.0 ── ────────────────────────────────── Dripping ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ Extendability and coating ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ Level dyeing ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ Smoothness ◎ ◎ ◎ ◎ ◎ ◎ ◎ Elasticity ◎ ◎ ◎ ◎ ◎ ◎ ◎ Dyeing property ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ ◎ Cleaning resistance ○ ○ ○ ○ ○ ○ ○ ─────────────────────────────────────

From the above, by using the sugar derivative of the present invention in combination with the cationic polymer compound,
It is understood that an oxidative hair dye composition is obtained which has excellent hair dyeing properties, dyeing properties, wash resistance, and smoothness of hair after dyeing.

Formulation Example 18 The first agent and the second agent c prepared by the following formulation were mixed in a weight ratio of 1:
When mixed in No. 1, it was a gel composition having a uniform and appropriate viscosity, and did not drip from the hair during hair dyeing treatment.
Good extensibility, coating property, level dyeing property, dyeing property, washing resistance,
An oxidative hair dye composition having a smooth feeling after hair dyeing was obtained. <First Agent> Isopropanol 5.0 Isostearyl Maltoside 5.0 Natrim Hydrosulfite 0.1 L-Ascorbic Acid 0.5 EDTA 0.1 Monoethanolamine 1.0 Ammonia Water 6.0 Paraphenylenediamine 1. 0 Resorcin 0.5 Meta aminophenol 0.1 Perfume Appropriate amount Exchanged water Residue <Second agent c> Hydrogen peroxide water 15.0 Phosphate buffer solution Appropriate amount Sodium stannate 0.1 Methylparaben 0.1 Mercoat 550 1 .0

Formulation Example 19 Three-agent hair dye <First agent> Isopropanol 5.0 Isostearyl maltoside 5.0 Thioglycol ammonium 1.0 L-Ascorbic acid 0.5 EDTA 0.5 Ammonia water 7.0 Fragrance Appropriate amount Ion-exchanged water Residual <Second agent d> Hydrogen peroxide 30% 15.0 Phosphate buffer 0.1 Methylparaben 0.1 Sodium stannate 0.1 Ion-exchanged water Residual polymer JR400 1.0 <Third agent> Ammonium sulfate 2.0 Sodium metasilicate 20.0 Ammonium persulfate 75.0 EDTA 1.0 Carboxymethylcellulose 2.0

(Production Method) The formulation of the above-mentioned first agent was sequentially dissolved in ion-exchanged water to obtain a first agent. Also, the second agent d was prepared in the same manner. Each component of the third agent was well pulverized and mixed to obtain a third agent. Dissolve the third agent in the second agent d,
The agents were mixed to obtain a three-component hair dye. Usually, they are mixed in the above order, but the order is not limited to this. When the first agent, the second agent d, and the third agent are mixed in a weight ratio of 1: 1: 1 in the above formulation, a gel composition having a uniform and appropriate viscosity is obtained.
No dripping from the hair during hair dyeing, good spreadability, applicability, level dyeability, dyeability, wash resistance, smooth feeling after hair dyeing, oxidative hair dyeing composition The thing was obtained.

The first agent prepared according to the formulations of the following formulation examples 20 to 38 was mixed with the second agent a or the second agent b in Table 3 in a weight ratio of 1:
When mixed in 1, a gel-like oxidative hair dye composition having a uniform and appropriate viscosity was obtained. All of these do not drip from the hair during hair dyeing treatment, and have extensibility, applicability,
An oxidative hair dye composition having good levelness, dyeing property, and wash resistance, and having smooth hair after dyeing and an excellent feeling in use was obtained. Further, all the hair dye compositions were safe hair dye compositions with no irritation to the scalp.

Formulation Example 20 Isopropanol 5.0 Isostearyl Maltoside 2.0 Compound represented by the above general formula 3, wherein A is a 3.0 polymer of three glucose monosaccharides, and R is an isostearyl group. 550 4.0 Sodium hydrosulfite 0.1 L-ascorbic acid 0.5 EDTA 0.5 monoethanolamine 0.5 paratoluene diaminosulfate 1.0 resorcin 1.0 orthoaminophenol 0.1 paraaminophenol 0.01 Para-amino orthocresol 0.05 Fragrance Suitable amount Ion-exchanged water Residual

Formulation Example 21 Isopropanol 5.0 Isostearyl Maltoside 2.0 Compound represented by the above general formula 3, wherein A is a 2.0 polymer of three glucose monosaccharides, and R is an isostearyl group. A compound represented by the general formula 3 wherein A is a 1.0 polymer of four glucose monosaccharides and R is an isostearyl group Polycoat H 3.0 Sodium pyrosulfite 0.1 L-ascorbic acid 0.5 EDTA 0.5 monoethanolamine 0.5 paratoluene diaminosulfate 1.0 resorcin 1.0 orthoaminophenol 0.1 metaphenylenediamine 0.01 paraaminoorthocresol 0.05 perfume proper amount ion-exchanged water residual

Formulation Example 22 1,3-butylene glycol 3.0 isopropanol 5.0 isostearyl maltoside 5.0 polymer JR-400 0.5 keratin hydrolyzate 1.0 dimethylpolysiloxane (20cs) 2.0 sodium Hydrosulfite 0.1 L-Ascorbic acid 0.5 Hydroxyethanediphosphonic acid 0.5 Ammonia water 6.0 Monoethanolamine 1.0 Paraphenylenediaminosulfate 1.0 Resorcin 1.0 Paraaminophenol 0.1 Paranitro Ortho-phenylenediamine 0.01 Para-amino-ortho-cresol 0.01 Perfume Suitable amount Ion-exchanged water Residual

Formulation Example 23 Isopropanol 5.0 Vaseline 0.5 Isostearyl Maltoside 5.0 Isostearyl Maltototrioside 5.0 Polymer JR-125 0.3 Dimethylpolysiloxane (20cs) 1.0 Ammonium thioglycolate 0.5 L-ascorbic acid 0.5 EDTA 0.5 methylparaben 1.0 monoethanolamine 0.5 sodium hydroxide 0.2 paraphenylenediamine 1.0 paraaminoorthocresol 1.0 orthoaminophenol 0.1 perfume suitable Quantity Ion-exchanged water Residual

Formulation Example 24 Isopropanol 5.0 Isostearyl maltoside 5.0 Polymer JR-30M 1.0 Polycoat H 1.0 Ammonium thioglycolate 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Monoethanolamine 0.5 sodium bicarbonate 1.0 para-phenylenediamine 1.0 meta-aminophenol 1.0 ortho-aminophenol 0.1 meta-phenylenediamine 0.01 para-amino-ortho-cresol 0.01 perfume proper amount ion-exchanged water residual

Formulation Example 25 Maltitol Aqueous Solution 14.0 Isopropanol 5.0 Squalane 3.0 Isostearyl Maltoside 7.0 Gaffcoat 755 2.0 Sodium Hydrosulfite 0.1 L-Ascorbic Acid 0.5 EDTA 0.5 Ammonia water 6.0 Ammonium carbonate 2.0 Paratoluene diaminosulfate 1.0 Metaaminophenol 2.0 Orthoaminophenol 0.3 Perfume Suitable amount Ion exchange water Residual

Formulation 26 Benzyl alcohol 2.0 Isostearyl maltoside 8.0 Gaffcoat 734 2.5 Sodium pyrosulfite 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Monoethanolamine 0.5 Paraphenylenediamine 1 0.0 resorcin 1.0 orthoaminophenol 0.2 metaaminophenol 0.1 paraaminoorthocresol 0.05 perfume proper amount ion-exchanged water residual

Formulation Example 27 Isopropanol 5.0 Isostearyl maltoside 5.0 Merquat 550 1.0 Sodium hydrosulfite 0.5 L-Ascorbic acid 0.5 EDTA 0.5 Monoethanolamine 2.0 Paratoluene diaminosulfate 1.0 Resorcin 1.0 Para-aminophenol 0.1 Perfume Suitable amount Ion-exchanged water Residual

Formulation Example 28 Propylene glycol 10.0 Isopropanol 5.0 Isostearyl maltoside 5.0 Polycoat H 10.0 Cetanol 4.0 Keratin hydrolyzate 0.5 Sodium hydrosulfite 0.1 L-Ascorbic acid 0 .5 EDTA 0.5 ammonia water 6.0 paraphenylenediamine 1.0 paraaminophenol 1.0 paraaminoorthocresol 0.02 perfume proper amount ion-exchanged water residual

Formulation Example 29 Liquid paraffin 2.0 Isopropanol 5.0 Isostearyl maltoside 5.0 Polymer JR-30M 3.0 Sodium hydrosulfite 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Ammonia water 6 0.0 Para-phenylenediamine 1.0 Meta-aminophenol 1.0 Para-nitro-ortho-phenylenediamine 0.02 Fragrance Suitable amount Ion-exchanged water Residual

Formulation Example 30 Lanolin 2.0 Ethanol 5.0 Isostearyl Maltoside 10.0 Polymer JR-400 3.5 Sodium Pyrosulfite 0.1 Sodium Hydroxide 0.3 L-Ascorbic Acid 0.5 EDTA 0.1. 5 Methylparaben 1.0 Ammonia water 6.0 Paratoluene diaminosulfate 1.0 Resorcinol 1.0 Paraaminoorthocresol 0.5 Perfume Suitable amount Ion exchange water Residual

Formulation Example 31 Propylene glycol 10.0 Isopropanol 5.0 Isostearyl maltoside 5.0 Gaffcoat 734 8.0 Sodium hydrosulfite 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Methylparaben 1.0 Mono Ethanolamine 2.0 Ammonia water 5.0 Para-phenylenediamine 1.5 Resorcin 1.0 Para-aminophenol 0.2 Meta-aminophenol 0.1 Perfume Suitable amount Ion-exchanged water Residual

Formulation Example 32 Vaseline 2.0 Ethanol 5.0 Isostearyl maltoside 5.0 Gaffcoat 755 5.0 Sodium thiosulfate 0.1 N-Methylpyrrolidone 0.5 L-Ascorbic acid 0.5 EDTA 0.5 Methylparaben 0.1 Monoethanolamine 3.0 Potassium hydroxide 0.3 Paraphenylenediamine 1.0 Resorcinol 1.0 Metaaminophenol 0.1 Paraaminoorthocresol 0.05 Perfume Appropriate amount Ion-exchanged water Residual

Formulation Example 33 Lanolin 2.0 Isopropanol 5.0 Isostearyl Maltoside 5.0 Polymer JR-125 7.0 Maltitol Hydroxy Aliphatic Ether 2.0 Sodium Hydrosulfite 0.1 L-Ascorbic Acid 0.1. 5 EDTA 0.5 methylparaben 0.1 monoethanolamine 0.5 paraphenylenediamine 1.0 paraaminophenol 1.0 resorcin 0.05 paranitroorthophenylenediamine 0.02 perfume proper amount ion-exchanged water residual

Formulation 34 Oleic acid 20.0 Isostearyl maltoside 7.0 Merquat 550 10.0 Isopropanol 10.0 Ammonia water (28%) 8.0 Sodium hydrosulfite 0.1 EDTA 0.4 Paraphenylenediamine 0.3 Resorcin 0.05 Ion-exchanged water Residual

Formulation Example 35 Isopropanol 6.0 Isostearyl maltoside 9.0 Polycoat H 15.0 Ammonium thioglycolate 0.5 L-Ascorbic acid 0.5 EDTA 0.5 Monoethanolamine 0.5 Paratoluene diaminosulfate 1.0 Resorcin 1.0 Orthoaminophenol 0.1 Metaphenylenediamine 0.01 Paraaminoorthocresol 0.05 Fragrance Suitable amount Ion exchange water Residual

Formulation Example 36 Isopropanol 8.0 Isostearyl Maltoside 5.0 Polymer JR-400 2.5 L-Ascorbic Acid 0.5 EDTA 0.5 Methylparaben 1.0 Monoethanolamine 0.5 Sodium Hydroxide 0.0. 2 Paraphenylenediamine 1.0 Paraaminoorthocresol 1.0 Orthoaminophenol 0.1 Perfume Appropriate amount Ion-exchanged water Residual

Formulation Example 37 Benzyl alcohol 2.0 Isostearyl maltoside 8.0 Polymer JR-30M 1.5 Sodium pyrosulfite 0.1 L-Ascorbic acid 0.5 EDTA 0.5 Monoethanolamine 0.5 Paraphenylene Diamine 1.0 Resorcinol 1.0 Orthoaminophenol 0.2 Metaaminophenol 0.1 Paraaminoorthocresol 0.05 Perfume Appropriate amount Ion-exchanged water Residual

Formulation 38 Cetyl alcohol 2.0 Isostearyl maltoside 1.0 Gaffcoat 755 6.0 Ammonium thioglycolate 2.0 Edetate 0.2 Paraphenylenediamine 2.0 Orthoaminophenol 2.0 Resorcin 0 2 Residual ion-exchanged water

[0085]

The oxidative hair dye composition according to the present invention contains the sugar derivative and the cationic polymer compound,
It has an appropriate viscosity, does not drip from the hair during hair dyeing, has good spreadability, applicability, level dyeability, dyeability, and wash resistance. There is a feeling of firmness,
It has the characteristics of smoothness and excellent usability.

 ─────────────────────────────────────────────────── ─── Continued Front Page (72) Inventor Keiichi Uehara 1050 Shinba-cho, Kohoku-ku, Yokohama-shi, Kanagawa Inside Shiseido Daiichi Research Center, Inc. (72) Inventor Masakazu Okumura 5-1-1 Umei, Takasago-shi, Hyogo No. 1 Inside the Nippon Seika Co., Ltd. (72) Inventor Takafumi Kusumoto 2-3-7 Shimbashi, Minato-ku, Tokyo Inside Nihon Seika Co., Ltd. Tokyo Branch

Claims (8)

[Claims] 1. An oxidative hair dye composition comprising a sugar derivative represented by the general formula 1, a cationic polymer compound, and an oxidative dye. Embedded image (In the formula, A is a residue obtained by removing n hydroxyl groups from sugar, R is
Represents a fatty chain having a total carbon number of 18 to 32 and having a branched chain, and n represents 1 or more. ) 2. The oxidative hair dye composition according to claim 1, wherein the sugar derivative is a branched aliphatic glycoside represented by the general formula 2. Embedded image (However, in the formula, A is a residue obtained by removing a hemiacetal hydroxyl group from a sugar, and R is the same as the above chemical formula 1.) 3. The oxidative hair dye composition according to claim 1, wherein the sugar derivative is a sugar-branched aliphatic ether represented by the general formula 3. Embedded image (However, in the formula, A is a residue obtained by removing n non-hemiacetal hydroxyl groups from a sugar, and R and n are the same as those in the above chemical formula 1.) 4. The oxidative hair dye composition according to claim 1, wherein the sugar derivative is isostearyl maltoside. 5. The oxidative hair dye composition according to claim 1 or 3, wherein the sugar derivative is maltitol isostearyl ether. 6. The oxidative hair dye composition according to claim 1, wherein the cationic polymer compound is a poly (dimethylallylammonium halide) type cationic polymer,
Copolymer type cationic polymer of dimethyldiallylammonium halide and acrylamide, polyethylene glycol, epichlorohydrin, cationic polymer, polyethylene glycol, epichlorohydrin, propyleneamine and coconut, which is a condensation product type of taloylamine obtained from polyethylene glycol, propyleneamine and tallow fatty acid. Selected from the group of cationic polymers that are condensation product types of cocoylamine obtained from oil fatty acids, vinylpyrrolidone, dimethylaminomethacrylate copolymer type cationic polymers, and quaternary nitrogen-containing cellulose ether type cationic polymers An oxidative hair dye composition comprising one or more of the following. 7. The oxidative hair dye composition according to any one of claims 1 to 6, further comprising an oxidant. 8. The oxidative hair dye composition according to any one of claims 1 to 7, which is of a multi-agent type and which, when mixed, contains a sugar derivative, a cationic polymer compound, an oxidative dye, and an oxidant. Hair dye composition.