JP2008056606A - Oxidative hair dye composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an oxidative hair dye composition able to uniformly dye hair from the root to the tip of the hair, e.g., hardly dye skin surface even when the composition is adhered to the skin during its application, and impart excellent finger-passing through the hair and natural gloss inherited to the hair with preventing damages of the hair during the application. <P>SOLUTION: The oxidative hair dye composition comprises (a) hydrocarbons and/or wax solid at room temperature, preferably microcrystalline wax, (b) glycerol and/or polyglycerol, (c) a nonionic surfactant, preferably polyoxyethylene-cured castor oil and (d) a quaternary ammonium salt expressed by general formula 1. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

  The present invention relates to an oxidative hair dye composition.

  In general, the oxidative hair dye is generally of a two-part formula comprising a first agent containing an alkaline agent and a second agent containing hydrogen peroxide. This two-part oxidative hair dye generates oxygen by mixing the first agent and the second agent at the time of use, and oxidatively decomposes melanin pigment in the hair with this oxygen, and also converts the oxidative dye into the hair. To oxidatively polymerize and dye hair. In addition to the action of hydrogen peroxide, the alkaline agent in the first agent has an effect of improving the hair dyeing effect by swelling the cuticle on the hair surface and penetrating the dye into the hair. For this reason, compared with a temporary hair dye, an acid hair dye, etc., it is possible to dye in a lighter color tone than the original hair, and there is an advantage that the hair dyeing effect is continuous.

  However, since the effect of the oxidative hair dye is continuous, the color difference between the hair dyed and the hair root becomes conspicuous as the hair grows daily. This tendency becomes prominent when the oxidative hair dye is used for white hair dyeing. For this reason, especially in the case of white hair dyeing, it is desired that the oxidative hair dye adheres firmly from the root part of the hair to the tip of the hair, and the already-dyed part and the undyed part are dyed simultaneously in the same color tone. . In addition, since a hair dye is applied to the root portion of the hair, a hair dye that is difficult to be dyed to the background even if it adheres to the background is desired.

  As a technique for uniformly dyeing from the base of the hair to the end of the hair, an emulsified first agent for oxidative hair containing a specific amino-modified silicone, a long-chain dialkyl type quaternary ammonium salt and a higher alcohol and having a specific pH Compositions and the like have been reported (for example, see Patent Document 1). In addition, as a technique for suppressing background stains, a hair dye composition containing ascorbic acid and polyethylene glycol, an aerosol hair dye containing a specific oxidation dye and liquefied petroleum gas or dimethyl ether, and the like have been proposed. (For example, refer to Patent Documents 2-3).

  On the other hand, since the oxidative hair dye uses an alkaline agent, the keratin protein on the hair surface is decomposed and the hair is damaged, and the hair after dyeing has a problem that it is inferior in fingering and gloss. .

  In order to solve such problems, a hair dye containing a dimethyldiallylammonium chloride / acrylic acid copolymer and a protein hydrolyzate (see Patent Document 4), 2- (β-hydroxyethyl) -p-phenylene Oxidative hair dye composition containing diamine and two or more specific protein hydrolysates (see Patent Document 5), Hair dye composition containing marine collagen hydrolyzate and silicone derivative (Patent Document 6) Have been proposed). However, no hair dye that solves any of the above problems has been proposed yet.

JP 2005-187334 A JP 2005-53877 A JP 2005-162614 A JP 2002-338443 A JP 2002-226339 A JP 2005-343826 A

  The present invention has been made in view of the prior art, can be uniformly dyed from the root of the hair to the tip of the hair, even if the drug adheres to the background during the treatment, the background is difficult to be dyed, Moreover, it is an object to provide an oxidative hair dye composition capable of preventing hair damage during treatment and imparting excellent fingering property and natural natural luster of hair after hair dyeing. .

で表される四級アンモニウム塩を含有してなる酸化染毛剤組成物、
〔２〕 前記（ａ）成分が、マイクロクリスタリンワックスである前記〔１〕に記載の酸化染毛剤組成物、並びに
〔３〕 前記（ｃ）成分が、ポリオキシエチレン硬化ヒマシ油である前記〔１〕又は〔２〕に記載の酸化染毛剤組成物
に関する。 That is, the present invention
[1] (a) Hydrocarbons and / or waxes that are solid at room temperature, (b) glycerin and / or polyglycerin, (c) nonionic surfactant, and (d) the following general formula 1

An oxidative hair dye composition comprising a quaternary ammonium salt represented by:
[2] The oxidative hair dye composition according to [1], wherein the component (a) is microcrystalline wax, and [3] the component (c), which is polyoxyethylene hydrogenated castor oil. It relates to the oxidative hair dye composition according to [1] or [2].

  The oxidative hair dye composition of the present invention can uniformly dye from the root of the hair to the hair tip, and even if the drug adheres to the background during the treatment, the background is difficult to be dyed, and the hair being treated It is possible to prevent the damage of the hair and to impart excellent finger-handing properties and natural natural luster to the hair after dyeing.

  In the oxidative hair dye composition of the present invention, as essential components, (a) hydrocarbons and / or waxes solid at room temperature, (b) glycerin and / or polyglycerin, (c) nonionic surfactant And (d) a quaternary ammonium salt.

  The hydrocarbons that are solid at room temperature of the component (a) are not particularly limited, and examples thereof include hydrocarbons that are solid at room temperature, such as ceresin, paraffin wax, microcrystalline wax, polyethylene powder, petrolatum, ozokerite. . The waxes are not particularly limited, and examples thereof include candelilla wax, carnauba wax, lanolin, shellac, beeswax, rice bran wax and the like. Among these components (a), it is preferable to use microcrystalline wax because adhesion from the root to the tip of the hair and spreadability on the hair are improved. Moreover, (a) component can also be used individually by 1 type or in combination of 2 or more types as appropriate. In addition, the room temperature in this invention means the atmosphere of 1-30 degreeC.

  The content of the component (a) is not particularly limited as long as the effect of the present invention is exhibited, but from the viewpoint of improving the retention in hair and the storage stability, it is usually 0.05% by weight or more in the composition. The content is preferably 0.1% by weight or more. Moreover, from a viewpoint of making the elongation on hair favorable, it is 5 weight% or less normally in a composition, Preferably it is 3 weight% or less. Accordingly, the content of the component (a) is usually 0.05 to 5% by weight, and preferably 0.1 to 3% by weight.

  As the component (b), polyglycerin is used in addition to glycerin. Examples of the polyglycerin to be used include diglycerin, triglycerin, tetraglycerin, hexaglycerin, decaglycerin and the like, and are listed in “Compositional component standard by cosmetic variety” (published in April 1997, Yakuji Nippo). Polyglycerin may be used. In addition, (b) component may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.

  The content of the component (b) is not particularly limited as long as the effect of the present invention is exerted, but since it exhibits leveling and the background is difficult to be dyed, it is usually 0.1% by weight or more in the composition. It is preferably 1% by weight or more. Further, from the viewpoint of dyeability, it is usually 20% by weight or less, preferably 10% by weight or less in the composition. Accordingly, the content of component (b) is usually 0.1 to 20% by weight, preferably 1 to 10% by weight.

  Examples of the nonionic surfactant (c) include propylene glycol fatty acid ester, glycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene castor Oil, polyoxyethylene hydrogenated castor oil, polyethylene glycol fatty acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene lanolin, etc. One type may be used alone, or two or more types may be used in appropriate combination. Of these nonionic surfactants, it is preferable to use polyoxyethylene hydrogenated castor oil because of its good spreadability and leveling.

  The content of the component (c) is not particularly limited as long as the effect of the present invention is exhibited. However, from the viewpoint of good elongation on the hair and leveling after treatment, the content of the component is usually 0.00. It is 1% by weight or more, preferably 1% by weight or more. Further, from the viewpoint of suppressing skin irritation during the treatment, it is usually 10% by weight or less, preferably 8% by weight or less in the composition. Accordingly, the content of component (c) is usually 0.1 to 10% by weight, preferably 1 to 8% by weight.

As the quaternary ammonium salt of component (d), a quaternary ammonium salt represented by the following general formula 1 is used in the present invention.

  Specifically, ethyl sulfate isoalkanoic acid (14-20) aminopropylethyldimethylammonium ethylsulfate isoalkanoate (18-22) aminopropylethyldimethylammonium, ethylsulfate isostearate aminopropylethyldimethylammonium, ethylsulfate isononanoate amino Propylethyldimethylammonium, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium, ethyl sulfate lanolin fatty acid aminoethyltriethylammonium, ethyl sulfate lanolin fatty acid aminoethyl diethylmethylammonium, ethyl sulfate lanolin fatty acid aminoethyltrimethylammonium, ethyl sulfate lanolin fatty acid aminopropyltriethyl Ammonium, lanolin methylsulfate fatty acid aminoethyltrimethylan Bromide, can be exemplified methyl sulfate lanolin fatty acid aminopropyl ethyl dimethyl ammonium and the like. Among them, it is preferable to use a quaternary ammonium salt of a lanolin fatty acid derivative such as ethyl sulfate lanolin fatty acid aminopropylethyldimethylammonium from the viewpoint of improving the fingering after treatment and the gloss of hair. In addition, (d) component may be used individually by 1 type, and may be used in combination of 2 or more type as appropriate.

  The content of the component (d) is not particularly limited as long as the effect of the present invention is exhibited, but from the viewpoint of improving the fingering property after the treatment and the gloss of the hair, the content is usually 0.1. % By weight or more, preferably 0.5% by weight or more. Moreover, from a viewpoint of suppressing the squeaky feeling to hair, it is 5 weight% or less normally in a composition, Preferably it is 3 weight% or less. Accordingly, the content of component (c) is usually 0.1 to 5% by weight, preferably 0.5 to 3% by weight.

  The oxidative hair dye composition of the present invention can contain silicones. The silicones that can be used are not particularly limited as long as the effects of the present invention are exhibited. For example, amino-modified silicone derivatives such as aminoethylaminopropylsiloxane / dimethylsiloxane copolymer, trimethylsilylamodimethicone; dimethylsiloxane / methylstea Alcohol-modified silicones such as loxysiloxane copolymers; polyoxyalkylene-modified silicones such as poly (oxyethylene / oxypropylene) methylpolysiloxane copolymers and dimethylsiloxane / methyl (polyoxyethylene) siloxane copolymers; methylcyclopoly Examples include cyclic silicones such as siloxane; polyglycerin-modified silicones such as polyglyceryl-3, disiloxane, and dimethicone; dimethylpolysiloxane, methylphenylpolysiloxane, and the like. Aliphatic alcohol-modified silicones, epoxy-modified silicones, fluorine-modified silicones, perfluoroalkyl polyoxyalkylene-modified silicone, may be other modified silicones such as ammonium modified silicones. Of these, polyoxyalkylene-modified silicones can be preferably used from the viewpoint of improving the fingering after treatment and the gloss of hair.

  The content of the silicone is not particularly limited as long as the effect of the present invention is exhibited, but from the viewpoint of improving the fingering property after the treatment and the gloss of the hair, it is usually 0.01% by weight in the composition. Above, preferably 0.1% by weight or more. Further, from the viewpoint of storage stability of the preparation, it is usually 10% by weight or less, preferably 5% by weight or less in the composition. From these, the content of the silicone content is usually 0.01 to 10% by weight, and preferably 0.1 to 5% by weight.

  The oxidative dye used in the present invention is a dye used for oxidative hair dyes such as oxidative dye precursors and couplers. Examples of oxidative dye precursors include phenylenediamines, aminophenols, diaminopyridines, And salts thereof such as hydrochlorides and sulfates thereof. Specifically, p-phenylenediamine, toluene-2,5-diamine, toluene-3,4-diamine, 2,5-diaminoanisole, N-phenyl-p-phenylenediamine, N-methyl-p-phenylenediamine N, N-dimethyl-p-phenylenediamine, 6-methoxy-3-methyl-p-phenylenediamine, N, N-diethyl-2-methyl-p-phenylenediamine, N-ethyl-N- (hydroxyethyl) -P-phenylenediamine, N- (2-hydroxypropyl) -p-phenylenediamine, 2-chloro-6-methyl-p-phenylenediamine, 2-chloro-p-phenylenediamine, N, N-bis- (2 -Hydroxyethyl) -p-phenylenediamine, 2,6-dichloro-p-phenylenediamine, 2-chloro-6-butyl Phenylenediamines such as mu-p-phenylenediamine; p-aminophenol, o-aminophenol, 2,4-diaminophenol, 5-aminosalicylic acid, 2-methyl-4-aminophenol, 3-methyl-4-amino Phenol, 2,6-dimethyl-4-aminophenol, 3,5-dimethyl-4-aminophenol, 2,3-dimethyl-4-aminophenol, 2,5-dimethyl-4-aminophenol, 2-chloro- Examples include aminophenols such as 4-aminophenol and 3-chloro-4-aminophenol; diaminopyridines such as 2,5-diaminopyridine, and salts thereof.

  Couplers include resorcin, m-aminophenol, m-phenylenediamine, 2,4-diaminophenoxyethanol, 5-amino-o-cresol, 2-methyl-5-hydroxyethylaminophenol, 2,6-diaminopyridine, catechol And pyrogallol, gallic acid, tannic acid and the like and salts thereof.

  As others, those listed in "Quasi-drug raw material standards" (issued in June 1991, Yakuji Nippo) can also be used as appropriate. Moreover, the above-mentioned oxidation dye precursor and coupler can be used individually by 1 type or in combination of 2 or more types, It is preferable to use an oxidation dye precursor at least. In addition, content of oxidation dye should just be about 0.01 to 10 weight% in a composition from viewpoints of safety, such as hair dyeing property and skin irritation.

  The alkali agent used in the present invention is not particularly limited. For example, ammonia, ammonium carbonate, ammonium bicarbonate, isopropanolamine, monoethanolamine, diethanolamine, triethanolamine, 2-amino-2-methyl-1-propanol These can be used, and one of these can be used alone, or two or more can be used in appropriate combination.

  The content of the alkaline agent is not particularly limited, but is preferably 0.01% by weight or more, more preferably 0.1% by weight or more in the composition from the viewpoint of hair dyeing power. Moreover, from a viewpoint of the hair damage prevention effect, 20 weight% or less is preferable in a composition, and 10 weight% or less is more preferable. From these, preferable content is 0.01 to 20 weight%, More preferably, it is 0.1 to 10 weight%.

  The oxidizing agent used in the present invention is not particularly limited as long as it exhibits an oxidizing action, and examples thereof include hydrogen peroxide, urea peroxide, and alkali metal bromate. Of these, hydrogen peroxide is preferably used, and is usually used as a hydrogen peroxide solution.

  The content of the oxidizing agent is preferably 0.1 to 5% by weight, more preferably 0.5 to 4% by weight in the composition from the viewpoint of exhibiting an oxidizing action and suppressing hair damage. preferable.

  In addition, ascorbic acid and / or an ascorbic acid derivative can be contained from the viewpoint of preventing oxidation of the oxidative dye during preparation storage. Ascorbic acid derivatives that can be used include, for example, sodium ascorbate, potassium ascorbate, calcium ascorbate, ammonium ascorbate, erythorbic acid, sodium erythorbate, magnesium ascorbate phosphate, ascorbyl citrate, ascorbyl acetate, tartaric acid Examples include ascorbyl, ascorbyl palmitate, ascorbyl stearate, and ascorbyl glucoside.

  In the oxidative hair dye composition of the present invention, in addition to the above-mentioned components, lower alcohols such as ethanol and isopropanol; lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, etc., as long as the effects of the present invention are not impaired Higher alcohols; higher fatty acids such as lauric acid, myristic acid, stearic acid, oleic acid; esters such as myristyl myristate, isostearyl myristate, stearyl stearate; Oil: Polyhydric alcohol such as polyethylene glycol, 1,3-butylene glycol, 1,2-pentanediol, 1,2-octanediol; higher fatty acid soap, alkyl sulfate ester salt, alkyl phosphate salt, polyoxyethylene alkyl ether Sulfate Anionic surfactants such as alkyl ether phosphates, alkyl ether carboxylates, acylmethyl taurates, alkylsulfosuccinic acids and their salts; cationic surfactants such as lauryltrimethylammonium chloride, cetyltrimethylammonium chloride, stearyltrimethylammonium chloride Glycine type amphoteric surfactants such as alkylglycine salts, carboxymethylglycine salts, N-acylaminoethyl-N-2-hydroxyethylglycine salts, aminopropionic acids such as alkylaminopropionates and alkyliminodipropionates -Type amphoteric surfactants, alkyl dimethylaminoacetic acid betaines, aminoacetic acid betaine-type amphoteric surfactants such as fatty acid amidopropyldimethylaminoacetic acid betaines, alkylhydroxysulfobetaines, etc. Amphoteric surfactants such as sulfobetaine type amphoteric surfactants; pigments such as Red No. 2, Red No. 102, Yellow No. 202 (1), Yellow No. 202 (2), Yellow No. 203, Black No. 401; pH Stabilizers, chelating agents, thickeners, anti-inflammatory agents, ultraviolet absorbers, fragrances, water and the like can be appropriately contained depending on the purpose.

  When the oxidative hair dye composition of the present invention is used as a two-part oxidative hair dye, among the above components, the first agent contains an alkali agent and an oxidative dye, and the second agent oxidizes. The first agent and the second agent may be mixed and used at a ratio of usually 1: 5 to 5: 1.

  EXAMPLES Hereinafter, although this invention is demonstrated further in detail based on an Example, this invention is not limited only to this Example. The content represents “% by weight” unless otherwise specified. Further, the number of moles of polyoxyethylene added is, for example, expressed as POE (20) hydrogenated castor oil when the number of moles added is 20 moles.

(Sample preparation)
According to the composition described in Table 1 and Table 2, the first oxidation hair dye was prepared by a conventional method. Moreover, the following formula was prepared by a conventional method as an oxidative hair dye second agent. The obtained 1st agent and 2nd agent were mixed by weight ratio 1: 1, and the oxidative hair dye composition of Examples 1-5 and Comparative Examples 1-4 was obtained.

(Second agent)
35% hydrogen peroxide solution 16.5
60% hydroxyethanediphosphonic acid 0.2
85% phosphoric acid 0.01
Purified water balance
Total 100.0

[Test Example 1: Evaluation of oxidative hair dye composition]
Each oxidative hair dye composition obtained above was uniformly applied to two-thirds from the tip of a white human hair bundle having a weight of 3 g and a length of 10 cm, left for 20 minutes in an atmosphere at 30 ° C., and then shampooed. The medicine was washed with water and dried with a dryer. Furthermore, after repeating the shampoo treatment and the dryer treatment three times, the hair bundle was applied with the same oxidative hair dye composition uniformly from the root to the tip, left standing at 30 ° C. for 20 minutes, and then shampooed. Dried with a dryer.

  By means of 20 expert panelists, uniform dyeability from the root of the hair to the tip of the hair, finger touchability (smoothness), and gloss were evaluated according to the following evaluation criteria. The results are shown in Tables 1 and 2.

(Evaluation criteria for dyeability)
A: 16 or more of 20 people answered that the hair was uniformly dyed from the root to the hair tip ○: 11-15 people out of 20 answered that the hair was uniformly dyed from the hair root to the hair tip Δ: 20 Responding that 6 to 10 of the names were uniformly dyed from the root of the hair to the tip of the hair. X: Answering that 5 or less of the 20 people were uniformly dyed from the root of the hair to the tip of the hair.

(Assessment criteria for fingering)
◎: Answer that 16 or more out of 20 people should follow the finger ○: Answer that 11 to 15 out of 20 people should follow the finger △: Answer that 6 to 10 out of 20 people should follow the finger ×: 20 5 or less people answered that they should follow their finger

(Evaluation criteria for gloss)
◎: More than 16 out of 20 responded that the gloss of the hair is natural gloss ○: 11-15 out of 20 responded that the gloss of the hair was natural △: 6-10 out of 20 Answered that hair gloss is natural gloss ×: 5 or less of 20 people answered that hair gloss is natural gloss

[Test Example 2: Evaluation of oxidative hair dye composition]
About 0.5 g of each oxidative hair dye composition obtained above was uniformly attached to the inner side of the upper arm in a circular shape having a diameter of 1 cm, and then allowed to stand at room temperature for 20 minutes. After washing the chemical with water, the moisture was wiped off with a towel, and the stainability on the background was evaluated by 20 professional panelists according to the following evaluation criteria. The results are shown in Tables 1 and 2.

(Evaluation criteria for dyeability on the background)
◎: More than 16 out of 20 people answered that there was little dyeing on the background ○: 11-15 out of 20 people answered that there was little dyeing on the background △: 6-10 out of 20 people answered on the background Answer that there is little dyeing property ×: 5 or less of 20 people answered that there is little dyeing property to the background

  From the results of Tables 1 and 2, the oxidative hair dye composition of the present invention can be uniformly dyed from the root of the hair to the hair tip, and even if the drug adheres to the background during the treatment, the background is difficult to be dyed. I understand that Moreover, it turns out that the oxidation hair dye composition of this invention can prevent the damage of the hair during treatment, and can provide the fingernail property excellent in the hair after hair dyeing, and the natural natural luster of hair.

Hereinafter, formulation examples of the oxidative hair dye composition of the present invention will be shown. The blending amount represents “% by weight”.
[Prescription Example 1]
(Oxidative hair dye 1st agent)
Polyoxyethylene (20) hydrogenated castor oil 5.0
Polyoxyethylene (20) cetyl ether 2.5
30% stearyltrimethylammonium chloride 3.0
Microcrystalline wax 2.0
Cetyl alcohol 4.0
Oleyl alcohol 2.0
Glycerin 3.0
Ethanol sulfate lanolin fatty acid aminopropyl
Ethyldimethylammonium 2.0
Polyoxyethylene (50)
Methylpolysiloxane copolymer 1.0
Monoethanolamine 4.0
28% ammonia water 3.0
Ammonium carbonate 0.8
Paraphenylenediamine 0.4
Resorcin 0.35
2,4-Diaminophenoxyethanol hydrochloride 0.03
Metaaminophenol 0.05
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Jojoba oil 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Purified water balance
Total 100.0

[Prescription Example 2]
(Oxidative hair dye 1st agent)
Polyoxyethylene (40) hydrogenated castor oil 5.0
Polyoxyethylene (20) stearyl ether 2.0
30% stearyltrimethylammonium chloride 3.0
Paraffin wax 2.0
Stearyl alcohol 4.0
Isostearyl alcohol 2.0
Polyglycerin 3.0
Ethanol sulfate lanolin fatty acid aminopropyl
Ethyldimethylammonium 2.0
Polyoxyethylene (50)
Methylpolysiloxane copolymer 1.0
Monoethanolamine 4.0
28% ammonia water 3.0
Paraphenylenediamine 0.4
Paraaminophenol 0.2
Resorcin 0.35
Metaaminophenol 0.05
L-cysteine hydrochloride 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
L-glutamic acid 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Purified water balance
Total 100.0

[Prescription Example 3]
(Oxidative hair dye 1st agent)
Polyoxyethylene (20) hydrogenated castor oil 5.0
Polyoxyethylene (20) behenyl ether 2.5
30% stearyltrimethylammonium chloride 3.0
Candelilla Row 1.5
Behenyl alcohol 4.0
Diglycerin 3.0
Aminopropyl isostearate ethylsulfate
Ethyldimethylammonium 2.0
Polyoxyethylene (50)
Methylpolysiloxane copolymer 1.0
Isopropanolamine 4.0
28% ammonia water 3.0
Ammonium carbonate 0.8
Paraphenylenediamine 0.4
Resorcin 0.35
Metaaminophenol 0.05
5- (2-Hydroxyamino) -2-methylphenol 0.2
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Panthenol 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Purified water balance
Total 100.0

[Prescription Example 4]
(Oxidative hair dye 1st agent)
Polyoxyethylene (20) hydrogenated castor oil 5.0
Polyoxyethylene (20) cetyl ether 2.5
30% stearyltrimethylammonium chloride 3.0
Vaseline 1.0
Cetyl alcohol 4.0
Oleyl alcohol 2.0
Decaglycerin 2.0
Ethanol sulfate lanolin fatty acid aminopropyl
Triethylammonium 2.0
Aminoethylaminopropylmethylsiloxane
Dimethylsiloxane copolymer 1.0
Monoethanolamine 4.0
28% ammonia water 3.0
Ammonium carbonate 0.8
Toluene sulfate-2,5-diamine 0.4
Resorcin 0.35
5-aminoorthocresol 0.03
Metaaminophenol 0.05
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Loquat leaf extract 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Purified water balance
Total 100.0

[Prescription Example 5]
(Oxidative hair dye 1st agent)
Polyoxyethylene (20) hydrogenated castor oil 3.0
Polyoxyethylene (20) cetyl ether 2.0
30% stearyltrimethylammonium chloride 3.0
Microcrystalline wax 2.0
Cetyl alcohol 3.0
Oleyl alcohol 2.0
Glycerin 3.0
Polyoxyethylene (50)
Methylpolysiloxane copolymer 1.0
Monoethanolamine 4.0
28% ammonia water 3.0
Ammonium carbonate 0.8
Paraphenylenediamine 0.4
Resorcin 0.35
2,4-Diaminophenoxyethanol hydrochloride 0.03
Metaaminophenol 0.05
Anhydrous sodium sulfite 0.5
Sodium L-ascorbate 0.5
Edetate disodium 0.2
Water-soluble collagen 0.1
Purified water balance
Total 100.0

(Oxidative hair dye second agent)
35% hydrogen peroxide solution 16.5
Polyoxyethylene (40) hydrogenated castor oil 0.5
Polyoxyethylene (20) cetyl ether 2.0
Aminopropyl isostearate ethylsulfate
Ethyldimethylammonium 0.8
Cetanol 2.0
60% hydroxyethanediphosphonic acid 0.2
85% phosphoric acid 0.01
Purified water balance
Total 100.0

Claims (3)

(A) hydrocarbons and / or waxes that are solid at room temperature, (b) glycerin and / or polyglycerin, (c) nonionic surfactant, and (d) the following general formula 1

An oxidative hair dye composition comprising a quaternary ammonium salt represented by the formula:   The oxidative hair dye composition according to claim 1, wherein the component (a) is a microcrystalline wax. The oxidative hair dye composition according to claim 1 or 2, wherein the component (c) is polyoxyethylene hydrogenated castor oil.