JP2009054641A - High-output diamond semiconductor element - Google Patents
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本発明は、高出力ダイヤモンド半導体素子に関し、とくにダイヤモンドショットキーバリアダイオードなどの高出力ダイヤモンド半導体素子に好適に用いることが出来る高出力ダイヤモンド半導体素子に関する。 The present invention relates to a high-power diamond semiconductor element, and more particularly to a high-power diamond semiconductor element that can be suitably used for a high-power diamond semiconductor element such as a diamond Schottky barrier diode.
ダイヤモンド半導体は、大きなバンドギャップ(5.5eV)、高いアバランシェ破壊電界(10MV/cm)、高い飽和キャリア移動度(4,000cm2/Vs)、高い熱伝導率(20W/cmK)を有し、高温度や放射線曝露環境下で実用動作可能な素子として期待されている。これまでにこれらの特徴を生かした電子素子を開発するため、ダイヤモンドダイオードの構造および作製方法が提案されている。
一般に高電圧動作ダイオードでは、電極縁辺に発生する電界集中を抑えるため、pn接合を用いたガードリング構造(非特許文献1参照)、フィールドプレート構造(非特許文献2参照)もしくはこれらを組み合わせた構造(非特許文献3参照)などが用いられる。ダイヤモンドにおいては、p型およびn型ドーピングが実現しておりpn接合が実現しているが、n型ドーピングは極めて難しく、形成したpn接合界面でのリーク電流値も大きい(非特許文献4及び非特許文献5参照)ため、高電圧で低リーク電流を実現する電極縁辺電界緩和技術は得られていない。
Diamond semiconductor has a large band gap (5.5 eV), high avalanche breakdown electric field (10 MV / cm), high saturation carrier mobility (4,000 cm 2 / Vs), high thermal conductivity (20 W / cmK), high temperature It is expected to be a device that can be used practically in environments exposed to radiation and radiation. In order to develop an electronic device taking advantage of these characteristics, a structure and a manufacturing method of a diamond diode have been proposed.
In general, in a high voltage operating diode, a guard ring structure using a pn junction (see Non-Patent Document 1), a field plate structure (see Non-Patent Document 2) or a combination of these is used in order to suppress electric field concentration occurring at the electrode edge. (See Non-Patent Document 3). In diamond, p-type and n-type doping is realized and a pn junction is realized. However, n-type doping is extremely difficult, and a leak current value at the formed pn junction interface is large (Non-Patent
本発明は、p型ダイヤモンド上の選択領域に半絶縁性窒素ドープダイヤモンド層を形成することにより、電極縁辺の電界集中を抑えることが可能となり、高電界でも低リーク電流で高い電圧まで動作するダイヤモンド素子を提供する。 In the present invention, by forming a semi-insulating nitrogen-doped diamond layer in a selected region on p-type diamond, it becomes possible to suppress electric field concentration at the electrode edge, and diamond that operates to a high voltage with a low leakage current even in a high electric field. An element is provided.
上記目的を達成するために本発明は、ショットキー電極とダイヤモンドp−ドリフト層の接合面の一部に、pn接合層を設けることにより、カソード電極付近の電界を緩和する構造を見出した。
すなわち、本発明は、ショットキー電極をカソードとし、オーミック電極をアノードとするショットキー電極、ダイヤモンドp−ドリフト層、ダイヤモンドp+オーミック層、オーミック電極からなる構造の高出力ダイヤモンド半導体素子において、ショットキー電極とダイヤモンドp−ドリフト層の接合面の一部に、pn接合層を設けることを特徴とする高出力ダイヤモンド半導体素子である。
また、本発明においては、上記のpn接合層を、窒素ドープn型ダイヤモンド層とすることができる。
さらに、本発明においては、窒素ドープの濃度を、1e15〜1e18/cm3とすることができる。
また、さらに本発明においては、pn接合層を、窒素ドープn型ダイヤモンド層であり、かつ、選択成長させたダイヤモンド層とすることができる。
さらに、本発明においては、ショットキー電極に接合するダイヤモンドは、ダイヤモンド表面が酸素終端のダイヤモンドが特に好ましい。
In order to achieve the above object, the present invention has found a structure that relaxes the electric field in the vicinity of the cathode electrode by providing a pn junction layer on a part of the junction surface between the Schottky electrode and the diamond p - drift layer.
That is, the present invention relates to a high-power diamond semiconductor element having a structure including a Schottky electrode having a Schottky electrode as a cathode and an ohmic electrode as an anode, a diamond p - drift layer, a diamond p + ohmic layer, and an ohmic electrode. The high-power diamond semiconductor element is characterized in that a pn junction layer is provided on a part of the junction surface between the electrode and the diamond p - drift layer.
In the present invention, the pn junction layer can be a nitrogen-doped n-type diamond layer.
Furthermore, in the present invention, the concentration of nitrogen dope can be set to 1e 15 to 1e 18 / cm 3 .
In the present invention, the pn junction layer can be a nitrogen-doped n-type diamond layer and a selectively grown diamond layer.
Furthermore, in the present invention, the diamond bonded to the Schottky electrode is particularly preferably a diamond whose diamond surface has an oxygen termination.
本技術により、高出力ダイヤモンド半導体素子の高電界印加時におけるリーク電流が減少し、また動作可能電圧を高くすることができる。 According to the present technology, the leakage current when a high electric field is applied to the high-power diamond semiconductor element is reduced, and the operable voltage can be increased.
本発明において用いるショットキー電極は、周知の材料を用いて、周知の方法により作成することができる。
本発明で用いる高出力ダイヤモンド半導体においては、ダイヤモンドp−ドリフト層、ダイヤモンドp+オーミック層、ダイヤモンドpn接合層は、ダイヤモンドならどのタイプのものでも良い。例えば、ダイヤモンド結晶構造に関しては、結晶構造(001)、(111)、(110)などが挙げられ、ダイヤモンド表面では、炭素終端ダイヤモンド、水素終端ダイヤモンド、酸素終端のダイヤモンドなどが挙げられる。
しかし、少なくともショットキー電極に接合するダイヤモンドは、ダイヤモンド表面が酸素終端のダイヤモンドが特に適していることが判明している。
The Schottky electrode used in the present invention can be manufactured by a known method using a known material.
In the high-power diamond semiconductor used in the present invention, the diamond p − drift layer, the diamond p + ohmic layer, and the diamond pn junction layer may be any type of diamond. For example, regarding the diamond crystal structure, crystal structures (001), (111), (110) and the like can be cited. On the diamond surface, carbon-terminated diamond, hydrogen-terminated diamond, oxygen-terminated diamond and the like can be cited.
However, it has been found that at least diamond bonded to the Schottky electrode is particularly suitable for diamond whose diamond surface is oxygen-terminated.
さらに、本発明におけるpn接合層は、メタンと水素と酸素原子を含んだガスとを原料ガスとするマイクロ波プラズマCVD法により形成することができる。
また、pn接合層は、pもしくはp-型ダイヤモンド上に選択合成もしくはイオン注入法により窒素ドープダイヤモンド領域を形成することができる。
Furthermore, the pn junction layer in the present invention can be formed by a microwave plasma CVD method using methane, hydrogen, and a gas containing oxygen atoms as source gases.
In the pn junction layer, a nitrogen-doped diamond region can be formed on p or p-type diamond by selective synthesis or ion implantation.
pn接合に逆方向バイアス、すなわち、カソード側に正の電圧を印加すると、n型、p型領域それぞれに於いて、多数キャリアが少数キャリアの注入によって減少する。これによって空乏層幅が増大する。このように、空乏層を十分に増大させるためには窒素ドープがp型(ボロンドープ)に対して同程度以上なものであることが望ましい。窒素ドープのほか、リンのドーピングはn型ダイヤモンド半導体を作るために有効だと考えらるが、リンのドーピングを使ったPN接合では漏れ電流が大きくなるので、好ましくない。その点Nドープは、比較的簡単に得られるうえ、絶縁性も良好であるので、Nドープが好ましい。
本発明について実施例を用いてさらに詳しく説明するが、本発明はこれら実施例に限定されるものではない。
When a reverse bias is applied to the pn junction, that is, a positive voltage is applied to the cathode side, majority carriers are reduced by minority carrier injection in each of the n-type and p-type regions. This increases the depletion layer width. Thus, in order to sufficiently increase the depletion layer, it is desirable that the nitrogen doping is equal to or higher than the p-type (boron doping). In addition to nitrogen doping, phosphorus doping is considered to be effective for making an n-type diamond semiconductor, but a PN junction using phosphorus doping is not preferable because the leakage current increases. In this respect, N-doping is preferable because it can be obtained relatively easily and has good insulating properties.
The present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples.
図1(a)の構造はp-基板をSiO2マスク等を用いることでエッチングし、エッチングを施した部位にN2ドープ半絶縁性ダイヤモンドを選択成長させることで実現する。あるいは、p-基板上にイオン打ち込み技術を使ってN2をドーピングすることで実現することができる。そのようにしてできたPN接合上にマスクを施し、ショットキー電極を設けることで耐圧構造を持つショットキーバリアダイオードとなる。
図1(b)の構造はp-基板にマスクを施し、N2ドープ半絶縁性ダイヤモンドを選択成長させることで作成される。そのようにしてできたPN接合上にマスクを施し、ショットキー電極を設けることで耐圧構造を持つショットキーバリアダイオードとなる。
The structure shown in FIG. 1 (a) is realized by etching the p-substrate using a SiO2 mask or the like and selectively growing N2 doped semi-insulating diamond in the etched portion. Alternatively, it can be realized by doping N 2 on the p-substrate using an ion implantation technique. A Schottky barrier diode having a withstand voltage structure is obtained by masking the PN junction thus formed and providing a Schottky electrode.
The structure of FIG. 1 (b) subjecting the mask to the p- substrate, is prepared by selectively growing the N 2 doped semi-insulating diamond. A Schottky barrier diode having a withstand voltage structure is obtained by masking the PN junction thus formed and providing a Schottky electrode.
図1(a),(b)において、10ミクロンのドリフト層を設け、その活性ボロン濃度は5×1015とし、電極サイズはΦ30ミクロンとした。初期の破壊電圧(1)は、なだれ破壊による絶縁破壊を主なパラメータとし、並行平板モデルで考えたときに最大4.3MV/cm程度の電界を想定したところ、880Vの破壊電圧となった。窒素ドープn型ドープ層を設けたところ、その破壊電圧はおよそ倍程度にすることができることがわかった。図2(2)および(3)にその逆方向バイアス特性を示している。それぞれ、図1(a),(b)に対応するものであるが、両者とも非終端電極に対して大幅な改善が見られる。 In FIGS. 1 (a) and 1 (b), a drift layer of 10 microns is provided, the active boron concentration is 5 × 10 15 , and the electrode size is Φ30 microns. The initial breakdown voltage (1) was a breakdown voltage of 880 V assuming an electric field of about 4.3 MV / cm when considering the dielectric breakdown due to avalanche breakdown as the main parameter and considering the parallel plate model. When a nitrogen-doped n-type doped layer was provided, it was found that the breakdown voltage can be approximately doubled. 2 (2) and 2 (3) show the reverse bias characteristics. Each corresponds to FIGS. 1 (a) and 1 (b), but both show significant improvements over the non-terminated electrodes.
高出力ダイヤモンド半導体素子は、とくにダイヤモンドショットキーバリアダイオードに適しているが、その他、ダイヤモンドpnダイオード、ダイヤモンドサイリスタ、ダイヤモンドトランジスタ、ダイヤモンド電界効果トランジスタなど幅広く応用することが出来るので、産業上の利用可能性が高いものである。 High-power diamond semiconductor devices are particularly suitable for diamond Schottky barrier diodes, but they can also be used in a wide range of applications such as diamond pn diodes, diamond thyristors, diamond transistors, and diamond field effect transistors, so that they can be used industrially. Is expensive.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012050157A1 (en) * | 2010-10-13 | 2012-04-19 | 独立行政法人産業技術総合研究所 | Diamond electronic element and process for production thereof |
JP2012084702A (en) * | 2010-10-13 | 2012-04-26 | National Institute Of Advanced Industrial & Technology | Diamond electronic element and manufacturing method thereof |
JP2012084703A (en) * | 2010-10-13 | 2012-04-26 | National Institute Of Advanced Industrial & Technology | Diamond electronic element and manufacturing method thereof |
WO2015079671A1 (en) * | 2013-11-29 | 2015-06-04 | 株式会社デンソー | Semiconductor device using diamond |
US9331150B2 (en) | 2014-02-17 | 2016-05-03 | Kabushiki Kaisha Toshiba | Semiconductor device and method of manufacturing the same |
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JP6727928B2 (en) | 2016-05-30 | 2020-07-22 | 株式会社東芝 | Semiconductor device |
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JPH0426161A (en) * | 1990-05-21 | 1992-01-29 | Sumitomo Electric Ind Ltd | Forming method of schottky junction |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012050157A1 (en) * | 2010-10-13 | 2012-04-19 | 独立行政法人産業技術総合研究所 | Diamond electronic element and process for production thereof |
JP2012084702A (en) * | 2010-10-13 | 2012-04-26 | National Institute Of Advanced Industrial & Technology | Diamond electronic element and manufacturing method thereof |
JP2012084703A (en) * | 2010-10-13 | 2012-04-26 | National Institute Of Advanced Industrial & Technology | Diamond electronic element and manufacturing method thereof |
WO2015079671A1 (en) * | 2013-11-29 | 2015-06-04 | 株式会社デンソー | Semiconductor device using diamond |
JP2015106650A (en) * | 2013-11-29 | 2015-06-08 | 株式会社デンソー | Semiconductor device |
US9711638B2 (en) | 2013-11-29 | 2017-07-18 | Denso Corporation | Semiconductor device using diamond |
US9331150B2 (en) | 2014-02-17 | 2016-05-03 | Kabushiki Kaisha Toshiba | Semiconductor device and method of manufacturing the same |
EP2908349B1 (en) * | 2014-02-17 | 2017-05-31 | Kabushiki Kaisha Toshiba | Semiconductor device and method of manufacturing the same |
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