JP2008513339A5 - - Google Patents
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- Publication number
- JP2008513339A5 JP2008513339A5 JP2007532541A JP2007532541A JP2008513339A5 JP 2008513339 A5 JP2008513339 A5 JP 2008513339A5 JP 2007532541 A JP2007532541 A JP 2007532541A JP 2007532541 A JP2007532541 A JP 2007532541A JP 2008513339 A5 JP2008513339 A5 JP 2008513339A5
- Authority
- JP
- Japan
- Prior art keywords
- reactor
- hydrogen
- metal layer
- catalyst bed
- gas separation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229910052739 hydrogen Inorganic materials 0.000 claims 19
- 239000001257 hydrogen Substances 0.000 claims 19
- 229910052751 metal Inorganic materials 0.000 claims 14
- 239000002184 metal Substances 0.000 claims 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 12
- 239000000758 substrate Substances 0.000 claims 10
- 239000003054 catalyst Substances 0.000 claims 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims 8
- 239000007789 gas Substances 0.000 claims 7
- 150000002431 hydrogen Chemical class 0.000 claims 7
- 238000000926 separation method Methods 0.000 claims 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 6
- 238000000629 steam reforming Methods 0.000 claims 5
- 239000000956 alloy Substances 0.000 claims 4
- 229910045601 alloy Inorganic materials 0.000 claims 4
- 210000004027 cells Anatomy 0.000 claims 4
- 239000000446 fuel Substances 0.000 claims 4
- 229910052763 palladium Inorganic materials 0.000 claims 4
- 238000006243 chemical reaction Methods 0.000 claims 3
- 239000007795 chemical reaction product Substances 0.000 claims 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- 239000012528 membrane Substances 0.000 claims 3
- 229910052987 metal hydride Inorganic materials 0.000 claims 3
- 150000004681 metal hydrides Chemical class 0.000 claims 3
- 229910052759 nickel Inorganic materials 0.000 claims 3
- 239000000047 product Substances 0.000 claims 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 2
- 239000001569 carbon dioxide Substances 0.000 claims 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 2
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 2
- 239000000919 ceramic Substances 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- 238000006356 dehydrogenation reaction Methods 0.000 claims 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- 239000011148 porous material Substances 0.000 claims 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N precursor Substances N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 claims 2
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- 210000004940 Nucleus Anatomy 0.000 claims 1
- 239000005092 Ruthenium Substances 0.000 claims 1
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 claims 1
- 239000006227 byproduct Substances 0.000 claims 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- 150000002739 metals Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 1
- 229910052750 molybdenum Inorganic materials 0.000 claims 1
- 239000011733 molybdenum Substances 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 238000002407 reforming Methods 0.000 claims 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims 1
- 229910052703 rhodium Inorganic materials 0.000 claims 1
- 239000010948 rhodium Substances 0.000 claims 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
- 229910052707 ruthenium Inorganic materials 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 239000010935 stainless steel Substances 0.000 claims 1
- 229910001220 stainless steel Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims 1
- 229910052727 yttrium Inorganic materials 0.000 claims 1
Claims (17)
を含む反応チャンバー;および
b) 触媒床からの反応生成物を受け、反応生成物を(1)水素を含む生成物流および(2)副生成物流に分離するように適合された少なくとも1つの水素選択性水素透過性ガス分離モジュール
を含む反応器であって、
該ガス分離モジュールは、
(i) 多孔質基材;
(ii) 多孔質基材上に重層される中間多孔質金属層;および
(iii) 中間多孔質金属層上に重層される水素選択性膜
を含む、反応器。 a) a reaction chamber comprising a catalyst bed adapted to produce a reaction product comprising hydrogen gas from a hydrogen production feed; and
b) at least one hydrogen selective hydrogen permeable gas separation adapted to receive the reaction product from the catalyst bed and to separate the reaction product into a (1) hydrogen-containing product stream and (2) a by-product stream. A reactor comprising a module,
The gas separation module comprises:
(i) a porous substrate;
(ii) an intermediate porous metal layer overlaid on the porous substrate; and
(iii) A reactor comprising a hydrogen selective membrane overlaid on an intermediate porous metal layer.
(b) 水素選択性水素透過性ガス分離モジュールを用い、前記反応チャンバーならびに前記二酸化炭素および前記一酸化炭素から水素を分離することを含み;ここで、ガス分離モジュールは、
(i) 多孔質基材;
(ii) 前記多孔質基材上に重層される中間多孔質金属層;および
(iii) 中間多孔質金属層上に重層される水素選択性膜
を含む、水素の生成のための水蒸気改質方法。 (a) in a steam reforming reaction chamber containing a reforming catalyst to produce a mixture of hydrogen and carbon dioxide and a smaller amount of carbon monoxide, at a temperature of 200 ° C. to 700 ° C. and about 0.1 MPa to about 2 Reacting water vapor with the hydrogen production feed at a pressure of 0 MPa; and
(b) using a hydrogen selective hydrogen permeable gas separation module and comprising separating hydrogen from the reaction chamber and the carbon dioxide and the carbon monoxide; wherein the gas separation module comprises:
(i) a porous substrate;
(ii) an intermediate porous metal layer overlaid on the porous substrate; and
(iii) A steam reforming method for producing hydrogen, comprising a hydrogen-selective membrane layered on an intermediate porous metal layer.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US61168204P | 2004-09-21 | 2004-09-21 | |
PCT/US2005/033295 WO2006034103A1 (en) | 2004-09-21 | 2005-09-19 | Reactor and process for steam reforming |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008513339A JP2008513339A (en) | 2008-05-01 |
JP2008513339A5 true JP2008513339A5 (en) | 2008-10-30 |
Family
ID=35677491
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007532541A Pending JP2008513339A (en) | 2004-09-21 | 2005-09-19 | Reactor and method for steam reforming |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1791631A1 (en) |
JP (1) | JP2008513339A (en) |
AU (1) | AU2005286955B2 (en) |
CA (1) | CA2580279A1 (en) |
NO (1) | NO20071531L (en) |
TW (1) | TW200624376A (en) |
WO (1) | WO2006034103A1 (en) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITPG20060028A1 (en) * | 2006-04-18 | 2006-07-18 | Leonardo Valentini | EQUIPMENT FOR THE THERMO-PHYSICAL CATALYTIC DETACHMENT OF THE LIQUID AMMONIA IN THE NITROGEN AND HYDROGEN CONSTITUENTS IN THE GASEOUS STATE |
JP4805736B2 (en) * | 2006-06-29 | 2011-11-02 | Jx日鉱日石エネルギー株式会社 | Indirect internal reforming type solid oxide fuel cell |
JP4805735B2 (en) * | 2006-06-29 | 2011-11-02 | Jx日鉱日石エネルギー株式会社 | Indirect internal reforming type solid oxide fuel cell |
JP4970556B2 (en) * | 2007-02-20 | 2012-07-11 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | Gas separation membrane system and its preparation or regeneration method and use |
US8048199B2 (en) | 2007-02-20 | 2011-11-01 | Shell Oil Company | Method of making a leak stable gas separation membrane system |
FR2914395B1 (en) * | 2007-03-30 | 2009-11-20 | Inst Francais Du Petrole | NEW COMPACT EXCHANGER REACTOR USING A POROUS BURNER |
AU2008236737A1 (en) | 2007-04-05 | 2008-10-16 | Worcester Polytechnic Institute | Composite structures with porous anodic oxide layers and methods of fabrication |
EP2103586A1 (en) | 2008-03-20 | 2009-09-23 | Bp Oil International Limited | Process for converting methane into ethane in a membrane reactor |
CA2785351A1 (en) * | 2009-12-22 | 2011-06-30 | Airscience Technologies | System and process for the production of hydrogen from raw gas using a nanoparticle ceria based catalyst |
US8911570B2 (en) * | 2010-03-26 | 2014-12-16 | Shell Oil Company | Supported gas separation membrane and method |
US8652239B2 (en) | 2010-05-03 | 2014-02-18 | Worcester Polytechnic Institute | High permeance sulfur tolerant Pd/Cu alloy membranes |
JP5649139B2 (en) * | 2010-12-01 | 2015-01-07 | Jx日鉱日石金属株式会社 | Surface coating layer structure on copper surface |
JP5672548B2 (en) * | 2011-04-07 | 2015-02-18 | 有限会社アイエンジ | Hydrogen recovery device |
JP5850329B2 (en) * | 2012-02-28 | 2016-02-03 | 株式会社リコー | Fluid purification device |
DE102012016561B4 (en) * | 2012-08-22 | 2019-05-16 | Airbus Defence and Space GmbH | Aircraft fuel cell system and use thereof |
WO2017146589A1 (en) * | 2016-02-25 | 2017-08-31 | Hydrogen Mem-Tech As | Hydrogen production from natural gas in combination with injection of co2 for enhanced oil recovery |
KR102683554B1 (en) * | 2017-12-08 | 2024-07-11 | 토프쉐 에이/에스 | Systems and methods for producing synthesis gas |
US11492255B2 (en) | 2020-04-03 | 2022-11-08 | Saudi Arabian Oil Company | Steam methane reforming with steam regeneration |
US11322766B2 (en) | 2020-05-28 | 2022-05-03 | Saudi Arabian Oil Company | Direct hydrocarbon metal supported solid oxide fuel cell |
US11639290B2 (en) | 2020-06-04 | 2023-05-02 | Saudi Arabian Oil Company | Dry reforming of methane with carbon dioxide at elevated pressure |
US11492254B2 (en) * | 2020-06-18 | 2022-11-08 | Saudi Arabian Oil Company | Hydrogen production with membrane reformer |
US11583824B2 (en) * | 2020-06-18 | 2023-02-21 | Saudi Arabian Oil Company | Hydrogen production with membrane reformer |
US11999619B2 (en) | 2020-06-18 | 2024-06-04 | Saudi Arabian Oil Company | Hydrogen production with membrane reactor |
US11787759B2 (en) | 2021-08-12 | 2023-10-17 | Saudi Arabian Oil Company | Dimethyl ether production via dry reforming and dimethyl ether synthesis in a vessel |
US11718575B2 (en) | 2021-08-12 | 2023-08-08 | Saudi Arabian Oil Company | Methanol production via dry reforming and methanol synthesis in a vessel |
US11578016B1 (en) | 2021-08-12 | 2023-02-14 | Saudi Arabian Oil Company | Olefin production via dry reforming and olefin synthesis in a vessel |
US11617981B1 (en) | 2022-01-03 | 2023-04-04 | Saudi Arabian Oil Company | Method for capturing CO2 with assisted vapor compression |
CN118765212A (en) * | 2022-02-28 | 2024-10-11 | 日本碍子株式会社 | Reactor assembly and separation membrane assembly |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5393325A (en) * | 1990-08-10 | 1995-02-28 | Bend Research, Inc. | Composite hydrogen separation metal membrane |
US5139541A (en) * | 1990-08-10 | 1992-08-18 | Bend Research, Inc. | Hydrogen-permeable composite metal membrane |
US5498278A (en) * | 1990-08-10 | 1996-03-12 | Bend Research, Inc. | Composite hydrogen separation element and module |
US5217506A (en) * | 1990-08-10 | 1993-06-08 | Bend Research, Inc. | Hydrogen-permeable composite metal membrane and uses thereof |
JPH04346824A (en) * | 1991-05-21 | 1992-12-02 | Mitsubishi Heavy Ind Ltd | Hydrogen separating membrane |
JPH0585702A (en) * | 1991-09-30 | 1993-04-06 | Mitsubishi Heavy Ind Ltd | Production of hydrogen separation membrane |
JP3117276B2 (en) * | 1992-04-09 | 2000-12-11 | 三菱重工業株式会社 | Hydrogen separation membrane |
JP3621785B2 (en) * | 1996-07-12 | 2005-02-16 | トヨタ自動車株式会社 | Hydrogen separation structure |
US6152987A (en) * | 1997-12-15 | 2000-11-28 | Worcester Polytechnic Institute | Hydrogen gas-extraction module and method of fabrication |
JP2001286742A (en) * | 2000-04-10 | 2001-10-16 | Mitsubishi Heavy Ind Ltd | Hydrogen separation membrane |
JP2002219341A (en) * | 2001-01-30 | 2002-08-06 | Kobe Steel Ltd | Supporting base for hydrogen-permselective membrane and hydrogen-permselective member |
FR2820988B1 (en) * | 2001-02-19 | 2003-04-25 | Cie D Etudes Des Technologies | COMPOSITE STRUCTURES OF SELECTIVELY HYDROGEN PERMEABLE MEMBRANES AND COMBUSTIBLE GAS PROCESSORS USING THE SAME |
DE10135390A1 (en) * | 2001-07-25 | 2003-02-20 | Fraunhofer Ges Forschung | Metallic solution-diffusion membrane, used for separating and purifying hydrogen for use in the electronics, metals and chemical industry, consists of a macroporous base body with a thin metallic membrane layer |
WO2004022480A2 (en) * | 2002-09-05 | 2004-03-18 | Shell Internationale Research Maatschappij B.V. | Apparatus and process for production of high purity hydrogen |
JP2006520686A (en) * | 2003-03-21 | 2006-09-14 | ウスター ポリテクニック インスティチュート | Composite gas separation module with intermediate metal layer |
WO2004098751A1 (en) * | 2003-05-02 | 2004-11-18 | Worcester Polytechnic Institute | Composite gas separation modules having high tamman temperature intermediate layers |
-
2005
- 2005-09-19 EP EP05798472A patent/EP1791631A1/en not_active Withdrawn
- 2005-09-19 TW TW094132239A patent/TW200624376A/en unknown
- 2005-09-19 JP JP2007532541A patent/JP2008513339A/en active Pending
- 2005-09-19 CA CA002580279A patent/CA2580279A1/en not_active Abandoned
- 2005-09-19 AU AU2005286955A patent/AU2005286955B2/en not_active Ceased
- 2005-09-19 WO PCT/US2005/033295 patent/WO2006034103A1/en active Application Filing
-
2007
- 2007-03-23 NO NO20071531A patent/NO20071531L/en not_active Application Discontinuation
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