JP2008307701A - Manufacturing method of tube made of fiber-reinforced resin and tube manufactured by the same - Google Patents

Manufacturing method of tube made of fiber-reinforced resin and tube manufactured by the same Download PDF

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JP2008307701A
JP2008307701A JP2007155118A JP2007155118A JP2008307701A JP 2008307701 A JP2008307701 A JP 2008307701A JP 2007155118 A JP2007155118 A JP 2007155118A JP 2007155118 A JP2007155118 A JP 2007155118A JP 2008307701 A JP2008307701 A JP 2008307701A
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prepreg
hoop
tubular body
laminated
fiber
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JP4362788B2 (en
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Hiroaki Fujimoto
博明 藤元
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Dunlop Sports Co Ltd
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SRI Sports Ltd
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Priority to US12/076,199 priority patent/US8057617B2/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00Golf clubs
    • A63B53/10Non-metallic shafts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/20Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres
    • B29C70/202Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres arranged in parallel planes or structures of fibres crossing at substantial angles, e.g. cross-moulding compound [XMC]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D23/00Producing tubular articles
    • B29D23/001Pipes; Pipe joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a general shape other than plane
    • B32B1/08Tubular products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/12Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer characterised by the relative arrangement of fibres or filaments of different layers, e.g. the fibres or filaments being parallel or perpendicular to each other
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2209/00Characteristics of used materials
    • A63B2209/02Characteristics of used materials with reinforcing fibres, e.g. carbon, polyamide fibres
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B60/00Details or accessories of golf clubs, bats, rackets or the like
    • A63B60/06Handles
    • A63B60/14Coverings specially adapted for handles, e.g. sleeves or ribbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/32Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core on a rotating mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • B29L2023/22Tubes or pipes, i.e. rigid
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/52Sports equipment ; Games; Articles for amusement; Toys
    • B29L2031/5227Clubs
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352Polymer or resin containing [i.e., natural or synthetic]
    • Y10T428/1372Randomly noninterengaged or randomly contacting fibers, filaments, particles, or flakes

Abstract

<P>PROBLEM TO BE SOLVED: To prevent the unwinding of a prepreg, without deteriorating the lightweight nature of a tube made of a fiber-reinforced resin and thus to enhance the strength thereof and the productivity therefor. <P>SOLUTION: The method comprises the process of winding a bias prepreg 21 or 22, a straight prepreg 23, 25, 27 or 28 and a hoop prepreg 24 or 26 on a core material each at least by one sheet. Of the hoop prepreg 24 or 26 at least one is in advance laminated/tightly attached onto a base prepreg consisting of the bias prepreg 21 or 22 or the straight prepreg 25 or 27, to form a laminate A1 or A2, and by winding the laminate A1 or A2 the hoop prepreg 24 or 26 is wound integrally with the base prepreg 25 or 27. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、繊維強化樹脂製の管状体の製造方法および該方法によって製造された繊維強化樹脂製管状体に関し、特に、フーププリプレグを用いた管状体の積層不良の防止を図るものである。   The present invention relates to a method for producing a tubular body made of fiber reinforced resin and a tubular body made of fiber reinforced resin produced by the method, and in particular, to prevent poor stacking of tubular bodies using a hoop prepreg.

近年、ゴルフクラブシャフトや釣竿などの管状体の材料は、軽量で、比強度、比剛性の高いカーボンプリプレグ等の繊維強化樹脂が主流となっている。
これら繊維強化樹脂製の管状体は、一般に繊維強化プリプレグを積層して形成されるが、繊維強化プリプレグは、その強化繊維の配列方向によって以下のような異なる特性を有する。
強化繊維の配列方向が管状体の軸線方向に対して傾斜して配されるバイアスプリプレグは、繊維が螺旋状に延在するため、主にねじり剛性、ねじり強度を高めることができる。
強化繊維の配列方向が管状体の軸線方向に対して略平行に配されるストレートプリプレグは、繊維が管状体軸線方向に延在するため、主に曲げ剛性、曲げ強度を高めることができる。
強化繊維の配列方向が管状体の軸線方向に対して略直角に配されるフーププリプレグは、繊維が管状体の周方向に延在するため、主につぶし剛性、つぶし強度を高めることができる。
In recent years, materials for tubular bodies such as golf club shafts and fishing rods are mainly fiber reinforced resins such as carbon prepregs that are lightweight and have high specific strength and high specific rigidity.
These tubular bodies made of fiber reinforced resin are generally formed by laminating fiber reinforced prepregs, and fiber reinforced prepregs have the following different characteristics depending on the arrangement direction of the reinforced fibers.
In the bias prepreg in which the arrangement direction of the reinforcing fibers is inclined with respect to the axial direction of the tubular body, since the fibers extend in a spiral shape, the torsional rigidity and the torsional strength can be mainly increased.
The straight prepreg in which the arrangement direction of the reinforcing fibers is arranged substantially parallel to the axial direction of the tubular body can mainly increase the bending rigidity and the bending strength because the fibers extend in the tubular body axial direction.
In the hoop prepreg in which the reinforcing fibers are arranged in a direction substantially perpendicular to the axial direction of the tubular body, since the fibers extend in the circumferential direction of the tubular body, the crushing rigidity and the crushing strength can be mainly increased.

管状体の製造にあたっては、前記バイアスプリプレグ、ストレートプリプレグ、フーププリプレグを併用することによって、軽量性を維持しながら管状体に必要な剛性や強度を調整する技術が知られている。
例えば、特開平8−131588号(特許文献1)では、図5に示すように、バイアスプリプレグからなるバイアス層2を外側に、ストレートプリプレグからなるストレート層3を内側に配置し、該ストレート層3のさらに内側に、フーププリプレグからなるフープ層4を設けたゴルフクラブシャフト1が提案され、これにより、軽量性を損なうことなく、ゴルフクラブシャフト1のねじり剛性および曲げ剛性を高めることができるとされている。
In manufacturing a tubular body, a technique is known in which the bias prepreg, straight prepreg, and hoop prepreg are used in combination to adjust rigidity and strength necessary for the tubular body while maintaining light weight.
For example, in JP-A-8-131588 (Patent Document 1), as shown in FIG. 5, a bias layer 2 made of a bias prepreg is arranged on the outer side, and a straight layer 3 made of a straight prepreg is arranged on the inner side. Further, a golf club shaft 1 provided with a hoop layer 4 made of a hoop prepreg is proposed on the inner side of the golf club shaft, whereby the torsional rigidity and bending rigidity of the golf club shaft 1 can be increased without impairing the lightness. ing.

しかしながら、前記フーププリプレグは、周方向に延在する強化繊維の弾性によって巻回時に曲げが抑制されてしまうため、芯材に巻きつけにくいという特徴を有する。そのため、フープ層とその下層とを積層密着させることが難しく、端部の巻き剥がれ等が発生しやすい。
このような巻き剥がれが生じると、フープ層が浮き上がり、その外周層の巻回作業においてプリプレグが折れ曲がるほか、浮き上がり箇所にエアー溜りが発生するため、強度が低下し、管状体の特性にもバラツキが生じ、品質低下を招く点に問題がある。また、このような不良箇所の再密着作業が必要となるため、生産性が低下する点にも問題がある。
However, the hoop prepreg has a feature that it is difficult to wind the hoop prepreg because the bending of the reinforcing fiber extending in the circumferential direction is suppressed during winding. For this reason, it is difficult to laminate the hoop layer and the lower layer thereof, and end portions are easily peeled off.
When such unwinding occurs, the hoop layer is lifted, the prepreg is bent in the winding operation of the outer peripheral layer, and an air pool is generated at the lifted portion, so that the strength is lowered and the characteristics of the tubular body are also varied. This is problematic in that it causes quality degradation. In addition, since it is necessary to re-adhere such a defective portion, there is a problem in that productivity is lowered.

前記問題への対策として、フープ層の外周側にストレート層を配置すると共に該ストレート層の巻回数(PLY数)を増やし、ラッピング効果によってフープ層の積層不良を防止する手法も知られている。しかしながら、ゴルフクラブシャフト等の管状体は軽量化への要請が強いため、ストレート層の余剰は排除する必要がある。しかも、軽量化による強度低下を防止するために、フープ層の多層化は今後必至と考えられるだけに、ストレート層の巻回数は多くてもフープ層と同一とすることが求められる。   As a countermeasure to the above problem, there is also known a method in which a straight layer is disposed on the outer peripheral side of the hoop layer and the number of windings (PLY number) of the straight layer is increased to prevent a hoop layer stacking failure by a lapping effect. However, since a tubular body such as a golf club shaft has a strong demand for weight reduction, it is necessary to eliminate the surplus of the straight layer. Moreover, in order to prevent a reduction in strength due to weight reduction, the hoop layer is expected to be multilayered in the future, and the straight layer is required to have the same number of turns as the hoop layer at most.

特開平8−131588号公報JP-A-8-131588

本発明は前記問題に鑑みてなされたもので、軽量性を損なうことなくフーププリプレグの巻き剥がれを防止し、品質および生産性を向上できる繊維強化樹脂製管状体の製造方法および該方法によって製造された管状体の提供を課題としている。   The present invention has been made in view of the above problems, and is manufactured by a method of manufacturing a fiber-reinforced resin tubular body capable of preventing unwinding of a hoop prepreg without impairing lightness and improving quality and productivity, and the method. It is an issue to provide a tubular body.

前記課題を解決するために、本発明は、強化繊維にマトリクス樹脂を含浸してなるプリプレグの積層体からなる繊維強化樹脂製の管状体の製造方法において、
強化繊維の配列方向が管状体軸線に対して傾斜して配されるバイアスプリプレグと、強化繊維の配列方向が管状体軸線に対して平行に配されるストレートプリプレグと、強化繊維の配列方向が管状体軸線に対して直角に配されるフーププリプレグとを、芯材上に巻回する工程を含み、
前記フーププリプレグのうち少なくとも1枚は積層フーププリプレグ(以下、積層フープと称する)として前記バイアスプリプレグまたは前記ストレートプリプレグからなる土台プリプレグに予め積層密着して一体化した積層体を形成おき、該積層体を巻回することによって前記土台プリプレグと一体に前記積層フープが巻回されることを特徴とする繊維強化樹脂製の管状体の製造方法を提供している。
In order to solve the above problems, the present invention provides a method for producing a tubular body made of a fiber reinforced resin comprising a laminate of prepregs obtained by impregnating a reinforcing fiber with a matrix resin.
Bias prepreg in which the arrangement direction of the reinforcing fibers is inclined with respect to the tubular body axis, a straight prepreg in which the arrangement direction of the reinforcing fibers is arranged in parallel to the tubular body axis, and the arrangement direction of the reinforcing fibers are tubular A step of winding a hoop prepreg arranged at right angles to the body axis on a core material;
At least one of the hoop prepregs is formed as a laminated hoop prepreg (hereinafter referred to as a laminated hoop) to form a laminated body in which the bias prepreg or the base prepreg made of the straight prepreg is laminated and adhered in advance, and the laminated body is formed. A method for producing a tubular body made of fiber reinforced resin is provided, wherein the laminated hoop is wound integrally with the base prepreg.

前記本発明の管状体の製造方法によれば、芯材に巻きつけにくいフーププリプレグを、巻き付けやすいストレートプリプレグまたはバイアスプリプレグに予め積層密着して積層フープとして積層体として形成しておき、該積層体を芯材に巻回するため、フーププリプレグ単体で巻回する場合に起こりやすい巻き剥がれ等の積層不良を防止でき、土台プリプレグの巻回数を多くすることなく、管状体の軽量性を維持したまま品質および生産性を向上させることができる。
なお、ストレートプリプレグ又はバイアスプリプレグの両側に予めフーププリプレグを積層密着して一体化した積層体としてもよい。
According to the method for producing a tubular body of the present invention, a hoop prepreg that is difficult to wind around a core material is laminated and adhered in advance to a straight prepreg or bias prepreg that is easy to wind to form a laminated hoop as a laminated body. As a result, it is possible to prevent the stacking failure such as peeling off, which is likely to occur when the hoop prepreg is wound alone, while maintaining the light weight of the tubular body without increasing the number of windings of the base prepreg. Quality and productivity can be improved.
In addition, it is good also as a laminated body which laminated | stacked and adhered the hoop prepreg beforehand on both sides of the straight prepreg or the bias prepreg.

複数枚のフープフリプレグを用いる場合は、全てのフーププリプレグを前記積層フープとしておくことが好ましい。
また、ストレートプリプレグはバイアスプリプレグに比してより巻回しやすいため、前記積層体を構成する土台プリプレグにはストレートプリプレグを用いることが好ましい。
さらに、前記積層体を芯材に巻回するときは、土台プリプレグによるラッピング効果も考慮して、土台プリプレグが積層フープの外周側となるように巻回することが好ましい。
When a plurality of hoop prepregs are used, it is preferable that all the hoop prepregs are the laminated hoops.
Moreover, since a straight prepreg is easier to wind than a bias prepreg, it is preferable to use a straight prepreg as the base prepreg constituting the laminate.
Furthermore, when winding the laminated body around the core material, it is preferable to wind the base prepreg so that the base prepreg is on the outer peripheral side of the laminated hoop in consideration of the wrapping effect of the base prepreg.

なお、本発明におけるフーププリプレグは、繊維の配列方向と管状体軸線方向との交差角度が80〜100度のものを指す。
また、ストレートプリプレグは、繊維の配列方向と管状体軸線方向との交差角度が−10〜+10のものを指す。
また、バイアスプリプレグは繊維の配列方向と管状体軸線方向との交差角度が10度を越えて80度未満、−10度を越えて−80度未満のものを指す。
In addition, the hoop prepreg in this invention points out that the crossing angle of the arrangement direction of a fiber and a tubular body axial direction is 80-100 degree | times.
Further, the straight prepreg refers to those having an intersection angle of −10 to +10 between the fiber arrangement direction and the tubular body axis direction.
Further, the bias prepreg refers to a fiber having an intersection angle between the fiber arrangement direction and the tubular body axis direction of more than 10 degrees and less than 80 degrees, more than -10 degrees and less than -80 degrees.

前記土台プリプレグに積層密着する積層フープの管状体軸線方向の両端縁および巻回終端縁のうち、少なくとも1箇所は、前記土台プリプレグの周縁と一致させている、もしくは土台プリプレグの周縁よりも土台プリプレグの内側に位置させている。
これにより、フーププリプレグの巻き剥がれが特に生じやすい管状体軸線方向の端縁および/または巻回終端縁において、土台プリプレグによるアンカー効果を発現でき、巻回作業がより容易となるうえ、フーププリプレグの積層不良を一層確実に防止することができる。
At least one of the both ends in the tubular body axial direction and the winding end edge of the laminated hoop that is laminated and adhered to the base prepreg is made to coincide with the peripheral edge of the base prepreg, or the base prepreg is more than the peripheral edge of the base prepreg. It is located inside.
As a result, the anchor effect of the base prepreg can be expressed at the end of the tubular body axial direction and / or the winding end edge where the hoop prepreg is particularly likely to be unwound, and the winding operation is facilitated. Stacking failure can be prevented more reliably.

なお、積層フープは、管状体軸線方向の両端縁および巻回終端縁の3箇所すべてにおいて、土台プリプレグの周縁と一致または該周縁より土台プリプレグの内側に位置することが好ましいが、さらには、前記3箇所に加えて、積層フープの巻回初端縁でも土台プリプレグの周縁と一致または土台プリプレグの内側に位置することがより好ましい。これは、積層フープの周縁のうち巻回初端縁のみが土台プリプレグの外側に位置すると、巻回初端縁の剛性だけが小さくなり、応力が集中して折れたり曲がったりしやすくなることに因る。   The laminated hoop is preferably located at the inner edge of the base prepreg at the same position as the peripheral edge of the base prepreg at all three positions of the both end edges and the winding end edge in the tubular body axial direction. In addition to the three places, it is more preferable that the winding initial end edge of the laminated hoop coincides with the periphery of the base prepreg or is located inside the base prepreg. This is because, if only the winding initial edge of the peripheral edge of the laminated hoop is located outside the base prepreg, only the rigidity of the winding initial edge is reduced, and stress is concentrated, making it easy to bend or bend. It depends.

また、積層フープの周縁は、土台プリプレグの周縁と一致させるよりも、土台プリプレグの内側に位置させることが一層好ましい。土台プリプレグの周縁部によるアンカー効果を一層効果的に発現することができ、フーププリプレグの積層不良をより確実に防止することができる。   Moreover, it is more preferable that the peripheral edge of the laminated hoop is positioned inside the base prepreg than the peripheral edge of the base prepreg. The anchor effect by the peripheral part of the base prepreg can be expressed more effectively, and the stacking failure of the hoop prepreg can be prevented more reliably.

積層フープの周縁と土台プリプレグの周縁とは、1mm以上、さらには3mm以上、さらには5mm以上、より好ましくは10mm以上離間させるのがよい。これは、積層フープの周縁と土台プリプレグの周縁を離間させることによって、土台プリプレグのアンカー効果を十分に発揮できるうえ、積層プリプレグ周縁部への応力集中を防ぎ、管状体の折損等を防止できることに因る。
一方、積層フープの周縁と土台プリプレグの周縁とを離間させすぎると、積層フープの長さが短くなってつぶし剛性/強度が低下する、あるいは土台プリプレグが不要に大きくなって重量増加を招くため、前記離間距離は、50mm以下、さらには30mm以下、より好ましくは20mm以下がよい。
The peripheral edge of the laminated hoop and the peripheral edge of the base prepreg should be separated from each other by 1 mm or more, further 3 mm or more, further 5 mm or more, more preferably 10 mm or more. This is because the anchoring effect of the base prepreg can be sufficiently exerted by separating the peripheral edge of the laminated hoop and the peripheral edge of the base prepreg, stress concentration on the peripheral part of the laminated prepreg can be prevented, and the tubular body can be prevented from being broken. It depends.
On the other hand, if the peripheral edge of the laminated hoop and the peripheral edge of the base prepreg are separated too much, the length of the laminated hoop is shortened and the crushing rigidity / strength is reduced, or the base prepreg is unnecessarily large, resulting in an increase in weight. The separation distance is 50 mm or less, further 30 mm or less, and more preferably 20 mm or less.

本発明は、前記方法で製造された管状体を提供しており、該管状体で、前記積層フープの管状体軸線方向の両端縁は、管状体の最終製品両端位置よりも内側に位置させている。 これは、フーププリプレグの巻き剥がれは、フーププリプレグの管状体軸線方向端部が管状体自体の端部に位置している場合に、その端部において特に発現しやすいうえ、ゴルフクラブシャフトや釣竿などの最終製品は、予め長めに設定された管状体の両端を所要寸法カットして作製するため、両端カット後の最終製品の状態において、フーププリプレグの管状体軸線方向端部が製品端部に位置しないことが求められることに因る。   The present invention provides a tubular body manufactured by the above method, wherein both end edges of the laminated hoop in the axial direction of the tubular body are located on the inner side of both end positions of the final product of the tubular body. Yes. This is because hoop prepreg unwinds easily when the tubular body axial end of the hoop prepreg is located at the end of the tubular body itself, and the golf club shaft, fishing rod, etc. The end product of the hoop prepreg is positioned at the end of the product in the state of the final product after both ends are cut because the end product of the end product is cut to the required dimensions. Because it is required not to.

積層フープを管状体全長に対して部分的に短く積層する場合は、積層フープの管状体軸線方向端縁を、管状体軸線方向に対して斜めにカットすることが好ましい。これにより、成型後の積層段差を緩和できるため、フープ層の両端への応力集中を防止でき、管状体の強度低下を抑制できる。   When laminating the laminated hoop partially shorter than the entire length of the tubular body, it is preferable to cut the edge of the laminated hoop in the tubular body axial direction obliquely with respect to the tubular body axial direction. Thereby, since the lamination | stacking level | step difference after shaping | molding can be relieve | moderated, the stress concentration to the both ends of a hoop layer can be prevented, and the strength reduction of a tubular body can be suppressed.

前記積層フープは、厚さを0.03〜0.06mmとしていることが好ましい。
該積層フープの厚さを0.03〜0.06mmとしているのは、0.03mm未満では薄すぎてつぶし剛性/強度が不足し、0.06mmを超えると、厚くなりすぎて積層が困難となり、端部の密着不足が生じやすいことに因る。
The laminated hoop preferably has a thickness of 0.03 to 0.06 mm.
The thickness of the laminated hoop is 0.03 to 0.06 mm. If it is less than 0.03 mm, it is too thin and the crushing rigidity / strength is insufficient. If it exceeds 0.06 mm, it becomes too thick and lamination becomes difficult. This is because the end portion is likely to be insufficiently adhered.

また、前記積層フープの強化繊維の引張弾性率を30〜80ton/mmとすることが好ましい。ここでいう引張弾性率とは、JISR7601:1986「炭素繊維試験方法」に準拠して測定している。
積層フープの強化繊維の引張弾性率を30〜80ton/mmとしているのは、30ton/mm未満では必要なつぶし剛性/強度が得られず、80ton/mmを超えると、繊維の弾性が強くなりすぎて積層が困難になることに因る。
Moreover, it is preferable that the tensile elastic modulus of the reinforcing fiber of the laminated hoop is 30 to 80 ton / mm 2 . The tensile elastic modulus here is measured in accordance with JIS R7601: 1986 “Carbon fiber test method”.
What the tensile modulus of the reinforcing fibers of the laminated hoop and 30~80Ton / mm 2 is, 30 ton / mm not obtained the required crushing rigidity / strength of less than 2, it exceeds 80 tons / mm 2, the elasticity of the fibers This is because it becomes too strong and lamination becomes difficult.

前記積層フープおよび/または土台プリプレグの樹脂含量率は30〜40%であることが好ましい。
これは、30%未満では積層フープ自体の積層密着力が低下し、40%を超えると、積層フープが厚くなりすぎて重量増加を招くうえ、積層段差が大きくなり、応力集中や外観不良を招くことに因る。
好ましくは、前記積層フープと土台プリプレグの両方について、樹脂含量率を30〜40%とするのがよい。
The resin content of the laminated hoop and / or base prepreg is preferably 30 to 40%.
This is because if less than 30%, the laminate adhesive strength of the laminate hoop itself decreases, and if it exceeds 40%, the laminate hoop becomes too thick, resulting in an increase in weight, and a laminate step becomes large, resulting in stress concentration and poor appearance. It depends on.
Preferably, the resin content is set to 30 to 40% for both the laminated hoop and the base prepreg.

本発明においては、前記フーププリプレグを5枚以上用いてもよいが、重量増加抑制と曲げ強度・ねじれ強度維持のバランスを考慮して、1〜4枚、さらには1〜3枚、特に1〜2枚とすることが好ましい。   In the present invention, five or more hoop prepregs may be used, but considering the balance between weight increase suppression and bending strength / torsion strength maintenance, 1 to 4 sheets, more preferably 1 to 3 sheets, Two sheets are preferable.

前記バイアスプリプレグは2〜8枚用いることが好ましく、さらには4〜6枚がより好ましい。これは、2枚未満ではねじれ剛性/強度が弱くなると共に、1枚ではねじれ剛性が非対称となり、8枚より多くすると、限られた重量のなかで他のストレートプリプレグやフーププリプレグの比率が小さくなりすぎ、曲げ剛性/強度、つぶし剛性/強度が低下してしまうことに因る。   It is preferable to use 2 to 8 bias prepregs, and more preferably 4 to 6 sheets. If less than 2 sheets, the torsional rigidity / strength will be weak, and if 1 sheet, the torsional rigidity will be asymmetrical. If more than 8 sheets, the ratio of other straight prepregs and hoop prepregs will be small within the limited weight. This is because the bending rigidity / strength and crushing rigidity / strength decrease.

前記ストレートプリプレグは1〜8枚用いることが好ましく、さらには2〜6枚、特に2〜4枚がより好ましい。これは、1枚未満では曲げ剛性/強度に加え、ねじれ剛性/強度も不足し、8枚より多くすると、プリプレグ枚数が多くなりすぎて作製時の作業性が悪く、コストもかかることに因る。   It is preferable to use 1 to 8 straight prepregs, more preferably 2 to 6 sheets, and more preferably 2 to 4 sheets. This is because if the number is less than one, the torsional rigidity / strength is insufficient in addition to the bending rigidity / strength. If the number is more than eight, the number of prepregs becomes too large, resulting in poor workability and cost. .

本発明をゴルフクラブシャフトに適用する場合は、管状体の重量(g)/シャフト長さ(mm)の値は、0.025g/mm以上0.050g/mm以下とすることが好ましい。これは、0.025g/mm未満では、現存の高強度材料で作製することができないうえ、作製できたとしても使用に耐えるだけの強度を有することができず、0.050g/mmを超えると、シャフトの軽量性を維持できないことに因る。さらに、管状体の単位当たり重量の下限は、0.026g/mm以上、特に0.027g/mm以上が好ましく、上限は、0.048g/mm以下、特に0.045g/mm以下がよい。   When the present invention is applied to a golf club shaft, the weight (g) / shaft length (mm) of the tubular body is preferably 0.025 g / mm or more and 0.050 g / mm or less. This is because if it is less than 0.025 g / mm, it cannot be produced with an existing high-strength material, and even if it can be produced, it cannot have sufficient strength to withstand use, and if it exceeds 0.050 g / mm. This is because the lightness of the shaft cannot be maintained. Furthermore, the lower limit of the weight per unit of the tubular body is preferably 0.026 g / mm or more, particularly preferably 0.027 g / mm or more, and the upper limit is preferably 0.048 g / mm or less, particularly 0.045 g / mm or less.

本発明をゴルフクラブシャフトに適用する場合における管状体の長さは、公式ルールに準拠して460mm以上1220mm以下が好ましい。   When the present invention is applied to a golf club shaft, the length of the tubular body is preferably 460 mm or more and 1220 mm or less in accordance with the official rules.

前記プリプレグに用いられる強化繊維としては、比重が小さく弾性率と強度が高いという点からカーボン繊維が好ましいが、その他、一般に高性能強化繊維として使用される繊維、例えば、ガラス繊維、アラミド繊維、ボロン繊維、アルミナ繊維、黒鉛繊維、炭化ケイ素繊維等も用いることができる。   The reinforcing fiber used in the prepreg is preferably a carbon fiber because it has a small specific gravity and a high elastic modulus and strength. However, other fibers that are generally used as a high-performance reinforcing fiber, such as glass fiber, aramid fiber, and boron. Fibers, alumina fibers, graphite fibers, silicon carbide fibers and the like can also be used.

前記プリプレグに用いられるマトリクス樹脂としては、熱硬化性樹脂、熱可塑性樹脂等が挙げられるが、強度と剛性の点より、熱硬化性樹脂が好ましい。
熱硬化性樹脂としては、エポキシ系樹脂、不飽和ポリエステル系樹脂、フェノール系樹脂、メラミン系樹脂、ユリア系樹脂、ジアリルフタレート系樹脂、ポリウレタン系樹脂、ポリイミド系樹脂、ケイ素樹脂等が挙げられる。これら樹脂の中では前記エポキシ樹脂が好適に用いられる。
熱可塑性樹脂としては、ポリアミド樹脂、飽和ポリエステル系樹脂、ポリカーボネート系樹脂、ABS樹脂、ポリ塩化ビニル系樹脂、ポリアセタール系樹脂、ポリスチレン系樹脂、ポリエチレン系樹脂、ポリ酢酸ビニル系樹脂、AS樹脂、メタクリル樹脂、ポリプロピレン樹脂、フッ素樹脂等が挙げられる。これら樹脂の中では前記ポリアミド樹脂が好適に用いられる。
Examples of the matrix resin used for the prepreg include a thermosetting resin and a thermoplastic resin, and the thermosetting resin is preferable from the viewpoint of strength and rigidity.
Examples of the thermosetting resin include epoxy resins, unsaturated polyester resins, phenol resins, melamine resins, urea resins, diallyl phthalate resins, polyurethane resins, polyimide resins, silicon resins, and the like. Among these resins, the epoxy resin is preferably used.
As thermoplastic resins, polyamide resins, saturated polyester resins, polycarbonate resins, ABS resins, polyvinyl chloride resins, polyacetal resins, polystyrene resins, polyethylene resins, polyvinyl acetate resins, AS resins, methacrylic resins , Polypropylene resin, fluorine resin and the like. Among these resins, the polyamide resin is preferably used.

上述したように、本発明によれば、単体では巻きつけ困難なフーププリプレグを、巻きつけしやすいストレートプリプレグやバイアスプリプレグ等の土台プリプレグに予め積層密着して一体化した積層体として形成しておき、この積層体を芯材に巻回することにより、土台プリプレグの巻回数を増やすことなくフーププリプレグの巻き剥がれ等の積層不良を防ぎ、管状体の軽量化、強度向上、および生産性向上を図ることができる。   As described above, according to the present invention, a hoop prepreg that is difficult to wind by itself is formed as a laminated body that is laminated and adhered in advance to a base prepreg such as a straight prepreg or a bias prepreg that is easy to wind. By winding this laminated body around the core material, it is possible to prevent stacking failure such as hoop prepreg unwinding without increasing the number of windings of the base prepreg, and to reduce the weight of the tubular body, improve the strength, and improve the productivity. be able to.

また、土台プリプレグと予め一体化しておく積層フープの管状体軸線方向の両端縁および巻回終端縁のうち、少なくとも1箇所を、前記土台プリプレグの周縁と一致させる、もしくは土台プリプレグの周縁よりも土台プリプレグの内側に位置させることにより、土台プリプレグの周縁部によるアンカー効果が一層発揮され、フーププリプレグの積層不良をより確実に防止することができる。   Further, at least one of both end edges and winding end edges in the tubular body axial direction of the laminated hoop previously integrated with the base prepreg is made to coincide with the peripheral edge of the base prepreg, or the base rather than the peripheral edge of the base prepreg By positioning it inside the prepreg, the anchor effect by the peripheral edge of the base prepreg is further exhibited, and stacking faults of the hoop prepreg can be more reliably prevented.

以下、本発明の実施形態を図面を参照して説明する。
図1乃至図4は、本発明の第一実施形態に係るゴルフクラブシャフト用の管状体10を示す。
管状体10は、8枚の繊維強化プリプレグ20(21〜28)のテーパー状の積層体からなり、該管状体10の両端を所要寸法カットして最終製品としてのシャフト10’が作製される。
前記シャフト10’は、図2に示すように、小径側のヘッド側先端部11にヘッド13が取り付けられ、大径側のグリップ側後端部12に、グリップ14が取り付けられる。
Hereinafter, embodiments of the present invention will be described with reference to the drawings.
1 to 4 show a tubular body 10 for a golf club shaft according to a first embodiment of the present invention.
The tubular body 10 is composed of a laminated laminate of eight fiber reinforced prepregs 20 (21 to 28), and both ends of the tubular body 10 are cut to required dimensions to produce a shaft 10 ′ as a final product.
As shown in FIG. 2, the shaft 10 ′ has a head 13 attached to a small-diameter head-side tip portion 11, and a grip 14 attached to a large-diameter-side grip-side rear end portion 12.

本実施形態ではシャフト10’の全長を1130mmとし、前記管状体10はシャフト10’よりも長めの1168mmに設定している。   In this embodiment, the total length of the shaft 10 'is 1130 mm, and the tubular body 10 is set to 1168 mm longer than the shaft 10'.

前記繊維強化プリプレグ20(21〜28)は、強化繊維F21〜F28にいずれもカーボン繊維を用い、マトリクス樹脂としてエポキシ樹脂を用いている。   The fiber reinforced prepreg 20 (21 to 28) uses carbon fibers for the reinforcing fibers F21 to F28, and uses an epoxy resin as a matrix resin.

詳しくは、図1に示すように、1枚目と2枚目はバイアスプリプレグ21、22であり、管状体10の軸線方向に対して強化繊維F21、F22の配向角を−45度、+45度としている。これらバイアスプリプレグ21、22は、長さは管状体10の全長とし、ヘッド側の幅は50mm、グリップ側の幅は100mmとしている。また、厚みは0.085mmとし、樹脂含有率は24%としている。強化繊維F21、F22の引張弾性率は30ton/mmとしている。 Specifically, as shown in FIG. 1, the first and second sheets are bias prepregs 21 and 22, and the orientation angles of the reinforcing fibers F21 and F22 with respect to the axial direction of the tubular body 10 are −45 degrees and +45 degrees. It is said. The bias prepregs 21 and 22 have a length that is the entire length of the tubular body 10, a head side width of 50 mm, and a grip side width of 100 mm. The thickness is 0.085 mm and the resin content is 24%. The tensile elastic modulus of the reinforcing fibers F21 and F22 is 30 ton / mm 2 .

3枚目はストレートプリプレグ23であり、管状体10の軸線方向に対して強化繊維F23の配向角を0度としている。長さは管状体10の全長(1168mm)とし、ヘッド側の幅は26mm、グリップ側の幅は52mmとしている。厚みは0.082mmとし、樹脂含有率は24%としている。強化繊維F23の引張弾性率は24ton/mmとしている。 The third sheet is a straight prepreg 23, and the orientation angle of the reinforcing fiber F23 is set to 0 degree with respect to the axial direction of the tubular body 10. The length is the total length (1168 mm) of the tubular body 10, the width on the head side is 26 mm, and the width on the grip side is 52 mm. The thickness is 0.082 mm and the resin content is 24%. The tensile elastic modulus of the reinforcing fiber F23 is 24 ton / mm 2 .

4枚目はフーププリプレグ24であり、管状体10の軸線方向に対する強化繊維F24の配向角を90度としている。長さは1128mmとし、ヘッド側の幅は28mm、グリップ側の幅は52mmとし、厚みは0.034mmとし、樹脂含有率は40%としている。強化繊維F24の引張弾性率は30ton/mmとしている。 The fourth sheet is a hoop prepreg 24, and the orientation angle of the reinforcing fiber F24 with respect to the axial direction of the tubular body 10 is 90 degrees. The length is 1128 mm, the width on the head side is 28 mm, the width on the grip side is 52 mm, the thickness is 0.034 mm, and the resin content is 40%. The tensile elastic modulus of the reinforcing fiber F24 is 30 ton / mm 2 .

5枚目はストレートプリプレグ25であり、管状体10の軸線方向に対する強化繊維F25の配向角を0度としている。長さは管状体10の全長とし、ヘッド側の幅は27mm、グリップ側の幅は53mmとし、厚みは0.103mmとし、樹脂含有率は24%としている。強化繊維F25の引張弾性率は24ton/mmとしている。 The fifth sheet is a straight prepreg 25, and the orientation angle of the reinforcing fiber F25 with respect to the axial direction of the tubular body 10 is 0 degree. The length is the entire length of the tubular body 10, the width on the head side is 27 mm, the width on the grip side is 53 mm, the thickness is 0.103 mm, and the resin content is 24%. The tensile elastic modulus of the reinforcing fiber F25 is 24 ton / mm 2 .

前記4枚目のフーププリプレグ24は5枚目のストレートプリプレグ25と予め一体化された積層フープであり、積層フープのフーププリプレグ24と土台プリプレグのストレートプリプレグ25とで積層体A1を構成している。該積層フープ24の長さは1128mm、ストレートプリプレグ25の長さは1168mmで、ストレートプリプレグ25の長さ方向の両端より積層フープ24の長さ方向の両端を内側に位置させている。   The fourth hoop prepreg 24 is a laminated hoop integrated with a fifth straight prepreg 25 in advance, and the laminated hoop prepreg 24 and the base prepreg straight prepreg 25 constitute a laminated body A1. . The length of the laminated hoop 24 is 1128 mm, the length of the straight prepreg 25 is 1168 mm, and both ends of the laminated hoop 24 in the length direction are located on the inner side from both ends in the length direction of the straight prepreg 25.

6枚目はフーププリプレグ26であり、管状体10の軸線方向に対する強化繊維F26の配向角を90度としている。長さは1128mmとし、ヘッド側の幅は29mm、グリップ側の幅は53mmとし、厚みは0.034mmとし、樹脂含有率は40%としている。強化繊維F26の引張弾性率は30ton/mmとしている。 The sixth sheet is a hoop prepreg 26, and the orientation angle of the reinforcing fiber F26 with respect to the axial direction of the tubular body 10 is 90 degrees. The length is 1128 mm, the width on the head side is 29 mm, the width on the grip side is 53 mm, the thickness is 0.034 mm, and the resin content is 40%. The tensile elastic modulus of the reinforcing fiber F26 is 30 ton / mm 2 .

7枚目はストレートプリプレグ27であり、管状体10の軸線方向に対する強化繊維F27の配向角を0度としている。長さは管状体10の全長とし、ヘッド側の幅は28mm、グリップ側の幅は54mmとし、厚みは0.082mmとし、樹脂含有率は24%としている。強化繊維F27の引張弾性率は24ton/mmとしている。 The seventh sheet is a straight prepreg 27, and the orientation angle of the reinforcing fiber F27 with respect to the axial direction of the tubular body 10 is 0 degree. The length is the entire length of the tubular body 10, the width on the head side is 28 mm, the width on the grip side is 54 mm, the thickness is 0.082 mm, and the resin content is 24%. The tensile elastic modulus of the reinforcing fiber F27 is 24 ton / mm 2 .

前記6枚目のフーププリプレグ26は7枚目のストレートプリプレグ27と予め一体化された積層フープであり、積層フープのフーププリプレグ26と土台プリプレグのストレートプリプレグ27とで積層体A2を構成している。積層フープ26の長さ方向は1128mm、ストレートプリプレグ27の長さは1168mmで、ストレートプリプレグ27の長さ方向の両端より積層フープ26の長さ方向の両端を内側に位置させている。   The sixth hoop prepreg 26 is a laminated hoop previously integrated with the seventh straight prepreg 27, and the hoop prepreg 26 of the laminated hoop and the straight prepreg 27 of the base prepreg constitute a laminated body A2. . The length direction of the laminated hoop 26 is 1128 mm, the length of the straight prepreg 27 is 1168 mm, and both ends in the length direction of the laminated hoop 26 are located on the inside from both ends in the length direction of the straight prepreg 27.

8枚目はストレートプリプレグ28であり、管状体10の軸線方向に対して強化繊維F28の配向角を0度としている。長さは250mmとし、ヘッド側の幅は100mm、グリップ側の幅は0mmとする三角形状としている。厚みは0.082mmとし、樹脂含有率は24%としている。強化繊維F28の引張弾性率は24ton/mmとしている。 The eighth sheet is a straight prepreg 28, and the orientation angle of the reinforcing fiber F 28 is 0 degree with respect to the axial direction of the tubular body 10. The length is 250 mm, the head side width is 100 mm, and the grip side width is 0 mm. The thickness is 0.082 mm and the resin content is 24%. The tensile elastic modulus of the reinforcing fiber F28 is 24 ton / mm 2 .

次に、前記管状体10の製造方法を説明する。
管状体10はシートワインディング製法によって作製している。
まず、芯金(マンドレル)にプリプレグを巻き付けて積層していく前に、図3に示すように、前記フーププリプレグ24は積層フープとし、土台プリプレグのストレートプリプレグ25に予め積層密着させて一体化した積層体A1を作製しておく。同様に、前記フーププリプレグ26も積層フープとし、土台プリプレグのストレートプリプレグ27に予め積層密着させて一体化した積層体A2を作製しておく。
Next, a method for manufacturing the tubular body 10 will be described.
The tubular body 10 is produced by a sheet winding method.
First, before the prepreg is wound around the cored bar (mandrel) and laminated, as shown in FIG. 3, the hoop prepreg 24 is a laminated hoop, and is laminated and adhered in advance to the straight prepreg 25 of the base prepreg. A stacked body A1 is prepared. Similarly, the hoop prepreg 26 is also formed as a laminated hoop, and a laminated body A2 is prepared by being laminated and adhered in advance to the straight prepreg 27 of the base prepreg.

前記積層体A1を作成する際、図3に示すように、積層フープのフーププリプレグ24の管状体軸線方向の両端縁24a、24bを土台プリプレグのストレートプリプレグ25の管状体軸線方向の両端縁25a、25bよりも20mm内側に位置させ、フーププリプレグ24の巻回方向の初端縁24cおよび終端縁24dは、ストレートプリプレグ25の巻回方向初端縁25cと終端縁25cよりも1mm内側に位置させる。かつ、フーププリプレグ24の前記両端縁24a、24bを、図4に示すように、管状体10の両端カット位置15、16よりも10mmづつ内側に位置させる。このように位置決めして両プリプレグを貼り合わせて一体化する。
積層体A2を作成する際、積層フープのフーププリプレグ26の周縁を、土台プリプレグのストレートプリプレグ27の周縁よりも内側で、かつ管状体最終カット位置15、16よりも内側に位置させて貼り合わせて一体化する。
When creating the laminate A1, as shown in FIG. 3, both end edges 24a, 24b in the tubular body axial direction of the hoop prepreg 24 of the laminated hoop are both end edges 25a in the tubular body axial direction of the straight prepreg 25 of the base prepreg, The first end edge 24c and the end edge 24d in the winding direction of the hoop prepreg 24 are positioned 20 mm inward from 25b, and the first end edge 25c and the end edge 25c in the winding direction of the straight prepreg 25 are positioned 1 mm inside. And the said both-ends edge 24a, 24b of the hoop prepreg 24 is located 10 mm inside from the both-ends cut position 15 and 16 of the tubular body 10, as shown in FIG. Positioning in this way, the two prepregs are bonded together and integrated.
When producing the laminated body A2, the hoop prepreg 26 of the laminated hoop is bonded to the inner side of the straight prepreg 27 of the base prepreg and to the inner side of the tubular body final cut positions 15 and 16. Integrate.

前記積層体A1、A2を作成した後に、前記プリプレグ20(21〜28)を芯金(図示せず)に順次巻き付けて積層していく。
まず、芯金に、バイアスプリプレグ21、22、ストレートプリプレグ23を順次巻きつけた後、前記積層体A1をフーププリプレグ24が内周側、ストレートプリプレグ25が外周側となるように巻きつける。次いで、積層体A2をフーププリプレグ26が内周側、ストレートプリプレグ27が外周側となるように巻きつける。
最後に、ストレートプリプレグ28をヘッド側先端部に巻き付けて積層する。
After creating the laminates A1 and A2, the prepregs 20 (21 to 28) are sequentially wound around a core bar (not shown) and laminated.
First, the bias prepregs 21 and 22 and the straight prepreg 23 are sequentially wound around the metal core, and then the laminate A1 is wound so that the hoop prepreg 24 is on the inner peripheral side and the straight prepreg 25 is on the outer peripheral side. Next, the laminate A2 is wound so that the hoop prepreg 26 is on the inner peripheral side and the straight prepreg 27 is on the outer peripheral side.
Finally, the straight prepreg 28 is wound around the head side tip and laminated.

次に、プリプレグ21〜28の積層体の表面をポリエチレンテレフタレート樹脂製等のテープでラッピングしてオーブン中で加熱加圧して樹脂を硬化させて一体的に成形し、その後、芯金を引き抜いて、管状体10を形成する。   Next, the surface of the laminate of prepregs 21 to 28 is wrapped with a tape made of polyethylene terephthalate resin or the like, and heated and pressed in an oven to cure the resin, and integrally molded, and then the core metal is pulled out, A tubular body 10 is formed.

このように管状体10は、その製造工程においてフーププリプレグ24、26を単体で巻きつけず、それぞれ土台プリプレグとなるストレートプリプレグ25、27に予め積層密着させた積層体A1、A2の状態で、ストレートプリプレグ25、27と一体に巻きつけている。このように、土台プリプレグとなるストレートプリプレグ25、27の巻回数を特に増やすことなくフーププリプレグ24、26を容易に巻きつけることができ、管状体10の重量増加を抑制しながらフーププリプレグ24、26の巻き剥がれや積層不良を防止できる。   As described above, the tubular body 10 is straight in the state of the laminated bodies A1 and A2 in which the hoop prepregs 24 and 26 are not wound alone in the manufacturing process, but are laminated and adhered in advance to the straight prepregs 25 and 27 to be the base prepregs. It is wound together with the prepregs 25 and 27. In this way, the hoop prepregs 24 and 26 can be easily wound without particularly increasing the number of windings of the straight prepregs 25 and 27 serving as the base prepreg, and the hoop prepregs 24 and 26 are suppressed while suppressing an increase in the weight of the tubular body 10. Can be prevented from being peeled off and poor stacking.

また、積層体A1、A2は、積層フープのフーププリプレグ24、26を土台プリプレグのストレートプリプレグ25、27の周縁からはみ出さないように配置しているため、ストレートプリプレグ25、27のアンカー効果を一層発揮でき、フーププリプレグ24、26の巻き剥がれをより確実に防止できる。   Moreover, since the laminated bodies A1 and A2 are arranged so that the hoop prepregs 24 and 26 of the laminated hoop do not protrude from the peripheral edges of the straight prepregs 25 and 27 of the base prepreg, the anchor effect of the straight prepregs 25 and 27 is further increased. The hoop prepregs 24 and 26 can be more reliably prevented from being peeled off.

さらに、フーププリプレグ24、26の管状体軸線方向の両端縁24a、24b、26a、26bを、管状体10の両端カット位置15、16よりも内側に位置させているため、最終商品であるシャフト10’の両端17、18にフーププリプレグ24、26の前記両端縁24a、24b、26a、26bが現れず、シャフト10’の両端17、18とフーププリプレグ24、26の前記両端縁24a、24b、26a、26bとの間に必ずストレートプリプレグ25、27の積層密着部が介在する。これにより、特に、シャフト10’の両端17、18で発現しやすいフーププリプレグ24、26の巻き剥がれを効果的に防止できる。   Furthermore, since both end edges 24a, 24b, 26a, 26b of the hoop prepregs 24, 26 in the axial direction of the tubular body are positioned inside the both end cut positions 15, 16 of the tubular body 10, the shaft 10 which is the final product. The both end edges 24a, 24b, 26a, 26b of the hoop prepregs 24, 26 do not appear at both ends 17, 18 of the ', and both the end edges 24a, 24b, 26a of the both ends 17, 18 of the shaft 10' and the hoop prepregs 24, 26 appear. , 26b always includes a laminated contact portion of straight prepregs 25 and 27. Thereby, in particular, it is possible to effectively prevent the hoop prepregs 24 and 26 from being easily peeled off at both ends 17 and 18 of the shaft 10 '.

また、フーププリプレグ24、26は、厚さを0.03〜0.06mmの範囲内とし、強化繊維F24、F26の引張弾性率を30〜80ton/mmの範囲内としているため、つぶし剛性/強度と巻き付けやすさの両方をバランスよく備えることができる。 Further, the hoop prepregs 24 and 26 have a thickness in the range of 0.03 to 0.06 mm, and the tensile elastic modulus of the reinforcing fibers F24 and F26 in the range of 30 to 80 ton / mm 2. Both strength and ease of winding can be provided in a balanced manner.

さらにまた、積層体A1、A2を構成する積層フープのフーププリプレグ24、26と土台プリプレグのストレートプリプレグ25、27のいずれもが、樹脂含有率を30〜40%の範囲内としているため、高い積層密着力でフーププリプレグ24、26の巻き剥がれを防ぎながら、重量増加を抑制することができる。   Furthermore, since both the hoop prepregs 24 and 26 of the laminated hoops constituting the laminates A1 and A2 and the straight prepregs 25 and 27 of the base prepreg have a resin content within a range of 30 to 40%, a high lamination The increase in weight can be suppressed while preventing the hoop prepregs 24 and 26 from being peeled off by the adhesion.

(実施例)
以上のことを確認するために、本発明に係るゴルフクラブシャフト用管状体の実施例1および比較例1について詳述する。なお、実施例によって本発明の効果が明らかにされるが、この実施例の記載に基づいて本発明は限定されない。
(Example)
In order to confirm the above, Example 1 and Comparative Example 1 of the golf club shaft tubular body according to the present invention will be described in detail. In addition, although the effect of this invention is clarified by the Example, this invention is not limited based on description of this Example.

実施例1と比較例1は、フーププリプレグの芯材へ巻回方法のみを異ならせて作製し、密着不良の有無について評価を行った。   Example 1 and Comparative Example 1 were prepared by differentiating only the winding method around the core material of the hoop prepreg, and evaluated for the presence or absence of poor adhesion.

実施例1と比較例1は、使用する繊維強化プリプレグの繊維角度と形状を前記第1実施形態と同一とした。即ち、バイアスプリプレグ21、22、ストレートプリプレグ23、フーププリプレグ24、ストレートプリプレグ25、フーププリプレグ26、ストレートプリプレグ27、ストレートプリプレグ28を芯材に巻きつけて、シートワインディング製法によって作製した。実施例1と比較例1は、いずれも、全長を1168mmとし、重量を45gとした。   In Example 1 and Comparative Example 1, the fiber angle and shape of the fiber-reinforced prepreg used were the same as those in the first embodiment. That is, the bias prepregs 21 and 22, the straight prepreg 23, the hoop prepreg 24, the straight prepreg 25, the hoop prepreg 26, the straight prepreg 27, and the straight prepreg 28 were wound around a core material and manufactured by a sheet winding manufacturing method. In Example 1 and Comparative Example 1, the total length was 1168 mm and the weight was 45 g.

実施例1と比較例1は、前記各プリプレグ21〜28の仕様についても同一とした。具体的には、全プリプレグ21〜28にカーボン繊維を強化繊維とする東レ社製のプリプレグを用い、表1に示すとおりである。即ち、
バイアスプリプレグ21、22は、繊維種はM30S、樹脂種は#2521R、繊維の引張弾性率は30ton/mm、厚みは0.085mm、樹脂含有率(プリプレグの重量比)は24%である。
ストレートプリプレグ23は、繊維種はT700G、樹脂はを#2521R、繊維の引張弾性率は24ton/mm、厚みは0.082mm、樹脂含有率は24%である。
フーププリプレグ24、26は、繊維種はM30S、樹脂種は#2500、繊維の引張弾性率は30ton/mm、厚みは0.034mm、樹脂含有率は40%である。
ストレートプリプレグ25は、繊維種はT700G、樹脂種は#2521R、繊維の引張弾性率は24ton/mm、厚みは0.103mm、樹脂含有率を24%である。
ストレートプリプレグ27、28は、繊維種はT700G、樹脂種は#2521R、繊維の引張弾性率は24ton/mm、厚みは0.082mm、樹脂含有率は24%である。
In Example 1 and Comparative Example 1, the specifications of the prepregs 21 to 28 were the same. Specifically, prepregs manufactured by Toray Industries, Inc. using carbon fibers as reinforcing fibers are used for all the prepregs 21 to 28 as shown in Table 1. That is,
In the bias prepregs 21 and 22, the fiber type is M30S, the resin type is # 2521R, the tensile elastic modulus of the fiber is 30 ton / mm 2 , the thickness is 0.085 mm, and the resin content (weight ratio of the prepreg) is 24%.
In the straight prepreg 23, the fiber type is T700G, the resin is # 2521R, the tensile elastic modulus of the fiber is 24 ton / mm 2 , the thickness is 0.082 mm, and the resin content is 24%.
In the hoop prepregs 24 and 26, the fiber type is M30S, the resin type is # 2500, the tensile elastic modulus of the fiber is 30 ton / mm 2 , the thickness is 0.034 mm, and the resin content is 40%.
In the straight prepreg 25, the fiber type is T700G, the resin type is # 2521R, the tensile elastic modulus of the fiber is 24 ton / mm 2 , the thickness is 0.103 mm, and the resin content is 24%.
In the straight prepregs 27 and 28, the fiber type is T700G, the resin type is # 2521R, the tensile elastic modulus of the fiber is 24 ton / mm 2 , the thickness is 0.082 mm, and the resin content is 24%.

(実施例1)
フーププリプレグ24、26の巻回方法は前記第一実施形態と同一とした。即ち、積層フープのフーププリプレグ24は土台プリプレグのストレートプリプレグ25と予め積層密着させて積層体A1を作製した。積層フープのフーププリプレグ26は土台プリプレグのストレートプリプレグ27に予め積層密着させて積層体A2を作製した。
芯材へは、プリプレグ21、22、23、積層体A1、A2、プリプレグ28の順に巻き付けた。積層体A1、A2は、それぞれ積層フープのフーププリプレグ24、26を土台プリプレグのストレートプリプレグ25、27の周縁からはみ出さないように貼り合わせ、フーププリプレグ24、26が内周側となるように巻きつけた。
Example 1
The winding method of the hoop prepregs 24 and 26 is the same as that in the first embodiment. That is, the hoop prepreg 24 of the laminated hoop was preliminarily laminated and adhered to the straight prepreg 25 of the base prepreg to produce a laminate A1. The hoop prepreg 26 of the laminated hoop was laminated and adhered in advance to the straight prepreg 27 of the base prepreg to produce a laminate A2.
The prepregs 21, 22, and 23, the laminates A1 and A2, and the prepreg 28 were wound around the core material in this order. The laminates A1 and A2 are laminated so that the hoop prepregs 24 and 26 of the laminate hoops are not protruded from the peripheral edges of the straight prepregs 25 and 27 of the base prepreg, and are wound so that the hoop prepregs 24 and 26 are on the inner peripheral side. Wearing.

(比較例1)
芯材にプリプレグ21〜28を順次内周側から巻きつけた。従って、フーププリプレグ24、26も単体で1枚ずつ巻きつけた。
(Comparative Example 1)
The prepregs 21 to 28 were wound around the core material sequentially from the inner peripheral side. Accordingly, the hoop prepregs 24 and 26 were also wound one by one.

(密着不良有無の評価)
実施例1と比較例1をそれぞれ50本ずつ作製し、その作製工程において、各プリプレグの巻回後に巻回状態の目視外観チェックを行い、プリプレグ端部における密着不良(下層からの浮き上がり)を確認し、不良が見つかったものは再度密着作業を行った後に次のプリプレグの巻回を行い、全巻回を完了した。
評価結果は、実施例1については、50本すべての全巻回において密着不良は存在しなかったが、比較例1については、50本のうち13本について、フーププリプレグ24および/またはフーププリプレグ26の巻回に密着不良が見つかった。
(Evaluation of adhesion failure)
50 each of Example 1 and Comparative Example 1 were produced, and in the production process, a visual appearance check of the wound state was performed after each prepreg was wound, and adhesion failure (lifting from the lower layer) at the end of the prepreg was confirmed. Then, for those in which defects were found, the next prepreg was wound after the contact work was performed again, and the entire winding was completed.
The evaluation results showed that there was no adhesion failure in all 50 windings for Example 1, but for Comparative Example 1, 13 out of 50 hoop prepregs 24 and / or hoop prepregs 26 A poor adhesion was found in the winding.

本発明の第1実施形態に係るゴルフクラブシャフト用管状体の繊維強化プリプレグの積層構成を示す図である。It is a figure which shows the laminated structure of the fiber reinforced prepreg of the tubular body for golf club shafts which concerns on 1st Embodiment of this invention. 最終製品であるゴルフクラブシャフトの概略図である。It is the schematic of the golf club shaft which is a final product. 積層プリプレグを示す平面図である。It is a top view which shows a lamination | stacking prepreg. 管状体の両端部を示す平面図である。It is a top view which shows the both ends of a tubular body. 従来例のプリプレグ積層構成を示す断面図である。It is sectional drawing which shows the prepreg laminated structure of a prior art example.

符号の説明Explanation of symbols

10 管状体
10’ ゴルフクラブシャフト(最終製品)
20 繊維強化プリプレグ
21、22 バイアスプリプレグ
23、25、27、28 ストレートプリプレグ
24、26 フーププリプレグ
A1、A2 積層体
10 Tubular body 10 'Golf club shaft (final product)
20 Fiber reinforced prepreg 21, 22 Bias prepreg 23, 25, 27, 28 Straight prepreg 24, 26 Hoop prepreg A1, A2 Laminate

Claims (6)

強化繊維にマトリクス樹脂を含浸してなるプリプレグの積層体からなる繊維強化樹脂製の管状体の製造方法において、
強化繊維の配列方向が管状体軸線に対して傾斜して配されるバイアスプリプレグと、強化繊維の配列方向が管状体軸線に対して平行に配されるストレートプリプレグと、強化繊維の配列方向が管状体軸線に対して直角に配されるフーププリプレグとを、芯材上に巻回する工程を含み、
前記フーププリプレグのうち少なくとも1枚は積層フーププリプレグとして前記バイアスプリプレグまたは前記ストレートプリプレグからなる土台プリプレグに予め積層密着して一体化した積層体を形成おき、該積層体を巻回することによって前記土台プリプレグと一体に前記積層フーププリプレグが巻回されることを特徴とする繊維強化樹脂製の管状体の製造方法。
In the method for producing a tubular body made of a fiber reinforced resin comprising a laminate of prepregs obtained by impregnating a reinforcing fiber with a matrix resin,
Bias prepreg in which the arrangement direction of the reinforcing fibers is inclined with respect to the tubular body axis, a straight prepreg in which the arrangement direction of the reinforcing fibers is arranged in parallel to the tubular body axis, and the arrangement direction of the reinforcing fibers are tubular A step of winding a hoop prepreg arranged at right angles to the body axis on a core material;
At least one of the hoop prepregs is formed as a laminated hoop prepreg by previously laminating and adhering to a base prepreg composed of the bias prepreg or the straight prepreg and forming a laminated body and winding the laminated body to form the base. A method for producing a fiber-reinforced resin tubular body, wherein the laminated hoop prepreg is wound integrally with a prepreg.
前記土台プリプレグに積層密着する積層フーププリプレグの管状体軸線方向の両端縁および巻回終端縁のうち、少なくとも1箇所は、前記土台プリプレグの周縁と一致させ、または土台プリプレグの周縁よりも内側に位置させている請求項1に記載の繊維強化樹脂製の管状体の製造方法。   At least one of the both ends and winding end edges in the tubular body axial direction of the laminated hoop prepreg which is laminated and adhered to the base prepreg is aligned with the peripheral edge of the base prepreg, or located inside the peripheral edge of the base prepreg. A method for producing a fiber-reinforced resin tubular body according to claim 1. 請求項1または請求項2に記載の方法で製造された管状体であって、
前記積層フーププリプレグの管状体軸線方向の両端縁は、管状体の軸線方向両端位置よりも内側に位置している繊維強化樹脂製の管状体。
A tubular body manufactured by the method according to claim 1 or 2,
Both ends of the laminated hoop prepreg in the tubular body axial direction are tubular bodies made of fiber reinforced resin that are located inside the axial end positions of the tubular body.
前記積層フーププリプレグは、厚さが0.03〜0.06mm、強化繊維の引張弾性率が30〜80ton/mmとしている請求項3に記載の繊維強化樹脂製の管状体。 The laminated hoop prepreg is a tubular body made of fiber reinforced resin according to claim 3, wherein the thickness is 0.03 to 0.06 mm and the tensile elastic modulus of the reinforcing fiber is 30 to 80 ton / mm 2 . 前記積層フーププリプレグおよび/または土台プリプレグの樹脂含量率は30〜40%である請求項3または請求項4に記載の繊維強化樹脂製の管状体。   The tubular body made of fiber-reinforced resin according to claim 3 or 4, wherein the resin content of the laminated hoop prepreg and / or the base prepreg is 30 to 40%. ゴルフクラブシャフトからなる請求項3乃至請求項5のいずれか1項に記載の繊維強化樹脂製の管状体。   The tubular body made of a fiber reinforced resin according to any one of claims 3 to 5, comprising a golf club shaft.
JP2007155118A 2007-06-12 2007-06-12 Manufacturing method of tubular body made of fiber reinforced resin and golf club shaft manufactured by the method Expired - Fee Related JP4362788B2 (en)

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