JP2008292258A - Characteristic evaluation device for electrophotography photosensitive element - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a characteristic evaluation device for an electrophotography photosensitiv element, capable of responding to various characteristic evaluations for the drum-shaped photosensitive element at a low-rotation rate, such as its charging characteristic, resistance, sensitivity and the like, and capable of determining a defect without developing any image. <P>SOLUTION: The characteristic evaluation device for the electrophotography photosensitive element is equipped with at least a charging means, an exposure means and a surface potential detecting means. A transparent probe is used as the surface potential detecting means, which is made up by applying a conductive material to the surface of a glass substrate, and an exposure/detection unit is configured by unifying the transparent probe and the exposure means. A plurality of exposure/detection units are arranged around the electrophotography photosensitive element. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to an apparatus for evaluating characteristics of an electrophotographic photosensitive member used in an image forming apparatus such as a laser printer or a copying machine.

  An electrophotographic photosensitive member (hereinafter also referred to as a “photosensitive member” or an “electrostatic latent image carrier”) is the most important component in an image forming apparatus using an electrophotographic process such as a copying machine or a laser printer. One of the elements, it is necessary to satisfy various characteristics in order to bring out the performance of the image forming apparatus main body. Therefore, the photoreceptor is inspected for various characteristics relating to electrophotography before shipment. In addition, when developing a new photoconductor for use in a new electrophotographic apparatus, various characteristics relating to electrophotography of the photoconductor prototyped in the development process have been evaluated. Various characteristic evaluation apparatuses have been proposed.

  For example, in Patent Document 1, a turntable having an opening for setting a sample piece of an electrophotographic photosensitive member, a means for rotating the turntable at a high speed, and the photosensitive sample piece arranged to face the turntable. And a means for simultaneously measuring the average charging potential of the surface of the photoconductor test piece mounted on the opening of the turntable and the current flowing into the photoconductor sample piece. Is integrated with time and processed as a charged charge, and an apparatus for non-destructively and non-contactingly measuring the electrostatic capacity of a photoconductor sample piece from the relational expression of Q = C · V has been proposed. According to this proposal, the true current with respect to the current flowing into the photoconductor sample piece of the turntable that rotates at a high speed when the capacitance of the photoconductor sample piece is measured is calculated to improve the measurement accuracy of the capacitance. .

Patent Document 2 is a method for evaluating characteristics of a photoconductor, in which various values are measured by moving a cylindrical photoconductor in the direction of the generatrix with an operating unit equipped with at least a charging unit, an exposure unit, and a surface potential measuring unit. . The photoreceptor has a photoconductive layer mainly composed of amorphous silicon, the effective charging range of the charging means is 2 cm to 15 cm, the exposure means has a variable exposure amount and exposure wavelength, It is described that various characteristics can be comprehensively and highly accurately evaluated.
Patent Document 3 discloses a process for rotating an electrophotographic photosensitive member at a high speed, an electrostatic charging step for charging the photosensitive surface of the electrophotographic photosensitive member, and a photodischarge for performing photodischarge on the photosensitive surface of the electrophotographic photosensitive member. A step of detecting a current signal of a current flowing into the electrophotographic photosensitive member and performing A / D conversion, and calculating a charge amount of the electrophotographic photosensitive member calculated and a surface potential of the electrophotographic photosensitive member There has been proposed a method for calculating the capacitance of an electrophotographic photosensitive member that detects an electric potential signal, performs A / D conversion, and obtains the electrostatic capacitance of the electrophotographic photosensitive member from the obtained charging potential of the electrophotographic photosensitive member. This proposal describes that the charge amount of the electrophotographic photosensitive member is calculated as a value obtained by adding a correction value to a value obtained by integrating a current value with time.
Patent Document 4 describes an apparatus that irradiates an object that reacts to light with pulsed light and measures its light response in response to an operation command signal.

Here, as the characteristics required for the electrophotographic photoreceptor, charging ability, charge retention ability, sensitivity, and the like can be mentioned. In measuring these electrical and optical characteristics, the characteristics are often evaluated by performing corona charging and exposure as in the electrophotographic process. For example, as one of the characteristic values, there is a method in which an electrophotographic photosensitive member is regarded as a capacitor and an electrostatic capacity is obtained and evaluated. Thus, in the model in which the electrophotographic photosensitive member is regarded as a capacitor, the current flowing through the photosensitive member sample by corona charging in the dark and the surface potential at this time are simultaneously measured, and the passing current is integrated over time. As shown in the lower graph, Q = C · V (where Q is the charge amount, V is the charge potential of the photoconductor, and C is the capacitance of the photoconductor). )
When corona discharge is applied to the electrophotographic photosensitive member, its surface potential usually rises as shown in the upper graph in FIG. During this time, the charge amount of the photoreceptor changes as shown by the middle graph in FIG. That is, the charge amount (Q) is represented by an integrated value of each charge amount (q1), (q2), (q3),... (Qn) per each time (Δt) and increases. . Each charge amount (q1), (q2), (q3),... (Qn) is an integral value represented by the product of time (Δt) and current (I), and current (I) Is determined by the measured sample charging current value / S (S is the area of the charged sample). The obtained charge amount (Q) and the corresponding surface potential (V) are plotted, a straight line is drawn, and the capacitance (C) is calculated from this slope. As described in the prior art document, in this calculation method, it is necessary to calculate the capacitance by rotating at a high speed in order to create and measure a gradually charged state.

As in Patent Document 1, when the photoconductor to be measured is a test piece such as a flat plate, since the sample size is small, there is no particular problem when the electrostatic capacity is calculated by rotating at high speed. Further, as in Patent Document 3, even when the object to be measured is a photosensitive drum, a photosensitive member with a small drum diameter may cause a large problem during rotation even if there is an uneven portion of the thickness of the support. Since the shake does not become very large, the electrostatic capacity can be calculated by rotating at high speed.
However, when the drum diameter is large and the support has a non-uniform thickness portion, a very large vibration occurs during rotation due to poor weight balance. As a result, the distance from the charging means, the exposure means, and the surface potential detection means arranged around the photosensitive member is not stabilized, and a situation in which accurate measurement cannot be performed may occur. Further, when the shake is large, the charging unit, the exposing unit, and the surface potential detecting unit arranged around the photosensitive member come into contact with each other and damage to these devices and the photosensitive member occur.
Therefore, as a method of suppressing the shake, there is a method of checking and measuring a position with a poor weight balance and attaching a weight to the position to suppress the shake amount. However, a mechanism and a device for measuring an unbalanced part are required, and there is a problem that it takes time for the measurer when measuring, and the capacitance can be calculated at a low speed. There has been a demand for an apparatus for evaluating characteristics of an electrophotographic photosensitive member.

  In Patent Document 2 and Patent Document 3, a drum-shaped photoconductor can be measured, and since exposure means and a surface potential probe are provided, it is possible to evaluate photosensitive characteristics, and exposure means Since the surface potential probe (surface potential sensor) exists at different positions, it is possible to evaluate the sensitivity by rotating the drum at high speed. However, when measuring a photoconductor with a large drum diameter that cannot be rotated at high speed, it is difficult to check potential fluctuations from the start of exposure or potential fluctuations during exposure with a similar layout. A measurable characteristic evaluation apparatus has been demanded.

  Patent Document 4 is a characteristic evaluation apparatus that uses a transparent probe as a surface electrometer probe, can measure the sensitivity characteristic of the photoconductor, and can measure the sensitivity in a stopped state. However, this device is a sensitivity measurement device for test pieces, not for drum-shaped photoconductors, and it does not describe any charging conditions at the time of measurement. I didn't. Furthermore, when a transparent probe is used, there is a problem in that the transmittance is different because the number of overlapping glasses differs depending on the position of the transparent probe.

  In addition, when confirming the density unevenness of the charge generation layer (CGL) of the photoconductor generated at the time of coating, it can be easily confirmed by visually checking the appearance of the photoconductor having a small drum diameter. However, as the drum diameter increases, it is difficult to check the density unevenness of the entire drum, so there is a problem with a photoconductor having a large drum diameter. For this reason, in order to check the CGL density unevenness, a method of actually mounting it on a copying machine and evaluating it by taking an image is taken. However, it takes time and effort, and an electronic device that can easily determine CGL density unevenness. There has been a demand for an apparatus for evaluating characteristics of a photographic photoreceptor.

  As described above, the drum diameter that can be measured is limited in the method using the high-speed rotation. Therefore, it is possible to deal with various characteristics evaluation of the drum-shaped photoconductor such as charging characteristics, resistance, and sensitivity at low-speed rotation, and image output. At present, there is a demand for providing an apparatus for evaluating the characteristics of an electrophotographic photosensitive member capable of discriminating problems that lead to image defects, such as CGL density unevenness, without performing the above.

Japanese Patent Laid-Open No. 10-282057 JP 2003-29572 A JP 2003-279608 A Japanese Patent No. 3136320

  An object of the present invention is to solve various problems in the prior art and achieve the following objects. That is, the present invention can respond to various characteristics evaluation of drum-shaped photoconductors such as charging characteristics, resistance, sensitivity, etc. at low speed rotation, and can also evaluate the characteristics of electrophotographic photoconductors that can discriminate defects without performing image output. An object is to provide an apparatus.

Means for solving the problems are as follows. That is,
<1> An apparatus for evaluating characteristics of an electrophotographic photosensitive member having at least charging means, exposure means, and surface potential detection means,
The surface potential detection means is a transparent probe formed by applying a conductive material on a glass substrate,
An exposure / detection unit in which the transparent probe and the exposure means are integrated,
An apparatus for evaluating characteristics of an electrophotographic photosensitive member, wherein a plurality of the exposure / detection units are arranged around the electrophotographic photosensitive member.
<2> The apparatus for evaluating characteristics of an electrophotographic photosensitive member according to <1>, further including a correction member having a function of correcting the transmittance distribution between the transparent probe and the exposure unit.
<3> The apparatus for evaluating characteristics of an electrophotographic photosensitive member according to <2>, wherein the correction member is made of the same material as the transparent probe.
<4> The apparatus for evaluating characteristics of an electrophotographic photosensitive member according to any one of <2> to <3>, wherein the same number of glasses made of the same material as the transparent probe are arranged in the light transmission direction of the transparent probe. is there.
<5> The apparatus for evaluating characteristics of an electrophotographic photosensitive member according to any one of <1> to <4>, further including a scorotron charger having a charge control function capable of uniformly charging the electrophotographic photosensitive member.
<6> The apparatus according to any one of <1> to <5>, including a corotron charger and a scorotron charger, wherein the characteristics of the electrophotographic photosensitive member are evaluated by switching according to the characteristics for evaluating the charging unit. This is an apparatus for evaluating characteristics of an electrophotographic photosensitive member.
<7> The characteristics of the electrophotographic photosensitive member according to any one of <1> to <6>, wherein the characteristic of the electrophotographic photosensitive member is determined based on the evaluation result of the characteristics of the electrophotographic photosensitive member at a plurality of locations. Evaluation device.
<8> The apparatus for evaluating characteristics of an electrophotographic photosensitive member according to any one of <1> to <7>, wherein the electrophotographic photosensitive member has a drum shape, and the evaluation is performed at a low speed of 200 rpm or less.

  According to the present invention, conventional problems can be solved, and various characteristics evaluations such as charging characteristics, resistance, and sensitivity can be performed even at low speed rotation without being affected by the drum diameter of the electrophotographic photosensitive member. In particular, in order to evaluate image defects such as charge generation layer (CGL) density unevenness when the diameter of the photosensitive drum is large, image evaluation with an actual machine is necessary. An apparatus for evaluating characteristics of an electrophotographic photosensitive member that can be easily determined can be provided.

The electrophotographic photosensitive member characteristic evaluation apparatus of the present invention includes at least a charging unit, an exposure unit, and a surface potential detection unit, and further includes other configurations as necessary.
In the present specification, the “discharge current” is a value for determining the discharge conditions of the charging means, and is an aluminum tube (the photosensitive layer is made of the same shape (diameter, overall length, thickness)) as the photoconductor to be measured. It means a current that flows to the aluminum base tube side at that time. The output of the charging means is set in advance by this discharge current.
In the present specification, “high speed” means a speed of 1,000 rpm or more, and “low speed” means a speed of 200 rpm or less.

-Charging means-
The charging means is not particularly limited as long as it can be charged by applying a voltage to the surface of the electrophotographic photosensitive member, and can be appropriately selected according to the purpose. Examples thereof include contact charging means provided with a conductive roll, brush, film, rubber blade, etc .; non-contact charging means using corona discharge such as a corotron charger and a scorotron charger.
Among these, a scorotron charger having a charge control function capable of uniformly charging the photoreceptor is preferable.
In addition, the charging means includes a corotron charger and a scorotron charger, and these charging means can be easily switched. For example, a corotron charger is used when calculating the capacitance, and a resistance is measured. A scorotron charger can be used, and a suitable charging means can be used according to the characteristics to be evaluated.

-Exposure means-
The exposure means is not particularly limited and may be appropriately selected according to the purpose. For example, a fluorescent lamp, a tungsten lamp, a halogen lamp, a mercury lamp, a sodium lamp, a light emitting diode (LED), a semiconductor laser (LD), an electro All luminescent materials such as luminescence (EL) can be used. In order to irradiate only light in a desired wavelength range, various filters such as a sharp cut filter, a band pass filter, a near infrared cut filter, a dichroic filter, an interference filter, and a color temperature conversion filter can be used. A neutral density filter can also be used to lower the value.

-Surface potential detection means-
As the surface potential detecting means, a glass substrate and a transparent probe in which a conductive material is applied on the glass substrate are used.
The shape, structure, size and the like of the glass substrate are not particularly limited and can be appropriately selected depending on the purpose. Examples of the shape include a disk shape and a flat plate shape. . Further, the structure may be a single layer structure or a laminated structure.
There is no restriction | limiting in particular as said electroconductive material, Although it can select suitably according to the objective, For example, Indium-Tin-Oxide (ITO), a tin oxide, etc. are mentioned.

In the present invention, an exposure / detection unit in which the transparent probe and the exposure means are integrated is formed.
The method for integrating the transparent probe and the exposure means is not particularly limited and may be appropriately selected according to the purpose. For example, a method of combining the exposure means and the transparent probe via an exposure guide box , Etc.
It is preferable that a correction member having a function of correcting a transmittance distribution is provided between the transparent probe and the exposure unit.
The correction member is preferably made of the same material as the transparent probe, and the same number of glasses made of the same material as the transparent probe are preferably arranged in the light transmission direction of the transparent probe.
A plurality of the exposure / detection units are arranged around the electrophotographic photosensitive member, preferably two or more, more preferably 2 to 4.
Thereby, the result of the characteristic of the electrophotographic photosensitive member in a plurality of places can be obtained, and the quality of the electrophotographic photosensitive member can be determined based on these results.

  As the other means, there is no particular limitation on the control means of the power circuit for charging means for charging the surface of the sample to be tested and the control means of the power circuit for light source for irradiating the sample to be tested with light. Conventionally known ones can be used as they are.

-Electrophotographic photoreceptor-
The electrophotographic photosensitive member used in the electrophotographic photosensitive member characteristic evaluation apparatus of the present invention is not particularly limited as to the material, shape, structure, size, etc., and can be appropriately selected according to the purpose. Examples of the shape include a drum shape, a sheet shape, and an endless belt shape. The structure may be a single layer structure or a laminated structure, and the size can be appropriately selected according to the size, specifications, etc. of the image forming apparatus. Examples of the material include inorganic photoreceptors such as amorphous silicon, selenium, CdS, and ZnO; organic photoreceptors (OPC) such as polysilane and phthalopolymethine, and the like.

  For example, the amorphous silicon photosensitive member is heated at 50 ° C. to 400 ° C., and a vacuum deposition method, a sputtering method, an ion plating method, a thermal CVD method, a photo CVD method, a plasma CVD method, or the like is applied on the support. A photosensitive layer made of a-Si is formed by the film forming method. Among these, the plasma CVD method is particularly preferable, and specifically, a method in which the source gas is decomposed by direct current, high frequency, or microwave glow discharge to form a photosensitive layer made of a-Si on the support is preferable. .

The organic photoreceptor (OPC) has (1) optical characteristics such as a wide light absorption wavelength range and a large amount of light absorption, (2) electrical characteristics such as high sensitivity and stable charging characteristics, (3) In general, it is widely applied because of the wide selection range of materials, (4) ease of production, (5) low cost, and (6) non-toxicity. The layer structure of such an organic photoreceptor is roughly divided into a single layer structure and a laminated structure.
The single-layered photoreceptor has a support and a single-layer type photosensitive layer provided on the support, and further includes a protective layer, an intermediate layer, and other layers as necessary.
The laminated structure of the photoreceptor comprises a support, and a laminate type photosensitive layer having at least a charge generation layer and a charge transport layer in this order on the support, and further includes a protective layer and an intermediate layer as necessary. And other layers.

  The characteristics of the electrophotographic photosensitive member include charging characteristics (capacitance), resistance, sensitivity (light attenuation characteristics), and the like. These characteristics can be measured, for example, as follows.

-Measurement of capacitance-
Regarding the method for calculating the capacitance, as shown in FIG. 3 described above, the electrophotographic photosensitive member is considered as a capacitor, and the current flowing through the photosensitive member sample by corona charging and the surface potential at this time are measured. As shown in the lower graph of FIG. 3, Q = C · V (where Q is the charge charge amount, V is the charge potential of the photoconductor, and C is the electrostatic capacity of the photoconductor. The capacitance (C) is obtained from the relationship of However, since the apparatus for evaluating characteristics of an electrophotographic photoreceptor measures at a low speed, the difference between the charging means and the location of potential measurement is affected.
Here, FIG. 4 shows a potential transition graph, and FIG. 5 shows a current transition graph. As a result, the timing at which the correspondence between the potential and the charge amount coincides only with the timing of the rotation cycle, and the charge amount (Q) and the surface potential corresponding thereto can be plotted only at one rotation cycle. For example, at 200 rpm, the interval is 0.3 sec. Furthermore, the potential and current may be delayed by a noise filter, an amplifier or the like in the signal path, and it is necessary to correct it. The correction method can be achieved by adding a product obtained by multiplying the current value at the timing of plotting by a correction coefficient to the charge amount. The charge amount (Q) obtained from these and the surface potential (V) corresponding thereto are plotted, a straight line is drawn, and the capacitance (C) is calculated from this slope. FIG. 6 shows a graph of the correspondence result between the charge amount and the surface potential.
This capacitance calculation itself is processed by the controller using the surface potential and current data stored in the storage area of the controller, and the capacitance can be calculated.

-Measurement of resistance-
With respect to the method for calculating the resistance of the electrophotographic photosensitive member, the charging member is charged to a predetermined potential by a charging means, and a potential (dark decay) attenuated by subsequent natural discharge is sampled for a certain period of time. The charging potential of the electrophotographic photosensitive member that is darkly attenuated after the charging by the charging means is stopped is replaced by an equivalent circuit in which the photosensitive member is paralleled by a resistor R and a capacitance C, and the dark decay start potential is V0. V = V0e− ^{t / RC} .
Therefore, the controller calculates 1 / RC from the dark decay start potential V0 and the charging potential V after a predetermined time has elapsed, and calculates the dark resistance R per unit area of the photoreceptor from the previously calculated capacitance C. it can.

-Measurement of optical attenuation characteristics-
The sensitivity for investigating the light attenuation characteristics includes the time (s) required for the potential to attenuate to a predetermined intended potential level and the exposure light amount (monochromatic light: μW / cm ² , white light: lx). Evaluation is performed by the exposure amount (monochromatic light: μJ / cm ² , white light: lx · s) calculated by multiplication.
When the electrophotographic photosensitive member characteristic evaluation apparatus is covered with a dark box that does not transmit light, or with a dark curtain, etc., and is not covered with a dark box or dark curtain, the influence of the external environment (wind, light, temperature) during testing is affected. As a result, accurate characteristic evaluation becomes difficult. However, objects that do not affect the evaluation of the photosensitive drum, such as a controller and a signal processing circuit, do not need to be covered with a dark box or a black curtain.

Here, FIG. 1 is a schematic view showing an example of the apparatus for evaluating the characteristics of the electrophotographic photosensitive member of the present invention. The electrophotographic photosensitive member characteristic evaluation apparatus of FIG. 1 includes an exposure means 10 for exposing an electrophotographic photosensitive member (photosensitive drum) 1, a surface potential meter probe 3 for measuring the potential of the photosensitive drum 1, and a photosensitive drum 1. A corona charging means 6 for charging the battery, a power supply 7 for supplying a voltage to the corona charging means 6, a switch 11 of the power supply 7, a light source 8 for discharging the photosensitive drum 1, and an electrophotographic photosensitive member for exposing the exposed light. The exposure guide box 2 guides to the irradiation surface.
In addition to the corona charging means 6, a scorotron charger 16 is used, and has a power source 17 for supplying a voltage to the scorotron and a switch 18 for the power source 17. The power source 14 and the switch for the power source 14 are provided on the grid. 15.

The exposure means 10, the exposure guide box 2, and the surface electrometer probe (transparent probe) 3 constitute an integrated exposure / detection unit, and a plurality of the exposure / detection units are arranged around the photosensitive member ( 4 in FIG. 1). Further, glass made of the same material as that of the transparent probe having the shape shown in FIG.
In FIG. 1, a scorotron charger is used as a charge control device capable of uniformly charging the photoconductor, but a contact-type charging roller can be used as the charge control device, but as a non-contact charging means, A scorotron charger is preferred.

In the electrophotographic photosensitive member characteristic evaluation apparatus of FIG. 1, the photosensitive drum 1 has a mechanism that is rotated by a motor 12, and rotates in the direction of the arrow in FIG. A high voltage is output from the power source 7 and the photosensitive drum 1 is charged by the corona charging means 6. The current passing through the photosensitive drum 1 at the time of charging is measured and sent to 5 signal processing circuits. Note that a smoothing circuit (not shown) is incorporated in the signal processing circuit, and the smoothing circuit smoothes the passing current.
Thereafter, the digital signal is converted into a digital signal by the A / D converter and sent to the controller 13 where the digital signal is processed.

  Further, the surface potential of the photosensitive drum 1 is sent from each surface potential meter probe 3 to the surface potential meter 4 as a monitor unit, monitored, and sent to the signal processing circuit 9. After that, it is converted by the A / D converter, and then sent to the controller 13 for arithmetic processing. A motor driver in a motor 12 that rotates the photosensitive drum 1 is connected to the controller 13. In this motor driver, a function for outputting the number of revolutions, a function for remotely controlling the number of revolutions, and a position detection function are also added, so that the number of revolutions can be controlled, the number of revolutions can be recognized, and the measurement position can be confirmed.

  Each exposure / detection unit around the photosensitive drum 1 is ON / OFF controlled by a digital relay output. Further, the post-exposure potential of the photoconductor can be measured by using the exposure means 10, and when the surface potential of the photoconductor is removed, it can be removed using the light source 8 for static elimination. It is possible to evaluate characteristics such as charging characteristics and light attenuation characteristics of the drum 1. Further, the controller 13 can further calculate the result of the characteristic evaluation and determine the quality of the photosensitive member from the calculation result.

  EXAMPLES Hereinafter, although an Example demonstrates this invention concretely, this invention is not limited at all by these Examples.

(Experimental example 1)
Each type of electrophotographic photosensitive member was produced as follows using four types (30 mm, 100 mm, 178 mm, 262 mm) of drum-shaped substrates having different drum diameters.
<Production of electrophotographic photoreceptor>
First, an undercoat layer coating solution having the following composition was dip-coated on the drum-shaped substrate, followed by drying at 130 ° C. for 20 minutes to form an undercoat layer having a thickness of 3.5 μm.
Next, after dip-coating using a coating solution for charge generation layer having the following composition, drying was performed at 130 ° C. for 20 minutes to form a charge generation layer having a thickness of 0.2 μm.
Next, after dip-coating using a charge transport layer coating solution having the following composition, drying was performed at 130 ° C. for 20 minutes to form a charge transport layer having a thickness of 27 μm. Thus, an electrophotographic photosensitive member was produced.

-Undercoat layer coating solution-
-Titanium oxide (CR-EL, manufactured by Ishihara Sangyo Co., Ltd.) ... 50 parts by mass-Alkyd resin (Beckolite M6401-50, solid content 50% by mass, manufactured by Dainippon Ink & Chemicals, Inc.) ... 15 masses Parts Melamine resin (L-145-60, solid content 60% by mass, manufactured by Dainippon Ink & Chemicals, Inc.) 8 parts by mass 2-butanone 120 parts by mass

-Coating solution for charge generation layer-
・ Asymmetric bisazo pigment represented by the following structural formula: 2.5 parts by mass
・ Polyvinyl butyral (“XYHL”, manufactured by UCC): 0.5 mass part ・ Methyl ethyl ketone: 110 mass part ・ Cyclohexanone: 260 mass part

-Coating liquid for charge transport layer-
・ Polycarbonate (Z Polyca, manufactured by Teijin Chemicals Ltd.): 10 parts by mass ・ Charge transport material represented by the following structural formula: 7 parts by mass
Tetrahydrofuran ... 80 parts by massSulfur-based antioxidant represented by the following structural formula: 0.5 parts by mass
・ Silicone oil (100cs, manufactured by Shin-Etsu Chemical Co., Ltd.) ... 0.002 parts by mass

The appearance of each electrophotographic photoreceptor thus obtained was confirmed visually, and the number of confirmed charge generation layer (CGL) density irregularities and the number of density irregularities determined by an output image mounted on a copying machine were evaluated. . The results are shown in Table 1.
When the halftone image was output, it was determined whether or not the unevenness in density was within an allowable range.

* Photoconductors that were judged to have unevenness by visual appearance inspection were also confirmed to be uneven by image inspection.
From the results shown in Table 1, it was found that the unevenness in density detected by the image inspection becomes more difficult to detect by visual appearance inspection as the drum diameter increases. For this reason, it has been found that there is a need for an evaluation device that can check density unevenness without image output when the drum diameter of the photosensitive member is large.

Next, of the produced photoreceptors, four drums with each drum diameter were evaluated by using the electrophotographic photoreceptor characteristic evaluation apparatus shown in FIG. The results are shown in Table 2.
〔Judgment criteria〕
“OK” was defined as “OK” when the deflection was 0.4 mm or less when rotated at a high speed of 1,000 rpm, and “NG” was defined when the deflection exceeded 0.4 mm.
Note that a non-contact displacement sensor (eddy current displacement sensor) was used for shake measurement. As the sensor unit, ANLOG SENSOR AH-416 (aluminum specification) manufactured by Keyence Corporation was used.

From the results in Table 2, it was found that as the drum diameter was increased, the number of photoconductors with increased vibration increased and high-speed rotation became impossible. This is considered to be because the larger the drum diameter, the greater the influence of poor weight balance during rotation. In such a situation, measurement is possible by confirming a position with a poor weight balance, attaching a weight to the position, and suppressing shake. However, if measurement can be performed at a low speed, such a measurer's trouble is eliminated.

Example 1
-Measurement of sensitivity-
Using a photosensitive drum in which a photosensitive layer having the same material and composition as the IPSIO CX8000 photosensitive drum manufactured by Ricoh Co., Ltd. was formed on a drum having a drum diameter of 262 mm, a drum total length of 530 mm, and a drum thickness of 5 mm, the following conditions were used. The sensitivity was measured at
・ Drum rotation speed: 200rpm
・ Surface potential / passing current sampling interval: 0.01 sec
Sensitivity measurement was performed using the electrophotographic photosensitive member characteristic evaluation apparatus shown in FIG. 1 (using an evaluation apparatus designed and manufactured in-house).
The measurement method was as follows. First, the photoreceptor was uniformly charged to −800 V with a scorotron charger at low speed (200 rpm), and the rotation of the drum was stopped. Exposure was performed after the drum was stopped, and sensitivity measurement was performed.
As a characteristic evaluation apparatus, a GH06550B2B LD manufactured by Sharp is used as an exposure means, a power source used for the scorotron charger is a grid and wire high voltage power supply Model 1610E manufactured by TREK, and a surface potential meter is manufactured by TREK. Model 370, surface potentiometer probe (transparent probe) is Model 3629A manufactured by TREK, the power source used for the corotron charger is a high voltage power model Model 610E manufactured by TREK, and the charging means is an internal product for both the scorotron charger and the corotron charger. The light source is a custom-made LED (wavelength 660 nm) manufactured by Hayashi Watch Industry Co., Ltd., the motor is a motor unit DX6150SD manufactured by Oriental, the controller is a PC manufactured by Dell (Optiplex GX270), and A / D conversion is performed by National Instruments. PCI-6025E manufactured by Luments Co., PCI-6503 manufactured by National Instruments Co., Ltd. were used for digital output, and other in-house electrophotographic photosensitive member characteristic evaluation devices were used for other signal processing circuits.
The surface electrometer probe (transparent probe) is integrated with the exposure means via an exposure guide box.

(Comparative Example 1)
-Measurement of sensitivity-
In Example 1, sensitivity measurement was performed as follows in the same manner as in Example 1 except that the conventional electrophotographic photosensitive member characteristic evaluation apparatus (evaluation apparatus designed and manufactured in-house) shown in FIG. 2 was used. Carried out.
2 is different from the characteristic evaluation apparatus of FIG. 1 in that no scorotron charger is provided and only one corotron charger 6 is provided as the exposure means. Further, the surface potential probe 3 is not disposed at the tip of the exposure unit, but is attached directly below the photoreceptor 1. Furthermore, a normal probe (not a transparent probe) is used as the surface potential probe 3.
In the measurement method, first, the photosensitive member is rotated a plurality of times by a corotron charger at a low speed rotation (200 rpm) and charged to −800V. Thereafter, exposure was performed while rotating at low speed, and sensitivity measurement was performed.
As a characteristic evaluation apparatus, a GH06550B2B LD manufactured by Sharp is used as the exposure means, the power source used for the corotron charger is a grid and wire high voltage power supply Model 1610E manufactured by TREK, and the surface potential meter is manufactured by TREK. Model 344 made by TREK, Model 6000B-7C made by TREK, the charging means is an in-house manufactured corotron charger, and the static elimination light source is a custom-made LED (wavelength 660 nm) made by Hayashi Watch Industry Co., Ltd. The motor is a motor unit DX6150SD manufactured by Oriental, the controller is a PC manufactured by Dell (Optiplex GX270), the A / D conversion is PCI-6025E manufactured by National Instruments, and the digital output is PCI-6503 manufactured by National Instruments. Otherwise the signal processing circuit and the like of using the characteristic evaluation apparatus manufactured by made in all.

The surface potential transition graph measured in Example 1 is shown in FIG. 7, and the surface potential transition graph measured in Comparative Example 1 is shown in FIG. However, the result of FIG. 7 is a result of one exposure / detection unit.
From the results of FIGS. 7 and 8, since the situation in which the potential gradually decreases with time as shown in FIG. 7 can be accurately grasped, the sensitivity can be accurately calculated. On the other hand, in FIG. 8, the time change of the electric potential is stepped, and cannot be accurately grasped, and the sensitivity cannot be calculated accurately.
Therefore, it was found that the sensitivity cannot be accurately measured by the method (Comparative Example 1) in which the measurement is performed at a low speed while the exposure unit and the surface potential probe are separated from each other. On the other hand, it was found that the sensitivity can be measured with high accuracy by the method (Example 1) in which the exposure means and the surface potential probe are at the same position and the sensitivity measurement is performed in the stopped state. In Example 1, since a plurality of exposure / detection units are arranged, it has been found that sensitivity measurement at a plurality of locations is possible.

  Next, the transmittance of the transparent probe used in the electrophotographic photosensitive member characteristic evaluation apparatus of FIG. 1 was investigated. 9 is a schematic front view of the transparent probe, FIG. 10 is a schematic top view of the transparent probe, 19 is a vibrating electrode, 20 is glass coated with a conductive material, 21 is an opening, and 22 is a glass substrate. I found out that the number of glasses differs depending on the position.

(Example 2)
-Measurement of illuminance-
The same electrophotographic photosensitive member characteristic evaluation apparatus as that of Example 1 was used, and glass of the same material as the transparent probe having the shape shown in FIG. 11 was attached to the back surface of the transparent probe. The illuminance distribution was measured in that state.
The glass of FIG. 11 has the same size as the probe (21.89 mm × 21.89 mm) and is cut by the same size as the vibrating electrode 19, but the opening 21 size region (diameter 4. 978 mm) is a shape in which glass is left. In addition, another glass is attached to a portion between the two vibrating electrodes and overlapping the opening region.

Example 2a
-Measurement of illuminance-
The illuminance distribution was measured using the same electrophotographic photosensitive member characteristic evaluation apparatus as in Example 1. However, there was no additional glass sticking.

In both Example 2 and Example 2a, the illuminance distribution was measured by measuring the light (655 nm LD light) that passed through the transparent probe with an optical power meter (Model 3292, manufactured by YOKOGAWA), and the result of not passing through the transparent probe. The illuminance distribution was confirmed from the ratio. The illuminance distribution was measured by measuring transmitted light from point A to point B as shown in FIG.
FIG. 14 shows the result of illuminance distribution in Example 2, and FIG. 13 shows the result of illuminance distribution in Example 2a.
From the results of FIGS. 13 and 14, in order to perform measurement with high accuracy, when using a transparent probe, the same material is used so as to cover the transmission of the transparent probe between the transparent probe and the exposure means. It was found that it was necessary to attach a correction member.

  Next, a resistance at −800 V is obtained using three photosensitive drums (drum diameter 100 mm, drum overall length 360 mm, drum thickness 1.2 mm) mounted on an image forming apparatus (manufactured by Ricoh Co., Ltd., imgio MF7070). Measurement was performed (drum rotation speed was 200 rpm, surface potential / passing current sampling interval: 0.01 sec).

(Example 3)
-Measurement of resistance-
Using the same electrophotographic photosensitive member characteristic evaluation apparatus as in Example 2, resistance measurement was performed as follows. The photoreceptor was charged using a scorotron charger (grid voltage: -810 V, wire applied voltage: -5.7 kV).

Example 3a
Using the same electrophotographic photosensitive member characteristic evaluation apparatus as in Example 2, resistance measurement was performed as follows. However, a scorotron charger was not provided, and a corotron charger was used for charging the photosensitive member (wire applied voltage: -5.2 kV).

<Measurement of resistance>
The resistance was measured by rotating at a low speed (200 rpm) and charging until a predetermined potential was reached. Then, rotation was stopped and resistance was computed with the following resistance measuring method. In both Example 3 and Example 3a, in order to calculate the resistance from the time until it decays from -810V to -790V, the charge was cut off when the voltage exceeded -810V. Table 4 shows the resistance measurement start voltage and the resistance calculation result.
-Resistance measurement method-
The photosensitive member was charged to a predetermined potential by the charging means, and the potential (dark decay) attenuated by the subsequent natural discharge was sampled for a certain period of time. The charging potential of the electrophotographic photosensitive member that is darkly attenuated after the charging by the charging means is stopped is replaced by an equivalent circuit in which the photosensitive member is paralleled by a resistor R and a capacitance C, and the dark decay start potential is V0. V = V0e− ^{t / RC} . Therefore, the controller calculated 1 / RC from the dark decay start potential V0 and the charging potential V after a predetermined time, and the dark resistance R per unit area of the photoconductor was calculated from the previously calculated capacitance C.

From the results shown in Table 4, it was somewhat difficult to make the charge cutting potential constant (the photoconductor was uniform) in the state where the scorotron charger capable of uniformly charging the photoconductor was not attached (Example 3a). In the state without a chargeable scorotron charger, the surface potential rises in a stepwise manner every rotation, making it difficult to obtain a predetermined surface potential). As a result, the dark resistance calculation results also differ, and in order to obtain highly accurate measurement results, it was found that a scorotron charger with a charge control function that can uniformly charge the photoconductor is required. It was. In addition, since the charging means can be easily switched between a scorotron charger and a corotron charger, it is possible to use a corotron charger when calculating the capacitance, and a scorotron charger to measure resistance. Depending on the characteristics to be achieved, it is possible to use a suitable charging means.

Example 4
-Measurement of sensitivity-
Among the 20 photosensitive drums having a drum diameter of 262 mm shown in Table 1 of Experimental Example 1, four of which the unevenness was found by the image inspection and four of which the unevenness was not found by the image inspection are shown in FIG. The sensitivity was measured as follows using a characteristic evaluation apparatus. The results are shown in Table 5.
<Measurement method of sensitivity>
The sensitivity was measured by charging the photosensitive member to −800 V with the scorotron charger 16 while rotating at a low speed (200 rpm). Thereafter, the rotation was stopped, and the sensitivity was measured by four exposure / detection units arranged around the photoconductor. The sensitivity was calculated when the light was attenuated from −800V to −150V.

From the results in Table 5, it was found that the photoconductors in which unevenness was confirmed in the output image had large variations in sensitivity due to differences in measurement positions. As for the photosensitive member in which unevenness in density is not confirmed by visual appearance inspection and the image unevenness is confirmed by outputting an image, the electrophotographic photosensitive member characteristic evaluation apparatus in FIG. The presence or absence of a problem can be determined by checking the sensitivity variation. In addition, since the motor used has a position detection function, it is possible to check the sensitivity distribution of the photoconductor by making multiple measurements using this function.

  Next, the time spent for evaluation was measured using a photosensitive drum (drum diameter 100 mm, drum overall length 360 mm, drum wall thickness 1.2 mm) mounted on IMAIO MF7070 manufactured by Ricoh Co., Ltd. The drum rotation speed was 200 rpm, and the surface potential / passing current sampling interval was 0.01 sec. Table 6 shows the measurement results.

(Example 5)
The electrophotographic photosensitive member property evaluation apparatus of Example 4 was used. This characteristic evaluation device has a function that can measure the sensitivity variation between exposure and detection units, and a function that displays the variation between exposure and detection units on a monitor connected to the controller to judge the quality of the electrophotographic photosensitive member. And have.

(Example 5a)
The electrophotographic photosensitive member property evaluation apparatus of Example 4 was used. This characteristic evaluation apparatus has only a function of outputting the sensitivity result of each exposure / detection unit.

(Comparative Example 5b)
The electrophotographic photoreceptor was evaluated by performing image inspection in the same manner as in Experimental Example 1. The results are shown in Table 6.

From the results of Table 6, it was found that the evaluation time was shortened when a pass / fail judgment function for measuring sensitivity variations between exposure and detection units was provided. Further, since the non-destructive or non-contact evaluation can be performed by using the electrophotographic photosensitive member characteristic evaluation apparatus of the present invention, it is possible to prevent damage to the photosensitive member due to the evaluation.

  The electrophotographic photosensitive member characteristic evaluation apparatus of the present invention can cope with various characteristic evaluations of a drum-shaped photosensitive member such as charging characteristics, resistance, and sensitivity at low speed rotation, and can determine defects without performing image output. In addition, the characteristics of the electrophotographic photosensitive member can be evaluated easily and accurately without image evaluation using an actual machine.

FIG. 1 is a schematic view showing an example of an apparatus for evaluating characteristics of an electrophotographic photosensitive member according to the present invention. FIG. 2 is a schematic view showing an example of a conventional electrophotographic photosensitive member characteristic evaluation apparatus. FIG. 3 is an explanatory diagram for explaining a capacitance calculation method. FIG. 4 is a surface potential transition comparison graph measured at the time of low speed rotation (200 rpm) with the electrophotographic photosensitive member characteristic evaluation apparatus according to the present invention. FIG. 5 is a passing current transition comparison graph measured at low speed rotation (200 rpm) with the electrophotographic photosensitive member characteristic evaluation apparatus according to the present invention. FIG. 6 is a graph showing the results of the charge amount and surface potential calculated by the electrophotographic photosensitive member characteristic evaluation apparatus according to the present invention. FIG. 7 is a graph of surface potential transition in Example 1. FIG. 8 is a surface potential transition graph in Comparative Example 1. FIG. 9 is a schematic front view of a transparent probe used in the electrophotographic photosensitive member characteristic evaluation apparatus of the present invention. FIG. 10 is a schematic top view of the transparent probe of FIG. FIG. 11 is a diagram showing the shape of the glass used in Example 2. FIG. 12 is an illuminance distribution schematic diagram measured in Example 2 and Example 2a. FIG. 13 is a graph showing the result of the illuminance distribution in Example 2a. FIG. 14 is a graph showing the results of the illuminance distribution in Example 2.

Explanation of symbols

1 Electrophotographic photoreceptor (photoreceptor drum)
2 Exposure guide box 3 Surface electrometer probe (transparent probe)
DESCRIPTION OF SYMBOLS 4 Surface potential meter 5 Signal processing circuit 6 Corona charging means 7 Power supply 8 Light source for static elimination 9 Signal processing circuit 10 Exposure means 11 Power switch 12 Motor 13 Controller 14 Power supply 15 Power switch 16 Scorotron charger 17 Power supply 18 Power switch 19 Vibrating electrode 20 Glass coated with conductive material 21 Opening 22 Glass substrate

Claims (8)

An apparatus for evaluating characteristics of an electrophotographic photosensitive member having at least a charging unit, an exposure unit, and a surface potential detection unit,
The surface potential detection means is a transparent probe formed by applying a conductive material on a glass substrate,
An exposure / detection unit in which the transparent probe and the exposure means are integrated,
An apparatus for evaluating characteristics of an electrophotographic photosensitive member, wherein a plurality of the exposure / detection units are arranged around the electrophotographic photosensitive member.   The electrophotographic photosensitive member characteristic evaluation apparatus according to claim 1, further comprising a correction member having a function of correcting the transmittance distribution between the transparent probe and the exposure unit.   The electrophotographic photosensitive member characteristic evaluation apparatus according to claim 2, wherein the correction member is made of the same material as that of the transparent probe.   4. The apparatus for evaluating characteristics of an electrophotographic photosensitive member according to claim 2, wherein the same number of glasses made of the same material as that of the transparent probe are arranged in the light transmission direction of the transparent probe.   5. The apparatus for evaluating characteristics of an electrophotographic photosensitive member according to claim 1, further comprising a scorotron charger having a charge control function capable of uniformly charging the electrophotographic photosensitive member.   6. The electrophotographic photosensitive member according to claim 1, wherein the electrophotographic photosensitive member has a corotron charger and a scorotron charger, and the characteristics of the electrophotographic photosensitive member are evaluated by switching according to the characteristics for evaluating the charging means. Characteristic evaluation device.   7. The apparatus for evaluating characteristics of an electrophotographic photosensitive member according to claim 1, which has a function of judging the quality of the electrophotographic photosensitive member based on the evaluation result of the characteristics of the electrophotographic photosensitive member at a plurality of locations.   8. The apparatus for evaluating characteristics of an electrophotographic photosensitive member according to claim 1, wherein the electrophotographic photosensitive member is in a drum shape and the evaluation is performed at a low speed rotation of 200 rpm or less.